CN101358292A - Feeding method for preparing high nickel matte - Google Patents
Feeding method for preparing high nickel matte Download PDFInfo
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- CN101358292A CN101358292A CNA2008101324591A CN200810132459A CN101358292A CN 101358292 A CN101358292 A CN 101358292A CN A2008101324591 A CNA2008101324591 A CN A2008101324591A CN 200810132459 A CN200810132459 A CN 200810132459A CN 101358292 A CN101358292 A CN 101358292A
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Abstract
The invention discloses a feeding method for preparing high grade nickel matte, which comprises the following steps: a) low grade nickel matte is put into a continuous converting furnace with the temperature of 1100 DEG C to 1300 DEG C; b) slagging agent is added into the continuous converting furnace, and oxidative gas is blown into the continuous converting furnace; the oxidative gas reacts with the low grade nickel matte to produce high grade nickel matte, slag and smoke gas; the slagging agent is added into the continuous converting furnace for at least three times. Because the adding method of the slagging agent has an important influence on the reaction temperature and the reaction progress, the invention can prepare the slag separated from the high grade nickel matte through adding the slagging agent into the converting furnace for a plurality of times; meanwhile, the invention can recover the nickel in the low grade nickel matte at a higher recovery rate and reduce the nickel content in the slag.
Description
Technical field
The present invention relates to prepare the feeding method of rich nickel product, be specifically related to a kind of feeding method of the high ice of the preparation nickel that blows.
Background technology
Nickel is widely used in fields such as stainless steel, plating, battery owing to having excellent mechanical intensity, ductility and very high chemical stability.Can two classes be arranged for the nickel resources that the people develops at present, a class is a red soil nickel ore, and another kind of is nickel sulfide ore.About 1.6 hundred million tons of the explored nickel resources in the whole world, wherein 30% is that nickel sulfide ore, 70% is red soil nickel ore, the nickel product has 60% to come from sulphide ores approximately.Yet the world can be for the nickelous sulfide resource of recent development, and except the nickel minerals of Canadian Wo Yisi gulf (Voisey bay), all the other are very few, and nickelous sulfide resource exploration cycle and construction period are all longer, and development and utilization is difficulty relatively.And the red soil nickel ore aboundresources, mining cost is low, selects nickel technology to be tending towards ripe, can produce the multiple middle sheet that produces such as nickel oxide, sulphur nickel, ferronickel, and mineral resources is convenient to transportation by the sea.Therefore, the development and use red soil nickel ore has great importance.
Red soil nickel ore is the loose argillaceous ore that hydrous oxides such as iron, aluminium, silicon are formed, by nickeliferous rock decay, soak pouring, alteration, enrichment and form.Existing explored red soil nickel ore resource is distributed in south, the tropic of Cancer one band more, as Australia, Papua New Guinea, New Caledonia, Indonesia, Philippines and Cuba and other places.Red soil nickel ore can be divided into two types, and a kind of is the limonite type, is positioned at the top in mineral deposit, and iron height, nickel are low, and silicon magnesium is lower, but cobalt contents is higher, and this ore should adopt hydrometallurgical processes to handle, and the slag that smelting ferronickel produces is used for the production of steel.Another kind is a noumeite, is positioned at the bottom in mineral deposit, and silicon, Mg content are higher, and iron, cobalt contents are lower, but nickel content is higher, and this ore should adopt fire metallurgy process to handle.Generally contain 30%～45% water in the laterite, wherein crystal water accounts for 10%～15%, and outside dewatering, its major ingredient of above-mentioned two types laterite can see Table 1, and the component content of being mentioned all is a weight ratio herein.
Two kinds of ore deposits of table 1 red soil nickel ore type main component (%)
At present, the pyrometallurgical smelting process of silicium magnesium laterite ore has ferronickel technology and two kinds of operational paths of nickel sulphur technology, and main melting equipment has rotary kiln, electric furnace and blast furnace.Main products by the silicium magnesium laterite ore preparation is a low nickel matte, and wherein nickel content is generally 8%～20%.Because it is that height 40% or more is iced nickel that low nickel matte can further prepare nickel content, this product has bigger handiness: directly the general nickel of stainless steel industry is produced in retailoring behind desulfurization with roasting technique, also can be used as the raw material production nickel rondelle and the nickel powder of normal pressure powder base method refining nickel, can also directly cast the plant produced cathode nickel that positive plate send the nickelous sulfide electrorefining.Therefore, nickel sulphur technology smelting red soil nickel ore has good market outlook.
Under prior art, adopt the high ice of low nickel matte preparation nickel to adopt converter usually, concrete technology is: the fused low nickel matte is sent into converter, add slag former, in converter, feed pressurized air again and blow the impurity in the oxidation low nickel matte, make the oxide compound slag making, obtaining main component is Ni
3S
2Height ice nickel.But shortcomings such as investment is big because converter has, long construction period, complicated operation, and when adding slag former, because the slag former temperature is lower, therefore can reduce the converter temperature, make reaction unstable, and slag former has little time to participate in reaction, causes that composition changes greatly in the slag, makes high ice nickel and slag separation difficulty.
Therefore, need a kind of high feeding method of icing nickel of preparation that helps blowing.
Summary of the invention
The technical problem that the present invention solves is to provide a kind of high feeding method of icing nickel of preparation that helps blowing.
The invention provides a kind of feeding method for preparing high ice nickel, comprise step:
A) low nickel matte being put into temperature is 1100 ℃～1300 ℃ continuous-blowing furnace;
B) in described continuous-blowing furnace, add slag former, the oxidizing gas of in stove, jetting, described oxidizing gas and low nickel matte and slag former reaction obtain high ice nickel, slag and flue gas, and described slag former divides three times at least and adds described continuous-blowing furnace.
Main component by the low nickel matte of silicium magnesium laterite ore preparation is nickel, iron, sulphur, and most of existence form of three kinds of elements is Ni
3S
2FeS, iron level is generally more than 40% in the low nickel matte, and the main purpose of low nickel matte blowing is iron and the most sulphur of removing as much as possible wherein, when blowing, behind the feeding oxidizing gas, because following reaction mainly takes place in the existence of oxygen:
2FeS+3O
2+SiO
2＝2FeO·SiO
2+2SO
2↑(1)
In addition, a part of nickelous sulfide also can be oxidized, and following reaction takes place:
2Ni
3S
2+7O
2＝6NiO+4SO
2↑(2)
Because the density of nickel protoxide is little, therefore meeting and slag are drained together, and when in the stove Iron sulfuret being arranged, the oxide compound of nickel can become sulfide again, and following reaction takes place:
3NiO+3FeS+O
2＝3FeO+Ni
3S
2+SO
2↑(3)
Like this, nickel protoxide can be entered in the nickel matte by slag, and when Iron sulfuret seldom the time, reaction (3) can stop, and nickel protoxide enters in the slag.Therefore, must ice the iron that keeps a part in the nickel at height.The blowing of low nickel matte is violent thermopositive reaction, and the heat during blowing provides by id reaction, and the too high meeting of temperature causes nickel content increase in the slag, and temperature is crossed low influence blowing effect.
After in stove, adding low nickel matte, make its stable for some time, calculate the silica volume that needs according to the iron level in the low nickel matte according to reaction (1) then, add suitably excessive silicon-dioxide.General actual addition is 101%～110% of an actual requirement, if what add too much also is inappropriate, not only can cause unnecessary waste, and because quartz sand also can reduce temperature of reaction, but also can cause in the slag dioxide-containing silica too much, increase the isolating difficulty of slag.Add when quartzy, if be inappropriate disposable quartz is all added in the Reaktionsofen, because the straying quatity of oxidizing gas is a fixed, so quartz sand has little time all can to cause more silicon-dioxide to enter into slag and to go referring to reaction.Therefore, quartz need be divided at least 2 addings; Preferably, quartz is divided into 3 addings; Preferred, divide 4 addings with quartz.But the quartz amount that should be noted that each adding can not be very little, if the quartz amount that adds is not enough, has that too much nickelous sulfide is oxidized to be entered in the slag.Therefore, add quartzy what and frequency and can whether meet aforementioned slag type according to nickel content and the quartz content that reaction be carried out in the central slag.
Therefore, when the blowing reaction, need at set intervals nickel matte and slag sampling to be carried out composition analysis,,, quartzy add-on is heightened, reduce total indegree that adds if the nickel content in the slag has surpassed the target value of nickel in the slag type according to target slag type; If dioxide-containing silica is too high in the slag, illustrate that silicon-dioxide fails complete reaction, the add-on of silicon-dioxide need be turned down, adding indegree increases.
In addition, when blowing, need gas to react from entering below the liquid level of low nickel matte, help making melt to keep the stirring condition like this, therefore the liquid level of low nickel matte need exceed blast inlet, and still, too high distance can make the reaction severe degree strengthen, cause the over-blowing of nickel matte, make nickel content increase in the slag; If liquid level is low excessively, speed of response is slow excessively, also can reduce the slag making level of response.Therefore, the liquid level of the interior low nickel matte of continuous-blowing furnace is higher than the air port 50mm～200mm of continuous-blowing furnace among the present invention, and preferred, the liquid level of low nickel matte is at the above 70mm～120mm in the air port of described continuous-blowing furnace.
From above reaction as can be seen, the main component of slag former is a silicon-dioxide, and therefore the slag former that can select for use has quartz sand etc.In addition, in order to be beneficial to the slag making reaction, the granularity D90 of quartz sand provided by the invention is 4mm～20mm, and preferred, the granularity D90 of quartz sand is 5mm～10mm.If the granularity of quartz sand is excessive or too small, when air stirs melt, all be unfavorable for the even dispersion in the melt of quartz sand, be unfavorable for the slag making reaction.
Normal temps during blowing is 1100 ℃～1300 ℃, and too high or low excessively temperature is unfavorable for that all the slag making successful reaction carries out.Therefore, the present invention with low nickel matte put into temperature be 1100 ℃～1300 ℃ begin the reaction, low nickel matte can be for molten state, also can be for solid-state, if it is solid-state, in continuous-blowing furnace, need to be incubated the sufficiently long time, the temperature of low nickel matte is remained in 1100 ℃～1300 ℃ the scope.Preferably, low nickel matte being placed on temperature is in 1170 ℃～1250 ℃ the scope.
In order to reach purpose of the present invention, the purpose that sprays into oxidizing gas in stove mainly provides oxygen with the FeS oxidation in the low nickel matte, therefore, can bubbling air or the air of oxygen enrichment, preferably, feed common air, because if oxygen content is too high in the air, can aggravation react, cause nickel too high levels in the slag.During blowing gas, gaseous tension has determined the speed that sprays into of gas, and the speed that gas sprays into is too high or cross the carrying out of the low reaction that all is unfavorable for blowing.This is because excessive for the stirring of low nickel matte during excessive velocities if gaseous tension is too high, the oxidized degree of nickelous sulfide increases, and may make nickel content increase in the slag.If gaseous tension is low excessively, do not reach requirement for the stirring of low nickel matte, reaction can not fully be carried out.When jetting oxidizing gas among the present invention in continuous-blowing furnace, the blast of oxidizing gas is 0.05MPa～0.2MPa; Preferably, the blast of oxidizing gas is 0.06MPa～0.16MPa; Preferred, the blast of oxidizing gas is 0.08MPa～0.16MPa.
In addition, in order to control the severe degree that reaction is carried out, need amount of oxygen in the controlled oxidation gas, the amount of being blown into that the invention provides oxygen in the oxidizing gas is 5～12m
3/ minm
2Preferably, the amount of being blown into of oxygen is 6～10m in the oxidizing gas
3/ minm
2Preferred, the amount of being blown into of oxygen is 7～9m in the oxidizing gas
3/ minm
2When spraying into air, can calculate the straying quatity of the air of should jetting according to the volumn concentration of airborne oxygen.If air quantity is excessive, amount of oxygen is too much so, and it is more violent that reaction (2) is carried out, so the increase of the nickel content in the slag, and the iron protoxide in air port is further generated Fe easily
3O
4, because Fe
3O
4Fusing point is up to 1597 ℃, can make in the stove melt thickness that becomes, and the slag properties deterioration brings many disadvantageous effects to converting process.If air quantity is too small, amount of oxygen is not enough so, and it is insufficient that the slag making reaction is carried out, and also is unfavorable for the enrichment of nickel.
By as can be known aforementioned, blowing main purpose for low nickel matte is to make the iron in the low nickel matte generate slag, and nickel wherein is retained in the melt, then slag is separated with nickel matte, therefore can the essence of blowing also be the process of refining slag, selects suitable slag type carry out smoothly and slag had great importance with separating of melt for reacting.Comprise following component in percentage by weight: SiO in the slag herein,
2: 15%～30%; Ni :≤4%; Preferably, SiO
2: 18%～25%; Ni :≤2%.If SiO
2Too much, slag is clamminess, and is mobile poor.If SiO
2Very few, the slag making reaction may be insufficient, but also have other unfavorable effect, as produce too much furnace accretion.According to the present invention, the height of generation ice nickel comprises following component in percentage by weight: Ni: 〉=45%, and Fe≤7%, S:20%～25%; Preferably, Ni: 〉=50%, Fe≤5%, S:20%～25%; Preferred, Ni: 〉=65%, Fe≤4.5%, S:22%～24%.
The invention provides a kind of feeding method for preparing high ice nickel.Of the present invention low nickel matte and slag former are put into continuous-blowing furnace after, the oxidizing gas of in stove, jetting, obtain high ice nickel, slag and flue gas after oxidizing gas and low nickel matte and the slag reaction, because the add-on of slag former influences temperature of reaction and degree is carried out in reaction, the invention provides and divide the adding continuous-blowing furnace at least three times slag former.Slag former be divided into repeatedly add continuous-blowing furnace after, can keep needed temperature in the stove, and help controlling level of response, prepare segregative slag, with the nickel enrichment in the low nickel matte, reduce the nickel content in the slag with higher recovery simultaneously.
Description of drawings
Fig. 1 is high ice nickel method synoptic diagram for the present invention prepares;
Fig. 2 be among Fig. 1 converting furnace along the sectional view of A-A direction;
Fig. 3 be among Fig. 1 converting furnace along the sectional view of B-B direction.
Embodiment
In order further to understand the present invention, below in conjunction with embodiment the preferred embodiment of the invention is described, but should be appreciated that these describe just to further specifying the features and advantages of the present invention, rather than to the restriction of claim of the present invention.
In order to reach purpose of the present invention, use the high ice of continuous-blowing furnace blowing nickel.See also Fig. 1, be used continuous-blowing furnace front view in the embodiment of the invention, continuous-blowing furnace comprises that basic is the cupola well 11 of rectangular shape, cupola well comprises two relative long side walls and the minor face sidewall that is connected two long side walls, on a minor face sidewall, comprise opening for feed 11a, on two relative long side walls, comprise some to symmetrical airduct 11b, on the minor face sidewall of a relative side with opening for feed, comprise slag notch 11c, in order to help separating of slag and high ice nickel, the furnace bottom of cupola well is in the part that is higher than near the part of opening for feed near slag notch, is connected with vertical flue 12 on the cupola well.
See also Fig. 2, Fig. 2 is that converting furnace is along the sectional view of A-A direction among Fig. 1, and the air port end of airduct 11b extend into and becomes 15 degree angles in the cupola well and with level
See also Fig. 3, Fig. 3 is that converting furnace on a long side wall, comprises discharge port 11d along the sectional view of B-B direction among Fig. 1, because slag is lighter than high ice nickel density, float over above the high ice nickel, so discharge port 11d is lower than slag notch 11c.
According to the present invention, when the granularity of quartz sand is carried out sampling and measuring, provide D10, D25, D50, D75 and D90 value respectively.On behalf of the material piece, the corresponding particle size values of D10, D25, D50, D75 and D90 reach maximum particle diameter value 10%, 25%, 50%, 75% and 90% respectively from the mass percent of small powder piece accumulative total respectively.The method of calculation of the rate of recovery of nickel herein account for the weight percent of the nickel content in the low nickel matte for the nickel content in the high ice nickel.
Embodiment 1
Get raw material 1a low nickel matte 120kg, its major ingredient content sees Table 2.After continuous-blowing furnace is warming up to 1150 ℃, put into continuous-blowing furnace after raw material 1a melted in smelting furnace, melt liquid level is higher than the air port distance and is about 98mm, be incubated 1 hour melt is stablized.Get raw material 1b quartz sand 38kg, its dioxide-containing silica and size-grade distribution are referring to table 3.Quartz sand is divided into 3 basic five equilibriums, in 90 minutes adding converting furnaces.
The air of jetting in stove measures that the oxygen volumn concentration is 20.9% in the air, and winding-up air pressure is that 0.1MPa, winding-up amount are 33m
3/ minm
2
After reaction was carried out 5 hours, the iron level of measuring in the high ice nickel was 4.9%, finishes melting, discharged the height of following composition in the stove and iced nickel and slag:
High ice nickel: 69.1wt%Ni, 4.9wt%Fe, 22.6wt%S.
Slag: 2.22wt%Ni, 31.3wt%SiO
2, 52.9wt%Fe.
Altogether high ice nickel 17.52kg, the rate of recovery that can calculate nickel is 81.9%.
Embodiment 2
Get raw material 2a low nickel matte 120kg, its major ingredient content sees Table 2.After continuous-blowing furnace is warming up to 1200 ℃, be placed on continuous-blowing furnace after raw material 2a melted in smelting furnace, melt liquid level is higher than the air port distance and is 98mm, be incubated 1 hour melt is stablized.The speed of air with 0.12MPa is blown in the stove, and blast volume is 38m
3/ minm
2Get the quartzy 30kg of raw material 2b, its dioxide-containing silica and size-grade distribution are referring to table 3.Quartz sand is divided into 4 basic five equilibriums, in 60 minutes adding converting furnaces.
The air of jetting in stove measures that the oxygen volumn concentration is 20.9% in the air, and air pressure is that 0.1MPa, winding-up amount are 38m
3/ minm
2
After reaction was carried out 5 hours, the iron level of measuring in the nickel matte was 4.5%, finished melting, discharged the height of following composition in the stove and iced nickel and slag:
High ice nickel: 70.5wt%Ni, 4.6wt%Fe, 23.2wt%S.
Slag: 2.02wt%Ni, 30.4wt%SiO
2, 48.3wt%Fe.
Altogether high ice nickel 15.36kg, the rate of recovery that can calculate nickel is 82.8%.
Embodiment 3
Get raw material 3a low nickel matte 120kg, its major ingredient content sees Table 2.After continuous-blowing furnace is warming up to 1180 ℃, be placed on continuous-blowing furnace after raw material 3a melted in smelting furnace, the melt nightside is higher than the air port distance and is 98mm, be incubated 1 hour melt is stablized.The speed of air with 0.12MPa is blown in the stove, and blast volume is 40m
3/ minm
2Get the quartzy 29.5kg of raw material 3b, its dioxide-containing silica and size-grade distribution are referring to table 3.Quartz sand is divided into 5 basic five equilibriums, in 50 minutes adding converting furnaces.
The air of jetting in stove measures that the oxygen volumn concentration is 20.9% in the air, and air pressure is that 0.1MPa, winding-up amount are 38m
3/ minm
2
After reaction was carried out 5 hours, the iron level of measuring in the high ice nickel was 3.5%, finishes melting, discharged the height of following composition in the stove and iced nickel and slag:
High ice nickel: 72.6wt%Ni, 3.5wt%Fe, 22.7wt%S.
Slag: 2.19wt%Ni, 27.5wt%SiO
2, 44.7wt%Fe.
Altogether high ice nickel 18.99kg, the rate of recovery that can calculate nickel has reached 85.1%.
Embodiment 4
Get raw material 4a low nickel matte 120kg, its major ingredient content sees Table 2.After continuous-blowing furnace is warming up to 1150 ℃, put into continuous-blowing furnace after raw material 4a melted in smelting furnace, melt liquid level is higher than the air port distance and is about 98mm, be incubated 1 hour melt is stablized.Get raw material 1b quartz sand 33kg, quartz sand is divided into 6 basic five equilibriums, in 40 minutes adding converting furnaces.
The air of jetting in stove measures that the oxygen volumn concentration is 20.9% in the air, and air pressure is that 0.11MPa, winding-up amount are 39m
3/ minm
2
After reaction was carried out 5 hours, the iron level of measuring in the nickel matte was 4.9%, finished melting, discharged the height of following composition in the stove and iced nickel and slag:
High ice nickel: 68.4wt%Ni, 4.9wt%Fe, 22.5wt%S.
Slag: 2.78wt%Ni, 27.5wt%SiO
2, 48.2wt%Fe.
Altogether high ice nickel 22.52kg, the rate of recovery that can calculate nickel is 82.3%.
Comparative example 1
Get raw material 1a low nickel matte 120kg, continuous-blowing furnace is warming up to 1150 ℃ after, put into continuous-blowing furnace after raw material 1a melted in smelting furnace, melt liquid level is higher than the air port distance and is about 98mm, be incubated 1 hour the fusion low nickel matte is stablized.Get raw material 1b quartz sand 37.5kg, in the disposable adding continuous-blowing furnace of quartz sand.
The air of jetting in stove measures that the oxygen volumn concentration is 20.9% in the air, and jetting pressure is that 0.1MPa, winding-up amount are 38m
3/ minm
2
After reaction was carried out 5 hours, the iron level of measuring in the high ice nickel was 23.8%, finishes melting, discharged the height ice nickel and the slag of following composition:
High ice nickel: Ni:21.1wt%; Fe:23.8wt%, S:20.6wt%.
Slag: 4.6wt%Ni, 33.1wt%SiO
2, 51.2wt%Fe.
Altogether high ice nickel 47.2kg, the rate of recovery that can calculate nickel is 67.4%.
Table 2, raw material low nickel matte composition (wt%)
Raw material 1a raw material 2a raw material 3a raw material 4a
Ni 12.3 10.9 13.5 15.6
Fe 54.1 45.6 43.1 48.3
S 20.5 22.4 21.6 25.4
Table 3, raw material quartz sand composition and size-grade distribution
Raw material 1a raw material 1b raw material 2b raw material 3b
SiO2 (weight %) 92.5 95.5 94.6
Size-grade distribution (mm)
D10 0.05 1.25 3.22
D25 1.35 2.63 5.18
D50 2.56 4.58 8.57
D75 3.12 5.36 11.3
D90 4.53 7.62 14.5
From above narration as can be known, with slag former be divided into repeatedly add continuous-blowing furnace after, can keep needed temperature in the stove, and help controlling level of response, prepare segregative slag, with higher recovery with the nickel enrichment in the low nickel matte.
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1, a kind of feeding method for preparing high ice nickel comprises step:
A) low nickel matte being put into temperature is 1100 ℃～1300 ℃ continuous-blowing furnace;
B) add slag former in described continuous-blowing furnace, be blown into oxidizing gas in stove, described oxidizing gas and low nickel matte and slag former reaction obtain high ice nickel, slag and flue gas, and described slag former divides three times at least and adds described continuous-blowing furnace.
2, method according to claim 1 is characterized in that described slag former is divided into four times at least and adds described continuous-blowing furnace.
3, method according to claim 1 and 2 is characterized in that it is basic equivalent that described slag former adds continuous-blowing furnace at every turn.
4, method according to claim 1 is characterized in that the weight percent of silicon-dioxide in the described slag former is at least 80%.
5, method according to claim 4 is characterized in that described slag former is that granularity D90 is the quartz sand of 4mm～20mm.
6, method according to claim 5, the granularity D90 that it is characterized in that described quartz sand is 5mm～15mm.
7, method according to claim 1 and 2 is characterized in that described high ice nickel comprises following component in percentage by weight: Ni: 〉=45%; Fe≤7%, S:20%～25%.
8, method according to claim 7 is characterized in that described high ice nickel comprises following component in percentage by weight: Ni: 〉=55%; Fe≤4%, S:21%～25%.
9, method according to claim 1 and 2 is characterized in that described slag comprises following component in percentage by weight: SiO
2: 15%～30%; Ni :≤4%.
10, method according to claim 9 is characterized in that described slag comprises following component in percentage by weight: SiO
2: 18%～25%; Ni :≤2%.
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|---|---|---|---|
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838746B (en) * | 2009-12-30 | 2011-11-30 | 中国恩菲工程技术有限公司 | Process for smelting nickel-bearing laterite ore |
| CN101705367B (en) * | 2009-11-23 | 2012-09-05 | 长沙有色冶金设计研究院有限公司 | Copper nickel smelting process with oxygen-enriched side-blowing bath smelting method |
| CN104694972A (en) * | 2015-02-06 | 2015-06-10 | 铜陵百荣新型材料铸件有限公司 | Method for preparing ferro-nickle alloy from laterite nickel ore |
| WO2023077641A1 (en) * | 2021-11-03 | 2023-05-11 | 中伟新材料股份有限公司 | Smelting furnace for smelting nickel matte and production method for low nickel matte |
-
2008
- 2008-07-16 CN CN2008101324591A patent/CN101358292B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705367B (en) * | 2009-11-23 | 2012-09-05 | 长沙有色冶金设计研究院有限公司 | Copper nickel smelting process with oxygen-enriched side-blowing bath smelting method |
| CN101838746B (en) * | 2009-12-30 | 2011-11-30 | 中国恩菲工程技术有限公司 | Process for smelting nickel-bearing laterite ore |
| CN104694972A (en) * | 2015-02-06 | 2015-06-10 | 铜陵百荣新型材料铸件有限公司 | Method for preparing ferro-nickle alloy from laterite nickel ore |
| WO2023077641A1 (en) * | 2021-11-03 | 2023-05-11 | 中伟新材料股份有限公司 | Smelting furnace for smelting nickel matte and production method for low nickel matte |
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|---|---|
| CN101358292B (en) | 2010-07-21 |
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