CN101457010A - Low smoke halogen-free flame retardant ABS resin - Google Patents
Low smoke halogen-free flame retardant ABS resin Download PDFInfo
- Publication number
- CN101457010A CN101457010A CNA2007101508656A CN200710150865A CN101457010A CN 101457010 A CN101457010 A CN 101457010A CN A2007101508656 A CNA2007101508656 A CN A2007101508656A CN 200710150865 A CN200710150865 A CN 200710150865A CN 101457010 A CN101457010 A CN 101457010A
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- CN
- China
- Prior art keywords
- flame retardant
- low smoke
- smoke halogen
- free flame
- abs resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- 239000000779 smoke Substances 0.000 title claims abstract description 27
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title claims abstract description 27
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims description 31
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 17
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 11
- -1 alcohol ester Chemical class 0.000 claims description 6
- 238000005538 encapsulation Methods 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229920002943 EPDM rubber Polymers 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- 229920005669 high impact polystyrene Polymers 0.000 claims description 4
- 239000004797 high-impact polystyrene Substances 0.000 claims description 4
- 239000003094 microcapsule Substances 0.000 claims description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 150000003926 acrylamides Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 claims description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- OXUXEYPUQOBPCX-UHFFFAOYSA-N ethene;prop-1-ene;prop-2-enenitrile;styrene Chemical group C=C.CC=C.C=CC#N.C=CC1=CC=CC=C1 OXUXEYPUQOBPCX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 2
- 150000004692 metal hydroxides Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- 101100155370 Human cytomegalovirus (strain AD169) UL90 gene Proteins 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical class O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010003694 Atrophy Diseases 0.000 description 1
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 description 1
- 230000037444 atrophy Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a low smoke halogen-free flame retardant ABS-typed resin in a polymer material technical field. The low smoke halogen-free flame retardant ABS-typed resin is prepared by the high-speed mixing of ABS-typed resin, main flame retardant, auxiliary flame retardant, smoke suppressant, toughening agent, antioxidant and pigment, twin-screw extrusion, hot cutting and air cooling. The application range of the low smoke halogen-free flame retardant ABS-typed resin is limited to products with red, black or intermediate colors; has good fluidity and stability, can be widely applied to injecting and extruding processing, and can enable users to change for using under the manufacturing condition of present materials or by small regulation without complicated and lengthy regulation for a new technology; and solves limitation problems like an European Union RoHS instruction, and provides an excellent material which can be suitable for a larger market for a majority of plastic product manufacturers. The low smoke halogen-free flame retardant ABS-typed resin of the invention realizes a UL90 VO grade of flame retardant only under the situation of slightly decreasing resin mechanical performance.
Description
Technical field
The present invention relates to technical field of polymer materials, especially a kind of low smoke halogen-free flame retardant ABS resin.
Background technology
The ABS resinoid is widely used in industrial spare and accessory parts, electric equipment products shell and driving member, and office equipment and other numerous areas, these use occasions often need product to have flame retardant resistance.European Union had issued " about use some objectionable impurities instruction in electronic and electrical equipment " (RoHS instruction) in 2003, and begin to carry out on July 1st, 2006, the contained Polybrominated biphenyl and the content of Poly Brominated Diphenyl Ethers must not surpass 1000PPM in the regulation flame retardant plastics.This behave, other country is imitateed in succession, has all issued similar decree after European Union in succession.This makes traditional is the produce market atrophy gradually of fire retardant with Polybrominated biphenyl and Poly Brominated Diphenyl Ethers, and the demand of various bittern-free flame-proof materials is expanded suddenly.At present, the bittern-free flame-proof material aspect mainly is to realize halogen-free flameproof by adding a large amount of hydroxide hydrates, organic phosphates fire retardant, the composite expansion type flame retardant of phosphorus nitrogen, silicon-series five-retardant.Wherein, if realistic existing UL94V0 level is fire-retardant, hydroxide hydrate need add very a large amount of could the realization, thereby causes other performance of material to descend significantly; The organic phosphates fire retardant also needs big consumption, and much is liquid, and the processing technology complexity is difficult for using in the high temperature process field; Though the composite intumescent system of phosphorus nitrogen is studied progress to some extent at home, does not still have the mature technology that uses in the ABS field at present; Silicone-based fire retardant investigative technique difficulty is too big, and cost is too high, only is applicable to the use of a few high-end occasion.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide and can realize halogen-free flameproof, not too influence other performance of material again, and the moderate a kind of low smoke halogen-free flame retardant ABS resin of cost.
Invention is achieved through the following technical solutions:
A kind of low smoke halogen-free flame retardant ABS resin, its component and parts by weight are respectively:
75～110 parts of ABS resinoids;
8～25 parts of main flame retardants;
3～15 parts of auxiliary flame retardants;
Press down 3～10 parts of fumicants;
1～15 part of toughner;
0.05～0.8 part in oxidation inhibitor;
0.3～2 part of pigment.
And, described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: described ABS resinoid is selected from one or more in acrylonitrile-butadiene-phenylethene grafted copolymer (ABS), acrylonitrile-styrene-acrylic terpolymer (ASA), methyl methacrylate-butadiene-styrene (MBS), polystyrene (PS), high-impact polystyrene (HIPS), styrene-acrylonitrile copolymer, methyl methacrylate-acrylate-styrene copolymer (MAS), the acrylonitrile-styrene-ethylene propylene diene monomer graft polymer (AES).
And described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: described main flame retardant is a micro encapsulation red phosphorus.
And, described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: described auxiliary flame retardant is one or more in magnesium hydroxide, aluminium hydroxide, zinc borate, zinc oxide, trimeric cyanamide, cyanogen urea acid melamine salt (MCA), silicon-dioxide, the expanded graphite.
And described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: but described fumicants is one or more in ammonium sulfate, molybdenum oxide, the molybdate.
And described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: described toughner is one or more in ethylene-vinyl acetate multipolymer (EVA), butadiene resin, SBS resin, the terpolymer EP rubber resinoid (EPDM).
And, described a kind of low smoke halogen-free flame retardant ABS resin, it is characterized in that: described oxidation inhibitor is 1010,1076,3,3 '-propane thioic acid bay alcohol ester (DLTP), 3, one or more in the stearic alcohol ester (DSTP) of 3 '-propane thioic acid, the distearyl acid thiodipropionate (DSTDP).
And described a kind of low smoke halogen-free flame retardant ABS resin is characterized in that: described pigment is one or more in carbon black, titanium dioxide, phthalocyanine blue, the phthalocyanine green.
And, described micro encapsulation red phosphorus, it is characterized in that: described micro encapsulation red phosphorus is meant phosphorus content 20%～80%, uses the melamine resinoid, phenolic resinoid, Resins, epoxy, metal hydroxides or oxide compound (are selected from Zn, Al, Mg, Si, Ti, Co, Zr, Sn, Ni, more than Cu is at least a), sulfuric acid based salt, acrylamides, urea or urea resinoid, lipid acid (salt), poly-unsaturated fatty acids (salt), carbonate, in the whiteness pigment one or more are coated on the red phosphorus surface and have realized micro-capsule red phosphorus or whiteness micro-capsule red phosphorus or their arbitrary composition that the red phosphorus microencapsulation is handled at least more than one deck.
Characteristics of the present invention are:
1. this low smoke halogen-free flame retardant ABS resin, has good flowability and stable, be widely used in injection moulding and extrude processing, can so that the user under the manufacturing condition of current material or very little adjustment just can replace use, need not the tediously long novel process of complexity and debug.
2. the invention solves the restricted problem of the similar RoHS of European Union instruction and so on, for vast plastic part manufacturer provides a kind of more excellent material of big market that adapts to.
3. the present invention realizes that under the situation that just reduces the resin mechanical property slightly the UL94V0 level is fire-retardant.
4. the present invention is owing to using red phosphorus, so use range is limited in the product of redness, black and middle shade thereof.Because at present a lot of products all use black, so still adaptability is very high in the present invention.
Embodiment
The present invention is described in further detail by following examples, and following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
Embodiment: housing of TV set low smoke halogen-free flame retardant ABS PP Pipe Compound
ABS 105kg
Main flame retardant 22kg
Auxiliary flame retardant 17kg
Ammonium sulfate 2kg
Ammonium octamolybdate 5kg
Toughner 13kg
Oxidation inhibitor 0.08kg
Phthalocyanine blue 0.02kg
Carbon black 0.3kg.
With ABS resin, toughner, fire retardant, press down fumicants, oxidation inhibitor is put into high mixer mixing 5-10 minute successively under low speed, add pigment high-speed mixing blowing after 5 minutes then, obtains mixed ingredients.Mixed ingredients is joined in the twin screw mixing machine (length-to-diameter ratio is greater than 35), and in 160～210 ℃ temperature range, screw speed is no more than under the condition of 400rpm, extrudes, fervent, air-cooled, promptly obtains housing of TV set halogen-free flame retardant ABS PP Pipe Compound.
Claims (9)
1. low smoke halogen-free flame retardant ABS resin, it is characterized in that: its component and parts by weight are respectively:
75～110 parts of ABS resinoids;
8～20 parts of main flame retardants;
3～15 parts of auxiliary flame retardants;
Press down 3～10 parts of fumicants;
1～10 part of toughner;
0.2～1 part in oxidation inhibitor;
0.3～2 part of pigment.
2. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: described ABS resinoid is selected from acrylonitrile-butadiene-phenylethene grafted copolymer (ABS), acrylonitrile-styrene acrylic terpolymer (ASA), methyl methacrylate-butadiene-styrene (MBS), polystyrene (PS), high-impact polystyrene (HIPS), styrene-acrylonitrile copolymer, methyl methacrylate-acrylate-styrene copolymer (MAS), in acrylonitrile-styrene-ethylene propylene diene monomer graft polymer (AES) one or more.
3. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: described main flame retardant is a micro encapsulation red phosphorus.
4. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: described auxiliary flame retardant is one or more in magnesium hydroxide, aluminium hydroxide, zinc borate, zinc oxide, trimeric cyanamide and derivative thereof, silicon-dioxide, the expanded graphite.
5. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: but described fumicants is one or more in ammonium sulfate, molybdenum oxide, the molybdate.
6. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: described toughner is one or more in ethylene-vinyl acetate multipolymer (EVA), butadiene resin, SBS resin, the terpolymer EP rubber resinoid (EPDM).
7. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1, it is characterized in that: described oxidation inhibitor is 1010,1076,3,3 '-propane thioic acid bay alcohol ester (DLTP), 3, one or more in the stearic alcohol ester (DSTP) of 3 '-propane thioic acid, the distearyl acid thiodipropionate (DSTDP).
8. a kind of low smoke halogen-free flame retardant ABS resin according to claim 1 is characterized in that: described pigment is one or more in carbon black, titanium dioxide, phthalocyanine blue, the phthalocyanine green.
9. micro encapsulation red phosphorus according to claim 3, it is characterized in that: described micro encapsulation red phosphorus is meant phosphorus content 20%～80%, uses the melamine resinoid, phenolic resinoid, Resins, epoxy, metal hydroxides or oxide compound (are selected from Zn, Al, Mg, Si, Ti, Co, Zr, Sn, Ni, more than Cu is at least a), sulfuric acid based salt, acrylamides, urea or urea resinoid, lipid acid (salt), poly-unsaturated fatty acids (salt), carbonate, in the whiteness pigment one or more are coated on the red phosphorus surface and have realized micro-capsule red phosphorus or whiteness micro-capsule red phosphorus or their arbitrary composition that the red phosphorus microencapsulation is handled at least more than one deck.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101508656A CN101457010A (en) | 2007-12-11 | 2007-12-11 | Low smoke halogen-free flame retardant ABS resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101508656A CN101457010A (en) | 2007-12-11 | 2007-12-11 | Low smoke halogen-free flame retardant ABS resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101457010A true CN101457010A (en) | 2009-06-17 |
Family
ID=40768144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101508656A Pending CN101457010A (en) | 2007-12-11 | 2007-12-11 | Low smoke halogen-free flame retardant ABS resin |
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| Country | Link |
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| CN (1) | CN101457010A (en) |
Cited By (26)
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| CN102399412A (en) * | 2011-11-09 | 2012-04-04 | 金发科技股份有限公司 | Low-cost high-performance halogen-free flame-retardant ABS composition and preparation method and application thereof |
| CN102604316A (en) * | 2012-03-21 | 2012-07-25 | 上海瀚氏模具成型有限公司 | Low-smoke-density ABS (Acrylonitrile Butadiene Styrene) plastic for automobile interior and preparation method thereof |
| CN102604355A (en) * | 2012-03-15 | 2012-07-25 | 常州侨光电工器材有限公司 | Low smoke zero halogen (LSOH) slot dosing and processing technology thereof |
| CN102775814A (en) * | 2012-08-10 | 2012-11-14 | 四川省精细化工研究设计院 | Method for preparing micro-encapsulation red phosphorus |
| CN102875953A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Halogen-free flame retardant ABS (Acrylonitrile Butadiene StyreneAcrylonitrile Butadiene Styrene) material |
| CN103224690A (en) * | 2012-12-29 | 2013-07-31 | 金发科技股份有限公司 | Low-smoke density plastic composition and its preparation method and use |
| CN103396647A (en) * | 2013-08-15 | 2013-11-20 | 常州汉邦工程塑料有限公司 | Anti-ultraviolet low-smoke fire retardation ABS resin for school buses, and preparation method thereof |
| CN103524973A (en) * | 2012-07-07 | 2014-01-22 | 汕头市广信电气设备有限公司 | HIPS/MBS (high impact polystyrene/methyl methacrylate-butadiene-styrene) composite material for insulated enclosure of metering distribution box |
| CN103788524A (en) * | 2014-01-23 | 2014-05-14 | 南通红石科技发展有限公司 | Polystyrene flame-retardant plastic |
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2007
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| CN106398012A (en) * | 2016-08-31 | 2017-02-15 | 北海威德电子科技有限公司 | Plastic material applied to display shell and processing method |
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| CN109251552A (en) * | 2018-09-19 | 2019-01-22 | 青岛威奥时代新材料有限公司 | A kind of halogen-free high flame-retardant sheet mold materials and preparation method |
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| CN111748179B (en) * | 2020-06-15 | 2022-04-19 | 金发科技股份有限公司 | Low-smoke-density high-performance halogen-containing flame-retardant reinforced PBT (polybutylene terephthalate) compound and preparation method thereof |
| CN112552636A (en) * | 2020-12-09 | 2021-03-26 | 重庆普利特新材料有限公司 | Halogen-free flame-retardant self-extinguishing ABS resin containing nanoscale flame retardant and preparation method thereof |
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