CN101325096A - Wire insulation material and manufacturing method thereof - Google Patents

Wire insulation material and manufacturing method thereof Download PDF

Info

Publication number
CN101325096A
CN101325096A CNA200810029746XA CN200810029746A CN101325096A CN 101325096 A CN101325096 A CN 101325096A CN A200810029746X A CNA200810029746X A CN A200810029746XA CN 200810029746 A CN200810029746 A CN 200810029746A CN 101325096 A CN101325096 A CN 101325096A
Authority
CN
China
Prior art keywords
insulating compound
wire
parts
electric arc
cpe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA200810029746XA
Other languages
Chinese (zh)
Inventor
麦志荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN SHUNDE KAIHUA ELECTRIC APPLIANCE Co Ltd
Original Assignee
FOSHAN SHUNDE KAIHUA ELECTRIC APPLIANCE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FOSHAN SHUNDE KAIHUA ELECTRIC APPLIANCE Co Ltd filed Critical FOSHAN SHUNDE KAIHUA ELECTRIC APPLIANCE Co Ltd
Priority to CNA200810029746XA priority Critical patent/CN101325096A/en
Publication of CN101325096A publication Critical patent/CN101325096A/en
Pending legal-status Critical Current

Links

Landscapes

  • Organic Insulating Materials (AREA)

Abstract

The utility model relates to a wire insulating material and the preparation method thereof. The wire insulating material comprises chlorinated polyethylene rubber (CPE), a flame retardant, a filling agent, a plasticizer, a cross-linking co-agent, a curing agent and an electric arc quencher, and the wire insulating material respectively comprise the following components by weight parts: 100 parts of chlorinated polyethylene rubber (CPE), 1 to 5 parts of the flame retardant, 20 to 80 parts of the filling agent, 10 to 30 parts of the plasticizer, 2 to 5 parts of the cross-linking co-agent, 2 to 5 parts of the curing agent and 20 to 50 parts of the electric arc quencher. The wire insulating material and the preparation method have good flame retardancy and arc resistance.

Description

A kind of wire-insulating compound and manufacture method thereof
Technical field
The present invention relates to a kind of wire-insulating compound and manufacture method thereof, is a kind of wire-insulating compound and manufacture method thereof of anti-electric arc specifically.
Background technology
Along with economic development, the popularity of electrical equipment is more and more higher, and the use amount of lead is also increasing.Present wire insulation layer material mainly is based on polyvinyl chloride (PVC), and adds corresponding adjuvants and make.But because thermal endurance, anti-flammability and the resistance to ag(e)ing of polyvinyl chloride are all relatively poor, thereby the useful life of lead is shorter, and fail safe and reliability are all relatively poor.And that polyvinyl chloride needs to add in the course of processing is leaded, the auxiliary agent of barium, cadmium, these auxiliary agents that contain the harmful heavy metal element lead is long-time can dissolving after using, environment is polluted.In addition, the lead that polyvinyl chloride the is made hydrogen chloride that in combustion process, can give off poisonous gas, harm people's health.Chlorinated polyethylene rubber (CPE) is used at lead, cable industry on a large scale as a kind of material of good cost performance in recent years, because at chlorinated polyethylene rubber is the chlorine-containing polymer that does not have two keys on a kind of main chain, so it has excellent chemical stability, resistance to ag(e)ing, anti-flammability and oil resistance are all better.In order to improve the anti-flammability of chlorinated polyethylene rubber lead, generally with antimonous oxide (Sb 2O 3) be the collaborative use of fire retardant and chlorinated polyethylene rubber, form halogen antimony flame-retardant system.In addition, when lead is applying when burning under the voltage condition, form carbide and generate heat owing to electric current flows through the burning back, charcoal is because heating and oxidized, generation electric spark when it disappears.Halogen antimony flame-retardant system very easily forms does not have the burning of falling into, and the carbide on top layer contains a large amount of heats, quickens charring layer formation and very easily produces electric spark, and existing technology generally is to add metal hydroxides in the chlorinated polyethylene rubber lead.Metal hydroxides in the lead is decomposes when wire combustion or generation electric arc, produces moisture, absorbs a large amount of heat, can reach the fire-retardant purpose of cancellation electric arc.But in this chlorinated polyethylene rubber lead, because of it needs to use a large amount of antimonous oxides in the course of processing, and the burning of antimonous oxide is flameless combustion, is not easy to control the cancellation of electric arc.And the cost of antimonous oxide is higher, and the production cost of lead is risen.Therefore, present chlorinated polyethylene rubber lead awaits further improvement.
Summary of the invention
Goal of the invention of the present invention is to overcome the deficiencies in the prior art, and a kind of have good anti-flammability, the wire-insulating compound of arc resistance are provided.
Another goal of the invention of the present invention provides a kind of method for preparing the said wires Insulation Material.
Goal of the invention of the present invention is achieved in that a kind of wire-insulating compound, it is characterized in that: described wire-insulating compound comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher, and each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), fire retardant 1-5 part, filler 20-80 part, plasticizer 10-30 part, crosslinking coagent 2-5 part, vulcanizing agent 2-5 part, electric arc quencher 20-50 part.
Described fire retardant is antimonous oxide (Sb 2O 3).
Described filler is that wherein one or more the above-mentioned composition of superfine talcum powder, calcium carbonate, potter's clay mixes with arbitrary proportion.
Described plasticizer is trioctyl trimellitate (TOTM) (TOTM).
Described crosslinking coagent is cyanacrylate (TAIC).
Described vulcanizing agent is a dual-tert-butyl peroxidating cumene (BIBP).
Described electric arc quencher is super fine magnesium hydroxide (MDH).
Contain activated magnesia (MgO) in the described wire-insulating compound.
The content of described activated magnesia (MgO) is figured part into 5-10 by weight.
Contain carbon black in the described wire-insulating compound.
The content of described carbon black is figured part into 2-3 by weight.
Described manufacture method may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 1-3 minute;
B. add plasticizer, under atmospheric pressure environment mixing 1-4 minute;
C. depress the pressure thallium, after the dnockout temperature reaches 70-80 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 90-110 ℃, add vulcanizing agent;
E. continue dnockout 30-70 second after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 10-20 hour, treated that rubber answer normality gets final product.
The present invention has the following advantages:
1, in the wire-insulating compound of the present invention, because fire retardant antimonous oxide (Sb 2O 3) content less, significantly reduced the phenomenon of glowing of charring layer after the wire combustion, also less to the negative effect of arc resistance, so lead has good arc resistance.In addition, add electric arc quencher (super fine magnesium hydroxide (MDH)) in lead, metal hydroxides meeting decomposes produces moisture when wire combustion, absorbs a large amount of heat, plays good flame-retardant effect.And in the wire combustion process, the electric arc quencher can produce cooperative effect with fire retardant, has further strengthened the arc resistance of lead.
2, in the wire-insulating compound of the present invention, because fire retardant antimonous oxide (Sb 2O 3) content less, its cost also decreases, and can save a large amount of production costs.
Embodiment
Mainly comprise chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher in the wire-insulating compound of the present invention, each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), fire retardant 1-5 part, filler 20-80 part, plasticizer 10-30 part, crosslinking coagent 2-5 part, vulcanizing agent 2-5 part, electric arc quencher 20-50 part.It is the product of CPE135B that chlorinated polyethylene rubber (CPE) can adopt the trade mark of AsiaSat chemical production.Fire retardant is selected antimonous oxide (Sb for use 2O 3), make itself and chlorinated polyethylene rubber (CPE) form halogen antimony flame-retardant system.Because antimonous oxide (Sb 2O 3) content the negative effect of arc resistance is played a decisive role, along with antimonous oxide (Sb 2O 3) increase of content, arc resistance is just poor more, and the phenomenon of glowing of charring layer is also just more serious after the wire combustion, so has reduced the ratio of fire retardant in this wire-insulating compound, improves the arc resistance of wire-insulating compound.Filler adopts wherein one or more the above-mentioned composition of superfine talcum powder, calcium carbonate, potter's clay to mix with arbitrary proportion, can regulate the ratio of three kinds of compositions according to the actual needs of producing, and perhaps allocates with a kind of, two kinds of compositions.Plasticizer is selected trioctyl trimellitate (TOTM) (TOTM) for use, and trioctyl trimellitate (TOTM) (TOTM) has good electrical properties, and durability and resistance to migration are better, and is good with the compatibility of chlorinated polyethylene rubber (CPE).Crosslinking coagent is selected cyanacrylate (TAIC) for use, cyanacrylate (TAIC) product that can adopt Liuyang Organic Chemical Plant to produce.Cyanacrylate (TAIC) can significantly improve thermal endurance, weatherability, corrosion resistance, anti-flammability and the insulating properties of cross-linked rubber.Vulcanizing agent is selected dual-tert-butyl peroxidating cumene (BIBP) for use, dual-tert-butyl peroxidating cumene (BIBP) product that can adopt Liuyang Organic Chemical Plant to produce.In the cross-linking process of chlorinated polyethylene rubber (CPE), dual-tert-butyl peroxidating cumene (BIBP) cross-linking efficiency is higher, and thermal endurance, low temperature resistant subduing property and the withstand voltage morphotropism of crosslinked back goods are all better.The electric arc quencher is selected super fine magnesium hydroxide (MDH) for use, this material is the meeting decomposes when plastics or rubber burning, emit water vapour, its white cigarette can play dilution, masking action with the black smoke of plastics or rubber burning generation, therefore it can reduce smog and toxic gas, and the anti-flammability of reinforced article and arc resistance are compared with existing electric arc quencher ultrafine aluminium hydroxide, charring layer after the ultrafine aluminium hydroxide burning presents loose ashes shape, easily drops under the air-flow that flame causes drives.Charring layer after opposite super fine magnesium hydroxide (MDH) burning is very closely knit, sticks to conductive surface, forms hard duricrust, has stoped the further transmission of heat.Flame retardant effect and arc resistance all are significantly increased than ultrafine aluminium hydroxide.In addition, also added carbon black and activated magnesia (MgO) in wire-insulating compound, it is the product of N774 that carbon black can be selected the trade mark for use.The content of activated magnesia (MgO) is figured part into 5-10 by weight; The content of carbon black is figured part into 1-3 by weight.The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 1-3 minute;
B. add plasticizer, under atmospheric pressure environment mixing 1-4 minute;
C. depress the pressure thallium, after the dnockout temperature reaches 70-80 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 90-110 ℃, add vulcanizing agent;
E. continue dnockout 30-70 second after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 10-20 hour, treated that rubber answer normality gets final product.
Below by table 1 each embodiment is further specified the present invention, but therefore do not limit the invention in the described scope of embodiments.
Embodiment 1
Wire-insulating compound of the present invention comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher.Fire retardant is antimonous oxide (Sb 2O 3), filler is that superfine talcum powder, plasticizer are that trioctyl trimellitate (TOTM) (TOTM), crosslinking coagent are that cyanacrylate (TAIC), vulcanizing agent are that dual-tert-butyl peroxidating cumene (BIBP), electric arc quencher are super fine magnesium hydroxide (MDH).In order to improve the compatibility between chlorinated polyethylene rubber (CPE) and the auxiliary agent, in wire-insulating compound, add carbon black.Add activated magnesia (MgO) in the wire-insulating compound, can improve the activity of electric arc quencher, make the electric arc quencher can be better compatible with chlorinated polyethylene rubber (CPE).Each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), antimonous oxide (Sb 2O 3) 3 parts, 70 parts of superfine talcum powders, 15 parts of trioctyl trimellitate (TOTM)s (TOTM), 3 parts of cyanacrylate (TAIC) agent, 3 parts of dual-tert-butyl peroxidating cumenes (BIBP), 30 parts of super fine magnesium hydroxides (MDH), 2 parts of carbon blacks, 8 parts of activated magnesias (MgO).The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 2 minutes;
B. add plasticizer, under atmospheric pressure environment mixing 3 minutes;
C. depress the pressure thallium, after the dnockout temperature reaches 75 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 105 ℃, add vulcanizing agent;
E. continue dnockout 30 seconds after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 10 hours, treated that rubber answer normality gets final product.
Wire-insulating compound of the present invention is used to extrude parallel heater flexible cable, in the no electric arc generation after 2 minutes of burning under the lead energising situation, the burning back does not have drippage, and the charcoal layer does not have Red Star (promptly not having the phenomenon of glowing), and flame retardant rating satisfies the requirement of the DZ-3 among the GB12666-90.
Embodiment 2
Wire-insulating compound of the present invention comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher.Fire retardant is antimonous oxide (Sb 2O 3), filler is that superfine talcum powder and calcium carbonate, plasticizer are that trioctyl trimellitate (TOTM) (TOTM), crosslinking coagent are that cyanacrylate (TAIC), vulcanizing agent are that dual-tert-butyl peroxidating cumene (BIBP), electric arc quencher are super fine magnesium hydroxide (MDH).In addition, carbon black and two kinds of auxiliary agents of activated magnesia (MgO) in chlorinated polyethylene rubber (CPE), have also been added.Each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), antimonous oxide (Sb 2O 3) 4 parts, 45 parts of superfine talcum powders, 30 parts in calcium carbonate, 17 parts of trioctyl trimellitate (TOTM)s (TOTM), 4 parts of cyanacrylate (TAIC) agent, 4 parts of dual-tert-butyl peroxidating cumenes (BI BP), 35 parts of super fine magnesium hydroxides (MDH), 1 part of carbon black, 9 parts of activated magnesias (MgO).The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 2 minutes;
B. add plasticizer, under atmospheric pressure environment mixing 2 minutes;
C. depress the pressure thallium, after the dnockout temperature reaches 70 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 100 ℃, add vulcanizing agent;
E. continue dnockout 40 seconds after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 13 hours, treated that rubber answer normality gets final product.
Wire-insulating compound of the present invention is used to extrude parallel heater flexible cable, in the no electric arc generation after 2 minutes of burning under the lead energising situation, the burning back does not have drippage, and the charcoal layer does not have Red Star (promptly not having the phenomenon of glowing), and flame retardant rating satisfies the requirement of the DZ-3 among the GB12666-90.
Embodiment 3
Wire-insulating compound of the present invention comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher.Fire retardant is antimonous oxide (Sb 2O 3), filler is that superfine talcum powder and potter's clay, plasticizer are that trioctyl trimellitate (TOTM) (TOTM), crosslinking coagent are that cyanacrylate (TAIC), vulcanizing agent are that dual-tert-butyl peroxidating cumene (BIBP), electric arc quencher are super fine magnesium hydroxide (MDH).In addition, carbon black and two kinds of auxiliary agents of activated magnesia (MgO) in chlorinated polyethylene rubber (CPE), have also been added.Each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), 5 parts of antimonous oxides (Sb2O3), 50 parts of superfine talcum powders, 30 parts in potter's clay, 30 parts of trioctyl trimellitate (TOTM)s (TOTM), 5 parts of cyanacrylate (TAIC) agent, 5 parts of dual-tert-butyl peroxidating cumenes (BIBP), 20 parts of super fine magnesium hydroxides (MDH), 3 parts of carbon blacks, 10 parts of activated magnesias (MgO).The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 3 minutes;
B. add plasticizer, under atmospheric pressure environment mixing 4 minutes;
C. depress the pressure thallium, after the dnockout temperature reaches 80 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 110 ℃, add vulcanizing agent;
E. continue dnockout 70 seconds after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 20 hours, treated that rubber answer normality gets final product.
Wire-insulating compound of the present invention is used to extrude parallel heater flexible cable, in the no electric arc generation after 2 minutes of burning under the lead energising situation, the burning back does not have drippage, and the charcoal layer does not have Red Star (promptly not having the phenomenon of glowing), and flame retardant rating satisfies the requirement of the DZ-3 among the GB12666-90.
Embodiment 4
Wire-insulating compound of the present invention comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher.Fire retardant is that antimonous oxide (Sb2O3), filler are that superfine talcum powder and potter's clay, plasticizer are that trioctyl trimellitate (TOTM) (TOTM), crosslinking coagent are that cyanacrylate (TAIC), vulcanizing agent are that dual-tert-butyl peroxidating cumene (BIBP), electric arc quencher are super fine magnesium hydroxide (MDH).In addition, carbon black and two kinds of auxiliary agents of activated magnesia (MgO) in chlorinated polyethylene rubber (CPE), have also been added.Each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), 1 part of antimonous oxide (Sb2O3), 10 parts of superfine talcum powders, calcium carbonate 5,5 parts in potter's clay, 10 parts of trioctyl trimellitate (TOTM)s (TOTM), 1 part of cyanacrylate (TAIC) agent, 1 part of dual-tert-butyl peroxidating cumene (BIBP), 50 parts of super fine magnesium hydroxides (MDH), 1 part of carbon black, 5 parts of activated magnesias (MgO).The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 1 minute;
B. add plasticizer, under atmospheric pressure environment mixing 1 minute;
C. depress the pressure thallium, after the dnockout temperature reaches 70 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 90 ℃, add vulcanizing agent;
E. continue dnockout 30 seconds after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 10 hours, treated that rubber answer normality gets final product.
Wire-insulating compound of the present invention is used to extrude parallel heater flexible cable, in the no electric arc generation after 2 minutes of burning under the lead energising situation, the burning back does not have drippage, and the charcoal layer does not have Red Star (promptly not having the phenomenon of glowing), and flame retardant rating satisfies the requirement of the DZ-3 among the GB12666-90.
Embodiment 5
Wire-insulating compound of the present invention comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking coagent, vulcanizing agent and electric arc quencher.Fire retardant is that antimonous oxide (Sb2O3), filler are that superfine talcum powder and potter's clay, plasticizer are that trioctyl trimellitate (TOTM) (TOTM), crosslinking coagent are that cyanacrylate (TAIC), vulcanizing agent are that dual-tert-butyl peroxidating cumene (BIBP), electric arc quencher are super fine magnesium hydroxide (MDH).In addition, carbon black and two kinds of auxiliary agents of activated magnesia (MgO) in chlorinated polyethylene rubber (CPE), have also been added.Each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), 2 parts of antimonous oxides (Sb2O3), 30 parts of superfine talcum powders, 20 parts in calcium carbonate, 10 parts in potter's clay, 13 parts of trioctyl trimellitate (TOTM)s (TOTM), 3 parts of cyanacrylate (TAIC) agent, 4 parts of dual-tert-butyl peroxidating cumenes (BIBP), 40 parts of super fine magnesium hydroxides (MDH), 2 parts of carbon blacks, 7 parts of activated magnesias (MgO).The manufacture method of wire-insulating compound may further comprise the steps:
A. in banbury, add fire retardant, crosslinking coagent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 2 minutes;
B. add plasticizer, under atmospheric pressure environment mixing 2 minutes;
C. depress the pressure thallium, after the dnockout temperature reaches 75 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 95 ℃, add vulcanizing agent;
E. continue dnockout 50 seconds after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 18 hours, treated that rubber answer normality gets final product.
Wire-insulating compound of the present invention is used to extrude parallel heater flexible cable, in the no electric arc generation after 2 minutes of burning under the lead energising situation, the burning back does not have drippage, and the charcoal layer does not have Red Star (promptly not having the phenomenon of glowing), and flame retardant rating satisfies the requirement of the DZ-3 among the GB12666-90.
Table 1
Figure A20081002974600101

Claims (12)

1, a kind of wire-insulating compound, it is characterized in that: described wire-insulating compound comprises chlorinated polyethylene rubber (CPE), fire retardant, filler, plasticizer, crosslinking agent, vulcanizing agent and electric arc quencher, and each components contents is calculated by weight and is respectively 100 parts of chlorinated polyethylene rubbers (CPE), fire retardant 1-5 part, filler 20-80 part, plasticizer 10-30 part, crosslinking coagent 2-5 part, vulcanizing agent 2-5 part, electric arc quencher 20-50 part.
2, according to the described wire-insulating compound of claim 1, it is characterized in that: described fire retardant is antimonous oxide (Sb 2O 3).
3, according to the described wire-insulating compound of claim 1, it is characterized in that: described filler is that wherein one or more the above-mentioned composition of superfine talcum powder, calcium carbonate, potter's clay mixes with arbitrary proportion.
4, according to the described wire-insulating compound of claim 1, it is characterized in that: described plasticizer is trioctyl trimellitate (TOTM) (TOTM).
5, according to the described wire-insulating compound of claim 1, it is characterized in that: described crosslinking coagent is cyanacrylate (TAIC).
6, according to the described wire-insulating compound of claim 1, it is characterized in that: described vulcanizing agent is a dual-tert-butyl peroxidating cumene (BIBP).
7, according to the described wire-insulating compound of claim 1, it is characterized in that: described electric arc quencher is super fine magnesium hydroxide (MDH).
8, according to the described wire-insulating compound of claim 1, it is characterized in that: contain activated magnesia (MgO) in the described wire-insulating compound.
9, described according to Claim 8 wire-insulating compound is characterized in that: the content of described activated magnesia (MgO) is figured part into 5-10 by weight.
10, according to the described wire-insulating compound of claim 1, it is characterized in that: contain carbon black in the described wire-insulating compound.
11, according to the described wire-insulating compound of claim 10, it is characterized in that: the content of described carbon black is figured part into 1-3 by weight.
12, a kind of manufacturing manufacture method of wire-insulating compound according to claim 1, it is characterized in that: described manufacture method may further comprise the steps:
A. in banbury, add fire retardant, crosslinking agent and electric arc quencher successively, to be mixedly add filler and chlorinated polyethylene rubber (CPE) successively after evenly, under atmospheric pressure environment mixing 1-3 minute;
B. add plasticizer, under atmospheric pressure environment mixing 1-4 minute;
C. depress the pressure thallium, after the dnockout temperature reaches 70-80 ℃, promote and press thallium;
D. clean dust, when the dnockout temperature reaches 90-110 ℃, add vulcanizing agent;
E. continue dnockout 30-70 second after adding vulcanizing agent, expect the enterprising one-step melting of mill then down;
F. the rubber that mixes was parked under normal temperature, normal pressure 10-20 hour, treated that rubber answer normality gets final product.
CNA200810029746XA 2008-07-21 2008-07-21 Wire insulation material and manufacturing method thereof Pending CN101325096A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA200810029746XA CN101325096A (en) 2008-07-21 2008-07-21 Wire insulation material and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA200810029746XA CN101325096A (en) 2008-07-21 2008-07-21 Wire insulation material and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN101325096A true CN101325096A (en) 2008-12-17

Family

ID=40188577

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200810029746XA Pending CN101325096A (en) 2008-07-21 2008-07-21 Wire insulation material and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN101325096A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103214748A (en) * 2013-03-25 2013-07-24 陕西省轻工业研究设计院 Preparation method of flame retardant high resistivity CPE cable sizing material
CN112063064A (en) * 2020-08-05 2020-12-11 广东凯华电器股份有限公司 Scratch-resistant rubber colored wire and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103214748A (en) * 2013-03-25 2013-07-24 陕西省轻工业研究设计院 Preparation method of flame retardant high resistivity CPE cable sizing material
CN112063064A (en) * 2020-08-05 2020-12-11 广东凯华电器股份有限公司 Scratch-resistant rubber colored wire and manufacturing method thereof

Similar Documents

Publication Publication Date Title
CN107286636B (en) Low-smoke flame-retardant ceramic thermoplastic polyurethane elastomer composite material and preparation method and application thereof
CN101319079B (en) Silicone hydride crosslinked non-halogen flame-proof smoke-restraining polyvinyl chloride cable material and manufacturing process thereof
CN105761839B (en) A kind of high flexibility fireproof cable and preparation method thereof
CN103571116B (en) A kind of ageing-resistant CABLE MATERIALS of low-smoke non-halogen flame-retardant for cable
CN105330943B (en) A kind of fire retardant insulating CABLE MATERIALS and preparation method thereof
CN103739927B (en) Temperature resistant grade is low-smoke zero-halogen cable material formula and the preparation method of 150 DEG C
CN103897292A (en) Low smoke antiflaming high shield cable sheath material
CN102250426A (en) Cable sheath rubber
CN102250406A (en) Polyethylene material with high flame resistance
CN105367965A (en) Halogen-free flame-retardant ceramic polyolefin cable material for fire-resisting cables and preparation method for halogen-free flame-retardant ceramic polyolefin cable material
CN109265813A (en) A kind of marine inflaming-retarding cable jacket material of salt spray proof and preparation method thereof
CN102408620A (en) Environment-friendly sheath material for cable and preparation method thereof
CN102108161A (en) Rubber wire insulating material and manufacturing method thereof
CN103788530A (en) Low-smoke low-halogen flame-retardant insulation-grade PVC (polyvinyl chloride) sheath material for ultrahigh-voltage cable, and preparation of low-smoke low-halogen flame-retardant insulation-grade PVC sheath material
CN104277451A (en) Electric wire insulating material with relatively high heat resistance
CN101325096A (en) Wire insulation material and manufacturing method thereof
CN201812530U (en) Fire-proof expansion type halogen-free high-flame-retardant environment-friendly cable
CN109467849A (en) A kind of material and preparation method thereof manufacturing fireproof cable PVC sheath
CN117143424A (en) Insulating cable sheath material and preparation method thereof
CN107501741A (en) A kind of fire-retardant ageing-resistant TPO waterproof rolls and its preparation technology
CN204066835U (en) A kind of environment-protective halogen-free low-smoke flame-retardant fire and heat endurance anticorrosive insulation electric wire
CN103709551A (en) High-temperature resistant fireproof nano insulating material
CN105400026A (en) Chloroprene rubber compound and preparation method thereof
CN101161775A (en) Novel halogen-free environment-friendly type flame-proof polypropylene material
CN105906995B (en) PVC based composites and preparation method thereof for attaching plug

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20081217