CN101357873B - Continuous technique for preparing emulsifying explosive and charging - Google Patents

Continuous technique for preparing emulsifying explosive and charging Download PDF

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Publication number
CN101357873B
CN101357873B CN2007100753913A CN200710075391A CN101357873B CN 101357873 B CN101357873 B CN 101357873B CN 2007100753913 A CN2007100753913 A CN 2007100753913A CN 200710075391 A CN200710075391 A CN 200710075391A CN 101357873 B CN101357873 B CN 101357873B
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powder charge
sensitization
phase solution
continuous production
production technology
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CN101357873A (en
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明刚
明景谷
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Shenzhen King Explorer Science And Technology Corp
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JIN'AOBO SCIENCE AND TECHNOLOGY Co Ltd SHENZHEN CITY
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Abstract

The invention provides a continuous producing process for pharmacy and charging of emulsion explosive, which comprises the following steps: (1) aqueous phase solution and oil phase solution are respectively prepared; (2) the aqueous phase solution and the oil phase solution are delivered into a colostrum device for mixing, and after the process of colostrum, the aqueous phase solution and the oil phase solution are delivered into a static mixer for refining colostrum; (3) after the refined colostrum latex are delivered into a sensitized charging system for sensitized treatment, charging is carried out and after being cooled by a cooling system, the products are delivered to a packaging system for packaging. The technique proposal of the process is characterized by no warming after the process of the colostrum, high safety, and little damage of latex.

Description

Emulsion [explosive pharmacy and powder charge continuous production technology
Technical field
The invention belongs to emulsion explosive prodn technology, relate in particular to a kind of emulsion [explosive pharmacy and powder charge continuous production technology.
Background technology
At present, there are a lot of problems in emulsion [explosive continuous production technology in the prior art.
At first, in the existing emulsion [explosive continuous production technology, generally comprise preparation aqueous phase solution and oil-phase solution, colostrum, smart breast, cooling, sensitization powder charge and packaging and other steps successively.Adopt such process method; Latex is processed the back and is cooled off colloid through continuous enclosed cooler, steel band cooler or immersion continuous cooling equipment earlier; After the colloid temperature is cooled to 40~70 ℃ of scopes from 100 ℃ ± 15 ℃; Add chemical sensitizer or physical sensitization agent again, form the emulsion [explosive of chemical sensitization or physical sensitization.Adopt the technology of this back sensitization powder charge of cooling earlier, during the latex cooling,, all can produce damage in various degree latex because of it directly soaks or receives cooler to stir, scrape.
Secondly, in the existing emulsion [explosive continuous production technology, smart newborn device all uses the emulsor of dynamic shearing formula, and the power of consumption is very big and production capacity is little.And, adopting rotary smart emulsor, the latex temperature generally is higher than water, oil phase temperature after the emulsification; No matter have or not sealing, in oil, water cutout back or the cutout of sealing water coolant, still in the running like emulsor; All be prone to produce heat built-up and explosion caused danger, thereby security is relatively poor.
At last, because of medicine attitude thickness that becomes after cooling, increased the difficulty of follow-up powder charge, sensitization powder charge system generally adopts the paper web charge machine to carry out powder charge, and loading rate is low.
Summary of the invention
The technical problem that the embodiment of the invention will solve does not have intensification after being to provide a kind of emulsification, and is safe, and the latex damage is few, emulsion [explosive pharmacy and powder charge continuous production technology.
The embodiment of the invention is achieved in that a kind of emulsion [explosive pharmacy and powder charge continuous production technology, comprises the steps:
(1) prepares aqueous phase solution and oil-phase solution respectively;
(2) press processing compound, aqueous phase solution and oil-phase solution are conveyed into the mixing of colostrum device respectively, carry out colostrum, send into static mixer then and carry out the essence breast;
(3) be to send into sensitization powder charge system under the 88-92 ℃ of condition to carry out sensitization processing back powder charge with the essence latex in temperature; After the cooling system cooling, deliver to packaging system again and pack, said essence latex is directly sent into sensitization powder charge system without cooling and is carried out sensitization processing back powder charge.
Compared with prior art; The technical scheme that the embodiment of the invention provides; Because smart newborn device does not adopt rotary smart emulsor, and adopt static mixer, thereby avoided because of latex temperature after the emulsification is higher than water, the oil phase temperature produces the explosion caused danger of heat built-up.And the embodiment of the invention adopts the technology of first sensitization powder charge postcooling, the direct immersion when having avoided the latex cooling, or receive cooler stirring, scrape, thereby also avoided the damage in various degree that thus latex is produced.
Description of drawings
Accompanying drawing is in the embodiment of the invention emulsion [explosive pharmacy and powder charge continuous production technology that provide, the structural representation of device systems one preferred embodiment of being adopted.
Embodiment
Clearer for technical problem, technical scheme and beneficial effect that the present invention will be solved, below in conjunction with accompanying drawing and embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
Emulsion [explosive pharmacy and powder charge continuous production technology that the embodiment of the invention provides comprise the steps:
(1) prepares aqueous phase solution and oil-phase solution respectively;
(2) press processing compound, aqueous phase solution and oil-phase solution are conveyed into the mixing of colostrum device respectively, carry out colostrum, send into static mixer then and carry out the essence breast;
(3) the essence latex is sent into sensitization powder charge system and carry out sensitization processing back powder charge, after the cooling system cooling, deliver to packaging system again and pack.
In the embodiment of the invention, sensitization powder charge system is physical sensitization powder charge system, chemical sensitization powder charge system or physics, chemically composited sensitization powder charge system.Wherein physical sensitization powder charge system comprises perlite system or glass microballon system.Smart latex carries out sensitization through the physical sensitization powder charge system that comprises said glass microballon system and handles powder charge again, can directly deliver to packaging system and pack without said cooling system.In the embodiment of the invention, oil phase and aqueous phase solution processing compound are the 3-6% that oil-phase solution accounts for two total solution weight, and aqueous phase solution accounts for the 94-97% of gross weight.Aqueous phase solution is the ammonium nitrate solution of 87-92% concentration; Oil-phase solution is made up of MO and emulsifying agent, and MO and emulsifying agent are MO well known in the art and emulsifying agent, and for example emulsifying agent can be selected SPAM80 and/or soybean lecithin for use.Its mineral oil in fluid accounts for the 66.6%-91.6% of oil phase weight, and emulsifying agent accounts for the 8.4%-33.3% of oil phase weight.In this oil phase material, do not add the paraffin and the compound wax that are prone to solidify, pipeline and heat-insulation system are simplified, delivery safety property is better.
In the embodiment of the invention, colostrum adopts the matrix spiral pump to carry, and this matrix spiral pump is provided with cutout dry grinding, overtemperature, superpressure safeguard protection deadman control, and rotating speed is lower than 200 rev/mins.The rotor of spiral pump adopts stainless steel 90, and stator adopts the paracril manufacturing, and spiral pump increases work-ing life greatly under this technical recipe.About 8 kilotons are just changed stator one time, and are higher 8 times than the life-span that about 1 kiloton of the screw pump stator of present use is changed once.
In the embodiment of the invention, the colostrum device is a small volume, is no more than 120L colostrum device.This colostrum body is long-pending small and exquisite, rotating speed is low (300~600 rev/mins) and power little (3 kilowatts), has improved security.
In the embodiment of the invention, charge machine adopts the plastic film charge machine, preferred big production capacity plastic film charge machine.
In the embodiment of the invention, latex is carried under 88~92 ℃.Under this temperature, add sensitizing agent after because good fluidity is prone to carry and mix, difficult generation is solidified plugging, breakdown of emulsion and is produced highly compressed danger.
Embodiment
Adopt device systems shown in the drawings in the embodiment of the invention.According to technical process, this device systems order of connection is followed successively by oil phase, water preparation system, emulsifying system, sensitization powder charge system, cooling system and packaging system 19.
In oil phase, the water preparation system, the water preparation system comprises that crusher 1, worm conveyor 2, water dissolve jar 3, toothed gear pump 4, water basin 5 and water pump 6; The oil phase preparation system comprises that oil phase dissolves jar 33, toothed gear pump 32, oil phase storage tank 31 and oil phase pump 30.
Emulsifying system comprises colostrum device 7, matrix spiral pump 8 and static mixer 9.
Sensitization powder charge system comprises chemical sensitization powder charge system and physics, chemically composited sensitization powder charge system.Wherein, chemical sensitization powder charge system comprises latex pump 10, whipping agent transferpump 11, whipping agent jar 12, back acid jar 13, afterwards sour transferpump 14, mixing tank 15 and charge machine 16; Physics, chemically composited sensitization powder charge system comprise the sour transferpump of charge machine 20, dynamic mixer 21, back 22, back acid jars 23, whipping agent transferpump 24, whipping agent jar 25, latex pump 26, latex pump 27, kneader 28 and perlite or glass microballon system 29.
Cooling system comprises that powder stick cooling system 17 and powder stick dry up system 18.
The colostrum device is a small volume in the system, is no more than 120L colostrum device; Matrix spiral pump 8 is provided with cutout dry grinding, overtemperature, superpressure safeguard protection deadman control, and rotating speed is lower than 200 rev/mins.Charge machine is big production capacity plastic film charge machine in the sensitization powder charge system.
Emulsion [explosive pharmacy that present embodiment provides and powder charge serialization device systems, according to arts demand wherein sensitization powder charge system physics, chemically composited sensitization powder charge system or chemical sensitization powder charge system can only be set separately.In addition, sensitization powder charge system also can only be provided with the physical sensitization powder charge system that comprises latex pump 26 and latex pump 27, kneader 28, perlite or glass microballon system 29 and charge machine 20 separately.And when being the glass microballon system in this physical sensitization powder charge system, can need not complicated cooling system this moment.
Adopt above device systems, with reference to accompanying drawing, emulsion [explosive pharmacy and powder charge continuous production process that present embodiment provides are following:
1, preparation aqueous phase solution and oil-phase solution.
Steam air pressure adds the water entry and mixes jars 3, after should not surpass under the condition of 0.25Mpa, be heated to 95 ℃; Industrial ammonium nitrate through crusher 1 fragmentation, through spiral conveyer 2, is sent into water jar 3; When solution temperature is raised to 75 when spending, stir and continue to be heated to 88~90 ℃ of technological temperatures, being mixed with concentration is 87-92% supersaturation ammonium nitrate liquid; Flow into toothed gear pump 4 through pipeline, send into water basin 5, be incubated subsequent use;
Take by weighing oil phase material MO and emulsifying agent and add oil phase molten jar 33, be heated to 60~70 ℃ of technological temperatures, dissolve, be incubated subsequent use after toothed gear pump 32 pumps into oil phase storage tank 31.Its mineral oil in fluid accounts for the 66.6%-91.6% of oil phase weight, and emulsifying agent accounts for the 8.4%-33.3% of oil phase weight.
2, the gross weight with water, oil phase two solution is a benchmark; Get the aqueous phase solution that accounts for gross weight 94% and 6% oil-phase solution; Aqueous phase solution is through water pump 6, and oil-phase solution is sent into colostrum device 7 respectively through oil phase pump 30 and carried out colostrum, sends into static mixer then and carries out the essence breast; Colostrum is sent into static mixer 9 through matrix through spiral pump 8, forms smart latex.
3, select physical sensitization, chemical sensitization or physics, chemically composited sensitization as required, and the corresponding subsequent step of taking.
(1) preparation physics sensitizing explosive.
The latex that static mixer 9 comes out is sent in the perlite system 29; Mixing in kneader 28; Send into charge machine 20 by latex pump 26 and latex pump 27; After sending in the powder stick cooling system 17 cooling again, get into powder stick and dry up in the system 18 dryly, get at last in the automatic packaging system 19 and pack.As changing the perlite system into the glass microballon system, can directly deliver to automatic packaging system 19 and pack without cooling system.
(2) preparation chemical sensitization explosive.
During chemical sensitization, smart latex is sent into dynamic mixer 15 through latex pump 10, and chemical sensitizer is by whipping agent transferpump 11 simultaneously; Whipping agent in the whipping agent jar 12 is sent in the dynamic mixer 15; The sour transferpump in back 14 will back acid back acid in jars 13 also send into mix in the dynamic mixer 15 after, form spice, get into charge machine 16 simultaneously; Be packaged into required explosive cartridge; After sending in the powder stick cooling system 17 cooling again, get into powder stick and dry up in the system 18 dryly, get at last in the automatic packaging system 19 and pack.
(3) preparation composite sensitization explosive.
When carrying out physics, chemically composited sensitization, the latex that static mixer 9 comes out gets in the perlite system 29, sneaks into the physics sensitizing agent; Mixing in kneader 28 is sent in the dynamic mixer 21 by latex pump 26 and latex pump 27, and chemical sensitizer is by whipping agent transferpump 24 simultaneously; Whipping agent in the whipping agent jar 25 is sent in the dynamic mixer 21; The sour transferpump in back 22 will back acid back acid in jars 23 also send into mix in the dynamic mixer 21 after, be mixed into spice after, get into charge machine 20 again; Be packaged into explosive cartridge, after powder stick cooling system 17, powder stick dry up system 18, get into automatic packaging system 19 successively and pack.
The technical scheme that adopts the embodiment of the invention to provide owing to adopt static mixer, thereby has avoided that the latex temperature is higher than water after the emulsification, the oil phase temperature produces heat built-up and explosion caused danger.Owing to adopt emulsion [explosive pharmacy and the powder charge continuous process method of first sensitization powder charge postcooling, the direct immersion when having avoided the latex cooling, or receive cooler stirring, scrape, thereby also avoided thus damage in various degree to the latex generation.The colostrum device be advantages of small volume preparatory breast jar, rotating speed low (300~600 rev/mins), power little (3 kilowatts), make security better; Emulsoid is under higher temperature (88~92 degree), to carry, add sensitizing agent after because good fluidity is prone to carry and mix, difficult generation is solidified plugging, breakdown of emulsion and is produced highly compressed danger.Chemical sensitizer is to add before after pumping, getting into charge machine, has the emulsified detonator loading of sensitivity smooth and easy and security good than the thickness after the cooling sensitization.Select big production capacity plastic film charge machine in addition in the sensitization powder charge system, improved production efficiency.
The above is merely preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. emulsion [explosive pharmacy and powder charge continuous production technology comprise the steps:
(1) prepares aqueous phase solution and oil-phase solution respectively;
(2) press processing compound, aqueous phase solution and oil-phase solution are conveyed into the mixing of colostrum device respectively, carry out colostrum, send into static mixer then and carry out the essence breast;
(3) be to send into sensitization powder charge system under the 88-92 ℃ of condition to carry out sensitization processing back powder charge with the essence latex in temperature; After the cooling system cooling, deliver to packaging system again and pack, said essence latex is directly sent into sensitization powder charge system without cooling and is carried out sensitization processing back powder charge.
2. continuous production technology according to claim 1 is characterized in that, said sensitization powder charge system is physical sensitization powder charge system, chemical sensitization powder charge system or physics, chemically composited sensitization powder charge system.
3. emulsion [explosive pharmacy as claimed in claim 2 and powder charge continuous production technology is characterized in that, said physical sensitization powder charge system comprises perlite system or glass microballon system.
4. like the said continuous production technology of claim 3, it is characterized in that smart latex carries out sensitization through the physical sensitization powder charge system that comprises said glass microballon system and handles powder charge again, without said cooling system, directly delivers to packaging system and packs.
5. continuous production technology according to claim 1; It is characterized in that said aqueous phase solution is the ammonium nitrate solution of 87-92% concentration, said oil phase is made up of MO and emulsifying agent; Its mineral oil in fluid accounts for the 66.6%-91.6% of oil phase weight, and emulsifying agent accounts for the 8.4%-33.3% of oil phase weight.
6. like the said continuous production technology of claim 5, it is characterized in that processing compound is the 3-6% that oil-phase solution accounts for water, oil phase mixing solutions weight in the said step (2), aqueous phase solution accounts for the 94-97% of its weight.
7. continuous production technology according to claim 1 is characterized in that, said colostrum adopts the matrix spiral pump to carry, and said matrix spiral pump is provided with cutout dry grinding, overtemperature, superpressure safeguard protection deadman control, and rotating speed is lower than 200 rev/mins.
8. continuous production technology according to claim 1 is characterized in that the colostrum device is a small volume described in the said step (2), is no more than 120L colostrum device.
9. continuous production technology according to claim 1 is characterized in that, said charge machine adopts the plastic film charge machine.
10. like each said continuous production technology of claim 1-9, it is characterized in that latex is carried in the said step (3) under 88~92 ℃.
CN2007100753913A 2007-08-01 2007-08-01 Continuous technique for preparing emulsifying explosive and charging Active CN101357873B (en)

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Families Citing this family (9)

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CN102603437A (en) * 2012-02-28 2012-07-25 薛世忠 Method for manufacturing emulsion explosive with swill-cooked dirty oil
CN103664424B (en) * 2013-09-26 2017-09-15 石家庄成功机电有限公司 The emulsification method and equipment of a kind of emulsion
CN104058904B (en) * 2014-07-07 2016-06-08 山东天宝化工股份有限公司 A kind of emulsion pilot production line and production technology thereof
CN104502561B (en) * 2014-11-24 2016-06-08 葛洲坝易普力股份有限公司 A kind of mixed explosive scientific research and testing platform
CN105272783A (en) * 2015-11-10 2016-01-27 天津宏泰华凯科技有限公司 Emulsification explosive-making system of emulsion explosive
CN105837387B (en) * 2016-04-29 2018-05-25 安徽江南化工股份有限公司 A kind of anti-desensitization type emulsion and preparation method thereof
CN106081630B (en) * 2016-08-11 2018-09-21 中国葛洲坝集团易普力股份有限公司 Glass microsphere transport system
CN110436205B (en) * 2019-06-26 2020-11-27 新疆天河化工有限公司 Large-diameter emulsion explosive conveying device and preparation method thereof
CN114591121B (en) * 2022-03-15 2022-11-15 广东华威化工股份有限公司 Emulsion explosive preparation method and system based on near infrared spectrum

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