CN101462781A - Ultraviolet water treatment apparatus - Google Patents

Ultraviolet water treatment apparatus Download PDF

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Publication number
CN101462781A
CN101462781A CNA2008101837516A CN200810183751A CN101462781A CN 101462781 A CN101462781 A CN 101462781A CN A2008101837516 A CNA2008101837516 A CN A2008101837516A CN 200810183751 A CN200810183751 A CN 200810183751A CN 101462781 A CN101462781 A CN 101462781A
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stream
water
ultraviolet
oxygenolysis
water treatment
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CNA2008101837516A
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CN101462781B (en
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山野井一郎
圆佛伊智朗
阴山晃治
原直树
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Hitachi Ltd
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Hitachi Ltd
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Abstract

The present invention provides an ultraviolet water treatment device capable of obtaining a plurality of water quality grades. The ultraviolet water treatment device of the invention includes: an ultraviolet irradiation groove (1) with an inflow path (5) and an outflow path (7), an ultraviolet ray source (2) for irradiating ultraviolet ray to water to be treated, a protection member for preventing direction contact between the water and the ultraviolet ray source (2), more than one branch path arranged between the inflow path (5) and the outflow path (7) for pumping out water to be treated from the groove (1), the ultraviolet water treatment device carries out different-period ultraviolet irradiation to the water to be treated in the ultraviolet irradiation groove between the branch path and the outflow path (7).

Description

UV water treatment equipment
Technical field
The present invention relates to obtain the UV water treatment equipment of a plurality of different quality grades.
Background technology
Ultraviolet ray is the hertzian wave of a kind of wavelength in the scope of 100~400nm.Handle in the water treatment up and down of a large amount of water at needs, use mercuryvapour lamp as ultraviolet source cheaply.Enclosing in seeing through the ultraviolet quartz glass tube of mercuryvapour lamp has mercury vapour, under the effect of the vapour pressure in the quartz glass tube that lamp is lit a lamp, generates the wavelength difference.The lamp of vapour pressure below 100Pa is called Cooper-Hewitt lamp, and generating wavelength is the monochromatic ultraviolet line of 254nm.Vapour pressure is called middle medium pressure mercury lamp at the lamp of 50~300kPa, and generating with 365nm is the light of predominant wavelength and the wavelength wide region from the ultraviolet ray below the 200nm to visible light.
In water treatment up and down, ultraviolet ray is mainly used in deactivation and the organic oxygenolysis of microorganism.The deactivation of so-called microorganism is meant the state of microorganism forfeiture fecundity, infection ability isoreactivity.The DNA of microorganism shows the peak value that absorbs near wavelength 260nm, if absorb near the ultraviolet ray this wavelength, then adjacent thymus pyrimidine (thymine) is Dimerized in the DNA chain, can not carry out duplicating of DNA, bacteria inactivation rate.
In organic oxygenolysis, though the situation of only decomposing to the organism irradiation ultraviolet radiation is also arranged, but the main light-catalyzed reaction that utilizes ultraviolet ray and photocatalyst, perhaps based on the promotes oxidn reaction of ultraviolet ray with ozone or superoxol, perhaps ultraviolet ray is decomposed with the light-catalyzed reaction of photocatalyst and ozone or superoxol etc. and the reaction after the combination of promotes oxidn reacting phase.
In light-catalyzed reaction, if illumination wavelength is at ultraviolet ray below the 400nm or the visible light more than the 400nm on the photocatalysts such as titanium oxide in being immersed in processed water, then water is decomposed and generates hydroxide radical free radical (hydroxy-radical).Free radical (radical) has strong oxidizing property, with oxidation operation, decomposition on every side.Absorbable long wavelength is by the kind decision of photocatalyst.
The ozone or the hydrogen peroxide that in the promotes oxidn reaction, use, owing to itself have oxidisability, so the oxidized decomposition of the organism in the processed water.In the promotes oxidn reaction, utilize ultraviolet ray to decompose ozone or the hydrogen peroxide that adds directly or indirectly.Under the situation of directly decomposing, the ultraviolet ray below processed water illumination wavelength 300nm.The ultraviolet light degradation ozone or the hydrogen peroxide of this frequency band generate the hydroxide radical free radical.Under the situation of decomposing indirectly, in processed water, sneak into photocatalyst.The not only ultraviolet ray of absorbing wavelength below 300nm of photocatalyst, also ultraviolet ray and the visible light of absorbing wavelength more than 300nm generates the hydroxide radical free radical.Hydroxide radical free radical ozone decomposition or hydrogen peroxide further generate the hydroxide radical free radical.Because the hydroxide radical free radical has than ozone, oxidisability that hydrogen peroxide is stronger,, organic oxidation and decomposition have been promoted so compare with the situation of independent use ozone or hydrogen peroxide.
Use under the situation of Cooper-Hewitt lamp in the deactivation of microorganism or organic oxygenolysis, the ultraviolet ray of generation is absorbed well by DNA, ozone or hydrogen peroxide.Therefore, the reaction of deactivation or promotes oxidn can be carried out expeditiously, the needed electric weight of water treatment can be reduced.On the other hand, in use under the situation of medium pressure mercury lamp, though the efficient of deactivation or promotes oxidn reaction is not high, because the ultraviolet work output that the per unit lamp body amasss is big, reduced the platform number of the needed lamp of water treatment, so have the advantage that device can miniaturization.
As such water treatment device, in [non-patent literature 1], [patent documentation 1], [patent documentation 2], disclose.
[non-patent literature 1] described water treatment device is the device that makes bacteria inactivation rate, is the structure of dipping UV-lamp in the groove of drum.[patent documentation 1] described water treatment device is the organic device of oxygenolysis, floods UV-lamp in the groove of drum, injects ozone bubbles in same groove.[patent documentation 2] described water treatment device, in internal configuration the processed liquid of collecting post's requirement in the treatment tank of UV-lamp, bottom side in treatment tank carries out aeration (aeration) and supply in turn with ozone and Air mixing gas, stir processed liquid and it is contacted with described mixed gas, impurity is carried out redox, sterilization.
The spout for the treatment of water all is one in any one device, the exposure intensity by changing ultraviolet source or handle flow etc., the control water quality treatment.That is, only can obtain a kind for the treatment of water of water quality from a device.
2003-No. 266088 communiques of [patent documentation 1] TOHKEMY
2004-No. 329988 communiques of [patent documentation 2] TOHKEMY
[non-patent literature 1] consortium as a juridical person's tap water Technical Research Center, " reduce the development research of environmental influence water purification technology (the guide collection of e-Water) ", p.285 (2005)
But, for example need sewage discharge water and reuse water to require the different processing of water quality like that sometimes in sewage disposal department.
For reuse water,, also have to require on this basis up to making organism such as odorous substance or chromatic(ity)component reduce just passable situation as long as the situation that bacteria inactivation rate is got final product is arranged.As long as under the situation that bacteria inactivation rate is got final product, the benchmark ratio sewage discharge water benchmark strictness of reuse water.For example, reuse water requires intestinal bacteria not detect/100mL, and sewage discharge water requires 3000/mL of coliform.
Therefore, if will be by the water after the benchmark processing of reuse water as sewage discharge, the water quality of discharging point of destination improves, and then handles surplus as sewage discharge water on the contrary, has the problem of the running cost increase of treatment plant.In order to use prior art more effectively to carry out water treatment, need a plurality of sewage discharge water different device of using with reuse water, exist the area change to be set greatly, the problem that cost also increases.
In addition, about requiring to reduce organic reuse water, the water quality difference of itself and sewage discharge water is bigger.This be because, in general for reducing organism, need be than making the more ultraviolet irradiation amount of volume of bacteria inactivation rate.In the reuse water of irradiation ultraviolet radiation till reducing organism, can fully reach the benchmark of bacteria inactivation rate.Like this, when the reuse water that will implement to reduce treatment of organic matters of organic during,, there is as the superfluous processing of sewage discharge water the problem of the running cost increase of treatment plant though the water quality of discharging point of destination becomes better as sewage discharge.In this case, carry out water treatment, also need a plurality of sewage discharge water different device of using with reuse water, exist the area change to be set greatly, the problem that cost also increases in order more effectively to use prior art.
Summary of the invention
The object of the present invention is to provide a kind of UV water treatment equipment that can obtain a plurality of different quality grades.
For achieving the above object, UV water treatment equipment of the present invention has: ultraviolet irradiation groove, and it has the stream of inflow and flows out stream, and the processed water that flows into from this inflow stream circulates described ultraviolet irradiation groove; Ultraviolet source, it is to described processed water irradiation ultraviolet radiation; Guard member, it prevents that described processed water from directly contacting with ultraviolet source, and sees through ultraviolet ray; And more than one branch stream, it is set at described inflow stream and flows out between the stream, extract treating water out from ultraviolet irradiation groove, described UV water treatment equipment carries out the uviolizing of different time to the processed water in the ultraviolet irradiation groove between described branch stream and the outflow stream.
In addition, possesses the oxygenolysis stream that is communicated with described branch stream in the inside of described ultraviolet irradiation groove.And this UV water treatment equipment has: the oxygenant generating unit, and it generates ozone or hydrogen peroxide; And oxygenant injection stream, it is connected with described oxygenolysis stream, injects described ozone or hydrogen peroxide.
The invention effect
According to the present invention,, can obtain the treating water of a plurality of different quality grades with a device by branch's stream is set in ultraviolet irradiation groove.Therefore, and use the situation of multiple arrangement to compare, can reduce the area that is provided with of device for the treating water that obtains a plurality of different quality grades.
Description of drawings
Fig. 1 is the longitudinal section of the UV water treatment equipment of embodiments of the invention 1;
Fig. 2 is the sectional view shown in arrow A-A of Fig. 1;
Fig. 3 is the longitudinal section of the UV water treatment equipment of present embodiment;
Fig. 4 is the sectional view shown in arrow B-B of Fig. 3;
Fig. 5 is the longitudinal section of the UV water treatment equipment of embodiments of the invention 2;
Fig. 6 is the longitudinal section of the UV water treatment equipment of embodiments of the invention 3;
Fig. 7 is the figure of expression for the specific absorption of the ultraviolet ray of sewage secondary treatment water and visible light;
Fig. 8 is the longitudinal section of the UV water treatment equipment of embodiments of the invention 4;
Fig. 9 is the longitudinal section of the UV water treatment equipment of embodiments of the invention 5;
Figure 10 is the sectional view shown in arrow C-C of Fig. 9;
Among the figure:
1-ultraviolet irradiation groove; 2-UV-lamp; 3-protective tube; 4-lamp control device; 5-inflow stream; 6,7,8-outflow stream; 9,10,43-open and close valve; 11-control valve device; 15-UV-lamp; 31-inner cylinder portion; 32-urceolus portion; 33-ultraviolet ray sees through wall; 34-influx; 35-stream; 36-oxygenant injection device; 38-photocatalyst; 41-oxygenolysis stream.
Embodiment
In conjunction with the accompanying drawings various embodiments of the present invention are described.
[embodiment 1]
In conjunction with Fig. 1~Fig. 4 embodiments of the invention 1 are described.Fig. 1 is the longitudinal section of the UV water treatment equipment of present embodiment, and Fig. 2 is the sectional view shown in arrow A-A of Fig. 1.In addition, Fig. 3 is the longitudinal section of the UV water treatment equipment of present embodiment, and Fig. 4 is the sectional view shown in arrow B-B of Fig. 3.
As shown in Figure 1 and Figure 2, the ultraviolet irradiation groove 1 of drum is to be fixed with dull and stereotyped sealed structure at two ends, and it is protective tube 3 that the guard member cylindraceous that is formed by quartz is installed between the central part of flat board.In protective tube 3 axially on ultraviolet source is set is UV-lamp 2, UV-lamp 2 is that lamp control device 4 is connected by distribution with the ultraviolet source control device.
Ultraviolet irradiation groove 1 is provided with and flows into stream 5, flows out stream 7, branch's stream promptly flows out stream 6, is provided with plural outflow stream 6.Flow into stream 5 and be arranged on the distolateral of ultraviolet irradiation groove 1, flow out the central part that stream 6 is arranged on ultraviolet irradiation groove 1, flow out stream 7 and be arranged on the end side of ultraviolet irradiation groove 1.Flow out stream 7 and be provided with open and close valve 10.On each outflow stream 6, open and close valve 9 is set, flows out stream 6 and flow out stream 8 interflow.Open and close valve 9, open and close valve 10 are connected with control valve device 11 by distribution, and are opened and closed by control valve device 11 controls.
Arrow among Fig. 1 is represented the flow direction of processed water, processed water 12 flows into from flowing into stream 5, processed water 12 after the inflow by ultraviolet irradiation groove 1 during, by UV-lamp 2 irradiation ultraviolet radiations, thereby become treating water 13, treating water 14, treating water 13 and treating water 14 flow out outside ultraviolet irradiation groove 1 from flowing out stream 8 and flowing out stream 7.If relatively shine ultraviolet energy on treating water 13 and the treating water 14, be ultraviolet irradiation amount, then shine to ultraviolet irradiation amount along the total length mobile treating water 14 of UV-lamp 2, greater than irradiation in the way of UV-lamp 2 from flowing out the ultraviolet irradiation amount of stream 6 effusive treating water 13, more microorganism is inactivated in the treating water 14.At this, ultraviolet irradiation amount is: ultraviolet irradiation amount=ultraviolet irradiation intensity * irradiation time.
In sewage disposal department, though sewage discharge water is different with the desired deactivation grade of reuse water, but by being suitable for the UV water treatment equipment of present embodiment, can more effectively generate as the treating water 13 of sewage discharge water with as treating water 14 these two kinds for the treatment of water of reuse water with a device.
Be control treating water 13 and treating water 14 flow and deactivation grade separately, by the exposure intensity of lamp control device 4 control UV-lamp 2, by control valve device 11 control open and close valves 9 separately open valve degree and open and close valve 10 open the valve degree.
In the present embodiment, though the UV water treatment equipment based on a UV-lamp 2 is illustrated, also can use a plurality of UV-lamp 15 as shown in Figure 3, Figure 4.In Fig. 3, infrared rays water treatment device shown in Figure 4; the ultraviolet irradiation groove 1 of drum is to be fixed with dull and stereotyped sealed structure at two ends; the protective tube 3 of a plurality of drums is installed in the ultraviolet irradiation groove 1 of drum, and the central shaft of described protective tube 3 is vertical with the central shaft of ultraviolet irradiation groove 1.On each protective tube 3 UV-lamp 15 is set, each UV-lamp 15 is connected with lamp control device 4 by distribution.Lamp control device 4 can be distinguished each UV-lamp of independent control.
In this case, be the deactivation grade of control treating water 13 and treating water 14,, perhaps control turning off the light, lighting a lamp the time of each UV-lamp 15 by the exposure intensity of lamp control device 4 each UV-lamp 15 of control.
Fig. 1~UV water treatment equipment shown in Figure 4 though expression is the UV water treatment equipment of internal irradiation, also can be the UV water treatment equipment of external lighting type.
[embodiment 2]
In conjunction with Fig. 5 embodiments of the invention 2 are described.Fig. 5 is the longitudinal section of UV water treatment equipment.
Present embodiment and UV water treatment equipment shown in Figure 1 constitute in the same manner; the ultraviolet irradiation groove 1 of the drum of present embodiment is to be fixed with dull and stereotyped sealed structure at two ends, and it is protective tube 3 that the guard member cylindraceous that is formed by quartz is installed between the central part of flat board.UV-lamp 2 is set in protective tube 3, and UV-lamp 2 is connected with lamp control device 4 by distribution.The ultraviolet irradiation groove 1 of present embodiment is the double pipe structure, and urceolus portion 32 and the external diameter little inner cylinder portion 31 big by the external diameter of central part form, and urceolus portion 32 is through ultraviolet ultraviolet ray with inner cylinder portion 31 and separates through wall 33.Seeing through wall 33 by ultraviolet ray is space 37 at urceolus portion 32 sides formation oxygenolysis stream, and urceolus portion 32 is communicated with by urceolus influx 34 with inner cylinder portion 31.
Distolateral a setting in inner cylinder portion 31 flows into stream 5, and the outflow stream 7 of open and close valve 10 is installed in another distolateral setting.Urceolus portion 32 from urceolus influx 34 side far away, a plurality of outflow streams 6 that open and close valve 9 is installed are set, urceolus portion 32 from the near side of urceolus influx 34, oxygenant is set injects stream 35, oxygenant injects stream 35 and is connected with oxygenant injection device 36.
Arrow among Fig. 5 is represented the flow direction of processed water, processed water 12 flows into from flowing into stream 5, processed water 12 after the inflow by ultraviolet irradiation groove 1 during, illuminated ultraviolet ray from UV-lamp 2, become the treating water 14 that microorganism is inactivated, a part flows out outside ultraviolet irradiation groove 1 from flowing out stream 7 as treating water 14.
On the other hand, processed from the processed water of urceolus influx 34 inflow urceolus portions 32 as intermediate treatment water 37, outside ultraviolet irradiation groove 1, flow out from flowing out stream 8 as treating water 13.By oxygenant injection device 36 oxygenants such as ozone or hydrogen peroxide are injected in the intermediate treatment water 37.By the ultraviolet ray of UV-lamp 2 irradiations, see through processed water 12 and ultraviolet ray through wall 33, the intermediate treatment water 37 of oxygenant has been sneaked in irradiation.Oxygenant in the intermediate treatment water 37 absorbs ultraviolet ray and generates hydroxide radical free radical, the organism in the oxygenolysis intermediate treatment water 37.
By such processing, the treating water 14 that obtain that microorganism is inactivated, the oxidized treating water 13 that has decomposed of organism and microorganism has been inactivated.In sewage disposal department, sometimes reuse water is required the high deactivation grade of ratio sewage discharge water, require deodorization, decolouring etc. to reduce organism.By using the UV water treatment equipment of present embodiment, can generate sewage discharge water by a device is that treating water 14 and reuse water are treating water 13 these two kinds for the treatment of water, can reduce device area is set.
Flow and deactivation grade for the control flow for the treatment of water 13 and oxygenolysis grade, treating water 14, the method that the exposure intensity of utilizing lamp control device 4 control UV-lamp 2 is arranged is by the method for opening the valve degree of opening valve degree and control open and close valve 10 of control valve device 11 each open and close valves 9 of control.In addition, by oxygenant injection device 36, the amount of the oxygenant of intermediate treatment water is injected in control.In the present embodiment although understand UV water treatment equipment based on a UV-lamp 2, but also can be as embodiment 1 shown in Figure 3, use a plurality of UV-lamp.In this case, turning off the light, lighting a lamp and control the method for ultraviolet irradiation amount by each UV-lamp among the control UV-lamp group arranged.And present embodiment also is applicable to the UV water treatment equipment of external lighting type.
[embodiment 3]
In conjunction with Fig. 6 embodiments of the invention 3 are described.Fig. 6 is the longitudinal section of the UV water treatment equipment of present embodiment.
Though present embodiment constitutes in the same manner with embodiment 2, the UV water treatment equipment of present embodiment is to enclose photocatalyst 38 in urceolus portion 32, removes the structure that oxygenant injects stream 35 and oxygenant injection device 36.
By a part of inflow and outflow stream 7 of the processed water after the uviolizing of UV-lamp 2 12, rest parts flows into urceolus portion 32 as intermediate treatment water 37 from urceolus influx 34.The intermediate treatment water 37 that flows into contacts the stream of inflow and outflow on one side 8 on one side with photocatalyst 38.At this moment, generated hydroxide radical free radical, the organism in the oxygenolysis intermediate treatment water 37 by the photocatalyst after the uviolizing 38.
Present embodiment have can effectively utilize in the advantage of medium pressure mercury lamp.Middle medium pressure mercury lamp is different with Cooper-Hewitt lamp, the ultraviolet ray below wavelength 300nm, also generates wavelength 300nm above ultraviolet ray and visible light.Because the deactivation that ultraviolet ray that wavelength 300nm is above and visible light are helpless to microorganism and the decomposition of oxygenant, so in embodiment 1 and embodiment 2, even medium pressure mercury lamp in using can not be utilized 300nm above ultraviolet ray and visible light.But, because photocatalyst not only can the ultraviolet ray of absorbing wavelength below 300nm, can also generate the hydroxide radical free radical by the ultraviolet ray and the visible light of absorbing wavelength more than 300nm, so can effectively utilize ultraviolet ray and visible light more than the 300nm by using photocatalyst.
In addition, by medium pressure mercury lamp in using, utilize the ultraviolet ray of wavelength below 300nm to carry out the deactivation of microorganism, organic oxygenolysis is then utilized ultraviolet ray and the visible light of wavelength more than 300nm, share wavelength region may like this, a kind of UV water treatment equipment that can effectively apply flexibly wavelength characteristic can be provided.
Fig. 7 is illustrated in the specific absorption of sewage secondary treatment water middle-ultraviolet lamp and visible light.The percentage that is absorbed by the test portion water sample when specific absorption is directly injected in the test portion water sample of 1cm with ultraviolet ray or visible light is represented.As shown in Figure 7, in sewage secondary treatment water, ultraviolet ray and the visible light of wavelength more than 300nm compared with the ultraviolet ray of wavelength below 300nm, and specific absorption is little, the difficult absorption.
Therefore, if irradiation is sent by middle medium pressure mercury lamp in secondary treatment water ultraviolet ray and visible light, then can form make wavelength more than 300nm ultraviolet ray and radiation of visible light in zone from middle medium pressure mercury lamp place far away.Be arranged on this zone by the urceolus portion 32 that will enclose photocatalyst 38, the ultraviolet ray of wavelength below 300nm can be used for the deactivation of microorganism of the processed water 12 of inner cylinder portion 31, with the ultraviolet ray of wavelength more than 300nm and the organic oxygenolysis of the visible light intermediate treatment water 37 that is used for urceolus portion 32.
And, for the processed water beyond the sewage secondary treatment water such as draining, water purification, rivers water, because also be the tendency identical, so can be identical apparatus structure with tendency shown in Figure 7.
Be the flow of control treating water 13 and the flow and the deactivation grade of oxygenolysis grade and treating water 14, by the exposure intensity of lamp control device 4 control UV-lamp 2.In addition, by each open and close valves 9 of control valve device 11 control open valve degree and open and close valve 10 open the valve degree.In the present embodiment although understand UV water treatment equipment based on a UV-lamp 2, but also can shown in embodiment 1, use a plurality of UV-lamp.In this case, turning off the light, lighting a lamp and control ultraviolet irradiation amount by each UV-lamp among the control UV-lamp group.
Though Fig. 6 expression is the UV water treatment equipment of internal irradiation, present embodiment also goes for the UV water treatment equipment of external lighting type.
[embodiment 4]
In conjunction with Fig. 8 embodiments of the invention 4 are described.Fig. 8 is the longitudinal section of the UV water treatment equipment of present embodiment.
Present embodiment constitutes similarly to Example 2, but the UV water treatment equipment of present embodiment is the structure of having enclosed photocatalyst 38 in urceolus portion 32.
In embodiment 2, shine the ultraviolet ray of sending by UV-lamp 2 at the oxygenant in the intermediate treatment water 37 of sneaking into urceolus portion 32, the decomposing oxidation agent, when generating the hydroxide radical free radical, need the ultraviolet ray of wavelength below 300nm, but as shown in Figure 7, the ultraviolet specific absorption of 12 pairs of wavelength of processed water below 300nm is big.Therefore, the diameter of inner cylinder portion 31 can not be enlarged, the processing flow for the treatment of water 14 can not be set significantly.
In embodiment 3,, also can utilize wavelength ultraviolet ray and the visible light 300nm more than little, so can enlarge the diameter of inner cylinder portion 31 to the specific absorption of processed water 12 because photocatalyst 38 is arranged in 32 inclosures of urceolus portion.But, as described in [non-patent literature 1], be generally less than oxygenolysis amount based on the promotes oxidn reaction based on the organic oxygenolysis amount of light-catalyzed reaction.Therefore,, need reduce the flow velocity of intermediate treatment water 37, prolong ultraviolet irradiation time, can not set the flow for the treatment of water 13 significantly for guaranteeing certain oxygenolysis grade.
In the present embodiment, for obtaining the flow of big treating water 13 and treating water 14, utilize the hydroxide radical free radical that is generated by the photocatalyst of enclosing in the urceolus portion 32 38, the decomposing oxidation agent further generates the hydroxide radical free radical.Thus, can be with ultraviolet ray and the visible light decomposition that is used for oxygenant more than 300nm of the wavelength that generates by middle medium pressure mercury lamp.Therefore, the diameter of inner cylinder portion 31 can be enlarged, the processing flow for the treatment of water 14 can be set significantly.In addition, because, can promote the generation of hydroxide radical free radical, so can set the processing flow for the treatment of water 13 significantly by increasing the injection rate of oxygenant.
Be the flow of control treating water 13 and the flow and the deactivation grade of oxygenolysis grade and treating water 14, by the exposure intensity of lamp control device 4 control UV-lamp 2.In addition, by the aperture of the valve of each open and close valves 9 of control valve device 11 control and the aperture of open and close valve 10.In addition, inject the amount of the oxygenant of intermediate treatment water by 36 controls of oxygenant injection device.In the present embodiment,, shown in embodiment 1, also can use a plurality of UV-lamp though the UV water treatment equipment that is provided with based on a UV-lamp 2 is illustrated.In this case, turning off the light, lighting a lamp and control ultraviolet irradiation amount by each UV-lamp among the control UV-lamp group.Though Fig. 8 expression is the UV water treatment equipment of internal irradiation, present embodiment also is applicable to the UV water treatment equipment of external lighting type.
[embodiment 5]
In conjunction with Fig. 9, Figure 10 embodiments of the invention 5 are described.Fig. 9 is the longitudinal section of the UV water treatment equipment of present embodiment, and Figure 10 is the sectional view shown in arrow C-C among Fig. 9.
As Fig. 9, shown in Figure 10, the ultraviolet irradiation groove 1 of drum is to be fixed with dull and stereotyped sealed structure at two ends, and it is protective tube 3 that the guard member cylindraceous that is formed by quartz is installed between the central part of flat board.UV-lamp 2 is set in protective tube 3, and UV-lamp 2 is connected with lamp control device 4 by distribution.
Ultraviolet irradiation groove 1 is provided with and flows into stream 5, flows out stream 7.Flow into stream 5 and be arranged on the distolateral of ultraviolet irradiation groove 1, flow out the end side that stream 7 is arranged on ultraviolet irradiation groove 1.On outflow stream 7, open and close valve 10 is set.Central part in ultraviolet irradiation groove 1 is provided with at least one oxygenolysis stream 41, and oxygenolysis stream 41 is communicated with ultraviolet irradiation groove 1 by influx 42.Oxygenolysis stream 41 is connected with oxygenant injection device 36 by the stream 35 that is used to inject oxygenant, and oxygenolysis stream 41 is connected with the outflow stream 8 with open and close valve 43.Open and close valve 9, open and close valve 10, open and close valve 43 are connected with control valve device 11 by distribution, and are opened and closed by control valve device 11 controls.And, a plurality of oxygenolysis streams 41 and open and close valve 43 also can be set.
The apparatus for ultraviolet light treamtent of present embodiment can be by adding oxygenolysis stream 41, influx 42, flowing out stream 8, open and close valve 43, stream 35, oxygenant injection device 36 on the ultraviolet irradiation groove 1 of drum, open that communicating pores etc. is easy to be added operation and realize.
The direction of arrow among Fig. 9 is represented flow direction, and processed water 12 flows in the ultraviolet irradiation groove 1 from flowing into stream 5, flows out from flowing out stream 7 as treating water 14.On the other hand, the intermediate treatment water 37 from influx 42 flows into the oxygenolysis stream 41 flows out from flowing out stream 8 as treating water 13.
Under the situation that oxygenolysis stream 41 is made by ultraviolet permeable material, can be to intermediate treatment water 37 irradiation ultraviolet radiations in the oxygenolysis stream 41, similarly to Example 1, can more effectively generate sewage discharge water by a device is that treating water 13 and reuse water are treating water 14 these two kinds for the treatment of water.
If will net wait sintering on the parts with space the photochemical catalysis carrier of photocatalyst as oxygenolysis stream 41, then processed water 12 can flow into oxygenolysis stream inside from the gap of agglomerating photocatalyst.Enclose under the situation of photocatalyst 38 in the inside of oxygenolysis stream 41, even oxygenolysis stream 41 does not use ultraviolet permeable material, also the same with embodiment 3, intermediate treatment water 37 contacts with photocatalyst 38 on one side and flows on one side when flowing out stream 8, photocatalyst 38 by uviolizing generates the hydroxide radical free radical, and the organism in the middle treating water 37 is carried out oxygenolysis.
Making oxygenolysis stream 41 with ultraviolet permeable material, and at the oxygenolysis stream 41 inner photocatalysts 38 of enclosing, inject under the situation of oxygenant, the same with embodiment 4, to the ultraviolet ray that the oxygenant irradiation that is blended in the intermediate treatment water 37 is sent by UV-lamp 2, decomposing oxidation agent, generate the hydroxide radical free radical, the hydroxide radical free radical that utilization is generated by the photocatalyst 38 of enclosing oxygenolysis stream 41 inside, the decomposing oxidation agent can further generate the hydroxide radical free radical.
Turning off the light, lighting a lamp and control ultraviolet irradiation amount by each lamp among the control UV-lamp group.In addition, though Fig. 9 expression is the UV water treatment equipment of internal irradiation, present embodiment also is applicable to the UV water treatment equipment of external lighting type.

Claims (12)

1. UV water treatment equipment, it possesses:
Guard member, it is configured in the ultraviolet wire casing, sees through ultraviolet ray;
Ultraviolet source, it is set in this guard member, irradiation ultraviolet radiation;
The ultraviolet source control device, it is connected with this ultraviolet source;
The inflow stream of processed water, it is set at the axial distolateral of described ultraviolet wire casing;
First for the treatment of water flows out stream, and its axial another that is set at described ultraviolet wire casing is distolateral, has first open and close valve;
Second for the treatment of water flows out stream, and the axial central part that it is set at described ultraviolet wire casing has second open and close valve; And
Control valve device, it controls the aperture of described first open and close valve and second open and close valve.
2. UV water treatment equipment, it possesses:
Ultraviolet irradiation groove, it has the stream of inflow and flows out stream, and the processed water that flows into from this inflow stream circulates described ultraviolet irradiation groove;
Ultraviolet source, it is to described processed water irradiation ultraviolet radiation;
Guard member, it prevents that described processed water from directly contacting with ultraviolet source, and sees through ultraviolet ray; And
More than one branch stream, it is set at described inflow stream and flows out between the stream, extracts treating water out from ultraviolet irradiation groove,
Described UV water treatment equipment carries out the uviolizing of different time to the processed water in the ultraviolet irradiation groove between described branch stream and the outflow stream.
3. UV water treatment equipment, it possesses:
Guard member, it is configured in the ultraviolet wire casing, sees through ultraviolet ray;
Ultraviolet source, it is set in this guard member, irradiation ultraviolet radiation;
The ultraviolet source control device, it is connected with this ultraviolet source;
The inflow stream of processed water, it is set at the axial distolateral of described ultraviolet wire casing;
First for the treatment of water flows out stream, and its axial another that is set at described ultraviolet wire casing is distolateral, has first open and close valve;
The oxygenolysis stream, the axial central part that it is set at described ultraviolet wire casing, have with described ultraviolet wire casing in the influx that is communicated with;
Second for the treatment of water flows out stream, and it is connected with this oxygenolysis stream, and has second open and close valve; And
Control valve device, it controls the aperture of described first open and close valve and second open and close valve.
4. UV water treatment equipment as claimed in claim 1 or 2, wherein:
Axial central part at described ultraviolet wire casing is provided with the oxygenolysis stream, and the oxygenolysis stream that is communicated with described branch stream perhaps is set.
5. as claim 3 or 4 described UV water treatment equipments, wherein:
Described oxygenolysis stream is that ultraviolet ray sees through part.
6. as claim 3 or 4 described UV water treatment equipments, it is provided with:
The oxygenant generating unit, it generates ozone or hydrogen peroxide; And
Oxygenant injects stream, and it is connected with described oxygenolysis stream, injects described ozone or hydrogen peroxide.
7. UV water treatment equipment as claimed in claim 4, wherein:
In described oxygenolysis stream, enclosed photocatalyst.
8. UV water treatment equipment as claimed in claim 5, wherein:
In described oxygenolysis stream, enclosed photocatalyst.
9. UV water treatment equipment as claimed in claim 6, wherein:
In described oxygenolysis stream, enclosed photocatalyst.
10. UV water treatment equipment as claimed in claim 7, wherein:
Described oxygenolysis stream is formed by the carrier of photocatalyst that has kept photocatalyst.
11. UV water treatment equipment as claimed in claim 8, wherein:
Described oxygenolysis stream is formed by the carrier of photocatalyst that has kept photocatalyst.
12. UV water treatment equipment as claimed in claim 9, wherein:
Described oxygenolysis stream is formed by the carrier of photocatalyst that has kept photocatalyst.
CN 200810183751 2007-12-19 2008-12-15 Ultraviolet water treatment apparatus Expired - Fee Related CN101462781B (en)

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JP2007326659 2007-12-19

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