CN101439029A - Method for preparing micro-encapsulated astaxanthin using pure glue gum as wall material - Google Patents
Method for preparing micro-encapsulated astaxanthin using pure glue gum as wall material Download PDFInfo
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- CN101439029A CN101439029A CNA2008102440496A CN200810244049A CN101439029A CN 101439029 A CN101439029 A CN 101439029A CN A2008102440496 A CNA2008102440496 A CN A2008102440496A CN 200810244049 A CN200810244049 A CN 200810244049A CN 101439029 A CN101439029 A CN 101439029A
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- astaxanthin
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Abstract
The invention relates to a preparation method of microencapsulated astaxanthin which takes pure gum as wall material, belonging to the technical field of function food additive. Astaxanthin is a naturalpigment with good physiological function but is greatly limited in use due to self solubility and instability. The method prepares the microencapsulated astaxanthin by preparing astaxanthin emulsion, homogenizing the emulsion and spray drying; at a high temperature ranging from 160 DEG C to 200 DEG C, the astaxanthin is dissolved in soybean oil in terms of 3 percent; the mixed solution, together with a wall material solution taking the pure gum as the main material, is homogenized at a pressure of 40MPa so as to obtain the stable emulsion; and then spray drying is carried out at an inlet temperature of 190 DEG C and an outlet temperature of 90 DEG C so that water-soluble microcapsules with good shapes can be obtained. The water solubility and the stability of the microencapsulated astaxanthin are improved so that the astaxanthin can be better applied in food industry, feedstuff industry and other industries.
Description
Technical field
A kind of is the preparation method of the micro-encapsulated astaxanthin of wall material with pure glue, belongs to the functional food additives technical field.
Background technology
Astaxanthin is to be found in the intravital a kind of carotenoid of some aquatic animal, has another name called the shrimp flavin.It is a kind of keto-acid carotenoid, and (OH) with 2 ketone groups (C=O), its natural product majority exists with the form of ester to contain 2 hydroxyls.From chemical constitution, astaxanthin can think that 3,4 on 2 β-purple trailing plants ketone ring at beta-carotene replace later product by a hydroxyl and ketone group respectively.
The color and luster of astaxanthin is pink, and is water insoluble, is soluble in most of organic solvent, all unstable easy oxidized degraded under acid, oxygen, high temperature, ultraviolet light conditions.
Astaxanthin has superpower oxidation resistance, is improving animal immunizing power, is suppressing to have outstanding physiological function aspect tumor, removing free radical and the active oxygen.It is carried out water soluble microcapsuleization can improve stability effectively, prolong the holding time, and make it can be widely used in food, medicine and feedstuff industry more.
The alkenyl succinic acid esterification starch is a big class modified starch, be allowed to be used in grocery trade only for a kind of, i.e. starch octenyl succinate anhydride.Starch octenyl succinate anhydride (commodity are called pure glue) as a kind of novel modified starch, is safe emulsifing thickener, is used by the approval of the major country of the U.S., Europe and the Asian-Pacific area.FAO (Food and Agriculture Organization of the United Nation) and World Health Organization (WHO) (FAO/WHO) estimate: day is permitted intake and be need not particular provisions, can use it for food, and the scope of application is not limited.The Chinese government can be used as after food additive uses ratifying this modified starch in 1997, and calendar year 2001 has ratified to enlarge the scope that this product uses again in food, and consumption can add according to demand, need not control.This series products of existing China approved can be used for having of food: two kinds of starch sodium octenyl succinate and octenyl succinic acid starch aluminum.
Octenyl succinic acid starch is as a kind of hydrophilic, oleophylic modified starch, have good emulsifying and filming performance, lower viscosity, easily dry, be difficult for characteristics such as the moisture absorption, therefore become a kind of important wall material of spray drying micro encapsulation.
Summary of the invention
The purpose of this invention is to provide a kind of is the preparation method of the micro-encapsulated astaxanthin of wall material with pure glue, utilizes starch octenyl succinate anhydride to prepare the microcapsule of astaxanthin for main wall material, improves the water solublity and the stability of astaxanthin.
Technical scheme of the present invention: a kind of preparation method of micro-encapsulated astaxanthin, preparation, the homogenizing of emulsion, spray drying by astaxanthin emulsion prepare micro-encapsulated astaxanthin, and step is:
(1) preparation of astaxanthin emulsion:
The weight % proportioning of astaxanthin oil solution:
Astaxanthin 0.3-0.45,
Soybean oil 10-12,
The weight % proportioning of wall material:
Starch octenyl succinate anhydride 9-10,
Maltodextrin 6-7,
Tween 20 0.4-0.6,
Sucrose ester-15 0.4-0.6,
60 0.2-0.3 of class of department,
Sodium carboxymethyl cellulose 0.15,
Deionized water 68-72,
Preparation: take by weighing astaxanthin by proportioning and add in the soybean oil, under nitrogen protection, be dissolved in fully in the soybean oil, make the astaxanthin oil solution in 160 ℃ of-200 ℃ of oil bath to astaxanthins;
Take by weighing each component of wall material by proportioning and be dissolved in water, add the astaxanthin oil solution while stirring under 70 ℃ of water-baths, 22000rpm high-speed homogenization 60s obtains astaxanthin emulsion;
(2) homogenizing of emulsion: homogenizing is 1 time under the 40MPa pressure;
(3) spray drying prepares microcapsule: carry out spray drying under 190 ℃ of inlet temperature, 90 ℃ of conditions of leaving air temp, obtain the product micro-encapsulated astaxanthin.
The present invention relates to pure glue is the main wall material micro-encapsulated astaxanthin, and each constituent content is: solid content is about 30%, solid content fuel load about 40%.
Beneficial effect of the present invention: utilize starch octenyl succinate anhydride to prepare the microcapsule of astaxanthin for main wall material, the astaxanthin microcapsule is a red powder, and content astaxanthin 1% has good stable and water solublity.Can be used as additive and be applied to the production of functional drinks.
The specific embodiment
Embodiment 1: with pure glue is wall material micro-encapsulated astaxanthin
Prescription
Astaxanthin 1.5g,
Soybean oil 48.5g,
Starch octenyl succinate anhydride (pure glue) 42g,
Maltodextrin 28g,
Tween 20 2g,
Sucrose ester-15 2g,
60 1g of class of department,
Sodium carboxymethyl cellulose 0.625g,
Deionized water 300g,
Method for making
(1) astaxanthin oil solution preparation
Astaxanthin 1.5g is put in the 150mL round-bottomed flask, add the 48.5g soybean oil again, vibration is rocked repeatedly, makes astaxanthin all by the soybean oil moistening.The round-bottomed flask Rotary Evaporators of packing into, 160 ℃ of following oil bath 90s dissolve fully to astaxanthin.
(2) spray drying prepares microcapsule
Pure glue 42g, maltodextrin 28g, tween 20 2g, sucrose ester-15 2g, 60 1g of class of department and sodium carboxymethyl cellulose 0.625g are dropped into the 600mL beaker, add deionized water 300mL, under 70 ℃ of water-baths, stir, all dissolve to component with Glass rod.Add the astaxanthin oil solution while stirring, and high-speed homogenization (22000rpm, 60s), high pressure homogenize (homogenization pressure 40MPa, homogenizing 1 time), spray drying (190 ℃ of inlet temperatures, 90 ℃ of outlet temperatures).Spray drying finishes promptly to obtain the astaxanthin microcapsule product.
Character: outward appearance is a red powder, has good stable.
Purposes:, be applied to functional product development as food additive.
Claims (1)
1. the preparation method of a micro-encapsulated astaxanthin is characterized in that preparation, the homogenizing of emulsion, the spray drying by astaxanthin emulsion prepares micro-encapsulated astaxanthin, and step is:
(1) preparation of astaxanthin emulsion:
The weight % proportioning of astaxanthin oil solution:
Astaxanthin 0.3-0.45,
Soybean oil 10-12,
The weight % proportioning of wall material:
Starch octenyl succinate anhydride 9-10,
Maltodextrin 6-7,
Tween 20 0.4-0.6,
Sucrose ester-15 0.4-0.6,
60 0.2-0.3 of class of department,
Sodium carboxymethyl cellulose 0.15,
Deionized water 68-72,
Preparation: take by weighing astaxanthin by proportioning and add in the soybean oil, under nitrogen protection, be dissolved in fully in the soybean oil, make the astaxanthin oil solution in 160 ℃ of-200 ℃ of oil bath to astaxanthins;
Take by weighing each component of wall material by proportioning and be dissolved in water, add the astaxanthin oil solution while stirring under 70 ℃ of water-baths, 22000rpm high-speed homogenization 60s obtains astaxanthin emulsion;
(2) homogenizing of emulsion: homogenizing is 1 time under the 40MPa pressure;
(3) spray drying prepares microcapsule: carry out spray drying under 190 ℃ of inlet temperature, 90 ℃ of conditions of leaving air temp, obtain the product micro-encapsulated astaxanthin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102440496A CN101439029A (en) | 2008-12-19 | 2008-12-19 | Method for preparing micro-encapsulated astaxanthin using pure glue gum as wall material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102440496A CN101439029A (en) | 2008-12-19 | 2008-12-19 | Method for preparing micro-encapsulated astaxanthin using pure glue gum as wall material |
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| CN101439029A true CN101439029A (en) | 2009-05-27 |
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| CNA2008102440496A Pending CN101439029A (en) | 2008-12-19 | 2008-12-19 | Method for preparing micro-encapsulated astaxanthin using pure glue gum as wall material |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102174503A (en) * | 2010-11-29 | 2011-09-07 | 天津市诺奥科技发展有限公司 | Spray drying micro-capsulation process for high-yield alkaline protease |
| CN102783653A (en) * | 2012-09-04 | 2012-11-21 | 郭威 | Collagen peptide nutritional supplement containing astaxanthin and processing method thereof |
| CN102802436A (en) * | 2010-03-29 | 2012-11-28 | 弗门尼舍有限公司 | Spray-dried crystalline active ingredient |
| CN103349785A (en) * | 2013-07-26 | 2013-10-16 | 广东省中医药工程技术研究院 | Traditional Chinese medicine volatile oil complex and preparation method thereof |
| CN104705654A (en) * | 2015-04-02 | 2015-06-17 | 徐权汉 | Preparation method for astaxanthin microcapsules |
| CN104757621A (en) * | 2015-04-10 | 2015-07-08 | 杭州鑫伟低碳技术研发有限公司 | Method for producing microcapsule spore powder by utilizing haematococcus pluvialis fresh seaweed mud |
| CN104856051A (en) * | 2015-04-10 | 2015-08-26 | 杭州鑫伟低碳技术研发有限公司 | Method for producing microcapsules of astaxanthin powder by utilizing haematococcus pluvialis |
| CN104886578A (en) * | 2015-06-15 | 2015-09-09 | 杭州鑫伟低碳技术研发有限公司 | Production device and production method for haematococcus pluvialis micro-capsule conidial powder |
| CN104997647A (en) * | 2015-07-09 | 2015-10-28 | 西安艾尔菲生物科技有限公司 | Astaxanthin-containing sunscreen spray and preparation method thereof |
| CN105997562A (en) * | 2016-07-19 | 2016-10-12 | 连云港利丰医用氧产品有限公司 | SOD containing liposome sun-blocking and moisturizing spray and preparation method thereof |
| CN106232055A (en) * | 2014-03-27 | 2016-12-14 | 盛势达（瑞士）有限公司 | Cleaning device and manufacture method thereof between tooth |
| CN108530939A (en) * | 2018-04-18 | 2018-09-14 | 济南大学 | A kind of foam spray drying method prepares Determination of Astaxanthin in Haematococcus Pluvialis microcapsules and preparation method thereof |
| CN109370298A (en) * | 2018-10-16 | 2019-02-22 | 惠州市舜丰印材科技有限公司 | A kind of edible water-based ink and preparation method thereof with microcapsule structure |
| WO2023125626A1 (en) * | 2021-12-28 | 2023-07-06 | Innobio Corporation Limited | Carotenoid preparations, preparation methods, and application thereof |
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2008
- 2008-12-19 CN CNA2008102440496A patent/CN101439029A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102802436A (en) * | 2010-03-29 | 2012-11-28 | 弗门尼舍有限公司 | Spray-dried crystalline active ingredient |
| CN106974316B (en) * | 2010-03-29 | 2019-07-19 | 弗门尼舍有限公司 | The spray-dried granules for preparing the method for spray dried products and being prepared by this method |
| CN106974316A (en) * | 2010-03-29 | 2017-07-25 | 弗门尼舍有限公司 | The crystal active component of spray drying |
| CN102174503A (en) * | 2010-11-29 | 2011-09-07 | 天津市诺奥科技发展有限公司 | Spray drying micro-capsulation process for high-yield alkaline protease |
| CN102783653A (en) * | 2012-09-04 | 2012-11-21 | 郭威 | Collagen peptide nutritional supplement containing astaxanthin and processing method thereof |
| CN103349785A (en) * | 2013-07-26 | 2013-10-16 | 广东省中医药工程技术研究院 | Traditional Chinese medicine volatile oil complex and preparation method thereof |
| CN103349785B (en) * | 2013-07-26 | 2015-08-12 | 广东省中医药工程技术研究院 | Traditional Chinese medicine volatile oil complex and preparation method thereof |
| CN106232055A (en) * | 2014-03-27 | 2016-12-14 | 盛势达（瑞士）有限公司 | Cleaning device and manufacture method thereof between tooth |
| CN106232055B (en) * | 2014-03-27 | 2019-02-19 | 盛势达（瑞士）有限公司 | Cleaning device and its manufacturing method between tooth |
| CN104705654A (en) * | 2015-04-02 | 2015-06-17 | 徐权汉 | Preparation method for astaxanthin microcapsules |
| CN104856051A (en) * | 2015-04-10 | 2015-08-26 | 杭州鑫伟低碳技术研发有限公司 | Method for producing microcapsules of astaxanthin powder by utilizing haematococcus pluvialis |
| CN104757621A (en) * | 2015-04-10 | 2015-07-08 | 杭州鑫伟低碳技术研发有限公司 | Method for producing microcapsule spore powder by utilizing haematococcus pluvialis fresh seaweed mud |
| CN104886578A (en) * | 2015-06-15 | 2015-09-09 | 杭州鑫伟低碳技术研发有限公司 | Production device and production method for haematococcus pluvialis micro-capsule conidial powder |
| CN104997647A (en) * | 2015-07-09 | 2015-10-28 | 西安艾尔菲生物科技有限公司 | Astaxanthin-containing sunscreen spray and preparation method thereof |
| CN104997647B (en) * | 2015-07-09 | 2017-12-19 | 西安艾尔菲生物科技有限公司 | A kind of Sun care spray containing astaxanthin and preparation method thereof |
| CN105997562A (en) * | 2016-07-19 | 2016-10-12 | 连云港利丰医用氧产品有限公司 | SOD containing liposome sun-blocking and moisturizing spray and preparation method thereof |
| CN108530939A (en) * | 2018-04-18 | 2018-09-14 | 济南大学 | A kind of foam spray drying method prepares Determination of Astaxanthin in Haematococcus Pluvialis microcapsules and preparation method thereof |
| CN109370298A (en) * | 2018-10-16 | 2019-02-22 | 惠州市舜丰印材科技有限公司 | A kind of edible water-based ink and preparation method thereof with microcapsule structure |
| WO2023125626A1 (en) * | 2021-12-28 | 2023-07-06 | Innobio Corporation Limited | Carotenoid preparations, preparation methods, and application thereof |
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Open date: 20090527 |