CN101319114A - Paint for artificial pearl coating and preparation thereof - Google Patents
Paint for artificial pearl coating and preparation thereof Download PDFInfo
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- CN101319114A CN101319114A CNA2007100877687A CN200710087768A CN101319114A CN 101319114 A CN101319114 A CN 101319114A CN A2007100877687 A CNA2007100877687 A CN A2007100877687A CN 200710087768 A CN200710087768 A CN 200710087768A CN 101319114 A CN101319114 A CN 101319114A
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Abstract
An imitation pearl coating material and a method for making the same belong to the coating material combination technical field which takes water-soluble synthetic resin coating material as a base material. The imitation pearl coating material is characterized in that the coating material is made from mixed water-soluble polyacrylic acid resin coating material, a low-temperature hardening agent, a moderate-temperature and normal-temperature hardening accelerating agent, an antifreezing agent, a thickening agent and a pearlescent pigment. The imitation pearl coating material does no harm to human body and is environment-friendly; meanwhile, the coating material has no peculiar smell and does not generate poison gas; moreover, the coating material does not cause explosion and fire hazards and contains hardly any lead.
Description
Technical field
The invention belongs to coating composition technical field based on water soluble resin, being specifically related to water-soluble polypropylene acid resin coating is coating composition and the method for making thereof that main raw material is made, and this coating composition is used for the coating of various jewellery such as necklace, bangle, ring, olivet.
Background technology
At the paint coatings of use of the surface of synthetic resins artificial pearl small ball or glass pellet and natural peral color similarity, the aesthetic feeling that makes its outward appearance is widely used on the coating of various artificial headdress not less than natural peral.
Compare with natural peral, that olivet or glass pellet have is cheap, numerous in variety, advantage that can suitability for industrialized production, thereby its demand sharply increases, as the method for the coating of its top coat and coating also by people cognition.
The top coat coating of olivet or glass pellet mainly is that the quantitative pearl pigment of adding is made add nitro-cotton and/or xylonite mixed dissolution in solvent acetone, ethyl acetate, butylacetate, pentyl acetate after in the prior art.
The weak point of above-mentioned coated coating is: because raw material all is a butyrous, can produce harmful gas or poison gas in manufacturing or coating procedure, also be easy to the danger that causes fire and blast is arranged.In addition, lead content height in the coating of prior art may work the mischief and causes environmental pollution human body.
The water-soluble synthetic paint resin of prior art has: phthalic resin coating, terpolycyantoamino-formaldehyde resin coating, acryl, phenolic resin, Resins, epoxy etc. are that main raw material is made the olivet coated coating with water soluble resin coating.
If adopt above-mentioned water soluble alkyd resin coating, water-soluble epoxy resins coating, the water-soluble poly butadiene resin coating of changing, because of its drying temperature height (120～170 ℃) easily makes synthetic resins bead at high temperature surface melting or distortion, bring difficulty to production; In addition, the greatest weakness of water soluble paint also is can freeze under zero degrees celsius.
Summary of the invention
The purpose of this invention is to provide the problem that a kind of paint for artificial pearl coating can effectively solve oil paint and water-borne coatings in the prior art, another object of the present invention has provided the method for making of described paint for artificial pearl coating.
The present invention adopts following technical scheme to realize:
A kind of method for making of artificial pearl coating coating is characterized in that, described artificial pearl coating coating is that main raw material is made with water-soluble polypropylene acid resin coating.
Specifically be, described paint for artificial pearl coating is a main raw material with water-soluble polypropylene acid resin coating, adds water, low-temperature stiffening agent, in, the cold setting accelerator, frostproofer, tackifier, pearl pigment is mixed and made into.
Water-soluble polypropylene acid resin coating of the present invention is to add amine according to prior art after copolymerization such as vinylformic acid, vinylbenzene, esters of acrylic acid, methacrylic acids to make water miscible aminated polypropylene acid resin or add the water-soluble polypropylene acid resin that other alkaline matters are made salt.
The method for making of described paint for artificial pearl coating, further be, comprise the steps: that water-soluble polypropylene acid resin coating 10Kg adds entry 1.5～2.5Kg, low-temperature stiffening agent 0.1～0.4Kg, in, cold setting accelerator 0.1～0.5Kg, frostproofer 0.1～0.5Kg, tackifier 0.1～0.5Kg, pearl pigment 0.5～1Kg, uniform mixing make described paint for artificial pearl coating.
Wherein, the low-temperature stiffening agent is the English LIAKTO commodity by name that SANYO GS changes into manufacturing for the low-temperature stiffening agent; In, the cold setting accelerator is that a kind of in furfuryl alcohol, the butylhydroperoxide or two kinds mix and use; Weight ratio is preferred 1: 1 when two kinds of hardening accelerators mix use.Frostproofer is a kind of in Virahol, isopropylcarbinol, methyl alcohol, the glycerine.
Described thickening material effect is to increase the viscosity of coating and oilness and certain sclerization, thickening material polyoxyethylene glycol, the polyoxyethylene glycol of preferred molecular weight 〉=4000.
Pearl pigment is the mixtures a kind of, any two kinds or three kinds in three kinds of titania powder, pearl white, guanin; Pearl pigment is preferably the mixture of titania powder and pearl white, and the two can mix with arbitrary proportion, and preferred ratio is: the weight ratio of titania powder and pearl white is 7: 3.
Beneficial effect of the present invention is:
1) compare with oil paint, coating of the present invention is harmless, free from extraneous odour, close environment, harmless to the producer, therefore produces to be more prone to, and has improved turnout.And according to the characteristics of water soluble paint, its coating is even, can produce high-quality olivet.
2) the present invention's water-soluble coating coating lead tolerance of producing is below 0.0015% (15ppm), and is not only harmless to the producer, also harmless to the people of the jewellery of wearing the paint coatings made from the present invention.
3) compare with oil paint, water soluble paint of the present invention does not have explosion hazard, do not have poison gas yet and produce, thereby carrying coating or keeping coating is more prone to.
4) water-soluble coating coating of the present invention can be dry at normal temperatures, significantly shortened time of drying.
Embodiment
Embodiment 1---most preferred embodiment
In the container that volume is fit to, add 10Kg water-soluble polypropylene acid resin, add 2Kg water, low-temperature stiffening agent LIAKTO0.3Kg, the mixture 0.3Kg of furfuryl alcohol and butylhydroperoxide, frostproofer Virahol 0.3Kg, hardening accelerator polyoxyethylene glycol 0.4Kg, the titania powder pearl pigment or and the mixture 0.6Kg of pearl white mix.
Wherein, furfuryl alcohol and butylhydroperoxide mix with arbitrary proportion; The molecular weight of polyoxyethylene glycol is greater than 4000.
In the present invention, low-temperature stiffening agent LIAKTO, in, identical the best of charging capacity of cold setting accelerator and Virahol, pearl pigment is best with 100% titania powder, and the addition of pearl pigment can increase or reduce according to the pearl gradation of color is an amount of.
The applicant finds by embodiment repeatedly: when the weight ratio of water-soluble polypropylene acid resin coating and water during less than 10: 1, uneven phenomenon occurred on the surface of artificial pearl coating.This is because water-soluble polypropylene acid resin coating makes the phenomenon of your generation of excessive concentration more.
When water-soluble ratio of mixture when water-soluble polypropylene acid resin coating and water is 9: 1, at this moment globule is immersed in when picking up behind the coating, the phenomenon of piling can appear in the bottom of globule (or bottom).This is because the concentration height of coating, makes the globule bottom after the coating thicker than top, in order to remove the thick-layer coating of bottom, globule is placed on when on glass, and coating is difficult for removing, and and glass contact partly stayed scar, produced bad product.
When according to the mixed of embodiment 1, coating result the best, when picking up after at this moment globule being soaked, the coating that is bonded at little bead surface splits away off rapidly, and the piling amount of the bottom of globule is considerably less, globule bottom is placed on when on glass, is deposited in globule bottom coating still and has transferred on glassly rapidly, the whole top coat of dry back globule is even.
In conjunction with the foregoing description, specify effect of the present invention below:
The present invention is in order to prevent that coating from freezing below 0 ℃, having added Virahol, and the result does not freeze under room temp-3 ℃ yet, and work does not bring influence to coating.
General water-borne coatings usually need be under high temperature Celsius 150～170 ℃ could complete drying, but the present invention by add stiffening agent and hardening accelerator furfuryl alcohol or/butylhydroperoxide, Virahol, after the polyoxyethylene glycol mixture carries out coating, when drying 30～40 minutes down for 50～60 ℃ Celsius, its top coat is complete drying very evenly and, and when carrying out 2～3 coating drying operations repeatedly with identical method, its coating result is very good.
Because the present invention has added low-temperature stiffening agent and middle temperature and cold setting agent, so temperature variation brings too big influence can for coating sclerosis of the present invention.
When adopting pigment of the present invention, on color sensation and natural peral do not have too big difference, satisfactory.
The present invention with general water-soluble dye or/and pigment when replacing pearl pigment, can be used for general artificial headdress coating.
Embodiment 2-11
According to the batching in the table 1, uniform mixing makes described paint for artificial pearl coating.
The table of getting the raw materials ready of table 1 embodiment 2-11
The above embodiments of the present invention are can not limit the present invention to explanation of the present invention, in implication suitable with claims of the present invention and any change and the combination in the scope, all should think in the scope of claims.
Claims (12)
1. the method for making of an artificial pearl coating coating is characterized in that, described artificial pearl coating coating is that main raw material is made with water-soluble polypropylene acid resin coating.
2. the method for making of paint for artificial pearl coating according to claim 1, it is characterized in that, described paint for artificial pearl coating is a main raw material with water-soluble polypropylene acid resin coating, add water, low-temperature stiffening agent, in, the cold setting accelerator, frostproofer, tackifier, pearl pigment is mixed and made into.
3. the method for making of paint for artificial pearl coating according to claim 2, it is characterized in that, comprise the steps: that water-soluble polypropylene acid resin coating 10Kg adds entry 1.5～2.5Kg, low-temperature stiffening agent 0.1～0.4Kg, in, cold setting accelerator 0.1～0.5Kg, frostproofer 0.1～0.5Kg, tackifier 0.1～0.5Kg, pearl pigment 0.5～1Kg, uniform mixing make described paint for artificial pearl coating.
4. according to the method for making of claim 2 or 3 described paint for artificial pearl coating, it is characterized in that the low-temperature stiffening agent is the English LIAKTO commodity by name that SANYO GS changes into manufacturing.
5. according to the method for making of claim 2 or 3 described paint for artificial pearl coating, it is characterized in that, in, the cold setting accelerator is that a kind of in furfuryl alcohol, the butylhydroperoxide or two kinds mix and use.
6. the method for making of paint for artificial pearl coating according to claim 5 is characterized in that, preferred 1: 1 of the weight ratio of furfuryl alcohol and butylhydroperoxide.
7. according to the method for making of claim 2 or 3 described paint for artificial pearl coating, it is characterized in that frostproofer is a kind of in Virahol, isopropylcarbinol, methyl alcohol, the glycerine.
8. according to the method for making of claim 2 or 3 described paint for artificial pearl coating, it is characterized in that tackifier are polyoxyethylene glycol.
9. according to the method for making of claim 2 or 3 described paint for artificial pearl coating, it is characterized in that pearl pigment is the mixtures a kind of, any two kinds or three kinds in three kinds of titania powder, pearl white, guanin.
10. the method for making of paint for artificial pearl coating according to claim 9 is characterized in that, pearl pigment is the mixture of titania powder and pearl white.
11. the method for making of paint for artificial pearl coating according to claim 10 is characterized in that, the weight ratio of titania powder and pearl white is 7: 3.
12. the paint for artificial pearl coating that the method for making of each described paint for artificial pearl coating makes in the claim 1 to 11.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100877687A CN101319114B (en) | 2007-03-08 | 2007-03-08 | Paint for artificial pearl coating and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100877687A CN101319114B (en) | 2007-03-08 | 2007-03-08 | Paint for artificial pearl coating and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101319114A true CN101319114A (en) | 2008-12-10 |
| CN101319114B CN101319114B (en) | 2011-06-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100877687A Expired - Fee Related CN101319114B (en) | 2007-03-08 | 2007-03-08 | Paint for artificial pearl coating and preparation thereof |
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| Country | Link |
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| CN (1) | CN101319114B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113163915A (en) * | 2018-11-08 | 2021-07-23 | 黄渊浩 | Healthy artificial pearl and its making method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1288919A (en) * | 2000-10-24 | 2001-03-28 | 上海南汇申利精细化工厂 | Aqueou antirust decorative varnish |
| CN1412260A (en) * | 2001-10-11 | 2003-04-23 | 钟义鑫 | Method for applying epoxy resin on surface of solid |
| CN1837306A (en) * | 2005-03-22 | 2006-09-27 | 韩建华 | Plastic decorative coating and corresponding diluent |
-
2007
- 2007-03-08 CN CN2007100877687A patent/CN101319114B/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113163915A (en) * | 2018-11-08 | 2021-07-23 | 黄渊浩 | Healthy artificial pearl and its making method |
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| Publication number | Publication date |
|---|---|
| CN101319114B (en) | 2011-06-15 |
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Granted publication date: 20110615 Termination date: 20140308 |