CN101455615B - Color circle ampoule - Google Patents
Color circle ampoule Download PDFInfo
- Publication number
- CN101455615B CN101455615B CN2007101152656A CN200710115265A CN101455615B CN 101455615 B CN101455615 B CN 101455615B CN 2007101152656 A CN2007101152656 A CN 2007101152656A CN 200710115265 A CN200710115265 A CN 200710115265A CN 101455615 B CN101455615 B CN 101455615B
- Authority
- CN
- China
- Prior art keywords
- ampoule
- color
- oxide
- glaze
- circle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003708 ampul Substances 0.000 title claims abstract description 70
- 239000000463 material Substances 0.000 claims abstract description 16
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 14
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 8
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 15
- 229910052796 boron Inorganic materials 0.000 claims description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims description 5
- 210000003811 finger Anatomy 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000005297 pyrex Substances 0.000 claims description 5
- 210000003813 thumb Anatomy 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000005388 borosilicate glass Substances 0.000 abstract 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 239000003814 drug Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 241001391944 Commicarpus scandens Species 0.000 description 2
- 239000006063 cullet Substances 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Glass Compositions (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
Abstract
The invention relates to a chromatic circle ampoule belongs to technical field of pharmaceutical glass and comprises an ampoule bottle. At least partial shape of ampoule bottle is a curved neck. The neck of ampoule bottle is provided with 1-3 color frit rings. The color frit rings are broken off when the ampoule is split with force. The invention is characterized in that the material of ampoule is semi-neutral borosilicate glass which is composed of the following oxides in weight fraction: 71% of SiO2, 3%-6% of Al2O3, 5.5% of RO, 11.5% of R2O, and 6%-7% of B2O3, wherein R is Na or K. The material of color frit ring is frit composed of the following raw materials: aluminum borosilicate, sodium oxide, potassium oxide and cerium oxide. The chromatic circle ampoule of the invention adopts the material of semi-neutral borosilicate glass so that has the advantages of semi-neutral borosilicate glass and easy break ampoule.
Description
Technical field
The invention belongs to the pharmaceutical glass technical field, be specifically related to a kind of color circle ampoule easy to break.
Background technology
Ampoule bottle is a medicine packing commonly used.Common ampoule bottle is straight neck ampoule, must be easy to generate tiny cullet during quite inconvenience, and use with just broken behind the grinding wheel cut before the use, possibly be splashed into medicinal liquid.
Easy cut ampule generally is bent neck ampoule bottle, as long as suitable breaking force is provided, ampoule just can be avoided producing cullet and pollute medicine in neat the fractureing of setting in the place of fractureing, and is simultaneously easy to operate, is convenient to management.The easy cut ampule of prior art comprises " indentation color dot easy cut ampule " and " colour circle easy cut ampule " (also claiming color circle ampoule).
" development of easy cut ampule color glaze " (Zhao Chunan) discloses a kind of color glaze of color circle ampoule easy to break, and the preparing process of its color glaze is: 1) according to chemical constituent: SiO
25～10%, PbO 60～70%, and ZnO 5～10%, B
2O
310～20%, R
2O 2～5% preparation low-melting glasses; 2) give low-melting glass painted or preparation color element; 3) adopt solid, liquid attitude industrial chemicals such as terpineol, ethyl cellulose, the solvent of preparation low-melting glass; 4) with low-melting glass, pigment and solvent proportional mixing." Study on Stressed Enamel for Easy Breaking Ampoules " (Liu Zhenjia " glass and pottery " 20 8 phases of volume) also disclose similar glaze formulation and method for making.
Above-mentioned glaze exists main deficiency to be: 1) preparing process is complicated, and condition is harsh; 2) there is a large amount of lead in the glaze, poisonous, there is the probability of medicine pollution.
" the curved neck easy breaking ampoule is prone to the research of ring glaze " (Jiang Jiayu, Liu Ziquan, Liu Xueqing " glass and enamel " roll up the 23rd～26 page of the 3rd phase in June the 32nd in 2004) discloses a kind of prescription and method for making of boron matter glaze, and the main component of its glaze is: aluminium oxide, silicon oxide, boron oxide, zinc oxide, Barium monoxide, sodium oxide.
Summary of the invention
The invention provides a kind of color circle ampoule, the material of ampoule bottle adopts half neutral Pyrex, and product had both had a bottle heavy and light, highly polished, lucifuge is sheltered from heat or light, drug reservoir is long advantage, possesses the advantage of easy cut ampule again.
The following technical scheme of the concrete employing of the present invention:
A kind of color circle ampoule comprises ampoule bottle, and said ampoule bottle at least a portion is shaped as bent neck, or/and body has 1～3 color glaze ring, when firmly breaking described ampoule off with the fingers and thumb, the place neatly fractures at described color glaze ring at the cervical region of ampoule bottle, it is characterized in that,
1) material of said ampoule is half neutral Pyrex, and its composition is counted based on oxide by weight percentage: SiO
271%, Al
2O
33%～6%, RO 5.5%, R
2O 11.5%, B
2O
36%～7%; Wherein: R is Na or K;
2) material of said colour circle is the glaze of being made up of following weight fraction material: boron sikicate aluminum, sodium oxide, potassium oxide, cerium oxide.
Described color glaze is made up of the component of following weight ratio: boron sikicate aluminum: the mixture of sodium oxide and potassium oxide: cerium oxide is 47～66: 7～33: 17～46, and wherein, sodium oxide and potassium oxide mix with arbitrary proportion.
The thermal coefficient of expansion of said color glaze>=80 * 10
-6
The consumption of said color glaze is: every Kg color glaze printing volume is ampoule bottle 90～1,100,000 of 1～20ml.
Described breaking force is 30～100N.
Ampoule bottle of the present invention is bent neck ampoule, and ampoule bottle is identical on shape and the present market, and particular type has straight barrel type, funnel type, enclosed type, two ends reducing, superior reducing etc., and its identical point is that body at least a portion is shaped as bent neck.
The method for making of ampoule bottle of the present invention is identical with general ampoule bottle, be described color glaze be back cover after, to be printed onto the ampoule bottle appointed positions through printing ring technology, and then anneal.
The principle that easy cut ampule of the present invention adopts is: the low melting point powder blow that a kind of coefficient of expansion is higher than the ampoule glass twice becomes ring-type at the ampoule cervical region; The cooling back is because the coefficient of expansion of two kinds of glass is different; Produce a circle permanent stress at the ring-type position; Firmly a folding gets final product smooth fractureing, and is difficult for producing glass chip.The thermal coefficient of expansion of color glaze of the present invention is 1.5～2.5 times of glass.
Compare with other prior aries, the characteristics that the present invention gives prominence to are that ampoule bottle adopts half neutral Pyrex, and itself has resistance to water, and anti-strong acid, highly basic performance are good, its bottle heavy and light, highly polished, lucifuge is sheltered from heat or light, the medicine storage life is long; The advantage that possesses simultaneously easy cut ampule again.
Color circle ampoule of the present invention detects by GB/T2828.1-2003, and the complete quality of its quality meets the requirements:
Table 1 quality control table
| Inspection item | Inspection level (IL) | Acceptance quality level (AQL) |
| Outward appearance | I | ?4.0 |
| Internal stress | S-3 | ?2.5 |
| Circle is beated | S-3 | ?4.0 |
| Breaking force | S-3 | ?4.0 |
Description of drawings
Fig. 1 is the ampule structure sketch map of embodiment 1;
Fig. 2 is the ampule structure sketch map of embodiment 2;
Fig. 3 is the ampule structure sketch map of embodiment 3.
The specific embodiment
Embodiment 1
As shown in Figure 1, a kind of color circle ampoule, it is shaped as straight barrel type, and promptly some is bent neck shape 2 on the top of body 1, and a circle color glaze ring 3 is arranged on bent neck 2, and when breaking described ampoule off with the fingers and thumb with the breaking force of 30～100N, 3 places neatly fracture at the color glaze ring.
The material of said ampoule is half neutral Pyrex, and it forms by weight that % counts based on oxide: SiO
271%, Al
2O
33%～6%, RO 5.5%, R
2O 11.5%, B
2O
36%～7%; Wherein: R is Na or K;
Described color glaze is made up of the material of following weight ratio: boron sikicate aluminum: the mixture of sodium oxide and potassium oxide: cerium oxide is 47: 7: 17, and wherein, sodium oxide and potassium oxide mix with arbitrary proportion.Thermal coefficient of expansion through detecting said color glaze is 85 * 10
-6
Chemical composition according to glass; Adopt primary raw materials such as quartz, Anhydrite, soda, calcite, dolomite according to the described ampoule of prior art for preparing; Be described color glaze be after back cover, to be printed onto the ampoule bottle appointed positions through seal ring technology; And then anneal, annealed temperature is 500～600 degrees centigrade.
The consumption of said color glaze is: every Kg color glaze printing volume is ampoule bottle 90～1,100,000 of 1～20ml.
As shown in Figure 2, a kind of color circle ampoule, it is shaped as superior reducing type; It is bent neck shape 2 that top is promptly arranged on the top of body 1, and its top reducing has three color glaze rings 3 on bent neck 2; When breaking described ampoule off with the fingers and thumb with the breaking force of 30～100N, 3 places neatly fracture at the color glaze ring.
The material of ampoule, method for making and embodiment 1 are basic identical; Just: described color glaze is made up of the material of following weight ratio: boron sikicate aluminum: the mixture of sodium oxide and potassium oxide: cerium oxide is 66: 33: 46; Wherein, sodium oxide and potassium oxide mix with arbitrary proportion.Thermal coefficient of expansion through detecting said color glaze is 80 * 10
-6
As shown in Figure 3, a kind of color circle ampoule, it is shaped as the two ends type, and bent neck shape 2 is promptly arranged at the two ends of body 1, and a circle color glaze ring 3 is respectively arranged on bent neck 2, and when breaking described ampoule off with the fingers and thumb with the breaking force of 30～100N, 3 places neatly fracture at the color glaze ring.
The material of ampoule, method for making and embodiment 1 are basic identical; Just: described color glaze is made up of the material of following weight ratio: boron sikicate aluminum: the mixture of sodium oxide and potassium oxide: cerium oxide is 55: 20: 24; Wherein, sodium oxide and potassium oxide mix with arbitrary proportion.Thermal coefficient of expansion through detecting said color glaze is 90 * 10
-6
Claims (3)
1. a color circle ampoule comprises ampoule bottle, and said ampoule bottle at least a portion is shaped as bent neck, at the cervical region of ampoule bottle 1～3 color glaze ring is arranged, and when firmly breaking described ampoule off with the fingers and thumb, the place neatly fractures at described color glaze ring, it is characterized in that,
1) material of said ampoule is half neutral Pyrex, and its composition is counted based on oxide by weight percentage: SiO
271%, Al
2O
33%～6%, RO 5.5%, R
2O 11.5%, B
2O
36%～7%;
2) material of said colour circle is to form glaze by the material of following weight fraction: boron sikicate aluminum, sodium oxide, potassium oxide, cerium oxide;
Its composition of described color glaze is by weight percentage: boron sikicate aluminum: the mixture of sodium oxide and potassium oxide: cerium oxide is 47～66: 7～33: 17～46, and wherein, sodium oxide and potassium oxide mix with arbitrary proportion.
2. color circle ampoule according to claim 1 is characterized in that, the thermal coefficient of expansion of said color glaze>=80 * 10
-6
3. color circle ampoule according to claim 1 is characterized in that, the consumption of said color glaze is: every Kg color glaze printing volume is ampoule bottle 90～1,100,000 of 1～20ml.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101152656A CN101455615B (en) | 2007-12-14 | 2007-12-14 | Color circle ampoule |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101152656A CN101455615B (en) | 2007-12-14 | 2007-12-14 | Color circle ampoule |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101455615A CN101455615A (en) | 2009-06-17 |
| CN101455615B true CN101455615B (en) | 2012-02-29 |
Family
ID=40766917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101152656A Active CN101455615B (en) | 2007-12-14 | 2007-12-14 | Color circle ampoule |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101455615B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817276B (en) * | 2015-04-21 | 2018-01-23 | 重庆长古科技有限公司 | The processing method of one koji neck indentation colour circle easy cut ampule |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2006678A (en) * | 1977-10-22 | 1979-05-10 | Grauel & Co Kg B | Colour coding system for ampoules |
| CN1107810A (en) * | 1994-11-11 | 1995-09-06 | 山东新华制药厂 | Frit as colour ring easy to rupture for ampoule |
| CN1771018A (en) * | 2003-04-17 | 2006-05-10 | 贝尔恩德·汉森 | ampoule |
-
2007
- 2007-12-14 CN CN2007101152656A patent/CN101455615B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2006678A (en) * | 1977-10-22 | 1979-05-10 | Grauel & Co Kg B | Colour coding system for ampoules |
| CN1107810A (en) * | 1994-11-11 | 1995-09-06 | 山东新华制药厂 | Frit as colour ring easy to rupture for ampoule |
| CN1771018A (en) * | 2003-04-17 | 2006-05-10 | 贝尔恩德·汉森 | ampoule |
Non-Patent Citations (2)
| Title |
|---|
| 刘振家.易折安瓿应力釉研究.《玻璃与搪瓷》.1992,第20卷(第3期), * |
| 李道国.国际中性玻璃在药品包装领域的应用及前景.《机电信息》.2004,(第21期),19-21. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101455615A (en) | 2009-06-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU764593B2 (en) | Glass with high proportion of zirconium-oxide and its uses | |
| CN105985018B (en) | Alumina silicate glass, preparation method and application | |
| CN103922591B (en) | A kind of High-strength heat-resistant glassware | |
| CN101891501A (en) | Lead-free and cadmium-free bone china glaze and preparation process thereof | |
| KR890006537A (en) | Lead free glass for glaze materials | |
| CN101148317A (en) | Formula of medicinal neutral borosilicate glass | |
| TW200406018A (en) | Sealing material for sealing a closure of an electron tube, method for making such sealing material, and the electron tube having a closure sealed by such sealing material | |
| CN103922580B (en) | A kind of crystal quartz glass and preparation method thereof | |
| CN107032621B (en) | Green glass ceramics and preparation method and application thereof | |
| EP1966099B1 (en) | Composition, frit, enamel and ceramic components and process to make the same | |
| CN103253865B (en) | A kind of containing the exquisite glaze of crystal frit and the manufacture craft of exquisite product | |
| TW201144247A (en) | Optical glass | |
| CN101455615B (en) | Color circle ampoule | |
| CN102786202A (en) | Manufacturing method for colored fluorine-free imitation ceramic glaze | |
| WO2017110906A1 (en) | Production method for borosilicate glass | |
| JPS61281041A (en) | Alkali-free glass | |
| US2726965A (en) | Ultramarine blue enamel pigment | |
| CN103922590B (en) | A kind of lightweight quartz glass product and preparation method thereof | |
| Wang et al. | Effect of Y2O3 dopant on structure and viscosity of silicate glass and melt | |
| GB447029A (en) | Improvements relating to vitreous enamel compositions or frits for the production of signs, decorations or the like by stencilling | |
| CN101462824B (en) | Semi-neutral boron silica glass for medicinal tubed phial | |
| CN101844937B (en) | High-voltage electrotechnical porcelain glaze suitable to be used in severe cold regions and preparation method thereof | |
| JP2000351650A (en) | Black stripe material for plasma display panel | |
| JPS5626744A (en) | Low melting point glass composition | |
| CN103011598A (en) | Ground coat material of enamel glaze |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |