CN101397414A - High abrasion-proof and anti static antibacterial coating - Google Patents

High abrasion-proof and anti static antibacterial coating Download PDF

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CN101397414A
CN101397414A CNA2008102283796A CN200810228379A CN101397414A CN 101397414 A CN101397414 A CN 101397414A CN A2008102283796 A CNA2008102283796 A CN A2008102283796A CN 200810228379 A CN200810228379 A CN 200810228379A CN 101397414 A CN101397414 A CN 101397414A
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paint
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high abrasion
zno whisker
antibacterial coating
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CN101397414B (en
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陈尔凡
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Shenyang Huada R & D Center Of Polymer Materials Co ltd
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Shenyang University of Chemical Technology
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Abstract

A high wear resistance and static-free antibiosis paint relates to an oil paint and takes natural resin or synthesis resin as the base; pigment, filler, four-footed zinc oxide T-ZnO crystal whisker treated with dispersion and coupling, charging material and addition agent and solvent are then added, finally the paint is manufactured by mechanical processing; the isotacticity of the crystal whisker is more than 90 percent, the foot length-diameter ratio of the T-ZnO crystal whisker is 16-20, the foot length is 40-50 Mum and the consumption of the T-ZnO crystal whisker accounts for 0.5-5 percent of the total weight of paint. Compared with corresponding similar paints, the paint has simple and unique preparation process, excellent quality, stronger adherence, outstanding anticorrosive performance and mechanical property and preparation cost not more than the corresponding paint.

Description

High abrasion, anti static antibacterial coating
Technical field
The present invention relates to a kind of oil paint, particularly relate to a kind of high abrasion, anti static antibacterial coating.
Background technology
The common traditional paint (oil paint) in market is that natural resin or synthetic resins are base-material, adds various pigment, various filler, auxiliary agent solvent again and forms through the mechanical workout manufacturing.Some resin wear no resistance and there is friction in some in environment for use, use and usually to cause the paint film wearing and tearing, and lose function; On the other hand,, in dry environment, usually can produce static, bring bigger harm because of macromolecular material mostly is the insulativity material, in addition dangerous; Because of can causing the enzyme flora of paint film, environment hygrothermal environment etc. gives birth to again.
Oil paint be used for more mechanical means and metal products/member and pipeline ,/protection and the decoration of road surface and woodenware or the like, in use can produce the motion friction and bear the impact of different media.Coating surface can cause wearing and tearing, come off being subjected to secular friction and impact, and loses protection and decoration to base material, influences its quality and life-span.Sometimes the reparation difficulty on its surface can very big (as inner-walls of duct etc.), and its expense is very high.
At present, being used to improve coating wear resistance major technique has:
(1) add mineral filler: hardness by improving coating and/or oilness to be improving its wear resistance, as: the application aluminum oxide micro-sphere (Al of description among the JP63227672 " Abrasion-resistant coating compositions containing alumina spheres " etc.s 2O 3); Mineral fillers such as usefulness molybdenumdisulphide, aluminum oxide such as Yang Jun prepare high abrasion epoxypaint " development of E-20 Resins, epoxy wear-resistant paint " (Chinese coating .2006, (3): 27-29); People such as Ma Haihua are in " research and development of wearing composite material coating " (Materials Science and Engineering .1995,13 (2): 34-37) introduced the influence to the epoxy coating wear resistance of titanium oxide, stannic oxide, ferric oxide, chromic oxide and corundum in the literary composition; Improve the hardness and the oilness of coating among the CN1687256A " a kind of corrosion-resistant abrasion coating " simultaneously with fluoro-resin and ceramic, to improve its wear resistance.
(2) modification of film-forming resin: as: the wear resistance " preparation of modified epoxy coating and performance study " of human base polyurethane prepolymer for use as modified epoxy coating such as Zhang Wei (Shanghai coating .2002,42 (3): 4-7); Human thiorubber modifications such as Shen Lixia have prepared wear-resistant paint " development of modified epoxy coating and application " (Sichuan chemical industry and corrosion control .2002,3 (5) 18-20).
(3) hybrid inorganic-organic, the wear-resistant paint that promptly prepares hybrid inorganic-organic by sol-gel process, as: usefulness silica gel and siloxanes cohydrolysis and polycondensation that EP604677-1994 " Silica-contaning siloxane-coated shaped articles and theirmanufacture " describes, the wear-resistant paint of preparation hybrid inorganic-organic; JP 06287470-1994 " Abrasion-resistant acrylic polyurethane coating composition " with silicon sol, contain isocynate silane coupling agent and the many palaces of hydroxyl and can roll into a ball acrylate and prepared urethane acrylate hydridization wear-resistant paint etc.
For the main means of coating static resistance are to add electroconductibility composition, the electric charge of ejecting/collecting effectively.As: CN1147552C is the method that adopts the mica conducting powder, has prepared polyurethane antistatic coating; CN1085927 is with aluminium powder system polyurethane antistatic coating; CN101260277A is with conducting powder system acrylic acid polyurethane antistatic paint; CN1184267C has made vinylformic acid, Resins, epoxy, polyester and polyurethane electrostatic resistance varnish with conductive carbon black; Lin Liping (material and surface treatment .2001, (7): 47-48) then adopt organic antistatic agentses such as S-1, ASA-150, ASB-2, ASB-5 to research and develop zapon varnish.
Giving the coating antibiosis function mainly is by adding the method for antiseptic-germicide.As: use triclosan and pyrithione antiseptic-germicide among the CN101250344A, prepared water anti-bacteria coating; Propose among the CN1436820A with commercially available be that antimicrobial component adds in the commercially available building coating and prepares antibiotic paint with silver, copper, zinc metal ion phosphate-based, that silicate is, oxide based inorganic materials is carrier; The CN100355839C invention is the antibiotic paint with titanium dioxide and the preparation of T-ZnO whisker silicon oxide antiseptic-germicide; People such as Shao Qing had once at large summarized antibiotic paint research new development (material Leader .2008,22 (3): 60-62,71), had described natural antibacterial agent, organic class antiseptic-germicide and mineral-type antiseptic-germicide.The mineral-type antiseptic-germicide comprises: mercury, silver, copper, zinc and compound thereof and inorganic carrier bonded preparation.
These effort are being more effective aspect the coating functional requirement that solves separately, antibacterial or static resistance or wear resistance aspect as coating, but what adopt respectively is special-purpose functional additive or the unifunctional method of modification, does not have comprehensive ground to solve wear-resisting, the anti-electrostatic and the germ resistance problem of coating simultaneously.Say on the other hand,, also exist complex process or cost keeping or " sacrifice "/some coating fundamental propertys of reduction or improve functional inapparent problem even solved single functional issues.
The bright grade of Chu Long is at " research of ZnOT-ZnO whisker complex antimicrobials " (material Leader .2003,17 (6): 84-85,79) in, speak of the preparation that is used for resin concentrates with four needle-like ZnO whiskers and sodium rice zinc oxide and sodium rice zinc oxide titanium complex antimicrobials, as plastics such as low density polyethylene (LDPE)s.The inventor had also once invented " high abrasion, antistatic type polyurethane material " (ZL2005100458985) patent.But all do not relate to four pin shape ZnO whiskers play wear-resisting, anti-electrostatic and germ resistance comprehensive function in coating effect.
Summary of the invention
The object of the invention provides a kind of high abrasion, anti-electrostatic antibiotic oil paint, by natural resin or synthetic resins is base-material, add again various pigment, filler, through disperse and four pin shape zinc oxide (T-ZnO) whiskers of coupling processing, variously add material, the auxiliary agent solvent forms through the mechanical workout manufacturing.
The objective of the invention is to be achieved through the following technical solutions:
High abrasion, anti static antibacterial coating are base-material by natural resin or synthetic resins, add again pigment, filler, through disperse and four pin shape zinc oxide T-ZnO whiskers of coupling processing, add material, the auxiliary agent solvent forms through the mechanical workout manufacturing; T-ZnO whisker regularity〉90%, T-ZnO whisker pin length-to-diameter ratio 16~20, pin long 40~50 μ m, T-ZnO whisker consumption is the weight fraction of paint total amount: 5 ‰~5%.
Described high abrasion, anti static antibacterial coating, through four pin shape zinc oxide T-ZnO whiskers of dispersion and coupling processing, used dispersion agent is ethanol or alcohols or stearic acid or organic acid; Used dispersing method is a supersonic method; The amount of used dispersion agent is the weight fraction of T-ZnO whisker consumption: 10~300%.
Described high abrasion, anti static antibacterial coating, through four pin shape zinc oxide T-ZnO whiskers of dispersion and coupling processing, used coupling agent is silane coupling agent or titante coupling agent; Used dispersing method is a supersonic method, and the amount of used coupling agent is the weight fraction of T-ZnO whisker consumption: 01~5%.
Advantage of the present invention and effect are:
The present invention compares with corresponding similar paint, its preparation technology's uniqueness, simple, and excellent quality have stronger sticking power, excellent antiseptic property and mechanical property, and preparation cost is not higher than corresponding paint.
Embodiment
The present invention is a base-material with natural resin or synthetic resins, adds various pigment again, through disperseing and the T-ZnO whisker of coupling processing, various filler, auxiliary agent solvent paint preparation method routinely, promptly forms through the mechanical workout manufacturing.
(1), pre-dispersed with organic acid dispersion agent usefulness supersonic methoies such as alcohols such as the water of its weight fraction 10~300%, ethanol and stearic acid with T-ZnO whisker (T-ZnO whisker regularity〉90%, long 40~50 μ m of T-ZnO whisker pin length-to-diameter ratio 16~20, pin); With silane coupling agent or the titante coupling agent of pre-dispersed good T-ZnO whisker, use the supersonic method coupling processing again with 0.1~5% weight fraction.Final is the pasty state raw material.
(2), pigment mixing, grinding are made mill base by the color requirement.
(3) will be various add material by prescription and pigment mixes, grinding, filtration make dry powder slurry.
(4) base-material (natural resin or synthetic resins), T-ZnO whisker paste, mill base and dry powder slurry are added in the mixing equipment in proportion mix, on grinding plant, grind again, in paint mixing tank, carry out paint then, be transferred to indexs such as the color of requirement and viscosity.
(5) last, thick product after filtration, after the assay was approved, packing becomes final colored paint product.
The present invention is described in further detail below in conjunction with example.
Embodiment 1:
Prepare the fast dried modified alkyd resin enamel paint of a kind of T-ZnO whisker.The T-ZnO whisker 5 ‰ (weight fraction) of chemical method preparation is poured into stir 5 minutes in the sherwood oil of its 2 times of weight numbers after, in ultrasonoscope, disperseed 10 minutes, in matrass, sherwood oil is distilled out.After the 1% silane resin acceptor kh-550 dissolving of 1 times sherwood oil of T-ZnO whisker volume with T-ZnO whisker weight, scattered T-ZnO whisker toppled over wherein simple agitation after, coupling processing is 10 minutes in ultrasonoscope, obtains the T-ZnO whisker and sticks with paste.Press the usage ratio of modified alkyd resin paint formula, with 60 parts modified alkyd resins (base-material), T-ZnO whisker stick with paste, in advance through mixing, grind, filter good painted and pigment extender (21 parts), add material (6 parts) and No. 200 solvent oils of solvent (12 parts) mix in the lump in mixing tank, grind through three-roll grinder again, behind fineness=20 μ m, pour paint mixing tank into.Adjust color more on request; With partial solvent viscosity is adjusted in the specialized range.Refilter, packing is put in storage after the assay was approved.The rerum natura of lacquer and paint film is tested by corresponding GB.
Comparative example 1:
Except that not adding the T-ZnO whisker, other prepares a kind of fast dried modified alkyd resin enamel paint fully with embodiment 1.The lacquer and the rerum natura of paint film are tested by corresponding national standard, and table 1 be every technical indicator that the routine of the high abrasion anti static antibacterial coating of embodiment 1 and comparative example 1 is coated with lacquer.
Table 1
Figure A200810228379D00071
Figure A200810228379D00081
A. under higher hardness, snappiness reaches 1mm, shows that it is better than the best snappiness of GB;
Sticking power is to measure at 23 ± 3 μ m among the b.GB, and practical measurement exists〉30 μ m, sticking power<1 grade;
C. conventional lacquer is 24h;
D. conventional lacquer is 48h.
Embodiment 2:
Prepare a kind of T-ZnO whisker red iron oxide alkyd primer.The T-ZnO whisker 5% (weight fraction) of chemical method preparation is poured into stir 5 minutes in the ethanol of its 2 times of weight numbers after, in ultrasonoscope, disperseed 10 minutes, in matrass, ethanol distillation is gone out.After the 1% titanic acid ester 402# coupling agent dissolving of 1 times acetone of T-ZnO whisker volume with T-ZnO whisker weight, scattered T-ZnO whisker toppled over wherein simple agitation after, coupling processing is 10 minutes in ultrasonoscope, obtains the T-ZnO whisker and sticks with paste.Press the usage ratio of modified alkyd resin paint formula, with 40 parts modified alkyd resins (base-material), T-ZnO whisker stick with paste, in advance through mixing, grind, filter good iron oxide red pigment (20 parts) and pigment extender (21 parts), add material (6 parts) and solvent (12 parts) mixes in the lump in mixing tank, grind through three-roll grinder again, behind fineness=35 μ m, pour paint mixing tank into, viscosity is adjusted in the specialized range with partial solvent.Refilter, packing is put in storage after the assay was approved.The rerum natura of lacquer and paint film is tested by corresponding GB.Table 2T-ZnO whisker red iron oxide alkyd primer physical index.
Table 2
Figure A200810228379D00082
A. under higher hardness, snappiness reaches 1mm, shows that it is better than the best snappiness of GB;
Sticking power is to measure at 23 ± 3 μ m among the b.GB, and practical measurement exists〉30 μ m, sticking power<1 grade.

Claims (3)

1. high abrasion, anti static antibacterial coating, it is characterized in that high abrasion, anti static antibacterial coating are base-material by natural resin or synthetic resins, add again pigment, filler, through disperse and four pin shape zinc oxide T-ZnO whiskers of coupling processing, add material, the auxiliary agent solvent forms through the mechanical workout manufacturing; T-ZnO whisker regularity〉90%, T-ZnO whisker pin length-to-diameter ratio 16~20, pin long 40~50 μ m, T-ZnO whisker consumption is the weight fraction of paint total amount: 5 ‰~5%.
2. high abrasion according to claim 1, anti static antibacterial coating is characterized in that used dispersion agent is ethanol or alcohols or stearic acid or organic acid through four pin shape zinc oxide T-ZnO whiskers of dispersion and coupling processing; Used dispersing method is a supersonic method; The amount of used dispersion agent is the weight fraction of T-ZnO whisker consumption: 10~300%.
3. high abrasion according to claim 1, anti static antibacterial coating is characterized in that used coupling agent is silane coupling agent or titante coupling agent through four pin shape zinc oxide T-ZnO whiskers of dispersion and coupling processing; Used dispersing method is a supersonic method, and the amount of used coupling agent is the weight fraction of T-ZnO whisker consumption: 0.1~5%.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103937390A (en) * 2014-03-21 2014-07-23 安徽蓝柯复合材料有限公司 Antistatic abrasion-resistant coating and preparation method thereof
CN104098982A (en) * 2013-04-02 2014-10-15 株式会社东芝 Coating material for electrical equipment, method for manufacturing coating material for electrical equipment, and encapsulated type insulating device
CN104649698A (en) * 2014-12-31 2015-05-27 东莞深圳清华大学研究院创新中心 Method for dispersing monocrystalline sapphire fibers in zirconia ceramic composite material and composite material
CN105220490A (en) * 2015-10-20 2016-01-06 湖州博润实业有限公司 A kind of novel textile material antistatic agent and preparation method thereof
CN105778713A (en) * 2016-03-26 2016-07-20 喻倩 Antibacterial coating for surface of metalware and preparation of antibacterial coating
CN106118354A (en) * 2016-06-29 2016-11-16 铜陵青铜时代雕塑有限公司 A kind of antistatic bronze sculpture Super hydrophobic anticorrosive paint and preparation method thereof
CN110564156A (en) * 2019-05-24 2019-12-13 湖北工业大学 Preparation method of intelligent insulating material with low filling ratio and nonlinear conductivity
CN116179062A (en) * 2022-12-08 2023-05-30 成都展辰涂料有限公司 Water-based antibacterial bi-component clean-surface wood material and manufacturing method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101275285A (en) * 2007-12-28 2008-10-01 中国人民解放军国防科学技术大学 Tetrapod zinc oxide whisker coated with functional layer and preparation thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101275285A (en) * 2007-12-28 2008-10-01 中国人民解放军国防科学技术大学 Tetrapod zinc oxide whisker coated with functional layer and preparation thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098982A (en) * 2013-04-02 2014-10-15 株式会社东芝 Coating material for electrical equipment, method for manufacturing coating material for electrical equipment, and encapsulated type insulating device
CN103937390A (en) * 2014-03-21 2014-07-23 安徽蓝柯复合材料有限公司 Antistatic abrasion-resistant coating and preparation method thereof
CN104649698A (en) * 2014-12-31 2015-05-27 东莞深圳清华大学研究院创新中心 Method for dispersing monocrystalline sapphire fibers in zirconia ceramic composite material and composite material
CN105220490A (en) * 2015-10-20 2016-01-06 湖州博润实业有限公司 A kind of novel textile material antistatic agent and preparation method thereof
CN105778713A (en) * 2016-03-26 2016-07-20 喻倩 Antibacterial coating for surface of metalware and preparation of antibacterial coating
CN106118354A (en) * 2016-06-29 2016-11-16 铜陵青铜时代雕塑有限公司 A kind of antistatic bronze sculpture Super hydrophobic anticorrosive paint and preparation method thereof
CN110564156A (en) * 2019-05-24 2019-12-13 湖北工业大学 Preparation method of intelligent insulating material with low filling ratio and nonlinear conductivity
CN116179062A (en) * 2022-12-08 2023-05-30 成都展辰涂料有限公司 Water-based antibacterial bi-component clean-surface wood material and manufacturing method thereof

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