CN101402529B - Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground - Google Patents
Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground Download PDFInfo
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- CN101402529B CN101402529B CN2008101698231A CN200810169823A CN101402529B CN 101402529 B CN101402529 B CN 101402529B CN 2008101698231 A CN2008101698231 A CN 2008101698231A CN 200810169823 A CN200810169823 A CN 200810169823A CN 101402529 B CN101402529 B CN 101402529B
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Abstract
The invention relates to cream stamp-pad ink for printing patterns on mesh plates of ceramic tiles, which is a mixture consisting of the following compositions by weight: 20 to 35 percent of ethylene glycol, 20 to 35 percent of glycerol, 30 to 45 percent of sorbitol, 1 to 7 percent of cellulose, 2 to 8 percent of a macromolecule polymer, and 0.2 to 1.0 percent of an exciting agent. The appearanceof the cream stamp-pad ink is of milk white cream shape without off flavor; the viscosity is between 4,800 and 5,200 MPa.S; the density at 20 DEG C is between 1.040 and 1.050; the pH value is between6 and 8; the water-soluble residue with 360 meshes is less than or equal to 0.2 percent; and the freezing point is 10 DEG C below zero. The burnt ash content of products is low without residues; the stability and the suspending power are good without layering; the proportion and the viscosity are adjustable; pattern-printing glaze slurry prepared from the cream stamp-pad ink can be used normally on-line after storage without the appearances of color differences and pinholes; and the cream stamp-pad ink is applicable to the pattern-printing requirements for various high-grade, middle grade andlow grade ceramic tiles produced by different ceramic building factories. The pattern-printing glaze slurry prepared from the cream has certain fluidity, the performances of moisture, lubrication, mesh brightening and the like, and increases the adhesive force of the pattern-printing glaze slurry on blanks; besides, the surface of a sintered tile finished product is smooth and has no defects of unevenness, pinholes and the like, and the patterns are clear and bright.
Description
Technical field
The invention belongs to the emulsifiable paste stamp-pad ink category in the ceramic industry, particularly a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground.This emulsifiable paste stamp-pad ink suitability is strong, can satisfy the different demands of all size internal wall brick and floor tile stamp fully; On high light brick, press polish brick, crystal brick, brick modelled after an antique, internal wall brick etc., can both use.
Background technology
Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground product in the prior art, quality and not fully up to expectations, or its proportion, thick dilution exists not enoughly, places and is easy to precipitated and separated, aberration occurs; Or oilness, saturating net are poor; Or a little less than the bonding force of glaze slip to base substrate, it is poor to burn till ceramic wall and floor bricks surface, back tidiness, has concavo-convex, pin hole or pattern clear inadequately, defectives such as luminance difference.
Summary of the invention
The application's goal of the invention provides and a kind ofly can overcome above-mentioned drawback, and effect is a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground of ideal comparatively.
The objective of the invention is to implement by following technical solution:
Develop a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground, it is characterized in that the mixture that it is made of by weight following each component: ethylene glycol 20～35, glycerol 20～35, sorbyl alcohol 30～45, Mierocrystalline cellulose 1～7, high molecular polymer 2～8, exciting agent 0.2～1.0;
Its proterties is: the appearance milky white paste, do not have bad smell; Viscosity 4800～5200MPaS; 20 ℃ of density 1.040～1.050; PH value 6～8; 360 order water-soluble residue≤0.2%; Freezing point-10 ℃.
Above-mentioned a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground is characterized in that described Mierocrystalline cellulose is meant carboxymethyl cellulose, Natvosol or hydroxypropylcellulose, wherein any one.
Above-mentioned a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground is characterized in that described high molecular polymer is meant the polypropylene glycol of vinylformic acid, acrylamide or molecular weight 〉=5000, wherein any one.
Above-mentioned a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground is characterized in that described exciting agent is meant Sodium Persulfate, Ammonium Persulfate 98.5 or Potassium Persulphate, wherein any one.
The method for making of above-mentioned a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground, it is characterized in that taking by weighing each component, add ethylene glycol, glycerol earlier by dosage, sorbyl alcohol and high molecular polymer, stir,, progressively evenly add exciting agent at 50～75 ℃, the following reaction of stirring adds Mierocrystalline cellulose and stirs evenly after 1～5 hour, measure viscosity and reach between 4800～5200MPaS, proportion reaches 1.040～1.050 afterreactions to be finished, and promptly obtains product.
The application of above-mentioned a kind of emulsifiable paste stamp-pad ink is characterized in that the application in the ceramic wall and floor bricks lamina printing decoration.
Advantage of the present invention is:
1. applicable to the various height of different building ceramics factories productions, the stamp demand of low and middle-grade ceramic wall and floor bricks; Proportion, viscosity can be according to the customer requirement adjustment.
2. emulsifiable paste stamp-pad ink good stability, suspending power is good, places not stratified.Dry place can deposit more than 6 months in the cool place, and quality product is not had influence.With the glaze slip of this emulsifiable paste stamp-pad ink configuration, one, can store 2 months the fourth quater; Or two, three season can store 1 month, still can guarantee the use of normally reaching the standard grade, and aberration, pin hole can not occur.
3. the stamp glaze slip with emulsifiable paste of the present invention configuration has certain fluidity, and performance such as the net of preserving moisture, lubricate, feel well, and has increased the cohesive force of stamp glaze slip to base substrate.
4. emulsifiable paste stamp-pad ink calcination ash content of the present invention is low, no residue, and it is smooth to burn the finished product wall floor tile surfacing that with the glaze slip of its configuration, flaws such as no concave-convex, pin hole, clear patterns light.
Embodiment
Below in conjunction with embodiment the present invention is further set forth:
Embodiment 1
Weight proportion:
Ethylene glycol 30kg, glycerol 20kg, sorbyl alcohol 45kg, Mierocrystalline cellulose carboxymethyl cellulose 1kg, high molecular polymer vinylformic acid 8kg, exciting agent Sodium Persulfate 0.2kg;
Ethylene glycol (ethyleneglycol), Beijing Yanshan Petrochemical Co. commodity, specification: the transparent thick liquid of appearance colorless, relative density (d20/4) 1.1130～1.1140,197.6 ℃ of boiling points, muriate (in Cl-) %≤0.0001, ash content %≤0.003.
Glycerol (glycerol) Qilu Petrochemical product, specification: appearance colorless thick liquid, content 〉=95%, 17.8 ℃ of fusing points, 290 ℃ of boiling points, relative density 1.2636 (20/20 ℃), 160 ℃ of flash-points, refractive index 1.4746.
Sorbyl alcohol (D-Sorbitol Powder), Shanghai detergents and cosmetic factory product, specification: appearance white crystalline powder, content (butt) 〉=91%, total sorbitol (butt) 〉=97%, moisture≤1%, arsenic (in As)≤3mg/kg, heavy metal (in Pb)≤10mg/kg.
Xylo-Mucine (Carmellose Sodium), Shandong Linyi City China imperial chemical plant commodity, specification: appearance white or micro-yellow powder, viscosity (2% aqueous solution) 〉=1200MpaS, sodium content 6.5～8.5%, pH value 6.5～8.0, moisture≤10%, substitution value (Degree of Substitution is called for short D.S) 0.9.
Vinylformic acid, specification: content 〉=99%, moisture≤0.1%, stopper 200 ± 20ppm, manufacturer Dongfang Chemical Plant, Beijing, The East Chemical Plant,Beijing.
Exciting agent uses Sodium Persulfate, appearance white crystalline powder, content 〉=98%, molysite (in Fe)≤0.04%, manufacturer Nanjing clock wound chemical industry company limited.
Reaction: take by weighing each component by dosage, add ethylene glycol earlier, glycerol, sorbyl alcohol and high molecular polymer vinylformic acid stir, at 50～60 ℃, evenly add exciting agent, stir reaction down and add carboxymethyl cellulose after 2～3 hours and stir evenly, measure viscosity and reach between 4800～5200MPaS, after proportion reached 1.040～1.050, reaction was finished and is promptly obtained product.
The product company standard: the appearance milky white paste, do not have bad smell; Viscosity 4800～5200MPaS; 20 ℃ of density 1.040～1.050; PH value 6～8; 360 order water-soluble residue≤0.2%; Freezing point-10 ℃.
Quality test: the appearance milky white paste, do not have bad smell; Viscosity 4900MPaS (Shanghai precision instrument factory, ND-J-1xin type rotary viscosity design determining); 20 ℃ of density 1.047 (the accurate weighting method of standard specific gravity cup is measured); PH value 7.0; 360 order water-soluble residues 0.2%; Freezing point-10 ℃; Product uses through practice, reaches the quality index of expection, meets the requirements of the customers.
Embodiment 2
Ethylene glycol 25kg, glycerol 35kg, sorbyl alcohol 30kg, Natvosol 7kg, high molecular polymer acrylamide 2kg, exciting agent Potassium Persulphate 1kg.
Natvosol (HEC) white or pale yellow powder, substitution value (D.S) 1.2-2.0; Moisture (%)≤7; Relative molecular weight 〉=305; Ph value 6-7; Water-insoluble≤2%; Viscosity (mpa.s) 2% aqueous solution 〉=8000,20 ℃ of aqueous solution 5-60000;
Acrylamide, specification: appearance white powder, content 〉=95%, moisture≤0.1%, manufacturer Beijing Chemical Plant.
Exciting agent uses: Potassium Persulphate, appearance white crystalline powder, content 〉=98%, amount of nitrides (in N)≤0.35%, molysite (in Fe)≤0.04%, manufacturer Nanjing clock wound chemical industry company limited.
Take by weighing each component by dosage, add ethylene glycol earlier, glycerol, sorbyl alcohol and acrylamide stir, at 60～65 ℃, evenly add the exciting agent Potassium Persulphate, stirring reaction adds Natvosol and stirs evenly after 1.5～3 hours, measures viscosity and reaches between 4800～5200MPaS, proportion reaches 1.040～1.050 afterreactions to be finished, and promptly obtains product.
Quality test: the appearance milky white paste, do not have bad smell; Viscosity 4800MPaS (Shanghai precision instrument factory, ND-J-1xin type rotary viscosity design determining); 20 ℃ of density 1.040 (the accurate weighting method of standard specific gravity cup is measured); PH value 6.5; 360 order water-soluble residues 0.152%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 3
Ethylene glycol 27kg, glycerol 25kg, sorbyl alcohol 43kg, hydroxypropylcellulose 3～4kg, high molecular polymer polypropylene glycol 4kg, exciting agent Ammonium Persulfate 98.5 0.3kg;
Hydroxypropylcellulose specification: white or micro-yellow powder, propoxyl group≤80.5%; Moisture (%)≤10; Relative molecular weight 〉=305; Ph value 5-8; Arsenic≤3mg/kg; Lead≤10mg/kg; Chemical plant, Huian, manufacturer Xi'an.
Exciting agent uses Ammonium Persulfate 98.5, appearance white crystalline powder, molysite (in Fe)≤0.04%, acidity (with sulphur acid meter)≤0.10%, manufacturer Nanjing clock wound chemical industry company limited.
Polypropylene glycol: appearance white powder, relative molecular weight 〉=5000; Manufacturer Jiangsu profit peace petroleum chemical plant.
Take by weighing each component by dosage, add ethylene glycol earlier, glycerol, sorbyl alcohol and high molecular polymer polypropylene glycol stir, at 65～75 ℃, evenly add exciting agent, add hydroxypropylcellulose behind stirring reaction 1.5～3h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product.
Quality test: the appearance milky white paste, do not have bad smell; Viscosity 4950MPaS (Shanghai precision instrument factory, ND-J-1xin type rotary viscosity design determining); 20 ℃ of density 1.045 (the accurate weighting method of standard specific gravity cup is measured); PH value 6.5; 360 order water-soluble residues 0.18%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 4
Ethylene glycol 28kg, glycerol 27kg, sorbyl alcohol 41kg, acrylamide 3kg, carboxymethyl cellulose 4kg, Ammonium Persulfate 98.5 0.5kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and acrylamide, stir evenly,, evenly add the exciting agent Ammonium Persulfate 98.5 at 50～65 ℃, adding carboxymethyl cellulose behind reaction 2～4h under stirring stirs evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product;
Quality test: the appearance milky white paste, do not have bad smell; Viscosity 5150MPaS; 20 ℃ of density 1.048; PH value 8.0; 360 order water-soluble residues 0.13%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 5
Ethylene glycol 26kg, glycerol 29kg, sorbyl alcohol 40kg, polypropylene glycol 6kg, Mierocrystalline cellulose hydroxypropylcellulose 3kg, exciting agent Sodium Persulfate 0.4kg;
Ethylene glycol, glycerol, sorbyl alcohol and polypropylene glycol stir evenly, at 65～75 ℃, evenly add the exciting agent Sodium Persulfate, add hydroxypropylcellulose behind stirring reaction 3～5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product;
Quality test: appearance milky white paste, viscosity 5050MPaS; 20 ℃ of density 1.045; PH value 6.5; 360 order water-soluble residues 0.17%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 6
Ethylene glycol 29kg, glycerol 20kg, sorbyl alcohol 31kg, vinylformic acid 5kg, Mierocrystalline cellulose Natvosol 1kg, exciting agent Potassium Persulphate 0.6kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and vinylformic acid, stir evenly, evenly add the exciting agent Potassium Persulphate, add Natvosol behind stirring reaction 1～2.5h and stir evenly at 50～55 ℃, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product; Quality test: appearance milky white paste, viscosity 5200MPaS; 20 ℃ of density 1.046; PH value 7.0; 360 order water-soluble residues 0.12%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 7
Ethylene glycol 20kg, glycerol 30kg, sorbyl alcohol 33kg, acrylamide 4kg, carboxymethyl cellulose 2kg, Sodium Persulfate 0.9kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and acrylamide stir evenly, at 55～65 ℃, evenly add exciting agent, add carboxymethyl cellulose behind stirring reaction 2.5～4.5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is after 1.040～1.050, and reaction is finished and promptly obtained product;
Quality test: viscosity 5100MPaS; 20 ℃ of density 1.046; PH value 7.0; 360 order water-soluble residues 0.19%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 8
Ethylene glycol 25kg, glycerol 23kg, sorbyl alcohol 37kg, vinylformic acid 8kg, hydroxypropylcellulose 5kg, Ammonium Persulfate 98.5 1.0kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and vinylformic acid stir evenly, at 60～65 ℃, evenly add Ammonium Persulfate 98.5, add hydroxypropylcellulose behind stirring reaction 1～2h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product;
Quality test: viscosity 4800MPaS; 20 ℃ of density 1.044; PH value 6.5; 360 order water-soluble residues 0.11%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 9
Ethylene glycol 30kg, glycerol 27kg, sorbyl alcohol 39kg, polypropylene glycol 2kg, Natvosol 4kg, Sodium Persulfate 0.2kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and polypropylene glycol stir evenly, at 70～75 ℃, evenly add Sodium Persulfate, add Natvosol behind stirring reaction 1～2.5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product; Quality test: viscosity 5100MPaS; 20 ℃ of density 1.050; PH value 7.5; 360 order water-soluble residues 0.15%; Freezing point-10 ℃; All the other are with embodiment 1.
Embodiment 10
Ethylene glycol 35kg, glycerol 29kg, sorbyl alcohol 45kg, acrylamide 3kg, carboxymethyl cellulose 3kg, Potassium Persulphate 0.3kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and acrylamide stir evenly, at 50～60 ℃, evenly add Potassium Persulphate, add carboxymethyl cellulose behind stirring reaction 1～3h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is after 1.040～1.050, and reaction is finished and promptly obtained product;
Quality test: appearance milky white paste, viscosity 5120MPaS; 20 ℃ of density 1.049; PH value 8.0; 360 order water-soluble residues 0.14%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 11
Ethylene glycol 20kg, glycerol 31kg, sorbyl alcohol 30kg, vinylformic acid 6kg, Mierocrystalline cellulose hydroxypropylcellulose 3kg, exciting agent Sodium Persulfate 0.4kg;
Ethylene glycol, glycerol, sorbyl alcohol and vinylformic acid stir evenly, at 65～75 ℃, evenly add the exciting agent Sodium Persulfate, add hydroxypropylcellulose behind stirring reaction 3～5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is after 1.040～1.050, and reaction is finished and promptly obtained product;
Quality test: appearance milky white paste, viscosity 5050MPaS; 20 ℃ of density 1.045; PH value 6.5; 360 order water-soluble residues 0.17%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 12
Ethylene glycol 24kg, glycerol 33kg, sorbyl alcohol 45kg, polypropylene glycol 4kg, Mierocrystalline cellulose hydroxypropylcellulose 1kg, exciting agent Potassium Persulphate 0.7kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and polypropylene glycol stir evenly, at 70～75 ℃, evenly add exciting agent, add hydroxypropylcellulose behind stirring reaction 4～5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product; Quality test: appearance milky white paste, viscosity 7950MPaS; 20 ℃ of density 1.049; PH value 7.5; 360 order water-soluble residues 0.18%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 13
Ethylene glycol 35kg, glycerol 35kg, sorbyl alcohol 4kg, acrylamide 5kg, carboxymethyl cellulose 6kg, Sodium Persulfate 0.9kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and acrylamide, stir evenly,, evenly add the exciting agent Sodium Persulfate at 60～70 ℃, adding carboxymethyl cellulose behind stirring reaction 1.5～3.5h stirs evenly, measure viscosity between 4800～5200MPaS, proportion is after 1.040～1.050, and reaction is finished and promptly obtained product;
Quality test: viscosity 5200MPaS; 20 ℃ of density 1.047; PH value 7.5; 360 order water-soluble residues 0.16%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 14
Ethylene glycol 33kg, glycerol 23kg, sorbyl alcohol 45kg, vinylformic acid 6kg, Natvosol 5kg, Ammonium Persulfate 98.5 0.2kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and vinylformic acid stir evenly, at 50～55 ℃, evenly add Ammonium Persulfate 98.5, add hydroxypropylcellulose behind stirring reaction 1.5～2.5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product;
Quality test: viscosity 4850MPaS; 20 ℃ of density 1.048; PH value 7.5; 360 order water-soluble residues 0.17%; Freezing point-10 ℃.All the other are with embodiment 1.
Embodiment 15
Ethylene glycol 29kg, glycerol 24kg, sorbyl alcohol 41kg, polypropylene glycol 7kg, carboxymethyl cellulose 4kg, Ammonium Persulfate 98.5 0.7kg;
Add ethylene glycol earlier, glycerol, sorbyl alcohol and polypropylene glycol stir evenly, at 60～65 ℃, evenly add Ammonium Persulfate 98.5, add Natvosol behind stirring reaction 1～2.5h and stir evenly, measure viscosity between 4800～5200MPaS, proportion is finished at 1.040～1.050 afterreactions, promptly obtains product; Quality test: viscosity 5200MPaS; 20 ℃ of density 1.050; PH value 7.5; 360 order water-soluble residues 0.15%; Freezing point-10 ℃; All the other are with embodiment 1.
Claims (3)
1. emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground is characterized in that the mixture that it is made of by weight following each component:
Ethylene glycol 20～35, glycerol 20～35, sorbyl alcohol 30～45, carboxymethyl cellulose, Natvosol or hydroxypropylcellulose 1～7, the polypropylene glycol 2～8 of vinylformic acid, acrylamide or molecular weight 〉=5000, Sodium Persulfate, ammonium persulphate or Potassium Persulphate 0.2～1.0;
Its proterties is: the appearance milky white paste, do not have bad smell; Viscosity 4800～5200MPaS; 20 ℃ of density 1.040～1.050; PH value 6～8; 360 order water-soluble residue≤0.2%; Freezing point-10 ℃.
2. according to the method for making of the described a kind of emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground of claim 1, it is characterized in that taking by weighing each component by dosage, add ethylene glycol earlier, glycerol, the polypropylene glycol of sorbyl alcohol and vinylformic acid, acrylamide or molecular weight 〉=5000 stirs, at 50～75 ℃, progressively evenly add Sodium Persulfate, Ammonium Persulfate 98.5 or Potassium Persulphate 0.2～1.0; The following reaction of stirring adds carboxymethyl cellulose, Natvosol or hydroxypropylcellulose after 1～5 hour and stirs evenly; Measure viscosity and reach between 4800～5200MPaS, proportion reaches 1.040～1.050 afterreactions to be finished, and promptly obtains product.
3. the application according to the described emulsifiable paste stamp-pad ink of claim 1 is characterized in that the application in the ceramic wall and floor bricks lamina printing decoration.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2008101698231A CN101402529B (en) | 2008-06-20 | 2008-09-28 | Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground |
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| CN200810017023.8 | 2008-06-20 | ||
| CN200810017023 | 2008-06-20 | ||
| CN2008101698231A CN101402529B (en) | 2008-06-20 | 2008-09-28 | Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground |
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| CN104130024B (en) * | 2014-07-23 | 2015-06-17 | 广东宏陶陶瓷有限公司 | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile |
| CN106866182A (en) * | 2016-12-30 | 2017-06-20 | 信阳科美新型材料有限公司 | Light thermal-insulation ceramic decorative panel hanging sand glaze and its preparation and application method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116194A (en) * | 1994-08-05 | 1996-02-07 | 江明 | Vegetable glycerin and producing technology |
| CN1485302A (en) * | 2002-09-29 | 2004-03-31 | 深圳市日月合天广告发展有限公司 | Process for producing luminous ceramic products |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116194A (en) * | 1994-08-05 | 1996-02-07 | 江明 | Vegetable glycerin and producing technology |
| CN1485302A (en) * | 2002-09-29 | 2004-03-31 | 深圳市日月合天广告发展有限公司 | Process for producing luminous ceramic products |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平8-283123A 1996.10.29 |
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