CN101430096A - Dual lift system - Google Patents
Dual lift system Download PDFInfo
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- CN101430096A CN101430096A CNA2008101490661A CN200810149066A CN101430096A CN 101430096 A CN101430096 A CN 101430096A CN A2008101490661 A CNA2008101490661 A CN A2008101490661A CN 200810149066 A CN200810149066 A CN 200810149066A CN 101430096 A CN101430096 A CN 101430096A
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- Prior art keywords
- valve
- flow distributor
- pressure
- sealing
- seal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangements of monitoring devices; Arrangements of safety devices
- F27D21/02—Observation or illuminating devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/008—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/004—Systems for reclaiming waste heat
- F27D2017/007—Systems for reclaiming waste heat including regenerators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/5544—Reversing valves - regenerative furnace type
- Y10T137/5689—Rotary reversing valve
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Lift Valve (AREA)
- Sliding Valves (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Multiple-Way Valves (AREA)
- Fluid-Driven Valves (AREA)
- Details Of Valves (AREA)
Abstract
The present invention relates to a double-lifting system. The system of the invention which is used for reducing friction in the moving period of valve comprises the following components: a flow distributor; a valve seat; a driver which is relevant with the flow distributor and is used for moving the flow distributor from a first fixed position to a second fixed position; a compressed gas source which is communicated with the fluid of fluid distributor; a first regulator which is used for supplying the compressed air to the air distributor with a first pressure which is enough for sealing the flow distributor relatively to the valve seat when the flow distributor is at a first fixed position or a second fixed position; and a second regulator which is used for supplying the compressed air to the air distributor with a second pressure lower than the first pressure when the flow distributor moves between the first fixed position and the second fixed position.
Description
Technical field
The present invention relates to dual lift system.
Background technology
Regenerative thermal oxidizer is generally used for destroying the VOC (VOC) in the effluent with high fluidity, low concentration of industry and power plant generation.This oxidation unit generally needs high oxidizing temperature, so that VOC is reached higher destructive power.In order to obtain higher heat recovery efficiency, need processed " dirty " process gas before oxidation, to be preheated.Usually use heat exchange tower and come these gases of preheating.This exchange column is usually with the heat exchange material parcel that has good heat and mechanical stability and have enough thermal masses.In operation, process gas is admitted to by pre-heated heat exchange tower, this heat change tower again process gas is heated near or reach the temperature of its VOC oxidizing temperature.The process gas that is preheated is admitted to the combustion zone then, and any incomplete VOC oxidation all can be finished usually there.The gas of treated " purification " now is discharged from the combustion zone then and returns by heat exchange tower or by second heat exchange tower.When the oxidizing gas of heat continued by this tower, described gas sent its heat in the described tower heat exchange medium, and refrigerating gas and preheating heat exchange media simultaneously are so that another batch process gas can be preheated before oxidation processes.Regenerative thermal oxidizer generally has 2 heat exchange towers at least, and it alternately receives process gas and gas to be processed.This process is continuously carried out, thereby a large amount of process gas is handled effectively.
The performance of regenerative oxidizer can become original with reduction operating cost and capital construction by the destruction efficient that increases VOC and optimize.The technology that increases VOC destruction efficient has been seen in documents and materials, for example, the device of use such as improved oxidative system and cleaning system (as holding back the chamber) and 3 or more heat exchanger so as in transfer process at the still untreated gas of oxidation unit inter-process.Operating cost can reduce by the pressure drop that increases heat recovery efficiency and reduction oxidation unit.Operating cost and capital construction cost can and select suitable heat transfer filler to reduce by correct design oxidation unit.
The critical elements of the efficient oxidation device is to be used for process gas is flowed the valve member that turns to another heat exchange tower from a heat exchange tower.Any leakage part that untreated process gas is taken place during by valve system can reduce the efficient of this equipment.In addition, also can cause disturbance and fluctuation in intrasystem pressure and/or the air-flow during threshold switch, this disturbance and fluctuation are undesirable.The wearing and tearing of valve also are a problem, and especially considering needs frequent switch valve in the application of regenerative thermal oxidizer.Obviously people do not wish valve is carried out frequent repairing or replacing.
A pair of lift valve is adopted in the design of a kind of common double-tower type, and one links to each other with first heat exchange tower, and one links to each other with second heat exchange tower.Though lift valve action is fast, when valve in the cycle during switch, not processed process gas still unavoidably can leak by valve.For example, in the oxidation unit of two chambers, the time point that in the cycle, has inlet valve and outlet valve all to partially open.On this time point, do not stop process gas stream, then air-flow is unprocessed just directly flows to outlet from inlet.Because also have conduit to link to each other, so just represented potential leakage volume with the untreated gas volume in the conduit that links to each other at the lifting valve pocket with valve system.Because the leakage of untreated process gas on valve block makes that gas is not processed and just is discharged from from equipment that therefore this leakage can reduce the destruction efficient of equipment greatly.In addition, traditional valve design can produce pressure oscillation when switch valve, and this has also aggravated the possibility of this leakage.
In the period of 10, rotary valve is used to directly flowing in regenerated heat and the catalytic oxidizing equipment always in the past.These valves or in a continuous manner, or move in numeral (stopping/beginning) mode.In order to carry out good sealing, come the fixture of maintaining valve and the constant force between the revolving part with some mechanisms.These mechanisms comprise spring, air diaphragms and cylinder.But, excessive wear still often takes place in the different parts of valve.
Summary of the invention
Thereby being desirable to provide a kind of valve and valve system and a kind of regenerative thermal oxidizer that is equipped with this valve and system that particularly is used in the regenerative thermal oxidizer, it can guarantee correct sealing, and can reduce or eliminate wearing and tearing.
It would also be desirable to provide a kind of valve and valve system, wherein sealing load can accurately be controlled.
The invention provides and a kind of valve is moved on to the method for second fixed position from first fixed position, it comprises: valve and valve seat are provided, and wherein said valve is suitable for relative valve base sealing; When described valve is in described first fixed position, by described valve is promoted to make the described relatively valve base sealing of described valve to described valve seat; The effect of described power is reduced to the amount of the described sealing of enough destruction; Described valve is moved on to described second fixed position; When being in described second fixed position when described valve, the effect of recovering described power is so that the described relatively valve base sealing of described valve.
The invention provides a kind of system that is used for reducing friction during valve moves, it comprises: flow distributor; Valve seat; With the driver that described flow distributor is associated, be used for described flow distributor is moved on to second fixed position from first fixed position; The compressed gas source that is communicated with described flow distributor fluid; First adjuster is when described flow distributor is positioned at described first or during described second fixed position, this first adjuster is used for supplying described Compressed Gas to described flow distributor with first pressure of enough described flow distributors of described relatively valve base sealing; With second adjuster, when described flow distributor was mobile between described first and second fixed positions, this second adjuster was used for supplying described Compressed Gas to described flow distributor with second pressure that is lower than described first pressure.
The invention provides and a kind of valve is moved on to the method for second fixed position from first fixed position, it comprises: valve and valve seat are provided, and described valve is suitable for relative valve base sealing; The Compressed Gas supply source is provided; When described valve is in described first fixed position, by supplying described Compressed Gas to described valve, with the described relatively valve seat bias voltage of described valve, thereby seal described valve with first pressure that is enough to form described sealing; Destroy described sealing by supplying described Compressed Gas to described valve with second pressure that is lower than described first pressure; Described valve is moved on to described second fixed position; When being in described second fixed position when described valve, by supplying described Compressed Gas to described valve with the 3rd pressure that is enough to form described sealing, so that the described relatively valve seat bias voltage of described valve, thereby seal described valve.
The invention provides a kind of system that is used for reducing friction during valve moves, it comprises: flow distributor; Valve seat; With the driver that described flow distributor is associated, it is used for described flow distributor is moved on to second fixed position from first fixed position; The compressed gas source that is communicated with described flow distributor fluid; Pressure regulator, when described flow distributor is positioned at described first or during described second fixed position, this pressure regulator is supplied described Compressed Gas to described flow distributor with first pressure that is enough to the described flow distributor of described relatively valve base sealing, when described flow distributor was mobile between described first and second fixed positions, this pressure regulator was supplied described Compressed Gas to described flow distributor with second pressure that is lower than described first pressure.
The invention provides a kind of regenerative thermal oxidizer that is used to handle gas, it comprises: the combustion zone; Exhaust apparatus; The first heat exchange platform that comprises heat exchange medium, it communicates with described combustion zone and described exhaust apparatus; The second heat exchange platform that comprises heat exchange medium, it communicates with described combustion zone and described exhaust apparatus; At least one is used for entering the valve that replaces between second fixed form of the described second heat exchange platform at first fixed form, move mode and the permission air-flow that allow described air-flow to enter the described first heat exchange platform, and described valve comprises valve drive and valve seat; The device that when described valve is in described first or second fixed form, is used for the described valve of described relatively valve base sealing; Device with the described valve that when described valve is in described move mode, is used to break seal.
Prior art problems has been overcome by the present invention, and it provides a kind of and has been used for elevator system, the switch valve of switch valve and comprises elevator system and the regenerative thermal oxidizer of switch valve.Valve of the present invention has good sealing characteristics, and it is minimum that wearing and tearing are dropped to.Described elevator system can help valve to seal with minimal friction forces rotation and when valve provides closely fixedly the time.In a preferred embodiment, when valve switched with the contact pressure between reduction moving member and the fixture, the sealing force of the relative valve seat of valve was lowered, thereby causes the required less moment of torsion of movement of valve.
For the application of regenerative thermal oxidizer, described valve preferably has sealing plate, and it can limit 2 chambers, and each chamber is all as one flow ports in 2 regeneration platforms that lead to oxidation unit.Described valve also comprises the switching flow distributor, and it can provide the passage that leads to each semitight plate for enter the mouth process gas or outlet process gas in turn.Valve is worked between dual mode: fixed form and valve move mode.Under fixed form, adopt the airtight closely leakage that minimizes or prevent process gas.According to the present invention, during valve moved, sealing load can reduce or eliminate, or applied counter-pressure or reaction force, to promote the mobile of valve and to reduce or eliminate wearing and tearing.The amount of used sealing load can accurately be controlled according to process characteristic, so that valve is carried out effective seal.
Description of drawings
Fig. 1 is the perspective view of regenerative thermal oxidizer according to an embodiment of the invention;
Fig. 2 is the perspective exploded view of a regenerative thermal oxidizer part according to an embodiment of the invention;
Fig. 3 is the valve port bottom perspective view that forms the part of the valve that is suitable for the present invention's use;
Fig. 4 is the perspective view that forms the flow distributor of a switch valve part that is suitable for the present invention's use;
Fig. 4 A is the profile of flow distributor shown in Figure 4;
Fig. 5 is the perspective view of a flow distributor part shown in Figure 4;
Fig. 6 is the top view that is suitable for the sealing plate of the valve that the present invention uses;
Fig. 6 A is the profile of a sealing plate part shown in Figure 6;
Fig. 7 is the perspective view of the axle of flow distributor shown in Figure 4;
Fig. 8 is suitable for the driving mechanism exploded view that the present invention uses;
Fig. 9 is the profile of a driving mechanism part shown in Figure 8;
Figure 10 is the profile that is depicted as the driving shaft of the valve of the present invention that links to each other with driving mechanism shown in Figure 8;
Figure 11 is the schematic diagram of elevator system according to an embodiment of the invention;
Figure 11 A is the schematic diagram of elevator system in accordance with another embodiment of the present invention;
Figure 12 is the profile of the elevator system of optional embodiment according to the present invention;
Figure 13 is the schematic diagram of the elevator system of another optional embodiment according to the present invention;
Figure 14 is the profile that is suitable for the rotation mouth of the flow distributor that the present invention uses;
Figure 15 is the profile than lower part that is suitable for the driving shaft of the flow distributor that the present invention uses;
Figure 16 is the profile that is suitable for the rotation mouth of the valve that the present invention uses;
Figure 16 A is the perspective view that is used to seal the clasp of the valve that is suitable for the present invention's use;
Figure 16 B is the profile of clasp shown in Figure 16 A;
Figure 16 C is the perspective view that is used to seal the mounting ring of the valve that is suitable for the present invention's use;
Figure 16 D is the profile of mounting ring shown in Figure 16 C;
Figure 16 E is the perspective view that is used to be suitable for the dull and stereotyped bearing arc of the valve that the present invention uses;
Figure 16 F is the profile of dull and stereotyped bearing arc shown in Figure 16 E;
Figure 16 G is the perspective view of an embodiment that is used to be suitable for the sealing ring of the valve that the present invention uses;
Figure 16 H is the profile of sealing ring shown in Figure 16 G; With
Figure 16 I is the profile of sealing ring upper groove shown in Figure 16 G.
The specific embodiment
Though what below describe most of explanation is that elevator system of the present invention is at United States Patent (USP) 6,261, the purposes of 092 switch valve aspect (it discloses by being cited in here and introduces), but should be noted that, the present invention is not limited in arbitrary special valve, and it can be used for the valve system of any needs sealing.
Suppose that we are familiar with the valve disclosed in patent ' 092.In brief, Fig. 1 and 2 illustrates two chambers regenerative thermal oxidizer 10 (catalysis or on-catalytics), and it is supported on the framework 12 as shown in the figure.Oxidation unit 10 comprises shell 15, wherein is provided with first and second heat-exchanging chambers and communicates with the combustion zone that is positioned at central part.The burner (not shown) can link to each other with the combustion zone, and has combustion blower can be supported on the framework 12, so that provide combustion air to burner.The combustion zone comprises bypass outlet 14, and it can be communicated with exhaust chimney 16 fluids that lead to atmosphere usually.The controller of control room 11 housing apparatus also preferably is positioned on the framework 12.With respect to control room 11 are the fan (not shown) that are supported on the framework 12, enter oxidation unit 10 so that drive process gas.Shell 15 comprises top chamber or top board 17, and it has one or more entrance doors 18, can provide the passage that enters shell 15 for the operator.Persons of ordinary skill in the art will appreciate that the description of aforementioned relevant oxidation unit only is for for the purpose of illustrating; Other design is also contained within the scope of the present invention well, comprises the oxidation unit that has greater or less than 2 chambers, the oxidation unit with horizontal orientation chamber and catalytic oxidizing equipment.Cold face plenum 20 has constituted the bottom of shell 15, and it can illustrate well at Fig. 2.Following description in more detail is provided with suitable supportive grid 19 on cold face plenum 20, it can be supported on the heat exchange matrix in each heat exchange tower.In an illustrated embodiment, heat-exchanging chamber is separated by partition wall 21, and partition wall 21 is preferably by thermal insulation.Also be in the embodiment shown, the stream by the heat exchange platform is vertical; Process gas enters described heat exchange platform from the valve port that is positioned on the cold face plenum 20, upwards (towards top board 17) flows into first, enter and first combustion zone that communicates, flow out the combustion zone and enter second Room, it flows to cold face plenum 20 by second downwards there.But, those skilled in the art will appreciate that other orientation also is fit to, and comprises horizontal structure, as if a kind of like this structure, wherein heat exchange tower faces one another and separates by the combustion zone of locating at the middle part.
Fig. 3 is the view of valve port 25 from the bottom.Plate 28 has 2 relative symmetrical openings 29A and 29B, and itself and baffle plate 26 (Fig. 2) define valve port 25 together.Arbitrarily rotating blades 27 is arranged in each valve port 25.Each moving blade 27 has first end that is fixed on the plate 28 and is fixed on second end that separates with first end on the baffle plate 24 from every limit.As shown in Figure 3, each moving blade 27 broadens to its second end from its first end, upwards changes angle at a certain angle, and flattening at the 27A place then is horizontal line.Described moving blade 27 runnings are so that guiding the process gas of emitting from valve port during operation flows away from valve port, to help the distribution by cold face plenum.Enter being evenly distributed with of cold face plenum 20 and help to guarantee even distribution, to obtain best heat exchanger effectiveness by heat exchange medium.
Fig. 4 and Fig. 4 A illustrate the flow distributor 50 that is contained in 51 li of collectors, and wherein collector 51 has process gas inlet 48 and process gas outlet 49 (though parts 48 can be outlets, 49 can be inlet, will use the embodiment of front for purposes of illustration here).Flow distributor 50 comprises the cylindrical drive axle 52 (Fig. 4 A, 5) that is preferably hollow, its link to each other with driving mechanism (seeing Fig. 8-10 for details).What be connected to driving shaft 52 is the local parts 53 of frustoconical shape that are.Parts 53 comprise the matching disc that is made of 2 relative pie shaped sealing surfaces 55,56, wherein each sealing surface is connected by circular outer rim 54 and stretches out from the angle of driving shaft 52 with 45 °, makes the space that is limited by two sealing surfaces 55,56 and outer rim 54 limit first gas passage or passage 60.Equally, second gas passage or passage 61 are by the side plate of 55,56 and 3 inclinations of sealing surface of relative first passage, and the side plate 57C that just angled relatively side plate 57A, 57B and central authorities tilt limits.The side plate 57 that tilts separates passage 60 from passage 61.The top design of described passage 60,61 gets the shape of symmetrical openings 29A, 29B on the matching disc 28, and under the condition that assembles, each passage 60,61 all aligns with each opening 29A, 29B.No matter flow distributor 50 orientation at any given time is how, 61 in passage and inlet 48 fluid communication, 60 in passage and outlet 49 are by air compartment 47 fluid communication.Like this, only pass through passage 61 by 48 process gas that enter collector 51 that enter the mouth and flow, only mobile by outlet 49 from the process gas of valve port 25 admission passages 60 via air compartment 47.
Sealing plate 100 (Fig. 6) is connected with the plate 28 that limits valve port 25 (Fig. 3).Followingly describe in more detail, between the end face of flow distributor 50 and sealing plate 100, preferably adopt airtight, and aeroseal preferably.Flow distributor can rotate through driving shaft 52 relative fixed plates 28 around vertical axis.The removable sealing surface 55,56 of this rotation makes it align with the part adjustment of opening 29A, 29B or does not line up.
Now a kind of method of seal valve will be discussed in conjunction with Fig. 4,6 and 7 at first.Described flow distributor 50 swims on the mattress, wearing and tearing can be reduced to minimum when moving with convenient flow distributor or eliminate wearing and tearing.Those skilled in the art will appreciate that, though air is preferred, and for also can be referred for the purpose of illustrating, can use other gas rather than air here.Mattress not only can seal valve, and can make flow distributor move not friction or roughly not friction.As the pressure-flow system of fan or similar object, it can be identical or different with the fan that is used for to combustion zone burner supply combustion air, is used for by the conduit (not shown) that is fit to and air compartment 64 driving shaft 52 air feed to flow distributor 50.Show clearly that as Fig. 5 and 7 air enters driving shaft 52 from conduit through one or more holes 81 that form in driving shaft 52 main bodys above the bottom 82 of driving shaft 52, described driving shaft 52 links to each other with driving mechanism 70.Although described hole 81 preferably is symmetrically distributed in around the axle 52, and be size equalization for the purpose of evenly, the definite position in hole 81 is not particularly limited.Shown in arrow among Fig. 5, the air of pressurized flows to the top of axle, and portion of air enters one or more radial conduit 83, describes in more detail as following, and this conduit and annular are rotated annular seal on the mouth 90 and communicated and supply with.The portion of air that does not enter radial conduit 83 continues to flow on driving shaft 52 and arrives passage 94 up to it, and passage 94 is assigned to air in the passage of the part that has semicircular part 95 and limited by full cheese voussoir 55,56.The coupling face of flow distributor 50, particularly the coupling face of pie shaped voussoir 55,56 and outer circular edge 54 as shown in Figure 4, are formed with many holes 96.Shown in Fig. 5 arrow, the air of pressurized by described hole 96 passing aways 95, forms mattress from passage 95 between the end face of flow distributor 50 and fixing seal plate 100 as shown in Figure 6.Sealing plate 100 comprise width be equivalent to flow distributor 50 end face 54 width outer circular edge 102 and a pair of in shape with pie shaped voussoir 55, the 56 corresponding pie shaped elements 105,106 of flow distributor 50.Sealing plate 100 matches with the plate 28 (Fig. 3) of valve port (and linking to each other).Hole 104 can hold the pivot pin 59 (Fig. 5) that is connected to flow distributor 50.Downside towards the outer circular edge 102 of flow distributor comprises one or more cannelures 99 (Fig. 6 A), and it aligns with the hole 96 on the flow distributor 50 coupling faces.Concentric groove 99 of 2 rows and the corresponding hole 96 of 2 rows are preferably arranged.Like this, described groove 99 helps to facilitate from end face 54 interior holes 96 discharges air, to form mattress between the outer circular edge 102 of coupling face 54 and sealing plate 100.In addition, the air of discharging from the hole 96 of pie shaped part 55,56 forms mattress between the pie shaped part 105,106 of pie shaped part 55,56 and sealing plate 100.The leakage that these mattress will also not be cleaned into the process gas of clean process gas stream minimizes or prevents its leakage.The relatively large pie shaped voussoir of flow distributor 50 and sealing plate 100 provides a path by the length at flow distributor 50 tops, and raw gas must be from this path process so that cause leakage.Since flow distributor 50 was all fixed in the most of the time during operation, between all coupling faces of valve, will form the mattress that is difficult to penetrate.
Preferably the air of pressurized is sent to the equipment that wherein uses valve from the fan different with the fan that transmits process gas, so that make the pressure of sealing air be higher than the process gas pressure of inlet or outlet, thereby forms positive seal.
As Fig. 7 and 14 clear shown in, flow distributor 50 comprises and rotating mouthful.The frusto conical part 53 of flow distributor 50 can center on ring-shaped cylinder wall 110 rotations of outer annular seal effect.Described wall 110 comprises and is used for being clipped in the outer annular flange 111 of (seeing Fig. 4 equally) on the collector 51 with wall 110 centerings and with it.Have the interior annular seal 116 (being preferably metal material) of E shape to be connected to flow distributor 50, it has groove 115A, the 115B of a pair of spaced-apart parallel to constitute thereon.As shown in the figure, piston ring 112A is positioned at groove 115A, and piston ring 112B is positioned at groove 115B.Each piston ring 112 relative outer shroud sealed wall 110 biasing, even when flow distributor 50 rotations, also keep motionless.Shown in Figure 14 arrow, pressurized air (or gas) flows through radial conduit 83, by the hole 84 that communicates with each radial conduit 83, enters passage 119 between piston ring 112A, the 112B and the slit between each piston ring 112 and the interior annular seal 116.When flow distributor relative fixed cylindrical wall 110 (with piston ring 112A, 112B) rotated, the air in the passage 119 made two space superchargings between piston ring 112A, the 112B, thereby formed a kind of continuing and the friction free sealing.Slit between piston ring 112 and the inner piston seal 116, and the slit 85 between inner piston seal 116 and the wall 110 can be regulated in the driving shaft 52 any (axially or in addition) that produces because of heat growth or other factors and moves.Those skilled in the art will appreciate that, though what illustrate is the sealing of dual-active plug ring, are that further sealing also can be with three or more piston rings.Can be with malleation or negative-pressure sealing.
Figure 15 illustrates to how relative drive shaft 52 sealings of the air compartment 64 of axle 52 supply pressurized air.Except seal not the pressurized, the mode of its sealing means and above-mentioned rotation mouth is similar, and only needs a piston ring to be used for air compartment each sealing about in the of 64.Present a demonstration with the sealing on the air compartment 64, form ring sealing 216 in the C shape by the boring central slot therein.The stationary annular cylindrical wall 210 that plays the outer shroud sealing function comprises and is used for being clipped in outer annular flange 211 on the air compartment 64 with wall 210 centerings and with it.Fixed piston ring 212 is located in the groove that forms in the annular seal 216 in the C shape, and wall 210 biasings relatively.Slit between the boring of piston ring 212 and C shape inner seal 216, and any moving that driving shaft 52 produces because of thermal expansion or similar factor can be regulated in the slit between C shape inner seal liner 216 and the outer cylindrical wall 210.As shown in figure 15, similar cylindrical wall 310, C shape inner seal 316 and piston ring 312 are used in the opposite side of air compartment 64.
Figure 16-16I shows the optional embodiment that is used to seal, and the same with shown in the common pendent U.S. Patent application 09/849,785, and it is disclosed in here and is incorporated herein by quoting as proof.At first referring to Figure 16, retaining ring seal 664, it is preferably made by carbon steel, illustrates to be attached on the runner assembly 53.Shown in the perspective view among Figure 16 A, keep preferably split ring of sealing ring 664, and have the cross section shown in Figure 16 B.To encircle opening helps to install and remove.Although can use other device attachment ring 664 that is fit to, keep sealing ring 664 to be attached on the runner assembly 53 with cap screw 140.Best runner assembly comprises and is used for the retaining ring seal is correctly fixed on locational groove.
Keeping sealing ring 664 relatively is installing rings 091, can clearly see Figure 16 C and 16D.Installing ring 091 also with cap screw 140 ' be connected to runner assembly 53, is formed for the groove of correct location and installation ring 091 on runner assembly.
In an illustrated embodiment, runner assembly rotates around vertical axis, and when sealing ring 658 relative installing rings 091 slided, its weight may cause wearing and tearing.In order to reduce or eliminate this wearing and tearing, installing ring 663 is formed with the tongue piece 401 that forms along it on every side, shown in Figure 16 D is clear, is preferably in the location, middle part.Optional dull and stereotyped bearing arc 663 has on shape and position and tongue piece 401 corresponding grooves 402 (Figure 16 E, 16F), and as shown in figure 16, it is positioned on the installing ring 091 when assembling.The dull and stereotyped bearing arc 663 the most handy materials that are different from sealing ring 658 are made, so that it can bring into play the effect of bearing.The material that is fit to comprises that bronze, pottery or other are different from the metal of sealing ring 658 used metal materials.
What keep locating between sealing ring 664 and the arc 663 is sealing ring 658.Shown in Figure 16 G and 16H, sealing ring 658 has and runs through the radial slot 403 that forms around it.As shown in figure 16, on a limit of sealing ring 658, radial slot 403 ends at semicircular structure on every side, forms distributing trough 145 when abutting sealing ring shell 659 with convenient sealing ring 658.Substitute, can use one or more radial slot 403.In the embodiment shown, annular seal 658 also have communicate with radial slot 403 and with the boring 404 of its quadrature.By to described boring 404 pressurizations, can form a kind of balance, prevent that wherein sealing ring 658 from moving down because of himself weight.If the direction difference of described valve as Rotate 180 °, can form boring 404 on the top of sealing ring 658.Substitute, on top or bottom or upper and lower part both can use more than one and hole 404.If for example, the direction half-twist does not then need balance.Since sealing ring 658 keeps motionless and described shell is also motionless, then seal 658 does not need to be circle; Comprise that ellipse and octagonal other shape also are fit to.Annular seal 658 can be a slice, or two or more than.
By using single ring assembly, can eliminate the power that promotion or dilatory double-piston annular seal separate.In addition, when numerical portion reduces, can realize saving, and monocycle can make bigger cross section, and thereby can make with more stable in size parts.Described ring is portion in two, so that can easier installation and replacement.Compression spring or other bias unit can be placed in the recess hole 405 (Figure 16 I) of opening, so that make the outside power of ring generation to boring.
Figure 15 illustrates air compartment 64 relative drive shafts 52 sealings that pressurized air is provided to axle 52.Except sealing not pressurized, sealing means is identical with the mode that above-mentioned rotation mouth adopts, and each sealing of air compartment 64 upper and lowers is only needed a piston ring.With the sealing on air compartment 64 tops as an example, form annular seal 216 in the C shape by the intermediate channel of holing therein.Be equivalent to the stationary annular cylindrical wall 210 that outer annular seal works and comprise outer annular flange 211, be used for wall 210 is placed the middle part and it is clipped in air compartment 64.Fixing piston ring 212 is located in the groove that forms on the annular seal 216 in the C shape, and wall 210 biasings relatively.Slit between the boring of piston ring 212 and C shape inner seal liner 216, and the slit between C shape inner seal liner 216 and the outer cylindrical wall 210 can regulate driving shaft 52 any because of moving that thermal expansion or similar factor produce.As shown in figure 15, on the relative edge of air compartment 64, adopt similar cylindrical wall 310, C shape inner seal liner 316 and piston ring 312.
Referring now to Fig. 8 and 9,, it shows the details of the suitable drive mechanisms that is used for flow distributor 50.Cylinder 800 places and drives under the bottom 802, and by connecting on it as the screw rod that is attached to the axle bush 805 that holds bearing 806.As shown, the approaching sensor 803 on the Support bracket 804 is gone back in bottom 802, relative rack support carriage 807A, 807B.Guide shaft 808 is positioned at bearing 806.Spur gear 809 has the mesopore that holds the axle 808 that is used for transmitting gear.A pair of relative tooth bar 810 each tooth bar all have a lot of teeth, and in the time of on correctly being positioned at gear 809 relative edges, the gear on these teeth and the spur gear 809 closely cooperates.Each tooth bar 810 all uses suitable coupling to be attached to be used for accordingly the cylinder 812 of tooth bar action.
To describe in conjunction with Figure 11 now and employedly be used to cause do not have friction or the power that moves of friction free valve or the effect of counter-force basically according to of the present invention.Watertight aircase 450 keeps best compressed air at least about 80 pounds.As mentioned above, watertight aircase 450 is communicated with cylinder 812 fluids of the driving mechanism that promotes valve forward backward.The action of cylinder 812 can be by solenoid 451 controls.Watertight aircase 450 (or different watertight aircases) also to shown in low-pressure regulator 460 and high pressure regulator 461 supply compressed air.Adjuster 460,461 communicates with switch 465, and it is solenoid preferably.Solenoid is changed air feed and is pressed between two adjusters.Can use discharge valve 467 arbitrarily as a kind of safety measure.For example, if the power failure phenomenon takes place, discharge valve 467 can block the compressed air stream that is used for seal valve, valve is fallen and thereby open path so that prevent that any one generation is overheated in the regenerative oxidizer platform.Pressure gauge 468, pressure transmitter and low-voltage safety switch also can be used to monitor force and be used for reducing pressure as a kind of safety precaution when breaking down.
In the environment of using regenerative thermal oxidizer, the 50 most times of flow distributor (for example about 3 minutes) all are in the fixing seal position, and only just are in move mode in cycle period (for example about 3 seconds).When fixedly, seal flow distributor with relative valve seat (being sealing plate 100) by high pressure regulator 461, the relative higher pressure of valve 465 with driving shaft 52 feeds.The supply pressure must be enough to contend with the weight of flow distributor and with it by putting valve base sealing.Before valve moves, 2-5 is before second according to appointment, solenoid 465 from by high pressure regulator 461 air feed to changing by low-pressure regulator 460 air feed, and thereby reduced (by driving shaft 52) pressure to the flow distributor supply, and allow flow distributor " floating " so that there is not the next position that rubs or frictionally shift to it near nothing subsequently.In case arrival the next position, solenoid 465 just from by the air feed of low-pressure regulator to returning by the air feed conversion of high pressure regulator, and be enough to once more the pressure of seal valve by driving shaft 52 supplies.
Depend on the size of flow distributor by the special pressure portion of low pressure and high pressure regulator supply, can determine by the ordinary skill people in this area at an easy rate.As an illustration, for the valve that can handle 6000 cubic feet of per minute flows, have been found that suitable pressure is low pressure 15 pound per square inches, high pressure (sealing load) 40 pound per square inches.For the valve that can handle 10,000 to 15,000 cubic feet of per minute flows, have been found that suitable pressure is low pressure 28 pound per square inches, high pressure 50 pound per square inches.For the valve that can handle 20,000 to 30,000 cubic feet of per minute flows, have been found that suitable pressure is low pressure 42 pound per square inches, high pressure 80 pound per square inches.For the valve that can handle 35,000 to 60,000 cubic feet of per minute flows, have been found that suitable pressure is low pressure 60 pound per square inches, high pressure 80 pound per square inches.
In another embodiment of the present invention, adopted a kind of similar system to come to transmit suitable pressure with the sealing and the described valve 50 of breaking seal to driving shaft 52.For example, with reference to Figure 11 A, when valve is in sealing means, can to adjuster, as be preferably disposed on the pressure transmitter that the Electropneumatic pressure adjuster 700 in the heat-seal communicates and carry signal.Can make adjuster 700 allow the certain pressure of supply like this with sealing flow distributor 50.Move or just before this moves, pressure transmitter indicator controller 700 reduces or eliminates sealing load, and is just removable so that flow distributor 50 need not to contact with sealing plate 100 at flow distributor.Like this, adjuster has been regulated output pressure based on control signal, and this control signal can allow to transmit in air pressure from 0 to 100% scope.If control signal removes (being zero setting), then adjuster is reduced to zero with output pressure, flow distributor is descended and stops sealing from a Room to another chamber.
Being applied to the pressure quantity that promotes and seal flow distributor 50 or reduction and unpacking flow distributor 50 can control with the programmable logic controller (PLC) that communicates with pressure transmitter (PLC).This allows extra flexibility, because the accurate quantity of being exerted pressure can be imported according to environment.For example, by oxidation unit than low-flow on, can only need less pressure come seal valve.Programmable logic controller (PLC) can according to various modes of operation change the pressure quantity of confession with seal valve.These modes of operation can be directly by PLC controls or sensing, can continue or constantly monitors and regulate along with time ground passage.For example, pressure can reduced during " baking " mode so that valve opens during in high-temperature operation at an easy rate.Described pressure also can reduce or increase according to the variation of the amount of air communication peroxidating device.This point can accomplish, with the aerodynamic characteristics of recuperation valve (as, its promotes or reduces the trend of air pressure).Also can on lower air-flow, need higher sealing load.This embodiment also can provide a kind of intrinsic security feature, even air-flow descends suddenly or stops fully, pressure transmitter also can be reduced to sealing load zero at once, thereby makes valve 50 landing.The also remote-controlled monitoring of pressure quantity and the input of confession.
Figure 12 shows optional embodiment of the present invention.In this embodiment, the sealing load of the driving shaft 52 of flow distributor 50 obtains stable supply, and offsets sealing load with counter-force during valve moves.In the embodiment shown, this counter-force is following provides.Annular chamber or groove 490 (being shown in the cross section) on sealing plate 100, have been formed.But cannelure 490 through ports 491 are communicated with compressed air fluid from source 495.Move constantly or just before valve moves (for example 0.5 second) at valve, solenoid 493 is activated, compressed air be directed flowing through flow control valve 494 also through port 491 enter cannelure 490.Have enough pressure to be supplied, it is dispersed in the top of valve by groove 490, so that offset the sealing load of eccentrically arranged valve to sealing station.This has formed a slit between the top of sealing plate 100 and flow distributor 50, thereby flow distributor and sealing plate can be in contact with one another during moving.When mobile finishing, the interior air-flow of cannelure reduces or stops until next circulation.The sealing load that the result is high makes the relative sealing plate sealing of flow distributor once more.Those skilled in the art can determine the required pressure of payment high sealing pressure easily.
Optional is, is used for the compressed air of counter-force also to can be used to cool off driving bearing 409.For this reason, show by flow control valve 494 ' to the compressed-air actuated cooling circuit of bearing 409 supply.
That can use other is used for counter-force to overcome the method for high sealing power, and this method within the scope of the present invention.For example, Figure 13 shows cylinder 620, and its location can make flow distributor 50 can stressedly leave sealing plate 100 when driving.Like this, cylinder 620 is with regard to available enough pins of trying hard to recommend by flow distributor 50 axis 59 (Fig. 5), the high pressure sealing power during moving with the valve that contends with.In case flow distributor is located on its reposition, described cylinder circulates until next with regard to regracting.
In a further embodiment, both can also can during valve moves, it be shifted out sealing relationship with in the sealing relationship of magnetic force with flow distributor suction and sealing plate 100.For example, the electromagnet that can be activated in the sealing plate 100 location comes seal valve, and removes excitation to it during valve moves so that flow distributor from the sealing relationship of sealing plate withdraw and do not have frictional movement.
As previously mentioned, the present invention can be used in other valve with air or air seal.For example, can use the lift cylinder relative valve base sealing lift valve similar with driving shaft 52.Can adopt system of the present invention to regulate and be used for the pressure quantity of seal valve according to process conditions.Like this, in special regenerative thermal oxidizer application,, under the situation that still can obtain suitably sealing, can reduce being used for the pressure (aequum when process gas flow rate is higher relatively) of sealing lift valve if the flow of process gas is lower than normal value.This can help to prolong the lift valve life-span by reducing wear.
Claims (14)
1. system that is used for during valve moves, reducing friction, it comprises:
Flow distributor;
Valve seat;
With the driver that described flow distributor is associated, be used for described flow distributor is moved on to second fixed position from first fixed position;
The compressed gas source that is communicated with described flow distributor fluid;
First adjuster is when described flow distributor is positioned at described first or during described second fixed position, this first adjuster is used for supplying described Compressed Gas to described flow distributor with first pressure of enough described flow distributors of described relatively valve base sealing; With
Second adjuster, when described flow distributor was mobile between described first and second fixed positions, this second adjuster was used for supplying described Compressed Gas to described flow distributor with second pressure that is lower than described first pressure.
2. the system as claimed in claim 1, it further comprises the solenoid that is connected with described first and second adjusters, is used to replace described adjuster and supplies described Compressed Gas to described flow distributor.
3. system as claimed in claim 2, it further comprises the discharge valve that is positioned at described solenoid downstream, is used for selectively stoping compressed air to flow to described flow distributor.
4. the system as claimed in claim 1, wherein said driver comprises that hollow drive shaft and wherein said compressed air are communicated with by described hollow drive shaft fluid with described flow distributor.
5. the system as claimed in claim 1, wherein said flow distributor comprises the end face with many holes, and wherein said sealing is formed by the described compressed air that flows out described hole and form mattress between described end face and described valve seat.
6. system that is used for during valve moves, reducing friction, it comprises:
Flow distributor;
Valve seat;
With the driver that described flow distributor is associated, it is used for described flow distributor is moved on to second fixed position from first fixed position;
The compressed gas source that is communicated with described flow distributor fluid;
Pressure regulator, when described flow distributor is positioned at described first or during described second fixed position, this pressure regulator is supplied described Compressed Gas to described flow distributor with first pressure that is enough to the described flow distributor of described relatively valve base sealing, when described flow distributor was mobile between described first and second fixed positions, this pressure regulator was supplied described Compressed Gas to described flow distributor with second pressure that is lower than described first pressure.
7. regenerative thermal oxidizer that is used to handle gas, it comprises:
The combustion zone;
Exhaust apparatus;
The first heat exchange platform that comprises heat exchange medium, it communicates with described combustion zone and described exhaust apparatus;
The second heat exchange platform that comprises heat exchange medium, it communicates with described combustion zone and described exhaust apparatus;
At least one is used for entering the valve that replaces between second fixed form of the described second heat exchange platform at first fixed form, move mode and the permission air-flow that allow described air-flow to enter the described first heat exchange platform, and described valve comprises valve drive and valve seat;
The device that when described valve is in described first or second fixed form, is used for the described valve of described relatively valve base sealing; With
The device of described valve is used to break seal when described valve is in described move mode.
8. regenerative thermal oxidizer as claimed in claim 7, the wherein said device that is used to seal described valve comprises by described valve to be enough to form the first pressure compressed gas supplying of mattress between described valve and described valve seat.
9. regenerative thermal oxidizer as claimed in claim 8, the device of the wherein said described valve that is used to break seal comprise with the second pressure compressed gas supplying that is lower than described first pressure to described valve.
10. regenerative thermal oxidizer as claimed in claim 7, the wherein said described device that is used to seal described valve comprises the power that described relatively valve is provided, so that described valve and described valve seat are in the sealing relationship and the device of the wherein said described valve that is used to break seal comprises the counter-force that provides opposite with described power.
11. regenerative thermal oxidizer as claimed in claim 10, wherein said power is by applying and wherein said counter-force applies by supplying compressed air with second pressure opposite with described power and that be enough to destroy the amount of described sealing through described axle compressed gas supplying with first pressure.
12. regenerative thermal oxidizer as claimed in claim 7, wherein said valve is a lift valve.
13. regenerative thermal oxidizer as claimed in claim 12, it further comprises at least one transfer canal valve, is used for arriving based on the Position Control of described lift valve the seal gas flow of described seal interface.
14. regenerative thermal oxidizer as claimed in claim 7, wherein said valve is a butterfly valve.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/230240 | 2002-08-28 | ||
| US10/230,240 US6669472B1 (en) | 2002-08-28 | 2002-08-28 | Dual lift system |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038203812A Division CN100501290C (en) | 2002-08-28 | 2003-06-24 | Method for shifting valve from a first fixing position to a second fixing position |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101430096A true CN101430096A (en) | 2009-05-13 |
| CN101430096B CN101430096B (en) | 2011-08-31 |
Family
ID=29735518
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038203812A Expired - Lifetime CN100501290C (en) | 2002-08-28 | 2003-06-24 | Method for shifting valve from a first fixing position to a second fixing position |
| CN2008101490661A Expired - Fee Related CN101430096B (en) | 2002-08-28 | 2003-06-24 | Dual lift system |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038203812A Expired - Lifetime CN100501290C (en) | 2002-08-28 | 2003-06-24 | Method for shifting valve from a first fixing position to a second fixing position |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US6669472B1 (en) |
| EP (1) | EP1532412A4 (en) |
| JP (3) | JP2005537456A (en) |
| KR (1) | KR101025544B1 (en) |
| CN (2) | CN100501290C (en) |
| AU (3) | AU2003245679B2 (en) |
| CA (2) | CA2706650A1 (en) |
| MX (1) | MXPA05000462A (en) |
| NO (1) | NO20051552L (en) |
| PL (1) | PL199990B1 (en) |
| RU (1) | RU2334150C2 (en) |
| WO (1) | WO2004020925A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI418503B (en) * | 2011-03-24 | 2013-12-11 | Univ Nat Chunghsing | Automatic adjustment of sheet conveyance |
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-
2002
- 2002-08-28 US US10/230,240 patent/US6669472B1/en not_active Expired - Lifetime
-
2003
- 2003-06-24 JP JP2004532585A patent/JP2005537456A/en active Pending
- 2003-06-24 MX MXPA05000462A patent/MXPA05000462A/en active IP Right Grant
- 2003-06-24 WO PCT/US2003/020000 patent/WO2004020925A1/en active Application Filing
- 2003-06-24 AU AU2003245679A patent/AU2003245679B2/en not_active Expired
- 2003-06-24 KR KR1020057001378A patent/KR101025544B1/en active IP Right Grant
- 2003-06-24 CN CNB038203812A patent/CN100501290C/en not_active Expired - Lifetime
- 2003-06-24 CA CA 2706650 patent/CA2706650A1/en not_active Abandoned
- 2003-06-24 CA CA2489331A patent/CA2489331C/en not_active Expired - Lifetime
- 2003-06-24 PL PL373471A patent/PL199990B1/en not_active IP Right Cessation
- 2003-06-24 EP EP03739303A patent/EP1532412A4/en not_active Withdrawn
- 2003-06-24 CN CN2008101490661A patent/CN101430096B/en not_active Expired - Fee Related
- 2003-06-24 RU RU2005108591A patent/RU2334150C2/en not_active IP Right Cessation
- 2003-10-30 US US10/696,886 patent/US6978977B2/en not_active Expired - Lifetime
- 2003-10-30 US US10/696,883 patent/US6783111B2/en not_active Expired - Lifetime
-
2005
- 2005-03-23 NO NO20051552A patent/NO20051552L/en not_active Application Discontinuation
-
2009
- 2009-11-12 AU AU2009236036A patent/AU2009236036A1/en not_active Abandoned
- 2009-11-12 AU AU2009236032A patent/AU2009236032B2/en not_active Expired - Fee Related
- 2009-11-27 JP JP2009269366A patent/JP2010112704A/en not_active Withdrawn
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2014
- 2014-05-20 JP JP2014104161A patent/JP5816332B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI418503B (en) * | 2011-03-24 | 2013-12-11 | Univ Nat Chunghsing | Automatic adjustment of sheet conveyance |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1532412A4 (en) | 2011-01-19 |
| RU2334150C2 (en) | 2008-09-20 |
| AU2009236036A1 (en) | 2009-12-03 |
| CN1678876A (en) | 2005-10-05 |
| NO20051552L (en) | 2005-05-25 |
| PL199990B1 (en) | 2008-11-28 |
| US20040086822A1 (en) | 2004-05-06 |
| CA2706650A1 (en) | 2004-03-11 |
| KR101025544B1 (en) | 2011-03-29 |
| AU2009236032B2 (en) | 2012-02-09 |
| US6783111B2 (en) | 2004-08-31 |
| JP5816332B2 (en) | 2015-11-18 |
| AU2009236032A1 (en) | 2009-12-03 |
| AU2003245679B2 (en) | 2009-12-10 |
| JP2005537456A (en) | 2005-12-08 |
| KR20050056945A (en) | 2005-06-16 |
| MXPA05000462A (en) | 2005-03-23 |
| CA2489331C (en) | 2011-05-24 |
| EP1532412A1 (en) | 2005-05-25 |
| US6978977B2 (en) | 2005-12-27 |
| AU2003245679A1 (en) | 2004-03-19 |
| CN101430096B (en) | 2011-08-31 |
| US6669472B1 (en) | 2003-12-30 |
| PL373471A1 (en) | 2005-09-05 |
| JP2014169859A (en) | 2014-09-18 |
| CA2489331A1 (en) | 2004-03-11 |
| US20040086431A1 (en) | 2004-05-06 |
| JP2010112704A (en) | 2010-05-20 |
| CN100501290C (en) | 2009-06-17 |
| RU2005108591A (en) | 2005-08-27 |
| WO2004020925A1 (en) | 2004-03-11 |
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