CN101445772B - Application of powdery polymer - Google Patents
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- CN101445772B CN101445772B CN 200810220381 CN200810220381A CN101445772B CN 101445772 B CN101445772 B CN 101445772B CN 200810220381 CN200810220381 CN 200810220381 CN 200810220381 A CN200810220381 A CN 200810220381A CN 101445772 B CN101445772 B CN 101445772B
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Abstract
The invention relates to application of powdery polymer; the powdery polymer is used for preparing a fancy soap; the prepared fancy soap mainly consists of genuine soap and powdery polymer. The powdery is used for preparing the fancy soap and used as filling material; part of the genuine soap is replaced by the powdery polymer; the prepared fancy soap mainly consists of the genuine soap and the powdery polymer. The powdery polymer is used as the component part of the fancy soap; therefore, the degreasing degree and stimulation of the fancy soap are reduced so that the fancy soap has moderate performance and is suitable for face-cleaning (namely cleaning the skin of face) under the conditions of washing-face, removing-cosmetics, and the like; meanwhile, functions of the soap such as foaming degree and decontamination, and the like are not lost so that the fancy soap is suitable for bath, the bath function is not weakened and is more moderate; furthermore, the powdery polymer has abundant source and low cost and can be degraded, thus greatly reducing the preparation cost of the fancy soap and being environment friendly.
Description
Technical field
The present invention relates to the application of powdery polymer.
Background technology
Common powdery polymer mainly contains natural family macromolecule material and semi-synthetic family macromolecule material at present.Wherein natural family macromolecule material gets by physical process or the extraction of physicochemical method usually take plant as raw material; This class material mainly contains flours (such as whole meal flour, potato flour, sweet potato flour, corn flour etc.) and starch based (such as wheat starch, potato starch, sweet potato starch, W-Gum etc.), starch based, flours polymer mainly are used for food, medicine and makeup, also can be used for textile and dyeing industry.Semi-synthetic family macromolecule material is to be got through modification by crude substance, be mainly modified-cellulose family macromolecule material and modified starch series polymeric material, wherein modified-cellulose family macromolecule material comprises carboxymethyl cellulose, methylcellulose gum, ethyl cellulose, Natvosol, hydroxypropylcellulose, Vltra tears and methylol Natvosol, and starch conversion family macromolecule material comprises carboxymethyl starch, hydroxyethylamyle, cyanoethyl starch, starch acetates, starch phosphates, cationic starch and polymerization starch; Modified-cellulose family macromolecule material and modified starch series polymeric material mainly use in industries such as makeup, oil field, buildings.
At present common perfumed soap all is to make take the soap base that obtained after the sodium hydroxide saponification by plam oil, Oleum Cocois or animal grease as starting material, its degreasing dynamics is strong, alkalescence is strong, pungency to skin is very large, therefore usually be only suitable for for shower, and be not suitable for washing one's face, clean when removing ornaments and formal dress skin of face.Continuous maturation along with biodiesel technology, plam oil, Oleum Cocois also become the main raw material(s) source of biofuel, these factors cause world market plam oil, coconut wet goods raw-material in short supply, and price significantly rises, so that the manufacturing cost of perfumed soap constantly rises.Therefore, be necessary the starting material of existing perfumed soap are selected to be improved.
Summary of the invention
Technical problem to be solved by this invention provides a kind of new purposes of powdery polymer, and powdery polymer as the manufacturing of starting material for perfumed soap, is made the perfumed soap low cost of manufacture of making, and both has been suitable for taking a shower, and is suitable for again clean.The technical scheme that adopts is as follows:
The application of powdery polymer is characterized in that: described powdery polymer is for the manufacture of perfumed soap, and the perfumed soap of making mainly is comprised of soap base and powdery polymer.
In preferred version, the method for utilizing powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with following raw material by following weight ratio: soap base 20-70 part, powdery polymer 20-70 part, lubricating auxiliary agent 0-25 part, water 0-20 part, sanitas 0-1 part, whitening agent 0-5 part, essence 0-2 part;
(2) water and sanitas, whitening agent are mixed, obtain the aqueous solution;
(3) soap base is added agitator kettle, the aqueous solution that again step (2) obtained adds agitator kettle, and is stirred to and mixes;
(4) powdery polymer is added agitator kettle, and be stirred to and mix;
(5) lubricating auxiliary agent and essence are mixed, then add agitator kettle, and be stirred to and mix, obtain mixture;
(6) mixture that step (5) is obtained is milled, is pushed, and the various raw materials in the mixture are further mixed;
(7) mixture that step (6) is obtained pushes by single screw extrusion machine, extrudes bar;
(8) bar of extruding in step (7) prints (can adopt the printer that is connected with cooling fluid to print), and carries out stripping and slicing, can obtain perfumed soap.
The weight ratio of lubricating auxiliary agent is 5-15 part in the preferred above-mentioned steps (1).
The temperature of single screw extrusion machine die head is between 30 ℃ to 70 ℃ in the preferred above-mentioned steps (7).
The purpose of printing in the above-mentioned steps (8) is to make the perfumed soap surface have required literal and/or pattern.
In more preferably scheme, in order to make the perfumed soap of making have shower, clean function in addition, for example, make perfumed soap have physical beauty hold or invigorate blood circulation, the functions such as whitening, tender skin, (such as quartz sand powder, polypropylene powder, polyethylene powder, chrysanthemum sheet, walnut powder, ginseng powder or ginseng tablet, wherein the fineness of quartz sand powder, polypropylene powder and polyethylene powder is generally the 80-500 order preferably also to be equipped with functional additive in above-mentioned steps (1); These functional additives can use separately, also can compound use) 0.1-10 part; Between step (3) and step (4), increase step (3-2), functional additive is added agitator kettle, and be stirred to and mix.The above-mentioned functions additive does not change the original attribute of perfumed soap.
Above-mentioned powdery polymer can be powdery natural high molecular substance or the semi-synthetic polymer substance of powdery, the perhaps mixture of powdery natural high molecular substance and the semi-synthetic polymer substance of powdery.Wherein natural high molecular substance gets by physical process or the extraction of physicochemical method usually take plant as raw material; This class material mainly contains flours (such as whole meal flour, potato flour, sweet potato flour, corn flour etc.) and starch based (such as wheat starch, potato starch, sweet potato starch, W-Gum etc.).Semi-synthetic polymer substance is to be got through modification by crude substance, be mainly modified-cellulose family macromolecule material and modified starch series polymeric material, wherein modified-cellulose family macromolecule material comprises carboxymethyl cellulose, methylcellulose gum, Walocel MT 20.000PV, ethyl cellulose, Natvosol, hydroxypropylcellulose, Vltra tears and methylol Natvosol, and the modified starch series polymeric material comprises carboxymethyl starch, hydroxyethylamyle, cyanoethyl starch, starch acetates, starch phosphates, cationic starch and polymerization starch.Powdery polymer of the present invention can be a kind of in the above-mentioned various polymer substance or multiple mixture wherein.
Above-mentioned soap base can adopt a kind of in plant soap base and the animal soap base or both mixtures.The plant soap base can be obtained after the sodium hydroxide saponification by plam oil or Oleum Cocois, and the animal soap base can be obtained after the sodium hydroxide saponification by animal grease.
After adopting powdery polymer to replace the part soap base to form to mix soap base, it is larger to mix soap base viscosity, and tending to run in actual production can not normal extrusion shaping, demoulding difficulty, print speed is slow even the problem that can not print.The effect of above-mentioned lubricating auxiliary agent is to reduce the viscosity of mixing soap base, increases the plasticity and the force of cohesion that mix soap base, makes and mixes normally shaping, the demoulding and printing of soap base.Above-mentioned lubricating auxiliary agent can be a kind of in polyalcohols material (such as ethylene glycol, propylene glycol, glycerol, sorbyl alcohol, wych-elm alcohol, tetramethylolmethane, hexadecanol, stearyl alcohol, two Lauryl Alcohols, polyoxyethylene glycol, polypropylene glycol, polyglycerol and polysorbate), glucose material (material that namely has the glucose structure), urea, the polyacrylamide or multiple kind mixture wherein.
The effect of above-mentioned water is that sanitas, whitening agent, soap base, powdery polymer can be mixed uniformly, and it is reached be fit to mill, the purpose of shaping, printing.Most preferably water is deionized water.
The effect of foregoing preservatives is to prevent perfumed soap moldy metamorphism in use and storage process.Foregoing preservatives can be a kind of in isothiazolinone (being Kathon CG), Sodium Benzoate, glycolylurea (being DMDMH), diazonium alkyl imidazole urea (namely extremely beautiful), Tegosept M and the propylben or multiple mixture wherein.
The effect of above-mentioned whitening agent is to make perfumed soap more attractive in appearance in appearance.Above-mentioned whitening agent can be white dyes (as: 2,5-pair-(the 5-tertiary butyl-2-benzoxazolyl) thiophene, 4, two (the 2-dimethoxy-styryl-) biphenyl of 4--, Isosorbide-5-Nitrae-two (5-methyl-2-benzoxazolyl) naphthalene etc.), a kind of in titanium dioxide, talcum powder, calcium carbonate, Calcium hydrogen carbonate, yellow soda ash, sodium bicarbonate, zinc oxide and the calcium oxide or multiple mixture wherein.
The effect of above-mentioned essence is taste and the smell of covering other raw material (such as soap base, powdery polymer) itself, makes perfumed soap have better taste and smell.Above-mentioned essence can be fruit class essence, animal class essence, fragrance of a flower class essence, the fragrant class essence of powder and other class essence.
The present invention for the manufacture of perfumed soap, utilizes powdery polymer as filler powdery polymer, adopts powdery polymer to replace the part soap base, and the perfumed soap of making mainly is comprised of soap base and powdery polymer.Powdery polymer is as the integral part of perfumed soap, reduce on the one hand degreasing dynamics and the pungency of perfumed soap, make its performance gentle, be suitable for washing one's face, in the situation such as makeup removing clean (namely cleaning skin of face), the functions such as the foaming dynamics of perfumed soap, detersive power are not lost again simultaneously, still be suitable for taking a shower, and the shower function do not weaken, gentleer; On the other hand, the powdery polymer source is abundant, with low cost, and can degrade, and so greatly reduces the manufacturing cost of perfumed soap, and very friendly to environment.
Description of drawings
Accompanying drawing is that the preferred embodiment of the present invention 1 powdery polymer is for the manufacture of the process flow sheet of perfumed soap.
Embodiment
The semi-synthetic polymer substance hydroxypropylcellulose of embodiment 1 powdery is for the manufacture of perfumed soap
With reference to the accompanying drawings, the method for utilizing above-mentioned powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with in proportion the raw materials such as soap base, powdery polymer, lubricating auxiliary agent, water, sanitas, whitening agent, essence, functional additive; In the present embodiment, by weight, get 60 parts of soap bases (all being the plant soap base), 40 parts of powdery polymers (all being hydroxypropylcellulose), 10 parts of lubricating auxiliary agent (all being sorbyl alcohol), 5 parts in water (all being deionized water), 0.5 part of sanitas (all being isothiazolinone (being Kathon CG)), 0.15 part in whitening agent (all being titanium dioxide), 1.5 parts in essence, 6 parts of functional additives (all being walnut powder);
(2) water and sanitas, whitening agent are mixed, obtain the aqueous solution;
(3) soap base is added agitator kettle, the aqueous solution that again step (2) obtained adds agitator kettle, and is stirred to and mixes;
(4) functional additive is added agitator kettle, and be stirred to and mix;
(5) powdery polymer is added agitator kettle, and be stirred to and mix;
(6) lubricating auxiliary agent and essence are mixed, then add agitator kettle, and be stirred to and mix, obtain mixture;
(7) mixture that step (6) is obtained is milled, is pushed, and the various raw materials in the mixture are further mixed;
(8) mixture that step (7) is obtained is extruded bar by single screw extrusion machine extruding (temperature of single screw extrusion machine die head can be arranged between 30 ℃ to 70 ℃);
(9) bar of extruding in step (7) prints (can adopt the printer that is connected with cooling fluid to print), and carries out stripping and slicing, can obtain perfumed soap.Through printing, have required literal and/or pattern on the perfumed soap surface.
In the perfumed soap of making, contain 60 parts of soap bases (all being the plant soap base), 40 parts of powdery polymers (all being hydroxypropylcellulose), 10 parts of lubricating auxiliary agent (all being sorbyl alcohol), 5 parts in water (all being deionized water), 0.5 part of sanitas (all being isothiazolinone (being Kathon CG)), 0.15 part in whitening agent (all being titanium dioxide), 1.5 parts in essence, 6 parts of functional additives (all being walnut powder).
The semi-synthetic polymer substance hydroxyethylamyle of embodiment 2 powderies and methylcellulose gum are for the manufacture of perfumed soap
The method of utilizing above-mentioned powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with in proportion the raw materials such as soap base, powdery polymer, lubricating auxiliary agent, water, sanitas, whitening agent, essence, functional additive; In the present embodiment, by weight, (wherein the plant soap base is 30 parts to get 40 parts of soap bases, 10 parts of animal soap bases), (wherein hydroxyethylamyle is 40 parts for 60 parts of powdery polymers, 20 parts of methylcellulose gum), (wherein ethylene glycol is 11 parts for 15 parts of lubricating auxiliary agent, 4 parts in urea), 3 parts in water (all being deionized water), (wherein Sodium Benzoate is 0.5 part for 0.6 part of sanitas, 0.1 part of diazonium alkyl imidazole urea (namely extremely beautiful)), (wherein zinc oxide is 1.35 parts for 4.58 parts in whitening agent, 3.23 parts of titanium dioxides), 1 part in essence, 5 parts of functional additives (all being the chrysanthemum sheet);
Step (2)-(9) are identical with embodiment 1.
In the perfumed soap of making, (wherein the plant soap base is 30 parts to contain 40 parts of soap bases, 10 parts of animal soap bases), (wherein hydroxyethylamyle is 40 parts for 60 parts of powdery polymers, 20 parts of methylcellulose gum), (wherein ethylene glycol is 11 parts for 15 parts of lubricating auxiliary agent, 4 parts in urea), 3 parts in water (all being deionized water), (wherein Sodium Benzoate is 0.5 part for 0.6 part of sanitas, 0.1 part of diazonium alkyl imidazole urea (namely extremely beautiful)), (wherein zinc oxide is 1.35 parts for 4.58 parts in whitening agent, 3.23 parts of titanium dioxides), 1 part in essence, 5 parts of functional additives (all being the chrysanthemum sheet).
Embodiment 3 powdery natural high molecular substance whole meal flours and the semi-synthetic polymer substance carboxymethyl cellulose of powdery are for the manufacture of perfumed soap
The method of utilizing above-mentioned powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with in proportion the raw materials such as soap base, powdery polymer, lubricating auxiliary agent, water, sanitas, whitening agent, essence; In the present embodiment, by weight, get 50 parts of soap bases (all being the plant soap base), (wherein whole meal flour is 50 parts for 55 parts of powdery polymers, 5 parts of carboxymethyl celluloses), (wherein polysorbate is 3 parts for 6 parts of lubricating auxiliary agent, 3 parts in urea), 10 parts in water (all being deionized water), (wherein isothiazolinone (being Kathon CG) is 0.2 part for 0.3 part of sanitas, 0.1 part of Buddhist nun uncle tortoise beetle ester), (wherein white dyes 2 for 2.6 parts in whitening agent, 0.1 part in 5-pair-(the 5-tertiary butyl-2-benzoxazolyl) thiophene, 0.5 part of titanium dioxide, 2.0 parts of talcum powder), essence is 0.5 part;
Owing to do not contain functional additive, so compare with embodiment 1, omit step (4), namely from step (3) directly to step (5); Step (2), (3), (5)-(9) are identical with embodiment 1.
In the perfumed soap of making, contain 50 parts of soap bases (all being the plant soap base), (wherein whole meal flour is 50 parts for 55 parts of powdery polymers, 5 parts of carboxymethyl celluloses), (wherein polysorbate is 3 parts for 6 parts of lubricating auxiliary agent, 3 parts in urea), 10 parts in water (all being deionized water), (wherein isothiazolinone (being Kathon CG) is 0.2 part for 0.3 part of sanitas, 0.1 part of Buddhist nun uncle tortoise beetle ester), (wherein white dyes 2 for 2.6 parts in whitening agent, 0.1 part in 5-pair-(the 5-tertiary butyl-2-benzoxazolyl) thiophene, 0.5 part of titanium dioxide, 2.0 parts of talcum powder), essence is 0.5 part.
Embodiment 4 powdery natural high molecular substance corn flours and the semi-synthetic polymer substance Natvosol of powdery are for the manufacture of perfumed soap
The method of utilizing above-mentioned powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with in proportion the raw materials such as soap base, powdery polymer, lubricating auxiliary agent, water, sanitas, whitening agent, essence, functional additive; In the present embodiment, by weight, get 20 parts of soap bases (all being the animal soap base), 70 parts of powdery polymers (wherein 5 parts of corn flours, 65 parts of Natvosols), 25 parts of lubricating auxiliary agent (wherein 10 parts of sorbyl alcohols, 10 parts of polyacrylamides, 5 parts of ethylene glycol), 15 parts in water, 1 part of sanitas (wherein 0.2 part of glycolylurea, 0.8 part of Sodium Benzoate), 3.5 parts in whitening agent (wherein 1 part in zinc oxide, 0.5 part of Calcium hydrogen carbonate, 2.0 parts of talcum powder), 2 parts of functional additives (all being that fineness is 200 purpose polypropylene powders);
Step (6) adds agitator kettle with lubricating auxiliary agent, and is stirred to and mixes, and obtains mixture; Step (2)-(5), (7)-(9) are identical with embodiment 1.
In the perfumed soap of making, contain 20 parts of soap bases (all being the animal soap base), 70 parts of powdery polymers (wherein 5 parts of corn flours, 65 parts of Natvosols), 25 parts of lubricating auxiliary agent (wherein 10 parts of sorbyl alcohols, 10 parts of polyacrylamides, 5 parts of ethylene glycol), 15 parts in water, 1 part of sanitas (wherein 0.2 part of glycolylurea, 0.8 part of Sodium Benzoate), 3.5 parts in whitening agent (wherein 1 part in zinc oxide, 0.5 part of Calcium hydrogen carbonate, 2.0 parts of talcum powder), 2 parts of functional additives (all being that fineness is 200 purpose polypropylene powders).
Embodiment 5 powdery natural high molecular substance sweet potato starchs and the semi-synthetic polymer substance starch acetates of powdery are for the manufacture of perfumed soap
The method of utilizing above-mentioned powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with in proportion the raw materials such as soap base, powdery polymer, lubricating auxiliary agent, water, sanitas, whitening agent, essence, functional additive; In the present embodiment, by weight, (wherein the plant soap base is 30 parts to get 68 parts of soap bases, 38 parts of animal soap bases), (wherein sweet potato starch is 10 parts for 25 parts of powdery polymers, 15 parts of starch acetateses), (wherein polypropylene glycol is 1 part for 2 parts of lubricating auxiliary agent, 1 part of glucose material), 1 part in water, 0.1 part of sanitas (all being propylben), 1 part in whitening agent (wherein 1,0.3 part of 4-two (5-methyl-2-benzoxazolyl) naphthalene, 0.7 part in yellow soda ash), 2 parts in essence, (wherein quartz sand powder is 5.5 parts for 9.5 parts of functional additives, 4 parts of ginseng powders);
Step (2)-(9) are identical with embodiment 1.
In the perfumed soap of making, (wherein the plant soap base is 30 parts to contain 68 parts of soap bases, 38 parts of animal soap bases), (wherein sweet potato starch is 10 parts for 25 parts of powdery polymers, 15 parts of starch acetateses), (wherein polypropylene glycol is 1 part for 2 parts of lubricating auxiliary agent, 1 part of glucose material), 1 part in water, 0.1 part of sanitas (all being propylben), 1 part in whitening agent (wherein 1,0.3 part of 4-two (5-methyl-2-benzoxazolyl) naphthalene, 0.7 part in yellow soda ash), 2 parts in essence, (wherein quartz sand powder is 5.5 parts for 9.5 parts of functional additives, 4 parts of ginseng powders).
Claims (2)
1. the application of powdery polymer is characterized in that: described powdery polymer is for the manufacture of perfumed soap, and the perfumed soap of making mainly is comprised of soap base and powdery polymer;
Described powdery polymer is the combination of hydroxyethylamyle and methylcellulose gum;
The method of utilizing powdery polymer to make perfumed soap comprises the steps:
(1) is equipped with following raw material by following weight ratio: 40 parts of soap bases, 60 parts of powdery polymers, 15 parts of lubricating auxiliary agent, 3 parts in water, 0.6 part of sanitas, 4.58 parts in whitening agent, 1 part in essence, 5 parts of functional additives; Described soap base is comprised of 30 parts of plant soap bases and 10 parts of animal soap bases, described powdery polymer is comprised of 40 parts of hydroxyethylamyles and 20 parts of methylcellulose gum, described lubricating auxiliary agent is comprised of 11 parts of ethylene glycol and 4 parts of urea, described water is deionized water, described sanitas is comprised of 0.5 part of Sodium Benzoate and 0.1 part of diazonium alkyl imidazole urea, described whitening agent is comprised of 1.35 parts of zinc oxide and 3.23 parts of titanium dioxides, and described functional additive is the chrysanthemum sheet;
(2) water and sanitas, whitening agent are mixed, obtain the aqueous solution;
(3) soap base is added agitator kettle, the aqueous solution that again step (2) obtained adds agitator kettle, and is stirred to and mixes;
(4) functional additive is added agitator kettle, and be stirred to and mix;
(5) powdery polymer is added agitator kettle, and be stirred to and mix;
(6) lubricating auxiliary agent and essence are mixed, then add agitator kettle, and be stirred to and mix, obtain mixture;
(7) mixture that step (6) is obtained is milled, is pushed, and the various raw materials in the mixture are further mixed;
(8) mixture that step (7) is obtained pushes by single screw extrusion machine, extrudes bar;
(9) bar of extruding in step (8) prints, and carries out stripping and slicing, can obtain perfumed soap.
2. the application of powdery polymer according to claim 1 is characterized in that: the temperature of single screw extrusion machine die head is between 30 ℃ to 70 ℃ in the described step (8).
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| CN 200810220381 CN101445772B (en) | 2008-12-20 | 2008-12-20 | Application of powdery polymer |
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| CN 200810220381 CN101445772B (en) | 2008-12-20 | 2008-12-20 | Application of powdery polymer |
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| CN105816346B (en) * | 2016-05-24 | 2019-05-17 | 浙江农林大学 | A kind of Tea Saponin face cleaning powder and preparation method thereof and application method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2008070015A1 (en) * | 2006-12-01 | 2008-06-12 | The Procter & Gamble Company | Cleansing bar compositions comprising a high level of water |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2008070015A1 (en) * | 2006-12-01 | 2008-06-12 | The Procter & Gamble Company | Cleansing bar compositions comprising a high level of water |
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