CN101392164A - Environment-friendly type high performance water vacuum plastics-absorption adhesive - Google Patents
Environment-friendly type high performance water vacuum plastics-absorption adhesive Download PDFInfo
- Publication number
- CN101392164A CN101392164A CNA2008100387945A CN200810038794A CN101392164A CN 101392164 A CN101392164 A CN 101392164A CN A2008100387945 A CNA2008100387945 A CN A2008100387945A CN 200810038794 A CN200810038794 A CN 200810038794A CN 101392164 A CN101392164 A CN 101392164A
- Authority
- CN
- China
- Prior art keywords
- percent
- type high
- environment
- high performance
- friendly type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 17
- 239000000853 adhesive Substances 0.000 title claims abstract description 15
- 238000010521 absorption reaction Methods 0.000 title claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000000839 emulsion Substances 0.000 claims abstract description 32
- 150000001412 amines Chemical class 0.000 claims abstract description 21
- 229920002635 polyurethane Polymers 0.000 claims abstract description 9
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 13
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 6
- 125000005375 organosiloxane group Chemical group 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 239000004971 Cross linker Substances 0.000 abstract description 5
- 239000004816 latex Substances 0.000 abstract description 2
- 229920000126 latex Polymers 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 25
- 238000003756 stirring Methods 0.000 description 24
- 239000000047 product Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 8
- 239000011094 fiberboard Substances 0.000 description 8
- 238000012856 packing Methods 0.000 description 7
- 230000008719 thickening Effects 0.000 description 7
- 239000012752 auxiliary agent Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000007725 thermal activation Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an environmental-protection type high-efficiency water-borne vacuum-formed adhesive which is characterized by comprising the following components with the following weight percentages: 30 percent to 50 percent of ethylene-vinyl acetate copolymer emulsion, 0.05 percent to 0.5 percent of organic amine, 1 percent to 10 percent of cross linker, 0.1 percent to 0.5 percent of leveling agent, 0.05 percent to 0.5 percent of polyurethane thickening agent and a polyurethane latex accounting for the rest percentage. The adhesive can be preserved for a long time, with high-temperature resistance thereof reaching over 80 DEG C. And the adhesive not only reduces complicated procedures in operation links, but also decreases the usage of a curing agent, thereby reducing the manufacturing cost.
Description
Technical field
The present invention relates to a kind of vacuum plastic-absorption, be specially a kind of environment-friendly type high performance water vacuum plastics-absorption adhesive.
Background technology
Vacuum plastic-absorption generally uses technology: glue is sprayed onto on the medium density fiberboard plate face by spray glue mode, leave standstill after the glue-line moisture evaporation dries film forming, sized medium density fiberboard is placed the vacuum forming board, by the heating mode that vacuumizes the PVC decorating film is overlayed on the medium density fiberboard face, thereby the glue-line at this moment on the medium density fiberboard face is by being subjected to the crosslinked adhesive effect that plays of polarization on thermal activation and the PVC film.Vacuum plastic-absorption is embodied in applied links process leading indicator: (1) bonding strength; (2) resistance to elevated temperatures; (3) profile pattern.
Be applied to the vacuum plastic-absorption of the bonding employing of PVC film and medium density fiberboard at present.The finished product temperature tolerance that single-component uses has only 65 ℃, product for some outlets, often need in the freight container of sealing, carry out seagoing transport, special transportation ship for need crossing the line circle, temperature in its freight container can reach 80～90 ℃, if the high temperature resistance of glue is not enough, just cause PVC decoration skin to come unglued easily and take off plate, make product rejection.Way in the past is to add 3～5% solidifying agent to improve thermotolerance in the process that glue uses, yet this has increased production process from the another one angle, has improved production cost, is unfavorable for being widely used.
For PVC decorating film and the bonding finished product of making of medium-density plate, only emphasize bonding strength and high thermal resistance requirement in early days, continuous development along with industry, especially the development of indoor paint-free door industry, more and more Duo producer also more payes attention to except the effect of the requirement of adhesiveproperties indoor paint-free being seen outdoors, because traditional operating procedure is in the mode that sprays glue to be sprayed on the medium density fiberboard, the surface tension of considering glue is big, the levelling effect is bad, form pit easily at the position of concentrating spray glue, produce " orange peel " phenomenon.After the PVC skin was adsorbed on the plate face, the outward appearance of film just mapped out the apparent state of glue-line, was the situation that pitted skin is also arranged on the PVC face, caused the finished product aesthetics to reduce greatly.The present invention introduces the technology of coating film forming levelling, reduce the surface tension of glue, when glue is sprayed on the medium density fiberboard plate face, can reduce and soak into the angle, reach fine levelling effect of impregnation may, make the glue-line smooth surface smooth, the PVC film covers the apparent effect in bonding back to be improved greatly, has improved the aesthetics of finished product.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, provide a kind of and have high cohesive force, high temperature resistance, saving cost and can satisfy the high-performance vacuum plastic-absorption of using required flat appearance simultaneously again.
The present invention is achieved through the following technical solutions, and high-performance vacuum plastic-absorption of the present invention comprises following component by weight percentage:
Ethene-vinyl acetate copolymer emulsion 30～50%;
Organic amine 0.05～0.5%;
Linking agent 1～10%;
Flow agent 0.1～0.5%;
Polyurethane thickener 0.05～0.5%;
Base-material: polyaminoester emulsion surplus.
Preferably, comprise following component by weight percentage:
Ethene-vinyl acetate copolymer emulsion 35～45%;
Organic amine 0.1～0.2%;
Linking agent 3～5%;
Flow agent 0.2～0.3%;
Polyurethane thickener 0.1～0.2%;
Base-material: polyaminoester emulsion surplus.
Preferably, described organic amine is selected from the water-based organic amine.
More preferably be that described water-based organic amine is selected from AMP95 organic amine, triethylamine, trolamine.
Preferably, described linking agent is selected from the organic titanate linking agent.
More preferably be that described organic titanate linking agent is selected from Tyzor-371 (commercially available, Dupont chemistry).
Preferably, described flow agent is selected from the organo-siloxane flow agent.
Preferably, described organo-siloxane flow agent is selected from BYK-301 (commercially available, Bi Ke chemistry).
Preferably, described polyurethane thickener is selected from PUR-40 (commercially available, German hamming this).
Production method of the present invention is: drop into material ethene-vinyl acetate copolymer emulsion and organic amine in stainless steel cauldron, stir 0.5-1hr, regulate about pH7.5, slowly splash into linking agent, in 0.5hr, finish adding of linking agent, add flow agent and polyaminoester emulsion then, stir 0.5-1hr, add polyurethane thickener and regulate viscosity, filter, packing.
The ethene-vinyl acetate emulsion has certain bonding activity to the PVC film, plays the effect of adhesion promotor in system, and reduces cost; Organic amine plays the effect of regulating the pH value, the ethene-vinyl acetate ph value of emulsion is adjusted to 7-8 mix with water-based organic titanate linking agent, and system pH can guarantee that the stabilized aqueous solution of organic titanate linking agent is deposited in the 7-8 scope; But the organic titanate aqueous solution at the pH=7-8 stable existence, is worked as temperature as the water-based system linking agent〉crosslinking reaction can take place in 100 ℃ or pH＜6, improves glue-line greatly to the bonding strength of PVC film and medium density fiberboard and improve the thermotolerance of glued membrane; Polyaminoester emulsion is main bonding base-material in this formula system, because it has highly active urethano, the active gene on thermal activation process and wood surface and PVC surface easily produces and is cross-linked to form strong bonding force; Organo-siloxane class flow agent reduces the surface tension of glue, can reach levelling in the latex film forming process, and effect of impregnation may makes the glued membrane surfacing; Poly-propylhomoserin class thickening material plays the effect of adjusting glue viscosity.
The present invention introduces internal crosslinker, water-based organic titanate linking agent, and in regulating the pH=7-8 scope of product, the organic titanate linking agent is not reacted, can be stable coexist with system.Just react in the glue use, improve final product bonding force and thermotolerance, and the additional crosslink agent of traditional vacuum plastic-absorption, mostly be isocyanates, since isocyanato because of high reactivity, can only add in the use of glue, and the glue that is mixed into isocyanates must use up in the regular hour, otherwise can cause the dead glue of glue curing.Introduce organo-siloxane class flow agent simultaneously, improve the film-formation result of glue-line, make final finished product outward appearance more attractive in appearance.
The technology of the production control of crux is the adjusting of pH, vacuum plastic-absorption in the past adopts the easy volatile triethylamine to regulate the pH value, as time passes, cause pH to descend easily, and be the stability of maintenance internal crosslinker in the body series, and adopt organic amine, can guarantee that the pH of glue system is stable, simultaneously deposit the membrane process organic amine and can volatilize again and reduce pH, make the organic titanate crosslinked action reach best at glue.
But the glue long storage time among the present invention can reach the high temperature resistance more than 80 ℃, has not only reduced the cumbersome program of operation link, and reduces the usage quantity of solidifying agent, has saved production cost.
Embodiment
Below embodiments of the invention are elaborated: present embodiment has provided detailed embodiment being to implement under the prerequisite with the technical solution of the present invention, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
Present embodiment is implemented under following implementation condition and technical requirements condition:
Adopt 1 ton of stainless steel scuffing of cylinder bore, in scuffing of cylinder bore, drop into 45% ethene-vinyl acetate emulsion, adjust the high speed dispersor rotating speed, slowly splash into the 0.05%AMP95 organic amine, regulate ph value of emulsion about 7.5; Drip 1%Tyzor-371, stir and add 0.1% leveling auxiliary agent BYK-301 after 0.5-1.0 hour, stir and drop into 53.8% polyaminoester emulsion after 0.5 hour, add 0.05% thickening material PUR-401 then, after the adjustment viscosity is qualified, continue to stir 0.5-1.0 hour, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.2Kg/cm, and the constant temperature heat resisting temperature has 85 ℃, and moment, heat resisting temperature was greater than 100 ℃; Reduce cost 15% with similar plastic uptake glue contrast.
Embodiment 2
Adopt 2 tons of stainless steel scuffings of cylinder bore, in scuffing of cylinder bore, drop into 46% ethene-vinyl acetate emulsion, open to stir and adjust the high speed dispersor rotating speed, slowly splash into the 0.09%AMP95 organic amine, regulate ph value of emulsion at 7.5-7.8; Drip 1% internal crosslinker Tyzor-371 in header tank, stir and drop into 52.7% polyaminoester emulsion more than 1.0 hours, stir after 0.5 hour, add 0.11% leveling auxiliary agent BYK-301 and 0.1% thickening material PUR-40 at last successively, continue to stir after 1.5-2.0 hour, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.5Kg/cm, and the constant temperature heat resisting temperature has 85 ℃, and moment, heat resisting temperature was greater than 105 ℃; Reduce cost 10% with similar plastic uptake glue contrast.
Embodiment 3
Adopt 3 tons of enamel stirring tanks, at first drop into 50% ethene-vinyl acetate emulsion, open and stir, slowly splash into the 0.09%AMP95 organic amine, stir and adjust ph value of emulsion more than 1 hour about 7.5, splash into 1.21% internal crosslinker Tyzor-371, stir more than 1 hour, drop into 48.32% kilogram of polyaminoester emulsion, stir more than 0.5 hour, drop into 0.25% leveling auxiliary agent BYK-301 and 0.13% thickening material PUR-40 at last successively; Continue to stir 2 hours, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.0Kg/cm, and the constant temperature heat resisting temperature has 85 ℃, moment heat resisting temperature be 105 ℃; Reduce cost 13% with similar plastic uptake glue contrast.
Embodiment 4
Present embodiment is implemented under following implementation condition and technical requirements condition:
Adopt 1 ton of stainless steel scuffing of cylinder bore, in scuffing of cylinder bore, drop into 30% ethene-vinyl acetate emulsion, adjust the high speed dispersor rotating speed, slowly splash into 0.5% triethylamine, regulate ph value of emulsion about 7.5; Drip 10%Tyzor-371, stir adding 0.5% leveling auxiliary agent BYK-301 after 0.5-1.0 hour, stir and drop into the surplus polyaminoester emulsion after 0.5 hour, add 0.5% thickening material PUR-401 then, after the adjustment viscosity is qualified, continue to stir 0.5-1.0 hour, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.6Kg/cm, 85 ℃ of constant temperature heat resisting temperatures, moment 110 ℃ of heat resisting temperatures; Reduce cost 7% with similar plastic uptake glue contrast.
Embodiment 5
Present embodiment is implemented under following implementation condition and technical requirements condition:
Adopt 1 ton of stainless steel scuffing of cylinder bore, in scuffing of cylinder bore, drop into 35% ethene-vinyl acetate emulsion, adjust the high speed dispersor rotating speed, slowly splash into 0.1% trolamine, regulate ph value of emulsion about 7.5; Drip 3%Tyzor-371, stir adding 0.2% leveling auxiliary agent BYK-301 after 0.5-1.0 hour, stir and drop into the surplus polyaminoester emulsion after 0.5 hour, add 0.2% thickening material PUR-401 then, after the adjustment viscosity is qualified, continue to stir 0.5-1.0 hour, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.4Kg/cm, and the constant temperature heat resisting temperature has 87 ℃, moment 105 ℃ of heat resisting temperatures; Reduce cost 10% with similar plastic uptake glue contrast.
Embodiment 6
Present embodiment is implemented under following implementation condition and technical requirements condition:
Adopt 1 ton of stainless steel scuffing of cylinder bore, in scuffing of cylinder bore, drop into 45% ethene-vinyl acetate emulsion, adjust the high speed dispersor rotating speed, slowly splash into the 0.2%AMP95 organic amine, regulate ph value of emulsion about 7.5; Dropwise 5 %Tyzor-371 stirs adding 0.3% leveling auxiliary agent BYK-301 after 0.5-1.0 hour, stirs and drops into the surplus polyaminoester emulsion after 0.5 hour, add 0.05% thickening material PUR-401 then, after the adjustment viscosity is qualified, continue to stir 0.5-1.0 hour, detect the qualified after-filtration packing of index.
Compared with prior art, the product that this example obtained has good stability, and its cohesive force can reach 3.5Kg/cm, and the constant temperature heat resisting temperature has 90 ℃, moment 110 ℃ of heat resisting temperatures; Reduce cost 15% with similar plastic uptake glue contrast.
The foregoing description only is used for that the present invention will be described, does not constitute the restriction to the claim scope, and other alternative means that it may occur to persons skilled in the art that are all in claim scope of the present invention.
Claims (9)
1. an environment-friendly type high performance water vacuum plastics-absorption adhesive is characterized in that, comprises following component by weight percentage:
Ethene-vinyl acetate copolymer emulsion 30～50%;
Organic amine 0.05～0.5%;
Linking agent 1～10%;
Flow agent 0.1～0.5%;
Polyurethane thickener 0.05～0.5%;
Base-material: polyaminoester emulsion surplus.
2. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 1 is characterized in that, comprises following component by weight percentage:
Ethene-vinyl acetate copolymer emulsion 35～45%;
Organic amine 0.1～0.2%;
Linking agent 3～5%;
Flow agent 0.2～0.3%;
Polyurethane thickener 0.1～0.2%;
Base-material: polyaminoester emulsion surplus.
3. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 1 and 2 is characterized in that described organic amine is selected from the water-based organic amine.
4. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 3 is characterized in that, described water-based organic amine is selected from AMP95 organic amine, triethylamine, trolamine.
5. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 1 and 2 is characterized in that described linking agent is selected from the organic titanate linking agent.
6. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 5 is characterized in that, described organic titanate linking agent is selected from Tyzor-371.
7. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 1 and 2 is characterized in that described flow agent is selected from the organo-siloxane flow agent.
8. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 7 is characterized in that, described organo-siloxane flow agent is selected from BYK-301.
9. environment-friendly type high performance water vacuum plastics-absorption adhesive according to claim 1 and 2 is characterized in that described polyurethane thickener is selected from PUR-40.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100387945A CN101392164B (en) | 2008-06-11 | 2008-06-11 | Environment-friendly type high performance water vacuum plastics-absorption adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100387945A CN101392164B (en) | 2008-06-11 | 2008-06-11 | Environment-friendly type high performance water vacuum plastics-absorption adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101392164A true CN101392164A (en) | 2009-03-25 |
| CN101392164B CN101392164B (en) | 2010-06-23 |
Family
ID=40492677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100387945A Expired - Fee Related CN101392164B (en) | 2008-06-11 | 2008-06-11 | Environment-friendly type high performance water vacuum plastics-absorption adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101392164B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105611755A (en) * | 2014-11-20 | 2016-05-25 | 张立忠 | 3C electronic product shell and manufacturing process |
| CN106189989A (en) * | 2016-07-15 | 2016-12-07 | 启东市江海农副产品专业合作社 | A kind of aqueous, environmental protective vacuum forming gluing agent |
| CN106590506A (en) * | 2016-12-08 | 2017-04-26 | 万华化学集团股份有限公司 | Waterborne vacuum plastic-absorbing glue and preparing method thereof |
| CN106916552A (en) * | 2017-04-24 | 2017-07-04 | 施玉芳 | A kind of plastic uptake adhesive |
| CN109868091A (en) * | 2017-12-01 | 2019-06-11 | 万华化学（宁波）有限公司 | A kind of water vacuum plastics-absorption glue and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5372335B2 (en) * | 2006-03-27 | 2013-12-18 | 住友化学株式会社 | Adhesive composition and method for producing the same |
-
2008
- 2008-06-11 CN CN2008100387945A patent/CN101392164B/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105611755A (en) * | 2014-11-20 | 2016-05-25 | 张立忠 | 3C electronic product shell and manufacturing process |
| CN106189989A (en) * | 2016-07-15 | 2016-12-07 | 启东市江海农副产品专业合作社 | A kind of aqueous, environmental protective vacuum forming gluing agent |
| CN106590506A (en) * | 2016-12-08 | 2017-04-26 | 万华化学集团股份有限公司 | Waterborne vacuum plastic-absorbing glue and preparing method thereof |
| CN106590506B (en) * | 2016-12-08 | 2019-07-23 | 万华化学集团股份有限公司 | A kind of water vacuum plastics-absorption glue and preparation method thereof |
| CN106916552A (en) * | 2017-04-24 | 2017-07-04 | 施玉芳 | A kind of plastic uptake adhesive |
| CN109868091A (en) * | 2017-12-01 | 2019-06-11 | 万华化学（宁波）有限公司 | A kind of water vacuum plastics-absorption glue and preparation method thereof |
| CN109868091B (en) * | 2017-12-01 | 2021-03-09 | 万华化学（宁波）有限公司 | Water-based vacuum plastic and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101392164B (en) | 2010-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101921381B (en) | Preparation method of aqueous polyurethane latex as vacuum plastic-absorption adhesive | |
| CN101392164B (en) | Environment-friendly type high performance water vacuum plastics-absorption adhesive | |
| TWI266656B (en) | Surface treated metal sheet | |
| MXPA05006892A (en) | Polyurethane dispersions with high acid content. | |
| CN103184791A (en) | Solid wood composite floor and manufacture method thereof | |
| CN109536108A (en) | The moisture-curable polyurethane hot melt adhesive of high-strength high temperature-resistant and preparation method thereof for furniture surfacing | |
| CN103965715A (en) | Water-based glass coating | |
| CN101362874A (en) | Unsaturated polyester modified polyurethane coating varnish | |
| CN110373947B (en) | Anti-seepage bead oil coating for bead blasting type tipping paper and preparation method thereof | |
| CN101343498B (en) | Paint for high-class woodenware artwork and preparation thereof | |
| CN103013420B (en) | The stain resistant aqueous urethane all-purpose gum of environment-friendly type | |
| CN106634720B (en) | A kind of water-fast glue bond of paper products of room temperature quickstick and preparation method thereof | |
| CN110330849A (en) | The general high solid coating varnish of aqueous BASE and oiliness BASE | |
| CN103232801B (en) | Employing removes polyurethane carpentry paint of urea formaldehyde and preparation method thereof | |
| CN104531036B (en) | Water-based double-component spray glue | |
| CN109735195A (en) | A kind of dumb light paint layer and preparation method thereof | |
| CN105038560A (en) | Golden water-borne coating for vacuum aluminum-plating paper and application method thereof | |
| CN102516447A (en) | Synthetic method and application of urea monomer modified hydroxyl acrylic emulsion | |
| CN110172329A (en) | Rubber made from soybean cake with great friction coefficient and preparation method thereof and the application in making sheet | |
| JPH1081865A (en) | Adhesive composition | |
| CN101328331A (en) | Highly water-resistant, wearing-resistant plastic printing ink and use method thereof | |
| CN103319674A (en) | Preparation method for natural vegetable gum-modified urea-formaldehyde resin | |
| CN101220248A (en) | Wood substance material adhesion agent manufactured with corn starch as main material and manufacturing method thereof | |
| CN106634701A (en) | Aqueous environmental protection adhesive with characteristics of wide use and water resistance | |
| CN109249657A (en) | A kind of blank and its manufacture craft |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANGHAI INNOVA NEW MATERIAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANGHAI INNOVATE CHEMICALS CO., LTD. Effective date: 20120717 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 201701 QINGPU, SHANGHAI TO: 201508 JINSHAN, SHANGHAI |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20120717 Address after: 201508 Shanghai City, Jinshan District Shanyang road 289 Lane 5, Fu Shan Patentee after: SHANGHAI INNOVATE NEW MATERIALS TECHNOLOGY CO.,LTD. Address before: 201701 No. 7612 Pine Road, Qingpu District, Shanghai Patentee before: SHANGHAI INNOVATE CHEMICALS Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100623 |