CN101346122A - Image controller - Google Patents
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- CN101346122A CN101346122A CNA2006800492692A CN200680049269A CN101346122A CN 101346122 A CN101346122 A CN 101346122A CN A2006800492692 A CNA2006800492692 A CN A2006800492692A CN 200680049269 A CN200680049269 A CN 200680049269A CN 101346122 A CN101346122 A CN 101346122A
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Abstract
It is intended to provide a skin image controller by which the skin image can be designed in various ways. A skin image controller wherein the relationship between chromaticnesses C<*>ab(0) and C<*>ab(45), which are measured by the measurement method 1 with an incident light angle 45 DEG respectively at light receiving angles 0 DEG and 45 DEG , satisfies C<*>ab(45)-C<*>ab(0)>0; and the lightness L<*> is 30 or above, the hue angle h is from 0 DEG to 90 DEG , and the chromaticness C<*>ab is 5 or above, each measured by the measurement method 2. (Measurement method 1) The above-described composition is evenly applied to a black artificial leather at a ratio of 8 mg/100 cm<2> and a chromaticness specified by the CIE 1976 L<*>a<*>b<*> color system is measured by using a multiangle colorimeter. (Measurement method 2) The above-described composition is put into a cell and a chromaticness of the cell surface specified by the CIE 1976 L<*>a<*>b<*> color system is measured by using a colorimeter.
Description
Technical field
The present invention relates to show the image controller of various skin images.
Background technology
As at the whole cosmetics of coating on the face, avoid from injury such as ultraviolet or hide resulting from skin is concavo-convex and irregular colour is even skin shortcoming etc. in order to protect skin, and use sun screen (makeup base), foundation cream etc.On the other hand, the cosmetics as the image that changes face have the cosmetics that eye shadow, rouge etc. are coated with on a part of skin.In order to put skin appearance in order, and further realize the target image, in present cosmetic, the former and the latter use in a series of cosmetics continuously.
In addition, a kind of cosmetics are proposed in patent documentation 1, its combination contains first cosmetics of particular shade of color and chroma and objective gloss degree and the powder body composition of the ratio of scattered reflection light intensity and contains second cosmetics of the tone different with the 1st cosmetics, chroma and objective gloss degree and the powder body composition of the ratio of scattered reflection light intensity, and is used to repeat to be coated with first cosmetics and second cosmetics.
But, also unknown by being coated with a kind of preparation on the face and can showing the cosmetics of various skin images whole.
On the other hand, foundation cream is mainly used in concavo-convex such skin shortcomings such as the even acne trace of irregular colour, pore such as hidden mottle freckle.In recent years, as the needs of consumer, wish to have the foundation cream that not only can put skin color in order but also can show more beautiful skin.
In foundation cream, as coloring agent, use inorganic pigments such as titanium oxide, ferrum oxide, Prussian blue, ultramarine, chromium oxide, organic pigment such as No. 201 red, No. 401 Huangs, No. 1 indigo plant, No. 3 are green etc.Use these coloring pigments, particularly on the colour of skin when painted,,, just become dark modification or the dull and stereotyped and such modification of expressionless idol sometimes then because the light absorption of coloring pigment if cooperate the coloring pigment of amount with abundant colorability.
Therefore, in order to realize becoming clear, have the retouching of transparent feel and seeing relief retouching, propose to use with the method (patent documentation 2, patent documentation 3, patent documentation 4) of mica titanium as the pearlescent pigment of representative.But, use pearlescent pigment only merely, though can obtain having transparent feel and relief retouching, the ornamenting skin color inhomogeneous and concavo-convex show simultaneously aspect the various skin images also insufficient.
Patent documentation 1: TOHKEMY 2005-187417 communique
Patent documentation 2: Japanese kokai publication hei 9-95431 communique
Patent documentation 3: TOHKEMY 2002-265332 communique
Patent documentation 4: TOHKEMY 2005-97218 communique
Summary of the invention
The invention provides a kind of image controller of skin, wherein by assay method 1 as 45 ° of incident angle of light, 0 ° and 45 ° each chroma C that measures of light angle
*Ab (0) and C
*The relation of ab (45) is C
*Ab (45)-C
*Ab (0)＞0, and the lightness L that measures by assay method 2
*Be more than 30, hue angle h is 0 °～90 °, chroma C
*Ab is more than 5.
(assay method 1) is uniformly coated into said composition and is 8mg/100cm on the black dermatine
2, use the angle colour meter to measure with CIE1976L
*a
*b
*The color-values of color specification system (colorsystem) regulation.
(assay method 2) adds said composition in testing cassete, use colour meter measure its surface with CIE1976L
*a
*b
*The color-values of color specification system regulation.
The specific embodiment
The present invention relates to can be by being coated with the skin image controlling agent that a kind of preparation just shows various skin images whole on the face.
Discoveries such as the inventor have certain optical properties and appearance color when being the compositions of skin color in whole coating on the face, can show various skin images.
Image controller of the present invention is by being coated with it on the face and can showing various skin images whole, and can access the bright retouching with transparent feel.
In addition, under situation about using as foundation cream, in coating at that time, the irregular colour of skin is even concavo-convex not obvious, is the bright retouching with transparent feel, and can shows various skin images.
Image controller of the present invention is at first according to each chroma Cs of said determination method 1 in 45 ° of incident angle of light, 0 ° and 45 ° following mensuration of light angle
*Ab (0) and C
*The relation of ab (45) is C
*Ab (45)-C
*Ab (0)＞0, preferred C
*Ab (45)-C
*Ab (0)＞1.5.
This C
*Ab (45)-C
*Ab (0)＞0 means that the surface reflectance light color is denseer than scattered reflection light, but it can not change skin image 0 when following.
Here, in assay method 1, at first on the black dermatine, get compositions and make it become 8mg/100cm
2Thereby, use sponge on dermatine, to wipe evenly coating lightly.It is used the angle colour meter, and (color institute system in the village GCMS-4), is measured for 0 ° and 45 ° with 45 ° of incident angle of light, light angle for example to use angle spectral photometry system.With 2 reflected light of this moment, with CIE1976L
*a
*b
*Color specification system stipulates, is C with the chroma of 0 ° of light angle
*Ab (0) is C with the chroma of 45 ° of light angles
*Ab (45) obtains C
*Ab (45)-C
*Ab (0).
In addition, image controller of the present invention is the lightness L that measures according to said determination method 2
*Be more than 30, hue angle h is 0 °～90 °, chroma C
*Ab is the image controller more than 5.
In assay method 2, at first in testing cassete, add compositions, to its surface (appearance color of compositions), use colour meter to obtain with CIE1976L
*a
*b
*The color-values of color specification system regulation is promptly obtained lightness L
*, hue angle h, chroma C
*Ab.As determinator,, for example, can use the beam splitting type colour difference meter SE2000 of the industrial society of Japanese electric color system etc. if in testing cassete, add object and can measure the device of its appearance color just passable.
In addition, with above-mentioned same, image controller of the present invention according to assay method 1 when the hue angle h (0) of 45 ° of incident angle of light, 0 ° of mensuration of light angle is 40 °＜h (0)＜100 °, promptly when only skin color and surface reflection also are skin color, can show magnificent image or sexy image in scattered reflection.
On the other hand, the chroma (a that when 45 ° of incident angle of light, light angle are-60 °, 0 ° and 45 °, measures respectively according to assay method 1
*, b
*) in, be accompanied by light angle from-60 ° of a to 0 ° angle variation
*b
*The direction that colourity in the space changes be accompanied by light angle from-60 ° of a that change to 45 ° angle
*b
*When the direction that colourity in the space changes has poor more than 10 °, when promptly changing tone by viewing angle, for example, in scattered reflection when only skin color and surface reflectance are only red, can show lovely image, women's image more, in scattered reflection when only skin color and surface reflectance are only green, can show experienced image, illusory image, when only skin color and surface reflectance are only blue, can show calm image, urban image in scattered reflection.
Above-mentioned each the vivid vocabulary of performance of lifting, be the face after making up to be observed and the image experienced serves as that tendency is held the vocabulary that obtains with expert group, the face after the above-mentioned cosmetic is that the compositions that will consider scattered reflection light and surface reflection to make it become the optical characteristics of various images and design is coated on that the model is whole to be obtained after on the face.
More specifically, by the chroma (a that measures respectively when 45 ° of incident angle of light, light angle-60 °, 0 ° and 45 ° according to assay method 1
*(60), b
*(60)), (a
*(0), b
*And (a (0))
*(45), b
*(45)) h ' (45) that obtains according to formula 1 and formula 2 and the relation of h ' (0) | h ' (45)-h ' (0) |＞10 o'clock, the various images that can show.
(formula 1) h ' (0)=tan
-1((b
*(0)-b
*(60))/(a
*(0)-a
*(60))
(formula 2) h ' (45)=tan
-1((b
*(45)-b
*(60))/(a
*(45)-a
*(60))
Like this, image controller of the present invention, coating color (scattered reflection composition) is skin color and the bright retouching that obtains transparent feel, simultaneously, can show the distinctive image of this color by changing the surface reflectance light color.
Image controller of the present invention, for example can pass through to use following composition (A), (B) and (C) manufacturing:
(A): the pearlescent pigment of the capping oxidation iron oxide yellow of mean diameter 5～15 μ m,
(B): the pearlescent pigment of the capping oxidation iron oxide red of mean diameter 5～15 μ m,
(C): the pearlescent pigment of mean diameter 20～50 μ m.
In the present invention, mean diameter is measured with laser scattering type particle size distribution device (for example the hole field boundary is made society of institute system, LA-700 type).
The composition (A) of relative small particle diameter and the pearlescent pigment of composition (B), the directivity of colour developing is low, is low colour developing.Pearlescent pigment with the iron oxide covering of composition (A) and composition (B) is made skin color.
On the other hand, the colour developing directivity height by the pearlescent pigment of the composition (C) of big relatively particle diameter causes can access high colour developing.The light that the pearlescent pigment manufacturing of the composition of this big relatively particle diameter (C) changes the image.Like this, the pearlescent pigment of the pearlescent pigment by the so relative small particle diameter of using ingredient (A) and (B) and the composition (C) of relative big particle diameter, can derive above-mentioned h, the relation of (45) and h ' (0) | h ' (45)-h ' (0) |＞10, can show various images.
Composition (A) is the composition that covers the pearlescent pigment surface with iron oxide yellow, and mean diameter is 5～15 μ m, 6～13 μ m preferably.The pearlescent pigment of Shi Yonging here, the preferably golden class interference colours of its interference colours.
Method at pearlescent pigment surface coverage iron oxide yellow can be used usual method.For example, can be inorganic at ferrous chloride, iron chloride, ferrous sulfate, iron sulfate, ferrous nitrate, ferric nitrate, Ferrox., iron ammonium oxalate, ammonium ferric sulfate, iron phosphate, ferric citrate, ferrous lactate, ferrous fumarate etc., in the organoiron compound aqueous solution, after adding pearlescent pigment, be warmed up to 50～100 ℃, preferably be warmed up to 80～100 ℃, made it ripening 1～10 hour, make the iron compound hydrolysis thus and separate out iron oxide yellow on the pearlescent pigment surface, after washing, the filtration, be dried below 150 ℃, and making.
Composition (B) is the composition that covers the pearlescent pigment surface with iron oxide red, and mean diameter is 5～15 μ m, 6～13 μ m preferably.The pearlescent pigment of Shi Yonging here, its interference colours are the interference colours of pink group, purple class preferably.
Method in pearlescent pigment surface coverage iron oxide red can be used usual method.For example, can be till the iron oxide yellow that covers composition (A), being identical method, thereby after this with more than 150 ℃, preferably to carry out sintering capping oxidation iron oxide red more than 400 ℃.
As the pearlescent pigment that raw material uses, composition (A) and (B) are the nacreous pigment that has that above-mentioned particle diameter is arranged and covered the different optical transmission material of refractive index on laminar base material.As laminar base material, can enumerate Muscovitum, synthetic mica, titanium dioxide silicon chip, aluminium flake, alumina wafer, oxidation iron plate, sheet glass etc., from transparent height, preferred Muscovitum, synthetic mica, sheet glass.Optical transmission material as cover sheet shape base material, can enumerate titanium oxide, zirconium oxide, zinc oxide, stannum oxide, ferrum oxide, chromium oxide, silicon dioxide, silicon dioxide, chromium, titanium nitride, titanium, Afluon (Asta) aluminium oxide, boehmite, boron oxide, their mixture etc., from the colour developing aspect, preferred titanium oxide, stannum oxide, ferrum oxide, their mixture.More specifically, preferably the mixture with titanium oxide or titanium oxide and ferrum oxide or stannum oxide covers mica surface, for example, can compatibly use the Flamenco Satin series of ENGELHARD corporate system and the Prestige Silk series of ECKART corporate system.
In addition, at composition (A) with the ferrum oxide coverage rate (B), with respect to pearlescent pigment preferably 1～15 quality %, 2～10 quality % especially preferably.If the coverage rate of this scope, then do not weaken interference colours and the even effect of hidden irregular colour becomes best, thereby preferred.
Composition (A) and (B) all can not obtain sufficient color developing effect in mean diameter during less than 5 μ m, if just can not show the natural skin color greater than 15 μ m, generation is glittered, thereby not preferred.
Composition (A) and content (B), its total amount is 2～15 quality %, particularly 3～10 quality % in all forming, because can obtain the even effect of hidden irregular colour fully, retouching is nature also, thereby preferred.
In addition, are preferred component (A) and containing (B) proportional (mass ratio) (A): (B)=2: 1～25: 1, be preferably 3: 1～23: 1 especially because this moment foundation cream outward appearance and retouching nature.
Composition (C) is mean diameter 20～50 μ m, the pearlescent pigment of 22～45 μ m preferably.Mean diameter can not fully obtain showing the effect of beautiful skin during less than 20 μ m, if greater than 50 μ m, and then because glitter and become big and become factitious retouching, thereby not preferred.Pearlescent pigment is the nacreous pigment that has that has covered the different optical transmission material of refractive index on laminar base material.As laminar base material, can enumerate Muscovitum, synthetic mica, titanium dioxide silicon chip, aluminium flake, alumina wafer, oxidation iron plate, sheet glass etc., from the high aspect of the transparency, preferred Muscovitum, synthetic mica, sheet glass.Optical transmission material as cover sheet shape base material, can enumerate titanium oxide, zirconium oxide, zinc oxide, stannum oxide, ferrum oxide, chromium oxide, silicon dioxide, chromium, titanium nitride, titanium, Afluon (Asta) aluminium oxide, boehmite, boron oxide, their mixture etc., from the colour developing aspect, preferred titanium oxide, stannum oxide, ferrum oxide, their mixture.More specifically, preferably cover mica surface with the mixture of titanium oxide or titanium oxide and ferrum oxide or stannum oxide.
As mean diameter is the mica titanium of 20～50 μ m, for example, can use Flamenco series, Flamenco Summit series, the TIMIRON SUPER series of メ Le Network society system and Prestige series, the Prestige Bright series of ECKART corporate system of ENGELHARD corporate system.
Preferably in all forming, contain 1～15 quality %, particularly contain the composition (C) of 2～10 quality %,, simultaneously, do not glitter and be the retouching of nature because can fully obtain showing the effect of various skin images.
In the present invention, preferred component (A), (B) and (C) contain proportional (mass ratio) they are (A)+(B): (C)=1: 3～5: 1, especially preferably 1: 2～4: 1, keep nature and cover even effect of irregular colour and the effect that shows various skin images because can fully take into account.
Image controller of the present invention can also contain the spherical powder body of (D) mean diameter 1～20 μ m, preferred 3～15 μ m.Here, so-called spherical powder body is to have a powder body that suppresses normal reflection and/or diffuse reflective nature, and its shape comprises positive sphere, spherical, ellipsoid of revolution roughly, also is included in the irregular spherical powder body in surface.
Mean diameter is if 1～20 μ m, just do not bury in the cosmetic film, and, evenly be attached to jog easily, make " desalination " effect of its effect that is difficult to find out so can fully show the rabbet boundary line of desalination pore, rugula stricture of vagina etc., the concavo-convex of pore, rugula stricture of vagina etc. is not easy obviously.The mean diameter that particularly makes spherical powder body is more than the 1 μ m, and spherical powder body is not buried in the cosmetic film, and it is smooth and good that usability becomes.
As the object lesson of so spherical powder body, can enumerate globular SiO
2, Al
2O
3Deng macromolecular compounds such as inorganic compound such as metal-oxide, barium sulfate, calcium carbonate, polyethylene, polymethyl methacrylate, polystyrene, nylon, cellulose, silicones, polyurethane.The mixture that spherical powder body can be used as more than a kind or 2 kinds uses.
Preferably contain 0.1～30 quality % in all forming, particularly contain the composition (D) of 1～20 quality %, because make excellence aspect the concavo-convex inapparent effect, simultaneously, usability is also good.
In the present invention, preferred component (A), (B), (C) and (D) contain proportional (mass ratio) they are (A)+(B)+(C): (D)=1: 4～15: 1, particularly 1: 3～10: 1, spare because can eliminate glitters and cover irregular colour glossily, and can show various skin images.
Composition (A), (B), (C) and powder body (D) can be handled its back, surface use by hydrophobization.As process for hydrophobicizing, for example, can enumerate making the powder surface absorb oil or utilize functional groups such as hydroxyl and make it to cause esterification or etherificate and make pigment become lipophilic oils and fats facture; Use the metallic soap facture of fatty acid zinc salt or magnesium salt; Use the silicone-treated method of dimethyl polysiloxane or methylhydrogenpolysi,oxane; Method of handling with fluorine compounds etc. with perfluoroalkyl.
Preferred image controller of the present invention composition (A), (B) and (C) content of contained in addition coloring agent be below the 3 quality %, particularly below the 0.5 quality %, because transparent feel is high and show the effect excellence of various skin images.More preferably do not contain composition (A), (B) and (C) in addition coloring agent in fact.Here, so-called coloring agent is inorganic Chinese white, coloring pigments such as titanium oxide, ferrum oxide, Prussian blue, ultramarine, chromium oxide; Organic pigment etc. such as No. 201 red, No. 401 Huangs, No. 1 indigo plant, No. 3 are green.
Colorant content is if below the 3 quality %, and then the transparent feel height shows various skin images easily, thereby preferred.
Image controller of the present invention except mentioned component, according to application target etc., can contain the composition that uses in cosmetics usually.For example, can contain surfactant, macromolecular compound, oil content, extender pigment, wetting agent, antiseptic, medicament, UV absorbent, antioxidant, inorganic acid salt or acylate, spice, chelating agen, pH regulator agent, water etc.
Can use mentioned component to make image controller of the present invention, can make dosage form arbitrarily such as powder solid type, high oil-containing powder solid type, oily decentralized, water-dispersion type, water-in-oil emulsion, oil-in-water emulsion according to usual method.Be particularly suitable as foundation cream.
In addition, when making the foundation cream that contains composition (A)～(D), can be used as the foundation cream that to control image and use.
[embodiment]
In an embodiment, assay method 1 and assay method 2 carry out in accordance with the following methods.
(assay method 1)
Use commercially available used for cosmetic sponge (foundation cream with), each compositions is uniformly coated on the black dermatine (the new and society's system of ォ カ モ ト, セ ラ ヌ バ ッ Network #010) is 8mg/100cm
2It is used angle colour meter (angle spectral photometry system (color institute system, GCMS-4 in the village)), measure with CIE1976L
*a
*b
*The color-values of color specification system regulation.
(assay method 2)
(reflection measurement is used, the industrial society of Japanese electric color system at circular testing cassete; Diameter 35 φ * high 15mmH quartz) fill each compositions in, use beam split colour difference meter SE2000 (the industrial society of Japanese electric color system), measure with CIE1976L
*a
*b
*The color-values of color specification system regulation.
Production Example 1
In 2000 mass parts ion exchange waters, make the dissolving of 60 mass parts iron sulfate n hydrates, it is adjusted into pH2.8 with the 0.1mol/L sodium hydrate aqueous solution, the mica titanium (Flamenco SatinGold) that in the aqueous solution that obtains thus, adds 100 mass parts ENGELHARD corporate systems, fully stir, make it homodisperse.Then, this mica titanium dispersion liquid limit heating is stirred on the limit, makes it to seethe with excitement 6 hours.Put cold after, filter, washing obtains the mica titanium that 103 mass parts cover with iron oxide yellow.
The mean diameter of the mica titanium that the iron oxide yellow that obtains covers is 7.0 μ m, and the iron oxide yellow coverage rate is 7 quality % with respect to integral body.
Production Example 2
In 2000 mass parts ion exchange waters, make the dissolving of 60 mass parts iron sulfate n hydrates, it is adjusted to pH2.8 with the 0.1mol/L sodium hydrate aqueous solution, the mica titanium (Flamenco SatinRed) that in the aqueous solution that obtains thus, adds 100 mass parts ENGELHARD corporate systems, fully stir, make it homodisperse.Then, this mica titanium dispersion liquid limit heating is stirred on the limit, makes it to seethe with excitement 6 hours.Put cold after, filter, washing with 800 ℃ of sintering 2 hours, obtains the mica titanium that covers with iron oxide red of 102 mass parts.
The mean diameter of the mica titanium that the iron oxide red that obtains covers is 7.2 μ m, and the coverage rate of iron oxide red is 7 quality % with respect to integral body.
Production Example 3
Except in Production Example 1, using the Prestige Silk Gold (ECKART corporate system) and Production Example 1 operate equally, obtain the mica titanium of iron oxide yellow covering as mica titanium.
The mean diameter of the mica titanium that the iron oxide yellow that obtains covers is 12.0 μ m, and the coverage rate of iron oxide yellow is 7 quality % with respect to mica titanium.
Production Example 4
Except in Production Example 2, using the Prestige Silk Violet (ECKART corporate system) and Production Example 2 operate equally, obtain the mica titanium of iron oxide red covering as mica titanium.
The mean diameter of the mica titanium that the iron oxide red that obtains covers is 12.0 μ m, and the coverage rate of iron oxide red is 7 quality % with respect to mica titanium.
Embodiment 1～4, comparative example 1～3
Be manufactured on the image controller of the composition shown in the table 1, for the image of sexuality, experienced image, urban image, lovely image, beautiful such sensation of making up, the retouching of transparent feel, bright retouching are arranged, estimate.Ecbatic in table 2.
(method for making)
Be heated with stirring to 70 ℃ oil-phase component ((1)～(3)) and powder body composition ((4)～(15)) with dispersion machine (2000rpm, 15 minutes), make it even.Then, be added on the water-phase component ((16)～(18)) of 70 ℃ of uniform dissolution, make it emulsifying, after this, cool to room temperature while stirring stirs with homogenizer (5000rpm, 10 minutes) at last, obtains liquid image controller.
(evaluation methodology)
By 14 special participants, all " think " 5 minutes, " thinking a little like that " 4 minutes, " which limit also be cannot say for sure " 3 minutes, " not thinking like that a little " 2 minutes, " not thinking like that " 1 minute like that with projects, estimate in whole " sexy image ", " experienced image ", " urban image ", " lovely image ", " beautiful such sensation of making up ", " retouching of transparent feel is arranged ", " bright retouching " when being coated with each image controller on the face, represent with its meansigma methods.
[table 1]
[table 2]
Embodiment 5～7, comparative example 4～6
Be manufactured on the liquid foundation cream of the composition of expression in the table 3, about the even covering power of retouching that transparent feel is arranged, bright retouching, irregular colour, concavo-convex not obvious, do not have glistening retouching, show effect (tone that color of filming from cosmetic and pearlescent pigment are observed), the usability (not rough smooth) of various skin images, estimate.Ecbatic in table 4.
(method for making)
Be heated with stirring to 70 ℃ oil-phase component ((1)～(3)) and powder body composition ((4)～(15)) with dispersion machine (2000rpm, 15 minutes), make it even.Then, be added on the water-phase component ((16)～(18)) of 70 ℃ of uniform dissolution, make it emulsifying, after this, cool to room temperature while stirring stirs with homogenizer (5000rpm, 10 minutes) at last, obtains liquid foundation cream.
(evaluation methodology)
By 14 special participants, with projects all is " well " 5 minutes, " good a little " 4 minutes, " common " 3 minutes, " poor slightly " 2 minutes, " poor " 1 minute, " retouching of transparent feel is arranged ", " bright retouching ", " covering power that irregular colour is even ", " concavo-convex not obvious ", " not having glistening retouching ", " showing the effect of skin image ", " usability (not rough smooth) " when estimating on skin the liquid foundation cream of coating are represented with its meansigma methods.
[table 3]
[table 4]
The foundation cream of embodiment 5～7 all shows good result in each assessment item.In addition, the observer during from each foundation cream of separate application on skin, embodiment 5,7 can give the image of the elegance of the rational faculty and beauty, and embodiment 6 can give sexuality and healthy image.
Embodiment 8 (paste foundation cream)
According to the composition of expression in table 5, be heated with stirring to 70 ℃ oil-phase component ((1)～(6)) and powder body composition ((11)～(15)) with dispersion machine (2000rpm, 15 minutes), make it even.Then, be added on the water-phase component ((7)～(10)) of 70 ℃ of uniform dissolution, make it emulsifying, after this, cool to room temperature while stirring stirs with homogenizer (5000rpm, 10 minutes) at last, obtains the paste foundation cream.
If the foundation cream of coating embodiment 8 just can provide great-hearted lovely image on skin.
[table 5]
| (composition) | (quality %) |
| (1) stearic acid | 5.5 |
| (2) lipophile glyceryl monostearate | 2.5 |
| (3) hexadecanol octadecanol | 1 |
| (4) single lauryl propylene glycol | 3 |
| (5) squalane | 7 |
| (6) olive oil | 8 |
| (7) Purified Water | Surplus |
| (8) p-Hydroxybenzoate | 0.1 |
| (9) triethanolamine | 1.2 |
| (10) Sorbitol | 3 |
| (11) mica titanium of the capping oxidation iron oxide yellow of Production Example 1 record has been carried out the composition that fluorine compounds are handled *10 | 4.8 |
| (12) mica titanium of the capping oxidation iron oxide red of Production Example 2 record has been carried out the composition that fluorine compounds are handled | 1.2 |
| (13) mica titanium (25 μ m) of fluorine compounds processing *11 | 3 |
| (14) mica titanium (35 μ m) of fluorine compounds processing *12 | 1 |
| (15) methylsiloxane network polymers (4.5 μ m) *13 | 5 |
*10: the perfluor alkyl ethide p diethylaminobenzoic acid hydramine (AG530, Asahi Glass society system) with 5 quality % is handled
*11:Flamenco Summit Red (ENGELHARD corporate system)
*12:Prestige Bright Red (ECKART corporate system)
*13:TOSPEARL 145A (the シ リ コ of GE Toshiba-Application society system): spherical powder body
Embodiment 9 (solid, powdery foundation cream)
Composition according to expression in table 6 after mixing composition (1)～(7), adds pre-heated composition (8) and (9), mixes and disperses, and pulverizes with pulverizer, and molding in the medium size vessel obtains the solid, powdery foundation cream.
If the foundation cream of coating embodiment 9 on skin just can give the rational faculty and beautiful graceful image.
[table 6]
| (composition) | (quality %) |
| (1) Muscovitum | Surplus |
| (2) sericite | 30 |
| (3) mica titanium that the iron oxide yellow of record covers in Production Example 3 | 8 |
| (4) mica titanium that the iron oxide red of record covers in Production Example 4 | 1.9 |
| (5) mica titanium (25 μ m) *14 | 10 |
| (6) spherical nylon (5 μ m) *15 | 18 |
| (7) p-Hydroxybenzoate | 0.2 |
| (8) methyl polysiloxane (6cSt) | 5 |
| (9) Liquid Paraffin | 5 |
*14:Flamenco Summit Blue (ENGELHARD corporate system)
*15:SP-500 (East レ society system)
Embodiment 10 (solid, powdery foundation cream)
According to the composition of expression in table 7, mix composition (1)～(8) after, add pre-heated composition (9), mix to disperse, after pulverizing with pulverizer,, obtain the loose shape foundation cream of powder by sieve.
If the foundation cream of coating embodiment 10 on skin just can give elegance and graceful image.
[table 7]
| (composition) | (quality %) |
| (1) Muscovitum | Surplus |
| (2) Pulvis Talci | 20 |
| (3) mica titanium that the iron oxide yellow of record covers in Production Example 1 | 7 |
| (4) mica titanium that the iron oxide red of record covers in Production Example 2 | 1.5 |
| (5) mica titanium (25 μ m) *5 | 5 |
| (6) mica titanium (35 μ m) *12 | 4 |
| (7) spherical polyurethane (6 μ m) *9 | 20 |
| (8) p-Hydroxybenzoate | 0.1 |
| (9) methyl polysiloxane (6cSt) | 5 |
Claims (7)
1. a skin image controlling agent is characterized in that,
According to each chroma C of assay method 1 in 45 ° of incident angle of light, 0 ° and 45 ° mensuration of light angle
*Ab (0) and C
*The relation of ab (45) is C
*Ab (45)-C
*Ab (0)＞0, and the lightness L that measures according to assay method 2
*Be more than 30, hue angle h is 0 °～90 °, chroma C
*Ab is more than 5,
Assay method 1: on the black dermatine, said composition is uniformly coated into 8mg/100cm
2, use the angle colour meter to measure with CIE1976L
*a
*b
*The color-values of color specification system regulation,
Assay method 2: in testing cassete, add said composition, use colour meter measure its surface with CIE1976L
*a
*b
*The color-values of color specification system regulation.
2. skin image controlling agent as claimed in claim 1 is characterized in that,
Is 40 °＜h (0)＜100 ° according to assay method 1 at the hue angle h (0) of 45 ° of incident angle of light, 0 ° of mensuration of light angle.
3. skin image controlling agent as claimed in claim 1 is characterized in that,
According to each colourity (a of assay method 1 in 45 ° of incident angle of light, light angle-60 °, 0 ° and 45 ° mensuration
*, b
*) in, follow light angle from-60 ° of a to 0 ° angle variation
*b
*The direction that colourity in the space changes and follows light angle from-60 ° of a that change to 45 ° angle
*b
*Between the direction that colourity in the space changes, have poor more than 10 °.
4. an image controller is characterized in that,
Contain following compositions (A), (B) and (C):
(A): the pearlescent pigment of the capping oxidation iron oxide yellow of mean diameter 5～15 μ m,
(B): the pearlescent pigment of the capping oxidation iron oxide red of mean diameter 5～15 μ m,
(C): the pearlescent pigment of mean diameter 20～50 μ m.
5. image controller as claimed in claim 4 is characterized in that,
The spherical powder body that also contains (D) mean diameter 1～20 μ m.
6. as claim 4 or 5 described image controllers, it is characterized in that,
Contained colorant content is below the 3 quality % except that composition (A), (B) and (C).
7. as any 1 the described image controller in the claim 4～6, it is characterized in that,
Described image controller is a foundation cream.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP379145/2005 | 2005-12-28 | ||
| JP2005379144A JP4709643B2 (en) | 2005-12-28 | 2005-12-28 | Skin impression production method |
| JP379144/2005 | 2005-12-28 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102800892A Division CN102813608A (en) | 2005-12-28 | 2006-12-27 | Image controller |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101346122A true CN101346122A (en) | 2009-01-14 |
Family
ID=38302396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006800492692A Pending CN101346122A (en) | 2005-12-28 | 2006-12-27 | Image controller |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4709643B2 (en) |
| CN (1) | CN101346122A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104661665A (en) * | 2012-03-19 | 2015-05-27 | 巴斯夫公司 | Treated platy substrates |
| CN106659286A (en) * | 2014-07-23 | 2017-05-10 | 博姿有限公司 | Method of selecting the colour of cosmetic products |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6178089B2 (en) * | 2013-03-27 | 2017-08-09 | ポーラ化成工業株式会社 | Dullness improvement cosmetic |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003012459A (en) * | 2001-06-25 | 2003-01-15 | Kao Corp | Cosmetic |
| JP3798266B2 (en) * | 2001-06-25 | 2006-07-19 | 花王株式会社 | Colored mica titanium |
| JP3892775B2 (en) * | 2002-08-22 | 2007-03-14 | 花王株式会社 | Cosmetics |
| JP4627960B2 (en) * | 2002-08-22 | 2011-02-09 | 花王株式会社 | Cosmetics |
-
2005
- 2005-12-28 JP JP2005379144A patent/JP4709643B2/en active Active
-
2006
- 2006-12-27 CN CNA2006800492692A patent/CN101346122A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104661665A (en) * | 2012-03-19 | 2015-05-27 | 巴斯夫公司 | Treated platy substrates |
| CN106659286A (en) * | 2014-07-23 | 2017-05-10 | 博姿有限公司 | Method of selecting the colour of cosmetic products |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007176874A (en) | 2007-07-12 |
| JP4709643B2 (en) | 2011-06-22 |
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Application publication date: 20090114 |