CN101426923A - Biodegradable compositions comprising renewably-based, biodegradable 1,3-propanediol - Google Patents

Abstract

Disclosed herein are biodegradable compositions comprising 1,3-propanediol, wherein the 1,3-propanediol in said biodegradable composition has a bio-based carbon content of about 1% to 100%. In addition, it is preferred that the 1,3-propanediol be biologically-derived, and wherein upon blodegradation, the biologically-derived 1,3-propanediol contributes no anthropogenic CO2 emissions to the atmosphere.

Description

Comprise renewable base biodegradation type 1, the biodegradation type composition of ammediol

The cross reference of related application

The application requires the interests of following application: the U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, 471; The U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, 194, the U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, 193, the U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, 111, the U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, the U.S. Provisional Application No.60/772 that on February 10th, 120,2006 submitted to, 110, the U.S. Provisional Application No.60/772 that on February 10th, 2006 submitted to, the U.S. Provisional Application No.60/846 that on September 25th, 112,2006 submitted to, 948, the U.S. Provisional Application No.60/853 that on October 24th, 2006 submitted to, the U.S. Provisional Application No.60/859 that on November 15th, 920,2006 submitted to, 264, the U.S. Provisional Application No.60/872 that on December 4th, 2006 submitted to, the U.S. Provisional Application No.60/880 that on January 17th, 705 and 2007 submitted to, 824, disclosing wherein specially incorporated this paper into as a reference in full.

Technical field

Herein disclosed is and comprise 1, the biodegradation type composition of ammediol, wherein 1, the bio-based carbon content that ammediol has in described biodegradation type composition is about 1% to 100%.In addition, preferred 1, ammediol is the biology origin, and wherein when biological degradation, 1 of biology origin, ammediol is not to the artificial CO of atmospheric contribution ₂Discharging.

Background technology

The biodegradation type product particularly as the human consumer of personal care articles, makeup and sanitising agent or the like, has been considered many factors when selecting to use product.Some nearest factor has become the focus of scientific research and product development and has driven scientific research and product development.These driving factors comprise Product Safety, environmental influence, the natural degree of component and the aesthetic properties of overall product.Therefore, manufacturer must be concerned about the environmental influence of their product.In fact, the work about environmental influence understanding is the worldwide affairs of being assert by government department.Be that the whole world is made great efforts to facilitate and had precedence over cost and efficient is considered the example that safer environment is produced at present by the Kyoto Protocol amendment of the UNFCCC (United Nations Framework Convention on Climate Change) (UNFCCC) of 156 country's signatures.When contact biodegradation type product, the human consumer more and more has selectivity to the source of the product that they bought.The consumption expenditure that 2004 Co-operative Bank ' s annual Ethical Consumerism Report (www.co-operativebank.co.uk) disclose on the retail product that is meeting the specification between 2003 to 2004 (considering the general classification of trade goods environmental safety, organic and fair) increases by 30.3%, and total consumption expenditure only increases by 3.7% in the same period.

Glycols is ethylene glycol for example, propylene glycol, and 1,3 butylene glycol and 2-methyl isophthalic acid, ammediol is the biodegradation type compound, can be used on from makeup and personal care formulations the different compositions to sanitising agent to heat transfer compositions.Although biological degradability is being an important factor aspect the protection environment, the inevitable result that the biological degradation of the glycols of fossil base source origin has discharges previous fixed CO ₂In atmosphere.Therefore, although glycols is usually because its biological degradability is favourable, to bring the potentiality of Global warming be significant to fossil base glycols during biological degradation.

Carbonic acid gas comes out as the composition of the maximum in the various greenhouse gases in the atmosphere is selected.The level of atmospheric carbon dioxide has increased by 50% in nearest 200 years.Recently report points out that present atmospheric carbon dioxide level is higher than in SHEET LOADING DURING LATE PLEISTOCENE, i.e. maximum (the Siegenthaler of the new period before the modern humans, U. etc., Stable Carbon Cycle-Climate RelationshipDuring the Late Pleistocene, Science, Vol.310, no.5752 (Nov.25,2005), 1313-1317 page or leaf).Therefore, think that any further increase carbonic acid gas promotes stable the moving to global temperatures heating direction of greenhouse gases effect from global temperatures in atmosphere.Human consumer and environmental protection mechanism have determined that in the same way the carbon that industry discharges in atmosphere is the source that causes the carbon of Greenhouse effect.

Greenhouse gas emission can take place at any time of product time limit of service point.Human consumer and environmental protection mechanism have considered the whole time limit of service of product when estimating the environmental influence of product.The human consumer seeks not product to the new carbon of atmospheric contribution based on the environmental influence of producing, using and degrade.Only the organic products of being made up of the carbon molecule and the final big gas carbon of plant sugar and starch origin is considered to further not promote Greenhouse effect.

Except increasing the carbonic acid gas in atmosphere, the industrial process of present glycols also produces pollutent and refuse, and they comprise sulfuric acid, hydrochloric acid, hydrofluoric acid, phosphoric acid especially, oxalic acid, tartrate, acetate, basic metal, alkaline-earth metal, transition metal and heavy metal, comprise iron, cobalt, nickel, copper, silver, molybdenum, tungsten, vanadium, chromium, rhodium, palladium, osmium, iridium, rubidium and platinum (United States Patent (USP) 2,434,110,5,034,134,5,334,778 and 5,10,036).

To the human consumer of the human consumer of biodegradation type product, particularly personal care articles, makeup and detergent product meaningfully to the individual reaction of this product.In nearest 20 years, increase significantly in the development speed of U.S.'s allergy.Many these reactions are because trace substance causes.Other reaction is that the spy sends the source.It all is the product that natural component is formed that the human consumer seeks by the composition in purer source and/or all.

Summary of the invention

The present invention relates to comprise 1, the biodegradation type composition of ammediol and composition, wherein said 1, the bio-based carbon content that ammediol has is at least 1%.

The invention further relates to and comprise 1, the biodegradation type composition of ammediol and composition, wherein said composition is selected from: acceptable carrier, promoting agent, water, aqueous solution, tensio-active agent, auxiliary agent (builder), pH regulator agent, inhibiter, defoamer, dyestuff and food composition, and wherein said 1, and the bio-based carbon content that ammediol has is at least 1%.

The present invention even further relate to and comprise 1, the biodegradation type composition of ammediol and composition, and further comprise being selected from the personal care product makeup, sanitising agent, heat transfer compositions, anti-freezing composition, food, the composition of coating and ink, wherein said 1, the bio-based carbon content that ammediol has is at least 1%.

The invention still further relates to and comprise 1, the biodegradation type composition of ammediol, wherein said 1, the ultraviolet light absorption value at 220nm that ammediol has is lower than about 0.200, be lower than about 0.075 and be lower than about 0.075 in the ultraviolet light absorption value of 250nm in the ultraviolet light absorption value of 275nm.

The present invention relates in addition and comprises 1, and the biodegradation type composition of ammediol is wherein said 1, and the concentration of total organic impurity that ammediol has is lower than about 400ppm.

The present invention even further relate to and comprise 1, the biodegradation type composition of ammediol, wherein said 1, the people when biological degradation that ammediol has in described composition is CO ₂Emission performance is zero.

Description of drawings

Fig. 1 is renewable basic 1, ammediol (Bio-PDO ^TM) during the photosynthesis from atmospheric CO ₂Fixed CO ₂Discharging (1.7kg CO ₂/ kg product) and during the biological degradation of following material to atmospheric CO ₂Discharge (kg CO ₂/ kg product) figure: ethylene glycol (EG) (+1.4kg CO ₂/ kg product), propylene glycol (PG) (+1.7kg CO ₂/ kg product), fossil base 1, ammediol (Chem-PDO) (+1.7kg CO ₂/ kg product) and the fermentation origin 1, ammediol (Bio-PDO ^TM) (+1.7kgCO ₂/ kg product).

Fig. 2 is that expression is renewable basic 1, and ammediol (Bio-PDO) is to atmospheric CO ₂Clean discharging is the figure of zero (0).

Fig. 3 is that expression is for data computing form shown in Fig. 1 and Fig. 2.

Detailed Description Of The Invention

The applicant introduces especially all and is quoted from the full content of document in the disclosure. In addition, when giving output, concentration or other value or parameter as scope, preferable range, or during the inventory of upper limit preferred value and lower limit preferred value, can be regarded as is concrete disclosed all scopes that formed by any a pair of any higher limit or preferred value and any lower limit or preferred value, and no matter whether this scope is disclosed separately. When having described number range in this article, except as otherwise noted, this scope is intended to comprise its endpoint value, and all integers and mark in this scope. Scope of the present invention is not intended to and is limited to the particular value of setting forth when scope is defined.

Composition disclosed herein comprises 100% 1,3-PD of the highest diol component that accounts for composition, and this 1,3-PD has at least 1% bio-based carbon content. In one embodiment, 1,3-PD accounts in fact whole diol components of composition of the present invention. In another embodiment, 1,3-PD accounts for whole diol components of composition.

1,3-PD

Term " bioPDO ", " the Biodegradable 1,3-PD of biology origin ", " 1 of biology origin; ammediol ", " renewable basic 1,3-PD ", " renewable base biodegradation type 1; 3-propane diols ", " 1,3-PD biogenetic derivation and that produce by biological method " and similar terms used herein refer to the carbon of being originated by atmosphere but not 1,3-PD that the microbial metabolism of the sugar of the plant origin that fossil fuel carbon forms obtains.

The people is CO ₂ Emission performance

The present invention relates to the Biodegradable composition, such as, particularly, the personal care product, cosmetics, cleaning agent, heat-transfer fluid, anti-icing fluid, food, coating and ink, it comprises renewable base biodegradation type 1,3 propane diols, the people that wherein said renewable base biodegradation type 1,3-PD has is CO₂Emission performance is zero (0). " anthropogenic discharge's characteristic " refer to when compound or composition during in biodegradation the people to atmospheric contribution be CO₂Discharging.

" biodegradation type " or " biological degradability " is meant for example ability of carbonic acid gas and water of compound that compound destroy to be generated simple and stable by active organism.

Photosynthesis is that effect by the sun is with carbonic acid gas (CO ₂) and water (H ₂O) transform the process that enters generation growth substance in the plant, and biological degradation is by the activity of Living Organism CO to be got back in the organic substance conversion ₂And H ₂The process of O.

The for example test method of the biological degradability of glycols of many measurement organic chemicals is disclosed.An internationally recognized method is ASTM E1720-01, at sealed vessel CO ₂Generate the standard test methods (StandardTest Method for Determining Ready, the Ultimate Biodegradability of OrganicChemicals in a Sealed Vessel CO that measure existing, the final biological degradability of organic chemicals in the test ₂Production Test).

Biological degradation will can take place and be divided into prior biological degraded type class in performance 60% biological degradation or better chemical under most of oxygenated environments in this test method.All glycolss of mentioning in this document satisfy this standard.

It is of the present invention 1 that following elaboration has illustrated, ammediol does not provide the people when biological degradation be CO ₂The calculating of the discovery of discharging.Support the form of these calculating in table 3, to provide.

When 1 of a part, during the ammediol degraded, discharge the CO of three molecules ₂Enter atmosphere.Because between degradative phase from " fermentation origin " 1, all these CO that ammediol discharges ₂Molecule is the atmosphere source, so CO ₂To atmospheric clean release is zero.Relatively, because 1 of the propylene glycol of fossil oil origin and fossil origin, ammediol comprises three carbon atoms from fixed carbon source (being fossil oil), the propylene glycol or 1 of the fossil oil origin of a part, and the degraded of ammediol causes to the clean CO that discharges three molecules of atmosphere ₂Similarly, because the ethylene glycol of fossil oil origin comprises two carbon atoms, it is originated from fixed carbon, so the degraded of the ethylene glycol of the fossil oil origin of a part causes to the clean CO that discharges two molecules of atmosphere ₂

In order to quantize 1 of one kilogram ethylene glycol, propylene glycol, chemical origin, ammediol and " the fermentation origin " 1, ammediol (Bio-PDO ^TM) CO that discharges separately ₂, with product weight (1kg) divided by its molecular weight.For being present in intramolecular each carbon atom, discharge the CO of a part ₂With CO ₂Molecule number (molecules) multiply by CO ₂Molecular weight (44kg/ kilomol) with the CO of the product that quantizes per unit (kg) ₂Discharge the influence of (kg).

The release of fossil fuel carbon raw material

The ethylene glycol * of the fossil oil origin of 1kg (1kmol EG/62.068kg) * (2kmolCO ₂/ 1kmol EG) * (44kg CO ₂/ kmol CO ₂)=1.4kg CO ₂

The propylene glycol * of the fossil oil origin of 1kg (1kmol PG/76.094kg) * (3kmolCO ₂/ 1kmol PG) * (44kg CO ₂/ kmol CO ₂)=1.7kg CO ₂

1 of the fossil oil origin of 1kg, ammediol * (1kmol Chem-PDO/76.094kg) * (3kmol CO ₂/ 1kmol Chem-PDO) * (44kg CO ₂/ kmol CO ₂)=1.7kg CO ₂Bio-based carbon raw material balance

Catch:

1kg of Bio-PDO ^TM*(1kmol Bio-PDO ^TM/76.094kg)*(-3kmol CO ₂/1kmol Bio-PDO ^TM)*(44kg CO ₂/kmol CO ₂)＝-1.7kg CO ₂

Discharge:

1kg of Bio-PDO ^TM*(1kmol Bio-PDO ^TM/76.094kg)*(3kmol CO ₂/1kmol Bio-PDO ^TM)*(44kg CO ₂/kmol CO ₂)＝1.7kg CO ₂

Clean discharging:

-1.7kg+1.7kg＝0kg

This bio-based carbon raw material balance result has proved that the people that the Bio-PDO biological degradation of renewable source origin obtains is CO ₂Discharging is zero.Term " artificially " is meant synthetical or fossil origin.

Bio-based carbon

" atmosphere source carbon " used herein is meant from being the carbon atom of free carbon dioxide molecule origin earth atmosphere in decades recently.The quality of this carbon can be identified by specific radioisotopic existence as herein described." green carbon ", " big gas carbon ", " environmental friendliness carbon ", " the life cyclic carbon, " non-fossil fuel carbon ", " non-petroleum base carbon ", " carbon in atmosphere source " and " bio-based carbon " can use with the free burial ground for the destitute at this paper.

" carbon of fossil sources " used herein is meant the carbon in petrochemical industry source.This carbon is exposed under the UV line unlike big gas carbon, and therefore the carbon of most fossil sources has radio isotope seldom in its colony.The carbon of fossil sources can be identified by mode as herein described." fossil oil carbon ", " fossil-carbon ", " pollution carbon ", " petrochemical industry carbon ", the carbon of " Petrocarbon " and fossil sources uses with the free burial ground for the destitute in this article.

Abbreviation " IRMS " is meant the CO that measures than mass spectroscopy by the high precision stable isotope ₂Observed value.

Term " carbon " be meant any can be by the carbon source of microbial metabolism, wherein this matrix comprises at least one carbon atom.

" renewable base " expression 1, the carbon content of ammediol is from " new carbon " source, measure according to ASTM methods of test D 6866-05, this method uses radiocarbon C14 and isotopic ratio mass spectroscopy to measure the bio-based content of NATURAL DISTRIBUTION material, and it is incorporated herein by reference.This test method measuring the C-14/C-12 isotopic ratio in the sample, and it is compared with the C-14/C-12 isotopic ratio in 100% bio-based materials of standard, with the percentage ratio of the bio-based content that obtains sample." bio-based materials " is meant that carbon wherein uses solar energy (photosynthesis) from nearest (calculating with human time scale) the fixed CO that is present in the atmosphere ₂Organic materials.On land, this CO ₂Caught by plant life (for example farm crop or forest land material) or fixing.In the ocean, CO ₂By the synthetic bacterium of luminous energy or plant plankton catches or fixing.The C-14/C-12 isotopic ratio of bio-based materials is that 1:0 arrives greater than 0:1.Relatively on the spot, the C-14/C-12 isotopic ratio of fossil sill is 0:1.

A spot of carbonic acid gas has radioactivity in the atmosphere.The generation of this 14C carbonic acid gas is to take place under following situation: nitrogen is clashed into by the neutron that ultraviolet ray generates, and causing nitrogen to lose proton and forming molecular weight is 14 carbon, and it is oxidized to carbonic acid gas at once.But this radio isotope accounts for the small portion of big gas carbon occupies measurable share.Atmospheric carbon dioxide is made organic molecule during being called photosynthetic process and is circulated known by green plants.When generating carbonic acid gas (it is released and turns back in the atmosphere), finishes the life metabolism organic molecule of green plants or other form this circulation.In fact, the life of form of ownership depends on this green plants and produces organic molecule to obtain to promote growth and regenerated chemical energy on the earth.Therefore, be present in the part that 14C in the atmosphere becomes all life forms and biologic thereof.These biological degradations obtain CO ₂Renewable basic organic molecule do not promote Global warming because atmospheric carbon emission is not had a net increase of length.By contrast, fossil fuel carbon does not have the radiocarbon C14 ratio of significant atmospheric carbon dioxide.

CO is being worked as in atmosphere used herein source and fixed carbon source ₂Being time cycle atmosphere source or fixing source to relate to 1, is relative terms during the life cycle of ammediol.Therefore, although a certain period very likely in atmosphere, find from fossil oil carbon (and as corollary, this Atmospheric CO ₂Have one day combined fixed carbon source of entering), but for this paper, before being released into atmosphere by degraded, carbon thinks that carbon originates from fixed carbon.

The evaluation of renewable basic carbon can be undertaken by standard test methods in the material.Use radiocarbon C14 and isotopic ratio mass spectroscopy, can measure the bio-based content of material.ASTM International, formal title is U.S.'s test and materialogy meeting (American Society for Testing andMaterials), has established the standard method of the bio-based content that is used for evaluating material.This ASTM method is known as ASTM-D6866.

Use ASTM-D6866 and obtain " bio-based content " and be based upon identical with radiocarbon dating conceptively, and do not use the age formula.The ratio of the amount of the radiocarbon C14 in the amount of this analysis by deriving the radiocarbon C14 (14C) in unknown sample and the current reference standard carries out.This than the report value represent that with percentage ratio unit is " pMC " (contemporary carbon %).If analyzed material is the current radiocarbon C14 and the mixture of fossil-carbon (not comprising radiocarbon C14), then the amount of the biological material that exists in the pMC value of Huo Deing and the sample is directly related.

The current reference standard of using in radiocarbon dating is NIST (national standard and technology meeting, a National Institute of Standards and Technology) standard, uses the known radiocarbon C14 content that is about as much as nineteen fifty in Christian era.Select nineteen fifty in Christian era to be and testing the time before by the thermonuclear weapon of a large amount of excessive radiocarbon C14 (being called " bomb carbon (bomb carbon) ") of in the atmosphere introducing of exploding at every turn because it has been represented.AD nineteen fifty reference value is 100pMC.

The twice that 1963 year almost reach standard level of " bomb carbon " in the atmosphere before testing the peak period and stopping test protocols.Its distribution in atmosphere is an approximation since it occurs, and for for the plant and animal of having survived since nineteen fifty in Christian era, the value of performance is greater than 100pMC.It reduces as time goes by gradually, and present value is near 107.5pMC.This means that fresh biological material such as cereal can provide the radiocarbon C14 sign near 107.5pMC.

Fossil-carbon and current carbon are combined into the desaturation (dilution) that will cause current pMC content in the material.107.5pMC represents current biological material by supposition, and 0pMC represents petroleum derivative, and the pMC observed value of these materials will reflect the ratio of two types of components.100% material from current soybean will provide the radiocarbon C14 sign near 107.5pMC.If this material is by 50% petroleum derivative institute desaturation, then it will provide the radiocarbon C14 sign near 54pMC.

By specifying 100% to equal 107.5pMC and 0% and equal 0pMC, obtain the biomass content result.In this, observed value is that the sample of 99pMC will provide and be equivalent to 93% bio-based content results.

" the fermentation origin " 1, the sample of ammediol is submitted to Hawkeye State university (Iowa State University) by DuPont, adopts ASTM method D6866-05 to carry out the bio-based content analysis.Shown that from the result of Hawkeye State university above-mentioned sample is 100% bio-based content (referring to Norton, Glenn.Results of Radiocarbon Analyses on samples fromDuPont Bio-Based Materials-reported 07-08-05).

According to ASTM-D6866 material described herein is estimated.The mean value of quoting in this report comprises that 6% absolute range (at every end ± 3% of bio-based content value) is to make an explanation to the variation of component radiocarbon C14 sign end value.Suppose all material be current or fossil sources and required result be the amount of the bio-based component in " being present in " this material, rather than in manufacturing processed the amount of the bio-based materials of institute's " use ".

Derive from the radiocarbon C14 analytical results of the sample of DuPont bio-based materials

The 07-08-05 report

Product	Bio-based content (%)
		1, ammediol	100

Have some situation, biodegradable composition wherein of the present invention can comprise 1 of biology origin, and the diol component of ammediol and one or more abiology origin is such as 1 of for example chemosynthesis, the combination of ammediol.In this case, if confirmable words may be difficult to also determine that how much percentage ratio of diol component is the biology origin, and not by calculating the bio-based carbon content of diol component.In this, in biodegradable composition of the present invention, diol component, and particularly 1, ammediol, can comprise at least about 1% bio-based carbon content to maximum 100% the bio-based carbon content and any percentage ratio wherein.

Purity

The applicant uses is used for describing 1 of biology origin obtained by the method for the present invention, the term of ammediol " purifying in fact " expression comprises having 1 of at least a following feature, the composition of ammediol: 1) the ultraviolet light absorption value at 220nm is lower than about 0.200, be lower than about 0.075 and be lower than about 0.075 with ultraviolet light absorption value in the ultraviolet light absorption value of 275nm at 250nm; Or 2) L that has of composition ^*a ^*b ^*＂ b ^*The ＂ colour is lower than about 0.15 and be lower than about 0.075 in the absorbancy of 270nm; Or 3) the superoxide composition is lower than about 10ppm; Or 4) concentration of total organic impurity is lower than about 400ppm.

＂ b ^*The ＂ value be with spectrophotometry by CIE L ^*a ^*b ^*Measuring method ASTM D6290 defined " yellow blue observed value ".

Abbreviation " AMS " is meant accelerator mass-spectrometry.

Acronym " NMR " is meant nucleus magnetic resonance.

Term " color " and " color body (color bodies) " are meant the existence of visible color, and it can use and use the spectrocolorimeter of about 400-800nm wavelength to carry out quantificational expression by comparing with pure water in visible-range.Reaction conditions can have a significant impact the character that color produces.The example of correlated condition comprises the temperature of use, the amount of catalyzer and catalyzer.Although be not wishing to be bound by theory, the applicant believes that the look precursor comprises the impurity of trace, comprises ethylene linkage, acetal and other carbonyl compound, and superoxide, or the like.In these impurity at least some can detect by the method such as ultraviolet spectroscopy or superoxide volumetry.

" colour index " is meant the analysis to measure value of the absorption of electromagnetic radiation character of material or compound.

Can be used in personal care disclosed herein and the cosmetic compositions the biology origin 1, ammediol has at least a following feature: 1) ultraviolet absorptivity at 220nm is lower than about 0.200, be lower than about 0.075 and be lower than about 0.075 with ultraviolet absorptivity at the ultraviolet absorptivity of 275nm at 250nm; Or 2) L that has of composition ^*a ^*b ^*" b ^*" colour is lower than about 0.15 and be lower than about 0.075 in the absorbancy of 270nm; Or 3) the superoxide composition is lower than about 10ppm; Or 4) concentration of total organic impurity is lower than about 400ppm." b ^*" value be with spectrophotometry by CIE L ^*a ^*b ^*Measuring method ASTM D6290 defined " yellow blue observed value ".

1, the purity level of ammediol can characterize by many different methods.For example, the reservation level of measurement contaminative organic impurity is a kind of useful measure.1 of biology origin, the purity level that ammediol can have are the total organic pollutants that is lower than about 400ppm; Preferably be lower than about 300ppm; Most preferably be lower than about 150ppm.The total organic purity of term ppm is meant the ppm level of the carbon compound measured by vapor-phase chromatography (rather than 1, ammediol).

1 of biology origin, ammediol also can use many other parameters to characterize such as the ultraviolet absorptivity under different wave length.220nm, 240nm and 270nm wavelength are considered to can be used for measuring the purity level of composition.1 of biology origin, the purity level that ammediol can have be, wherein is lower than about 0.200 and be lower than about 0.075 and be lower than about 0.075 in the UV of 270nm absorbancy in the UV of 240nm absorbancy in the UV of 220nm absorbancy.

1 of biology origin, the b that ammediol can have ^*Colour (CIE L ^*a ^*b ^*) be lower than about 0.15.

1 of biology origin, the purity of ammediol composition also can be estimated by the method for significant measurement peroxide level.1 of biology origin, the concentration of the superoxide that ammediol can have is lower than about 10ppm.

It is believed that above-mentioned that be used for the biology origin and purified 1, the purity level parameter of ammediol (use with U.S. Patent application No.2005/0069997 in the same or similar method of those disclosed method) make this composition and prior art from originate from oil through 1 of chemical purification, 1 of ammediol preparation, the ammediol composition is had any different.

Fermentation

" biology generates " is meant by one or more living organism species or strain, comprises the organic compound that specific bacterium, yeast, fungi and other microbial strain generate.Using with the free burial ground for the destitute in this article of " biological generation " and " biology generation ".This organic compound is by forming from atmospheric carbon dioxide and by the carbon that green plants changes into sugar and starch.

" biologically-based " is meant that organic compound is synthetic from the organic constituent that biology generates.Considered that especially synthetic method disclosed herein can be effectively from removing 1, the alcohol that the biology outside the ammediol generates synthesizes other monoesters and diester; Described alcohol comprises ethylene glycol especially, glycol ether, triglycol, 1,2-propylene glycol, dipropylene glycol, tripropylene glycol, 2-methyl isophthalic acid, ammediol, neopentyl glycol and dihydroxyphenyl propane." bio-based " and " biogenetic derivation "; " the biology origin " and " biological origin " are used with the free burial ground for the destitute in this article.

" fermentation " used is meant the method that the monose metabolism is become other organic compound.Fermentation used herein specifically is meant the metabolism of the sugar of plant origin, and this sugar is made up of the carbon in atmosphere source.

1 of biology origin, ammediol can be based on using before the fermenting broth (" the fermentation origin ") that disclosed genetically engineered large intestine Ai Xi Salmonella (E.coli) generates in United States Patent (USP) 5,686,276 for example to obtain.Yet, can use the combination of other single creature body or organism to come to generate 1 with biology, ammediol, employing is carried out genetically engineered organism according to means known in the art and is carried out." fermentation " is meant such system, and it comes reaction between catalytic substrate and other nutritive substance to generate product by using biological catalyst.Biological catalyst can be full organism, isolating enzyme, or it has short active any combination of ester or composition.Can be used for generating with purifying biological and learn 1 of origin, the fermentation system of ammediol is open in laid-open U.S. Patents application No.2005/0069997 for example incorporated herein by reference.

1 of the biology origin used in this invention that generates by methods described herein, ammediol comprises the carbon that derives from atmosphere and merged by plant, and it is configured for producing the raw material of Bio-PDO.This shows that the Bio-PDO that uses in the present composition only contains renewable carbon, rather than fossil fuel carbon or petroleum base carbon.Therefore composition of the present invention is less to the influence of environment, because the propylene glycol that uses in the composition does not consume the fossil oil that is reducing, and discharges carbon turn back to atmosphere and re-use for plant when degraded.Therefore, the invention is characterized in and compare more natural with the analogous composition that comprises the petroleum base glycol and have lower environmental influence.

In addition, because the purity of the Bio-PDO that uses in the present composition is higher than 1,3 propylene glycol of chemosynthesis and other glycol, preferentially is used by its glycols such as propylene glycol commonly used and makes introducing can cause the risk of irritating impurity to be lowered.

Of the present invention this 1, ammediol can separate from fermenting broth and be introduced in personal care of the present invention and the cosmetic compositions, is undertaken by the known method of Application Areas those of ordinary skill.

Contain renewable base biodegradation type 1, the composition of ammediol

As mentioned above, can be with 1, ammediol is incorporated in numerous compositions as diol component.For example, 1, ammediol can be used as the whole of the part of diol component of personal care and cosmetic compositions or this diol component.

Other the renewable base or the glycols of biology origin contained in this paper, especially, such as ethylene glycol, glycol ether, triglycol, 1,2 propylene glycol, dipropylene glycol, tripropylene glycol, neopentyl glycol and dihydroxyphenyl propane or the like can be used in the biodegradable composition of the present invention.

Bio-PDO can use with the biodegradable composition in one or more commonly used any compositions combinations.Typical biodegradable end-use product and use therein typical composition have below been described, total preparation and embodiment, all these can be used on the present invention.

Personal care articles and makeup

Although the general custom in this area is to distinguish between personal care composition and cosmetic compositions,, in fact, normal conditions are that some personal care product is commonly called cosmetics, vice versa.Therefore, in order to simplify and to avoid confusion, based on the application's purpose, term " personal care " and " cosmetic " be although separately use, and be that it is intended to be considered to synonym and run through application and exchanged to make and be used for describing composition of the present invention.

In composition of the present invention, said composition is commonly called cosmetic compositions (also being called as the composition through skin liminent in the art) in the art, Bio-PDO can be used as gentle dose, solvent, neutralizing agent, sanitas, emulsifying agent, softener, softening agent, the handle effect agent, water activity reduces agent and/or spices toughener.Similarly, in composition of the present invention, said composition is commonly referred to as personal care composition in the art, and Bio-PDO is usually as tensio-active agent, and gentle dose, solvent, neutralizing agent, emulsifying agent, sanitas and/or spices toughener.

Some examples of typical personal care and cosmetic compositions include but not limited to lipstick, the bright lipstick of transparent height, liner, eye shadow cream, foundation cream, rouge, liquid kermes, facial pulvis, makeup, Correct, gel eye shadow cream, mascara, the bright lipstick of transparent height, the eye pen, liner, eye is made up remover, eyeliner, eye shadow cream, eye shadow cream washing lotion, the gel eye shadow cream, nail rumbling compound, lipstick nail rumbling compound, gel gloss remover, liquid kermes, rouge and facial pulvis, skin care compositions, skin cleansing compositions, skin clean rod, skin clean liquid, facial scrubs, face cream, the creme wetting Agent for Printing Inks, health washing composition, body wash; The footcare product is as foot creme, hand creme; Deodorizing and hidroschesis stylus, spin agent, aerosol, gelifying agent, creme, pump sprays, pulvis, odor mask, taste neutralizing agent, taste quencher, taste inhibitor; Bar-shaped dose of Gu Long, perfume compound is scraped palpus cream, scrapes palpus liquid, the creme trichogen, the washing lotion trichogen, wax is made up trichogen, by the facial mask that clay material is made, anti-aging product, anti-wrinkle product, anti-liparitosis product, nail remover, nail varnish, acne ointment, acne cleaning scrubbing agent; Mouth product such as toothpaste, gargarism, mouth wash shua, collutory, membrane agent, jelly; Shampoo, hair care product such as amendment, hair therapy creme, hair styling gel having, typing foaming agent, hair mousse, hair spray, hair shaping liquid blows and sends out style keeping liquid, hair rinse, creme and hair dye, bleaching hair cream, the hair fluffy powder, straighter, curly hair activator gel, fragrant gloss finishing composition (standardized product and auxiliary agent); SYNTHETIC OPTICAL WHITNER, sun care products such as sun rod (sun stick) and sun-screening agent, artificial tanned product, skin whitening product; The soap class, hand cleaner, the body and function scrubbing agent, the hand scrubbing agent, oil is bathed in the foam bath agent, convenient type hand sterilizing agent, hand disinfecting gel agent, germ resistance cleanser/hand, deodorant, anti-sweat agent, baby's washing lotion, the diaper rash creme, wet smear agent and baby bathe and use product and VITAMIN creme or the like.Above-mentioned enumerate be not intended to comprise all or restrictive with other any way, those skilled in the art are familiar with the type of all personal cares and cosmetics very much, it can use Bio-PDO diol component of the present invention to play a role effectively.

The amount that Bio-PDO can exist in above-mentioned personal care and cosmetic composition is that its field those of ordinary skill is known, weight based on total composition is generally about 12 weight % at most, although for example bathing with preparation, some compositions can comprise nearly 50% glycol, and some professional preparations such as VITAMIN creme can contain in addition higher percentage ratio up to 65% glycol with up to 85% deodorant.

Preferred BIO-PDO concentration range

Baby's product is used shampoo such as for example baby, soap class, wiping agent, washing lotion, finish, pulvis and creme, the concentration range of wherein preferred Bio-PDO be about 0.1 weight % to about 25 weight %, more preferably about 1 weight % is to about 10 weight %, even 1 to 5 weight % more preferably.

Bathe with preparation such as for example bathing oil, sheet bath salt and bath salt; Foam bath agent and bathing with capsule (bath capsules), wherein the concentration range of preferred Bio-PDO is about 0.001% to about 50%, more preferably from about 0.1% to about 10%, even more preferably from about 1% to about 5%.

Eye uses make-up preparation such as for example eyebrow pencil; Eyeliner; Eye shadow cream; The eye washing lotion; Eye is made up remover; And mascara, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 75%, more preferably 0.01% to about 25%, even more preferably 0.05% to about 5%.

Balm is such as for example Gulong perfume and toilet water; Perfume compound; Pulvis (toilet powder shui and talcum powder) (do not comprise and scrape palpus back talcum); And sachet, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 99%, more preferably from about 0.01% to about 10%, even more preferably from about 0.05% to about 5%.

Hair preparation (colourless) is such as for example hair conditioner; Hair spray (aerosol fixing agent); Straighter; Long-acting setting lotion; Rinsing (colourless); Shampoo (colourless); Tonic; Finishing composition and other hair modification auxiliary agent; With the curly hair suit, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 90%, and more preferably from about 0.01% to about 50%, even more preferably from about 0.05% to about 10%.

Hair colorant preparation such as for example hair dye (requiring warning statement and patch test); The hair toning agent; Hair Rinsing (colored); Hair shampoo (colored); Hair dyeing sprays (aerosol); The agent of hair colour bright; With the bleaching hair agent, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 50%, and more preferably from about 0.1% to about 25%, even more preferably from about 1% to about 10%.

Make-up preparation (non-eye is used) is such as for example kermes (all types of); Face powder; Foundation cream; Leg and health coating; Lipstick; Cosmetic matrix; Kermes; With the cosmetic fixing agent, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 99%, and more preferably from about 0.01% to about 25%, even more preferably from about 0.05% to about 10%.

Manicure preparations such as for example base coating and middle coating; The stratum corneum tenderizer; Moisten the first frost and wash first liquid; Nail weighting agent (nail extenders); Nail rumbling compound and nail varnish; And nail rumbling compound and enamel remover, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 50%, more preferably from about 0.1% to about 10%, even more preferably from about 1% to about 5%.

Dental health product such as for example dentifrice agent (aerosol, liquid, paste and pulvis); With mouthwash and oral cleansing lotion (liquid and sprays), the concentration range of wherein preferred Bio-PDO is about 0.001% to about 80%, more preferably from about 1% to about 5%.

Personal cleansing product is such as for example bath soap and washing composition; Deodorant (oxter is used); Antiperspirant; Irrigating; With women's health deodorant, the concentration range of wherein preferred Bio PDO is about 0.001% to about 99%, and more preferably from about 0.01% to about 50%, even more preferably from about 0.05% to about 10%.

Scrape the palpus preparation such as for example scraping palpus water, scrape after shave lotion; The beard softening agent; Men's talcum powder; Scrape the preceding washing lotion (all types of) of palpus; Scrape palpus cream (aerosol; Brushless and foaming formula); With scrape must soap (pie, bar-shaped etc.), wherein the concentration range of preferred Bio-PDO is about 0.001% to about 50%, more preferably from about 0.01% to about 10%, even more preferably from about 0.1% to about 5%.

Skin care formulation (creme, washing lotion, pulvis and sprays) such as for example sanitising agent (cold cream, Clean-washing lotion, liquid, and pad); Trichogen; Facial and neck is with preparation (do not comprise and scrape the palpus preparation); Body and hand are with preparation (do not comprise scrape must preparation); Foot-powder and sufficient sprays; Hormone product; Wetting Agent for Printing Inks; Late frost (night); Paste facial mask (mud facial mask); Skin-whitening agents; The skin freshener; With the level and smooth product of wrinkle (wrinkle remover), the concentration range of wherein preferred Bio-PDO is about 0.001% to about 50%, and more preferably from about 0.01% to about 15%, even more preferably from about 0.05% to about 5%.

Shine black preparation such as for example tanned gelifying agent, creme, liquid, pulvis, stylus and sprays; With indoor solarization black preparation; The concentration range of wherein preferred Bio-PDO is about 0.001% to about 25%, more preferably from about 1% to about 10%.

Sanitas (antiseptic-germicide/anti-mycotic agent/biocide) is such as for example parabens; Whitfield's ointment; Sorbic Acid; And phenoxyethyl alcohol, the concentration range of wherein preferred Bio-PDO is about 0.001% to about 100%, more preferably from about 95% to about 99.99%.

Be used for some final typical main preparation of using

Described generally in this section, preparation widely is used for that few personal care and beauty treatment are final uses, and is intended to provide the Bio-PDO overview that the variation in personal care and cosmetics is used.This section attempts to limit the present invention never in any form, and those skilled in the art can easily determine the suitable use of Bio-PDO in other known personal care and cosmetics as diol component.

Skin product

The more vectorial examples that are used for the skin products preparation comprise oil-in-water emulsion (O/W), Water in Oil emulsion (W/O), silicon water-in type (W/Si), oil emulsion, water-soluble emulsion, hydrogel emulsion and absorption base emulsion.

Typical O/W skin products preparation can comprise the tensio-active agent of 5%-35%, the emulsifying agent of 2%-15%, the Bio-PDO of 0.5%-15% and the water of 5%-60%.

Typical W/O skin products preparation can comprise the tensio-active agent of 45%-80%, the emulsifying agent of 0.5%-5%, the Bio-PDO of 0.5%-15% and the water of 20%-50%.

Typical O/W/O﹠amp; W/O/W skin products preparation can comprise the tensio-active agent of 18%-23%, the emulsifying agent of 3%-8%, the Bio-PDO of 0.5%-15% and the water of 60%-70%.

Typical W/Si and O/Si skin products preparation can comprise the tensio-active agent of 5-35%, the emulsifying agent of 2%-3%, the Bio-PDO of 0.5%-15%; Water with 60%-80%.

The hair product

The more vectorial examples that are used for the hair products preparation comprise oil-in-water emulsion (O/W), Water in Oil emulsion (W/O), silicon water-in type (W/Si), oil emulsion, water-soluble emulsion, hydrogel emulsion and absorption base emulsion or the like.

Typical shampoo and hair conditioner can comprise the tensio-active agent of 0.1-40%; The Bio-PDO of 0.1-10% and the water of 35-55%.

Coloured hair dye of typical liquid and cream can comprise the 70-80% dye-based, the Bio-PDO of 5-25%, 0.1-5% dyestuff intermediate and 0.1-10% developer.

Typical hair fluffy powder and straighter can comprise oil/wax of 30-60%, the water of 10-60%, the Bio-PDO of 1-10% and the caustic alkali of 0.1-5.0%.

Typical hair finishing composition can comprise membrane-forming agent/softening agent of 0.01-7%, the Bio-PDO of 0.01-90%, the propelling agent of 0-30% and the water of 10-90%.

The mouth product

Be used for mouthful more vectorial examples and comprise solid form with product formulation, such as paste, gel, creme and paste; And liquid form, such as lotion, purificant, gargle and sprays.

Typical toothpaste/gel/creme/paste can comprise the abrasive of 1-60/15-55/30-50%, the Bio-PDO of 1-80/1-50/1-30%; 0.01-30/0.1-15/0.5-5% thickening material, the tensio-active agent of 0.01-10/0.1-7.5/0.5-5% and 0.0001-2/0.001-1/0.01-0.5% sterilant.

Typical mouth wash shua/purificant/gargle/sprays can comprise the Bio-PDO of 0.1-55/0.5-40/1-25%, 0.1-55/0.5-40/1-25% alcohol, the thickening material of 0.01-10/0.1-7.5/0.5-5%, the tensio-active agent of 0.001-2/0.01-1/0.1-0.5% and the sterilant of 0.0001-5/0.001-2.5/0.01-1%.

Colour cosmetic

The more vectorial examples that are used for the color make-up preparation comprise, are used for foundation cream: O/W and W/O emulsion, anhydrous pulvis and stylus and oil-suspending agent and water suspending agent; Be used for mascara: O/W and W/O emulsion, and anhydrous solvent; Be used for eyeliner: aqueous and anhydrous; Be used for eye shadow cream: creme and pulvis; Be used for kermes: pulvis; Be used for lip gloss: (volatile) that light lipstick and unglazed lipstick (classical) and solvent are arranged.

The typical formulation that is used for O/W foundation cream product can comprise the emulsifying agent of 2%-15%, the Bio-PDO of 50%-75%, the pearling agent commonly used of 6%-12% pigment and 8%-12%.

The typical formulation that is used for W/O foundation cream product can comprise the emulsifying agent of 4%-6%, the Bio-PDO of 50%-75%, the pearling agent commonly used of 6%-12% pigment and 8%-12%.

The typical formulation that is used for anhydrous foundation cream product can comprise the Bio-PDO of 30-60%, the wax of 5-10%, the texturizing agent of the wetting agent of 0.5-1.0% and 30-60%.

The typical formulation that is used for O/W, W/O mascara product can comprise the emulsifying agent of 4%-10%, the thickening material of 2%-5%, the Bio-PDO of 40%-60% and the pigment of 6%-12%.

The typical formulation that is used for solvent base mascara product can comprise the Bio-PDO of 40-60%, the wax of 10-20%, the resin of 3-10%, the thickening material of 3-7%, the tinting material of 5-15% and the filler of 2-10%.

The typical formulation that is used for the eye shadow cream product can comprise the Bio-PDO of 35-55%, the thickening material of 1.5-3.5%, the wax of 7-12%, the softener of 3-8%, the tinting material of 5-20% and the filler of 5-20%.

The typical formulation that is used for the eyeliner product can comprise the water of 50-70%, the thickening material of 0.5-1.5%, the Bio-PDO of 4-12%, the tinting material of 10-20%, the alcohol of 5-10% and the dispersion agent of 3-8%.

The typical formulation that is used for classical lipstick product can comprise the Bio-PDO of 40-70%, the wax of 8-15%, the softening agent of 2-5%, the tinting material of 0.5-8%, the pearling agent commonly used of 1-6%, the filler of 1-15% and the sanitas of 0.1-0.5%.

The typical formulation that is used for volatility lipstick product can comprise the solvent of 25-60%, the Bio-PDO of 1-85%, the wax of 10-25%, the fixing agent of 1-10%, the filler of 1-15% and the tinting material of 1-15%.

Deodorant

The more vectorial examples that are used for the deodorant preparation comprise stylus well known in the art, aerosol and pump sprays or the like.

The typical formulation that is used for stylus type deodorant can comprise the emulsifying agent of 5-9%, the Bio-PDO of 1-30%, the finings of 5-80% and the reodorant of 0.1-2%.

The typical formulation that is used for the aerosol-type deodorant can comprise the emulsifying agent of 0.1-2%, the Bio-PDO of 30-50%, the finings of 5-80%, the reodorant of 0.1-2% and the propelling agent of 40-60%.

The typical formulation that is used for water alcohol (hydroalcoholic) pump aerosol deodorant can comprise the solvent of 30-40%, the Bio-PDO of 50-70%, the solubilizing agent of 0.1-5% and the reodorant of 0.1-5%.

The typical formulation that is used for phase transition temperature emulsion (PIT) emulsion pumping aerosol deodorant can comprise the tensio-active agent of 0.1-10%, the oil of 0.1-15%, the Bio-PDO of 65-85% and the reodorant of 0.1-5%.

Antiperspirant

The more vectorial examples that are used for the antiperspirant preparation comprise stylus well known in the art (suspension agent, gelifying agent and emulsion), bobbin type (emulsion O/W, W/O, W/Si, colourless water alcohol and suspension agent), and aerosol.

Typical stylus type antiperspirant preparation can comprise the gelifying agent of 1-30%, the Bio-PDO of 15-55%, the softener of 1-20%, the tensio-active agent of 0-20% and the antiperspirant of 15-55%.

Typical bobbin type antiperspirant preparation can comprise the tensio-active agent of 0-5%, the gelifying agent of 0.5-15%, the softener of 0-5%, the antiperspirant of 15-25% and the Bio-PDO of 60-85%.

Typical aerosol-type antiperspirant preparation can comprise the gelifying agent of 0.1-2%, the antiperspirant of 5-15%, the Bio-PDO of 5-20% and the propelling agent of 70-80%.

The composition inventory:

Beauty treatment of the present invention and personal care composition preferably comprise Bio-PDO and one or more and include but not limited to that the beauty treatment of following routine or dermatology are with additive or auxiliary agent: carrier; Promoting agent; Filler; Tensio-active agent; Thixotropic agent; Antioxidant; Sanitas; Dyestuff; Pigment; Perfume compound; Thickening material; VITAMIN; Hormone; Wetting Agent for Printing Inks, ultraviolet radiation absorption opalizer, ultraviolet scattering inorganic sunscreen, wetting agent, cationic, anionic, non-ionic type or amphiphilic polymers; With the hair dyeing active substance.

Conventional optional member is well known to a person skilled in the art.These conventional optional members include but not limited to: softener, oil absorber, biocide, tackiness agent, buffer reagent, denaturing agent, beauty treatment astringent matter, external application analgesic agent, membrane-forming agent, wetting Agent for Printing Inks, opalizer, perfume compound, pigment, skin are releived and healant, sanitas, propelling agent, the transdermal penetration toughener, solvent, suspending agent, emulsifying agent, sanitising agent, thickening material, solubilizing agent, wax, inorganic and organic sunscreen agent, the Sunless tanning agent, antioxidant and/or radical scavenger, sequestrant, anti-acne agent, anti-inflammatory agent, furfur agent/keratoderma stripper, organic alkyd, VITAMIN, natural extract and inorganic particulate such as silicon-dioxide and boron nitride.Be described in Harry ' s Cosmeticology, 7th Ed., Harry ﹠amp; Wilkinson (Hill Publishers, London 1982); Pharmaceutical DosageForms--Disperse Systems; Lieberman, Rieger ﹠amp; Banker, Vols.1 (1988) ﹠amp; 2 (1989); Marcel Decker, Inc.; The Chemistry and Manufacture of Cosmetics, 2nd.Ed., deNavarre (Van Nostrand 1962-1965); With The Handbook ofCosmetic Science and Technology, 1st Ed..Knowlton ﹠amp; The nonexcludability example of these materials among the Pearce (Elsevier1993) is also in the present invention available.

Yet, can understand, available promoting agent and other composition surpass a kind of beauty treatment and/or therapeutics benefit or play a role to surpass a kind of mode of action can providing in some cases herein.These components are particularly preferred other compositions, common save money of their use and formulation space (space).The example of these components comprises ethanol, Isopropyl myristate and the many component such as the silicon-dioxide that can be used as structure agent and sense organ conditioning agent.Therefore, the classification of this paper is for convenience's sake, is not to be intended to composition is restricted to that particularly point out or cited application.

Auxiliary agent is that cosmetic field is known and describe in many publications, referring to, Harry ' s Cosmeticology for example, 8 ^ThEdition, Martin Rieger compiles, Chemical Publishing, New York (2000).Usually the amount that is present in the auxiliary agent in above-mentioned beauty treatment and the personal care composition is well known in the artly (referring to for example owning together and the common title of submitting to is " PersonalCare Compositions ", to act on behalf of case and number be the U.S. Patent application of CL3428US PRV.

Carrier

Composition of the present invention preferably includes the acceptable carrier that is suitable for being locally applied to skin of safety and significant quantity, wherein can add basic material and make basic material and optional components to be delivered to skin under suitable concentration with other optional material.Therefore carrier can play thinner for any activeconstituents, dispersion agent, and the effect of solvent etc. has guaranteed that they can be applied to, and are uniformly distributed in selected target under suitable concentration.

The kind of the carrier that adopts among the present invention is according to the difference of desired composition product form and different.Can be used for topical compositions of the present invention can be made into such as multiple product form known in the art.These include but not limited to washing lotion, creme, gelifying agent, stylus, sprays, paste, paste and the agent (mousses) of evil spirit silk.These product forms can comprise the solution that includes but not limited to of several types, aerosol, emulsion, gel, the carrier of solid and liposome form.

Carrier preferably of the present invention comprise the acceptable hydrophilic thinner of dermatology such as, preferably renewable base biodegradation type 1, ammediol.

Promoting agent

The promoting agent that is used for the conditioning skin situation

Composition of the present invention randomly comprises the safety that is used for conditioning skin situation (conditioning skin situation) and the promoting agent of significant quantity with comprising prevention and therapeutic.Preventative conditioning skin situation comprises delay, minimizes and/or prevents visible and/or the tactile disconnected line (discontinuities) in the skin.Therapeutic conditioning skin situation comprises to be improved as reduces, and minimizes and/or eliminate this disconnected line.The conditioning skin situation also comprises improves skin appearance and/or sensation.Also comprise the conditioning aging sign, it can comprise prophylactically conditioning and/or one or more this signs of therapeutic ground conditioning, such as microgroove, and wrinkle, pore etc.

The composition that can be used for the conditioning skin situation is selected from vitamin b 3 compound, retinoids class, and combination.As described about wetting Agent for Printing Inks, above-claimed cpd can produce high-caliber tackiness when self uses, particularly when using with higher level.Yet but the particle that has been found that this sensation the application of the invention of being clamminess is offset.Composition of the present invention preferably includes about 0.1% to about 15%, and more preferably from about 0.3% to about 10%, even 1% to about 5% promoting agent more preferably from about.

As described herein, " vitamin b 3 compound " is meant the compound that has with following formula 1:

Wherein R is--CONH ₂(that is, niacinamide),--COOH (that is nicotinic acid) or--CH ₂OH (that is nicotinic alcohol); Its derivative; With any above-mentioned salt.One or more vitamins Bs ₃Compound or its salt or its mixture can be used on herein.In preferred version, vitamins B ₃Compound contains the salt form that is lower than this compound of about 50% usually.As used herein, " retinoids " comprises the natural and/or synthetic analogues of the compound of bioactive retinoid all vitamin A or have vitamin A in skin, and the geometrical isomer of these compounds and steric isomer.In addition, all skin condition materials of discussing in application WO 00/24372 should be considered to be applicable to the present invention.

The antibacterial activity agent

Be applicable to that any antibacterial activity agent that use the oxter can be used in the deodorant composition.The non-limitative example of antibacterium composition comprises and is selected from those following materials: triclosan, biocidal property quaternary ammonium compound be such as benzalkonium chloride, benzethonium chloride, cetylpyridinium chloride, chloride laurylpyridine, and methyl benzethonium chloride; Triclocarban; The zinc phenolsulfonate; Castor oil acid zinc; Triethyl citrate; Essential oil; And combination etc.Most preferred deodorant promoting agent is a triclosan.Perfume compound also can have antibacterial property.

Anti-inflammatory agent

The anti-inflammatory agent of safety and significant quantity can be added in the composition of the present invention, and preferably about 0.1% of composition to about 5%, and more preferably from about 0.1% to about 2%.Anti-inflammatory agent strengthens skin appearance benefits of the present invention, and for example this medicament promotes more uniform and acceptable skin color or color.The exact amount of the anti-inflammatory agent that composition uses will be according to the difference of used specific anti-inflammatory agent and different, because the effect difference of this medicament is bigger.The anti-inflammatory agent that can be used for this paper comprises steroide such as hydrocortisone; Non-carrier anti-inflammatory agent (NSAIDS) is such as Ibuprofen BP/EP; Panthenol and ether thereof and ester derivative such as panthenol ether, nitrilotriacetic panthenol ester; Pantothenic acid and salt thereof and ester derivative, particularly calcium pantothenate; Aloe, Hydagen B, the compound of wallantoin and Radix Glycyrrhizae (plant genus/glycyrrhiza glabra) family comprises glycyrrhetinic acid, Potenlini, and derivative are such as salt such as Monoammonium glycyrrhizinate and ester such as glycyrrhetinic acid stearyl.The preferred especially panthenol of this paper, pantothenic acid and ether thereof, ester or salt derivative and its mixture; Proper level is about 0.1 to about 5%, preferred about 0.5 to about 3%.Preferred especially panthenol.

Biocide

Conventional organic biocide also can be advantageously utilised in method of the present invention and the product.The introducing level is preferably 0.01% to 3% of their existing compositions (not comprising also simultaneous any volatile propellant), more preferably 0.03% to 0.5 weight %.Major part in the drug categories of using always in this area can be used.Preferred other organic biocide is a sterilant, for example quaternary ammonium compound such as cetyltrimethyl ammonium salt; Chlorhexidine and salt thereof; And DMC, the Glycerol dimer mono-laurate, glyceryl monolaurate, with as at " DeodorantIngredients ", " the Antiperspirants andDeodorants " of S.A.Makin and M.R.Lowry, similar substance described in the Ed.K.Laden (1999, Marcel Dekker, New York).The preferred other biocide that is used in the present composition is a poly hexamethylene biguanide salt; 2,4,4 '-trichlorine, 2 '-hydroxyl-diphenyl ether (triclosan); With 3,7,11-trimethyldodecane-2,6,10-three enols (farnesol).

Inorganic biocide also can be used in the composition of the present invention.This material plays the effect of anti-sweat promoting agent usually when existing with proper concn.Example is selected from usually: the astringent matter active salt comprises the salt of aluminium, zirconium and blended aluminium/zirconium comprising inorganic salt the salt that forms with organic anion, and mixture especially.Preferred astringent salts comprises the halogenide and the halide salts hydrate of aluminium, zirconium and aluminium/zirconium, such as the muriate hydrate.When comprising at that time, preferred is 0.5% to 60% of composition in conjunction with level, particularly 5% to 30% or 40%, and 5% or 10% to 30% or 35 weight % particularly.Particularly preferred aluminum halide salt hydrate is called active aluminum chloride hydrate, at EP6, describes among 739 (the Unilever PLC and NV).Aluminum chloride hydrous zirconium thing promoting agent also is preferred material, is called ZAG (zirconium-aluminium-glycine) mixture at present, for example at United States Patent (USP) 3,792, and those disclosed among 068 (the Procter and Gamble Co.).Also can use the zinc phenolsulfonate, preferably account for 3 weight % of composition at most.

Antioxidant/radical scavenger

Composition of the present invention can further comprise antioxidant/radical scavenger.Antioxidant/radical scavenger is used to provide antagonism can cause that cuticular peeling off increases or the protection of the uv-radiation that quality changes and protection at other environmental factors that can cause skin injury is provided especially.Suitable amount be composition about 0.1% to about 10%, more preferably from about 1% to about 5%.

Spendable antioxidant/radical scavenger such as xitix (vitamins C) and salt thereof, the acid ascorbyl ester of lipid acid, ascorbic acid derivates (for example magnesium ascorbyl phosphate), β-GAMMA-Carotene, tocopherol (vitamin-E), vitamin-E sorbic ester, vitamin e acetate, or other ester of vitamin-E, butylated Para Hydroxy Benzoic Acid and salt thereof, gallate and alkyl ester thereof be propyl gallate particularly, uric acid and salt thereof and alkyl ester, Sorbic Acid and salt thereof, amine is (as N, the N-diethyl hydroxylamine, aminoguanidine), sulfhydryl compound (for example gsh), dihydroxy fumaric acid and salt thereof, Vitamin P complex, Methionin, methionine(Met), proline(Pro), superoxide dismutase, silymarin, tea extract, Pericarpium Vitis viniferae/seed extract, melanochrome, and rosemary extract.Preferred anti-oxidants/radical scavenger is selected from: vitamin e acetate, other ester of vitamin-E sorbic ester and vitamin-E, more preferably vitamin e acetate.As described about wetting Agent for Printing Inks, above-mentioned compound obtains high-caliber tackiness when using with self, when particularly using under higher level.Yet but the particle that has been found that this sensation the application of the invention of being clamminess is offset.

Sequestrant

Comprising of sequestrant for providing at promoting excessively to peel off or the protection of the uv-radiation that the skin quality changes and the protection particularly advantageous that can cause the environmental factors of skin injury at other is provided.Suitable amount be composition about 0.01% to about 1%, more preferably from about 0.05% to about 0.5%.The exemplary sequestrant that can be used for this paper is at United States Patent (USP) 5,487, and open in 884, it is incorporated herein by reference.The preferred sequestrant that can be used in the composition of the present invention is ethylenediamine tetraacetic acid (EDTA) (EDTA), furil-dioxime, and derivative.

Tinting material and sanitas

The other component that also can be included is tinting material and sanitas, for example P-hydroxybenzoic acid C1-C3 alkyl ester.

Furfur agent/keratoderma stripper

The furfur agent of safety and significant quantity can be added in the composition of the present invention, be more preferably composition about 0.1% to about 10%, even more preferably from about 0.2% to about 5%, also preferred about 0.5% to about 4%.The furfur agent strengthens skin appearance benefits of the present invention.For example, the furfur agent tends to improve the quality (for example polishing) of skin.Various furfur agent are known in the art and are applicable to this paper, comprise organic alkyd such as Whitfield's ointment, oxyacetic acid, lactic acid, 5-MEXORYL SAM, Hydroxyoctanoic acid, Hydroxyoctanoic acid, and lanolin fatty acid.The furfur system of a kind of this paper of being applicable to comprises sulfhydryl compound and zwitterionics and description in WO 96/01101, and it is incorporated herein by reference.Another is applicable to that the furfur system of this paper comprises Whitfield's ointment and zwitterionics and description in WO 95/13048, and it is incorporated herein by reference.Preferred Whitfield's ointment.

Softener

Softener is a class material known in the art, gives skin with the effect of releiving.These are compositions of the flexibility, slipperiness and the pliable and tough outward appearance that help to keep skin.Also known softener reduces turning white of skin and/or improves aesthstic.The example of the chemical classes of findable suitable softener comprises:

(a) fat and oils, it is the glyceryl ester or the triglyceride level of the lipid acid generally found in animal vegetable tissue, comprises being hydrogenated to reduce and to eliminate those of degree of unsaturation.In addition, also comprise the glycerine of synthetic preparation and the ester of lipid acid.Lipid acid through separation and purifying can use glycerine to carry out esterification to obtain monoglyceride, triglyceride and triglyceride level.These are pure relatively fat, and it is only slightly had any different with fat and the oil found naturally.The general structure of general formula is represented by formula III:

R wherein ₁, R ₂And R ₃In each can be identical or different and have the carbon chain lengths (saturated or unsaturated) of 7-30.Object lesson comprises peanut oil, sesame oil, Lipoval A, Oleum Cocois, theobroma oil, Prunus amygdalus oil, Thistle oil, Semen Maydis oil, oleum gossypii seminis, Viscotrol C, hydrogenated castor oil, sweet oil, Jia Jiaba oil, haddock liver oil, plam oil, soybean oil, wheat germ oil, Toenol 1140 and wunflower seed oil;

(b) hydro carbons, it is one group of compound that only comprises carbon and hydrogen.They derive from petroleum chemicals.Their structural difference is very big and comprise aliphatic hydrocrbon, clicyclic hydrocarbon and virtue group hydrocarbon compound.Object lesson comprises paraffin, vaseline, Parleam, and mineral oil.

(c) ester class, it is the covalent compound that forms between acids and alcohols with chemical mode.The ester class can form from organic carboxyl acid class and any alcohol.Ester class as herein described derives from monocarboxylic acid class and alcohols (monohydroxy-alcohol or as the polyvalent alcohol of glycol).General formula is R ₄COOR ₅R ₄And R ₅Chain length can not wait from 7-30, and can be saturated or unsaturated, straight or branched.Object lesson comprises Isopropyl myristate, Wickenol 111, isopropyl stearate, the Unimac 5680 isopropyl ester, butyl stearate, octyl stearate, lauric acid hexyl ester, the stearic acid cetyl ester, Wickenol 116, Isodecyl oleate, Wickenol 117, lactic acid iso stearyl ester, phenylformic acid C _12-15Alkyl ester, tetradecyl polyoxyethylene (3) ether myristinate, oxysuccinic acid dioctyl ester, neopentyl glycol two heptanoates, neopentyl glycol dicaprylate, dibenzoic acid dipropylene glycol ester, lactic acid C _12-15Alcohol ester, capric acid isohexyl ester, capric acid isohexyl ester, two sad glycol ether esters, different octyl pelargonate, sad isodecyl ester, two different n-nonanoic acid glycol ether esters, the different nonyl ester of different n-nonanoic acid, Unimac 5680 iso stearyl base, docosoic acid docosyl ester, fumaric acid C _12-15Alkyl ester, dodecyl polyoxyethylene (2) ester benzoic ether, propylene glycol isocetyl polyoxyethylene (3) ether acetic acid ester, propylene glycol hexadecyl polyoxyethylene (3) ether acetic acid ester, the tetradecanoic acid stearyl, ricinoleate acid cetyl ester, tetradecanoic acid tetradecyl ester.

The ester class of the glycols preparation of use such as Bio-PDO or other biology origin also can be used in these compositions.The ester class of being produced comprises 1,3 propylene glycol of biology origin and all suitable compound monoesters and diester that the organic carboxyl acid class forms.Some concrete esters of being produced comprise propylene glycol SUNSOFT Q-182S and monostearate, a propylene glycol dilaurate and a lauric acid ester, Rikemal PO 200 and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and a nutmeg acid esters, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and their all mixtures.

(d) saturated and undersaturated lipid acid, it is to separate the carboxylic acid that obtains by animal or plant fat and profit.These general formula is R ₆COOH, wherein R ₆The carbon chain lengths of group is 7-30, is straight or branched.Object lesson comprises lauric acid, nutmeg acid, palmitinic acid, stearic acid, oleic acid, linolic acid He docosoic.

(e) saturated and undersaturated Fatty Alcohol(C12-C14 and C12-C18) (comprising Guerbet (guerbet) alcohol), general formula is R ₇OH, wherein R ₇Can be straight chain or side chain, and have the carbon chain lengths of 7-30.Object lesson comprises lauryl alcohol, myristyl alcohol, hexadecanol, different hexadecanol, stearyl alcohol, isooctadecanol, oleyl alcohol, Viscotrol C oleyl alcohol and erucyl alcohol;

(f) lanolin and derivative thereof, it is the compound esterification mixture of the high-molecular weight ester of (hydroxylated) lipid acid and fatty alcohol and alicyclic alcohol and sterol.General formula comprises R ₈CH ₂--(OCH ₂CH ₂) _NOH, R wherein ⁸Expression derives from the fatty group of lanolin, and n=5-75, perhaps comprises R9CO--(OCH ₂CH ₂) _nOH, wherein R ₉CO--represents to derive from the lipid acid of lanolin, and n=5-100.Object lesson comprises lanolin, lanolin oil, lanolin wax, Wool wax alcohol, lanolin fatty acid, lanoceric acid isopropyl esters, ethoxylation lanolin and Acetylated lanolin alcohols.

(g) oxyalkylated alcohol, wherein alcohol moiety is selected from and contains 2-18 carbon, the fatty alcohol of preferred 4-18 carbon, alkylene moiety is selected from oxyethane, and propylene oxide, and the number of the oxyalkylene units that has is 2-53, more especially 2-15.Object lesson comprises PPG-14 butyl ether and PPG-53 butyl ether.

(h) organosilicon and silane, the polysiloxane of linear organic replacement, it is the polymkeric substance of silicon/oxygen, formula is:

(1) (R ₁₀) ₃SiO (Si (R ₁₁) _2O) _xSi (R ₁₂) _-3, R wherein ₁₀, R ₁₁And R ₁₂Can be selected from phenyl and C1-C60 alkyl identical or different and independently of one another;

(2) HO (R ₁₄) ₂SiO (Si (R ₁₅) _2O) _xSi (R ₁₆) ₂OH, wherein R ₁₄, R ₁₅And R ₁₆Can be selected from phenyl and C1-C60 alkyl identical or different and independently of one another; Perhaps

(3) silicon compound of organic replacement, it is by formula R ₁₇Si (R ₁₈) ₂OSiR ₁₉₃Expression is not polymer-type, wherein R ₁₇, R ₁₈And R ₁₉Can be selected from phenyl and C1-C60 alkyl identical or different and independently of one another, its randomly one or two end group R base also comprise hydroxyl.Object lesson comprises polydimethylsiloxane, polydimethyl silanol docosoic ester, and C30-45 alkyl methyl siloxanes (methicone), octadecane oxygen base trimethyl silane, phenyl gathers trimethicone, and Stearyl dimethicone.

(i) mixture and the blend of above-mentioned two or more.

Interested especially softener comprises that (FINSOLV TN derives from Finetex Inc. to phenylformic acid C12-15 alkyl ester, Elmwood Park, N.J.) Isopropyl myristate; With two enanthic acid DOPCP.

Be attached to the mixture of softener in the composition of the present invention or softener or blend can illustrative ground with the 0.1-20% of composition total weight, preferred 1-15%, more preferably the level of 1-10% is introduced into.

Emulsifier/surfactant

The composition of this paper preferably contains emulsifying agent and/or tensio-active agent, is commonly used to help disperse and the suspension discontinuous phase at continuous aqueous phase.Attempt to be used for skin clean as fruit product and then also can use tensio-active agent.For the purpose of hereinafter convenient, emulsifying agent will be in term " tensio-active agent " use down, and therefore, " tensio-active agent " can be used to the tensio-active agent that refers to no matter be used for the emulsifying agent purpose or be used for other tensio-active agent purpose such as skin clean purpose.Known or conventional tensio-active agent can be used in the composition, and condition is that the basal component of selected reagent and composition is being compatible chemically and physically, and required feature is provided.Suitable tensio-active agent comprises the material of non-organic silicon origin, and composition thereof.All tensio-active agents of discussing in WO 00/24372 should be considered to be applicable among the present invention.

Composition of the present invention preferably includes about 0.05% to about 15% tensio-active agent or surfactant mixtures.The definite tensio-active agent or the selection of surfactant mixtures will be according to other component of the pH of composition and existence different and different.

Preferred surfactants is a nonionic surface active agent.The nonionic surface active agent that is used in this paper especially is that those can be to be that for example C8-30 is pure and the condensation product of sugar or starch polymer, i.e. glucosides for long-chain alcohol by broad interpretation.Other useful nonionic surface active agent comprises the condensation product (being oxidation of fatty acids alkene ester) of olefin oxide and lipid acid.The general formula of these materials is RCO (X) nOH, and wherein R is the C10-30 alkyl, and X is--OCH2CH2--(promptly deriving from ethylene glycol or ethylene oxide) or--OCH2CHCH3--(promptly deriving from propylene glycol or propylene oxide), and n is about 6 to about 200 integer.Other nonionic surface active agent is the condensation product (being oxidation of fatty acids alkene diester) of the lipid acid of olefin oxide and 2 moles.The general formula of these materials is RCO (X) nOOCR, and wherein R is the C10-30 alkyl, and X is--OCH2CH2-(promptly deriving from ethylene glycol or ethylene oxide) or--, and OCH2CHCH3-(promptly deriving from propylene glycol or propylene oxide) and n are about 6 to about 100 integers.Even further suitable examples comprises mixture, 16/octadecyl glucosides of 16/stearyl alcohol, as can be available under the trade(brand)name Montanov 68 of the Seppic of Cognis UK Ltd. and EmulgadePL68/50 those.Suitable 16/octadecyl glucosides examples of substances of not adding Fatty Alcohol(C12-C14 and C12-C18) is Tego (RTM) Care CG90, available from GoldschmidtGmbH.Other nonionic surface active agent is a fat alkane alcohol amide, and general formula is R-CO-N-(CH2CH2OH) n, and wherein R is a hydrocarbon chain, and n is 1 or 2 integer.The most normally used is coconut oleoyl amine DEA (diglycollic amide) and coconut monoethanolamide MEA (glycollic amide).

The spendable hydrophilic surfactant active of this paper alternately or additionally comprises such as in multiple cationic, anionic known in the art, amphoteric ion type and the amphoterics any.Referring to, the Detergents and Emulsifiers of McCutcheon for example, NorthAmerican Edition (1986), open by Allured Publishing Corporation; Licensed to the United States Patent (USP) 5,011,681 of Ciotti etc. on April 30th, 1991; License to the United States Patent (USP) 4,421,769 of Dixon etc. December 20 nineteen eighty-three; With the United States Patent (USP) 3,755,560 that licensed to Dickert etc. on August 28th, 1973.Multiple aniorfic surfactant also can be used on herein, referring to, for example licensed to the United States Patent (USP) 3,929,678 of Laughlin etc. on December 30th, 1975.

Multiple anion surfactant also can be used on herein.Referring to, for example the United States Patent (USP) 3,929,678 of Laughlin etc. was authorized on December 30th, 1975.Exemplary anion surfactant comprises alkyloyl isethionate (as C12-C30); alkyl and alkyl ether sulphate and salt thereof; alkyl and alkyl ether phosphate and salt thereof; alkyl methyl taurine salt (as C12-C30); soap class (for example an alkali metal salt, for example salt of sodium or potassium) with lipid acid.

Amphoteric and amphoteric ionic surfactant also can be used for herein.Can be used on the amphoteric in the composition of the present invention and the example of amphoteric ionic surfactant is that those extensively are described as being the derivative of aliphatic secondary amine and tertiary amine, wherein aliphatic radical can be a straight or branched, and wherein one of aliphatic substituting group comprises about 8 and comprises anionic water solubilizing group to about 22 carbon atoms (preferred C8-C18) and an aliphatic substituting group, carboxyl for example, sulfonate radical, sulfate radical, phosphate radical, or phosphonate radical.Example is alkyl imino acetate and iminodiacetic alkanoate and amino-alkane hydrochlorate, tetrahydroglyoxaline and ammonium derivative.Amphoteric that other is suitable and amphoteric ionic surfactant are to be selected from following those: trimethyl-glycine, and sultaine, the alkyloyl sarcosinate of hydroxyl sulfo betaine and non-side chain and side chain, and composition thereof.

Perfume compound

Perfume compound also is the required other component in the present composition.Suitable material comprises conventional spices such as perfume oil, and comprises so-called deodorizing essence, described in disclosing with other as EP 545,556.These materials described later also can be regarded other organic biocide as.The level of introducing is maximum 4 weight %, particularly 0.1% to 2 weight % of composition preferably, most preferably are 0.7% to 1.7 weight %.Synergy can be present between basal component of the present invention and some fragrance components, and the result who obtains is persistent smell control.

Perfume compound can be selected from the acceptable perfume compound of any cosmetology or be applicable to the perfume compound of topical application.Perfume compound should be suitable for sheltering foul smell, as the foul smell relevant with people's sweat.As exemplary and nonrestrictive example, these perfume compound comprise those that comprise middle note and/or high note volatile constituent, for example be selected from following: allyl group amyl group oxyacetate, dihydromyrcenol, aldehyde C-12MNA, decyl alcohol, isobornyl acetate, LILAL.RTM., tricyclodecenyl acetate, benzyl salicylate etc., and combination.

Wetting Agent for Printing Inks

Wetting Agent for Printing Inks also is the required other component in the present composition, and it helps to increase humidification character.Exemplary wetting Agent for Printing Inks can include but not limited to polyvalent alcohol (promptly 1,2-propylene glycol, 1,3 and 1,4-butyleneglycol, 2-methyl isophthalic acid, ammediol, glycerine, and hexylene glycol) and polyvalent alcohol (being polypropylene glycol, polyoxyethylene glycol), and composition thereof.

Propelling agent

When the present invention relates to the use of aerosol combination, volatile propellant is the main component of this composition.The introducing level of volatile propellant is 30 to 99 weight parts normally, particularly 50 to 95 weight parts.Non-chlorating volatile propellant is preferred, particularly boiling point be lower than 10 ℃ especially boiling point be lower than 0 ℃ liquefied hydrocarbon and halogenated hydrocarbon gas (particularly hydrofluoric ether as 1,1-C2H4F2 C2H4F2 and/or 1-three fluoro-2-fluoroethanes).The preferred especially hydrocarbon gas that uses liquefaction, particularly the C3-C6 hydro carbons comprises propane, different propane, butane, Trimethylmethane, pentane, and two or more mixture of iso-pentane and its.Preferred propelling agent is a Trimethylmethane, Trimethylmethane/different propane, Trimethylmethane/propane, and the mixture of different propane, Trimethylmethane and butane.

Propelling agent in other can be encompassed in comprises alkyl ether such as dme, or non-active gas such as air, nitrogen or the carbonic acid gas of compression.

The sense organ conditioning agent

Some sense organ conditioning agent is a further required component in the present composition.This material preferably is used with the level of maximum 20 weight % of composition.Softener, wetting Agent for Printing Inks, ethereal oil, fixed oil oil and the fine-particle solid of giving oilness all is the sense organ conditioning agent of suitable classification.This examples of substances comprises the cyclohexyl methyl siloxanes, polydimethylsiloxane, polydimethyl silanol, Isopropyl myristate, Wickenol 111, talcum, silica particle (as Aerosil 200), polyethylene (for example Acumist B18), polysaccharide, W-Gum, phenylformic acid C12-C15 alcohol ester, PPG-3 myristyl ether, Standamul G, the C7-C14 isoparaffin, Wickenol 116, lauric acid Coronex, PPG 14 butyl ethers, glycerine, Parleam, poly decene, titanium dioxide, phenyl gathers trimethicone, Octyl adipate, and hexamethyldisiloxane.

Thickening material (comprising viscosifying agent and jelling agent)

Composition of the present invention also can preferably include thickening material, more preferably from about 0.1% to about 10%, even more preferably from about 0.1% to about 9% and 0.25% to about 8% thickening material most preferably from about.

Preferred composition of the present invention comprises and is selected from following thickening material: carboxylic acid polyalcohol, and crosslinked polyacrylic ester, polyacrylamide, xanthan gum, and composition thereof, more preferably be selected from polyacrylamide polymers, xanthan gum and composition thereof.Preferred polyacrylamide be pre-dispersed in not with water miscible solvent such as mineral wet goods in, it comprises tensio-active agent (HLB is about 7 to about 10), it helps lend some impetus to the water dispersible of polyacrylamide.What most preferably be used for this paper is non-ionic polyalcohol, and the CTFA name is called: polyacrylamide and isoparaffin and dodecyl polyoxyethylene (7) ether, available from Seppic Corporation, commodity are called Sepigel 305.Also spendable is vinylformic acid/ethyl acrylate copolymer and carboxy vinyl polymer, is sold by B.F.Goodrich Company, and trade mark is the carbopol resin.Suitable carbopol resin is described in WO98/22085.All thickening materials of discussing in application WO 00/24372 should be considered to be applicable to the present invention.

In addition, any jelling agent that uses in soap class or the deodorant field can be with in the present invention.These jelling agents normally chain length are the metal-salt of one or more lipid acid of 12-22 carbon atom.Saturated or the undersaturated C12-C22 lipid acid that the fatty acid part of jelling agent is preferably pure relatively comprises nutmeg acid, palmitinic acid, stearic acid, oleic acid, linolic acid, linolenic acid, and combination.Preferred jelling agent comprises sodium stearate, potassium stearate, and Sodium pentadecanecarboxylate, potassium myristate, Sodium tetradecanoate, and combination etc.

The structure agent

The structure agent is also the other component of the present composition, and it is needs highly in some product form.When using the structure agent, its content is 1% to 30 weight % of composition preferably.

Suitable structure agent comprises Mierocrystalline cellulose multiviscosisty agent such as hydroxypropylcellulose and Natvosol, and Sorbitol dibenzal.Other suitable structure agent comprises sodium stearate, stearyl alcohol, hexadecanol, hydrogenated castor oil, synthetic wax; paraffin, oxystearic acid, dibutyl lauroyl glutamine, alkyl silicone waxes; polyquaternium-18 wilkinite, polyquaternium-18 hectorite, silicon-dioxide, and propylene carbonate.

The organosilicon based component

Composition of the present invention preferably also comprises organic silica-based composition.Preferred example is discussed below:

I) organic silica-based softener.Organopolysiloxane oil can be used as the composition with softener benefit in composition of the present invention.Suitable organopolysiloxane oil comprises volatile organosilicon, nonvolatile organosilicon or volatile and nonvolatile organosilyl mixture.The term that uses under this paper background " nonvolatile " is meant some such organosilicons, and it is liquid under envrionment conditions and has and be equal to or greater than about 100 ℃ flash-point (under a normal atmosphere).The term that uses under this paper background " volatile " is meant some such organosilicons, and it has and is lower than 100 ℃ flash-point.Suitable organopolysiloxane can be selected from various have volatility and the bigger organosilicons of viscosity span.Nonvolatile polysiloxane is preferred.Suitable organosilicon is open in the United States Patent (USP) 5,069,897 of authorizing on December 3rd, 1991, and it incorporates this paper into as a reference in full.

The organopolysiloxane that this paper preferably uses is selected from poly-alkylsiloxane, the polydimethylsiloxane that alkyl replaces, and the polydimethyl silanol, the polyoxyethylene alkyl aryl radical siloxane, and composition thereof.What this paper more preferably used is poly-alkylsiloxane and cyclohexyl methyl siloxanes.Preferred polydimethylsiloxane in poly-alkylsiloxane is for example available from the DC200 of Dow Corning with available from the SF96 of GE Silicone.

Ii) organic silica-based emulsifying agent.Preferred emulsion of the present invention comprises and contains organosilyl emulsifying agent or tensio-active agent.This paper can use multiple organosilyl surfactant.These organosilyl surfactants normally pass through organically-modified organopolysiloxane, and it also is called organic silicon surfactant by those skilled in the art.Useful organosilyl surfactant comprises dimethicone copolyol.These materials are polydimethylsiloxanes, thereby it comprises polyether lateral chain such as polyethylene oxide chain through modification, polyoxytrimethylene chain, the mixture of these chains and comprise ethylene oxide and the polyether chain of the part of propylene oxide origin.Other example comprises alkyl-modified dimethicone copolyol,, contains the compound that C2-C30 hangs side chain that is.Other useful dimethicone copolyol comprises the material with different cationic, anionics, amphoteric and amphoteric ion type suspended portion.

Skin lightening agent

Composition of the present invention also can comprise skin lightening agent.When using skin lightening agent, composition preferably includes about 0.1% to about 10%, and more preferably from about 0.2% to about 5%, and preferred about 0.5% to about 2% skin lightening agent.Suitable skin lightening agent comprise known in the art those, comprise kojic acid, ursin, xitix and derivative thereof are as Ascorbic acid 2-phosphate magnesium.The further skin lightening agent that is applicable to this paper also is included in those described in WO 95/34280 and the WO 95/23780, and is incorporated herein by reference separately.

Opalizer

Inorganic sunscreen

Inorganic sunscreen is used titanium dioxide and zinc oxide.They mainly work by reflection and scatters ultraviolet.Organic opalizer comprises the composition that is widely used, as methoxy cinnamic acid octyl group ester (OMC), and 4 methyl benzylidene camphor (4-MBC), avobenzone, oxybenzone, and homosalate.They mainly work by absorbing ultraviolet ray and it being dissipated as heat.

Formulator is united use to reach synergy with inorganic and organic opalizer usually.In fact, be exactly how farthest to realize very high SPF (solar protection coefficient) rank.SPF is how the opalizer in the preparation limits measuring under the UV-B ray that skin is exposed to skin ambustion effectively.This numeral is high more, and then to give the antagonism sun protectiveness of burning just high more for opalizer.

As described below is the opalizer medicament production inventory of the OTC (over-the-counter) human of process approval, unites when using when it to be applicable among the present invention that said preparation must be followed the guide (21 CFR 352Sec.352.10) of FDA.

Promoting agent Limit, weight %

A. benzaminic acid (PABA) 15

B. avobenzone 3

C. cinoxate 3

D. dioxybenzone 3

E. ensulizole 4

F. homosalate 15

G. Sunburn preventive No. 25

H. meradimate 5

i.Octinoxate 7.5

J. octisalate 5

K. Octocrilene 10

L. methoxy cinnamic acid octyl group ester 7.5

M. Whitfield's ointment octyl group ester 5

N. hydroxyl methoxy ketone 6

O. Padimate O 8

P. Phenylbenzimidazolesulfonic acid 4

Q. Sulisobenzone 10

R. titanium dioxide 25

S. Trolamine salicylate 12

T. zinc oxide 25

Except that the organic sunscreen agent, composition of the present invention can comprise inorganic physics sun-screening agent in addition.The non-limitative example of suitable physical sunscreen agent is described in CTFA InternationalCosmetic Ingredient Dictionary, 6th Edition, 1995, pp.1026-28 and 1103, Sayre, R.M. etc., ＂ Physical Sunscreens ＂, J.Soc.Cosmet.Chem., vol 41, no 2, among the pp.103-109 (1990).Preferred inorganic physics sun-screening agent is zinc oxide and titanium dioxide, and composition thereof.

When using, the content of physical sunscreen agent is to make that composition of the present invention is transparent (that is, non-turn white) on skin, preferably is less than or equal to about 5%.When using titanium dioxide, it can have anatase octahedrite, rutile or amorphous structure.Physical sunscreen agent particle, for example titanium dioxide and zinc oxide can be coated with or not therewith coating with many materials, and described material includes but not limited to amino acid, aluminum compound such as aluminum oxide, aluminum stearate, Aluminum trilaurate or the like; Carboxylic-acid and salt thereof are as stearic acid and salt thereof; Phosphatide such as Yelkin TTS; Silicoorganic compound; Inorganic silicon compound such as silicon-dioxide and silicate; And composition thereof.Preferred titanium dioxide is commercially available, derives from Tayca (Japan) and by Tri-K Industries (Emerson, the MT micro-ion series of N.J.) selling (as, MT 100SAS).

Composition of the present invention preferably includes about 0.1wt% to about 10wt%, and more preferably from about 0.1wt% is to about 4wt%, and most preferably from about 0.5wt% is to the inorganic sunscreen of about 2.5wt%.

The ester class

The ester class can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of 3 propylene glycol preparation comprises all suitable compound (conjugate) monoesters and diester class.Special some esters that generate comprise propylene glycol SUNSOFT Q-182S and monostearate, a propylene glycol dilaurate and a lauric acid ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Natural component

The composition any natural or natural origin similar to mentioned component can be used in these compositions on forming or on function.

Viscosity

It is about 1,000 that the apparent viscosity that preferred compositions has arrives for about water sample is thin, 000mPa.s (centipoise).For example, the apparent viscosity that preferred washing lotion has is about 500 to about 25,000mPa.s; The apparent viscosity that preferred creme has is about 20,000 to about 250,000mPa.s.

Some comprise personal care composition such as colourless shampoo and the no vitriol shampoo of Bio-PDO, may need approximately than comprising for example propylene glycol of comparable glycols, butyleneglycol, 2-methyl isophthalic acid, other composition of 3 propylene glycol etc. are lower than 30% salt to regulate its viscosity.At other composition health washing composition for example, Bio-PDO can help to keep and set up viscosity.

pH

It is 9.5 or lower that composition of the present invention is configured to the pH that has usually, and the pH that has usually is about 4.5 to about 9, more preferably from about 5 to about 8.5.Some compositions particularly comprises other promoting agent such as salicylic composition, requires lower pH, thereby makes other promoting agent fully effective.It is about 2.5 to about 5 that these compositions are configured to the pH that has usually, more preferably from about 2.7 to about 4.

Skin irritation and sensitization

In about 100 experimenters' human skin paster test, 5,25 and 50% PDO does not cause that any showing stimulates or the skin reaction of sensitization.Second individual's skin paster test, the PDO of 25,50 and 75% concentration under pH7, or 75% PDO under pH4 and 9 do not produce any clinically significant skin irritation or sensitivity response.Based on these research, PDO is not considered to skin irritant or sensitizing agent in the people.In the test of the second individual's skin paster, also under 25,50 and 75% (pH 7), tested propylene glycol (1,2-propylene glycol or PG), and the PG of all three kinds of concentration is the paster trial stimulus thing and the accumulation stimulator of human skin.

Sanitising agent

In cleanser compositions, diol component is emulsifying agent and/or phase stabilizer normally, hydrotropic solvent/solvent or enzyme stabilizers.

The form of composition

Composition of the present invention can be taked many physical form, comprises particle, gel, sheet, rod and liquid form.These compositions comprise so-called spissated granular detergent composition, and it is suitable for being added in the washing machine by means of the distribution device that is placed in the machine roll of loading staining fabric.

Exemplary sanitising agent comprises but is not limited to hand with washing the dish sanitising agent; Machine comprises the solid block sanitising agent with washing the dish sanitising agent; The solid laundry sanitising agent, the liquid laundry sanitising agent comprises light-duty liquid sanitising agent (LDLD) and heavy-filth liquid sanitising agent (HDLD); Organic or inorganic clothes softening agent, laundry soap slab and carwash sanitising agent or the like.

Cleanser compositions of the present invention can comprise any known in the art or form of using, such as powder, and liquid, particle, gel, stick with paste sheet, pouch, bar, with separate twin containers, sprays, or foam cleaner and other homogeneity or heterogenetic daily cleaning agent product form.This product can manual mode uses or coating, and/or can usual amounts or freely changes the consumption use, perhaps by the automatic loading equipment use, perhaps can be used on electronic product for example in the washing machine.These products can have various pH, and as 2 to 12 or higher, and the preparations that can add per 100 grams are tens gram equivalents NaOH.These products can have various preliminary basicity.Comprise high bubble and low foaming cleaner.

Light-duty liquid sanitising agent (LDLD) composition comprises: contain be useful on improve surface-active magnesium ion and/or organic diamine and/or multiple suds-stabilizing agent and/or suds booster for example amine oxide and/or tensio-active agent and relafant the skin feel activator and/or comprise the enzyme type of proteolytic enzyme and/or the LDLD composition of sterilant.

Heavy-filth liquid sanitising agent (HDLD) composition comprises the kind of liquid of all so-called " structure " or heterogenetic and " non-structure " or homogeneous, and generally comprise water-based or nonaqueous SYNTHETIC OPTICAL WHITNER, and/or enzyme, or do not comprise SYNTHETIC OPTICAL WHITNER and/or enzyme.

Heavy dirty particle sanitising agent (HDGD) composition comprises so-called " compacting " or " caking ", or non-spray-dired form and so-called " flocculation " or spray-dired form.These compositions comprise phosphoric acid salt addition type and the non-addition type of phosphoric acid salt.The type that this sanitising agent can comprise comprises that more generally aniorfic surfactant is as substrate, it perhaps can be so-called " high nonionic surface active agent " type, be included in the general nonionic surface active agent that keeps on the absorption agent, for example be within zeolite or other porous inorganic salt or on the surface.

Softening agent (STW) composition comprises the particle or the liquid product of various types, and it is softened by laundering, and can usually comprise organically (for example quaternary amine (guaternary)) or inorganic (for example clay) softening agent.

Soap slab (BS ﹠amp; HW) composition comprises that laundry soap slab and comprising contains synthetic detergent and as the type of the soap of substrate with comprise the type of softening agent.This composition comprises the composition of producing by general soap production technology such as press molding technology, or is not general technology such as casting and the composition that tensio-active agent is absorbed the technology production that enters porous support.The hand that also comprises other is with washing sanitising agent.

Fabric softener (FS) comprises conventional liquid and concentrated liquid type and the kind that adds or supported by substrate by moisture eliminator.Other fabric softener comprises those of solid form.

The sanitising agent (SPC) that comprises the special purpose of following product also is the sanitising agent of being considered that is used for purpose of the present invention: home-use dried cleaning form; the prefinished products of laundry bleaching agent; the prefinished products that is used for the fabric protection; the senior clean fabric agent of liquid type; particularly high bubble product; liquid bleach; comprise chlorine type and oxygen bleaching formulation; sterilizing agent; cleaning additive; the pre-treatment type comprises and for example bleaches additive and " scrubbing rod " or special alveolitoid sanitising agent and the anti-fade treatment by daylight of rising.

The special household cleaning agent (SHC) that comprises following product also is the sanitising agent that is considered for the object of the invention: multifunctional cleaning agent is creme, gelifying agent, liquid form, and floor cleaner; The multi-usage sprays, as be used for the sanitising agent on cleaning glass surface; Wiping agent comprises the multi-usage wiping agent, glass cleaner, floor cleaner and sterilizing agent; Bathroom, shower room and lavatory sanitising agent; Remove mould sanitising agent and SYNTHETIC OPTICAL WHITNER.

Renewable base biodegradation type 1 of the present invention, the content of ammediol in above-mentioned cleanser compositions are that the those of ordinary skill in suitable field is known, are generally the highest about 25 weight % of total composition weight.

Typical non-special sanitising agent prescription can include but not limited to the renewable base biodegradation type 1 of following components in weight percentage: 0.01-50.0%, ammediol, the lipid acid of 5.0-40.0% and the carboxylicesters of low carbon number, or other tensio-active agent or the surfactant mixture of monoesters and/or di-esters (tensio-active agent) and 1.0 to 70.0%.In addition, can comprise the following component of maximum 5.0 weight %: bubble suds-stabilizing agent/suds booster (preferred 1-10%), pH damping fluid (preferred 2-8%), enzyme, sequestrant, perfume compound, washing assistant, antioxidant, auxiliary agent, washing agent.

The basic recipe embodiment that is used for light dirt liquid detergent (LDLD) product can comprise the tensio-active agent of 0.1-70%, the Bio-PDO of 0.1-20% and reach 100% water in right amount.LDLD is used in the wash up application usually, comprises automatic washing, hand washing, dishwasher rinsing, plastics dirt remover, basin jar sanitising agent, pretreating agent and water-softening chemicals.

The basic recipe embodiment that is used for heavy duty liquid laundry detergent (LDLD) product can comprise the tensio-active agent of 0.1-50%, the Bio-PDO of 0.1-20% and reach 100% water in right amount.HDLD is generally used for comprising laundry product in the laundry applications that it contains SYNTHETIC OPTICAL WHITNER, hypoallergenic medicament, the material of no phosphoric acid salt, the dry-cleaning material, fabric conditioner, fabric intensifier, fabric finishing agent, the textile sizing agent, fabric softener, pre-wash agent, scale remover and starch.

The basic recipe embodiment that is used for washing composition (LADD) product of liquid automatic dish washer can comprise the washing assistant of 0.1-30%, caustic alkali/SYNTHETIC OPTICAL WHITNER of 0.1-17%, the Bio-PDO of 0.1-20% and reach 100% water in right amount.Application comprises washes dish, the pre-dirt remover of liquid, rinse aids, no phosphate material, the material of no hypochlorite and enzyme.

The basic recipe embodiment that is used for special household cleaning agent (SHC) can comprise the tensio-active agent of 0.1-70%, the Bio-PDO of 0.1-50% and reach 100% water in right amount.Specialized application comprises the multipurpose purifying agent, is creme, gelifying agent, liquid form, and floor cleaner; The multi-usage sprays is as being used for the surface of cleaning glass; Wiping agent comprises the multi-usage wiping agent, glass cleaner, floor cleaner and sterilizing agent; Bathroom, shower room and detergent for toilet; Remove mould sanitising agent and SYNTHETIC OPTICAL WHITNER.

Detergent components

Cleanser compositions of the present invention can comprise any general auxiliary component below one or more of 0.01 to 99 weight %: washing assistant, tensio-active agent, enzyme; polymkeric substance, SYNTHETIC OPTICAL WHITNER, bleaching surfactant; catalyst component, various active component or special-purpose component such as polymer dispersant, dyestuff particulate (color speckle); silver protecting agent, anti-foggant and/or sanitas, dyestuff; filler, sterilizing agent, alkaline agent; hydrotropic solvent; antioxidant, enzyme stabilizers helps perfume compound (pro-perfume); perfume compound; softening agent, carrier, processing aid; pigment and liquid preparation solvent.

Usually, detergent components is comprised that the composition that is used for only comprising minimum necessary component is converted into the composition that can be used for the required cleaning purpose.Those skilled in the art can determine easily which kind of detergent components is that required cleaning is used needed.

The definite character of the component that these are other, its introducing level, will be according to the characteristic of the physical form of composition and stand-by clean operation different and different.

Detersive surfactant

Cleanser compositions of the present invention can comprise any known detersive surfactant, and this tensio-active agent is known for those skilled in the art.Specifically, detersive surfactant of the present invention can comprise anionic, and non-ionic type, amphoteric ion type or amphoteric tensio-active agent, trimethyl-glycine and diamines are the known tensio-active agents that can be used for cleaning applications.

In all detersive surfactant, the chain length of hydrophobic part is typically C8 usually to C20, and particularly in the situation of cleaning with cold water, chain length often is preferably C8 to C18.

Clean-enzyme

Cleanser compositions of the present invention can use enzyme to be used for various purposes, for example removes protein-based dirt, carbohydrate-based dirt or triglyceride level base dirt from substrate, and the transfer and the fabric of the dyestuff that takes off during the inhibition fabric cleans restore." Clean-enzyme " used herein be meant all washing, decontamination, and other clean the enzyme that has advantageous effects in using.

Washing assistant

Lotion-aid combination preferably is controlled at mineral substance those of hardness of Ca and/or Mg particularly in the bath water, has therefore simplified to remove from the surface and/or disperse granular dirt, the effect of also optionally giving alkaline agent and/or buffer reagent simultaneously.In granular or Powdered sanitising agent, washing assistant can be used as the absorption agent that is used for tensio-active agent and works.Perhaps, some compositions can be formulated into complete water miscible form, and it can be organic or inorganic, decides according to predetermined the application.

Suitable silicate-like builder comprises water-soluble type and hydration solid type, and the kind that comprises other, such as kind with chain, layer or three-dimensional arrangement, amorphous solid silicate, and be prepared as and make them especially as those of the liquid cleaner that makes up.

The aluminosilicate washing assistant, so-called zeolite can be used in the granular detergent especially, but can be merged in paste and the gelifying agent.But aluminosilicate crystalline or unbodied, perhaps natural or synthetic.

In order to be easy to be controlled at the mineral substance hardness of Ca and/or Mg particularly in the bath water, perhaps for the ease of from the surface removal granular solids, composition of the present invention can optionally comprise detergent builders, is used for replacing or is additional to above silicate and aluminosilicate.Washing assistant can number of mechanisms work, and makes the mixture that forms solubility or insolubility with mineral ion by the bigger mineral ion of ion exchange or the surface adhesion by its surface material more to be cleaned is provided with mineral ion.The amount of washing assistant can be according to the final application of composition with physical appearance and different widely.

Herein, suitable washing assistant can be selected from: phosphoric acid salt and polyphosphate, particularly sodium salt, carbonate, supercarbonate, yellow soda ash, organic one, two, three and the acid of tetracarboxylic acid hydrochlorate, particularly water miscible nonsurfactant, sodium, potassium, or the carboxylate of alkanol ammonium form and comprise oligopolymer or the aliphatics of water miscible low-molecular(weight)polymer carboxylate and aromatics type.For example, purpose for the pH buffer reagent, these washing assistants can be supplemented with all fillers or carrier (they are comprising that borate or sulfuric acid are important in the cleanser compositions technology of sodium sulfate particularly) and other stabilized surfactant and/or washing assistant.

In the present invention, can use the washing assistant mixture, usually, the washing assistant mixture randomly comprises the washing assistant that two or more are common, and is supplemented with sequestrant, pH buffer reagent or filler.

The example of phosphorous washing assistant comprises polyphosphate, and by the tri-polyphosphate of basic metal and ammonium and alkanol ammonium, pyrophosphate salt and glassy polymers metaphosphate are represented, and phosphonate.

Suitable carbonate builders comprises alkaline-earth metal or alkali-metal carbonate, comprises carbonate minerals for example sodium bicarbonate and yellow soda ash, and the complex salt of yellow soda ash or salt of wormwood and lime carbonate are interior.

As described herein, " the organic detergent washing assistant " that be fit to use with an alkarylsulphonic acid salt surfactant comprises the polycarboxylic acid salt compound, comprises water miscible non-surface active dicarboxylate and tricarboxylate.In general, the washing assistant polycarboxylate has a plurality of carboxylate group, preferably has at least three carboxylate radicals.The carboxylate salt washing assistant can form acid or part neutrality, neutrality or excessive alkalescence be introduced into.In the situation of salt form, basic metal is sodium for example, and the salt of potassium and lithium or alkanol ammonium salt are preferred.The polycarboxylate washing assistant comprises ether type polycarboxylic acid salt.

Nitrogenous washing assistant comprises amino acid such as Methionin, or rudimentary hydramine such as Monoethanolamine MEA BASF, diethanolamine and trolamine, three (methylol) aminomethane, 2-amino-2-methyl propyl alcohol, and disodium glutamate.

Citrate trianion such as citric acid and soluble salt thereof are important polycarboxylate washing assistants, and it is used for for example heavy-filth liquid sanitising agent (HDL), because they can be from regenerating and the acquisition of biodegradable resource.Citrate trianion also can be used in the granular composition, particularly in the combination of zeolite and/or layered silicate.Oxygen base disuccinate is particularly useful for this composition and combination.

In cleanser compositions of the present invention, any known washing assistant in this area can be generally about 0.1 to about 50 weight %, more preferably 0.5 to 30 weight % and most preferably the amount of 1 to 25 weight % be introduced into.

Oxygen bleaching agent

In one embodiment, the present invention includes " oxygen bleaching agent " as part or all of detergent composition.Can use any known oxygenant.Perhaps, also can use the oxidant bleach agent, such as the system that generates hydrogen peroxide by oxygen or enzyme, or hypohalite, for example chlorine bleach is such as hyposulfite.

The example of peroxide-based general oxygen bleaching agent comprises hydrogen peroxide, the inorganic peroxy hydrate, and organic peroxy hydrate, and organic peroxide acid comprise wetting ability or a hydrophobic peroxy acid or diperoxy acid.These components can be peroxycarboxylic acids, the peroxide imidic acid, and amide group peroxycarboxylic acid, or its salt comprise their calcium salt, magnesium salts, or mixed-cation salt.Polytype peracid is releasing pattern or be known as " bleaching use tensio-active agent " or the precursor material form of " bleach boosters " is used, and described precursor material is hydrolysis release peracid when supplying raw material combination with hydrogen peroxide.

Inorganic peroxide, super-oxide, organic hydroperoxide are such as cumene hydroperoxide hydrogen and tertbutyl peroxide, and inorganic peroxy acid and salt thereof, such as peroxysulphate, also can be used as oxygen bleaching agent.

Blended oxygen bleaching agent system generally is effective as oxygen bleaching agent and known bleaching during with the form of mixtures of tensio-active agent, organic catalyst, enzyme catalyst or its mixture.In addition, these mixtures can further comprise the brightening agent of type known in this field, gently float agent (lightbleaching agent), and dye transfer inhibitor.

Hydroperoxide and peroxyhydrate are organic salt, perhaps more generally are the inorganic salt that can easily discharge hydrogen peroxide.Peroxyhydrate is the general example in " hydrogen peroxide source ", and comprises perborate, percarbonate, superphosphate, and persilicate.Preferred peroxyhydrate comprises the Equivalent of all yellow soda ash hydroperoxide and commercially available " percarbonate " SYNTHETIC OPTICAL WHITNER, also can use so-called Sodium peroxoborate hydrate and trisodium phosphate hydroperoxide.The urea hydroperoxide also can be used as peroxyhydrate.

Comprise the inorganic peroxy hydrate, the organic peroxy hydrate, wetting ability or a hydrophobic peracid or diperacid, organic peracid comprises peroxycarboxylic acid, peroxide imidic acid and amide group peroxycarboxylic acid, calcium salt, magnesium salts, or blended cationic salts.

In cleanser compositions of the present invention, any oxygen bleaching agent is with about 0 to 15%, and most preferably from about 0.2 to 12% scope is added in this preparation.

Also can use bleaching surfactant.The example of useful bleaching surfactant comprises acid amides, imide, ester and acid anhydrides.Usually, in this bleaching surfactant, in structure R--C (O)-L, there is at least one substituted or unsubstituted acyl moiety that contains leavings group.Alternative using method comprises bleaching surfactant and hydrogen peroxide source of supply such as perborate and percarbonate is used in combination.Can exist one or more peracid to form part or leavings group.Also can use the mixture of bleaching surfactant.

But the usage quantity of bleaching surfactant is maximum 20 weight % of composition, preferred 0.1 to 10 weight %.The form of adding product for highly spissated SYNTHETIC OPTICAL WHITNER, or be used in form in the automatic loading equipment for bleaching surfactant, its can 40 weight % or higher amount use.

Transition metal bleach agent catalyzer can also be used for the present invention.For example, manganic compound is optionally as the bleaching compounds with katalysis.As useful cobalt bleaching catalyst, can use known cobalt bleaching catalyzer.

Except that the above-mentioned bleaching surfactant of enumerating, can use the hydrogen peroxide of enzyme base source of supply.For example, suitable hydrogen peroxide generting machanism comprises C1-C4 alkanol oxydase and C1 combination, particularly methanol oxidase (MOX) and the alcoholic acid combination to the C4 alkanol.Bleach other relevant enzyme material such as peroxidase, halo peroxidase, and oxydase, superoxide molecular replacement enzyme, katalaze enzyme, and toughener, or more generally, also have inhibitor, optionally be used for composition.

Oxygen-transfer agent and precursor

All known organic bleach catalysts, oxygen-transfer agent, or its precursor also can be used on herein.These materials comprise their compound self and/or its precursor, are suitable for making bisoxirane such as all, and/or the ketone of the analogue of bisoxirane precursor or all bisoxirane that contains different atoms.As the preferred example of these components, comprise wetting ability or the hydrophobic ketone of making bisoxirane on the spot with a peroxysulphate especially.Preferably the example of these oxygen bleaching agents that use with oxygen-transfer agent or precursor comprises percarboxylic acids and salt, percarbonic acid class and salt, and peroxide one sulfuric acid and salt, and composition thereof.

The polymer-type soil release agent

Composition of the present invention can optionally comprise one or more soil release agents.The polymer-type soil release agent is characterised in that the possess hydrophilic property segment so that the surperficial tool hydrophilic interaction of hydrophobic fibre such as polyester and nylon and have hydrophobic chain segment to deposit on the hydrophobic fibre and so as to finishing the effect with the anchor that plays hydrophilic segment attached to it wash(ing)cycle.Like this can be so that the easier quilt in washing process subsequently of the dirt after handling with soil release agent is clean.

In use, soil release agent generally accounts for about 0.01 to about 10 weight % of composition.

Clay remover/anti redeposition agent

Composition of the present invention also optionally comprises the water-soluble ethoxylated amine with removing property of clay and antiredeposition.The granular detergent composition that comprises these compounds comprises about 0.01% to about 10.0 weight % water-soluble ethoxylated amine usually, and liquid detergent composition comprises about 0.01% to about 5 weight % water-soluble ethoxylated amine usually.

Preferred contamination releasing agent and anti redeposition agent are the tetraethylenepentamines of ethoxylation.Other preferably stains release remover/anti redeposition agent is ethoxylated amine polymer, amphoteric ion type polymkeric substance and amine oxide class.Other contamination known in the art discharges remover and/or anti redeposition agent also can be used for composition of the present invention.The preferred anti redeposition agent of another type comprises the basic component of carboxymethyl cellulose (CMC).

Polymer dispersant

Polymer dispersant can arrive the amount use of about 10 weight % effectively with about 0.01 of the present composition, when particularly having zeolite and/or layered silicate washing assistant.Suitable polymer dispersant comprises polymer-type polycarboxylate and polyoxyethylene glycol, although also can use other dispersion agent known in the art.It is believed that polymer dispersant when with other washing assistant (polycarboxylate that comprises lower molecular weight) when being used in combination, suppress by crystal growth, particulate contaminants discharges, peptization and anti-redeposition strengthen the performance of total detergent builders.

Polymer-type polycarboxylate material can form by the polymerization or the copolymerization of suitable unsaturated monomer (being preferably its sour form).The undersaturated monomer acids that can polymerization forms suitable polymer-type polycarboxylate comprises vinylformic acid, toxilic acid (or maleic anhydride), fumaric acid, methylene-succinic acid, equisetic acid, methylfumaric acid, citraconic acid and methylene radical propanedioic acid.

Suitable especially polymer-type polycarboxylate can be from vinylformic acid.This acrylic acid based polymer that can be used for this paper is the acrylic acid water-soluble salt of polymeric.It is about 1,000 to 500,000 that the molecular-weight average of the polymkeric substance of this sour form is preferably, and more preferably from about 2,000 to 250,000, most preferably from about 3,000 to 100,000.The water-soluble salt of this acrylate copolymer can comprise for example an alkali metal salt, ammonium salt and the ammonium salt that replaces.

Vinylformic acid/maleic copolymer also can be used as the preferred ingredient of dispersion agent/anti redeposition agent.This material comprises the water-soluble salt of the multipolymer of vinylformic acid and toxilic acid.It is about 2,000 to 100,000 that the molecular-weight average of the multipolymer of this sour form is preferably, and more preferably from about 3,000 to 80,000, most preferably from about 4,000 to 70,000.Propylene acid group in this multipolymer is generally about 9:1 to about 1:9 with maleate segmental ratio, and more preferably from about 8:2 is to 3:7.The water-soluble salt of this vinylformic acid/maleic acid can comprise for example an alkali metal salt, ammonium salt and the ammonium salt that replaces.

The multipolymer of vinylformic acid and/or toxilic acid and polyglycol also can be used as the preferred ingredient of dispersion agent/anti redeposition agent.Multipolymer is the graftomer of vinylformic acid and/or toxilic acid and polyglycol preferably, the multipolymer of the alkylene oxide affixture of vinylformic acid and/or toxilic acid and vinyl carbinol or isoprene alcohol, the multipolymer of vinylformic acid and/or toxilic acid and polyglycol acrylate or methacrylic ester, the more preferably multipolymer of the alkylene oxide affixture of the graftomer of vinylformic acid and/or toxilic acid and polyglycol and vinylformic acid and/or toxilic acid and vinyl carbinol or isoprene alcohol.

It is about 2,000 to 100,000 that the molecular-weight average of multipolymer is preferably, and more preferably from about 3,000 to 80,000, most preferably from about 4,000 to 70,000,

The acrylic acid base co-polymer also can be used as the preferred ingredient of dispersion agent/anti redeposition agent.It is about 3,000 to 100,000 that the molecular-weight average of the multipolymer of this sour form is preferably, and more preferably from about 4,000 to 20,000, most preferably from about 4,000 to 10,000.Acrylamide content in this multipolymer is usually less than the about 50% of polymer weight, preferably be lower than polymer weight about 20% and most preferably polymer weight about 1 to about 15%.

The polymer-type component of introducing in addition is polyoxyethylene glycol (PEG).PEG can show dispersing agent performance and take on clay remover/anti redeposition agent.The typical molecular weight ranges that is used for these purposes is about 500 to about 100,000, preferred about 1,000 to about 50,000 and more preferably from about 1,500 to about 10,000.

Also can use polyaspartic acid salts and polyglutamic acid dipersant, particularly with being used in combination of zeolite builders.Dispersion agent such as polyaspartic acid salts preferably has (weight average) molecular weight of about 10,000.

In cleanser compositions of the present invention, polymer dispersant known in the art usually can about 0.01 to about 15%, more preferably 0.05 to 10%, most preferably 0.1 to 5% amount is introduced.

Brightening agent

In cleanser compositions of the present invention, any white dyes known in the art or other light agent or whitening agent can about 0.01 amount to about 1.2 weight % be introduced into usually.This white dyes is through being commonly used in the situation that sanitising agent wherein is designed to fabric washing or processed and applied.

The polymer-type dye transfer inhibitor

Composition of the present invention can comprise that also one or more are effective to suppress dyestuff is transferred to other fabric from a kind of fabric during cleaning course material.Usually, this dye transfer inhibitor comprises polyvinyl pyrrolidone polymers, polymeric amide N-oxide polymer, and the multipolymer of N-vinyl pyrrolidone and N-vinyl imidazole, manganese phthalocyanine, peroxidase, and composition thereof.If use, these reagent account for about 0.01 to about 10 weight % of composition usually, preferred about 0.01 to about 5 weight % and more preferably from about 0.05 to about 2 weight %.

Selection is used for white dyes of the present invention and shows the especially effectively benefit of dye transfer inhibition when being used in combination with the polymer-type dye transfer inhibitor.In aqueous cleaning solution, being used in combination of the polymer-based material of this selection and the white dyes of this selection, any the independent use than in these two kinds of cleanser compositions components provides significantly better dye transfer restraining effect.

Sequestrant

Cleanser compositions of the present invention also optionally comprises one or more sequestrants, especially for the sequestrant of transition metal from other.Transition metal usually in the washings that comprises water miscible, gelationus or granulous iron and/or manganese as seen, and associate sometimes as oxide compound or oxyhydroxide.Preferred sequestrant is the sequestrant that effectively suppresses this transition metal, particularly suppress adhering to of this transition metal or their compound and fabric, and/or be suppressed in the washing medium and/or the interface of fabric or crust on the preferred redox reaction that takes place.General sequestrant is selected from: aminocarboxylic acid ester, and phosphoramidate, the aromatic chelating agent that polyfunctional group replaces, and composition thereof.

Composition of the present invention also can comprise water miscible methylglycine diacetate as sequestrant, and it can use with insoluble washing assistant such as zeolite and layered silicate effectively.

If the use sequestrant, then sequestrant accounts for about 0.1 to about 15 weight % of composition usually.More preferably, if use sequestrant, then sequestrant accounts for about 0.1 to about 3.0 weight %.

Suds suppressor

When in predetermined the application, needing to wash, when particularly wash, be used for reducing or the compound that suppresses foam formation can be introduced in composition of the present invention by washing machine.For other composition, for example be designed for the composition of washing one's hands, may need foam many, therefore this component can be omitted.In so-called " high density cleaning course " and washing machine (so-called drum-type washing machine) in preceding charging formula European style, this foam inhibition be particularly important.

Very the material of wide class can be used as froth suppressor.Composition of the present invention generally includes the suds suppressor of 0 weight % to about 10 weight %.

Fabric softener

Multiple (through-the-wash) fabric softener by washing is optionally with about 0.5 to about 10 weight % be used to provide and the clean fabric sofetening benefit of carrying out simultaneously of fabric.The clay softening agent can be used in combination with amine and cationic softener.Further, in cleaning course of the present invention, but comprise that the use-pattern of those known fabric softeners of biological degradation type comprises: pre-treatment, main cleaning, the laundry aftertreatment and join washing machine and moisture eliminator in.

Perfume compound

Can be used for the perfume compound of composition and method and fragrance ingredient and comprise natural and synthetic chemical ingredients miscellaneous, include but not limited to aldehydes, ketone and ester class.In addition, also comprise multiple natural extract and essence, it can comprise the complex mixture of each composition, such as orange oil, and lemon peel oil, rose extract, lavender, Moschus, Wrinkled Gianthyssop Herb, face cream essence, santal wood oil, pine tar, and arborvitae.The perfume compound finished product accounts for about 0.01 to about 2 weight % of cleanser compositions usually, and the discrete fragrance ingredient can account for about 0.0001 to about 90 weight % of perfume composition finished product.

The ester class

The ester class can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of ammediol preparation comprises all suitable monoesters and diester class.Special some esters that generate comprise propylene glycol SUNSOFT Q-182S and monostearate, a propylene glycol dilaurate and a lauric acid ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Other component

Other composition miscellaneous that can be used in the cleanser compositions can be incorporated in the composition, comprises other composition, and carrier, hydrotropic solvent, processing aid, dyestuff or pigment, liquid preparation are used solvent and be used for the dirt of stylus composition (soil) filler.Many if desired foams, suds booster such as C10 can be incorporated in the composition to the C16 alkanolamide, and common amount is that 1 weight % is to 10 weight %.C10 is the typical types of this suds booster to C14 single ethanol amide and diglycollic amide.This suds booster and above-mentioned many foams auxiliary tensio-active agent are such as amine oxide, and the use of trimethyl-glycine and sultaine (sultanines) also is favourable.If desired, can add water miscible magnesium salts and/or the calcium salt of 0.1 weight % usually, so that other foam to be provided to the amount of 2 weight %.

The multiple detergent composition that uses in the composition can be optionally further by being adsorbed onto composition on the hydrophobic substrate of porousness, and it is stabilized to apply substrate with hydrophobic coating then.Preferably, detergent composition mixes with tensio-active agent, is adsorbed to then in the porousness substrate.In use, detergent composition discharges into from substrate and contains the water lotion, and it realizes the cleaning action that it is predetermined there.

Liquid detergent composition can comprise the solvent of water and other as thinner.Low-molecular-weight primary alconol or secondary alcohol are suitable, and its example is a methyl alcohol, ethanol, propyl alcohol and Virahol.Monohydroxy-alcohol is preferred for surface of stability promoting agent, but polyvalent alcohol also can be used to the polyvalent alcohols (such as 1, ammediol, ethylene glycol, glycerine and propylene glycol) of about 6 hydroxyls to about 6 carbon atoms and 2 such as containing 2.Composition can 5 weight % to 90 weight %, preferred 10 weight % comprise this thinner to the amount of 50 weight %.

Cleanser compositions preferably is configured to and makes that the pH of bath water is about 6.5 to about 12.5, preferred 7 to 12 and more preferably from about 7.0 to about 11 when aqueous cleaning operating period use.Laundry product is in pH 9 to 11 times usually.Comprise the use buffer reagent in the technology of recommending to be used under the consumption level to control pH, alkali, acid, or the like.

Cleanser compositions of the present invention can comprise any suitable natural component.Natural component comprise any on component or function the composition of the natural or natural origin similar to above-mentioned any composition of enumerating.

The liquid laundry sanitising agent

Although some compositions of enumerating are particularly suitable for the liquid laundry sanitising agent, can determine in those skilled in the art's ken obviously whether this composition can be used for other sanitising agent application.

Bio-PDO is preferably with about 0.1% to about 25%, and more preferably from about 0.5% to about 20% and most preferably from about 1% to about 15% concentration range is provided in the liquid laundry sanitising agent.

Thickening material

In detergent product, improve the physical stability of product liquid or the denseness of change product liquid by adding the crosslinked polypropylene thickening material as thixotropic thickening agent.

PH regulates component

The aforesaid liquid Betengent product is preferably low foaming, can easily be dissolved in the washing medium and be the most effective improving under the most useful pH value of clean-up performance, described pH value wishes it is about pH 6.5 to about pH 12.5, preferred about pH 7.0 to about pH 12.0, more preferably from about pH 8.0 to about pH 12.0, most preferably are lower than about 9.0pH.The pH regulator component can preferably be selected from sodium hydroxide or potassium hydroxide, yellow soda ash or salt of wormwood or concentrated crystal soda or sesquialter salt of wormwood, and water glass or potassium silicate, boric acid, sodium bicarbonate or saleratus, Sodium Tetraborate or potassium borate, and composition thereof.NaOH or KOH are used to increase the preferred component of pH in above-mentioned scope.Other preferred pH regulator composition is a yellow soda ash, salt of wormwood, and composition thereof.

Low foam surface activity agent

Can be used for putting into practice the preferably alkylethoxylate in non-Chlorine Bleach body ADW composition of liquid nonionic type tensio-active agent sanitising agent of the present invention.The example that non-chlorine floats surface of stability promoting agent is SLF18.RTM, is produced by BASF Corporation..Perhaps, in the chloride liquid A DW composition that floats, it is preferred that chlorine floats stable low foam surface activity agent, and this tensio-active agent exists with about 0.1% scope to about 10 weight % of liquid composition.This tensio-active agent is normally well known by persons skilled in the art and need not here set forth for the purpose of brief.The example that chlorine floats stabilized surfactant is the Dowfax.RTM. aniorfic surfactant, derives from Dow Chemical Company.

Examples of nonionic surfactants comprises polyoxyalkylene alkyl, polyoxy alkylidene diol fatty acid ester, the polyether polyols sorbitan ester, the polyether polyols sorbitan-fatty acid ester, polyether polyols Span, polyether polyols glycerol fatty acid ester, monoglyceride, sorbitan-fatty acid ester, lipid acid one glycollic amide, fatty diglycollic amide and alkyl glucosan glucoside.

The example of amphoterics comprises the acetate trimethyl-glycine, amide group acetate trimethyl-glycine, sultaine, amidosulfobetaines, phosphoric acid betaine, alkyl amine oxide and amido amine oxide compound.Wherein fatty acid acyl amido CAB such as coconut monoethanolamide base CAB and lauroyl amido CAB are preferred.The amphoterics that comprises the tetrahydroglyoxaline origin: the amino disodium beclomethasone of N-cocamidopropyl ethyl-N-hydroxyethyl.

Two or more these tensio-active agents use capable of being combined.Foam property during use and clean and liquid property consider that the preferred content of tensio-active agent is 5 to 50 weight % of cleanser compositions of the present invention, more preferably 10 to 30 weight %, even more preferably 10 to 20 weight %.

Siloxanes

Cleanser compositions of the present invention can comprise siloxanes and be used for further improving regulating effect.Siloxanes comprises dimethyl polysiloxane (viscosity: 5mm ²/ s to 20,000,000mm ²/ s), amino modified siloxanes, polyether-modified siloxanes, methyl phenyl silicone, fatty acid modified siloxanes, the siloxanes of alcohol modification, alkoxy-modified siloxanes, epoxide modified siloxanes, the siloxanes of fluorine modification, cyclosiloxane and alkyl-modified siloxanes, wherein dimethyl polysiloxane is preferred.The content of the siloxanes in the cleanser compositions of the present invention is 0.01 to 10 weight % preferably.Cleanser compositions of the present invention can comprise other adjusting component such as cationic polymers (cationic cellulose, positively charged ion guar gum, or the like).Their content in cleanser compositions of the present invention is 0.1 to 5 weight % preferably.

General liquid ingredient

Cleanser compositions of the present invention can comprise the component that is generally used for the predetermined cleanser compositions of using in addition.The example of this component comprises wetting agent such as propylene glycol, glycerine, diethylene glycol monoethyl ether, sorbyl alcohol and panthenol; Tinting material such as dyestuff and pigment; Viscosity regulator is such as methylcellulose gum, polyoxyethylene glycol and ethanol; Plant milk extract; Sanitas; Sterilant; Sequestrant; Vitamin preparation; Anti-inflammatory agent; Perfume compound; UV light absorber; And antioxidant.

Solid and semisolid laundry detergent

Although the composition of below enumerating is particularly suitable for the solid laundry sanitising agent, can determine whether in those skilled in the art's ken that obviously this composition can be used for other sanitising agent application.

The Bio-PDO that solid laundry cleanser compositions of the present invention comprises: the ratio of base-material be 1:20 to 20:1, count by weight percentage; Preferred 1:5 is to 5:1, and most preferably 1:2 is to 2:1, so 0.1 to 25%, 0.5 to 15%, 1 to 10%, about 0.001 weight % is to about 0.5 weight %, more preferably from about 0.1 weight % is to about 0.25 weight %, and most preferably from about 0.25 weight % is to the bio-PDO of about 0.1 weight %.

Preferably, the size distribution of cleanser compositions is for making the granularity of the composition of 10 weight % at the most greater than 850 microns, and the granularity of the composition of 10 weight % is lower than 250 microns at the most.

Composition optionally comprises one or more auxiliary components.Auxiliary component is selected from usually: other aniorfic surfactant, cationic surfactant, nonionic surface active agent, zwitterionics, other washing assistant, polymer-type are total to washing assistant such as the polymer-type polycarboxylate, SYNTHETIC OPTICAL WHITNER, other hydrotropic solvent, sequestrant, enzyme, the antiredeposition polymkeric substance, soil release polymers, polymer-type dirt dispersant and/or soil-suspending agent, dye transfer inhibitor, the fabric smoothing agent, fluorescent bleaches, suds suppressor, fabric softener, flocculation agent, cationic fabric sofetening component, perfume compound, and combination.

Suitable auxiliary component may be the aniorfic surfactant that is different from alkyl alkoxylated sulfate surfactant and linear alkyl sulfonate surfactant.Other suitable anion surfactant is the C8-C18 alkyl sulfate surfactant of side chain or straight chain.Other suitable especially anion surfactant is the C8-C18 alkyl sulfate surfactant of methyl branch.

Suitable auxiliary component may be the aniorfic surfactant that is different from alkyl alkoxylated sulfate surfactant and linear alkyl sulfonate surfactant.Other suitable anion surfactant is the C8-C18 alkyl sulfate surfactant of side chain or straight chain.Other suitable especially anion surfactant is the C8-C18 alkyl sulfate surfactant of methyl branch.

Suitable auxiliary component may be the hydrotropic solvent that is different from alkoxylated alkyl alcohol.Suitable hydrotropic solvent comprises cumene sodium sulfate, toluene sodium sulfate and xylene sulphonic acid sodium.

Gel cleanser

Although the composition of below enumerating is particularly suitable for gel cleanser, can determine whether in those skilled in the art's ken that obviously this composition can be used for other sanitising agent application.Automatically wash that the dish preparation is the most common to be used with gel form.

Bio-PDO is preferably with about 0.1% to about 25%, and more preferably from about 0.5% to about 20% and most preferably from about 1% to about 15% concentration range is provided in the liquid laundry sanitising agent.

Preferably, sheet phase gel laundry composition of the present invention comprises 1 to 8wt%, more preferably 3 to 6wt% jelling agent.

This jelling agent can suitably be the Fatty Alcohol(C12-C14 and C12-C18) shown in the following formula: R ₁--(CHOH)--R ₂, R wherein ₁, R ₂Be independently selected from hydrogen and C saturated or undersaturated, straight or branched ₁-C ₁₆Alkyl, wherein the carbonatoms in the Fatty Alcohol(C12-C14 and C12-C18) is 8 to 17.

Preferably, use to have the Fatty Alcohol(C12-C14 and C12-C18) jelling agent shown in the following formula, wherein R1 saturated or undersaturated, the straight or branched C9-C13 alkyl that is that hydrogen and R2 are selected from.The similar Fatty Alcohol(C12-C14 and C12-C18) of mean chain length of the tensio-active agent that exists in using wherein overall chain length and preparation can obtain advantageous results during as jelling agent usually.This jelling agent is preferably selected from 1-decanol, the 1-dodecanol, and the 2-decyl alcohol, the 2-dodecanol, 2-methyl isophthalic acid-decyl alcohol, 2-methyl isophthalic acid-dodecanol, 2-ethyl-1-decanol, and composition thereof.The commercially available material that particularly suitable is made jelling agent comprises Neodol 23 or Neodol 25, produce by Shell Chemical Co., Exxal 12 or Exxal 13, produce by Exxonmobil ChemicalCo., with Isalchem 123 or Lialchem 123, produce by Sasol Chemical Co..

Jelling agent can suitably be non-neutral lipid acid also, and it is by formula R ₃--(COOH)--R ₄Expression, wherein R ₃And R ₄Be independently selected from hydrogen and C saturated or undersaturated, straight or branched ₁-C ₂₂Alkyl, therefore the total number of carbon atoms in lipid acid is 10-23.This lipid acid jelling agent is preferably selected from oleic acid, lauric acid, and tetradecanoic acid, palmitinic acid, stearic acid, linolic acid, linolenic acid, and composition thereof.

In addition, jelling agent can suitably be can natural acquisition lipid acid, be selected from: butter, cocounut oil and pal Kernel lipid acid.

Aniorfic surfactant

The aniorfic surfactant that can be present in the gelatinous composition of the present invention is preferably selected from linear alkylbenzene sulfonate, alkylsulfonate, and alkyl, polyether vitriol, alkyl-sulphate, and composition thereof.

Nonionic surface active agent

Surfactant system in the gelatinous composition of the present invention also can comprise nonionic surface active agent.

The non-ionic detergent tensio-active agent is well known in the art.They are generally by forming with the poly-alkylene oxide group of the chemically combined water solubilising of organo-phobicity group or strand alkylolamide or two alkanolamide groups, described organo-phobicity group is from for example alkylphenol (wherein alkyl comprises about 6 to about 12 carbon atoms), dialkyl group phenol (wherein primary, the second month in a season or uncle's fatty alcohol or its alkyl-blocked derivative preferably have 8 to 20 carbon atoms), monocarboxylic acid (in alkyl, containing 10) and polyoxytrimethylene to about 24 carbon atoms.Also commonly lipid acid one alkanolamide and two alkanolamides, wherein the alkyl of fatty acid group contains 10 and contains 1 to 3 carbon atom to about 20 carbon atoms and alkyloyl.In an alkanolamide and two alkanolamide derivatives any, randomly can there be the polychlorostyrene alkylene moiety that is connected with the back group and the hydrophobic parts of molecule.

Washing assistant

In the present embodiment, can washing assistant used according to the invention comprise conventional alkaline washing detergent builders, inorganic or organic, 0% to the 50 weight % that it can gelatinous composition, the level of preferred 1% to 35 weight % is used.

The example of spendable inorganic detergent builders suitably is water miscible alkali metal phosphate, polyphosphate, borate, silicate, and carbonate and supercarbonate.The object lesson of this washing assistant is the triphosphate of sodium and potassium, pyrophosphate salt, orthophosphoric acid salt, hexametaphosphate, tetraborate, silicate, and carbonate.

The example of suitable organic detergent washing assistant is: (1) water soluble amino polycarboxylate, the edetate of sodium and potassium for example, nitrilotriacetic acid(NTA) salt and N-(2-hydroxyethyl)-nitrilo diacetin; (2) water-soluble salt of phytic acid, for example phytate of sodium and potassium; (3) water-soluble poly phosphonate specifically comprises the ethane-1-hydroxyl-1 of sodium and potassium, the salt of 1-di 2 ethylhexyl phosphonic acid; The methylene diphosphonate of sodium and potassium; The ethylidene diphosphonic acid salt of sodium and potassium; With the ethane-1,1 of sodium and potassium, 2-triphosphine hydrochlorate.

In addition, the polycarboxylate washing assistant can be used satisfactorily, comprises benzene hexacarboxylic acid, water-soluble salt, the salt of the polymkeric substance of methylene-succinic acid and toxilic acid, tartrate monosuccinic acid salt and the tartrate disuccinate of citric acid and carboxyl methoxyl group succsinic acid.

Wish ground, detergent builders is selected from carboxylate salt, polycarboxylate, and aminocarboxylate, carbonate, supercarbonate, phosphoric acid salt, phosphonate, silicate, borate, and composition thereof.

The Citrate trianion of basic metal (being sodium or potassium) is to be used for most preferred washing assistant material of the present invention.

Unbodied and crystalline zeolite or aluminosilicate also can be suitably as the detergency washing assistants in the gelatinous composition of the present invention.

Enzyme

The suitable enzyme that is used for existing embodiment of the present invention comprises proteolytic enzyme, amylase, and lipase, cellulase, peroxidase, and composition thereof, they are from any suitable source, such as plant, and animal bacteria, fungi and yeast source.Preferred select to be subjected to activity, thermostability and to the stability of active bleach clean-up agent, the influence of the factor of washing assistant etc. such as pH.In this respect, bacterial enzyme and fungal enzyme are preferred, such as protease and the fungin enzyme of bacterium.

Enzyme is merged in the cleanser compositions with the level that " cleaning significant quantity " enough is provided usually.Term " cleaning significant quantity " is meant any cleaning that can produce the substrate of handling, decontamination, abstersive, bleaching, or the amount of pure and fresh improvement effect.Be used for the commercial off-the-shelf actual terms of standard, the typical amount of organized enzyme is that every gram cleanser compositions is about 5 milligrams at most, is more typically 0.01 milligram to 3 milligrams.Explanation is that composition of the present invention can comprise 0.001 to 5% usually, the commercial enzyme preparation of preferred 0.01 to 1 weight % in addition.

The proteolytic enzyme enzyme is that the active level of 0.005 to 0.1 Anson unit (AU) is present in this commercial formulation so that every gram composition enough to be provided usually.Higher activity level is wished in highly spissated detergent formulations.

The suitable examples of protease is the Validase TSP Concentrate II that derives from B.subtilis and the special strain of B.licheniformis.A suitable proteolytic enzyme derives from bacillus strain, has maximum activity in the pH of 8-12 entire area, by the Novozymes of Industries A/S exploitation and the conduct of Denmark

.RTM. sell.

Other suitable protease comprises

With With

Derive from Novozymes, With

Derive from Genencor International and

Derive from International Bio-Synthetics, Inc., The Netherlands.

The suitable lipase enzyme that is used for composition of the present invention comprises those enzymes by the Rhodopseudomonas microorganisms, such as at GB-1, and disclosed pseudomonas stutzeriATCC 19.154 in 372,034.Very suitable lipase is the lipase that derives from humicola lanuginosa, and derives from Novozymes, Denmark Nordisk, and trade name is

Other suitable lipase is

Derive from Novozymes.

The suitable Mierocrystalline cellulose enzyme that is used for composition of the present invention comprises those that are produced by aspergillus microorganism.Suitable Mierocrystalline cellulose enzyme is with trade name:

Derive from Novozymes,

With

LUNA derives from Genencor International.

The α-Dian Fenmei enzyme can obtain by the microorganisms of genus bacillus and with following trade name:

Derive from Novozymes, Denmark.α-Dian Fenmei with

Obtain, derive from GenencorInternational.

The mannase enzyme is to derive from Novozymes, the trade name of Denmark With the trade name that derives from Genencor International Obtain.

The mixture or the blend that are used for the enzyme of composition of the present invention obtain with following trade name: T-BLEND T-BLEND

T-BLEND

T-BLEND

T-BLEND T-BLEND T-BLEND SAVINASE/ Derive from Novozymes, Denmark.

The component that other is optional

Except that above-described aniorfic surfactant and nonionic surface active agent, surfactant system of the present invention can optionally comprise cationic surfactant.

In addition, the alkali buffer reagent can be added in the composition of the present invention, and it comprises monoethanolamine, trolamine, borax etc.

As other optional member, organic solvent can suitably be present in the gelatinous composition of the present invention, and preferred concentration is maximum 10 weight %.

In preparation, also can comprise a spot of dirt suspending agent or anti redeposition agent, as polyvinyl alcohol, fatty amide, Xylo-Mucine or HPMC.

Also can use the white dyes and antifoam agent such as silicone oil and the silicone oil emulsion that are used for cotton, polymeric amide and polyester textile.

Other optional ingredients that can be added on a small quantity is a dirt release polymer, dye transfer inhibitor, and polymer dispersant, suds suppressor, dyestuff, perfume compound, pigment, filling salt, anti-stripping agent, and composition thereof.

The liquid hand is with washing the dish sanitising agent

Although some compositions of enumerating are particularly suitable for the liquid hand with washing the dish sanitising agent, can determine whether in those skilled in the art's ken that obviously this composition can be used for other sanitising agent application.

In said composition the concentration of polyoxyethylene glycol be 0.5 weight % to 10 weight %, more preferably 0.75 weight % is to 6 weight %.

Aniorfic surfactant

The anionic sulfonate surfactant that is applicable to this paper comprises the C5-C20 linear alkylbenzene sulfonate; alkyl ester sulfonate; C6-C22 uncle or secondary alkyl sulfonate; the C6-C24 alkene sulfonate; the sulfonation poly carboxylic acid, alkyl glycerol sulfonate, fatty acyl group glycerol sulfonate; fatty oil base glycerol sulfonate, and composition thereof.

Be applicable to that anionic sulfated surfactant in the composition of the present invention comprises primary and secondary alkyl-sulphate, alkyl ethoxy sulfate, fatty oil acylglycerol vitriol and the alkylphenol ethylene oxide ether sulfate of straight chain and side chain.

Suitable anionic carboxylate surfactant comprises alkyl ethoxy carboxylate, alkyl polyethoxye polycarboxylate tensio-active agent and soap class (" alkyl carboxyl ").

The example of preferred anionic type tensio-active agent (sulfonate and vitriol) is commercially available secondary alkansulfonic acid sodium salt, its trade name be Hostapur.RTM.SAS (Clariant Corporation, Charlotte, N.C.).

Sulfonate: linear alkylbenzene sulfonate (LAS), sulfonated (AOS), paraffin sulfonate (PS).

Vitriol: sodium lauryl sulphate (SLS), lauryl oxyethyl group sodium sulfate (SLES).

Water

The final component of inventive composition is a water.Normally 35 weight % of common composition are to 85 weight % for the ratio of water in composition, and preferred 50 weight % are to 80 weight %.

Amine oxide

Can be used for the alkyl amine oxide that amine oxide of the present invention comprises long-chain, that is, have those compounds of following formula structure:

R ³(OR ⁴) _x--(NO)--(R ⁵) ₂

R wherein ³Be selected from alkyl, hydroxyalkyl, acyl group amidopropyl and alkyl phenyl, or its mixture contain 8 to 26 carbon atoms, preferred 8 to 16 carbon atoms; R ⁴Be alkylidene group or the hydroxy alkylidene that contains 2 to 3 carbon atoms, preferred 2 carbon atoms, or its mixture; X is 0 to 3, preferred 0; And each R ⁵Be to contain 1 to 3, the alkyl or the hydroxyalkyl of preferred 1 to 2 carbon atom, or contain the polyoxyethylene group of 1 to 3 preferred 1 ethylene oxide group.R ⁵Group can be connected to each other, and for example connects by oxygen or nitrogen-atoms, to form ring texture.

These amine oxide tensio-active agents comprise C especially ₁₀-C ₁₈Alkyl-dimethyl amine oxide and C ₈-C ₁₂Alkoxyethyl dihydroxy ethyl amine oxide and alkylamidoalkyl propyl group amine oxide.This examples of material comprises dimethyl octyl group amine oxide, diethyl decyl amine oxide compound, two-(2-hydroxyethyl) n-Laurylamine oxide compound, dimethyl n-Laurylamine oxide compound, laurylamide base propyl group dimethylamine oxide compound and dimethyl-2-hydroxyl octadecane amine oxide.Preferred C ₁₀-C ₁₈Alkyl-dimethyl amine oxide, and C ₁₀-C ₁₈Acyl group amido alkyl dimethylamine oxide compound.

Trimethyl-glycine

Can be used for trimethyl-glycine of the present invention is the compound with following formula structure: R (R ¹) ₂N ⁺R ²COO ^-, wherein R is C ₆-C ₁₈Alkyl, preferred C ₁₀-C ₁₆Alkyl, each R ¹C normally ₁-C ₃Alkyl, preferable methyl, R ²Be C ₁-C ₅Alkyl, preferred C ₁-C ₅Alkylidene group, more preferably C ₁-C ₂Alkylidene group.The example of suitable trimethyl-glycine comprises cocoyl amidopropyl dimethyl betaine, hexadecyldimethyl benzyl ammonium trimethyl-glycine; C ₁₂-C ₁₄The acyl group amido propyl betaine; C ₁₂-C ₁₈Acyl group amide group hexyl diethyl betaines; 4-[C ₁₄-C ₁₆Acyl group methyl nitrosourea base diethyl ammonium]-1-carboxyl butane; C ₁₆-C ₁₈Acyl group amide group dimethyl betaine; C ₁₂-C ₁₆Acyl group amide group pentane diethyl betaines; C ₁₂-C ₁₆Acyl group methyl nitrosourea base dimethyl betaine, and cocamidopropyl betaine.Preferred trimethyl-glycine is C ₁₂-C ₁₈Dimethyl Ammonium acetate and C ₁₀-C ₁₈Acyl group amide group propane (or ethane) dimethyl (or diethyl) trimethyl-glycine.Also comprise the sultaine shown in the following formula (sultaines): R (R ₁) ₂N+R ₂SO ₃--, wherein R is C ₆-C ₁₈Alkyl, preferred C ₁₀-C ₁₆Alkyl, more preferably C ₁₂-C ₁₃Alkyl; Each R ₁C normally ₁-C ₃Alkyl, preferable methyl, and R ₂Be C ₁-C ₆Alkyl, preferred C ₁-C ₃Alkylidene group, or preferred hydroxy alkylidene.The example of suitable sultaine is C ₁₂-C ₁₄Dihydroxy ethyl ammonium propane sulfonate, and C ₁₆-C ₁₈Dimethyl Ammonium hexane sulfonate, C ₁₂-C ₁₄Amidopropyl ammonium-2-hydroxypropyl sultaine is preferred.

The alkanolamide compound

Preparation of the present invention can comprise the alkanolamide compound, such as alkyl one alkanolamide and alkyl two alkanolamides, and composition thereof.

Preparation of the present invention can comprise hydrotropic solvent, is selected from: ethanol, and Virahol, sodium xylene sulfonate, propylene glycol, cumene sodium sulfonate, polyoxyethylene glycol, and composition thereof.

Solvent

Preparation of the present invention can comprise and is selected from following solvent: alcohols (ethanol, Virahol), and glycols (propylene glycol, polyoxyethylene glycol), polyvalent alcohol and polyethers (dipropylene glycol, dipropylene glycol methyl ether), and composition thereof.Can use among the present invention many other can be miscible with water liquid, as the lower alkane alcohols, glycols, other polyalcohols, ethers, amine or the like.Preferred C1-C4 alkanol.When having solvent, composition of the present invention preferably comprises the about 0.01% of composition at least, more preferably at least about 0.5%, even more preferably at least about the solvent of 1 weight %.Composition also preferably comprises the about at the most 20% of composition, and is more preferably about at the most 10%, even the more preferably solvent of about at the most 8 weight %.

Inorganic salt

Preparation of the present invention can comprise particularly Mg of polyvalent cation ⁺⁺Inorganic salt or organic salt or oxide compound, it has phase stability matter.Some benefits that polyvalent cation salt or oxide compound provide are included in the dilution usage and improve clean-up performance, particularly minimize in soft water area and the feasible amount that obtains the required perfume compound of microemulsion state.Sal epsom, it is anhydrous or (for example heptahydrate) hydration is preferably used as magnesium salts.Also reported magnesium oxide, magnesium chloride, magnesium acetate, propionic acid magnesium and magnesium hydroxide also have good result.These magnesium salts can use with preparation under neutrality or acid pH, because magnesium hydroxide can not precipitate under these pH levels.

Although magnesium is preferably to form the salt polyvalent cation of (comprising oxide compound and oxyhydroxide), also can use other polyvalent metal ion, condition is that their salt is nontoxic and dissolves in system's aqueous phase under required pH level.

Other component

Liquid cleansing composition of the present invention also can comprise other optional component if desired other effect to be provided or to make product more attractive for consumers.Below be illustrated: the tinting material of maximum 0.5 weight % or dyestuff; Sanitas or antioxidant, such as formalin, 5-bromo-5-nitro-dioxs-1,3; 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2,6-di-t-butyl-p-cresol, or the like, it measures maximum 2 weight %; PH regulator agent as required is as sulfuric acid or sodium hydroxide.In addition, opaque if desired composition can add the opalizer of maximum 4 weight %, and preferably, optional ingredients is selected from: hydrotropic solvent, perfume compound, tinting material, pH regulator agent, sanitas, sterilant, inorganic salt, opalizer, viscosity modifier, and composition thereof.

Specialization household cleaning agent (SHC)

Specialized household cleaning agent of the present invention comprises Bio-PDO and the typical detergent composition described in the joint on one or more.Those skilled in the art can determine easily that suitable composition and Bio-PDO combination is to obtain required specialized household cleaning agent.

Viscosity

Some comprise Bio-PDO cleanser compositions may than comprising of other comparable glycols such as propylene glycol, butyleneglycol, 2-methyl isophthalic acid, the composition of 3 propylene glycol or the like is compared and is required approximately to lack 30% salt to regulate viscosity.In other composition, Bio-PDO can help to keep and set up viscosity.

The thermal conduction composition

Term used herein " heat-transfer fluid " is meant can be from first name a person for a particular job some transfer of heat energy and/or be dissipated to fluid or liquid at second.Heat-transfer fluid comprises refrigerant.

Heat-transfer fluid can comprise strong solution and the Bio-PDO mixture and the preferred deionized water blended of the water dilute solution of Bio-PDO mixture as used in this article.Can the strong solution form buy, transport or be used although can understand heat-transfer fluid, the particularly deionized water dilution of the frequent water of this enriched material is incorporated into then or is used in fuel cell for example.Exemplary thermal conduction composition includes but not limited to be used for radiant heating system and industrial heating is used, the heating medium of heating, heating ventilation and air-conditioning application and thermal energy storage, heating and cooling.Heat-transfer fluid also can be used in many markets, comprises vehicle and equipment (as frostproofer), processing and manufacturing industry (for example chemistry, medicine, plastics, fiber and food), energy discharges, pitch, laundry, biotechnology, low-temperature corrosion protection, metal manufacturing, mining, rink, refrigeration system and heating system, metal manufacturing, transportation is dug up mine and other are such as rink.

In the thermal conduction composition, glycols is the main ingredient of composition normally, and the amount with about 1% to about 100% exists.

In antifreeze composition, glycols is the main ingredient of composition normally, and the amount with about 1% to about 100% exists.

In thermal conduction of the present invention and antifreeze composition, Bio-PDO can be the main ingredient of composition, exists with the amount of maximum 100 weight % of the weight of total composition.The amount of the Bio-PDO that uses in product is the surplus after typical composition such as the sanitas, defoamer, dyestuff and the water that add certain percentage ratio normally.

Those of ordinary skills now can understand, and in appropriate circumstances, consider such as erosion, toxicity, viscosity, fluid life, the equipment and technology requirement, fluid color, items such as cost, other composition is such as for example one or more tinting material, wetting agent, defoamer, sterilant, bitterant, non-ionic dispersing agent, antifoam agent, Anti-icing Additive, antiwear additive, demulsifying compound, sanitising agent, dispersion agent, emulsifying agent, EP additive, oiliness improver, oxidation retarder, pour point reducer, rust-preventive agent, tackiness agent, viscosity modifier, sanitas, alcohols, or its combination, with any other optional member, can be added in thermal conduction of the present invention or the anti-freezing composition.

More particularly, except the glycols component of Bio-PDO or other biology origin, the typical heat-conducting flow body preparation of the present invention can comprise the water of 1.0-95.0 weight %, 0.10% to 50.0% sanitas, 0.10% to 50.0% defoamer, and/or in 0.10% to 50.0% the dyestuff one or more.

In typical antifreeze fluid of the present invention or refrigerant preparation, except the glycols component of Bio-PDO or other biology origin, said preparation also can comprise the water of 1.0-90.0 weight %, 0.10% to 50.0% sanitas, in 0.10% to 50.0% defoamer and 0.10% to 50.0% the dyestuff one or more.

Composition

Below enumerated the non-limiting inventory that can be used for being used in the composition in thermal conduction of the present invention and the antifreeze preparation with the Bio-PDO combination.This tabulation is not intended to all-embracing, and those skilled in the art know other the principal component that can be used for preparation of the present invention.

Corrosion inhibitor

Useful corrosion inhibitor can enough suppress or the corrosive amount of the metallic surface of the exposure that minimizing contacts with engine cool composition of the present invention is used, and preferably uses with the amount of 0.01 to 50 weight %.Preferred corrosion inhibitor comprises the corrosion inhibitor of any routine or commercial use, includes but not limited to inorganic nitrate and nitrate, preferred Na, K, Mg, the salt of Ca and Li; Pyroles is selected from tolyl-triazole, hydrocarbyl triazole, benzotriazole, sulfydryl phenyl thiazole, pyrazoles ， isoxazole, isothiazole class, thiazoles, thiadiazoles salt, 1,2,3-benzotriazole, 1,2,3-tolytriazole and 2-sulfydryl phenyl thiazole sodium; Inorganic molybdate, as Sodium orthomolybdate, potassium molybdate, lithium molybdate, ammonium molybdate, ammonium dimolybdate, MoO3, assorted poly molybdate, molybdic acid disodium dihydrate, sila poly molybdate and phospha poly molybdate; Monocarboxylic acid, C3-16-carboxylic acid (or lipid acid) (or corresponding alkali metal salt) normally, particularly caproic acid for example, enanthic acid, isoamyl acetic acid, sad, 2 ethyl hexanoic acid, n-nonanoic acid, capric acid, undecanoic acid, dodecylic acid and new n-nonanoic acid; Inorganic phosphate for example comprises, K2HPO4, and Na2HPO4, KH2PO4, K3PO4, NaH2PO4, and Na3PO4, and composition thereof.More preferably corrosion inhibitor is one of PENRAY corrosion inhibitor that derives from Penray Companies, such as PENRAY 2792 (aqueous solution of nitrite, nitrate and sodium hydroxide).

Defoamer

Thereby defoamer is strongly to discharge the air carry secretly and enough reduce foam and assemble or reduce foam or the amount of the air carried secretly is used by bubble is quick-fried.Preferably the usage quantity of defoamer is 0.01 to 50 weight %.The defoamer that can have one or more.Preferred defoamer includes but not limited to, for example, PATCOTE 415 or 462 (ethylene glycol n-butyl ether base defoamer, produce by AmericanIngredients Company), PLURONIC L61 (segmented copolymer, produce by BASF Corp.), DOW AF9020 (silicone oil emulsion is produced by Dow Chemical), ADVANTAGE831 (hydrocarbon ils emulsion, by Hercules, Inc. produces), POLYTERGENT P32A (EO/PO multipolymer, produce by Olin Corp.), LANDA 5600 (defoamer of oil-soluble water miscibility is produced by Landa Corp.) and AF-20F (silicone oil emulsion is produced by Performance ChemicalsLLC).

Water

The water that comprises in the composition can be any aequum, preferred 1 to 99 weight %.More preferably, the amount of water is 30 to 70 weight %, most preferably 40 to 60 weight %.Water is distilled water and/or deionized water preferably.Preferably, water be removed ion before other component of composition contacts.

Tinting material/dyestuff

Composition of the present invention can comprise tinting material/dyestuff, easily composition and colourless liquid is particularly separated in the pool to help the user.The appropriate colouring agent can be the tinting material of any routine, and can have any required color, include but not limited to orange, blueness, green, red and yellow, and any combined color.If there is dyestuff, then the amount that required color is provided that dyestuff can be any is used, and is preferably 0.01 to 50 weight %.The dyestuff that can have one or more.More preferably, stable, the transparent water-soluble organic dye of any light is suitable, include but not limited to acid red dye, methylenum coeruleum, the uranine dyestuff, wool yellow dyes and if tannin dyestuff, preferred coloring agent such as 15189 eosin OJ (the acid red 87 radical dye is available from Chemcentral Dyes and Pigments) especially.

Fluorine surfactant

Composition of the present invention further comprises at least a fluorine surfactant of 0.001 to 50 weight %.Wish that the ground fluorine surfactant causes that comparing contact angle (for example droplet height) with raw water/diol mixture reduces, improve the surface properties of liquid or solid, or reduce the interfacial tension between the intravital surface tension of stream or two kinds of non-miscible fluids such as oils and the water.Contact angle and/or capillary measurement are known in the art.Term fluorine surfactant and fluorinated surfactant are used interchangeably in this article.Preferably, fluorine surfactant water soluble.Preferred fluorine surfactant includes but not limited to ZONYL fluorine surfactant (anionic, non-ionic type, with the amphoteric fluorinated surfactant), include but not limited to, ZONYL FSA, FSE, FSJ, FSP, TBS, FSO, FSH, FSN, FSD and FSK, more preferably non-ionic type ZONYL fluorine surfactant, ZONYL FSH most preferably, FSN or FSP (the normally polyoxyethylene glycol that replaces of fluoroalkyl alcohol and the mixture of water and glycols or glycol ethers such as dipropylene glycol methyl ether) (all available from DuPont).Fluorine surfactant can use separately, perhaps as required, can with other fluorine surfactant or not fluorochemical surfactant be used in combination.

The ester class

The ester class can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of 3 propylene glycol preparation comprises all suitable compound monoesters and diester class.Particularly some esters of Sheng Chenging comprise propylene glycol SUNSOFT Q-182S and monostearate, propylene glycol dilaurate ester and January silicon ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Other composition

Composition of the present invention can optionally comprise one or more other additive.These for example include but not limited to the alkali metal borate as corrosion inhibitor, and are such as at United States Patent (USP) 4,149, disclosed in 985,2,566,923,3,960,740,2,373,570 and 2,815,328; As the basic metal sebacate of corrosion inhibitor, such as at United States Patent (USP) 2,726,215, English Patent 1,004,259, United States Patent (USP) 4,382, disclosed in 008,4,561,990,4,587,028 and 4,588,513; As the alkali metal molybdate of corrosion inhibitor, such as at United States Patent (USP) 2,147, disclosed in 409 and 4,561,990; Basic metal sulfydryl phenyl thiazole, such as at United States Patent (USP) 2,815, disclosed in 328,4,455,248,4,414,126 and 4,545,925; As the base metal nitrate of corrosion inhibitor, such as at United States Patent (USP) 2,815, disclosed in 328,4,508,684,4,455,248 and 4,587,028; Tolyl-triazole, such as at United States Patent (USP) 4,242,214,2,587,028,4,382,008 and English Patent 1,004,259 in disclosed; Alkalimetal silicate, such as at United States Patent (USP) 2,815, disclosed in 328,4,242,214,4,382,008,4,382,870,4,455,248 and 4,149,985, its relevant portion separately is incorporated herein by reference.

Natural component

Thermal conduction of the present invention or anti-freezing composition can comprise any suitable natural component.Natural component comprise any form or function on the composition of the natural or natural origin similar to above-mentioned any composition of enumerating.

Anti-freezing composition

Antifreeze/anti-icing compositions can be used in the antifreeze and/or anti-icing application of any needs.In some embodiments, composition is used to remove before taking off the sedimentary or lip-deep frost of road/runway on the aircraft outside surface, ice and/or snow, and/or at these time limitation protection.Composition can by for predetermined use be under the pressure of standard and the flow velocity through commerce antifreeze/anti-icing delivery system is applied on the described surface.

Except that being applied to aircraft, composition also can be used for other anti-icing/antifreeze application, such as, runway Surface for example, road, walkway, side line, bridge, inlet, electric tower structure and assembly thereof, electrical transmission lines, water channel, sluice, boats and ships, navigation assembly, the surface of track switch and Motor vehicles.In addition, composition can be used to such as following application: the basin shape ornament of playing with water or drinking water for bird, open-air fountain, ornamental pond and other wherein water freezing are aesthetically or be unwelcome open-air area on the function.In these were used, described fluid can prevent water freezing in the winter time under cold climate, reduced the biological risks to Wildlife or domestic animal.

Also can predict composition of the present invention can liquid or solid form use.For example, compound can be become liquid form and spray or spread on the surface.Perhaps, it can be prepared into solid form and use with form of powder.Randomly, solid can use method well known in the art further processed, such as for example making bead, granule, sheet, or dipping, so that the preparation of final available powder or granular form to be provided.Any base-material well known by persons skilled in the art optionally exists, and can be inert or can be made up of the component that help to reduce freezing point energetically.For example, slag, sawdust, sand, gravel, sugar, Star Dri 5, and composition thereof can be used.

In the method for the invention, antifreeze and/or anti-icing compositions of the present invention is such as being applied by injection or the injection system that is used for liquid form.

In anti-icing or anti-freezing composition of the present invention, the glycols component of Bio-PDO or other biological origin can be the main ingredient of composition, exists with the amount of maximum 100 weight % of the weight of total composition.The amount of the Bio-PDO that uses in the product is the surplus after adding one or more tensio-active agents, corrosion inhibitor, water and any optional ingredients normally.Deicing fluid/anti-freeze fluid preferably comprises about 10wt% to the Bio-PDO of about 95wt%, and more preferably from about 25% to about 92%.Typically antifreeze/anti-icing the preparation that is used for aircraft may include but not limited to following component: the Bio-PDO of 25-95 weight % or its mixture; With every kind of following component of maximum 1%: at least a tensio-active agent or tensio-active agent blend, at least a corrosion inhibitor, pH regulator agent, thickening material, and dyestuff.Water can constitute the surplus of said preparation.More detailed description for alternative preparation and composition vide infra.

In certain embodiments, comprise in the embodiment of glycerine and Bio-PDO combination such as those, composition of the present invention preferably comprises about 10% to about 88% glycerine, and therefore is low to moderate about 1% to about 30% Bio-PDO.

Functional ingredient and other composition

Of the present invention antifreeze/anti-icing product can comprise one or more functional ingredient and other composition.Can be used for the functional ingredient of this paper and other composition can classify in this article or describe by the mode of action of their benefits in antifreeze or anti-icing compositions or its supposition.Yet, will be understood that functional ingredient and other composition of can be used for this paper are providing in some cases above a kind of benefit or by playing a role above a kind of mode of action.Therefore, classify herein for convenience's sake, and be not intended to composition is restricted in the application of specifically noting or listed application.

Tensio-active agent

Preferred surfactants is a nonionic surface active agent; Anionic, cationic and amphoteric (amphoteric ion type) tensio-active agent are more not preferred.The non-limiting ion of some of suitable nonionic surface active agent is: alkylphenol ethoxylate (C ₃₂Or lower, C ₈Or lower be preferred); Fatty Alcohol(C12-C14 and C12-C18) or oxo alcohol polyglycol ether (C ₁₆Or lower, C ₆Or lower be preferred); Ethylene oxide-propylene oxide polymer (C ₈₀Or lower, C ₂Or lower be preferred); Poly alkyl alcohol glycol ethers (C ₁₈Or lower, C ₈Or lower be preferred); Polyethoxylated is such as Soxylat A 25-7; Poly-propoxylated glycerine is such as polyethenoxy ether; Glycosyl surfactant active such as alkyl glycoside (for example alkylbenzene and tert.-butoxy ethanol); The C of 2 to 50 polyoxyethylene units ₁To C ₈The ether of polyoxyethylene repeating unit (low-carbon alkyl and high-carbon ethoxylate group be preferred) slightly; MW is 1000-10,000 polyvinyl alcohol; And Polyvinylpyrolidone (PVP).

Nonionic surface active agent can be selected from polyoxy alkylidene ether.Some preferred polyoxy alkylidene ethers are C ₁₂To C ₁₈The ether of the polyoxyethylene repeating unit of alcohol and 2 to 100 polyoxyethylene units.This tensio-active agent for example comprises the tensio-active agent (for example Brij 30,35,52,56,58,72,76,78,92,97,98 and 700) of the Brij.TM. series of being produced by ICI.Brij 35 is polyoxyethylene lauryl ether, and average MW is 718, and chemical formula is: CH ₃(CH ₂) ₁₁(CH ₂CH _2O) _XH, wherein x on average is 23.

Fluid can comprise the tensio-active agent of any appropriate amount.Preferably, fluid comprises the tensio-active agent of about 0.01 weight % to about 0.9 weight %, and more preferably from about 0.05 weight % is to about 0.5 weight %.

The pH regulator agent

Of the present invention antifreeze/anti-icing compositions can comprise optionally that one or more pH regulator agent are under the constant pH to keep fluid.Composition can have any suitable pH value.The pH scope of composition is about 3.5 to about 12, any number between preferred about 6 to about 9.Can use mineral alkali such as sodium hydroxide, ammonium hydroxide and potassium hydroxide, or amine is such as trolamine, diethanolamine or Monoethanolamine MEA BASF obtain the pH that wishes.

Some non-limitative examples of suitable buffer reagent comprise: phosphoric acid salt (K ⁺, NH ₄ ⁺); Pyrophosphate salt (Na ⁺, K ⁺, NH ₄ ⁺); Metaphosphate (Na ⁺, K ⁺, NH ₄ ⁺); Carbonic acid and salt (Na thereof ⁺, K ⁺, NH ₄ ⁺); Hydroxyl ammonium (Na ⁺, K ⁺, NH ₄ ⁺); Adidic acid and salt (Na thereof ⁺, K ⁺, NH ₄ ⁺); Toxilic acid and salt (Na thereof ⁺, K ⁺, NH ₄ ⁺); With xitix and salt (Na thereof ⁺, K ⁺, NH ₄ ⁺).

Defoamer

Also can use defoamer.Can use any commercially available defoamer, but particularly preferred defoamer is a silicone antifoam agent, sells that trade mark is SAG and derives from Ultra Additives Inc., Patterson, the FOAMBAN of N.J by Union Carbide Corporation ^TMDefoamer.The usage quantity of defoamer is preferably about 0.05% to about 0.5 weight % of total composition weight.

Corrosion inhibitor

Suitable corrosion inhibitor is known in the art, and generally includes the mixture of multiple functional material in one or more solvents, for example buffer reagent, sequestrant or the like, the ester of the acid of mineral acid such as phosphorus and boron, aromatic triazole such as tolyl-triazole and benzyl triazole, or the like.Preferred mixture against corrosion is the product that is called " Sandocorin 8132 " by the name that Sandoz sells.Those skilled in the art will be understood that the type on the surface that the selection of suitable corrosion inhibitor can may contact based on composition of the present invention, and how long they may keep on this surface and carry out under which type of condition.

Suitable corrosion inhibitor comprises those that belong to following classification: inorganic metal salt, the an alkali metal salt of lipid acid, monoalkylamine and dialkylamine (its optional alkoxyization) and salt thereof, alkanolamine (its optional alkoxyization) and salt thereof, the ester of inferior phosphorus (phosphorus) acid or phosphoric acid, and triazole.The usage quantity of corrosion inhibitor is preferably about 0.05% to about 0.8 weight % of total composition weight.

Thickening material

Thickening material can be used in the composition of the present invention, and often comprises polymer-type water activation thickening material.Thickening material accounts for 0.1 and 15.0 weight % of total composition usually.For example comprise the polysaccharide thickening material, natural gum thickening material, marine alga colloid and ether of cellulose thickening material.Preferred thickening is the polysaccharide that is commonly referred to xanthan gum.

Oil

Composition can optionally comprise at least a nonpolar oil, such as aliphatic oil and aromatic oil, and such as mineral oil, paraffin oil, silicone oil, and oxypropylene/oxyethylene copolymers.The amount of this oil normally composition total weight about 0.01% to about 5 weight %.Preferable range is 0.1% to 1.0 weight % of composition total weight.

Thermo-stabilizer

Antifreeze/anti-icing product may further include the material of the thermostability of improving material.Any suitable material with these character can be used, for example some phosphoric acid salt.Object lesson is the mixture of SODIUM PHOSPHATE, MONOBASIC and Sodium phosphate dibasic, such as the mixture of monohydrate SODIUM PHOSPHATE, MONOBASIC and heptahydrate Sodium phosphate dibasic.

Product can comprise the buffer reagent/frostproofer of any appropriate amount.Fluid preferably comprises the SODIUM PHOSPHATE, MONOBASIC and about 0.02wt% Sodium phosphate dibasic to about 2wt% of about 0.02wt% to about 2wt%, and more preferably from about 0.3wt% arrives about 1.5% SODIUM PHOSPHATE, MONOBASIC and the Sodium phosphate dibasic of about 0.3wt% to about 1.5wt%.

Biocide

Antifreeze/anti-icing product can optionally comprise one or more biocides.Some non-limitative examples of suitable biocide comprise: sodiumazide; Quaternary ammonium compound (for example, 2-methyl-4,5-trimethylene-4-isothiazoline-3-ketone; N-alkyl dimethyl benzyl ammonium X ^-[wherein the carbon number of alkyl is C _12-18]; N-alkyl trimethyl ammonium X ^-[wherein the carbon number of alkyl is C _12-18]; Dialkyl dimethyl ammonium X ^-[wherein the carbon number of alkyl is C _12-18]; Octyl-decyl Dimethyl Ammonium X ^-[X wherein ^-Be Cl ^-, Br ^-, I ₃ ^-, HCO ₃ ^-, CO ₃ ^2-, phosphate radical, phosphonate radical, OH, carboxylate radical, poly carboxylic acid root]); Phenylformic acid M ⁺Salt (M wherein ⁺Be Na ⁺, K ⁺, NH ₄ ⁺Alkyl dimethyl benzyl ammonium chloride; With alkyl dimethyl benzyl/ethylbenzylammonium chloride.

Fire retardant

Antifreeze/anti-icing product can also optionally comprise one or more fire retardants and/or corrosion inhibitor.Some common additives that are used as fire retardant and corrosion inhibitor comprise tolyl-triazole sodium and 1H-benzotriazole, methyl.

Vinyl pyrrolidone

In other embodiments of the present invention, deicing fluid/anti-freeze fluid comprises aforesaid bio-based frostproofer, with molecular weight be about 10,000 to about 700,000 vinyl pyrrolidone polymer and water combination." vinyl pyrrolidone polymer " is meant the homopolymer or the multipolymer of vinyl pyrrolidone or derivatives thereof.The suitable derivatives of ethenyl pyrrolidone polymkeric substance comprises alkylating polyvinylpyrrolidone, the 2-methyl.Preferably, vinyl pyrrolidone polymer is a polyvinylpyrrolidone.

The preferred molecular weight of vinyl pyrrolidone polymer is about 10,000 to about 700,000, preferably is not more than about 360,000.The vinylpyridine that it is believed that higher molecular weight is pressed against the alkane ketone polymer and can be produced the deicing fluid/anti-freeze fluid with more undesirable character, antifreeze especially for aircraft and runway.

Antifreeze/anti-icing product can comprise the vinylpyridine of any appropriate amount and press against the alkane ketone polymer.Usually, this product comprise about 5% or lower vinylpyridine press against the alkane ketone polymer, and be generally about 0.1% to about 3%.

Advantageously, vinylpyridine is pressed against the alkane ketone polymer often plays thickening material and tensio-active agent in fluid effect.Therefore, the product with required character can use the component of minimal number to be produced.Yet optionally, this product also can comprise other composition such as antioxidant and/or second surface promoting agent.

Water-containing solvent

Antifreeze/anti-icing product can also comprise the water-containing solvent (being water) of any appropriate amount, is generally about 30% to about 70 weight %.What note is that the percentage ratio of the composition that this paper provides is based on the ready-made product that can use.Product of the present invention can also concentrate formulation form provide, in this case, the percentage ratio of water-containing solvent reduces (for example enriched material may comprise about 5% to about 20% water) and the percentage ratio of other material will correspondingly increase.

Tinting material or dyestuff

Antifreeze/anti-icing product can also comprise the tinting material or the dyestuff of any appropriate amount, is generally maximum 0.25 volume % of preparation.

The ester class

The ester class can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of 3 propylene glycol preparation comprises all suitable compound monoesters and diester class.Special some esters that generate comprise propylene glycol SUNSOFT Q-182S and monostearate, propylene glycol dilaurate ester and January silicon ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Miscellaneous additive

Composition also can comprise multiple other functional ingredient, such as UV inhibitor, odor improvers, stablizer or the like.Each of these components account for usually total composition weight less than 1.0%.

In concrete the application, because some management or industrial principle, certain embodiments of the present invention are particularly preferred.For example, in aircraft antifreeze and/or anti-icing, preferably use Bio-PDO, the deicing fluid of water and/or anti-freeze fluid; Bio-PDO and other the biological origin glycols and the mixture of water, or Bio-PDO, the mixture of the reagent of petrochemical industry origin glycols and water beetle base glucosides; The mixture of sorbyl alcohol and Bio-PDO; Or methylglycoside, the mixture of sorbyl alcohol and Bio-PDO and Sodium.alpha.-hydroxypropionate and/or potassium lactate.

Antifreeze and/or anti-icing for runway can preferably be used following frostproofer and/or deicing agent: Sodium.alpha.-hydroxypropionate; Potassium lactate; The mixture of Sodium.alpha.-hydroxypropionate and potassium lactate; The organic compound of hydroxyl and Sodium.alpha.-hydroxypropionate, potassium lactate and/or potassium acetate and Bio-PDO combination; The mixture of Sodium.alpha.-hydroxypropionate and/or potassium lactate and potassium acetate; Or salt of wormwood and Bio-PDO.

Preceding fruit and all if trees of vegetables or grape vine are antifreeze and/or anti-icing for gathering in the crops, and can preferably use organic compound and Bio-PDO and the particularly Lactated frostproofer of organic acid salt and/or the deicing agent of hydroxyl.

Antifreeze and anti-icing compositions of the present invention can comprise any suitable natural component.Natural component comprise any form or function on the composition of the natural or natural origin similar to above-mentioned any composition of enumerating.

Food compositions

Food compositions of the present invention comprises food or the food component of being made up of one or more food ingredients.In addition, food compositions comprises human food, moves to the material of food, beverage, pet food, and animal feedstuff compositions from the goods of contacting foodstuff.

" food ingredient " comprises any composition that can be used in the food compositions.Preferred this composition is suitable food grade composition; It can be used as food ingredient and is produced and handles; And the amount that this composition adds in the food is no more than predetermined physics, nutrition or the required reasonable amount of other special effect of realization in the food.

Food compositions of the present invention can comprise the Bio-PDO of 0.1wt% to 100wt%, and more preferably from about 2wt% is to the Bio-PDO of about 97wt%.Typical food products composition of the present invention can comprise 2% to 97% Bio-PDO and one or more compositions of 3% to 98%.

In food compositions of the present invention, Bio-PDO can be an anti-caking agent, free-flow agent (free-flow agent), antioxidant, dough reinforcer, emulsifying agent, emulsifier salt, seasonings, seasoning auxiliary, formulation aid, water retention agent, processing material, solvent, carrier, stablizer, thickening material, tensio-active agent, and/or texturizers.

When relating to Bio-PDO doing in food compositions of the present invention, they are suitable for the time spent to give a definition.

" anti-caking agent and free-flow agent " be construed as usually be added to finely powdered or crystalline food in to prevent caking, become the material of piece or reunion.

" antioxidant " be construed as usually by postponing since oxidation produce go bad, become sour or the material of food is preserved in variable color.

" dough reinforcer " is construed as usually and is used to improve starch and gluten, thereby obtain the material of more stable dough, comprise the suitable effect that national academy of sciences (the National Academy ofSciences)/National Research Council (National Research Council) is enumerated that produces under " dough conditioner " title.

" emulsifying agent and emulsifier salt " is construed as the surface tension of component in mutually of improving emulsion usually with the dispersion that forms homogeneous or the material of emulsion.

" seasonings and seasoning auxiliary agent " is construed as usually and is added to give or to help to give the taste of food or the material of fragrance.

" formulation aid " is construed as usually and is used to promote or produce the required physical condition of food or the material of quality, comprises carrier, tackiness agent, filler, softening agent, film forming agent and film-making auxiliary agent etc.

" water retention agent " is construed as the material that is incorporated in the food with the retention that promotes moisture usually, comprises moisture retention agent and antidusting agent.

" processing aid " is construed as usually as producing auxiliary agent to increase food or the magnetism of food component or the material of practicality, comprises finings, clouding agent, catalyzer, flocculation agent, flocculating aids and crystallization inhibitor etc.

" solvent and carrier " is construed as the material that is used to extract or dissolve other material usually.

" stablizer and thickening material " is construed as usually and is used to produce viscous solution or dispersion to produce main body, to improve the material of stickiness or stable emulsion, comprises suspending agent and rheology modifier, setting agent, jelling agent and expanding material etc.

" tensio-active agent " is construed as the material that is used to improve the liquid foodstuff component surface properties that is used for many effects usually, except emulsifying agent, but comprise solubilizing agent, dispersion agent, sanitising agent, wetting agent, the rehydration toughener, beat foam (whipping) agent, pore forming material and defoamer etc.

" texturizers " is construed as the outward appearance that influences food or the material of sensation usually.

Food ingredient

As mentioned above, in preferred embodiments, it is of the present invention 1 that food compositions of the present invention comprises, ammediol and at least a food ingredient.It below is the non restrictive description that can be used for the composition of food compositions of the present invention.

The center (CFSAN) that FDA (FDA) is used for food safety and applied nutrition has kept database (" EAFUS:A Food Additive database "; Http:// vm.cfsan.fda.gov/～dms/eafus.html) be in the program of carrying out that is known as Priority-based Assessment of Food Additives (PAFA).PAFA comprises and surpasses 2000 the medicine that is directly joined the material in the food, chemistry and toxicology information, comprising the direct additive of conduct by the U.S. FDA management, " inferior " directly and the material of color additives, and generally recognized as safe (GRAS) and the material formerly checked and approved.In addition, this database only comprises about medicine and chemical information less than 1000 this materials.Surpassing 3000 total material constitutes together to be commonly referred to as in the U.S. and is added into " all things " (EAFUS) inventory of (Everything Added to Food in the United States) in the food.Contained all compositions of in EAFUS, enumerating and can be used as composition in the food compositions of the present invention, and those skilled in the art can easily be identified for the proper composition of certain food.Above-mentioned EAFUS foodstuff additive database is incorporated this paper into as a reference in full.

The EAFUS inventory of material comprise directly be added in the food by FDA approval as foodstuff additive or the composition that is listed or confirms as GRAS.Yet it only comprises all part inventories that in fact can be joined the food ingredient in the food legally, because according to federal law, some compositions can rely on the GRAS regulation of independently being formulated by FDA to be added in the food.This inventory comprises many but is not the independently material identified of GRAS of whole experience.Please refer to GRAS bulletin inventory about the information of GRAS bulletin program.Additional Information about the situation of food and color additives can obtain from the Food Additive Status List or the ColorAdditive Status List (former title Appendix A of the Investigations OperationsManual).

Below general introduction is direct come and the bread and cheese composition that enumerated some kind of copy from EAFUS foodstuff additive database, some examples of their using method and the title that can find on Product labelling.Some additive application targets are above one.

The layout of following composition inventory is as follows:

The composition classification

The composition function

The food classification

The composition example

Sanitas

Prevent that food is because of bacterium, mould, fungi or zymic corruption (biocide); Slow down or prevent the change of color, local flavor or quality or delay become sour (antioxidant); Keep fresh

Jam and jelly, beverage, baking goods, bacon, oil and oleomargarine, cereal, seasonings, snack food prod, fruit and vegetables

Xitix, citric acid, Sodium Benzoate, calcium propionate, SODIUM ISOVITAMIN C, Sodium Nitrite, calcium sorbate, potassium sorbate, BHA, BHT, EDTA, tocopherol (vitamin-E)

The sweet taste material

Increasing has or does not have other caloric sweet taste material

Beverage, baking goods, candy, edible (table-top) sugar, surrogate, many processed foods

Sucrose (sugar), glucose, fructose, sorbyl alcohol, N.F,USP MANNITOL, maize treacle, high-fructose corn syrup, asccharin, aspartame, trichlorogalacto-sucrose, Sunnett, knob sweet (neotame)

Colour additive is arranged

Compensation is owing to the color loss that is exposed under light, air, temperature limitation, moisture and the storage condition; Correct changing naturally of color; Strengthen naturally occurring colour; Provide color to colourless and " amusement " food

Many processed foods (toffee, snack food prod oleomargarine, cheese, soft drink, jam/jelly, gelatin, pudding and cake filling)

FD﹠amp; C Blue Nos.1 and 2, FD﹠amp; C Green No.3, FD﹠amp; C Red Nos.3 and 40, FD﹠amp; C Yellow Nos.5 and 6, Orange B, Citrus Red No.2, Arnotto extract, β-Hu Luobusu, grape skin color, cochineal extract or famille rose, oleoresin capsicum, caramel colour, fruit and plant juice, Stigma Croci (note: immune color additives does not require by the title on the label to be represented, but can show as the color or the color of adding simply)

Seasonings and spices

Increase specific seasonings (natural and synthetic)

Pudding and cake filling, gelatin dessert compound, cake mix, salad cream, toffee, soft drink, ice-creams, BBQ sauce

Natural seasonings, artificial flavors and spices

Flavour enhancer

Strengthen the local flavor (not needing to provide their independent local flavor) in the food Already in

Many processed foods

Monosodium glutamate (MSG), hydrolysing soybean protein, autolyzed yeast extract, Sodium guanylate or inosine acid disodium

Fat substitutes (with the component that is used to replace fatty preparation)

In few fat foods, provide required quality and cream " mouthfeel "

Baking goods, seasonings, frozen dessert, candy, cake and assorted dessert, milk-product

Sucrose polyester (Olestra), Microcrystalline Cellulose (cellulose gel), carrageenin, poly-dextrin, food treated starch, particulate Protalbinic acid matter, guar gum, xanthan gum, Lactalbumin concentrate

Nutritive substance

Replenish the VITAMIN and the mineral substance (enrichment) of forfeiture in the processing, the nutritive substance that interpolation may lack (reinforcement) in food

Flour, bread, cereal, rice, macaroni, oleomargarine, salt, breast, fruit beverage, energy bar, instant breakfast beverage

Thiamine hydrochloride, riboflavin (Wei ShengsuB2), nicotinic acid, niacinamide, folate or folic acid, β-Hu Luobusu, potassiumiodide, ferrous sulfate, alpha-tocopherol, xitix, vitamins D, amino acid (L-tryptophane, L-Methionin, L-leucine, L-methionine(Met))

Emulsifying agent

Make each composition mix glibly, prevent to separate.The stability that keeps emulsifying product reduces viscosity, crystallization control, and the maintenance composition is disperseed and helps product more easily to dissolve

Salad cream, peanut butter, chocolate, oleomargarine, frozen dessert

Soybean lecithin, monoglyceride and triglyceride, yolk, polysorbate, Stearinsaeure sorbitan ester

Stablizer and thickening material, tackiness agent, texturizers

Reach uniform quality, improve " mouthfeel "

Frozen dessert, milk-product, cake, pudding and gelatin mixture, seasonings, jam and jelly, soy sauce

Gelatin, pectin, guar gum, carrageenin, xanthan gum, whey

PH regulator agent and souring agent

Control acidity and basicity prevent corruption

Beverage, frozen dessert, chocolate, low-acid canned food, saleratus

Lactic acid, citric acid, ammonium hydroxide, yellow soda ash

Raising agent

Promote the rising of baking goods

Bread and other baking goods

Fermentation soda, mono-calcium phosphate, lime carbonate

Anti-caking agent

Keep the unrestricted flow of powdery-food, prevent moisture absorption

Salt, saleratus, the sugar of confectioner

Calucium Silicate powder, ferric ammonium citrate, silicon-dioxide

Wetting agent

Keep moisture

Shredded coconut, marsh-mallow (marshmallows), soft toffee, preserved fruit

Glycerine, sorbyl alcohol, propylene glycol

The yeast nutrition material

Improve yeast growth

Bread and other baking goods

Calcium sulfate, ammonium phosphate

Dough reinforcer and conditioning agent

Obtain more stable dough

Bread and other baking goods

Ammonium sulfate, Cellmic C 121, L-halfcystine

Solidifying agent

Keep fragility and soundness

The fruits and vegetables of processing

Calcium chloride, calcium lactate

Zymin

Carry out modified protein, polysaccharide and fat

Cheese, milk-product, meat

Enzyme, Sumylact L, papoid, rennet, rennin,

Gas

As propelling agent, inflation or generation carbonic anhydride are saturated

Oil cooking spray agent is beaten butterfat, carbonated beverages

Carbonic acid gas, Nitrous Oxide

In addition, ester can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of 3 propylene glycol preparation comprises all suitable compound monoesters and diester class.Special some esters that generate comprise propylene glycol SUNSOFT Q-182S and monostearate, propylene glycol dilaurate ester and January silicon ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Food compositions of the present invention can comprise any suitable natural composition.Natural component comprise any form or function on the composition of the natural or natural origin similar to above-mentioned any composition of enumerating.

Food and drink are used

Below be the non-limiting inventory of food compositions of the present invention, it is of the present invention 1 that this food compositions comprises, ammediol:

Herbaceous plant, seed, spices, seasonings, mixture, extract, and food flavouring comprise all natural and synthetical spices, mixture and seasonings comprise the Bio-PDO of about 97 weight % at most.

Preserved fruit and frost sugar comprise the frost sugar of candy and perfuming, marsh-mallow, cure chocolate and adustion, blocky, hard candy, maple sugar, powder sugar and raw sugar, comprise about 24% Bio-PDO at most.

Alcoholic beverage comprises malt beverage, wine, and liquor and cocktail compound comprise the Bio-PDO of about 5 weight % at most.

Nut and nut products comprise complete woody nut or the woody nut of band shell, peanut, and coconut and nut and peanut are broken, comprise the Bio-PDO of about 5 weight % at most.

Sweet dairy products of refrigerated and mixture comprise ice-creams, iced milk, and ice cream and other freezing sweet dairy products and special product comprise the Bio-PDO of about 2.5 weight % at most.

Baking goods and cure compound comprises all be ready to eat and products that be ready to cure, and flour, and mixture are needs preparation persons before service, comprise the Bio-PDO of maximum about 2 weight %.

Nonalcoholic drink and beverage matrix only comprise teas special or perfuming, soft drink, and for coffee, and the gelatin beverage of fruit and plant perfuming, comprise the Bio-PDO of about 2 weight % at most.

Breakfast cereals comprises instant food and fast food and general hot cereal, comprises the Bio-PDO of about 2 weight % at most.

Cheese comprises curdled milk and whey cheese, and cream is natural, fractionated, processing, coating, soak account for and other cheese, comprise the Bio-PDO of about 2 weight % at most.

Chewing gum comprises all forms, comprises the Bio-PDO of about 2 weight % at most.

Coffee ﹠ tea comprises general type, and decaffeinated type and instant type comprise about 2% Bio-PDO at most.

Pungent seasonings and seasonings comprise common seasoning sauce and coating, olive, and pickles, and seasonings, but do not comprise spices or herbaceous plant, comprise the Bio-PDO of about 2 weight % at most.

The milk-product analogue comprises non-breast milk, freezing or liquid cream, and synthetic cream (coffeewhiteners) waters and drenches material and other non-milk product, comprises the Bio-PDO of about 2 weight % at most.

Egg-products comprise liquid, and are freezing, or egg powder and egg dish prepared therefrom, that is, egg roll, egg Foo Yung, egg salad and refrigerated multicourse egg meals, but do not comprise bright egg, comprise the Bio-PDO of about 2 weight % at most.

Fatty and oily, comprise oleomargarine, be used for the seasonings of salad, butter, salad oil, shortening and cooking oil comprise the Bio-PDO of about 2 weight % at most.

Fishery product comprises full preparation entree, salad, and appetizer, freezing multicourse meal and comprise the coating of fish, shellfish and other Shui nationality animal, but do not comprise fresh fish, comprise the Bio-PDO of about 2 weight % at most.

Bright egg comprises and cooks egg and only from the egg dish of bright shell egg preparation, comprise the Bio-PDO of about 2 weight % at most.

Fresh fish only comprises fresh and the refrigerated fish, and shellfish and other Shui nationality animal comprise the Bio-PDO of about 2 weight % at most.

Fresh fruit and fruit juice only comprise unprocessed fruit, citrus, and melon, and berry and from them be in " nectar (ades) " and the punch of preparation comprise the at most Bio-PDO of about 2 weight %.

Fresh meat only comprises beef fresh or home freezing or veal, pork, and the fresh meat of lamb meat or mutton and family manufacture comprises dish, salad, appetizer, or sandwich spread prepared therefrom comprise the Bio-PDO of about 2 weight % at most.

Bright bird only comprises the bright poultry of poultry fresh or home freezing or hunting bird and family manufacture comprising dish, salad, and appetizer, or sandwich spread prepared therefrom comprise the Bio-PDO of about 2 weight % at most.

Fresh vegetables, tomato and potato only comprise fresh and vegetables family manufacture, comprise the Bio-PDO of about 2 weight % at most.

Fruit and ice cream comprise all refrigerated fruit and ice cream, comprise the Bio-PDO of about 2 weight % at most.

Gelatin, pudding and cake filling comprise the gelatin dessert of perfuming, pudding, custard, parfait (parfaits), cake filling and gelatin substrate salad comprise the Bio-PDO of about 2 weight % at most.

Cereal product and pasta comprise macaroni and noodle product, and rice dishes and refrigerated multicourse meals do not contain meat or vegetables, comprise the Bio-PDO of about 2 weight % at most.

Meat soup and dip comprise all meat dip and meat soup, and tomato-sauce, newborn sauce, and mayonnaise and special dip comprise the Bio-PDO of about 2 weight % at most.

Hard candy and cough drops comprise the sugar of all hard types, comprise the Bio-PDO of about 2 weight % at most.

Jam and jelly, family manufacture, only comprise the jam of family manufacture, jelly, puree, jam and sweet coating comprise the Bio-PDO of about 2 weight % at most.

Jam and jelly, commercially available, only comprise the jam of commercial processing, jelly, puree, jam and sweet coating comprise the Bio-PDO of about 2 weight % at most.

Meat product comprises all meat and contain the meat dish, salad, and appetizer, freezing multicoursemeat meals and by commerce processing or use and commercially carry out the sandwich composition of family manufacture through pretreated meat comprises the Bio-PDO of about 2 weight % at most.

Breast, full milk and skimming milk only comprise full milk, low fat milk and degreasing liquid breast comprise the Bio-PDO of about 2 weight % at most.

Milk-product comprise perfuming breast and city milk, and milk powder waters and drenches breast, snack dips, and coating, unit weight control milk beverage and other milk-derived product comprise the Bio-PDO of about 2 weight % at most.

Plant protein prod comprises national academy of sciences/National Research Council's " plant protein of reconstruct " classification, and meat, fowl and fish surrogate, and analogue and the extender product of being made by plant protein comprise the Bio-PDO of about 2 weight % at most.

Poultry product comprises all birds and the dish that contains bird, salad, appetizer, freezing multicourse poultry meals and by commerce processing or use and commercially carry out the sandwich composition of family manufacture through pretreated bird comprises the Bio-PDO of about 2 weight % at most.

The fruit and the fruit juice of processing comprise the fruit of all commercial processing, citrus, berry, and mixture; Salad, juice and juice punch, enriched material, dilution, " nectar " and beverage surrogate prepared therefrom comprise the Bio-PDO of about 2 weight % at most.

The vegetables and the plant juice of processing comprise the vegetables of all commercial processing, vegetable dish, and freezing multicourse vegetable meals and plant juice and mixture comprise the Bio-PDO of about 2 weight % at most.

Snack food prod comprises section, and pretzel (pretzels) and other novel snack comprise the Bio-PDO of about 2 weight % at most.

Soft sweets comprises candy bar, chocolate, and the milk chocolate soft sweets, mint and other are chewed or oagat (nougat) sugar comprises the Bio-PDO of about 2 weight % at most.

Soup, family manufacture, comprise meat, fish, bird, the family manufacture soup of plant and combination comprises the Bio-PDO of about 2 weight % at most.

Soup and powder comprise the meat of commercial preprocessing, fish, and bird, the soup and the powder of plant and combination comprise the Bio-PDO of about 2 weight % at most.

Sugar, white, granulous only comprises white sugar, comprises the Bio-PDO of about 2 weight % at most.

The sugar surrogate comprises granulous, liquid and compacting loaf sugar surrogate, comprise the Bio-PDO of about 2 weight % at most.

Sweet sauce waters and drenches material and syrup, comprises chocolate, berry, and fruit, the sweet sauce of maize treacle and maple drenches material with watering, and comprises the Bio-PDO of about 2 weight % at most.

Industrial application

1 of biology origin, ammediol also can be used for industry that biological degradability wherein paid close attention to and other application.The example of industrial application comprises especially: agricultural, automobile, coating, paint, printing ink, building and casting, mining, oil, medicine plastics, paper pulp and paper, rubber, synthetic lubricant, weaving and fiber, water treatment and cryopreservation or the like.

In agricultural application, Bio-PDO can finally use as agricultural chemicals (weedicide, insecticide, mycocide), and fertilizer works the effect of irrigating auxiliary agent and/or agricultural chemicals (emulsifying agent, spreader-sticker, sticking agent, and whipping agent) in animal-feed and the soil improvement agent.The general quantity of Bio-PDO in this composition can be about 0.1% to about 80 weight %.

In automobile was used, Bio-PDO can use as the vehicle washing final, plays tensio-active agent, the effect of solvent or thickening material in waxing and the polishing.The general quantity of Bio-PDO in this composition can be about 0.1% to about 50 weight %.

In coating and paint application, Bio-PDO is finally using as varnish, biocide, and medicine, weaving can play solvent in the rubber etc., stablizer, the effect of dispersion agent or antifreezing agent.The general quantity of Bio-PDO in this composition can be about 1% to about 50 weight %.

In printing ink was used, Bio-PDO can play emulsifying agent, polymerizing agent, stablizer, the effect of dispersion agent and/or wetting agent final the application such as printing with in tattooing.The general quantity of Bio-PDO in this composition can be about 1% to about 50 weight %.

In mining is used, but Bio-PDO super fatting agent in finally using such as drilling well and hydraulic liquid, the effect of solvent or wetting agent.The general quantity of Bio-PDO in this composition can be about 1% to about 75 weight %.

In oil was used, Bio-PDO was finally using such as drilling fluid, and oil production can play siccative in well cementation and the well stimulation (stimulation), emulsifying agent, demulsifying compound, corrosion inhibitor, lubricant, tensio-active agent, the effect of sterilant and/or defoamer.The general quantity of Bio-PDO in this composition can be about 0.5% to about 50 weight %.

In medicinal application, Bio-PDO can play emulsifying agent, stablizer, the effect of solvent or biocide in finally using such as pharmaceutical carrier (tablet, capsule, liquid, glue class).The general quantity of Bio-PDO in this composition can be about 0.5% to about 95 weight %.

In paper pulp and paper application, Bio-PDO can play emulsifying agent, boiling, deinking, froth breaking, sterilant, solubilizing agent, the effect of dispersion agent final the application in handling and processing.The general quantity of Bio-PDO in this composition can be about 0.1% to about 5 weight %.

In synthetic lubricant was used, Bio-PDO was in the final compressor of using such as engine, hydraulic efficiency system, oil drilling, metal working fluid, roller oil, wire rod is extruded, can play sanitising agent, corrosion inhibitor, or the effect of lubricant in Medium and Heavy Plate Rolling and the tinsel processing.The general quantity of Bio-PDO in this composition can be about 0.5% to about 50 weight %.

In water treatment applications, Bio-PDO is finally using such as agricultural, paper pulp and paper, and oil production, personal care can play biocide in sanitising agent or the like, sterilant, the effect of tensio-active agent or foam control agent.The general quantity of Bio-PDO in this composition can be about 0.1% to about 50 weight %.

Bio-PDO works as wetting agent or with ester-formin in such as the application below for example; Agricultural application increases the absorbed dose of promoting agent, keeps flexibility in the tobacco operation, and the formation of water-retentivity and dust minimizes, in the printing ink application with in drug transdermal is used; As the solvent that is used for the polyvinyl alcohol spinning; As the paint remover of low VOC, the lubricant that spinning is used as synthon; With mold release solution as electron device; As at the production of Sweet natural gas and the dehydration liquid desicoant between the delivery period.

In coating composition, the glycols component is because the slow and normally compatilizer of its vaporator rate, reactive thinner or improved application feature.Exemplary coating composition includes but not limited to water base (latex) building coats, particularly semi-gloss coating.The amount that glycols is present in the above-mentioned coating composition is that corresponding field those of ordinary skill is known, is generally maximum about 20 weight % of total composition weight.The exemplary formulations of emulsion paint preparation can include but not limited to following component: the glycols of 1 to 20 weight %, the latex emulsion of 20 to 60 weight %, the filler of 0 to 30 weight % and maximum 20% following additive: coalescing agent, tensio-active agent, defoamer, stablizer, sterilant and thickening material.

Bio-PDO also can be used in some biodegradable plastics application.

Bio-PDO can further be used as low toxicity, and is vitrified, the antifreeze material of the cell/tissue/organ of biological origin (being used for the people, animals and plants).

The ester class can play the effect of above-mentioned many compositions.Although those skilled in the art can determine easily which ester class is suitable for the required effect that provides specific most, what specify is that ester class used among the present invention can comprise that use organic carboxyl acid class is from 1 of biology origin, the ester class of 3 propylene glycol preparation comprises all suitable compound monoesters and diester class.Special some esters that generate comprise propylene glycol SUNSOFT Q-182S and monostearate, propylene glycol dilaurate ester and January silicon ester, propylene glycol dioleate and monooleate, propylene glycol two valerates and a valerate, a propylene glycol dicaprylate and an octanoate, propylene glycol two myristinates and mono-myristate, propylene glycol dipalmitate and monopalmitate, propylene glycol Er docosoic ester and Yi docosoic ester, propylene glycol adipic acid ester, propylene glycol maleic acid ester, propylene glycol dioxalic acid ester, the propylene glycol dibenzoate, propylene-glycol diacetate, and all mixtures.

Industry group compound of the present invention can comprise any suitable natural composition.Natural component comprise any form or function on the composition of the natural or natural origin similar to above-mentioned any composition of enumerating.

Disclosed herein and claimed all compositions and method can need not over-drastic test practice and carry out according to the disclosure.Although composition of the present disclosure and method are described with regard to its preferred embodiment, but those skilled in the art obviously can change composition and method, and can change aspect the step neutralization procedure order of methods described herein, and do not break away from notion of the present invention, spirit and scope.More particularly, obviously some reagent that chemistry is relevant can replace reagent as herein described, and obtains same or analogous result simultaneously.Those skilled in the art conspicuous all these similarly substitute and change is considered to be in as the defined spirit of the present invention of claim, in scope and the notion.

Embodiment

The present invention further describes in following examples.Know very much these embodiment, although expression the preferred embodiments of the invention only provide with exemplary approach.From top discussion and these embodiment, those skilled in the art can determine preferred feature of the present invention, and under the condition that does not break away from the spirit and scope of the present invention, can carry out multiple changes and improvements so that it is fit for various uses and condition to the present invention.

Embodiment 1

Renewable based, biodegradable type 1 in cosmetic emulsions, ammediol

Composition: Weight %

The A phase

Deionized water 61.34

EDTA four sodium 0.10

Bio-PDO 5.00

Carbopol 980 (2% solution) 10.00

The B phase

2 5.00

165 2.50

Stearic acid XXX 2.50

Spermaceti/stearyl alcohol 0.50

Polydimethylsiloxane DC 200-100 1.00

The C phase

NaOH (20% solution) reaches Ph 7.0-7.5 1.06 in right amount

The D phase

Germaben II 1.00

Mix the A phase at 75 ℃, mix the B phase at 75 ℃.With B be added to A mutually in.Then C is added to A/B mutually in.Then A/B/C is cooled to 40 ℃ mutually, adds the D phase then.With C Ph is adjusted to 7.0-7.5.The preparation of producing is pure white and obvious stable emulsion.

Result-Ph7.38, the viscosity under 20RPM is 12000cps.

Checked baking oven stability, it is acceptable that the result is considered to.

Also checked freeze/thaw stability.Freeze/thaw stability is considered to acceptable.

Contain 1 of biology origin, the viscosity of the cosmetic emulsions of ammediol equates with (12600cps) of propylene glycol, and than (6000cps) or the 2-methyl isophthalic acid of 1,3 butylene glycol, the height of (9600cps) of ammediol.

Embodiment 2

Renewable based, biodegradable type 1 in face and hand usefulness transparent lotion, ammediol

Composition: Weight %

Deionized water 66.20

Bio-PDO 16.00

Ritasail 190 (RITA) (dimethicone copolyol) 2.00

((sodium 3.80 for the caproyl Sodium.alpha.-hydroxypropionate for 122A (RITA)

Caproyl lactylate) 21.1% the aqueous solution)

ESY (Rhodia) (polyoxyethylene lauryl ether 4.00

The aqueous solution of sodium sulfate 26%)

Germaben II (ISP/Sutton) (propylene glycol, N-(hydroxyl first 1.00

Base)-and N-(1, the two methylols-2 of 3-, 5-dioxy-4-imidazolidine

Base)-and N '-(methylol) urea, methyl p-hydroxybenzoate and to hydroxyl

Propyl benzoate)

The aqueous solution 1.00 of EDTA four sodium 5%

22 (ISP/Rohm ﹠amp; Haas) (acrylate/stearyl 5.00

Polyoxyethylene (20) ether metacrylic acid ester multipolymer 25% water-soluble

Liquid)

Trolamine 1.00

Spices is an amount of

Process: each composition merges with listed order.

Character: Ph:7.0, viscosity: 6,780cps

Embodiment 3

Renewable based, biodegradable type 1 in hand and health usefulness creme, ammediol

Composition: Weight %

Deionized water 75.49

PCG 10(Amerchol) 0.20

EDTA trisodium (Universal Preserv-A-Chem) 0.10

Bio-PDO 6.50

Refining (RITA) (shea oil) 2.00

60(Uniqema) 4.00

52S(Uniqema) 0.50

Stearic acid diol ester (Stepan) 2.00

DC SF 200/350(Dow Corning) 4.00

Wickenol 111 (Stepan) 3.00

Vitamin A Palmitate 1.7 M.I.U/Gram (Roche) 0.01

Aloe gel (Bio-Botanica) 0.50

Fructus Cucumidis sativi extract (Bio-Botanica) 0.50

Semen Ginkgo extrac (Bio-Botanica) 0.50

Red clover extract (Bio-Botanica) 0.50

(Bio-Botanica) 0.20

Process: under agitation will

PCG 10 is distributed in the deionized water.Stir and add EDTA trisodium and Bio-PDO down ^TMAnd be heated to 80 ℃.Adding back seven also continues to stir up to becoming homogeneous.Remove thermal source and make its cooling,, add Aloe gel, Fructus Cucumidis sativi extract, Semen Ginkgo extrac and red clover extract at 30 ℃.Add And stir up to homogeneous.

Embodiment 4

Renewable based, biodegradable type 1 in humidification body care creme, ammediol

Composition: Weight %

The A phase

A6 (BASF) (spermaceti/stearyl alcohol polyoxyethylene 2.0

(6) ether)

A25 (BASF) (spermaceti/stearyl alcohol polyoxyethylene 2.0

(25) ether)

Raisin seed oil 6.0

Glyceryl stearate SE 3.0

Spermaceti/stearyl alcohol 2.0

Polydimethylsiloxane 0.5

Luvitol EHO (BASF) (sad spermaceti/stearic alcohol ester) 8.0

2004 (Merck KgaA) (1, ammediol, BHT, 0.1

Ascorbyl palmitate, stearin and Citric Acid)

The B phase

Bio-PDO 5.0

Edeta BD (BASF) (EDTA disodium) 0.1

D-panthenol USP (BASF) 1.0

Sanitas is an amount of

Water reaches 100 in right amount

The C phase

Luvigel EM (BASF) (caprylic/capric triglyceride and vinylformic acid 1.0

The sodium multipolymer)

The D phase

Vitamin e acetate (BASF) 0.5

Perfume compound is an amount of

Process: heating A arrives about 80 ℃ mutually with B mutually.Stir B and enter the middle mutually homogenization simultaneously of A mutually.Add C in phase A/B and homogenization once more.Be cooled to about 40 ℃, add D also homogenization at once mutually.

Character: viscosity: be approximately 25,000mPas (brookfield viscosity); PH value: 6.5

Embodiment 5

Renewable based, biodegradable type 1 in humidification body care creme, ammediol

Composition: Weight %

The A phase

GC7 (BASF) (PEG7-glyceryl-cocounut oil acid esters) 8.0

A-25 (BASF) (spermaceti/stearyl alcohol polyoxyethylene (25) ether) 22.0

WO7 (BASF) (hydrogenated castor oil) 1.0

Bio-PDO 3.0

SF19 (BASF) (PEG8 methylsiloxane) 1.0

The B phase

Water 65.0

The C phase

Sanitas is an amount of

Spices is an amount of

Process: add each composition with said sequence at 80 ℃ and also stir up to homogeneous.Guarantee that each composition dissolves before adding step in the back.Heat B to 80 ℃ and merge mutually with A.Be cooled to 50 ℃.Add spices and sanitas.When as liquid, also place at room temperature in the impouring container.

Embodiment 6

Renewable based, biodegradable type 1 in humidification hand and health usefulness washing lotion, ammediol

Composition: Weight %

The A phase

TA-100 (Goldschmidt) (VARISOFT TA100) 4.75

Crodacol C-70 (Croda) (hexadecanol) 2.00

Penreco Snow White petrolatum (Penreco) (vaseline) 4.00

DC Fluid 200,1,000cst (Dow Corning) (polydimethylsiloxane) 0.25

The B phase

Deionized water is an amount of

IPM (Stepan) (isopropyl myristate) 3.25

Bio-PDO 4.00

The C phase

CI-50(Ondeo Nalco) 3.00

(starch hydroxypropyl trimethyl ammonium chloride)

AA040513 Cucumber (Aryl essence) (spices) 0.25

Sanitas is an amount of

Sodium hydroxide reaches Ph 6 in right amount

Process: in the container that separates, fully stir A mutually with B each composition to 75 mutually ℃.With A be poured into mutually B mutually in; Under this temperature, fully stirred 10 minutes.Remove thermal source and continue to stir and be lower than 40 ℃ up to temperature.Add the C phase component with listed order, between adding, fully stir.Regulate Ph to 6.

Embodiment 7

Renewable based, biodegradable type 1 in humidification washing lotion SPF15, ammediol

Composition: Weight %

The A phase

Stearyl alcohol 2.00

1543 (Uniqema) (palm acid ethyl polyhexamethylene) 5.00

3609 (Uniqema) (triethyl hexanoin) 5.00

60 (anhydrous sorbitol polyoxyethylene (20) ether stearates) 2.00

Isohexadecane 7.50

CT100 (Uniqema) (phenylformic acid C12-C15 alkyl ester 15.00

(with) titanium dioxide (with) poly-oxystearic acid (with) aluminum stearate (with) oxygen

Change aluminium)

The B phase

Distilled water 54.40

2121 (Uniqema) (sorbitan stearate (with) sucrose cocounut oil 2.50

Acid esters)

Monomate RMEA-40 (Viscotrol C alkyd acid amides MEA-sulfo group fourth 0.200

The two acid disodium aqueous solution)

The C phase

Ultra (RT Vanderbilt) (neusilin) 0.80

RD (Nutrosweet Kelco) (xanthan gum) 0.20

Sodium.alpha.-hydroxypropionate 50% 0.40

II (ISP) (propylene glycol (with) (1,3-two 1.00 for N-(methylol)-N-

Methylol-2,5-dioxy-4-imidazolidyl)-N '-(methylol) urea (with) to hydroxyl

The yl benzoic acid methyl esters (with) propylparaben)

Bio-PDO 4.00

Process: heating is B to 80 ℃ under the mild stirring, up to

2121 disperse fully.Add

With Stirring is up to homogeneous.Add the remainder water phase composition, maintain the temperature at 80 ℃.Heat A to 80 ℃.Under vigorous stirring, add A to B/C mutually in.Homogenization two minutes.Cool to room temperature under mild stirring.

Embodiment 8

The skin treatment washing lotion

Composition: Weight %

The A phase

Deionized water 61.7

CG (Kelco) (xanthan gum) 0.2

Bio-PDO 5.0

BSC(Arch Personal Care) 3.0

Jeescreen benzophenone-4 (Jeen) (benzophenone-4) 0.1

Jeechem GMS-165 (Jeen) (stearin (with) PEG-100 tristearin 3.0

Acid esters)

The B phase

Jeesilc IDD (Jeen) (polydimethylsiloxane cross-linked polymer-3 (with) different 10

Dioxane)

Jeesilc 245 (Jeen) (ring first siloxanes) 8.0

Jeesilc 200 MV (100cst) (polydimethylsiloxane) 2.0

NS(Seppic) 4.0

The C phase

Jeesilc 6056 (Jeen) (dimethyl polysiloxane glue) 3.0

Jeecide G-II (Jeen) (propylene glycol (with) N-(methylol)-N-(1, the two hydroxyl first 1.0 of 3-

Base-2,5-dioxy-4-imidazolidyl)-N '-(methylol) urea (with) the para hydroxybenzene first

The acid methyl esters (with) propylparaben)

Arnica montana dried flower preface extract (Botanicals Plus) (arnica rabic) 2.0

Red (the Flamingo Super Red) 1.0 of flamingo spy

The D phase

Jeesorb L-20 (Jeen) (anhydrous sorbitol polyoxyethylene (20) ether laurate) 1.0

Vitamin e acetate (Jeen) (Vitamin E-acetate) 0.5

Spices 0.5

Process: add hot water to 65 ℃.Pre-mixing

With Bio-PDO and join aqueous phase.Stirring is up to dissolving.Other composition of disposable adding A phase also fully stirs.Be cooled to 50 ℃.In the oil phase jar, add Jeesilc IDD, Jeesilc 245 and Jeesilc 200 MV (100cst) also stir up to homogeneous, add

And be stirred to 50 ℃.Use homogenizer, add B to A mutually in and stirred 10 minutes.Be cooled to 40 ℃.Forwarding water screw to stirs.The composition of disposable adding C phase fully stirs in main jar and in each back that adds.Pre-mixing D mutually and join in main jar in secondary container.Thorough mixing.

Embodiment 9

Wide spectrum SPF sun-screening agent

Composition: Weight %

The A phase

Deionized water 57.85

Carbopol 980 (Noveon) (carbomer) 0.30

EDTA disodium (Dow Chemical) 0.10

Bio-PDO 4.00

The B phase

Escalol 557 (ISP) (Ao Xinuo ester (octinoxate)) 7.50

Escalol 567 (ISP) (oxybenzone) 6.00

Escalol 517 (ISP) (avobenzone) 2.00

X-Tend 226 (ISP) (phenylformic acid 2-phenethyl ester) 10.00

141 (ISP) (stearin, behenyl alcohol, palmitinic acid, 4.00

Stearic acid, Yelkin TTS, lauryl alcohol, tetradecyl alcohol and hexadecanol)

The C phase

Deionized water 5.00

Trolamine 99% 0.40

The D phase

Liquapar Optima (ISP) (Phenoxyethanol, methyl p-hydroxybenzoate, 1.25

P-Hydroxybenzoic acid isopropyl ester, p-Hydroxybenzoic acid isobutyl ester and to hydroxyl

Butyl benzoate)

Liquapar Oil (ISP) (p-Hydroxybenzoic acid isopropyl ester, hydroxy-benzoic acid 0.40

Isobutyl ester and butyl p-hydroxybenzoate)

Lexguard O (Inolex) (capryloyl (caprylyl) glycol) 1.00

The E phase

(Lonza) (iodine proyl butyl carbamate) 0.20

Process: merge A each composition in mutually; Stirring is up to all being heated to 75 ℃ in the lump.Merge B each composition in mutually; Be heated to 75 ℃.In homogenization, merge B mutually with A mutually.In homogenization, merge C mutually with A/B mutually.Be cooled to 45 ℃ (heating Lexguard O also is added to LiquaPar Optima) and add the D phase.Add the E phase.Cool to room temperature.The loss of appropriate supplement water-filling.

Character: viscosity: 17,600cps, Ph 6.44

Embodiment 10

The standard sun-screening agent

Composition Weight %

The A phase

Lanolin 5.0

Uniderm Homsal 8.0

White vaseline 2.5

Stearic acid 4.0

Propylparaben 0.1

The B phase

Methyl p-hydroxybenzoate 0.1

Zonon D 0.1

Bio-PDO 5.0

Trolamine 1.0

Purified water USP 74.3

Process: A is heated to 77 to 82 ℃ separately mutually with B mutually, and constant speed stirs simultaneously, up to the contents melting of each several part.Under agitation A is slowly joined mutually B mutually in.Continue to stir emulsion cool to room temperature (15 to 30 ℃) up to forming.Add enough purified water and obtain the 100 standard sun-screening agent preparations that restrain.

Embodiment 11

Water resisting property Tropical Gold Sunscreen SPF 21

Composition: Weight %

The A phase

Deionized water 63.10

NA (Dow) (EDTA disodium) 0.05

Carbopol Ultrez 10 polymkeric substance (Noveon) (carbomer) 0.25

TR-2 polymer-type emulsifying agent (Noveon) 0.15

(acrylate/vinylformic acid C10-30 alkyl ester cross-linked polymer)

Bio-PDO 3.00

The B phase

NeoHeliopan，Type AV(Haarmann & Reimer) 5.00

(methoxy cinnamic acid octyl group ester)

Whitfield's ointment octyl group ester 3.00

BHB (C.P.Hall) (Whitfield's ointment butyl octyl ester) 5.00

1789 (Roche) (avobenzone) 3.00

Procol CS-20-D (Protameen) (spermaceti/stearyl alcohol and spermaceti/stearyl alcohol 1.50

Polyoxyethylene (20) ether)

Crodamol CAP (Croda) (sad spermaceti/stearyl ester) 2.00

Vitamin e acetate (BASF) 0.50

The C phase

Crovol A-70 (Croda) (PEG-60 almond glyceryl ester) 0.50

DC 1401 Fluid (Dow Corning) (polydimethyl silanol and cyclohexyl methyl 1.50

Siloxanes)

Ultrasil Copolyol-1 Silicone (Noveon) (PEG-8 polydimethyl silicon 1.50

Oxygen alkane)

(Clariant) (Phenoxyethanol, methyl p-hydroxybenzoate is to 1.00

Nipagin A, propylparaben, P-hydroxybenzoic acid fourth

Ester and p-Hydroxybenzoic acid isobutyl ester)

Tapioca Pure (National starch) (tapioca (flour)) 4.00

Sodium hydroxide 18% 1.00

UR 450 polymkeric substance (Noveon) 3.95

(solid of PPG-17/IPDI/DMPA multipolymer 38%)

Process: dissolving EDTA disodium is in warm water (～50 ℃).Add carbopol Ultrez10 polymkeric substance and allow drenched about five minutes.Disperse

The polymer-type emulsifying agent also mixed about 15 minutes.Add Bio-PDO ^TMMake A reach mutually～70 ℃.Add about 15% of the mutually required total neutralizing agent of A.Mix the composition of B phase and reach～80 ℃, guarantee the solids component dissolving.Under vigorous stirring, add B to A mutually in.Add PEG-60 almond glyceryl ester.Add polydimethyl silanol and cyclohexyl methyl siloxanes.Add Ultrasil Copolyol-1 organosilicon.After＜60 ℃ of emulsion coolings, add

Add tapioca (flour).Add remaining neutralizing agent.Add UR 450 polymkeric substance.

Ph：7.0-7.5

Viscosity (mPas) ^*: 15,000-21,000

SPF (waterproof) ^*: 21 (in vitro method, 80 minutes. immerse)

Embodiment 12

The sun-proof SPF 20 of water-proof protective

Composition: Weight %

The A phase

Simusol 165 (Seppic) (stearin and PEG-100 stearic acid 3.20

Ester)

S (Seppic) (cocounut oil glucosides and lauric alcohol) 1.30

Isodecyl Neopentanoate 10.00

PVP rabic te multipolymer 5.00

Bio-PDO 5.00

Methoxy cinnamic acid (ethyl hexyl) ester 7.50

Benzophenone-3 2.50

Whitfield's ointment (ethyl hexyl) ester 5.00

Zinc oxide 7.10

The B phase

Sepicalm VG (Seppic) (sodium palmitoyl rabic and water lily 3.00

Immersion liquid

Cyclohexyl methyl siloxanes 5.00

The C phase

EG (Seppic) (sodium acrylate/acryl dimethyl ox sulphur 1.00

Acid ester copolymer, isohexadecane and anhydrous sorbitol polyoxyethylene (20) ether

Oleic acid ester 80)

The D phase

Tromethane is an amount of

EDTA four sodium 0.20

Xanthan gum 0.15

Neusilin 1.00

Water reaches 100 in right amount

The E phase

Sepicide HB (Seppic) (phenoxyethyl alcohol (with) P-hydroxybenzoic acid first 0.30

Ester (with) ethyl p-hydroxybenzoate (with) propylparaben (with) right

Butoben)

Sepicide CI (Seppic) (Imidurea) 0.20

DL-alpha-tocopherol 0.05

Spices 0.30

Process: at 75-80 ℃ of one-tenth fractional melting that makes the A phase, and with zinc oxide be dispersed in the temperature fat mutually in.Silicate and xanthan gum are dispersed in the water up to homogeneous, introduce EDTA and tromethane then.Under violent stirring, add

EG obtains the expansible polymkeric substance in this blend, be heated to 80 ℃ then.Add fatty A mutually to aqueous phase and began homogenization 5 minutes.Begin to cool down and continue homogenization.Introduce Sepicalm VG and cyclohexyl methyl siloxanes at 60 ℃, and homogenization 5 minutes.Under mild stirring, cool off and adding E phase composition under 30 ℃.

Embodiment 13

The hand cold cream

Composition: Weight %

1 phase

Deionized water reaches 100.0 in right amount

Bio-PDO 4.00

GA-70PG ^* 2.86

2 phases

Vaseline 4.00

IPP 3.00

Hexadecanol, NF 2.00

TiO2Sperse 40% solution is at Isoarachidyl neopentanoate 10.00

In, (Collaborative Labs)

3 phases

KCl 0.40

Citric acid is an amount of

Sanitas is an amount of

Amount to 100.00

Process: by adding water, Bio-PDO ^TMWith

GA-70PG ^*The preparation water.Thorough mixing.Begin to be heated to 160 ℉.By the interpolation vaseline,

IPP,

Hexadecanol and TiO2Sperse prepare oil phase.Be heated to 160-165 ℉.Add oil phase to aqueous phase.Emulsification 20-25 minute.Cool to room temperature.Pre-mixing KCl and water also join in the bath.Add sanitas.Regulate Ph to 4.0 if necessary.

Physical properties: Ph 4.0-5.0; Viscosity 2,000-3,000cps.

Embodiment 14

Common oily skin washing lotion

Composition: Weight %

1 phase

Deionized water reaches 100.0 in right amount

Carbopol 934 (BF Goo drich) carbomer 0.15

Bio-PDO 3.00

2 phases

Different n-nonanoic acid octyl group ester 5.00

Dow Corning 200 Fluid (Dow Corning) polydimethylsiloxane 0.10

S 0.50

Hexadecanol, NF 0.50

Kartacid 1890 (Akzo Nobel BV) stearic acid 3.00

3 phases

200 (Dow Corning) EDTA, four sodium 0.10

Trolamine 1.80

Sanitas is an amount of

Amount to 100.0

Process: by adding deionized water in suitable mixing vessel and begin to stir preparation 1 phase.Under good the stirring, add carbopol 934 and do not contain block up to solution with high-speed mixing.Add Bio-PDO ^TMAnd stir.Be heated to 165-170 ℉.Prepare 2 phases in the container separately, and be heated to 170-175 ℉.Under good the stirring, be added to 1 mutually and mixed 30 minutes with 2.Begin to cool down and reach 90 ℉.Each composition that under 110 ℉, adds 3 phases.Stop to cool off and stirring at 90 ℉.

Character: at 25 ℃ viscosity: 2000-5000cps; Ph7.8-8.0.

Embodiment 15

The skin washing lotion of releiving

Composition: Weight %

1 phase

Deionized water reaches 100.0 in right amount

Carbopol 940 (B.F.Goo drich) carbomer 0.20

P-20 (Amerchol) PPG-20 methyl glucose ether 0.14

Bio-PDO 2.25

2 phases

M-20 4.50

S 0.75

653 0.50

Hexadecanol, NF 0.50

Kartacid 1890 (Akzo Nobel BV) stearic acid 2.95

3 phases

Sanitas 0.10

220 (Dow) EDTA, four sodium 0.10

Trolamine 0.25

Amount to 100.0

Process: prepare 1 phase.Under good the stirring, carbopol 940 joined in the deionized water and do not contain block up to solution.Add PPG-20 methyl glucose ether and Bio-PDO ^TMStirring is up to dissolving fully.Be heated to 165 ℉.In independent container, prepare 2 phases.Be heated to 165-170 ℉, under good the stirring, be added to 1 phase (bath under 165-170 ℉) 2.Emulsification 20 minutes begins to cool down under slowly stirring then.The composition that adds 3 phases at 110 ℉.Stop cooling and stirring at 90 ℉.

Character: at 25 ℃ viscosity: 2200-3700cps

Embodiment 16

Colourless wetting Agent for Printing Inks

Composition: Weight %

Aloe gel reaches 100.0 in right amount

Bio-PDO 3.50

Methyl p-hydroxybenzoate 0.15

Carbopol 934 0.50

Alcohol 190 Proof 20.00

PEG 600 ML 1.00

2.00

Spices is an amount of

TEA 88％ 0.8

Glydant is an amount of

Amount to 100.0

Process: with Aloe gel and Bio-PDO ^TMMerge.Begin to mix.Add methyl p-hydroxybenzoate.Stirring is clarified up to solution.Add carbopol 934, stirring does not contain block up to solution.Add alcohol, thorough mixing.Pre-mixing PEG 600 mono-laurates, anhydrous sorbitol polyoxyethylene (20) ether laurate and perfume compound.Join in the batch of material.Thorough mixing.Add Glydant.Add TEA.Solution should be clarifying.

Physical properties: Ph6.0-6.5

Embodiment 17

Hand and health therapeutic washing lotion

Composition: Weight %

1 phase

Deionized water reaches 100.0 in right amount

Bio-PDO 4.00

GA-70PG 18.4

2 phases

Vaseline 4.0

IPP 3.0

Silicone DC-200(350cps) 1.0

Hexadecanol, NF 2.0

3 phases

KCl 0.4

Citric acid is an amount of

Glydant is an amount of

Amount to 100.0

Process: by adding water, Bio-PDO ^TMWith

GA-70PG prepares water.Thorough mixing.Begin to be heated to 160 ℉.By the interpolation vaseline,

IPP, silicone,

Hexadecanol prepares oil phase, is heated to 160-165 ℉.Oil phase is joined aqueous phase.Emulsification 20-25 minute.Begin to cool down.Pre-mixing KCl and water also join in the batch of material of 100-110 ℉.Under 100 ℉, add Glydant.Adjust Ph if needed.Carry out homogenization if needed.

Physical properties: Ph4.0-4.5; Viscosity: 3,000-4,000cps

Embodiment 18

The creme hair conditioner that is used for permanent hair-waving

Composition: Weight %

4 5.00

Bio-PDO 1.50

Panthenol 0.50

Citric acid is an amount of

Deionized water reaches 100 in right amount

Hexadecanol, NF 2.50

PPG-hexadecyl polyoxyethylene (20) ether 1.25

Stearyl alcohol 97 0.75

Spices, Ran Liao ﹠amp; Sanitas is an amount of

Amount to 100.0

Process: add each composition and mix, be heated to 75 ℃ simultaneously, stir, stir and be cooled to 30 ℃ and add spices down up to thorough mixing, sanitas and dyestuff if necessary, with citric acid adjusting Ph to 3-5.

Physical properties: outward appearance: opaque and white liquid; Viscosity: 2000cps

Embodiment 19

Colourless hair conditioner

Composition: Weight %

KP 3.00

CETAC 1.50

Bio-PDO 1.50

Natvosol 0.90

Polyquaternium 10 0.25

Spices, Ran Liao ﹠amp; Sanitas is an amount of

Citric acid is an amount of

Deionized water reaches 100 in right amount

Amount to 100.0

Process: under agitation Natvosol is dispersed in the deionized water up to clarification.Add

KP also stirs up to homogeneous.Slowly add CETAC also stirs up to homogeneous.Polyquaternium-10 is dispersed among the Bio-PDO, and under agitation it is joined in the above-mentioned solution up to clarification.Use citric acid to regulate Ph to 5.5 if necessary.Add spices if necessary, dyestuff and sanitas.

Physical properties: Ph 5.5; Viscosity: 750cps

Embodiment 20

Spary coating type removes the hair conditioner that tangles

Composition: Weight %

Deionized water reaches 100.0 in right amount

Bio-PDO 1.50

KP 1.00

Tensio-active agent 193 (Dow Corning) polydimethylsiloxane copolymer-1 .00

Polyvalent alcohol

20 (ICI) anhydrous sorbitol polyoxyethylene (20) ether laurate 0.30

Citric acid (50%) is an amount of

Spices, Ran Liao ﹠amp; Sanitas is an amount of

Amount to 100.0

Process: in being equipped with the container that stirs, add preceding four kinds of compositions.Thorough mixing.In independent container pre-mixing spices and

20.Join in the batch of material thorough mixing.Use citric acid Ph if necessary.Add dyestuff and sanitas as required.

Physical properties: Ph 4.0-4.4; Viscosity at 25 ℃: water sample is thin

Embodiment 21

The humidification sprays

Composition: Weight %

Water 70.8

Sanitas 0.2

Bio-PDO 28.0

GA-70PG 0.9

Hydrolyzed-silk 0.1

Spices 0.1

Amount to 100.0

Process: add entry.Add Bio-PDO ^TMBe heated to 50 ℃ and

Mix among the GA-70PG.Thorough mixing is up to homogeneous.Stir cooling down.At 30 ℃, add propylparaben and hydrolyzed-silk.Be cooled to 25 ℃, add spices.Regulate Ph to 5.5-6.5 with citric acid or sodium hydroxide.

Physical properties: viscosity: 20cps

Embodiment 22

Men's scraping must the colourless microemulsion in back

Composition: Weight %

1 phase

PEG 400 MO 12.7

IPM 11.0

PEG 400 ML 7.0

Bio-PDO 3.5

GMO 3.0

DC 556 Silicone Fluid(Dow Corning) 1.0

2 phases

Ethanol 25.0

Trolamine is an amount of

Spices, dyestuff, sanitas is an amount of

Deionized water reaches 100 in right amount

Amount to 100.0

Process: deionized water is heated to 95 ℃.Each composition of (1) phase is mixed and be heated to 95 ℃.Stir down (1) is added in the deionized water.Be cooled to 30 ℃, and add ethanol.Regulate Ph to 7.0-8.0 with trolamine.Add spices if necessary, dyestuff and sanitas.This prescription will obtain colourless microemulsion.

Physical properties: Ph 7.0-8.0; Viscosity: 40cps

Embodiment 23

Cleanser/hand

Composition: Weight %

Ammonium lauryl sulfate (ALS) (28%) 26.0

Coconut oleoyl amine DEA 6.0

Sodium lauryl sulphate (SLS) (25%) 18.0

Bio-PDO propylene glycol 1.0

Water 44.5

Bio-PDO stearate 0.5

Irgasan 0.2

EDTA four sodium (5 weight %) 2.0

Spices 0.2

Citric acid (50 weight %) is an amount of

Process

Mix ALS, coconut oleoyl amine DEA, SLS and Zemea ^TMPropylene glycol

Add Bio-PDO stearate and Irgsan

Be heated to 60 ℃

Be cooled to 30 ℃, add EDTA

Stirring is up to forming uniform solution

Be adjusted to Ph6 with citric acid

Add spices

Advantage

High stability

Higher tack

Excellent foaminess

Embodiment 24

Cleanser/hand

Composition: Weight %

Carbopol 934NF 0.50

Germaben II 0.06

Bio-PDO 5.00

Virahol (IPA) 47.70

Deionized water 43.79

Trolamine (20 weight %) 2.50

Spices 0.50

Process

Add hot water and germaben II solution at 50 ℃

Add carbopol

Stir content to forming the homogeneous gel

Add Bio-PDO, IPA and water

Stirring is up to forming uniform solution

Be cooled to be lower than 30 ℃

Be adjusted to Ph7 with TEA

Add spices

Advantage

High stability

Higher tack

Excellent hydrotropy

Embodiment 25

Hair conditioner

Composition	Weight %
		Ammonyx R4 4	5.00
Bio-PDO 1	1.50
		Panthenol	0.50
Hexadecanol 2	3.50
		16/polyoxyethylene octadecanol 3	1.25
Germaben II 2	0.50
		Spices, dyestuff	In right amount
Deionized water	Reach 100 in right amount

¹DuPont Tate & Lyle Bio Products

²The Chemistry Store.com，Cayce，SC

³Somerset Cosmetic Co.LLC，Renton，WA

⁴Stephan Co.Northfield，IL

Process: will go up listed each composition merging in the table, thorough mixing also is heated to 75 ℃.Stirring is up to thorough mixing.With mixture cooling and adding sanitas.Use citric acid to regulate Ph to 5 then if necessary.The mixture stirring is spent the night.Form opaque and white liquid.

Physical properties: Ph:5; Form opaque and white liquid.

Embodiment 26

Cleanser/hand

Composition	Weight %
		Carbopol 934 NF 2	0.50
BioPDO 1	5.00
		Virahol	57.0
Deionized water	35.0
		Trolamine (20 weight %)	2.0
Spices	In right amount

¹DuPont Tate&Lyle Bio Products

²Noveon，Cleveland，OH

Process: 100g water is heated to 50 ℃, and this hot solution is joined in the 4g carbopol 940.Stirred this gel 4 hours at 50 ℃.Stop heating and continue stirring 20 hours.Can form the homogeneous gel.Add Bio-PDO, Virahol and water stir up to formation homogeneous mixture, and cooling.Use the trolamine dilute solution to regulate Ph to 7.Add spices.Mixture should be colourless after Ph regulates.

Embodiment 27

Solid deodorizer

Composition	Weight %
		Bio-PDO 1	48.0
Sodium stearate	6.5
		Poly-(ethylene glycol) mono-laurate 6	2.0
Irgasan 6	0.2
		Water	In right amount

¹DuPont Tate & Lyle Bio Products

⁶Sigma-Aldrich，Milwaukee，WI

Process: in the mixture of Bio-PDO and water, add sodium stearate, and be heated 100 ℃, add the PEG mono-laurate up to forming clarified liq.Mixture is cooled to 50 ℃ and be poured in the container.

Embodiment 28

Colourless tanned spray gel

¹DuPont Tate & Lyle Bio Products

²The Chemistry Store.com，Cayce，SC

³Somerset Cosmetic Co.LLC，Renton，WA

⁴Stephan Co.Northfield，IL

⁵Noveon，Cleveland，OH

⁶Sigma-Aldrich，Milwaukee，WI

Process: the water of mixture A phase and Germaben II with mixture heating up to 50 ℃, join this hot solution in the carbopol.Stirred this gel 4 hours down at 50 ℃.Stop heating and continue stirring 20 hours.In independent container, add 2-phenyl-5-benzoglyoxaline sulfonic acid, add entry and trolamine.Mix each component up to forming settled solution, add Bio-PDO, ethanol PEG mono-laurate and anhydrous sorbitol polyoxyethylene (20) ether stearate.Stirring is up to forming the homogeneous gel.Add the C phase, thoroughly mixed gel adds entry and sanitas, continues to stir up to forming classifying gel.Ph should be about 7.

Embodiment 29

Men's scraping must the back preparation

Viscosity: 21cps

¹DuPont Tate & Lyle Bio Products

²The ChemistryStore.com，Cayce，SC

³Somerset Cosmetic Co.LLC，Renton，WA

⁴Stephan Co.Northfield，IL

⁵Noveon，Cleveland，OH

⁶Sigma-Aldrich，Milwaukee，WI

Process: merge each component of A phase and be heated to 80 ℃.Add entry and be heated to 80 ℃.Be cooled to 30 ℃, and add ethanol.Regulate Ph to 7.0-8.0 with trolamine if necessary.Add spices, dyestuff and sanitas.

Embodiment 30

Skin lotion

Physical properties: Ph7.5; Viscosity: #4@60rpm2240cps

¹DuPont Tate&Lyle Bio Products

²The ChemistryStore.com，Cayce，SC

³Somerset Cosmetic Co.LLC，Renton，WA

⁴Stephan Co.Northfield，IL

⁵Noveon，Cleveland，OH

Process: merge each component of A phase, thorough mixing also is heated to 80 ℃.In different vessels, merge Stephan IPM, polydimethylsiloxane and hexadecanol, and with mixture heating up to 80 ℃ up to forming clear solution.To B add in mutually stearic acid and once more with this mixture 80 ℃ down heating up to forming clear solution.Merge A mutually with B up to thorough mixing.Mixture is cooled to 50 ℃ and add trolamine and EDTA four sodium solutions.With mixture heating up up to the mixture thorough mixing.Water and sanitas with mixture cooling and adding aequum.

Embodiment 31

Colourless wetting Agent for Printing Inks

¹DuPont Tate & Lyle Bio Products

²The Chemistry Store.com，Cayce，SC

⁵Noveon，Cleveland，OH

Process: merge Aloe gel, Bio-PDO and GermabenII.Stirring is transparent up to solution becomes.Add carbopol.Under agitation mixture heating up to 60 ℃ is not contained block up to solution.Add alcohol.Thorough mixing.Add PEG.Thorough mixing is up to forming clear solution.Add perfume compound, TEA and sanitas.

Embodiment 32

Colourless shampoo

Composition	Weight %
		Blend 213 2Sodium laureth sulfate cocamidopropyl betaine coconut oleoyl amine DEA PEG-150 SUNSOFT Q-182S	25
Cocamidopropyl betaine 2	5
		Bio-PDO 1	5
Deionized water	65
		Sodium chloride solution (25 weight %)	In right amount

¹DuPont Tate & Lyle Bio Products

²The Chemistry Store.com，Cayce，SC

Process: Blend 213 and cocamidopropyl betaine are mixed, add BioPDO, thorough mixing.Add entry, and stirred 20 hours.Regulate viscosity with sodium chloride solution if necessary.

Embodiment 33

The infant who contains antiseptic-germicide uses soap

¹DuPont Tate & Lyle Bio Products

⁷The Custom composition, Inc.Chester, SC

Character: Ph:7; Viscosity: 3000cps

Process: each component and the thorough mixing that merge the A phase.Heating makes dissolves fully to obtain clear solution.Slowly add warm water and be heated to clarification.Stir very slow cooling down.Regulate viscosity with sodium-chlor.Add required spices.

Embodiment 34

Foundation cream

The production process of this emulsion is the canonical process that is used for all oil-in-water-type products.Dispersion order A, and, the order B (pigment phase) that grinds in advance being joined wherein when the complete hydration of jelly and when becoming homogeneous mutually, and with the two-phase mixing up to complete and homogeneous and homogeneous.The order C that weighs in independent container, and be heated to 75-80 ℃ melts and is homogeneous mutually up to all solids.Then order A is heated to 75-80 ℃.All be in proper temperature following time mutually when all, addition sequence C (oil phase) slowly in order A and B (water).Emulsion was mixed 15 minutes down at 75 ℃, be cooled to 25 ℃ then.To test then with sample and topple over out and be placed on separately stability station, be that the research of 4 weeks is prepared.The colorant of these preparations and powder load loading level and remain under 11.30% the dried pigment constant.Select common powder packed composition so that eliminate any potential variability in test-results to these preparations.

Physical test:

Brookfield type RV-axle 5, under 20rpm, 1 minute (factor x200)

Initial p h	Initial viscosity	The 1st all viscosity	The 2nd all Ph	The 2nd all viscosity	The 3rd all viscosity	The 4th all Ph	The 4th all viscosity
								8.03	2400	2900	7.94	2900	2900	8.02	2900

Viscosity reading in the duration of test in whole 4 weeks shows and forms not that unusual viscosity raises or viscosity reduces.Baking oven stability is by R/T, and 45 ℃ and 2 freeze are formed.After 4 weeks, sample does not separate, ooze out, and the viscosity heavy losses, denseness changes, structure forfeiture, bad-smell problem, or the sign of variable color under any temperature.

Aesthetic properties

Estimated all samples in smell, color, outward appearance, application, quality, sensation, wear resistance, or the possible difference of any others, if any.All foundation cream samples are estimated side by side.In aspect any aesthetic properties relevant with the beauty treatment character of these types definitely without any perceivable difference.Any difference of noticing is inessential and is not the result that composition changes.These all are the preparations of perfume-free, do not have tangible smell difference in any sample.

Embodiment 35

Mascara

In proper order	Composition	Weight %
			A	Deionized water	49.00
A	Xanthan gum	0.15
			A	Neusilin HV particle	0.55
A	The EDTA disodium	0.05
			A	Trolamine 99%	0.50
A	Alcolec S (Yelkin TTS)	0.20
			A	Methyl p-hydroxybenzoate	0.30
A	Bio-PDO	10.00
			B	Iron oxide black	9.00
C	DC 345 Fluid (D5 cyclohexyl methyl siloxanes)	4.50
			C	The DC5225C formulation adjuvant	0.90
C	Cera alba	7.25
			C	Carnauba wax #1	3.50
C	Triple pressed stearic acid	1.80
			C	Lipomulse 165 (glycerol monostearate base ester)	1.80
C	Indopol H100 (polybutene)	3.50
			C	Phenoxyethyl alcohol	1.00
C	Propylparaben	0.20
			C	PVP/ eicosylene multipolymer (colpolymer)	4.00
C	Lipocol S (stearyl alcohol)	1.80
				Prescription amounts to:	100.00

The production process of foundation cream that is used for the production process of said preparation and embodiment 24 is similar.Need higher temperature for oil phase, because in this product, used high-caliber hard wax.Dispersion order A, and, the order B (pigment phase) that grinds in advance being joined wherein when the complete hydration of jelly and when becoming homogeneous mutually, and with the two-phase mixing up to complete and homogeneous and homogeneous.The order C that weighs in independent container, and be heated to 80-85 ℃ melts and is homogeneous mutually up to all solids.Then order A is heated to 75-85 ℃, all is in proper temperature following time mutually, addition sequence C (oil phase) slowly in order A and B (water) when all.Emulsion was mixed 15 minutes at 75 ℃.When batch of material begins to thicken when thick at about 45 ℃, use paddle mixer to make batch of material is overturn fully and mix.Batch of material is mixed and be cooled to 35 ℃.To test then with sample and topple over out the stability station that is placed on separately, be that the research of 4 weeks is prepared.The colorant loading level of these preparations remains unchanged under 9.00% dried pigment.Except black iron oxide pigment, do not use other powder weighting material at these preparations.Other powder weighting material will cause turning white and burnt hair, and this is unwelcome in mascara.

Physical test:

Brookfield type RV-axle T, under 5rpm, 1 minute (factor x10,000)

Initial p h	Initial viscosity	1 all viscosity	2 all Ph	2 all viscosity	3 all viscosity	4 all Ph	4 all viscosity
								8.58	180,000	320,000	8.55	380,000	430,000	8.55	420,000

Viscosity reading in the duration of test in whole 4 weeks shows and forms not that unusual viscosity raises or viscosity reduces.The variation of observing for such product is very typical, and is in the tolerance interval of mascara type products.Baking oven stability is by R/T, and 45 ℃ and 2 freeze are formed.After 4 weeks, sample does not separate, ooze out, and the viscosity heavy losses, denseness changes, structure forfeiture, bad-smell problem, or the sign of variable color under any temperature.

Aesthetic properties:

Estimated all samples in smell, color, outward appearance, application, quality, sensation, wear resistance, or the possible difference of any others, if any.All mascara samples are estimated side by side.In aspect any aesthetic properties relevant with the beauty treatment character of these types definitely without any perceivable difference.Any difference of noticing is inessential and is not the result that composition changes.In addition, the water tolerance that shows of mascara sample does not have difference.Although mascara is not designed to be water resisting property especially, similarly estimate sample is parallel.These all are the preparations of perfume-free, do not have tangible smell difference in any sample.

Embodiment 36

Body detergent

Merge each composition in the following sequence, use propeller-type mixer to stir, make each composition before adding the next one, dissolve fully and disperse.At 60 ℃ batch of material is handled: water, acrylate copolymer, ALS, ALES, GAB, guar gum hydroxypropyl-trimethyl ammonium chloride, EDTA, PEG10 Sunflower Receptacle glyceryl ester, soybean oil, coconut oleoyl amine MEA, the PEG5 coconut oleoyl amine, Yi Bingchunan/methylcellulose gum/carbomer/guanine, mica/titanium oxide, glycerine.

Embodiment 37

The body and function washing lotion

Merge each composition in the following sequence, make every kind of composition dissolution fully before adding the next one:

A phase: under high-speed stirring, carbomer is dispersed in the water, makes particle by complete wetting.Add Bio-PDO.Be heated to 70 ℃.

B phase: merge following composition: tetradecanoic acid tetradecyl ester, stearin, oleic acid, anhydrous sorbitol polyoxyethylene (4) ether stearate, phenylformic acid C12-15 alkyl ester, polydimethylsiloxane, Wickenol 111, the stearic acid sorb is smooth, hexadecanol, synthetic bees wax, stearyl alcohol, phenylcarbinol, methyl p-hydroxybenzoate, propylparaben, butyl p-hydroxybenzoate, and BHT, be heated to 70 ℃.

Continuation slowly joins the middle mutually emulsion that forms of A mutually with B under high-speed stirring.Remove thermal source and under continue stirring, begin to cool down.After mixed for several minutes, add the NaOH that is dissolved in the less water.The batch of material retrogradation when batch of material reaches room temperature, adds pigment, spices, and replenish the water loss of evaporation.Batch of material is finished.

Embodiment 38

Sulfate-free shampoo

Production process:

A phase: the A phase composition is merged in the water, and under mixing, be heated to 75 ℃.Slowly add the residual A phase composition.Remain under 75 ℃ the temperature and slowly and stir.

B phase: merge the B phase composition and under slowly stirring, be heated to 75 ℃.With B be added to A mutually in and mix up to homogeneous.

C phase: disposable adding C phase.

D phase: use D to regulate the Ph of batch of material mutually to 6.0-6.5.

Embodiment 39

Colored cosmetic compositions (liquid makeup agent)

Preparation method: the composition of B phase (water) mixed being incorporated under the abundant stirring with mixture heating up to 65 ℃, to form the homogeneous water.

The content that mixes the A phase individually is up to forming the homogeneous gel.A is mixed mutually with B mutually and under agitation mixture was heated 1 hour down at 65 ℃, with composition cools and transfer in the container.

Composition Weight %

The A phase

Titanium dioxide 6.0

Red iron oxide 1.0

Pigment blend 5 0.5

Bourdaux mica 0.5

Castor oil 8.0

The B phase

Water 46.9

Bio-PDO 22.0

Emulsifying wax 9.0

Sodium stearate 4.5

GelMaker EMU 1.3

Methyl p-hydroxybenzoate 0.3

Obtained stable oil-in-water emulsion.

Embodiment 40

Colored cosmetic compositions (liquid makeup agent)

Preparation method: the composition of B phase (water) mixed being incorporated under the abundant stirring with mixture heating up to 65 ℃, to form the homogeneous water.

The content that mixes the A phase individually is up to forming the homogeneous gel.A is mixed mutually with B mutually and under agitation mixture was heated 1 hour down at 65 ℃, with composition cools and transfer in the container.

Composition Weight %

The A phase

Titanium dioxide 5.0

Ferric oxide red colorant 1.0

Pigment blend 5 0.5

Bourdaux mica 0.5

Castor oil 9.0

The B phase

Water 46.9

Bio-PDO 22.0

Emulsifying wax 9.0

Sodium stearate 4.5

GelMaker EMU 1.3

Methyl p-hydroxybenzoate 0.3

Obtained stable oil-in-water emulsion.

Embodiment 41

Eye is made up remover

Composition Weight percentage

The C13-15 alkane ( 25) 5.00

The C15-19 alkane (

40) 10.00

Oil base polyoxyethylene (5) ether 13.00

DEA oil base polyoxyethylene (3) ether phosphate 5.75

Deionized water 47.45

Bio-PDO 12.00

Glycerine 99% 6.50

Germaben II-E 0.30

Production process:

In proper container, weigh the order A composition.Under good the stirring, begin to be heated to 75-80 ℃.Composition among the order of in second container, the weighing B.Under good the stirring, begin to be heated to 75-80 ℃.When two der group branches are in suitable following time of temperature, under successive propeller formula is mixed, order B is slowly joined among the order A.Along with each merges the speed that increases mixing tank in proper order.Being transformed into side wiping formula mixing tank also continues to stir to mix well homogeneous and homogeneous up to batch of material.Mixed 15 minutes, and under continuously stirring, begin to cool down batch of material.Batch of material is cooled to 25 ℃.In the 25 ℃ of taking-up batch of materials and the airtight container of packing into.Check the viscosity and the Ph value of batch of material.

Embodiment 42

Eye shadow cream

Composition Weight percentage

Deionized water 44.15

Keltrol F 0.20

Magnesium aluminum silicate rule particle 2.00

EDTA disodium 0.10

Trolamine 99% 0.50

Bio-PDO 10.00

Reed fragrant plant glue (Lubrajel Oil) 1.00

PIVALIC ACID CRUDE (25) isodecyl ester 7.35

Lipo GMS 450 2.00

Behenyl alcohol 0.50

Tetradecanol 0.50

Hexadecanol 0.50

Stearic acid 1.50

Alcolec S 0.15

PIVALIC ACID CRUDE (25) iso stearyl ester 5.00

Vitamin E-acetate 0.05

Allianz ^TM OPT 1.00

DC 345 Fluid-cyclohexyl methyl siloxanes 7.50

Germaben II-E 1.00

Cosmetic Russet C33-5138 0.60

Cosmetic Yellow C33-1700 0.12

Iron oxide black LC989 0.24

Sericite PHN 0.24

Timica Sparkle 110P 13.80

Production process:

The composition of A in mutually merged, and begin to stir and mix well mutually and homogeneous up to this.Under continuously stirring, merge the composition of B phase and begin to be heated to 80 ℃.The A heat phase is arrived 75-80 ℃.When A mutually is in suitable following time of temperature mutually with B, the homogenization mixing condition of use continuous high speed with B slowly join mutually A mutually in, under homogeneous mixing condition, C is added in the batch of material.When batch of material all for the moment, beginning batch of material is cooled to 55 ℃ under the homogenizer mixing condition continuously.At 55 ℃, in batch of material, add the D phase.Mixing is up to homogeneous.In batch of material, add the E phase, and mix up to homogeneous.The F phase of in suitable mixing machine, weighing.F is ground by micropulverizer or Equivalent.When F does not mutually contain pigment particle, add the G phase to F in mutually, and mixing is up to homogeneous.In main batch of material container, be transformed into side and wipe the formula mixing machine and begin batch of material is cooled to 25 ℃.At 25 ℃, in batch of material, add F and G mutually and mixing disperseed up to all powder, and batch of material is mixed well and homogeneous.Batch of material is kept in the gas tight container, up to prepare to add fill before.Check the viscosity and the Ph value of batch of material.

Embodiment 43

Rouge

Composition	Weight percentage
		Deionized water	62.00
Bio-PDO	8.00
		Stepanquat ML	2.00
Germaben II-E	1.00
		SI-TEC TMCM-040 cyclohexyl methyl siloxanes	20.00
Abil EM-90	1.00
		Salcare SC-95	2.00
Phenoxyethyl alcohol	1.00

SI-TEC TMCM-040 cyclohexyl methyl siloxanes	1.80
		Titanium dioxide 328	0.68
D&C Red 30(Puricolor Red VRE1)	0.52

Production process:

Attention: this is the emulsion that cold process obtains, and at room temperature (25 ℃) are produced.In suitable mixing vessel, merge the A phase.Mixing is transparent and homogeneous up to this mutually.In suitable mixing vessel, merge the B phase.Mixing is transparent and homogeneous up to this mutually.Pre-mixing C phase in independent container, and grind up to there not being pigment particle by 3 roller machines.With C be added to B mutually in and mix, up to colo(u)rant dispersion.When A and B and C mutually all for the moment, with A slowly join mutually B and C mutually in and mix up to all being combined mutually.Transfer in the intimate mixing device and mixed 10-15 minute.With batch of material be kept in the gas tight container up to prepare to add fill before.Check the viscosity and the Ph value of batch of material.

Embodiment 44

Eye-liner

Composition Weight percentage

Deionized water 35.00

Keltrol F 0.20

Methyl p-hydroxybenzoate 0.25

PVP K-30 (10% the aqueous solution) 11.75

Trolamine 99% 1.00

Bio-PDO 10.00

Cosmetic Russet C33-5138 5.00

Cosmetic Yellow C33-1700 1.00

Iron oxide black LC989 2.00

Sericite PHN 2.00

Carnauba wax #1 4.00

Cera alba 2.00

Permethyl 104A 6.00

Stearic acid 2.50

Lipo GMS 450 1.00

Propylparaben 0.20

Phenoxyethyl alcohol 1.00

Deionized water 1.00

Germall 115 0.10

Reed fragrant plant glue (Lubrajel Oil) 14.00

Production process:

Merge the composition of A phase in suitable mixing vessel, mixing up to this is homogeneous mutually.In micropulverizer, grind the B phase.When B does not mutually contain pigment particle, under mixing condition continuously, B is added to A mutually in.Mixing up to described be mutually homogeneous and do not contain block.Make the batch of material homogenization 10-15 minute, and perhaps, made A mutually and the B smooth and homogeneous that becomes mutually as required.The composition that in independent container, merges the C phase, and under good the stirring, begin to be heated to 80-85 ℃.Begin to heat A and arrive 75-80 ℃ mutually.Be in suitable following time of temperature mutually when all, under mixing condition continuously, C slowly joined mutually A and B mutually in.Cover batch of material and mix 15 minutes to prevent dehydration.Begin batch of material is cooled off.The composition that in independent container, merges the D phase.At 50 ℃, under the mixing condition D is slowly being joined in the batch of material mutually continuously.Continuation is with the batch of material cool to room temperature.At 25 ℃, take out batch of material and be kept in the gas tight container up to prepare to add fill before.Check the viscosity and the Ph value of batch of material.

Embodiment 45

Hair dyes matrix and tone preparation

Embodiment 46

Use composition before scraping palpus

Composition Weight percentage

EDTA 35％

Sodium lauryl sulphate 3.3%

Ni Baijin 20%

Nipazol 0.08％

Hexadecanol 1.8%

Carbopol 940 1.4%

Chinese wax 0.15%

Anhydrous sorbitol polyoxyethylene (20) oleic acid ester 4%

Bio-PDO 11.5％

Trolamine 1.7%

Water 21.07%

Embodiment 47

Use composition after scraping palpus

Composition Weight percentage

Virahol 30-70%

SD alcohol-40 10-30%

Acetylsalicylic acid 8-22%

Carbomer 0.25-1.75%

Propylene glycol 2-15%

Glycerine 2-15%

PEG 1-8％

Water reaches 100% in right amount

Embodiment 48

Containing scraping of wetting Agent for Printing Inks must makeup

Composition Weight percentage

Bio-PDO 50-90％

Oil 0.1-30%

H2O 0.01-10％

Also contain:

H2O 5.0％

Glycerine 31.5%

1,3 butylene glycol 20.0%

Bio-PDO 20.0％

Polyoxyethylene glycol 15.0%

Unimac 5680 7.0%

Dimethyl polysiloxane 1.0%

Perfume compound 0.5%

Embodiment 49

Bar-shaped delivery system

Razor burning sensation treatment agent

Composition Weight percentage

Solvent ^*

Bio-PDO 72％

Jelling agent ^*

Sodium stearate 8%

Medicament ^{* *}

Lignocaine 4%

Menthol 1%

Water 15%

^*Polyvalent alcohol

^*Alkali metal stearic acid salt and/or palmitate

^{* *}Narcotic, antihistaminic agent, anti-inflammatory agent, anti-mycotic agent

Embodiment 50

Water-in-oil emulsion is brushless still shaving cream

Composition Weight percentage

Long chain aliphatic alcohol ^*4-15%

Tensio-active agent ^*1-10%

Wetting agent ^{* *}1-10%

Softener ^{* * *}4-20%

^*Dodecanol, Stearyl alcohol, cetyl alcohol, tetradecanol

^*Anionic, non-ionic type, amphoteric or quaternary ammonium type surfactants

^{* *}Glycerine, propylene glycol, sorbyl alcohol or polyoxyethylene glycol

^{* * *}rabic t or mineral oil

Embodiment 51

Scraping must cream

Composition Weight percentage

70% sorbyl alcohol 6.19%

Bio-PDO 6.19％

Stearic acid 22.80%

C10-16 lipid acid 19.00%

40％KOH 20.60％

Boric acid 0.70%

H2O 23.35-26.37％

Perfume compound 1.00-1.17%

Wallantoin 0.20%

Ni Baijin 0.20%

Vegetables oil 3.00%

Embodiment 52

Scraping must cream

Composition Weight percentage

A)

Tristearin and Oleum Cocois 40.56%

40％KOH 20.68％

70% sorbyl alcohol and Bio-PDO 13.66%

H3BO3 2.74％

Wallantoin 2.74%

Ethyl aminobenzoate 2.74%

Ni Baijin 2.74%

H2O 22.36％

B)

Tristearin 31%

Oleum Cocois 10%

40％KOH 20.48％

70% sorbyl alcohol 6.0%

Bio-PDO 7.65％

H3BO3 0.65％

Ni Baijin 1.0%

Wallantoin 1.0%

Ethyl aminobenzoate 0.74%

Perfume compound 1.0%

Dyestuff 0.05%

Sodium alginate 0.07%

H2O 20.36％

Embodiment 53

Scraping must preceding stylus

Composition Weight percentage

A)

Glyceryl monooleate 25-70%

Sodium stearate 8-25%

Bio-PDO 0-50％

H2O 1-10％

B)

Atlas G-3496 61.65％

Sodium stearate 15.0%

Water 3.0%

Perfume compound 0.35%

Bio-PDO 20.0％

Embodiment 54

Liquid is scraped must composition

Composition Weight percentage

A)

Nonionic surface active agent 60-97%

Bio-PDO 2-25％

H2O 1-15％

B)

Glyceryl monooleate 77.8%

Polyoxyethylene (20) sorbitol anhydride mono-laurate 6.6

H2O 6％

Bio-PDO 9.6％

Embodiment 55

Scraping must liquid

Composition Weight percentage

Bio-PDO 50-80％

Deionized water 1-50%

Embodiment 56

Scraping must liquid

Composition Weight percentage

Bio-PDO 50-80％

Deionized water 1-50%

Embodiment 57

Skin preparation solution

Be applicable to skin surface before scraping palpus

Composition Weight percentage

Bio-PDO 10-80％

Deionized water 10-80%

Imidurea 0.02-4%

Methyl p-hydroxybenzoate 0.02-4%

Propylparaben 0.01-2%

Embodiment 58

Skin care solution after hair is removed

Composition Weight percentage

Deionized water reaches 100% in right amount

Aloe gel 6-7.4%

Soybean oil 6-7.4%

Alpha-lipoic acid 0.2-1.3%

Stearic acid 3.5-4.3%

Glycerol monostearate 3-3.7%

Bio-PDO 2.5-3.1％

Laurylamide DEA 1.4-1.6%

Vitamin-E 0.4-0.5%

Hydrocortisone acetate 0.2-0.5%

Vitamins C 0.2-0.25%

Carbomer 0.2-0.25%

Walocel MT 20.000PV 0.2-0.25%

Methyl p-hydroxybenzoate 0.2-0.25%

Propylparaben 0.09-0.1%

Polyquaternium-15 0.09-0.1%

Embodiment 59

Transparent scraping must glue

Composition Weight percentage

Bio-PDO 15-20％

Lubricant/skin conditioning agent 2-5%

Thickening material 0.5-0.8%

Neutralizing agent 0.5-0.8%

Sanitas 0.2-0.5%

Embodiment 60

Enzyme-containing toothpaste

Composition Weight percentage

Bio-PDO 20-73

Friction materials 15-50

Thickening material 1-1.7

Tensio-active agent 1-6

Essence 0.8-1.2

Water 8-35

Asccharin 0.1-0.3

Pigment 0-0.5

PEG 0-6

Biological enzyme 0.01-2

Menthol 0-0.1

SODIUM PHOSPHATE, MONOBASIC 0.1-0.5

Titanium dioxide 0-1

Biological enzyme stablizer 0.1-4

Embodiment 61

The oral treatment composition

Use toothpaste to carry out the anti-inflammatory and the antimicrobial treatment in oral cavity

Composition Weight percentage

Clindamycin 0.01-0.1%

Metronidazole 0.01-0.1%

Propylene glycol 5-10%

Sorbyl alcohol (70%) 1-10%

Dimethyl P-hydroxybenzoic acid sodium 0.1-0.5%

Embodiment 62

Beauty treatment toothpaste

Composition Weight percentage

Hairdressing agent 0.5%-5

Sepiolite 0.25-4%

Polyvinylpyrolidone (PVP) (PVP) 0.1-2.5%

Wetting Agent for Printing Inks 15%-25%

·Bio-PDO

Tackiness agent 1%-2.5%

Xanthan gum

Pore forming material 1.5-2.5%

Sodium lauryl sulphate (SDS)

Grinding/friction agent 40-50%

Lime carbonate

Essence 1%-1.5%

Asccharin 0.1-0.5

Water reaches 100 in right amount

Embodiment 63

The multifunctinoal health care toothpaste

The treatment carious tooth, and have antimicrobial, anti-inflammatory and desensitization character.

Composition Weight percentage

Abrasive 30-55

CaCO3, CaHPO4, Al (OH) 3 or SiO2

Wetting agent 15-25

·Bio-PDO

Thickening material 1.0-1.4

Xanthan gum

Discoloring agent (tensio-active agent) 2.0-2.5

Sodium lauryl sulphate

Polymkeric substance 0.1-2.0

Triclosan 0.1-0.3

Chinese herbal medicine extract 0.1-0.5

Desensitizing agent 0.2-0.4

Fluorochemical 0.2-0.8

Asccharin 0.25-0.35

Perfume compound 0.8-1.2%

Water reaches 100%

Embodiment 64

Dentifrice composition

Composition Weight percentage

Abrasive 5-50%

Silicon-dioxide

Tackiness agent 0.1-30%

Xanthan gum

Wetting Agent for Printing Inks 10-80%

Propylene glycol

Tensio-active agent 0.1-5%

The alkyl poly glucoside of non-ionic type

Embodiment 65

Toothpaste

The composition weight percentage

Lime carbonate 40-45%

Natvosol 1-1.3%

Bio-PDO 22-25％

Sodium lauryl sulphate 1.8-2%

Ni Baijin 0.09-0.10%

Propylparaben 0.025-0.30%

Proteinase-10 .25-0.50%

Sodium acetate 0.15-0.25%

Asccharin 0.10-0.15%

Seasonings 0.75-1%

Water reaches 100% in right amount

Embodiment 66

The infant uses mouth wash shua

The infant that per 100 grams or M1 contain following composition uses mouth wash shua

Composition Weight percentage

Sorbyl alcohol 3.00

Glycerine 3.00

Methyl p-hydroxybenzoate 0.20

Propylparaben 0.10

Bio-PDO 4.00

EDTA disodium 0.10

Sodium lauryl sulphate 0.40

Soluble saccharin 0.06

Petitgrain volatile oil 0.02

Tea tree volatile oil 0.03

Potassium sorbate 0.20

Trisodium Citrate 0.05

Potassiumphosphate 0.10

Citric acid 0.50

CI19140 0.02

CI47090 0.01

Water reaches 100 in right amount

Embodiment 67

Anti-spot mouth aqueous composition

Comprise the germ resistance ester, arginine derivative, tensio-active agent, the mouth rinse of wetting Agent for Printing Inks

Composition Weight percentage

Lauroyl arginine ethyl ester-HCl 0.1

Sorbyl alcohol 10.0

Glycerine 10.0

Bio-PDO 7.0

Anhydrous sorbitol polyoxyethylene (20) ether laurate 0.8

Cocamidopropyl betaine 0.8

Soluble saccharin 0.03

Spices 0.10

Water reaches 100% in right amount

Embodiment 68

Mouth care is with preventing and therapeutical agent

Composition Weight percentage

Tackiness agent 0.1-5.0%

Na CM-Mierocrystalline cellulose

Foaming component 0.1-5.0%

Sodium lauryl sulphate

Antidesiccant 1.0-15.0%

·Bio-PDO

Sanitas 0.02-0.5%

Methyl p-hydroxybenzoate or propyl ester

Spices 0.1-2.0%

Spearmint oil

Abrasive 5.0-25%

Colloidal silica, SiO 2 powder

Solvent 0.1-90.0%

Water 50.0-90.0%

Phosphate buffer Ph6.5-7.5 0.5-3.0%

Ethanol 0.1-50.0%

Bioactive ingredients 0.01-8.0%

Protamine 0.1-5.0%

Wallantoin 0.05-1.0%

Sodium Fluoride 0.03-3.0%

Vitamin PP 0.01-5.0%

Provitamin B5 0.05-8.0%

Embodiment 69

Antimicrobial composition

Antimicrobial creme or paste

Composition Weight percentage

Glycerine 6%

Bio-PDO 5.5％

Sodium lauryl sulphate 1%

Hexadecanol 4.5%

Palmitic acid spermaceti alcohol ester 4%

Stearyl alcohol 4.5%

Stearic acid 4%

White vaseline 5%

Biocide 1%

Water 64.5%

Embodiment 70

The oral composition that contains biocide

Mouthwash, gargle, dentifrice agent, anti-spot compound, mouth film dentifrice agent, general antiseptic-germicide, denture cleaning tablet or solution

Mouth rinse:

Composition Weight percentage

Alcohol 15%

Biocide 0.05%

Flavor oil 0.1%

Bio-PDO 3％

Lauryl methyl cocoyl Sodium taurine salt 0.3%

Trisodium Citrate 0.08%

Citric acid 0.02%

Soluble saccharin 0.1%

FD&C Green No 30.0002％

Water reaches 100% in right amount

Embodiment 71

Sterilization property mouthwash

Composition Weight percentage

Ethanol 6-7

Bio-PDO 12-13

Propolis 0.001-0.10

Phenylacrolein 0.003-0.35

Alkyl dimethyl benzyl ammonium chloride 0.003-0.35

Water reaches 100% in right amount

Embodiment 72

The composition that contains antibacterial agent

Composition Weight percentage

Phenols antibacterial agent 0.05-5

Sterilization property alcohol 1-40

Jelling agent 0.1-5

Hydrotropic solvent 0.1-30%

Bio-PDO 0.1-50％

H2O reaches 100% in right amount

Embodiment 73

The mouthwash composition that contains sterilant

Artificial sprays:

Composition Weight percentage

Terpane 2.7

Thymol 1.8

Wintergreen oil 1.5

Menthol 1.5

Ethoxylated hydrogenated castor oil 10

Shellac 1.0

Bio-PDO 30

Ethanol 51.5

Embodiment 74

Liquid is washed the dish sanitising agent automatically

Composition: Weight %

Water 54.30

Citric acid 5.93

Bio-PDO 6.92

Carbopol ^TM934 2.18

NaOH(50％) 5.74

Sodium Tetraborate 0.99

Trisodium Citrate 3.96

Sodium formiate 1.98

CaCl 0.10

Sodium xylene sulfonate (40%) 4.95

EO/PO segmented copolymer 1.98

Sodium polyacrylate Mn1200 (45%) 9.89

Proteinase-10 .69

Amylase 0.20

Lemon essential oil 0.20

Amount to 100.0

Process: merge and stirring water H2O citric acid and Bio-PDO ^TMIn mixture, add carbopol ^TM, and rab is up to dissolving.Slowly add sodium hydroxide, add all the other components then.

Embodiment 75

The liquid laundry sanitising agent

Composition: Weight %

Phenylsulfonic acid straight chain dodecyl ester 6.93

Fatty acid distribution of coconut oil (C12-C18) 7.52

Tergitol 15-S-7 16.83

Trolamine 7.52

Bio-PDO 10.89

Citric acid (50%) 6.33

KOH(45％) 9.30

Water 33.65

Proteinase-10 .69

Amylase 0.20

Lavandula angustifolia volatile oil 0.10

FD&C Blue 1 0.03

FD&C Red 40 0.01

Amount to 100.0

Process: combined benzene sulfonic acid straight chain dodecyl ester, H ₂O, trolamine and Bio-PDO ^TM, stir the mixture at 70 ℃.Add Tergitol.The lipid acid fusion is joined it in mixture then.Slowly add KOH, slowly add citric acid then.Mixture is cooled to be lower than 30 ℃.Add enzyme, spices and dyestuff.

Embodiment 76

The liquid laundry sanitising agent

Composition: Weight %

C12-C13 branched-chain alcoho EO-7 4.0

Phenylsulfonic acid straight chain dodecyl ester (60%) 14.0

Sodium laureth sulfate (60%) 5.0

Trisodium Citrate 4.0

Sodium Tetraborate 4.0

Bio-PDO 3.0

Tinopal CBS-X 0.1

Proteinase-10 .7

Amylase 0.2

Monoethanolamine 0.5

Fatty acid distribution of coconut oil (C12-C18) 2.0

Water 62.5

Amount to 100.0

Process: merge each composition in the following sequence, make every kind of complete dissolution of composition to add next composition again: water, Tinopal CBS-X, Trisodium Citrate, Sodium Tetraborate, monoethanolamine, fatty acid distribution of coconut oil, C12-C13 straight chain alcohol EO-7, Phenylsulfonic acid straight chain dodecyl ester (60%), sodium laureth sulfate (60%), proteolytic enzyme, amylase and Bio-PDO ^TM

Embodiment 77

The hand dish washing liquid

Composition: Weight %

Bio-PDO 15.35

Phenylsulfonic acid straight chain dodecyl ester 19.95

Trolamine 6.14

Coconut oleoyl amine DEA 10.74

Tergitol 15-S-7 4.60

Lauryl polyoxyethylene (3) ether sodium sulfate (28%) 4.60

AMONYL 380LC 7.67

Polyquaternium-6 (20%) 3.07

NaCl(25％) 1.53

Sodium xylene sulfonate (40%) 6.55

Water 19.19

Lemon essential oil 0.58

FD&C Yellow 5 0.03

FD&C Red 40 0.01

Amount to 100.0

Process: merge all liquid ingredients and stir this mixture at 70 ℃.Add Phenylsulfonic acid straight chain dodecyl ester gradually and stir up in mixture, dissolving, and the mixture bleach.Mixture is cooled to be lower than 30 ℃ and add spices and tinting material.

Embodiment 78

The hand dish washing liquid

Composition: Weight %

Bio-PDO 15.56

Phenylsulfonic acid straight chain dodecyl ester 20.23

Trolamine 6.22

Coconut oleoyl amine DEA 10.89

Tergitol 15-S-7 4.67

Sodium lauryl sulphate 4.67

AMONYL 380LC 7.78

Polyquaternium-6 (20%) 3.11

NaCl(25％) 3.11

Sodium xylene sulfonate (40%) 3.50

Water 19.45

Lemon essential oil 0.78

FD&C Yellow 5 0.04

Amount to 100.0

Process: merge all liquid composition and stir the mixture at 70 ℃.Add sodium lauryl sulphate and stirring gradually up to dissolving and liquid mixture bleach.Add Phenylsulfonic acid straight chain dodecyl ester and stirring gradually up to dissolving and liquid mixture bleach.Mixture is cooled to be lower than 30 ℃, and adds spices and tinting material.

Embodiment 79

Engine coolant

Composition Weight percentage

Bio-PDO 30-60

Deionized water 36.5-69

Azole compounds 0.05-0.22

Polymkeric substance 0.60-1.60

Polyacrylic acid 0.05-0.20

Sodium Benzoate 0.15-0.90

AEO9 scavenging agent 0.05-0.10

Monocarboxylic acid 0.05-0.25

Dicarboxylate 0.05-0.25

4-butoben 0.0001-0.0002

Defoamer 0.0001-0.0002

Green colouring material 0.0001-0.0002

Embodiment 80

Heat transfer liquid with anticorrosion glass protection

The composition weight percentage

Bio-PDO 94％

Polyacrylic acid＜0.5%

KOH(50％) <0.3％

Azimido-toluene＜0.2%

Benzotriazole＜0.1%

Dehydration Sodium orthomolybdate＜0.1

Hydroxyalkyl amine＜5%

Defoamer 0.004%

Starso 0.2%

Water reaches 100% in right amount

Embodiment 81

Frostproofer and/or refrigerant

Composition Weight %

Bio-PDO 0.1-99.9％

3-hydracrylate or ester 0.1-99.9%

Embodiment 82

The anhydrous frostproofer of no phosphoric acid salt

Composition Weight %

Bio-PDO 92-98％

Boric acid ester (being B4O7) 0.16-0.81%

Molybdate (being MoO4) 0.13-0.66%

Nitrate (being NO3) 0.073-0.36%

Nitrite (being NO2) 0.67-0.33%

Tolyl-triazole 0.15-0.50%

Silicate (being SiO2) 0.014-0.07%

Embodiment 83

The antifreeze composition that is used for diesel motor

Composition Weight %

Monocarboxylic acid 0.1-10%

Nitrate 0.01-10%

Nitrite 0.001-10%

Pyrroles 0.01-5.0%

Molybdate 0.001-5.0%

Organosilicon-silicate copolymer thing 0.01-10%

Polyvinylpyrrolidone 0.001-5.0%

Bio-PDO reaches 100% in right amount

Embodiment 84

Moisture antifreeze coolant

Composition Weight %

Sodium polyacrylate/polyacrylic acid 0.001-10%

Nitrate 0.001-10%

Nitrite 0.001-10%

Pyrroles 0.001-10%

Polysilicate 0.001-10%

Phosphoesterase 30 .001-10%

Molybdate 0.001-10%

Bio-PDO reaches 100 in right amount

Embodiment 85

The anti-freeze type refrigerant

Composition Weight %

Bio-PDO 93％

2 ethyl hexanoic acid 3.1%

Neodecanoic acid 1.1%

SODIUMNITRATE 0.2%

Sodium Nitrite 0.4%

Tolytriazole 0.09%

Embodiment 86

The sealing agent that contains frostproofer

Composition Weight %

Natural rubber latex 55%

Tackifier resins emulsion 15%

Bio-PDO ^TM 30％

Embodiment 87

Be adapted at the water-based coating material that freezing point is used

Composition Weight %

Acronal YJ 2730D 45％

Solvent soluble resin 15%

Bio-PDO 2％

Methyl alcohol 3%

Butyl cellosolve 5%

Embodiment 88

Antifreeze foam

Composition Weight %

Bio-PDO ^TM 45％

Virahol 40%

Polyoxyethylene glycol octadecyl ether 5%

Refrigerant 12 7.5%

Propane 2.5%

Embodiment 89

The food product refrigeration frostproofer

Composition Weight %

Ethanol 49%

Water 48.5%

Polydimethylsiloxane 0.2%

Bio-PDO 1.7％

Sodium malate 0.3%

Monooctamoin/caproate 0.2%

Glycine 0.1%

Embodiment 90

The solid surface frostproofer

Composition Weight %

Bio-PDO 70.0％

Ethanol 5.0%

EO/PO multipolymer 20.0%

Water 5.0%

Inhibiter 0.12%

Nonionic surface active agent 0.5%

Perfume compound 0.1%

Embodiment 91

Agrochemicals liquid frostproofer

Composition Weight %

2,4 dichloro benzene ethoxyacetic acid 43%

Sulfonated lignin 1.5%

Bio-PDO 2％

Aluminum hydroxide gel (10%) 9.0%

Hydroxypropylguar gum 0.2%

Defoamer 0.1%

Water 44.2%

Embodiment 92

The fuel container frostproofer

Composition Weight %

Virahol 69.95%

Bio-PDO 29.95％

Trolamine 0.05%

SODIUMNITRATE 0.03%

Benzotriazole amine salt 0.02%

Embodiment 93

The electric boiler heat-transfer fluid

Composition Weight %

Bio-PDO 30-55％

Sodium phosphate 0.04-0.10%

Ammonium molybdate 0.03-0.09%

Water reaches 100% in right amount

Embodiment 94

Be used to prepare the enriched material of frostproofer and thermal conduction agent

Composition Weight %

Phosphoric acid (78%) 2.0-20.0%

Trolamine 10.0-60.0%

2-mercaptobenzothiazole sodium salt 0.1-1.2%

EDTA disodium salt dihydrate 0.5-1.5%

Hexanolactam 0.1-3.0%

1,4-dihydroxy-benzene 0.001-3.0%

Phosphorous acid ester (salt) P-24 0.001-0.005%

Defoamer 0.02-0.03%

Dyestuff 0.05-0.06%

Butyl cellosolve 0.2-0.3%

Water 10.0-35.0%

Bio-PDO reaches 100% in right amount

Embodiment 95

The solar energy equipment heat transfer oil

Composition Weight %

Triethylene glycol 45-98%

Bio-PDO 1-55％

Inhibiter 1-6%

Embodiment 96

Bubble-tight heat of liquid transduction agent

Composition Weight %

Bio-PDO 96.42％

Polyacrylic acid sodium salt 0.02%

Sodium Tetraborate 2%

Sodium Benzoate 1%

Sodium Nitrite 0.15%

SODIUMNITRATE 0.1%

Benzotriazole 0.2%

Polydimethylsiloxane 0.01%

Water glass 0.1%

Embodiment 97

The thermal conduction refrigerating fulid

Composition Weight %

Bio-PDO 45％

Propylene carbonate 5%

H2O 50％

Embodiment 98

Anti-freezing composition

Composition Weight %

The A part

Cellulose gum 0.5%

Lalgine 0.5%

Gelatin 2%

Water 47%

Bio-PDO 50％

The B part

Iron trichloride 5%

Water 45%

Bio-PDO 50％

Embodiment 99

Engine coolant

Bio-PDO 49.74％

Water 48.76%

Fluoro-tensio-active agent 0.01%

Inhibiter 1.29%

Defoamer 0.08%

Dyestuff 0.12%

Embodiment 100

The thermal conduction matrix material

This matrix material comprises that Bio-PDO and/or G ﹠ W are as main ingredient, and the C8-12 aliphatic dibasic acids and an alkali metal salt that comprise 0.5-5.0 weight %, 0.5-5.0 the phenylformic acid of weight % and an alkali metal salt, the thiazole of the triazole of 0.05-1.0 weight % and 0.01-0.5 weight %.

Embodiment 101

Reusable heat bag and delay in flow gel

Gel mat in the first flexible seal bag that the heat bag that is used for the treatment of purposes is included in pressure chamber from the expandable second flexible seal bag is connected.Gel comprises clay (wilkinite) and Bio-PDO, and comprises the filamentary material that prevents to flow and increase thermal capacity.

Embodiment 102

Non-aqueous heat transfer oil

The present invention relates to comprise the thermal conduction system of heat transfer oil.Heat-transfer fluid comprises non-buffered Bio-PDO and at least a molybdate that is selected from, the Bio-PDO of nitrate compound and azole compounds ^TMSoluble additive.

Embodiment 103

Be used for the antifreeze coolant composition that high temperature is used

The present invention includes improved antifreeze coolant composition, it has some additive (0.01 weight % is to 5.0 weight %), and this additive is used to increase the Bio-PDO of Bio-PDO/ water (5-95:95-5) coolant composition ^TMThe thermostability of component and minimizing Bio-PDO component are in the tendency of high heat condition degraded.These additives comprise the organic compound with carboxylic moiety and hydroxylic moiety, and tricarballylic acid.Another aspect of the present invention relates to the method for stability of the Bio-PDO component of the Bio-PDO/ water coolant composition in improvement engine cool/heating system, this method comprises: the Bio-PDO/ water coolant composition that preparation contains thermal stability additives forms improved coolant composition, and engine cool/heating system is contacted with improved coolant composition.

Embodiment 104

The deep cooling preservation composition of Bio-PDO and vehicle solution

Component Concentration

Bio-PDO 0.05M is to about 6.0M

0.5M to about 4.0M (more preferably)

0.5M to about 3.0M (most preferably)

EuroCollins solution:

Sodium (Na+) 10Mm

Potassium (K+) 115Mm

Chlorion (Cl-) 15Mm

Dihydrogen phosphate (H2PO4-) 15Mm

Hydrogen phosphate (HPO42-) 42.5Mm

Bicarbonate radical (HCO3) 10Mm

Glucose 194Mm

Embodiment 105

Aircraft deicing fluid

Composition: Weight %

Bio-PDO 92

Water 7.14

Polyglycol ether 0.2

EO/PO alcoxylates 0.2

KOH (50% solution) .06

Sandocorin 8132C 0.4

Embodiment 106

Aircraft deicing fluid

Composition: Weight %

Bio-PDO 45.5

Water 53.165

Tolyl-triazole 0.4

Silicon defoaming agent 0.2

Potassium hydroxide .035

Trolamine 0.3

Arylalkyl sulfonic acid sodium 0.4

Embodiment 107

Aircraft runway anti-freezing composition

Composition Weight %

Alkali metal carboxylate 20-25%

Alkaline earth metal carboxylation 1-15%

Bio-PDO 1-35％

Alkali metal phosphate 0.01-1%

Alkalimetal silicate 0.01-1%

Triazole 0.01-1%

Embodiment 108

Aircraft runway anti-freezing composition

Composition Weight %

Alkali metal carboxylate 1-40%

Alkaline earth metal carboxylation 1-25%

Bio-PDO 1-35％

Alkali metal phosphate 0.01-1%

Alkalimetal silicate 0.01-1%

Triazole 0.01-1%

Water reaches 100% in right amount

Embodiment 109

Aircraft frostproofer/deicing agent

Composition Weight %

Water 41%

Bio-PDO 50％

Polysaccharide 3%

Inhibiter 6%

Embodiment 110

The frostproofer that is used for the LPG jar of polyurethane foam lining

Composition Weight %

Virahol 40%

Bio-PDO 60％

Embodiment 111

Liquid carboxylic salt antifreeze composition

The liquid frostproofer compound that is suitable for road, runway and bridge comprises: (a) water-based alkali-metal carboxylate salt, particularly formate, propionic salt, and/or lactic acid salt; (b) be used for the inhibiter that galvanized steel is protected; (c) be used for the particularly auxiliary inhibiter of Al alloy of non-ferrous metal; (d) optional Bio-PDO.Inhibiter is the polyvalent metal mixture preferably, particularly La acetate hydrate or mix the aqueous solution and the optional Mg ionic compound of lanthanon salt, and/or sulphide salt.Frostproofer randomly comprises 50-10, and the tolyl-triazole of 000ppm is as the auxiliary inhibitor on non-ferrous metal surface.Typical moisture frostproofer comprises 50% potassium acetate, the tolyl-triazole of 0.15-0.75%, and the tri-thiol triazine trisodium salt of the lanthanon nitrate hexahydrate of 1.0-3.0% and 10.10-0.75% reaches 100% water in right amount.

Embodiment 112

Water activatory exothermicity chemistry deicing agent

The icing compositions that removes that is used for from the surface deicing is provided, it comprises succsinic acid or succinyl oxide, or the two, with in and matrix such as sodium hydroxide, potassium hydroxide, perhaps ammonium hydroxide wherein should remove icing compositions and generate succinate when mixing with water, and this is swift in response and discharges enough heats to melt lip-deep ice and succinate as frostproofer and freezing point lowering agent.Remove icing compositions and can further comprise Bio-PDO, the formation again of icing on its inhibition deicing surface.Remove icing compositions and be used for the airport that the wherein corrosion of aircraft alloy and concrete track is paid close attention to aptly and effectively.

Embodiment 113

Deicing fluid or anti-freeze fluid

Described nonelectrolyte, nontoxic, biodegradable anti-icing or remove icing compositions and comprise: (a) water; (b) be selected from following nontoxic freezing point lowering agent: C2-6 monohydroxy-alcohol, Bio-PDO, the mono-methyl of C3-12 polyvalent alcohol or mono ethyl ester, or its mixture, (c) nontoxic thickening material.Composition is to show pseudoplastic continuous single-phase liquid, and can be used on for example following surface: aircraft, runway Surface, road, walkway, bridge, inlet, buildings, groove, sluice, parts, container, navigation part, track switch and Motor vehicles.Typical composition comprises water, Bio-PDO ^TMAnd/or propyl alcohol and xanthan gum.

Embodiment 114

Animal feedstuff additive WO9733488A1

Composition Weight percentage

Sodium Propionate 10%

Bio-PDO 5％

White oil fat 40%

Filler 45%

(breast, fiber, cereal, and sweetener)

Embodiment 115

High energy feed supplement

Composition Weight percentage

Bio-PDO 25-48％

Glycerine 25-48%

The sour 1-17% that nutrition is suitable

(for example C2-C20 aliphatic carboxylic acid class)

Water 1-32%

VITAMIN and mineral substance 0001-4%

Embodiment 116

The aerosol combination US2006034978A1 that is used for animal-feed

Composition Weight percentage

Molasses 25%

Propylene glycol 23%

Soybean lecithin 10%

Water 22%

Bio-PDO 4.5％

Seasonings 0.5%

Trimethylmethane/propane/butane 15%

Embodiment 117

The ink jet printing liquid of perfuming

Composition Amount

Bio-PDO 94.2％

Glycerine 4.0%

FD&C Blue 1 1.6％

Balls of fire flavor 0.2％

Embodiment 118

The strawberry flavor enriched material

Composition Amount

Bio-PDO 53％

Ethanol 10%

Water 30%

Strawberry flavor 3%

Citric acid 4%

Embodiment 119

The edible pet chaw

Composition Amount

Protein 5-50%

Carbohydrate 20-80%

Bio-PDO 5-50％

Water 5-30%

Embodiment 120

The low-calorie sweetener surrogate

Composition Amount

Sorbyl alcohol 48.34%

Water 48.34%

Sodium alginate 0.4%

Calcium sulfate rabic te 0.3%

Guar gum 1.0%

Wheat plant fiber 0.5%

Bio-PDO 1.0％

Sweet (neotame) 0.02% of knob

Potassium sorbate 0.1%

Embodiment 121

Ice-creams waters and drenches material

Composition Amount

Seasonings 0.05-40%

Fat 0.01-50%

Bio-PDO 0.1-40％

Sweeting agent is the highest by 80%

Emulsifying agent is the highest by 10%

Water 0-20%

Embodiment 122

Frozen beverage

Composition Amount

Water 60.6%

Bio-PDO 20.2％

Polyethylene 18.3%

Propylene glycol alginic acid ester 0.7%

Caramel color 0.2%

Embodiment 123

The perfume delivery system

Composition Amount

Phenyl aldehyde 20%

Anhydrous sorbitol polyoxyethylene (20) oleic acid ester 40%

Bio-PDO 40％

Embodiment 124

Soft frozen chicken tail Wine

Composition Amount

Ethanol 2-15%

Bio-PDO 12-14％

The base perfume compound reaches 100% in right amount

Embodiment 125

Beverage perfuming microemulsion

Composition Amount

Flavor oil 4.1%

Polysorbate60 4.1%

Water 16.5%

Bio-PDO 75.4％

Embodiment 126

Food dressing

Composition Amount

L-glutamic acid 9.5g

IMP 0.25g

GMP 0.25g

Lactose 5.0g

Sodium-chlor 10.0g

Water 60.0kg

Bio-PDO 15.0kg

Embodiment 127

The thermostable type seasonings

Composition Amount

Tamarind seed gum 50g

Bio-PDO 50g

Water 200g

Trisodium phosphate 3g

Embodiment 128

The fried food product sanitas

Composition Amount

75 parts of soybean oil

20 parts in Yelkin TTS

5 parts of Bio-PDO

Embodiment 129

Non-aqueous beverage gel

Composition Amount

10 parts of methylcellulose gum

100 parts of Bio-PDO

Embodiment 130

The food preservation emulsifying agent

Composition Amount

Sunsoft 767 75%

Bio-PDO 15％

Water 7%

Sodium Glutamate 3%

Embodiment 131

Heat of liquid setting candy

Composition Amount

Bio-PDO 17.7％

Glyceryl monooleate 0.7%

Yelkin TTS 0.7%

Antioxidant 0.0%

Honey 0.1%

Tinting material 0.3%

Seasonings 0.3%

Tripotassium Citrate 1.2%

Artificial sweetner 0.2%

Glycerine 53.1%

Starch 23.6%

Carrageenin 2.1%

Embodiment 132

The fast food dumpling

Composition Amount

Fine flour 40-60 part

Yam starch 20-30 part

Amylcose acetate 10-20 part

Refined salt 0.5-5 part

Emulsifying agent 0.2-1 part

Sorbyl alcohol 2-8 part

Bio-PDO 2-6 part

Embodiment 133

The grated cheese sanitas

Composition Amount

20 parts of Bio-PDO

18 parts in sodium-chlor

0.1 part of lactic acid

0.1 part of propionic acid

2 parts of sucrose

0.05 part in xitix

0.1 part of Zerol

59.65 parts in water

Embodiment 134

The edible solid that is used for candy coating or cake or biscuit dough

Composition Amount

Bio-PDO 80％

Skim-milk 20%

Embodiment 135

The sanitas of ready-made/ready-to-eat

Composition Amount

50 parts of Bio-PDO

3 parts of acetate

1.5 parts of sodium acetates

(95%) 105.3 part of ethanol

Embodiment 136

The heterogeneous delivery system that is used for food supplement and meals surrogate

Composition Amount

Creatine monohydrate 16.71%

Glycerine 15.97%

Maize treacle 21.20%

High-fructose corn syrup 24.78%

Gelatin 5.51%

Bio-PDO 5.51％

Treated starch 2.75%

Water 4.96%

Other composition 2.61%

Embodiment 137

The mulberry leaf sanitas

Composition Weight % Total amount

Promoting agent 3-8%

Ph conditioning agent 20-30%

Oxysuccinic acid 1-35%

Citric acid 18-25%

Sorbic Acid 15-20%

Hydrochloric acid 8-14%

Phytic acid 16-25%

Dehydration acetate 8-15%

Redox agent 20-30%

Sodium sulfate 15-25%

Vitriolate of tartar 18-28%

Stomach en-25-40%

Papoid 5-42%

The wet active agent 20-30% that reduces

Trisodium phosphate 10-15%

Sodium-chlor 6-10%

Bio-PDO 8-15％

Agar 5-40%

Carrageenin (Kara gum) 15-25%

Gelatin 21-30%

Sterilizing agent 15-25%

Josamycin 15-40%

Fupaisuan 18-25％

Phage 22-30%

N,O-Diacetylmuramidase 20-30%

Water reaches 100% in right amount

Embodiment 138

The clarification product

Composition Amount

Collagen 3-40%

Bio-PDO 2-50％

Buffering system 0.5-5%

Sanitas 0.1-5%

Embodiment 139

Herbivore is used the semi-humid feed

Composition Amount

Gelling starch 5-55%

Sugar 5-80%

Bio-PDO 2-8％

Water 15-30%

Embodiment 140

The bakery product sanitas

Composition Amount

Ethanol 1.0%

Bio-PDO 0.5％

Acetate 0.03%

Sodium acetate 0.02%

Water 98.45%

(sweet ground rice 600g, water 400Ml and sanitas 16g)

Embodiment 141

Starch and (or) protein starting material food wetting Agent for Printing Inks

Composition Amount

Bio-PDO 40-90％

Sorbyl alcohol 10-60%

(breaded fish stick (Pu is tried to gain (kamaboko)) 96% and wetting Agent for Printing Inks 4%)

Embodiment 142

The solid food seasonings

Composition Amount

Bio-PDO 1-70 part

10 parts in gelatin

Seasonings ^*The total solids of 80-93%

^*Tomato-sauce, vinegar, pomace, dried onion sheet, mustard, pickles seasonings

Embodiment 143

Microbiologically stabilisedization, ripe dehydrated meat, vegetables or fruit

Composition Amount

Cryodesiccated chicken 34.3%

Glycerine 32.4%

H2O 27.8％

Salt 0.8%

Sugar 1.5%

Monosodium glutamate 1.8%

Bio-PDO 1.1％

Potassium sorbate 0.3%

Embodiment 144

The stabilising emulsifier that is used for bulk cake and cream

Composition Amount

Sorbyl alcohol (70%) 570g

Bio-PDO 200g

Ethanol 20g

Water 800g

Sucrose monostearate 160g

Sodium hydroxide (10%) 16ml

Propylene glycol monostearate 40g

Zerol 200g

Embodiment 145

The fruit coating

Composition Amount

Bio-PDO 5％

Water 45%

Ethanol 50%

Embodiment 146

Through meat coating freezing or that handle

Composition Amount

45 parts of cellulose propionate thin slices

55 parts of tributyl acetylcitrates

5 parts of Bio-PDO

Embodiment 147

The stablizer that is used for half-dried feed

Composition Amount

Bio-PDO 51.2％

Glycerine 35.3%

Sorbyl alcohol 13.5%

Embodiment 148

The salt brine solution that is used for frozen fresh food (fish, meat, plant etc.)

Composition Amount

Ethanol 40-60%

Bio-PDO 2-20％

Sanitas 0.05-1%

H2O reaches 100% in right amount

Embodiment 149

Lyeopene pigment

Composition Amount

Lyeopene pigment 0.8g

Natural VE 0.2g

Limonene 2g

Plam oil 5g

SAIB 6g

Water 60g

Gum arabic 20g

L-xitix 0.1g

Bio-PDO 10g

Embodiment 150

Honey surrogate low in calories

Composition Amount

Carboxymethyl cellulose gum 0.500%

HPMC glue 0.500%

Xanthan gum 0.223%

Propylene glycol alginic acid ester 0.0525%

Sodium bicarbonate 0.131%

Glycerine 5.91%

Bio-PDO 1.31％

Aspartame 0.223%

Acesulfame K 0.0421%

Food color blend 0.237%

Honey spices 0.17%

Vanilla extract 0.0657%

Water 90.7%

Embodiment 151

The process water chankings

Composition Weight % In sheet, account for %

Soft strawberry core 90.0%

Maize treacle 20.3%

Blueberry spices 1.1%

Bio-PDO 52.8％

Water 7.2%

Modified corn starch 5.4%

Modified tapioca starch 5.5%

Fructose 4.0%

Oxysuccinic acid 0.7%

Citric acid 1.0%

Grape skin color tinting material 1.0%

Exsiccant blueberry powder 0.5%

Salt 0.5%

100％

Film coating 10.0%

Trisodium Citrate 0.23%

Water 76.98%

Gellan gum 0.59%

Citric acid 0.20%

Sucrose 10.0%

Grape skin color tinting material 0.5%

Blueberry powder 0.5%

Bio-PDO 10.0％

Sunflower oil 0.5%

100％

Embodiment 152

Produce the method for feed

Composition Weight percentage

Fish meal 70%

Wheat-flour 19%

Bio-PDO 6％

Soybean cake 3%

VITAMIN 3%

Mineral substance 0.8%

Salt 0.4%

Embodiment 153

Agrochemicals suspension

Composition Weight percentage

Ammonium sulfate 30-70%

Bio-PDO 20-80％

RC-630 1-9％

Embodiment 154

Liquid and pasty state motor vehicle sanitising agent

Composition Weight percentage

Bio-PDO 0.5-20％

Fatty acid distribution of coconut oil alkanolamine 0.8-50%

Zetesol NL 0.5-45%

Sodium lauryl sulphate 0.5-40%

Witco 1298 Soft Acid 1-50%

Cocamidopropyl betaine 1-35%

Fatty acid distribution of coconut oil diglycollic amide 0.3-35%

Trolamine 1-30%

Tri sodium Phosphate 0.2-10%

Starso 0.5-20%

NaCl 0.2-10％

MgCl2 0.2-10％

NaOH 0.2-10％

Formaldehyde 0.1-5%

Pigment/dye 0.1-50%

Spices 0.3-10%

Embodiment 155

Emulsion paint

Composition Weight percentage

Water 10-40%

Natvosol 0.2-1.0%

Defoamer 0.2-1.0%

Dispersion agent 0.2-1.0%

Mould inhibitor and sanitas 0.2-0.8%

Bio-PDO 1-5％

Pigment 5-30%

White bole 10-50%

Nanoparticle 0.5-1.5%

Silicone resin 0.5-1.5%

Copolymer in cinnamic acrylic ester microemulsion 15-45%

Film coalescence aid 0.5-5%

Auxiliary 0.2-1.0%

Embodiment 156

Rainproof coating

Composition Weight percentage

Acrylic acid series emulsion 23-32

Polycarboxylate salt dispersant 0.5-1.2

Defoamer BA-202 0.4-1.0

Bio-PDO 1.5-2.5

Sanitas LXE 0.1-0.3

KOH(40％) 0.2-0.4

Ester12 is as film coalescence aid 1.5-2.5

Vinylformic acid polycarboxylate thickening material 0.5-1.5

Nano level SiO2 1.0-3.0

Nano level TiO2 0.8-1.8

Titanium dioxide 10-20

Lime carbonate 8-15

White bole 8-15

Fluorocarbon resin 5-15

Deionized water 10-20

Embodiment 157

Be used for the ink-jet of food printing

Composition Weight percentage

Bio-PDO 92％

Glycerine 4%

Virahol 2%

FD&C Blue No.1 2％

Embodiment 158

The cuttlefish ink mixture

Composition Weight percentage

Cuttlefish printing ink 15-30%

Bio-PDO 15-30％

Sweeting agent 30-60%

Ethanol 10-15%

Embodiment 159

Blue writing ink

Composition Weight percentage

Bio-PDO 1-10％

Prussian blue 1.0-5%

Oxalic acid 0.2-5%

DBS 0.01-2%

Gum□rabic 0.1-1％

Inhibiter 0.1-1%

Water reaches 100% in right amount

Embodiment 160

Hydrodynamic lubrication liquid

Composition Weight percentage

Epoxy ethane-epoxy propane-glycerine 27.6%

Bio-PDO 16.7％

PEG-600 6.6％

Styrene-maleic acid polyester 5.0%

Methyl phenyl silicone 0.5%

Trolamine 0.5%

Benzotriazole 0.1%

NaNO2 0.5％

Water 42.5%

Embodiment 161

Liquid suspension

Composition Weight percentage

Bio-PDO 27.6％

Glycerine 47.0%

Polymer-type fatty acid ester 0.2%

Dispersion agent 0.2%

Polyethylene oxide (doing) 25%

Embodiment 162

The liquid denitrfying agent that is used for oil

Composition Weight percentage

Bio-PDO 5-20％

Ethylene glycol 10-30%

Propionic acid 10-20%

Propanedioic acid 20-50%

Oxalic anhydride 20-30%

Embodiment 163

Pharmaceutical composition

Composition Weight percentage

Pharmaceutically active agents (1) 0.35%

Pharmaceutically active agents (2) 0.28%

Phenylephrine hydrochloride 0.28%

Methyl p-hydroxybenzoate 0.25%

Propylparaben 0.03%

Bio-PDO 7.30％

Soluble saccharin 0.09%

Citric acid 0.14%

Strawberry flavor 0.28%

Banana spices 0.28%

Sorbyl alcohol (70%) 90.56%

Water 0.14%

Embodiment 164

Pharmaceutical composition

Composition Weight percentage

Polyoxyethylene hydrogenated castor oil 5-50%

Azone 0-10%

Radix Ginseng extract 0-10%

Folium Ginkgo extract 0-10%

Collagen protein 0-10%

Hyaluronic acid 0-3%

Wallantoin 0.1-1%

Zinc Gluconate 0-3%

Vitamins C 0.1-1%

Vitamin-E 0.01-0.1%

Bio-PDO 3-30％

Glycerine 3-30%

Embodiment 165

The soluble oil mixture

Composition Weight percentage

Polyglycol ether 70-90%

Water-resin (water resin) 5-15%

Flow agent 0.5-1.5%

Bio-PDO 0.5-1.5％

Polyethylene wax oxide compound 1-7%

Deionized water 1.5-10%

Embodiment 166

Sterilant and antifouling dispersion agent

Composition Weight percentage

Alkyl dimethyl benzyl ammonium chloride 5.0-45.0%

Dialkyl dimethyl ammonium chloride 1.0-15%

Bio-PDO 10-3.0％

Water reaches 100% in right amount

Embodiment 167

Be used for water system and suppress corrosion and sedimentary composition

Composition Weight percentage

Oxygen base second two basic bisphosphate 1-58%

Alkyl-dimethyl amine oxide 1-26%

Bio-PDO 1-30％

Water reaches 100% in right amount

Embodiment 168

The polyblend of fully biodegradable

Composition Weight percentage

Starch 30-60

Polyvinyl alcohol 10-35

Ethylene-acrylic acid copolymer 2-5

Ethylene glycol 0-25

Polyoxyethylene glycol 0-25

Bio-PDO 0-25

Polypropylene glycol 0-25

Acetate sorbitol ester 0-25

Ethoxylated sorbitol 0-25

Glycerine 0-25

Magnesium hydroxide 2-5

Magnesium borate 0.2-0.4

Water 10-20

Embodiment 169

The embryo transfer of cryopreservation and rabbit oocyte in vitro fertilization

After with the induced ovulation of HCG injection 13 hours, the ovocyte of the ovulation of collecting from virgin's uterine tube can be lentamente by cryopreservation to-30 ℃ and directly the input liquid nitrogen.The mixture of the Bio-PDO of use 1.5M and the sucrose of 0.1M is as frostproofer.After thawing, ovocyte was cultivated 5 hours with the seminal fluid of external capacitation in the Brackett ' s substratum of regulation.Then zygote was cultivated other 20 hours, up to reaching 4 to 8 cell division phases.These embryos are transferred on the false pregnancy receptor rabbit, and rabbit says it should is " nonsynchronous " on the meaning that was given the HCG injection in 30,24 and 18 hours before the beginning embryo transfer.

Claims (25)

1. comprise 1, the biodegradable composition of ammediol and composition, wherein said 1, the bio-based carbon content of ammediol is at least 1%.

2. the biodegradable composition of claim 1, wherein composition is selected from: acceptable carrier, promoting agent, water, aqueous solution, tensio-active agent, auxiliary agent (builder), pH regulator agent, inhibiter, defoamer, dyestuff and food ingredient.

3. the biodegradable composition of claim 1 further comprises being selected from following composition: the personal care product, and cosmetics, sanitising agent, the thermal conduction composition removes icing compositions, food, coating and printing ink.

4. the biodegradable composition of claim 1, wherein 1, ammediol has at least 5% bio-based carbon.

5. the biodegradable composition of claim 1, wherein 1, ammediol has at least 10% bio-based carbon.

6. the biodegradable composition of claim 1, wherein 1, ammediol has at least 25% bio-based carbon.

7. the biodegradable composition of claim 1, wherein 1, ammediol has at least 50% bio-based carbon.

8. the biodegradable composition of claim 1, wherein 1, ammediol has at least 75% bio-based carbon.

9. the biodegradable composition of claim 1, wherein 1, ammediol has at least 90% bio-based carbon.

10. the biodegradable composition of claim 1, wherein 1, ammediol has at least 99% bio-based carbon.

11. the biodegradable composition of claim 1, wherein 1, ammediol has 100% bio-based carbon.

12. the biodegradable composition of claim 1, wherein 1, ammediol is the biology origin.

13. the biodegradable composition of claim 12, wherein 1 of the biology origin, ammediol generates by fermenting process biology.

14. comprise 1, the biodegradable composition of ammediol, wherein said 1, ammediol is lower than about 0.200 and be lower than about 0.075 and be lower than about 0.075 at the ultraviolet absorptivity of 275nm at the ultraviolet absorptivity of 250nm at the ultraviolet absorptivity of 220nm.

15. the biodegradable composition of claim 14 is wherein said 1, the ＂ b ＂ colour of ammediol is lower than about 0.15 and be lower than about 0.050 in the absorbancy of 275nm.

16. the biodegradable composition of claim 14 is wherein said 1, the peroxide concentrations of ammediol is lower than about 10ppm.

17. the biodegradable composition of claim 14 is wherein said 1, ammediol has the concentration of the total organic impurity in described composition that is lower than about 400ppm.

18. the biodegradable composition of claim 14 is wherein said 1, the concentration of total organic impurity of ammediol is lower than about 300ppm.

19. the biodegradable composition of claim 14 is wherein said 1, the concentration of total organic impurity of ammediol is lower than about 150ppm.

20. comprise 1, the biodegradable composition of ammediol, wherein said 1, the concentration of total organic impurity of ammediol is lower than about 400ppm.

21. the biodegradable composition of claim 20 is wherein said 1, the concentration of total organic impurity of ammediol is lower than about 300ppm.

22. the biodegradable composition of claim 20 is wherein said 1, the concentration of total organic impurity of ammediol is lower than about 150ppm.

23. the biodegradable composition of claim 20 is wherein said 1, the concentration of the superoxide of ammediol is lower than about 10ppm.

24. the biodegradable composition of claim 20 is wherein said 1, the concentration of the carbonyl of ammediol is lower than about 10ppm.

25. comprise 1, the biodegradable composition of ammediol, 1 in the wherein said composition, the people that ammediol has when biological degradation is zero for the CO2 discharging.

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