CN101323519B - Magnesium slag composite silicate hydraulic cementing gelate material - Google Patents
Magnesium slag composite silicate hydraulic cementing gelate material Download PDFInfo
- Publication number
- CN101323519B CN101323519B CN2007102008309A CN200710200830A CN101323519B CN 101323519 B CN101323519 B CN 101323519B CN 2007102008309 A CN2007102008309 A CN 2007102008309A CN 200710200830 A CN200710200830 A CN 200710200830A CN 101323519 B CN101323519 B CN 101323519B
- Authority
- CN
- China
- Prior art keywords
- magnesium
- slag
- hydraulic cementing
- gelate
- composite silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/08—Slag cements
- C04B28/085—Slags from the production of specific alloys, e.g. ferrochrome slags
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a magnesium slag compound silicate hydraulic cementing material. The preparation method is as follows: the materials which are matched by weight shares as follows: 41 to 55 shares of magnesium-smelting reduced-slag, 15 to 33 shares of silicate cement grog, 1 to 8 shares of gypsum and 5 to 20 shares of fly ash or cinder, or/and granulated blast-furnace slag are mixed and then milled into thin powder which is directed processed into the hydraulic cementing material which takes the magnesium slag compound silicate as a main content and can be directly used for construction and reaches the 'compound silicate cement' standard. The invention can directly lead the reduced slag generated during magnesium smelting by heat-reduction method to be converted into the hydraulic cementing material used for construction so as to recycle the wastes, reduce the contamination to environment by the magnesium-reduction waste slag and reduce the cost of disposal of waste slag.
Description
Technical field
The present invention relates to a kind of hydraulic cementing materials, particularly relate to the preparation of magnesium slag composite silicate hydraulic cementing gelate material.
Background technology
The present reducing slag that produces with smelting magnesium by thermal reduction process is usually as waste disposal, and waste material needs the stockyard to stack, not only the land occupation resource; Also since the reducing slag that produces with smelting magnesium by thermal reduction process powdered normally when stacking, meet wind and be easy to produce airborne dust, serious environment pollution.How will turn waste into wealth with the reduction waste residue that smelting magnesium by thermal reduction process produces, and to make full use of waste material and be prepared into the material that can be used for building use, be a problem that helps society and can increase economic efficiency.
Summary of the invention
The objective of the invention is to, a kind of magnesium slag composite silicate hydraulic cementing gelate material is provided.The reducing slag that the present invention utilizes smelting magnesium by thermal reduction process to produce directly generates and can be used for building the magnesium slag composite silicate hydraulic cementing gelate material of use, has accomplished utilization of waste material, has also reduced the pollution of environment and the cost of processing waste residue.
Technical scheme of the present invention.Magnesium slag composite silicate hydraulic cementing gelate material is characterized in that: be with the following weight parts proportion raw material, and magnesium-smelting reduction slag 41-55 part; Portland clinker 15-33 part, gypsum 1-8 part, flyash or cinder; Or/and granulated blast-furnace slag 5-20 part is mixed levigate the processing in back.
In the above-mentioned magnesium slag composite silicate hydraulic cementing gelate material, described Portland clinker is the 25-33 weight part.
In the aforesaid magnesium slag composite silicate hydraulic cementing gelate material, levigate surface-area to every gram is 3000-5000cm after the described raw materials mix
2
In the aforesaid magnesium slag composite silicate hydraulic cementing gelate material, described magnesium-smelting reduction slag is meant that the smelting magnesium by thermal reduction process process step by routine obtains magnesium-smelting reduction slag.
In the aforesaid magnesium slag composite silicate hydraulic cementing gelate material, described gypsum is meant the plaster of paris, phosphogypsum, fluorgypsum or industrially desulfurized gypsum.
In the aforesaid magnesium slag composite silicate hydraulic cementing gelate material, described magnesium-smelting reduction slag at high temperature needs cooling fast, and its process of cooling is controlled at below 10～150 minutes internal cooling to 200 ℃.
In the aforesaid magnesium slag composite silicate hydraulic cementing gelate material, rapid cooling method adopts cold slag machine cooling, and cold slag machine can adopt the scheme of wind or water-cooled.
Compared with prior art; The reducing slag that the present invention produces with smelting magnesium by thermal reduction process is that main raw material is after cooling; Add Portland clinker, gypsum, flyash again or/and cinder; Or/and granulated blast-furnace slag, wear into the direct generation technique index of powder after the mixing and meet " composite Portland cement " standard, what can be used for building use is main hydraulic cementing materials with the magnesium slag composite silicate; The present invention uses simple method and simple equipment just to accomplish utilization of waste material, has reduced the magnesium reduction waste residue to the pollution of environment and the cost of processing waste residue.
Embodiment
Embodiment 1: magnesium slag composite silicate hydraulic cementing gelate material.Its preparation method is: get the high temperature magnesium-smelting reduction slag 55Kg by the process for smelting magnesium step acquisition of routine; In 60 minutes, be cooled fast to 180 ℃ with cold slag machine, again with Portland clinker 20Kg, gypsum 8Kg; After flyash 15 Kg mixed, levigate surface-area to every gram was 4000cm
2, what obtain promptly that technical indicator meets " composite Portland cement " standard is main hydraulic cementing materials with the magnesium slag composite silicate.
Embodiment 2: magnesium slag composite silicate hydraulic cementing gelate material.Its preparation method is: get the high temperature magnesium-smelting reduction slag 48Kg by the process for smelting magnesium step acquisition of routine; In 60 minutes, be cooled fast to 150 ℃ with cold slag machine, again with Portland clinker 29Kg, gypsum 6Kg; After flyash 12Kg mixed, levigate surface-area to every gram was 3500cm
2, what obtain promptly that technical indicator meets " composite Portland cement " standard is main hydraulic cementing materials with the magnesium slag composite silicate.
In above-mentioned each example, flyash can adopt cinder or granulated blast-furnace slag, also can adopt the mixture of flyash and granulated blast-furnace slag or the mixture of cinder and granulated blast-furnace slag.If (can be the two or three's mixture; Then the description about " flyash or cinder are or/and granulated blast-furnace slag " should change " flyash, cinder or granulated blast-furnace slag or wherein the two or three's mixture " in the claim) gypsum in the magnesium slag composite silicate hydraulic cementing gelate material can be the plaster of paris, phosphogypsum, fluorgypsum or industrially desulfurized gypsum.
Quick cooling magnesium-smelting reduction slag in the preparation process of above-mentioned magnesium slag composite silicate hydraulic cementing gelate material can improve the activity of reducing slag; Increase the intensity of magnesium slag composite silicate hydraulic cementing gelate material, rapid cooling method can adopt naturally cooling and the method for forcing cooling to combine.
Claims (4)
1. magnesium slag composite silicate hydraulic cementing gelate material is characterized in that: be with the following weight parts proportion raw material, and magnesium-smelting reduction slag 41-55 part; Portland clinker 25-33 part; Gypsum 1-8 part, flyash, cinder or granulated blast-furnace slag 5-20 part are mixed levigate the processing in back; Described magnesium-smelting reduction slag is meant that the smelting magnesium by thermal reduction process process step by routine obtains magnesium-smelting reduction slag; Described magnesium-smelting reduction slag at high temperature needs cooling fast, and its process of cooling is controlled at below 10～150 minutes internal cooling to 200 ℃.
2. magnesium slag composite silicate hydraulic cementing gelate material according to claim 1 is characterized in that: levigate surface-area to every gram is 3000-5000 cm after the described raw materials mix
2
3. magnesium slag composite silicate hydraulic cementing gelate material according to claim 2 is characterized in that: described gypsum is meant the plaster of paris, phosphogypsum, fluorgypsum or industrially desulfurized gypsum.
4. magnesium slag composite silicate hydraulic cementing gelate material according to claim 3 is characterized in that: rapid cooling method adopts cold slag machine cooling, and cold slag machine adopts wind or water-cooled scheme.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007102008309A CN101323519B (en) | 2007-06-15 | 2007-06-15 | Magnesium slag composite silicate hydraulic cementing gelate material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007102008309A CN101323519B (en) | 2007-06-15 | 2007-06-15 | Magnesium slag composite silicate hydraulic cementing gelate material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101323519A CN101323519A (en) | 2008-12-17 |
| CN101323519B true CN101323519B (en) | 2012-02-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007102008309A Expired - Fee Related CN101323519B (en) | 2007-06-15 | 2007-06-15 | Magnesium slag composite silicate hydraulic cementing gelate material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101323519B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788029A (en) * | 2015-03-23 | 2015-07-22 | 苏州市德莱尔建材科技有限公司 | Rapid hardening Portland cement and preparation method thereof |
| CN105036576A (en) * | 2015-06-25 | 2015-11-11 | 西安美吕环保科技有限公司 | Composite Portland cement prepared from metallic magnesium reducing slag and mineral regulator thereof |
| CN109851258B (en) * | 2018-12-29 | 2020-09-11 | 山东永正水泥有限公司 | Cementing material and preparation method thereof, concrete road and paving method thereof |
| CN112608046A (en) * | 2020-11-21 | 2021-04-06 | 河北京兰水泥有限公司 | Coal-fired furnace slag composite mixed material and preparation method and application thereof |
| CN112851277A (en) * | 2021-03-27 | 2021-05-28 | 西安弗尔绿创矿业科技有限责任公司 | Magnesium-cinder-based novel paving and mining filling material and preparation method thereof |
| CN113857227B (en) * | 2021-09-27 | 2022-05-13 | 生态环境部南京环境科学研究所 | Method for restoring heavy metal cadmium farmland soil by using stabilized restoring material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702051A (en) * | 2000-01-08 | 2005-11-30 | 山西广灵精华化工集团有限公司 | Method for producing masonry cement by using magnesium-smelting waste residues |
-
2007
- 2007-06-15 CN CN2007102008309A patent/CN101323519B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702051A (en) * | 2000-01-08 | 2005-11-30 | 山西广灵精华化工集团有限公司 | Method for producing masonry cement by using magnesium-smelting waste residues |
Non-Patent Citations (1)
| Title |
|---|
| 黄从运等.利用镁渣作混合材生产复合硅酸盐水泥试验研究.《水泥技术》.2005,(第5期),第21－22页. * |
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| Publication number | Publication date |
|---|---|
| CN101323519A (en) | 2008-12-17 |
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