CN101397437B - Coating composition for improving filter material surface and coating formation method thereby - Google Patents
Coating composition for improving filter material surface and coating formation method thereby Download PDFInfo
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- CN101397437B CN101397437B CN2008100714701A CN200810071470A CN101397437B CN 101397437 B CN101397437 B CN 101397437B CN 2008100714701 A CN2008100714701 A CN 2008100714701A CN 200810071470 A CN200810071470 A CN 200810071470A CN 101397437 B CN101397437 B CN 101397437B
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Abstract
The invention discloses a coating composite for improving the surface of filtering material and a method for producing coatings by using the coating composite. The coating composite for improving the surface of filtering material provided by the invention comprises polytetrafluoroethylene water dispersion, thickening agent, foaming agent and water. A compact polytetrafluoroethylene protective layer of 30-80g/m<2> can be formed on the surface of the filtering material to improve chemical resistance, surface property and dust cleaning performance of the filtering material, increase filtration precision to a certain extent, lengthen the dust cleaning period and prolong the service life of the filtering material.
Description
Technical field
The present invention relates to coating composition and with its method that forms coating, relate to especially and a kind ofly be used to improve the coating composition of filter material surface and form the method for coating with it.
Background technology
Continuous enhancing and continuous progress in science and technology along with environmental consciousness in the world wide and requirement; The scientific research personnel studies and utilizes every material and method untiringly; Develop new, more effective filtering material cleaning cycle and work-ing life with the chemical resistance that improves filtrate, deashing property, prolongation filtrate; Or improve existing filtrate character, and the structure formation that raw material type that filtering material is selected for use and material form is the important assurance that achieves the above object.The exploitation of high performance filtrate and development, make filtration art technical and functional on noticeable lifting has all been arranged.When high dirt, highly corrosive environments such as clean coal firing boiler, waste incineration, Metal smelting, cement, chemical industry, especially need be high temperature resistant, corrosion-resistant, and the filtering material with high filtering performance.Filtering material quality quality and design rationality are directly determining filtering validity and economic feasibility.
Summary of the invention
The purpose of this invention is to provide a kind of coating composition that is used to improve filter material surface, to solve the problems referred to above that exist in the prior art.Coating composition among the present invention can form the fine and close tetrafluoroethylene resist of one deck on the top layer of filtrate, improves chemical resistance, surface effect and the deashing property of filtrate, prolongs the cleaning cycle and the work-ing life of filtrate.
A further object of the invention provides a kind of method of using the formation coating of coating composition.
The technical scheme that the present invention adopts is following:
Be used to improve the coating composition of filter material surface, comprise that the weight percent concentration that accounts for weight percent 50 ~ 95% is 30% ~ 50% polytetrafluoroethylene aqueous dispersion, 0.1 ~ 1% whipping agent and 0.5 ~ 3% thickening material and 1 ~ 46% water.
The coating composition of said ratio can form one deck 30 ~ 80g/m on the top layer of filtrate
2Fine and close tetrafluoroethylene resist improves the chemical resistance and the surface effect of filtrate, improves the deashing property of filtrate, prolongs the cleaning cycle and the work-ing life of filtrate, and finally reduces filtering energy consumption and running cost.
The aforementioned coating composition that is used for improving filter material surface, polytetrafluoroethylene aqueous dispersion are a kind of in anionic polytetrafluoroethylene aqueous dispersion, cationic tetrafluoroethylene aqueous dispersions or the non-ionic type polytetrafluoroethylene aqueous dispersion.
The aforementioned coating composition that is used for improving filter material surface, whipping agent can be in Triple Pressed Stearic Acid, X 2073, sodium lauryl sulphate, polyoxyethylenated alcohol sodium sulfate, quaternary ammonium compound, benzalkonium chloride, Morpan BB or the rosined soap class whipping agent a kind of.Whipping agent has higher surface activity, can effectively reduce the surface tension of liquid, forms bubble.Because benzalkonium chloride or Morpan BB have certain disinfecting power, be difficult for causing and go mouldy, so preferred benzalkonium chloride or the Morpan BB of using.
The aforementioned coating composition that is used for improving filter material surface; Thickening material can be in the plain verivate of starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide, methylcellulose gum, CMC 99.5, ZX-I, polyoxyethylene, Vinylpyrrolidone polymer, Z 150PH, low-molecular polyethylene wax or the SEPIGEL 305 a kind of; But preferred methylcellulose gum or the CMC 99.5 that uses synthetic; Most preferably be molecular weight at 4000 ~ 15000 methylcellulose gum or CMC 99.5; When guaranteeing the coating composition performance, reduce production costs.
The aforementioned coating composition that is used for improving filter material surface can also comprise that trace does not influence other any materials of coating composition performance.
The aforementioned coating composition that is used to improve filter material surface is that 40% non-ionic type polytetrafluoroethylene aqueous dispersion, 0.5% benzalkonium chloride or Morpan BB, 1.5% molecular weight are that 8000 ~ 10000 methylcellulose gum or CMC 99.5 and 23% water are formed by the weight percent concentration that accounts for weight percent 75% most preferably.
A kind of method of using the formation coating of coating composition may further comprise the steps:
The weight percent concentration that will account for weight percent 50 ~ 95% is that 30% ~ 50% polytetrafluoroethylene aqueous dispersion, 0.1 ~ 1% whipping agent and 0.5 ~ 3% thickening material, 1 ~ 46% water uniform mixing are made into slurries; In slurries, import pressurized air, shear and foam; Foam is coated onto filtrate, high temperature sintering behind roll.
With the polytetrafluoroethylene aqueous dispersion is main raw material, after joining operations such as slurry, foaming, coating, high temperature sintering, forms one deck 30 ~ 80g/m on the top layer of filtrate
2Fine and close tetrafluoroethylene resist after the fine particle shape material in the polytetrafluoroethylene aqueous dispersion is coated in filter material surface or is filled in the filtrate space, has increased the specific surface area of filtrate, and hole is diminished, and has improved the filtering accuracy of filtrate to a certain extent.
In the method for the formation coating of aforementioned use coating composition; The weight percent concentration that will account for weight percent 50 ~ 95% is that uniform mixing is made into slurries in 30% ~ 50% polytetrafluoroethylene aqueous dispersion, 0.1 ~ 1% whipping agent and 0.5 ~ 3% thickening material, 1 ~ 46% water adding whisking appliance, slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; In the mixing and emulsifying head, import pressurized air, slurry is sheared foaming; Then foam delivery is arrived padding machine, through the to-and-fro movement of padding machine upper spray nozzle foam-coated is arrived the filtrate top layer, filtrate is sintering behind roll.
In the method for the formation coating of aforementioned use coating composition, use the rotating speed of 3000rpm~10000rpm that slurry is sheared foaming.
In aforesaid method, can control foaming effect through rotating speed, mixing and emulsifying head shearing frequency and the compressed gas flow of adjusting screw(rod) pump, and can be through the reciprocating speed of adjustment nozzle and the linear speed of pressure roller, the glue spread of control tetrafluoroethylene intumescent coating.Filtrate behind the roll is sent into baking oven carry out sintering, make polytetrafluorethylecoatings coatings, form even, firm, the fine and close polytetrafluorethylecoatings coatings of one deck on the top layer of filtrate securely attached to the filtrate top layer at 200 ℃ ~ 300 ℃.
Embodiment
Can further understand the present invention through the embodiment of the invention given below; Following examples are merely several specific embodiment of the present invention; But design concept of the present invention is not limited thereto; Allly utilize this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Embodiment 1
With the 500g weight percent concentration is that 50% anionic polytetrafluoroethylene aqueous dispersion, 10g benzalkonium chloride and 30g CMC 99.5 and 460g water add that uniform mixing is made into slurries in the whisking appliance, with the rotating speed of 40rpm slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; Input flow rate is the pressurized air of 600L/h in the mixing and emulsifying head, with the rotating speed of 3500rpm slurry is carried out the high speed shear foaming, and the mixing and emulsifying head uses water coolant to cool off; Through pipeline foam delivery is arrived padding machine, the padding machine upper spray nozzle evenly is coated to the filtrate top layer with the speed to-and-fro movement of 3m/min with foam, and filtrate forms the layer of even polytetrafluorethylecoatings coatings on the filtrate top layer behind the speed roll of pressure roller with 4m/min; Filtrate behind the roll is sent into baking oven,, make polytetrafluorethylecoatings coatings, form even, firm, the fine and close polytetrafluorethylecoatings coatings of one deck securely attached to the filtrate top layer at 250 ℃ of high temperature sinterings.
Embodiment 2
With the 950g weight percent concentration is that 40% cationic tetrafluoroethylene aqueous dispersions, 10g Morpan BB, 30g methylcellulose gum and 10g water add that uniform mixing is made into slurries in the whisking appliance, with the rotating speed of 20rpm slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; Input flow rate is the pressurized air of 600L/h in the mixing and emulsifying head, with the rotating speed of 3000rpm slurry is carried out the high speed shear foaming, and the mixing and emulsifying head uses water coolant to cool off; Through pipeline foam delivery is arrived padding machine, the padding machine upper spray nozzle evenly is coated to the filtrate top layer with the speed to-and-fro movement of 3m/min with foam, and filtrate forms the layer of even polytetrafluorethylecoatings coatings on the filtrate top layer behind the speed roll of pressure roller with 4m/min; Filtrate behind the roll is sent into baking oven,, make polytetrafluorethylecoatings coatings, form even, firm, the fine and close polytetrafluorethylecoatings coatings of one deck securely attached to the filtrate top layer at 250 ℃ of high temperature sinterings.
Embodiment 3
With the 950g weight percent concentration is that 30% cationic tetrafluoroethylene aqueous dispersions, 1g Morpan BB, 5g methylcellulose gum and 44g water add that uniform mixing is made into slurries in the whisking appliance, with the rotating speed of 30rpm slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; Input flow rate is the pressurized air of 600L/h in the mixing and emulsifying head, with the rotating speed of 10000rpm slurry is carried out the high speed shear foaming, and the mixing and emulsifying head uses water coolant to cool off; Through pipeline foam delivery is arrived padding machine, the padding machine upper spray nozzle evenly is coated to the filtrate top layer with the speed to-and-fro movement of 3m/min with foam, and filtrate forms the layer of even polytetrafluorethylecoatings coatings on the filtrate top layer behind the speed roll of pressure roller with 4m/min; Filtrate behind the roll is sent into baking oven,, make polytetrafluorethylecoatings coatings, form even, firm, the fine and close polytetrafluorethylecoatings coatings of one deck securely attached to the filtrate top layer at 250 ℃ of high temperature sinterings.
Embodiment 4
With the 750g weight percent concentration is that 40% non-ionic type polytetrafluoroethylene aqueous dispersion, 5g Morpan BB, 15g methylcellulose gum and 230g water add that uniform mixing is made into slurries in the whisking appliance, with the rotating speed of 30rpm slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; Input flow rate is the pressurized air of 600L/h in the mixing and emulsifying head, with the rotating speed of 8000rpm slurry is carried out the high speed shear foaming, and the mixing and emulsifying head uses water coolant to cool off; Through pipeline foam delivery is arrived padding machine, the padding machine upper spray nozzle evenly is coated to the filtrate top layer with the speed to-and-fro movement of 3m/min with foam, and filtrate forms the layer of even polytetrafluorethylecoatings coatings on the filtrate top layer behind the speed roll of pressure roller with 4m/min; Filtrate behind the roll is sent into baking oven,, make polytetrafluorethylecoatings coatings, form even, firm, the fine and close polytetrafluorethylecoatings coatings of one deck securely attached to the filtrate top layer at 250 ℃ of high temperature sinterings.
The quality index of the filtrate of the intumescent coating compsn that the present invention makes embodiment 1, embodiment 2, embodiment 3 and embodiment 4 is tested, and the result is as shown in table 1:
The detected result of table 1 coating composition
Claims (4)
1. be used to improve the coating composition of filter material surface, comprise that the weight percent concentration that accounts for weight percent 75% is 40% polytetrafluoroethylene aqueous dispersion, 0.5% benzalkonium chloride or Morpan BB, methylcellulose gum or CMC 99.5 and the 23% water composition that 1.5% molecular weight is 8000-10000.
2. method of using the formation coating of coating composition; May further comprise the steps: the weight percent concentration that will account for weight percent 50-95% is that uniform mixing is made into slurries in the polytetrafluoroethylene aqueous dispersion of 30%-50%, 0.1-1% whipping agent and 0.5%-3% thickening material, the 1-46% water adding whisking appliance; In slurries, import pressurized air, shear and foam; Foam is coated onto filtrate, high multifuel combustion knot behind roll.
3. according to the method for the formation coating of the use coating composition described in the claim 2; It is characterized in that: the weight percent concentration that will account for weight percent 50-95% is that uniform mixing is made into slurries in the polytetrafluoroethylene aqueous dispersion of 30%-50%, 0.1-1% whipping agent and 0.5%-3% thickening material, the 1-46% water adding whisking appliance, slurries is transported to the mixing and emulsifying head of foaming machine through spiral pump; In the mixing and emulsifying head, import pressurized air, slurry is sheared foaming; Then foam delivery is arrived padding machine, through the to-and-fro movement of padding machine upper spray nozzle foam-coated is arrived the filtrate top layer, filtrate is sintering behind roll.
4. according to the method for the formation coating of the use coating composition described in the claim 3, it is characterized in that: use the rotating speed of 3000rpm~10000rpm that slurry is sheared foaming.
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Families Citing this family (9)
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CN101829453B (en) * | 2010-05-28 | 2012-01-04 | 浙江理工大学 | Preparation method of high-temperature-resistant filtering material with high filtering efficiency |
CN102268216A (en) * | 2010-06-07 | 2011-12-07 | 厦门三维丝环保股份有限公司 | Method for performing oil-proof water-repellent finish on filter material and coating composition applied to same |
CN102059027A (en) * | 2010-10-31 | 2011-05-18 | 房县诚信汽配有限责任公司 | Dust-free fiber deep filtration filter element |
CN102872649B (en) * | 2011-07-15 | 2015-09-09 | 上海特安纶纤维有限公司 | Composite filtering material of a kind of high-temperature flue gas bag-type dust removing system and preparation method thereof |
CN103521002B (en) * | 2013-10-28 | 2016-04-27 | 营口创世纪滤材有限公司 | A kind of glass fiber filter material and preparation method thereof |
CN104193251B (en) * | 2014-08-04 | 2016-08-24 | 马鞍山科信网络科技有限公司 | A kind of anti-corrosive antibacterial thermal insulation mortar and preparation method thereof |
CN106515163A (en) * | 2016-10-27 | 2017-03-22 | 张峰 | Oxidation-resistant high-temperature-resistant polytetrafluoroethylene film covered filter material, and preparation method thereof |
CN108690419A (en) * | 2018-05-10 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of filter core fire resisting water paint and its preparation and application |
CN110938365A (en) * | 2018-09-25 | 2020-03-31 | 天津大学 | Waterborne polyurethane antibacterial coating and preparation method thereof |
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CN1265932A (en) * | 2000-03-17 | 2000-09-13 | 王珂伟 | Method for making high molecular filter material |
CN1111076C (en) * | 1999-08-05 | 2003-06-11 | 东北大学 | Coated filter material and its preparing process |
CN1895759A (en) * | 2006-06-19 | 2007-01-17 | 阜宁县正大玻璃纤维有限公司 | Polytef double-film composite filtering materials |
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CN1111076C (en) * | 1999-08-05 | 2003-06-11 | 东北大学 | Coated filter material and its preparing process |
CN1265932A (en) * | 2000-03-17 | 2000-09-13 | 王珂伟 | Method for making high molecular filter material |
CN1895759A (en) * | 2006-06-19 | 2007-01-17 | 阜宁县正大玻璃纤维有限公司 | Polytef double-film composite filtering materials |
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Address after: 361000 No. 5 Xiang Ming Road, Torch Industrial Zone (Xiangan), Fujian, Xiamen Patentee after: Xiamen Zhongchuang Environmental Protection Technology Co.,Ltd. Address before: 361000 No. 5 Xiang Ming Road, Torch Industrial Zone (Xiangan), Fujian, Xiamen Patentee before: XIAMEN SAVINGS ENVIRONMENTAL Co.,Ltd. |
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