CN101364358B - Light accumulating, emitting and reflecting mark plaster and preparation thereof - Google Patents

Light accumulating, emitting and reflecting mark plaster and preparation thereof Download PDF

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Publication number
CN101364358B
CN101364358B CN 200810304340 CN200810304340A CN101364358B CN 101364358 B CN101364358 B CN 101364358B CN 200810304340 CN200810304340 CN 200810304340 CN 200810304340 A CN200810304340 A CN 200810304340A CN 101364358 B CN101364358 B CN 101364358B
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China
Prior art keywords
light
layer
emitting
hardening agent
varnish
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Expired - Fee Related
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CN 200810304340
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CN101364358A (en
Inventor
蓝智华
赵昆
张明
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Shenzhen Sunfor Lighting Co., Ltd.
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Sichuan Sunfor Light Co Ltd
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Priority to CN 200810304340 priority Critical patent/CN101364358B/en
Publication of CN101364358A publication Critical patent/CN101364358A/en
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Publication of CN101364358B publication Critical patent/CN101364358B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention provides a label capable of storing, emitting and reflecting light, which is not liable to damage and has the functions of light emitting, light reflecting, wear resistance and skid prevention. The label comprises a backing material, a light storing and emitting layer, a pattern and letter layer, wherein, a light reflecting layer is arranged between the light storing and emitting layer and the pattern and letter layer, and the light reflecting layer is made of aluminium powder, glass beads, diluent, varnish, polyester resin and curing agent. By using the light reflecting layer which is arranged between the light storing and emitting layer and the pattern and letter layer and made from glass microballoons, the inventive label can reflect light and effectively prevent liquid or other substances from entering into the backing material; and as the glass microballoons are wear-resistant, the inventive label has the functions of light emitting, light reflecting, wear resistance and skid prevention. The inventive label can be widely used in entertainment places, public places such as subways, airports and markets, as well as special places such as filling stations, mining shafts and underground passages, etc.; and can be used as the emergency indication for evacuation in case of emergency incidents such as power supply failures, fire hazards, etc.

Description

Light accumulating, emitting and reflecting mark plaster and preparation method thereof
Technical field
The present invention relates to a kind of labeling and preparation method thereof, particularly relate to a kind of labeling and preparation method thereof with light-accumulated luminous and reflection function.
Background technology
The change of Along with people's habits and customs; The time of working at night and lying fallow has increased, and people have higher requirement to the sign of public places such as subway, airport, market, road, on the one hand; Warning Mark must have lighting function; On the other hand, Warning Mark also preferably has reflection function, and such luminous reflecting Warning Mark just can be widely used in public spheres such as fire-fighting, civil administration, traffic.But, because this product often all is used in the big place of flow of the people, exist fragile and problem such as difficult installation, received limitation in the use.
Existing luminous Warning Mark mainly is luminous with electroluminescence or twilight sunset material, and reflective Warning Mark is spread upon on the Warning Mark by reflectorized material, does not see the Warning Mark that possesses luminous reflecting simultaneously, and has wear-resisting anti-skidding antiseptic property.
Summary of the invention
Technical matters to be solved by this invention provides a kind of light accumulating, emitting and reflecting mark plaster, and this labeling is not fragile and have luminous, a reflective and wear-resisting antiskid function.
The technical scheme that technical solution problem of the present invention is adopted is: light accumulating, emitting and reflecting mark plaster; Comprise base material, light-accumulated luminous layer and pattern and character layer; Between said light-accumulated luminous layer and pattern and character layer, also have reflector layer, said reflector layer is processed by silver powder, glass microballoon, thinning agent, varnish, polyester resin and hardening agent.
The method for making of light accumulating, emitting and reflecting mark plaster may further comprise the steps:
1) base material is pressed required form cutting polishing moulding;
2) light-accumulated luminous powder, thinning agent, varnish, polyester resin and hardening agent are mixed by the weight portion of 20-60 part, 10-20 part, 10-20 part, 10-20 part and 5-15 part after, spray or be printed on the surface of base material and form light-accumulated luminous layer;
3) silver powder, glass microballoon, polyester resin, thinning agent, varnish and hardening agent are mixed by the weight portion of 0.001-0.05 part, 50-70 part, 15-20 part, 5-15 part, 40-60 part, 5-15 part after, spray or be printed on the surface of step 2 and form reflector layer;
4) printing ink, resin and hardening agent are mixed by the weight portion of 45-65 part, 12-21 part, 5-15 part after, spray or be printed on the surface of reflector layer and form pattern and character layer.
The invention has the beneficial effects as follows: owing between light-accumulated luminous layer and pattern and character layer, the reflector layer that adopts glass microballoon to process is arranged; Making the present invention have reflection ray also can effectively stop liquid or other materials to get into the effect of base material; And because glass microballoon also has wear-resisting effect, so the present invention has just had luminous reflecting and wear-resisting anti-skidding antiseptic property simultaneously; The present invention also can be provided with the wear-resisting skid resistant course that one deck adopts glass dust and emergy to process, and makes its wear-resisting anti-skidding antiseptic power stronger; The present invention also can paste double faced adhesive tape at substrate backside, forms the luminous reflecting sign of band gum, and is convenient during use.The present invention can be widely used in special places such as public places such as public places of entertainment such as skyscraper, Internet bar, hotel, dancing hall and subway, airport, market and oily station, mine, underpass; Can also have a power failure, play the effect of dredging during accident such as fire, as urgent indication.
Description of drawings
Fig. 1 is a synoptic diagram of the present invention.
Fig. 2 is that structure of the present invention is dissected synoptic diagram.
Fig. 3 is the device synoptic diagram that the present invention carries out the anti-wear performance test.
Embodiment
As depicted in figs. 1 and 2, light accumulating, emitting and reflecting mark plaster of the present invention is on base material 1, to set gradually light-accumulated luminous layer 2, reflector layer 3 and pattern and character layer 4.Wherein materials such as the PVC plate of the following thickness of base material 1 employing 3.0cm, aluminium sheet are processed; Light-accumulated luminous layer 2 is processed by light-accumulated luminous powder, thinning agent, varnish, polyester resin and hardening agent; Reflector layer 3 is processed by silver powder, glass microballoon, thinning agent, varnish, polyester resin and hardening agent, and the silver powder in the reflector layer 3 can provide one deck reflective surface around glass microballoon, thereby plays the effect that improves the glass microballoon reflecting effect; Pattern and character layer 4 adopt spraying or mode of printing to process.
Above-mentioned light-accumulated luminous powder holds light, the luminous function in dark place owing to having when light is arranged; Therefore make light-accumulated luminous layer 2 have light-accumulated luminous function; And, therefore make pattern and character layer 4 have observable brightness at the dark place because pattern and character layer 4 are provided with above that; Therefore above-mentioned glass microballoon makes reflector layer 3 have the function of reflection ray owing to have the effect of reflection ray, and because pattern and character layer 4 are provided with above that, therefore makes pattern and character layer 4 also have observable brightness at the dark place; Also can effectively stop other materials to get into base material 1 because glass microballoon is the material with granularity again, so reflector layer 3 has had wear-resisting, anti-skidding and the corrosion-resistant function again.
The glass microballoon of above-mentioned reflector layer 3 can adopt the specification of 200-800 order fineness.
In order to strengthen wear-resisting anti-skidding antiseptic power of the present invention, the wear-resisting skid resistant course 5 of one deck also can be set on above-mentioned pattern and character layer 4, wear-resisting skid resistant course 5 is processed by glass dust, polyester resin, thinning agent, varnish, hardening agent and emergy.The effect of glass dust in wear-resisting skid resistant course 5 has two: the firstth, strengthen the rub proofness of wear-resisting skid resistant course 5, and the secondth, fill and strengthen the intensity of wear-resisting skid resistant course 5.The specification of glass dust can adopt 200-600 order fineness, and the specification of emergy can adopt 50-400 order fineness, because emergy is bigger than the granularity of glass microballoon, therefore wear-resisting skid resistant course 5 has stronger wear-resisting, the anti-skidding and function that is easy to discern.
In order the background of a white to be provided for light-accumulated luminous layer 2; The light that light-accumulated luminous layer 2 is sent can not receive the influence of background and upwards send largely; The present invention also has white background layer 7 between base material 1 and light-accumulated luminous layer 2; White background layer 7 is processed by titanium white powder, resin, hardening agent and thinning agent, and wherein titanium white powder also can adopt the white powder of other discord resin reaction to substitute.
Thinning agent of the present invention can adopt all-purpose diluent or nitro-diluent; Resin can adopt polyvinyl chloride resin, epoxy resin or acryl resin; Hardening agent adopts the hardening agent with corresponding resin complete.
Above-mentioned polyester resin can adopt synthetic polyester resin or other polyester resin, and varnish can adopt quartzy varnish or other varnish, and printing ink can adopt colored ink or other printing ink.
The concrete method for making of light accumulating, emitting and reflecting mark plaster of the present invention is:
1) base material 1 is pressed required form cutting polishing moulding;
2) light-accumulated luminous powder, thinning agent, varnish, polyester resin and hardening agent are mixed by the weight portion of 20-60 part, 10-20 part, 10-20 part, 10-20 part and 5-15 part after, spray or be printed on the surface of base material 1 and form light-accumulated luminous layer 2;
3) silver powder, glass microballoon, polyester resin, thinning agent, varnish and hardening agent are mixed by the weight portion of 0.001-0.05 part, 50-70 part, 15-20 part, 5-15 part, 40-60 part, 5-15 part after, spray or be printed on the surface of step 2 and form reflector layer 3;
4) printing ink, resin and hardening agent are mixed by the weight portion of 45-65 part, 12-21 part, 5-15 part after, spray or be printed on the surface of reflector layer 3 and form pattern and character layer 4.
Also having following steps between above-mentioned steps 1 and the step 2: after titanium white powder, resin, hardening agent, thinning agent are mixed by the weight portion of 8-10 part, 8-10 part, 6-8 part, 2.5-5 part, spray or be printed on and form white background layer 7 on the said base material 1.
In order to provide the silver end to strengthen the reflection strength of reflector layer 3 for reflector layer 3; Also having following steps between above-mentioned steps 2 and the step 3: after silver powder, thinning agent, varnish and hardening agent are mixed by the weight portion of 0.01-0.03 part, 35-45 part, 25-35 part, 5-12 part, spray or be printed on the surface of light-accumulated luminous layer 2.
In order to strengthen wear-resisting anti-skidding antiseptic power of the present invention; Also have following steps in above-mentioned steps 4 back: after glass dust, polyester resin, thinning agent, varnish and hardening agent are mixed by the weight portion of 5-10 part, 35-40 part, 12-21 part, 12-21 part, 5-15 part, spray or be printed on the surface of said pattern and character layer 4; Then emergy is evenly sprayed in the 50-500g/m2 ratio or print on it, form wear-resisting skid resistant course 5.
In practical application; Can light accumulating, emitting and reflecting mark plaster of the present invention directly be sticked on ground, metope or other places that need use; Also can paste double faced adhesive tape 7 at base material 1 back side, form the light accumulating, emitting and reflecting mark plaster of band gum, only need tear the diaphragm of double faced adhesive tape 7 during installation off; Then light accumulating, emitting and reflecting mark plaster is sticked on the place that needs use, use convenient.
Below be 3 wear-resisting embodiment; Be respectively that the 2 kinds of labelings of the present invention (labeling 1 and labeling 2 in the table 1) of 0.5cm and other labeling (labeling 3 in the table 1), PVC plate, aluminium sheet and the acrylic board of same thickness carry out the anti-wear performance test as specimen respectively with thickness; Proving installation is as shown in Figure 3, and device comprises stirrer 9, connecting link 10, nog plate 11, specimen 12 and backing plate 13.Test condition: 200 rev/mins of rotating speeds, wear surface pressure 0.025kg/cm 2(nog plate 11 diameter 10cm, area 78.5cm 2, keep 2 kilograms of contact weight.), wearing time 5 minutes.Abrasion high computational method is: after the anti-wear performance test, with the average abrasion of five some gained of miking sample wear surface highly.
Labeling 1 in the table is the labeling that the present invention has light-accumulated luminous layer, the silver end, white background layer, reflector layer, pattern and character layer and wear-resisting skid resistant course; Labeling 2 is labelings that the present invention has light-accumulated luminous layer, reflector layer and pattern and character layer; Labeling 3 is the labelings that have only light-accumulated luminous layer and pattern and character layer.
Embodiment 1:
Light accumulating, emitting and reflecting mark plaster of the present invention is processed by following material and proportioning:
1) white background layer: titanium white powder, polyvinyl chloride resin, hardening agent, nitro-diluent are mixed by 8 parts, 8 parts, 6 parts, 2.5 parts weight portion;
2) light-accumulated luminous layer: light-accumulated luminous powder, nitro-diluent, varnish, polyester resin and the hardening agent weight portion by 20 parts, 10 parts, 12 parts, 10 parts and 6 parts is mixed;
3) the silver end: silver powder, nitro-diluent, varnish and the hardening agent weight portion by 0.01 part, 35 parts, 25 parts, 5 parts is mixed;
4) reflector layer: silver powder, glass microballoon, polyester resin, nitro-diluent, varnish and the hardening agent weight portion by 0.002 part, 50 parts, 15 parts, 5 parts, 40 parts, 5 parts is mixed;
5) pattern and character layer: printing ink, polyvinyl chloride resin and the hardening agent weight portion by 45 parts, 15 parts, 6 parts is mixed;
6) wear-resisting skid resistant course: glass dust, polyester resin, nitro-diluent, varnish and the hardening agent weight portion by 5 parts, 35 parts, 15 parts, 15 parts, 5 parts is mixed, and emergy is pressed 50g/m 2Ratio evenly sprays.
Wear-resisting data are seen table 1:
Specimen Abrasion percentage by weight (%) Average abrasion height (cm)
Labeling 1 0.51 0.013
Labeling 2 3.41 0.092
Labeling 3 4.21 0.111
Aluminium sheet 1.83 0.047
The PVC plate 4.28 0.109
Acrylic board 2.32 0.059
Can find out from table 1: labeling 1 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 2, that is to say that the labeling of the present invention of wear-resisting skid resistant course is more much better than the anti-wear performance of the labeling of the present invention that does not have wear-resisting skid resistant course; Labeling 2 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 3, that is to say that the labeling of the present invention of reflector layer is more much better than the anti-wear performance of the labeling of the prior art that does not have reflector layer; The anti-wear performance of labeling 1 is all more much better than PVC plate, aluminium sheet and acrylic board; The anti-wear performance of labeling 2 is more less better than aluminium sheet and acrylic board, but more much better than the anti-wear performance of PVC plate; The anti-wear performance of labeling 3 and PVC plate is similar basically.
Embodiment 2:
Light accumulating, emitting and reflecting mark plaster of the present invention is processed by following material and proportioning:
1) white background layer: titanium white powder, epoxy resin, hardening agent, nitro-diluent are mixed by 10 parts, 10 parts, 8 parts, 5 parts weight portion;
2) light-accumulated luminous layer: light-accumulated luminous powder, nitro-diluent, varnish, polyester resin and the hardening agent weight portion by 40 parts, 15 parts, 20 parts, 15 parts and 15 parts is mixed;
3) the silver end: silver powder, nitro-diluent, varnish and the hardening agent weight portion by 0.02 part, 40 parts, 35 parts, 12 parts is mixed;
4) reflector layer: silver powder, glass microballoon, polyester resin, nitro-diluent, varnish and the hardening agent weight portion by 0.01 part, 55 parts, 15 parts, 10 parts, 50 parts, 15 parts is mixed;
5) pattern and character layer: printing ink, epoxy resin and the hardening agent weight portion by 50 parts, 18 parts, 10 parts is mixed;
6) wear-resisting skid resistant course: glass dust, polyester resin, nitro-diluent, varnish and the hardening agent weight portion by 9 parts, 38 parts, 18 parts, 18 parts, 12 parts is mixed, and emergy is pressed 300g/m 2Ratio evenly sprays.
Wear-resisting data are seen table 2:
Specimen Abrasion percentage by weight (%) Average abrasion height (cm)
Labeling 1 0.36 0.009
Labeling 2 3.35 0.086
Labeling 3 4.18 0.108
Aluminium sheet 1.83 0.047
The PVC plate 4.28 0.109
Acrylic board 2.32 0.059
Can find out from table 2: labeling 1 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 2, that is to say that the labeling of the present invention of wear-resisting skid resistant course is more much better than the anti-wear performance of the labeling of the present invention that does not have wear-resisting skid resistant course; Labeling 2 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 3, that is to say that the labeling of the present invention of reflector layer is more much better than the anti-wear performance of the labeling of the prior art that does not have reflector layer; The anti-wear performance of labeling 1 is all more much better than PVC plate, aluminium sheet and acrylic board; The anti-wear performance of labeling 2 is more less better than aluminium sheet and acrylic board, but more much better than the anti-wear performance of PVC plate; The anti-wear performance of labeling 3 and PVC plate is similar basically.
Embodiment 3:
Light accumulating, emitting and reflecting mark plaster of the present invention is processed by following material and proportioning:
1) white background layer: titanium white powder, acryl resin, hardening agent, all-purpose diluent are mixed by 10 parts, 10 parts, 8 parts, 5 parts weight portion;
2) light-accumulated luminous layer: light-accumulated luminous powder, all-purpose diluent, varnish, polyester resin and the hardening agent weight portion by 60 parts, 20 parts, 20 parts, 20 parts and 15 parts is mixed;
3) the silver end: silver powder, all-purpose diluent, varnish and the hardening agent weight portion by 0.03 part, 45 parts, 35 parts, 12 parts is mixed;
4) reflector layer: silver powder, glass microballoon, polyester resin, all-purpose diluent, varnish and the hardening agent weight portion by 0.05 part, 70 parts, 20 parts, 15 parts, 60 parts, 15 parts is mixed;
5) pattern and character layer: printing ink, acryl resin and the hardening agent weight portion by 65 parts, 20 parts, 15 parts is mixed;
6) wear-resisting skid resistant course: glass dust, polyester resin, all-purpose diluent, varnish and the hardening agent weight portion by 10 parts, 40 parts, 21 parts, 21 parts, 15 parts is mixed, and emergy is pressed 400g/m 2Ratio evenly sprays.
Wear-resisting data are seen table 3:
Specimen Abrasion percentage by weight (%) Average abrasion height (cm)
Labeling 1 0.28 0.007
Labeling 2 3.26 0.083
Labeling 3 4.11 0.105
Aluminium sheet 1.83 0.047
The PVC plate 4.28 0.109
Acrylic board 2.32 0.059
Can find out from table 3: labeling 1 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 2, that is to say that the labeling of the present invention of wear-resisting skid resistant course is more much better than the anti-wear performance of the labeling of the present invention that does not have wear-resisting skid resistant course; Labeling 2 highly all lacks with average abrasion than the abrasion percentage by weight of labeling 3, that is to say that the labeling of the present invention of reflector layer is more much better than the anti-wear performance of the labeling of the prior art that does not have reflector layer; The anti-wear performance of labeling 1 is all more much better than PVC plate, aluminium sheet and acrylic board; The anti-wear performance of labeling 2 is more less better than aluminium sheet and acrylic board, but more much better than the anti-wear performance of PVC plate; The anti-wear performance of labeling 3 and PVC plate is similar basically.
Can find out from above 3 embodiment: have the labeling of the present invention of wear-resisting skid resistant course better than the anti-wear performance of the labeling of the present invention that does not have wear-resisting skid resistant course; There is the labeling of the present invention of reflector layer better than the anti-wear performance of the labeling of the prior art that does not have reflector layer.
Though the present invention is through being described with reference to preferred embodiment.But those skilled in the art should understand, and in the scope of claims, can do various variations on form and the details.

Claims (11)

1. light accumulating, emitting and reflecting mark plaster; Comprise base material (1), light-accumulated luminous layer (2) and pattern and character layer (4); It is characterized in that: between said light-accumulated luminous layer (2) and pattern and character layer (4), also have reflector layer (3); On said base material (1), set gradually light-accumulated luminous layer (2), reflector layer (3) and pattern and character layer (4), said reflector layer (3) is processed by the weight portion of 0.001-0.05 part, 50-70 part, 15-20 part, 5-15 part, 40-60 part, 5-15 part by silver powder, glass microballoon, polyester resin, thinning agent, varnish and hardening agent.
2. light accumulating, emitting and reflecting mark plaster as claimed in claim 1 is characterized in that: on said pattern and character layer (4), also have wear-resisting skid resistant course (5).
3. light accumulating, emitting and reflecting mark plaster as claimed in claim 2 is characterized in that: said wear-resisting skid resistant course (5) is processed by glass dust, polyester resin, thinning agent, varnish, hardening agent and emergy.
4. light accumulating, emitting and reflecting mark plaster as claimed in claim 1 is characterized in that: between said base material (1) and light-accumulated luminous layer (2), also have white background layer (7).
5. light accumulating, emitting and reflecting mark plaster as claimed in claim 4 is characterized in that: said white background layer (7) is processed by titanium white powder, resin, hardening agent and thinning agent.
6. light accumulating, emitting and reflecting mark plaster as claimed in claim 1 is characterized in that: said light-accumulated luminous layer (2) is processed by light-accumulated luminous powder, thinning agent, varnish, polyester resin and hardening agent.
7. light accumulating, emitting and reflecting mark plaster as claimed in claim 1 is characterized in that: be provided with double faced adhesive tape (6) at the back side of said base material (1).
8. the method for making of the described light accumulating, emitting and reflecting mark plaster of claim 1, it is characterized in that: this method may further comprise the steps:
1) base material (1) is pressed required form cutting polishing moulding;
2) light-accumulated luminous powder, thinning agent, varnish, polyester resin and hardening agent are mixed by the weight portion of 20-60 part, 10-20 part, 10-20 part, 10-20 part and 5-15 part after, spray or be printed on the surface of base material (1) and form light-accumulated luminous layer (2);
3) silver powder, glass microballoon, polyester resin, thinning agent, varnish and hardening agent are mixed by the weight portion of 0.001-0.05 part, 50-70 part, 15-20 part, 5-15 part, 40-60 part, 5-15 part after, spray or be printed on the surface of step 2 and form reflector layer (3);
4) printing ink, resin and hardening agent are mixed by the weight portion of 45-65 part, 12-21 part, 5-15 part after, spray or be printed on the surface of reflector layer (3) and form pattern and character layer (4).
9. the method for making of the described light accumulating, emitting and reflecting mark plaster of claim 8; It is characterized in that: also having following steps between said step 1 and the step 2: after titanium white powder, resin, hardening agent, thinning agent are mixed by the weight portion of 8-10 part, 8-10 part, 6-8 part, 2.5-5 part, spray or be printed on said base material (1) and go up and form white background layer (7).
10. the method for making of light accumulating, emitting and reflecting mark plaster as claimed in claim 8; It is characterized in that: also having following steps between said step 2 and the step 3: after silver powder, thinning agent, varnish and hardening agent are mixed by the weight portion of 0.01-0.03 part, 35-45 part, 25-35 part, 5-12 part, spray or be printed on the surface of light-accumulated luminous layer (2).
11. the method for making of light accumulating, emitting and reflecting mark plaster as claimed in claim 8; It is characterized in that: also have following steps: after glass dust, polyester resin, thinning agent, varnish and hardening agent are mixed by the weight portion of 5-10 part, 35-40 part, 12-21 part, 12-21 part, 5-15 part, spray, be imprinted on the surface of said pattern and character layer (4) in said step 4 back; Then emergy is pressed 50-500g/m 2Ratio evenly sprays or prints on it, forms wear-resisting skid resistant course (5).
CN 200810304340 2007-09-07 2008-09-02 Light accumulating, emitting and reflecting mark plaster and preparation thereof Expired - Fee Related CN101364358B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200810304340 CN101364358B (en) 2007-09-07 2008-09-02 Light accumulating, emitting and reflecting mark plaster and preparation thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200710201614 2007-09-07
CN200710201614.6 2007-09-07
CN 200810304340 CN101364358B (en) 2007-09-07 2008-09-02 Light accumulating, emitting and reflecting mark plaster and preparation thereof

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CN101364358B true CN101364358B (en) 2012-12-05

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Publication number Priority date Publication date Assignee Title
CN103578377A (en) * 2012-07-19 2014-02-12 深圳市蓝港反光材料有限公司 Water transfer printed light-reflecting marking manufacturing method and light-reflecting device manufacturing method
CN103129031A (en) * 2013-03-11 2013-06-05 方显峰 High-brightness long-afterglow illuminant and manufacturing method thereof
CN107734892B (en) * 2017-10-30 2020-04-10 Oppo广东移动通信有限公司 Shell manufacturing method, shell and electronic equipment

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Address before: 611731 Sichuan city of Chengdu province high tech Zone (West) New Road No. 2

Patentee before: Sichuan Sunfor Light Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121205

Termination date: 20180902

CF01 Termination of patent right due to non-payment of annual fee