CN101463282A - Industrial briquette and technique for producing the same - Google Patents
Industrial briquette and technique for producing the same Download PDFInfo
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- CN101463282A CN101463282A CNA2007103048197A CN200710304819A CN101463282A CN 101463282 A CN101463282 A CN 101463282A CN A2007103048197 A CNA2007103048197 A CN A2007103048197A CN 200710304819 A CN200710304819 A CN 200710304819A CN 101463282 A CN101463282 A CN 101463282A
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Abstract
The invention discloses an industrial molded coal and a manufacture process thereof, which uses soft coal with high moisture and high volatilization as raw material, coking coal, sodium humic acid and clay as caking agents. The method comprises the following steps: iron is removed from the raw material soft coal, and the raw material soft coal is crushed with the crushed particle less than or equal to 3mm; solid caking agents clay and coking coal are added to the crushed soft coal, and the liquid caking agent sodium humic acid is added to the crushed soft coal to be stirred and mixed; a storage stack is retted for aging for more than 24 hours; the aged coal is subjected to a secondary stirring; the aged coal is shaped at the pressure 10-30MPa; and the shaped coal is dried at a temperature lower than 90 DEG C to manufacture the molded coal. The industrial molded coal can be used for a fixed layer pressure coal gasification furnace.
Description
Technical field
The present invention relates to a kind of moulded coal, especially a kind of industrial shaping coal and production technique thereof.
Background technology
At present, social economy is in develop rapidly, the consumption of lump coal is increasing, along with the mechanical mining of coal is increasing, natural lump coal yield falls sharply, and the imbalance between supply and demand of lump coal becomes increasingly conspicuous, and price day by day goes up, the same place of production, the price of mixed coal of equal in quality (ungarbled raw coal) and lump coal differs more than 100 yuan.The existing large-scale Coal Gasification Technology of China has: shell Coal Gasification Technology, coal water slurry gasification technology and immovable bed pressing gas technology.Because the immovable bed pressing gasization must be made raw material with lump coal, this has just restricted immovable bed pressing gas The Application of Technology.The formed coal for gasification that China is present all is an immovable bed normal pressure gas stove moulded coal, does not also have immovable bed pressing gas stove moulded coal; And the feed coal that adopts all is hard coal, and the lower bituminous coal of market value also of no use is as the moulded coal raw material, production immovable bed pressing gas stove moulded coal.
Summary of the invention
In order to solve above-mentioned problems of the prior art, the purpose of this invention is to provide a kind of pattern production greatly, cheaply, be the industrial shaping coal and the production technique thereof of raw material with the bituminous coal of high moisture content and high-volatile.
For achieving the above object, the present invention has adopted following technical scheme:
Described industrial shaping coal, its bituminous coal with high moisture content and high-volatile is raw material, binding agent is coking coal, Sodium salts humic acids, clay, the weight percent of each component is: bituminous coal is 62%~82%, coking coal is 7%~15%, and clay is 5%~10%, and Sodium salts humic acids is 6%~13%.
Described industrial shaping coal, its bituminous coal as received basis moisture content is less than 14%, and the dry ash-free basis fugitive constituent is less than 50%.
The production technique of described industrial shaping coal, its processing step is: with the deironing of raw material bituminous coal, pulverizing, the grinding particle size≤3mm of raw material; In the bituminous coal of pulverizing, add solid binder clay and coking coal, add the liquid-containing binder Sodium salts humic acids again, mix and stir; The ageing of storage stack retting system, digestion time is more than 24 hours; Secondary stirring; Extrusion forming under 10~30Mpa pressure; Dry under less than 90 ℃ temperature, make moulded coal.
The production technique of described industrial shaping coal, raw material bituminous coal is quantitative by the raw coal constant feeder, transports by belt, sends into the raw coal crusher after the raw coal tramp iron separator removes de-iron, is crushed to the following fine coal of 3mm, is transported in the stirrer B with belt; Clay is sent through the clay constant feeder, delivers to fine coal belt after the fragmentation by belt; Coking coal is sent through the coking coal constant feeder, transports by belt, after the coking coal tramp iron separator removes de-iron, sends into the coking coal crusher in crushing, and the coking coal after the fragmentation is delivered to fine coal belt after the fragmentation with belt; Sodium salts humic acids by valve control, arrives in the stirrer B by flow by gravity after the Sodium salts humic acids reactor is prepared into sodium humate solution; Mixed coal after fine coal, clay, coking coal, Sodium salts humic acids fully stir is delivered to the ageing pond through belt, and ageing was delivered to ageing coal additive bin by forklift after at least 24 hours, delivers to stirrer A through belt and carries out secondary stirring; Ageing coal after the stirring is delivered to shaper through belt again, extrusion forming under 10~30Mpa pressure; Send after the moulding in the drying kiln, under 30~90 ℃ temperature, dry, promptly make moulded coal.
The production technique of described industrial shaping coal, its moulded coal that makes can be used as the raw material of immovable bed pressing gas stove.
Owing to adopted technical scheme as mentioned above, the present invention has following superiority:
This industrial shaping coal and production technique thereof, it is a raw material with bituminous coal, and the cold strength of the moulded coal that makes is 700N/, and hot strength can reach 400N/, meet of the requirement of immovable bed pressing gas stove fully, indexs such as cold strength height, hot strength height, Heat stability is good, reactive behavior height with moulded coal.
Description of drawings
Fig. 1 is the schema of industrial shaping coal production technique.
Among the figure: 1-drying kiln; 2-coking coal crusher; 3-coking coal tramp iron separator; 4-coking coal constant feeder; 5-clay constant feeder; 6-raw coal crusher; 7-raw coal constant feeder; 8-raw coal tramp iron separator; 9-Sodium salts humic acids reactor; 10-ageing pond; 11-forklift; 12-ageing coal additive bin; 13-stirrer A; 14-shaper; 15-stirrer B.
Embodiment
Embodiment one
The component of industrial shaping coal and weight percent are: bituminous coal 62%, coking coal 15%, clay 10%, Sodium salts humic acids 13%.
By quantitative 9.3 tons/hour bituminous coal of raw coal constant feeder 7, transport by belt, after removing de-iron, raw coal tramp iron separator 8 sends into raw coal crusher 6, be crushed to the following fine coal of 3mm, be transported in the stirrer B15 with belt; 1.5 ton/hour clay send through clay constant feeder 5, deliver to fine coal belt after the fragmentation by belt; 2.25 ton/hour coking coal send through coking coal constant feeder 4, transport by belt, after coking coal tramp iron separator 3 removes de-iron, send into 2 fragmentations of coking coal crusher, the coking coal after the fragmentation is delivered to fine coal belt after the fragmentation with belt; Sodium salts humic acids by 1.95 tons/hour (not moisture) of valve control, arrives in the stirrer B15 by flow by gravity after Sodium salts humic acids reactor 9 is prepared into sodium humate solution; Mixed coal after fine coal, clay, coking coal, Sodium salts humic acids fully stir is delivered to ageing pond 10 through belt, and ageing was delivered to ageing coal additive bin 12 by forklift 11 after at least 24 hours, delivers to stirrer A 13 through belt and carries out secondary stirring; Ageing coal after the stirring is delivered to shaper 14 through belt again, extrusion forming under 10~30Mpa pressure; Send after the moulding in the drying kiln 1, under 35 ℃ temperature, dried 13~15 hours, promptly make immovable bed pressing gas stove moulded coal.
Embodiment two
The component of industrial shaping coal and weight percent are: bituminous coal 72%, coking coal 10%, clay 8%, Sodium salts humic acids 10%.
By quantitative 10.8 tons/hour bituminous coal of raw coal constant feeder 7, transport by belt, after removing de-iron, raw coal tramp iron separator 8 sends into raw coal crusher 6, be crushed to the following fine coal of 3mm, be transported in the stirrer B 15 with belt; 1.2 ton/hour clay send through clay constant feeder 5, deliver to fine coal belt after the fragmentation by belt; 1.5 ton/hour coking coal send through coking coal constant feeder 4, transport by belt, after coking coal tramp iron separator 3 removes de-iron, send into 2 fragmentations of coking coal crusher, the coking coal after the fragmentation is delivered to fine coal belt after the fragmentation with belt; Sodium salts humic acids by 1.5 tons/hour (not moisture) of valve control, arrives in the stirrer B 15 by flow by gravity after Sodium salts humic acids reactor 9 is prepared into sodium humate solution; Mixed coal after fine coal, clay, coking coal, Sodium salts humic acids fully stir is delivered to ageing pond 10 through belt, and ageing was delivered to ageing coal additive bin 12 by forklift 11 after at least 24 hours, delivers to stirrer A 13 through belt and carries out secondary stirring; Ageing coal after the stirring is delivered to shaper 14 through belt again, extrusion forming under 10~30Mpa pressure; Send after the moulding in the drying kiln 1, under 55 ℃ temperature, dried 9~11 hours, promptly make immovable bed pressing gas stove moulded coal.
Embodiment three
The component of industrial shaping coal and weight percent are: bituminous coal 82%, coking coal 7%, clay 5%, Sodium salts humic acids 6%.
By quantitative 12.3 tons/hour bituminous coal of raw coal constant feeder 7, transport by belt, after removing de-iron, raw coal tramp iron separator 8 sends into raw coal crusher 6, be crushed to the following fine coal of 3mm, be transported in the stirrer B 15 with belt; 0.75 ton/hour clay send through clay constant feeder 5, deliver to fine coal belt after the fragmentation by belt; 1.05 ton/hour coking coal send through coking coal constant feeder 4, transport by belt, after coking coal tramp iron separator 3 removes de-iron, send into 2 fragmentations of coking coal crusher, the coking coal after the fragmentation is delivered to fine coal belt after the fragmentation with belt; Sodium salts humic acids by 0.9 ton/hour (not moisture) of valve control, arrives in the stirrer B 15 by flow by gravity after Sodium salts humic acids reactor 9 is prepared into sodium humate solution; Mixed coal after fine coal, clay, coking coal, Sodium salts humic acids fully stir is delivered to ageing pond 10 through belt, and ageing was delivered to ageing coal additive bin 12 by forklift 11 after at least 24 hours, delivers to stirrer A 13 through belt and carries out secondary stirring; Ageing coal after the stirring is delivered to shaper 14 through belt again, extrusion forming under 10~30Mpa pressure; Send after the moulding in the drying kiln 1, under 80 ℃ temperature, dried 4~6 hours, promptly make immovable bed pressing gas stove moulded coal.
In the foregoing description, raw material bituminous coal requires as received basis moisture content less than 14%, and the dry ash-free basis fugitive constituent is less than 50%; Used ageing pond in the production technique, can be arranged to some every, as be divided into four every, use by turns, can guarantee digestion time.
Claims (5)
1, a kind of industrial shaping coal, it is characterized in that: its bituminous coal with high moisture content and high-volatile is raw material, binding agent is coking coal, Sodium salts humic acids, clay, the weight percent of each component is: bituminous coal is 62%~82%, coking coal is 7%~15%, clay is 5%~10%, and Sodium salts humic acids is 6%~13%.
2, industrial shaping coal as claimed in claim 1 is characterized in that: its bituminous coal as received basis moisture content is less than 14%, and the dry ash-free basis fugitive constituent is less than 50%.
3, a kind of production technique of making industrial shaping coal as claimed in claim 1, it is characterized in that: its processing step is: with the deironing of raw material bituminous coal, pulverizing, the grinding particle size≤3mm of raw material; In the bituminous coal of pulverizing, add solid binder clay and coking coal, add the liquid-containing binder Sodium salts humic acids again, mix and stir; The ageing of storage stack retting system, digestion time is more than 24 hours; Secondary stirring; Extrusion forming under 10~30Mpa pressure; Dry under less than 90 ℃ temperature, make moulded coal.
4, the production technique of industrial shaping coal as claimed in claim 3, it is characterized in that: raw material bituminous coal is quantitative by raw coal constant feeder (7), transport by belt, after removing de-iron, raw coal tramp iron separator (8) sends into raw coal crusher (6), be crushed to the following fine coal of 3mm, be transported in the stirrer B (15) with belt; Clay is sent through clay constant feeder (5), delivers to fine coal belt after the fragmentation by belt; Coking coal is sent through coking coal constant feeder (4), transports by belt, after coking coal tramp iron separator (3) removes de-iron, sends into coking coal crusher (2) fragmentation, and the coking coal after the fragmentation is delivered to fine coal belt after the fragmentation with belt; Sodium salts humic acids by valve control, arrives in the stirrer B (15) by flow by gravity after Sodium salts humic acids reactor (9) is prepared into sodium humate solution; Mixed coal after fine coal, clay, coking coal, Sodium salts humic acids fully stir is delivered to ageing pond (10) through belt, and ageing was delivered to ageing coal additive bin (12) by forklift (11) after at least 24 hours, delivers to stirrer A (13) through belt and carries out secondary stirring; Ageing coal after the stirring is delivered to shaper (14), extrusion forming under 10~30Mpa pressure through belt again; Send after the moulding in the drying kiln (1), under 30~90 ℃ temperature, dry, promptly make moulded coal.
5, the production technique of industrial shaping coal as claimed in claim 3 is characterized in that: its moulded coal that makes can be used as the raw material of immovable bed pressing gas stove.
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CN200710304819A CN101463282B (en) | 2007-12-21 | 2007-12-21 | Industrial briquette and technique for producing the same |
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Cited By (8)
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CN102372265A (en) * | 2010-08-06 | 2012-03-14 | 马叔骥 | Method for producing blast furnace phosphoric acid by adopting coke replacing with raw coal |
CN102492507A (en) * | 2011-11-16 | 2012-06-13 | 安徽天之源型煤有限公司 | Casting briquette and production method |
CN103525495A (en) * | 2013-11-04 | 2014-01-22 | 江苏良友农牧机械有限公司 | Coal dust pelletizing method |
CN104845694A (en) * | 2014-10-29 | 2015-08-19 | 薛峰 | Environment-friendly energy-saving briquette coal production device and method |
CN105754675A (en) * | 2016-03-09 | 2016-07-13 | 大同煤矿集团朔州煤电宏力再生工业股份有限公司 | Novel industrial briquette production process |
CN105778958A (en) * | 2016-03-23 | 2016-07-20 | 山煤国际能源集团临汾有限公司 | Coal blending coking system using high-sulfur coal and coal blending method of coal blending coking system |
CN106350142A (en) * | 2016-03-21 | 2017-01-25 | 中国矿业大学(北京) | Method for increasing heat stability of coal briquette |
CN107726736A (en) * | 2017-10-25 | 2018-02-23 | 西安华瑞联环保节能科技发展有限公司 | A kind of method and system for drying coal slime |
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CN1040215A (en) * | 1989-09-19 | 1990-03-07 | 马红龙 | Smoke-eliminating, moisture-proof and combustion-supporting industrial coal briquet with compound binder |
CN1038600C (en) * | 1993-01-14 | 1998-06-03 | 叶敬胜 | Binder and process for production of briquet for gasifing |
CN1211613A (en) * | 1997-09-12 | 1999-03-24 | 中国科学院福建物质结构研究所 | Method for manufacturing clean coal with anthracite and bituminous coal |
CN1337449A (en) * | 2000-08-15 | 2002-02-27 | 孟祥云 | Smoke-less coal briquette producing process with bituminite as material |
KR100468455B1 (en) * | 2000-12-19 | 2005-01-29 | 주식회사 포스코 | Coal briquette having high temperature property |
US7208023B2 (en) * | 2002-02-15 | 2007-04-24 | Hazen Research, Inc. | Dry dust control materials |
CN1563295A (en) * | 2004-03-25 | 2005-01-12 | 王茂春 | Molded coal and fabricating method |
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- 2007-12-21 CN CN200710304819A patent/CN101463282B/en not_active Expired - Fee Related
Cited By (10)
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CN102372265A (en) * | 2010-08-06 | 2012-03-14 | 马叔骥 | Method for producing blast furnace phosphoric acid by adopting coke replacing with raw coal |
CN102492507A (en) * | 2011-11-16 | 2012-06-13 | 安徽天之源型煤有限公司 | Casting briquette and production method |
CN103525495A (en) * | 2013-11-04 | 2014-01-22 | 江苏良友农牧机械有限公司 | Coal dust pelletizing method |
CN104845694A (en) * | 2014-10-29 | 2015-08-19 | 薛峰 | Environment-friendly energy-saving briquette coal production device and method |
CN104845694B (en) * | 2014-10-29 | 2017-08-29 | 薛峰 | Moulded coal environmental protection, the device and method of production energy-saving |
CN105754675A (en) * | 2016-03-09 | 2016-07-13 | 大同煤矿集团朔州煤电宏力再生工业股份有限公司 | Novel industrial briquette production process |
CN106350142A (en) * | 2016-03-21 | 2017-01-25 | 中国矿业大学(北京) | Method for increasing heat stability of coal briquette |
CN105778958A (en) * | 2016-03-23 | 2016-07-20 | 山煤国际能源集团临汾有限公司 | Coal blending coking system using high-sulfur coal and coal blending method of coal blending coking system |
CN105778958B (en) * | 2016-03-23 | 2018-12-04 | 山煤国际能源集团临汾有限公司 | High-sulphur coal coke making Coal Blending System and its blending method |
CN107726736A (en) * | 2017-10-25 | 2018-02-23 | 西安华瑞联环保节能科技发展有限公司 | A kind of method and system for drying coal slime |
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