CN101372163B - Method for processing waterproof thermoplastic elastomer toughening thin film composite fabric - Google Patents
Method for processing waterproof thermoplastic elastomer toughening thin film composite fabric Download PDFInfo
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- CN101372163B CN101372163B CN2007100765376A CN200710076537A CN101372163B CN 101372163 B CN101372163 B CN 101372163B CN 2007100765376 A CN2007100765376 A CN 2007100765376A CN 200710076537 A CN200710076537 A CN 200710076537A CN 101372163 B CN101372163 B CN 101372163B
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- thermoplastic elastomer
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- elastomer toughening
- toughening thin
- hot pressing
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Abstract
The invention relates to a processing method of a waterproof thermoplastic elastomer toughing film composite material, which is a film cementing, wet combining and hot pressing technology and comprises the following steps: surface treatment is carried out on the thermoplastic elastomer toughing film on a corona machine; the film treated and a textile base material are placed in the composite adhesives of a cementing groove for cementing, and the composite material is extracted by a preheat extraction wheel with the preheat temperature being controlled at 60 DEG C to 90 DEG C; hot pressing on the composite material is carried out in a heating mantle with the film surface temperature being 150 DEG C to 180 DEG C, the pressing roll pressure being 4kg/cm<2> to 6kg/cm<2> and the lathing speed being 7m/min to 15m/min; water-sprinkling resistance treatment is carried out on the surface of the composite material after the hot pressing and then drying is carried out by an oven; and lines are made by hot pressing and rolling is carried out by natural cooling. The processing method guarantees a fine peeling strength of the TPEVA film and the textile base material after composition, and leadsthe composite material to obtain the fine functional effect of water-sprinkling resistance on the premise that low-cost technique is kept.
Description
Technical field:
The present invention relates to a kind of processing method of waterproof thermoplastic elastomer toughening thin film composite fabric, it is the processing method of the anti-water-sprinkling function of environmental protection TPEVA composite material, it belongs to the technical field of finishing functions of textile fabrics and thermoplastic elastomer toughening goods, particularly relates to the functional Combined Machining Technology field of environmental protection TPEVA film and textile fabric.
Background technology:
Thermoplastic elastomer toughening thin film composite and goods, it is environmental protection TPEVA composite material product, be mainly used in the case and bag bag lining of various reputable brand (as: NIKE, ADIDAS, PUMA etc.), meet of requirement and the restriction of current international market overall situation to this respect material environment friendly aspect, can substitute the PVC goods that traditional being considered to do not meet environmental requirement, be a kind of very rising product, this series products is higher for the anti-water-sprinkling functional requirement of lining usually.
The anti-water-sprinkling function processing of composite material at present, the preceding textile substrates of fitting that adopt are prevented water-sprinkling resin finishing processing method more, this processing method causes the compound fastness (peel strength) of TPEVA film/textile substrate obviously to descend, and anti-water-sprinkling effect also is difficult for guaranteeing.
Summary of the invention:
It is easy to the purpose of this invention is to provide a kind of operation, does not promptly influence the processing method that the compound fastness of film/textile substrate can guarantee to have the waterproof thermoplastic elastomer toughening thin film composite fabric with anti-water-sprinkling function of good anti-water-sprinkling functional effect again.
The object of the present invention is achieved like this:
A kind of processing method of waterproof thermoplastic elastomer toughening thin film composite fabric, described processing method is a film gluing wet combining heat pressing process, it comprises following processing step:
A: the one side that thermoplastic elastomer toughening thin film is prepared to fit is placed on the surface treatment of carrying out routine on the corona machine;
B: the thermoplastic elastomer toughening thin film that surface treatment is good is placed on putting on the film frame of compounding machine, is placed on putting on the cloth holder of compounding machine with preparing compound textile substrate;
C: composite adhesive is added in the gluing groove, adopt upper glue roller to give surface-treated thermoplastic elastomer toughening thin film top sizing;
D: draw that to prepare compound textile substrate compound with the thermoplastic elastomer toughening thin film that applied composite adhesive, the temperature that wheel is drawn in preheating is controlled to be 60-90 ℃;
E: in heating mantles the composite material of finishing above-mentioned steps is carried out hot pressing after compound, the process conditions of its hot pressing are: the face temperature is 150-180 ℃, and pressure roller pressure is 4-6KG/CM
2, the speed of a motor vehicle is 7-15M/MIN;
F: the composite material after hot pressing is through the resin liquid bath, and roller with liquid is the cloth cover feeding that composite material improves water resistance, afterwards through oven for drying;
G: the oven dry lining is through the hot pressing line, and the back is cooled off clot naturally.
Described thermoplastic elastomer toughening thin film is ethylene propylene diene rubber thermoplastic elastomer (TPE)/polyvinyl acetate/vinyl polymer rete, perhaps, thermoplastic polystyrene elastomer/hydrogenated polystyrene thermoplastic elastomer (TPE)/polyvinyl acetate/vinyl polymer rete, perhaps, TPO/polyvinyl acetate/vinyl polymer rete.
The soft durometer of described thermoplastic elastomer toughening thin film is shore hardness 45-90A, and thickness is 0.10-0.40MM.
The surface treatment of described thermoplastic elastomer toughening thin film is the corona machine treatment process, and power is 7000-10000VA, and the speed of a motor vehicle is 15-25M/MIN.
Described composite adhesive is a modified polyurethane high molecular bonding glue.
Described thermoplastic elastomer toughening thin film and textile substrate bonding compound after, carry out the anti-water-sprinkling resin finishing of textile substrate surface feeding according to the F step, again through the hot pressing line, make composite material rolling with good anti-water-sprinkling function.
Anti-water-sprinkling inorganic agent is a fluorocarbon resin class water repellent finishing agent in the anti-water-sprinkling of described F step is handled.
Described fluorocarbon resin class water repellent finishing agent is the mixed liquor of fluorocarbon resin, glacial acetic acid and isopropyl alcohol fluorocarbon resin.
The present invention has adopted rear defence water-sprinkling finishing functions processing method to replace preceding water-sprinkling operating procedure method of the prior art, guaranteed thermoplastic elastomer toughening thin film, being that TPEVA film and textile substrate are compound has a good peel strength, can also make simultaneously composite material obtain good anti-water-sprinkling functional effect, and operation of the present invention is easy, and processing cost is low.
Description of drawings:
Fig. 1 is the structural representation of composite material of the present invention
Fig. 2 is the process chart of invention
The specific embodiment:
The present invention is further illustrated below in conjunction with accompanying drawing 1 and Fig. 2 and embodiment.
Embodiment:
As shown in Figure 1, composite material of the present invention is made up of macromolecule membranous layer 1, adhesive linkage 2, textile substrate 3 and anti-water-sprinkling layer 4.Described anti-water-sprinkling layer 4 is for handling the resin film layer that the back forms through fluorocarbon resin class water repellent finishing agent.Described macromolecule membranous layer 1 is a thermoplastic elastomer toughening thin film, i.e. the TPEVA film.
In the present embodiment, processing step of the present invention and concrete technological parameter are as follows:
As shown in Figure 2, the one side that thermoplastic elastomer toughening thin film 1 is prepared to fit is placed on the surface treatment of carrying out routine on the corona machine 4, its concrete technological parameter is: the Shao Shi thickness of thermoplastic elastomer toughening thin film is 90A, and the power of corona machine is 8000VA, and the speed of a motor vehicle is 15M/MIN; Thermoplastic elastomer toughening thin film 5 then that surface treatment is good adopts the composite adhesive gluing by glue groove 8 and upper glue roller 9, and the composite caking agent that uses in the present embodiment is modified polyurethane high molecular bonding glue.Thermoplastic elastomer toughening thin film 10 volumes that applied glue are placed on the cloth holder 6, draw textile substrate 3 of prepare fitting and the film 10 that applied glue to carry out hot pressing hot pressing heating mantles 11 compound from putting cloth holder 7 again, its process conditions are: 70 ℃ of wheel heating are drawn in preheating, and the face temperature of hot pressing heating mantles heating is 150 ℃; Lining after hot pressing is compound, entering the anti-water-sprinkling that resin liquid bath 14 and roller with liquid 15 carry out the textile substrate surface by pressure roller 18 handles, in the present embodiment, during the anti-water-sprinkling that uses is handled anti-water-sprinkling inorganic agent be the mixed liquor of fluorocarbon resin, glacial acetic acid and isopropyl alcohol fluorocarbon resin, the weight fraction of each composition ratio is glacial acetic acid in its mixed liquor: isopropyl alcohol=30: 1: 10, unit are grams per liter.Composite material after anti-water-sprinkling is handled is dried through baking oven 16 again, and bake out temperature 90-150 ℃, speed of a motor vehicle 10M/MIN, the composite material 17 after the oven dry carries out the hot pressing line through pressure roller embossing device 12 again, and pressure is 6.0KG/CM
2, the speed of a motor vehicle is 10M/MIN, last cooling naturally is through 18 clots of clot equipment.
Claims (6)
1. the processing method of a waterproof thermoplastic elastomer toughening thin film composite fabric is characterized in that described processing method is a film gluing wet combining heat pressing process, and it comprises following processing step:
A: the one side that thermoplastic elastomer toughening thin film is prepared to fit is placed on the surface treatment of carrying out routine on the corona machine;
B: the thermoplastic elastomer toughening thin film that surface treatment is good is placed on putting on the film frame of compounding machine, is placed on putting on the cloth holder of compounding machine with preparing compound textile substrate;
C: composite adhesive is added in the gluing groove, adopt upper glue roller to give surface-treated thermoplastic elastomer toughening thin film top sizing;
D: draw that to prepare compound textile substrate compound with the thermoplastic elastomer toughening thin film that applied composite adhesive, the temperature that wheel is drawn in preheating is controlled to be 60-90 ℃;
E: in heating mantles the composite material of finishing above-mentioned steps is carried out hot pressing after compound, the process conditions of its hot pressing are: the face temperature is 150-180 ℃, and pressure roller pressure is 4-6KG/CM
2, the speed of a motor vehicle is 7-15M/MIN;
F: the composite material after hot pressing is through the resin liquid bath, and roller with liquid is that composite material carries out the cloth cover feeding, afterwards through oven for drying; Resin liquid in the described resin liquid bath is anti-water-sprinkling inorganic agent; Anti-water-sprinkling inorganic agent is a fluorocarbon resin class water repellent finishing agent; Described fluorocarbon resin class water repellent finishing agent is the mixed liquor of fluorocarbon resin, glacial acetic acid and isopropyl alcohol fluorocarbon resin;
G: the oven dry lining is through the hot pressing line, and the back is cooled off clot naturally.
2. according to the processing method of the described waterproof thermoplastic elastomer toughening thin film composite fabric of claim 1, it is characterized in that described thermoplastic elastomer toughening thin film is ethylene propylene diene rubber thermoplastic elastomer (TPE)/polyvinyl acetate/vinyl polymer rete, perhaps, thermoplastic polystyrene elastomer/hydrogenated polystyrene thermoplastic elastomer (TPE)/polyvinyl acetate/vinyl polymer rete, perhaps, TPO/polyvinyl acetate/vinyl polymer rete.
3. the processing method of waterproof thermoplastic elastomer toughening thin film composite fabric according to claim 1 and 2, the soft durometer that it is characterized in that described thermoplastic elastomer toughening thin film is shore hardness 45-90A, thickness is 0.10-0.40MM.
4. according to the processing method of the described waterproof thermoplastic elastomer toughening thin film composite fabric of claim 1, it is characterized in that, the surface treatment of described thermoplastic elastomer toughening thin film is the corona machine treatment process, and power is 7000-10000VA, and the speed of a motor vehicle is 15-25M/MIN.
5. the processing method of the described waterproof thermoplastic elastomer toughening thin film composite fabric of claim 1, the described composite adhesive of its feature is a modified polyurethane high molecular bonding glue.
6. the processing method of the described waterproof thermoplastic elastomer toughening thin film composite fabric of claim 1, it is characterized in that described thermoplastic elastomer toughening thin film and textile substrate bonding compound after, carry out the anti-water-sprinkling resin finishing of textile substrate surface feeding according to the F step, again through hot pressing line, rolling.
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CN2007100765376A CN101372163B (en) | 2007-08-24 | 2007-08-24 | Method for processing waterproof thermoplastic elastomer toughening thin film composite fabric |
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CN2007100765376A CN101372163B (en) | 2007-08-24 | 2007-08-24 | Method for processing waterproof thermoplastic elastomer toughening thin film composite fabric |
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CN101372163B true CN101372163B (en) | 2011-02-16 |
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Families Citing this family (6)
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CN105328962A (en) * | 2015-12-16 | 2016-02-17 | 常熟市天辰针织有限公司 | Waterproof thermoplastic elastomer toughening thin film composite fabric |
JP7001357B2 (en) * | 2016-04-21 | 2022-02-03 | 住友化学株式会社 | Resin film transport method |
CN108773151A (en) * | 2018-07-03 | 2018-11-09 | 浙江美欣达纺织印染科技有限公司 | That is patch i.e. point general boiling hot pad pasting shock processing |
CN109203628B (en) * | 2018-08-20 | 2020-12-04 | 福建省向兴纺织科技有限公司 | Fabric compounding process |
CN114263002A (en) * | 2021-12-21 | 2022-04-01 | 明达光电(厦门)有限公司 | Hydrolysis-resistant treatment method for air bag material |
TWI799204B (en) * | 2022-03-23 | 2023-04-11 | 財團法人中華民國紡織業拓展會 | Continuous manufacturing equipment and continuous manufacturing method of elastic three-dimensional fabric |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1272569A (en) * | 2000-04-11 | 2000-11-08 | 毅宸兴业股份有限公司 | Filmextrusion of styrene-butadiene by using double-head film-spraying back-gluing process and processing technotogy for connecting it with fabrics |
CN2441839Y (en) * | 2000-10-02 | 2001-08-08 | 山东科亿达集团有限公司 | Water-proof wet permeable coating fabric wet adhisive machine |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1272569A (en) * | 2000-04-11 | 2000-11-08 | 毅宸兴业股份有限公司 | Filmextrusion of styrene-butadiene by using double-head film-spraying back-gluing process and processing technotogy for connecting it with fabrics |
CN2441839Y (en) * | 2000-10-02 | 2001-08-08 | 山东科亿达集团有限公司 | Water-proof wet permeable coating fabric wet adhisive machine |
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