CN101434859A - Biomulsifier and use thereof - Google Patents
Biomulsifier and use thereof Download PDFInfo
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- CN101434859A CN101434859A CNA2008102287782A CN200810228778A CN101434859A CN 101434859 A CN101434859 A CN 101434859A CN A2008102287782 A CNA2008102287782 A CN A2008102287782A CN 200810228778 A CN200810228778 A CN 200810228778A CN 101434859 A CN101434859 A CN 101434859A
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Abstract
The invention relates to a bio-emulsifier and an application thereof, comprising the technical proposal that: according to weight percentage, the bio-emulsifier consists of 96-98 percent of main material, 0.08-0.2 percent of isopropyl nitrate, 0.01-0.15 percent of ethanolamine, 1.9-3.5 percent of potassium hydroxide, and 0.01-0.15 percent of cyclohexane; wherein, the main material is one or the mixture of more then one components out of animal oleic acid or plant oleic acid or animal fatty acid or plant fatty acid or plant acidic oil or naphthenic acid. The bio-emulsifier can be applied to bio-emulsified oil. The bio-emulsifier can sufficiently dissolve the water and crude oil. The physical and chemical performances of the bio-emulsified oil containing the bio-emulsifier is similar to that of petrochemical oil; after emulsification, the bio-emulsified oil can be dissolved with normal petrochemical diesel or fuel oil or fire oil at any proportion, thus saving and replacing the fuel.
Description
Technical field: the invention belongs to the chemical composition field, relate in particular to a kind of biological emulsifier and application thereof that can promote that water and diesel oil polymerization are dissolved each other.
Background technology: in order to solve the problem of energy scarcity, international fuel association in 1981 decision water blending fuel as one of three big conservation measuress.More the legal status of biological diesel oil emulsification is obtained clearly in " People's Republic of China's renewable energy source method ", regulation must not hinder biological diesel oil emulsification by any way and enter main marketing channels such as service station.Diesel oil emulsification is to utilize reproducible Biological resources to alleviate energy scarcity, reduces and pollutes and the scientific and technological product innovation of Development and Production.Yet the problem that existing diesel oil emulsification exists is: can not be cold-resistant; The ratio of dissolving each other is limited; Oil in water emulsion is opaque, is difficult to cause breakdown of emulsion to damage filter screen by filtering net; There is poor stability; The easy breakdown of emulsion of high temperature is difficult to mix mutually with former diesel oil, and this is the major reason that causes diesel oil emulsification to be difficult to promote.
Summary of the invention: in order to address the above problem, the invention provides a kind of biological emulsifier, the oil that water and diesel oil or oil fuel or industry can be made a fire is fully fused.
Another object of the present invention provides a kind of biological oil in water emulsion that contains biological emulsifier, and its physical and chemical performance and petrochemical industry oil phase are near, can dissolve each other with arbitrary proportion with common petrifaction diesel or oil fuel or the industry oil that makes a fire after the emulsification, saves and replaces fuel.To achieve these goals, the technical solution used in the present invention is: a kind of biological emulsifier, form by weight percentage by following component:
Major ingredient 96%～98%, nitric acid isooctyl 0.08%～0.2%,
Thanomin 0.01%～0.15%, potassium hydroxide 1.9%～3.5%,
Hexahydroaniline 0.01%～0.15%;
Wherein, major ingredient is one or more mixing of animal oleic acid or vegetable oil acid or tallow fatty acid or vegetable fatty acid or vegetable acid carburetion or naphthenic acid.
Above-mentioned biological emulsifier can be used on biological oil in water emulsion.
A kind of biological oil in water emulsion, form by weight percentage by following component:
Crude oil 68%～74%, biological emulsifier 13%～16%,
Water 13%～16%;
Wherein, crude oil is diesel oil or oil fuel or industrial a kind of of oil that make a fire.
Diesel oil can be label diesel oil or non-label diesel oil.
The preparation method of above-mentioned biological oil in water emulsion is as follows: by proportioning make a fire oil and biological emulsifier of diesel oil or oil fuel or industry mixed earlier, add entry then and stir.
The technical indicator such as the table 1 of biological emulsifier of the present invention.
Table 1
| Project | Index |
| Density g/m 3 | 0.87～0.89 |
| Kinematic viscosity (20 ℃) mm 2/s | 4～8 |
| Flash-point (remaining silent) ℃ | 100～110 |
| Cetane value | 45～55 |
| Condensation point ℃ | 14-18 |
The technical indicator such as the table 2 of biological oil in water emulsion of the present invention.
Table 2
| Project | Index |
| Outward appearance | Basic identical with the crude oil that uses |
| Density g/m 3 | With the crude oil that uses mutually specific density be lower than 0.89 increase 0.01-0.015, density is higher than 0.89 minimizing 0.01-0.015 |
| Copper corrosion (50 ℃, 3h) level | 1 |
| Kinematic viscosity (20 ℃) mm 2/s | Compare slightly increase with the crude oil that uses |
| Flash-point (remaining silent) ℃ | Compare increase 5-10 with the crude oil that uses |
| Cetane value | Compare increase 3-5 with the crude oil that uses |
| Cold filter clogging temperature ℃ | Compare slightly increase with the crude oil that uses |
The invention has the beneficial effects as follows: biological emulsifier of the present invention is applicable to various labels and unlabelled diesel oil or oil fuel or the industry oil that makes a fire, and can make water and diesel oil or oil fuel or the industry oil that makes a fire fully fused, and the matter that remains unchanged for a long period of time is not stratified.Utilize the biological oil in water emulsion of biological emulsifier preparation of the present invention, not " water becomes oil ", it is based on diesel oil or oil fuel or the industry oil that makes a fire, add biological emulsifier and water, become the biological oil in water emulsion of a kind of " water-in-oil " type environmental protection and energy saving through mixing and emulsifying, outward appearance and crude oil are approaching, and is limpid transparent, not muddy; After the fixed ratio of the biological emulsification W/O after the configuration, add water again and can not add, only can be sunken to the oil in water emulsion bottom.Through the long-term practice checking, the biological oil in water emulsion of preparation never degenerated through the time more than 1 year, and is not stratified, cold-resistant effective, stability height; Energy-conservation more than 10%～15%, the tail gas clean-up rate improves 30%, and cost is low, produces simple and easy.Biological oil in water emulsion of the present invention possesses six big effects: 1, cracking energization effect, and water is made up of hydrogen and oxygen, can cracking go out the hydrogen participation burning higher 3.52 times than diesel oil energy under the High Temperature High Pressure; 2, confession oxygen effect, cracked oxygen makes burning more abundant for burning has increased comburant oxygen; 3, effect of micro-explosion when producing the steam than self big 1700 times of volume during water vapor, can be broken through oil film and atomize once again, thus more abundant burning; 4, water-gas effect, water vapour with fail incendiary CO and be converted into CO
2And a large amount of heat releases; 5, equal heat effect, steam can reduce cylinder body localized hyperthermia effectively and protect body, the resistance of reducing friction, alleviate coking; 6, environmental protection effect, emulsifying combustion can reduce the flue gas blowdown flow rate more than 30%.The water and the biological emulsifier of adding about 30% mean to have substituted about 30% oil fuel, thereby have huge energy-saving significance in diesel oil.Diesel oil emulsification outward appearance and ordinary diesel oil after biological emulsifier emulsification are basic identical, and use range is the same, need not using body to do any change and adjustment, and using method and ordinary diesel oil are without any difference.
Embodiment:
Embodiment 1
A kind of biological emulsifier, form by weight percentage by following component:
Major ingredient 97%, nitric acid isooctyl 0.15%,
Thanomin 0.05%, potassium hydroxide 2.75%,
Hexahydroaniline 0.05%;
Wherein, major ingredient is an animal oleic acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 2
A kind of biological emulsifier, form by weight percentage by following component:
Major ingredient 97%, nitric acid isooctyl 0.15%,
Thanomin 0.05%, potassium hydroxide 2.75%,
Hexahydroaniline 0.05%;
Wherein, major ingredient is the mixing of animal oleic acid and vegetable oil acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 3
A kind of biological emulsifier, form by weight percentage by following component:
Major ingredient 96%, nitric acid isooctyl 0.2,
Thanomin 0.15%, potassium hydroxide 3.5%,
Hexahydroaniline 0.15%;
Wherein, major ingredient is the mixing of animal oleic acid and vegetable oil acid and tallow fatty acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 4
A kind of emulsifying agent, form by weight percentage by following component:
Major ingredient 96%, nitric acid isooctyl 0.2%,
Thanomin 0.15%, potassium hydroxide 3.5%,
Hexahydroaniline 0.15%;
Wherein, major ingredient is the mixing of animal oleic acid and vegetable oil acid and tallow fatty acid and vegetable fatty acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 5
Major ingredient 98%, nitric acid isooctyl 0.08%,
Thanomin 0.01%, potassium hydroxide 1.9%,
Hexahydroaniline 0.01%;
Wherein, major ingredient is the mixing of animal oleic acid and vegetable oil acid and tallow fatty acid and vegetable fatty acid and vegetable acid carburetion.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 6
Major ingredient 98%, nitric acid isooctyl 0.08%,
Thanomin 0.01%, potassium hydroxide 1.9%,
Hexahydroaniline 0.01%;
Wherein, major ingredient is the mixing of animal oleic acid and vegetable oil acid and tallow fatty acid and vegetable fatty acid and vegetable acid carburetion and naphthenic acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 7
Major ingredient 98%, nitric acid isooctyl 0.08%,
Thanomin 0.01%, potassium hydroxide 1.9%,
Hexahydroaniline 0.01%;
Wherein, major ingredient is a naphthenic acid.
Preparation method: by said ratio each component is put into container, stir.The results are shown in Table 3
Embodiment 8
A kind of biological oil in water emulsion, form by weight percentage by following component:
Label diesel oil 0#70%, biological emulsifier 15% (preparation among the embodiment 1) and water 15%.
The preparation method mixes label diesel oil 0# and biological emulsifier by proportioning earlier, adds entry then and stirs.The technical indicator such as the table 4 of the biological oil in water emulsion of preparation.
Embodiment 9
A kind of biological oil in water emulsion is made of by weight percentage following component: non-label diesel oil 68%, biological emulsifier 16% (embodiment 3 preparations) and water 16%.
Preparation method: by proportioning non-label diesel oil and biological emulsifier are mixed earlier, add entry then and stir.The technical indicator such as the table 4 of the biological diesel oil emulsification of preparation.
Embodiment 10
A kind of biological oil in water emulsion is made of by weight percentage following component: oil fuel 74%, biological emulsifier 13% (embodiment 5 preparations) and water 13%.
Preparation method: by proportioning oil fuel and biological emulsifier are mixed earlier, add entry then and stir.The technical indicator such as the table 4 of the biological diesel oil emulsification of preparation.
Embodiment 11
A kind of biological oil in water emulsion is made of by weight percentage following component: industry make a fire oil 72%, biological emulsifier 14% (embodiment 7 preparation) and water 14%.
The preparation method: elder generation makes a fire industry oily by proportioning and biological emulsifier mixes, and adds entry then and stirs.The technical indicator such as the table 4 of the biological diesel oil emulsification of preparation.
Table 3
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Density g/m 3 | 0.87 | 0.88 | 0.88 | 0.88 | 0.87 | 0.87 | 0.87 |
| Kinematic viscosity (20 ℃) mm 2/s | 6 | 6 | 6 | 6 | 5 | 5 | 4 |
| Flash-point (remaining silent) ℃ | 100 | 104 | 110 | 102 | 105 | 107 | 103 |
| Cetane value | 49 | 49 | 52 | 49 | 52 | 50 | 46 |
| Condensation point ℃ | 18 | 18 | 15 | 15 | 15 | 15 | 14 |
Table 4
Claims (4)
1, a kind of biological emulsifier is characterized in that being made up of by weight percentage following component:
Major ingredient 96%～98%, nitric acid isooctyl 0.08%～0.2%,
Thanomin 0.01%～0.15%, potassium hydroxide 1.9%～3.5%,
Hexahydroaniline 0.01%～0.15%;
Wherein, major ingredient is one or more mixing of animal oleic acid or vegetable oil acid or tallow fatty acid or vegetable fatty acid or vegetable acid carburetion or naphthenic acid.
2, the application of the described biological emulsifier of claim 1 on biological oil in water emulsion.
3, a kind of biological oil in water emulsion is characterized in that being made up of by weight percentage following component:
Crude oil 68%～74%, biological emulsifier 13%～16%,
Water 13%～16%;
Wherein, crude oil is diesel oil or oil fuel or industrial a kind of of oil that make a fire.
4, the preparation method of the described biological oil in water emulsion of a kind of claim 3 is characterized in that the preparation method is as follows: by proportioning make a fire oil and biological emulsifier of diesel oil or oil fuel or industry mixed, add entry then and stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102287782A CN101434859A (en) | 2008-11-14 | 2008-11-14 | Biomulsifier and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102287782A CN101434859A (en) | 2008-11-14 | 2008-11-14 | Biomulsifier and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101434859A true CN101434859A (en) | 2009-05-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008102287782A Pending CN101434859A (en) | 2008-11-14 | 2008-11-14 | Biomulsifier and use thereof |
Country Status (1)
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| CN (1) | CN101434859A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479733A (en) * | 2014-12-29 | 2015-04-01 | 江苏健神生物农化有限公司 | Oil antibacterial cleaning agent and preparation method thereof |
| CN111793511A (en) * | 2020-07-14 | 2020-10-20 | 张建国 | Environment-friendly mixed biodiesel |
-
2008
- 2008-11-14 CN CNA2008102287782A patent/CN101434859A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479733A (en) * | 2014-12-29 | 2015-04-01 | 江苏健神生物农化有限公司 | Oil antibacterial cleaning agent and preparation method thereof |
| CN104479733B (en) * | 2014-12-29 | 2016-11-23 | 烟台史密得机电设备制造有限公司 | Oil antibacterial purifying agent and preparation method thereof |
| CN111793511A (en) * | 2020-07-14 | 2020-10-20 | 张建国 | Environment-friendly mixed biodiesel |
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Application publication date: 20090520 |