CN101314151A - Electrostatic atomization apparatus - Google Patents

Electrostatic atomization apparatus Download PDF

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Publication number
CN101314151A
CN101314151A CNA2007101063760A CN200710106376A CN101314151A CN 101314151 A CN101314151 A CN 101314151A CN A2007101063760 A CNA2007101063760 A CN A2007101063760A CN 200710106376 A CN200710106376 A CN 200710106376A CN 101314151 A CN101314151 A CN 101314151A
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China
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needle part
water
mentioned
electrostatic atomization
mist
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小田岛贞雄
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Freudenberg Apollo Filtration Technologies Co Ltd
Massachusetts Institute of Technology
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Massachusetts Institute of Technology
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention provides an electrostatic atomization device which releases a large amount of ultrafine fog with nanometer dimensions from cold storages, air conditioners, air purifiers, humidifiers, cosmetic instruments and so on, to play the effects of deodorization, sterilization, preservation and so on, in rooms or the cold storages in order to improve indoor environment or the environment in the cold storages. The invention also provides an electrostatic atomization device which releases functional components such as vitamins or catechuic acid without volatility and so on, to the air in the form of the ultrafine fog with the nanometer dimensions. The electrostatic atomization device comprises that: a porous water retaining component (11) is protrudingly provided with a porous release pin component (12) to form a porous shaped body (2) with water absorptivity, water retention property and updraught characteristic, and the porous shaped body (2) is connected with a negative pole (5) to ensure that the porous shaped body (2) is electrified into a direct current high voltage power supply (4) with negative polarity. Moreover, an antipode of positive polarity corresponding to the negative polarity formed by electrifying the porous shaped body (2) does not exist.

Description

Electrostatic atomization apparatus
Technical field
The present invention relates in air, discharge the electrostatic atomization apparatus of ultra micro mist.
Background technology
In the past, in air-conditioning or air purifier, utilized filter to improve indoor environment.And in recent years, also be expected to discharge mist and have the commodity of indoor humidity adjusting or deodorizing, bacteria-eliminating efficacy selling from air-conditioning or air purifier.Mainly utilize method to be, functional components be used for healthy tonic or pharmaceuticals and cosmetics or clothing etc., the taking of the picked-up by healthy tonic, pharmaceuticals, cosmetics smear or the dress of clothing etc. directly is absorption of human body.
And, if utilize the ultrasonic generation device, then can be with the functional components of fixedness with the state atomizing of the aqueous solution and discharge.But the mist that utilizes ultrasonic wave to produce is the size that naked eyes can be seen particle, and it is excessive or moist and cause corroding or the generation of mould etc. to tend to humidity.
Again, in air-conditioning or air purifier, humidifier etc., as the means of improving indoor environment, be equipped with the anion generating device that utilizes corona discharge or evaporate the water and discharge the damping device of mist, or have the auxiliary function that the electrolysis of utilizing produces the mist of hydroxidion water.
For example, known have a following air purifier, it has the electrostatic atomization apparatus of band negative ion generation function, and this electrostatic atomization apparatus comprises: to the opposite electrode, the above-mentioned water of contact that are accommodated in voltage application electrode, ground connection that water in the water maintaining part applies negative voltage and make terminal needle-like atomizing portion and above-mentioned opposite electrode opposed and make the water-absorbing body of the water electrostatic atomization of inhaling from the water maintaining part and the ionization pin (reference example such as patent documentation 1) of the generation of the corona discharge between utilization and above-mentioned opposite electrode anion.
Patent documentation 1: the spy opens the 2004-358358 communique.
But, as patent documentation 1 disclosed anion generating technique, the generation device of commercially available nano-grade size mist, owing to utilize typical corona discharge effect, thus can produce anion in a large number, or produce ozone.Its reason is, in order to increase the generation of anion, the terminal part that often mist is discharged base material forms the shape of point, so, enough moisture can not be drawn onto the end that mist discharges base material, thus enough mist amounts can not be obtained because moisture-holding capacity is few, thus can not atomize and discharge amount of moisture arbitrarily, and because terminal point discharges so be difficult to make functional components to be included in the mist.
Again, as the commercially available relieving mechanism that functional components is discharged in air, except volatile ingredient, also have vitamin ion inducting device, but in utilizing hyperacoustic generation device, fog particles is the micron order size, excessive, thus be difficult to be impregnated in the skin, and, in utilizing the generation device of anion, though fog particles is little of nano-grade size, because terminal point, so can not obtain enough mist amounts.
Summary of the invention
Therefore, the object of the present invention is to provide a kind of ultra micro mist that discharges a large amount of nano-grade sizes for environment in the storehouse of improving indoor environment or freezer from freezer, air-conditioning, air purifier, humidifier, beauty instrument etc., bring into play the electrostatic atomization apparatus of deodorizing in indoor or the storehouse, sterilization, effect such as fresh-keeping.Again, another purpose is to provide a kind of electrostatic atomization apparatus that will not have functional components such as volatile vitamins or catechuic acid to discharge in air with the mist form of fine nano-grade size.
In order to achieve the above object, electrostatic atomization apparatus of the present invention, comprise: by form at the release needle part that porous matter is set on the water conservation parts of porous matter highlightedly and have water imbibition, water-retaining property and on inhale the porous matter formed body of characteristic and on this porous matter formed body, connect the DC high-voltage power supply that negative pole makes the charged one-tenth negative polarity of this porous matter formed body, and, not relative positive polarity with the charged above-mentioned negative polarity that forms of above-mentioned porous matter formed body to the utmost point.
And above-mentioned release needle part has curved surface shape that forms the band circular arc and the terminal part that is used for concentrating the mist that produces diameter 1~50nm.
And, upload at above-mentioned water conservation parts and to hold the aqueous solution that contains the fixedness functional components, discharge the mist that contains above-mentioned fixedness functional components from above-mentioned release needle part.
In addition, above-mentioned release needle part and above-mentioned water conservation parts are by with the porous body of ceramic material, synthetic resin material, metal material or compound formation the more than a kind or 2 kinds in the fiberizing body.
And the water retention of above-mentioned water conservation parts is 30%~150% and sets to such an extent that be higher than the water retention of above-mentioned release needle part, and the last suction speed of the water of above-mentioned release needle part is in 60 seconds.
Above-mentioned release needle part has the clavate shape.
In addition, above-mentioned water conservation parts are uploaded the above-mentioned fixedness functional components of holding, be with vitamins, vitamin derivative, catechuic acid, hyaluronic acid, amino acid, the so organic class water soluble ingredient of collagen, the perhaps material of the combination more than a kind or 2 kinds in the such mineral-type soluble component of silver or salt.
In addition, connect at above-mentioned release needle part under the situation of negative pole of DC high-voltage power supply, moisture in the accommodating container is drawn onto on the above-mentioned water conservation parts, only when this moisture is drawn onto the terminal part of above-mentioned release needle part from the water conservation parts, discharges, only when discharge, discharge above-mentioned mist.
And water conservation under the situation of the negative pole that connects DC high-voltage power supply, and produces electric discharge phenomena to the above-mentioned release needle part of terminal part between vapor in the atmosphere, produce the OH base, but do not produce ozone.
If according to electrostatic atomization apparatus of the present invention, then can discharge the mist of nano-grade size in a large number.And, contain the particulate water of having given functional composition and in air, disperse by making, can effectively obtain deodorizing, bactericidal action.Owing to just do not have,, can not cause harmful effect but not convention is thought to environment so in the mist that discharges, do not have ozone generating fully to the utmost point again.
Description of drawings
Fig. 1 is the explanation synoptic diagram of an embodiment of expression electrostatic atomization apparatus of the present invention.
Fig. 2 is the major part enlarged drawing that expression discharges needle part.
Fig. 3 is that major part is amplified sectional side elevation.
Fig. 4 is the major part enlarged drawing that expression discharges needle part.
Fig. 5 is that major part is amplified sectional side elevation.
Fig. 6 is the major part enlarged drawing that expression discharges needle part.
Fig. 7 is cross-sectional figure.
Fig. 8 is cross-sectional figure.
Fig. 9 is a sectional side elevation.
Figure 10 is the explanation synoptic diagram of expression release test equipment.
Figure 11 is the major part enlarged drawing that expression discharges needle part, (a) be the major part enlarged drawing that expression has the release needle part that the elongate of circular arc terminal part is arranged, (b) be the major part enlarged drawing that expression has the release needle part of circular arc terminal part, (c) be the major part enlarged drawing that expression has the release needle part of triangular taper terminal part, (d) being the major part enlarged drawing that expression has the release needle part of elongated sharp triangular taper terminal part, (e) is the major part enlarged drawing that expression has the release needle part of general planar shape terminal part.
Figure 12 is the chart of the relation of expression conduction time and ascorbic acid concentrations.
Figure 13 is the chart of the relation of expression conduction time and vitamin release concentration.
Figure 14 is the explanation synoptic diagram of expression release test equipment.
The specific embodiment
Below, with reference to the description of drawings embodiments of the present invention.
Fig. 1 is the synoptic diagram of an embodiment of expression electrostatic atomization apparatus of the present invention.The 1st, discharge the mist generating device of the mist of nano-grade size, comprising: absorb and keep containing the aqueous solution of fixedness functional components porous matter formed body 2, to porous matter formed body 2 supply with the aqueous solution that contains the fixedness functional components water supply mechanism 3, make the DC high-voltage power supply 4 of the porous matter formed body 2 charged one-tenth negative polarity of the aqueous solution that is keeping containing the fixedness functional components.
Porous matter formed body 2 comprises: have water imbibition and water-retaining property and be the water conservation parts 11 of flat porous matter, be arranged on the release needle part 12 of the porous matter on the water conservation parts 11 highlightedly.Water conservation parts 11 and release needle part 12 have good water absorbing force and moisture holding capacity, utilize the porous body of ceramic material, synthetic resin material or metal material or corpus fibrosum to form.
Ceramic material as the water conservation parts 11 that constitute porous body or corpus fibrosum, silica, aluminium oxide, magnesia, titanium dioxide, the such single oxide of zirconia are arranged, or mullite, zeolite, bentonite, sepiolite, attapulgite, sillimanite, kaolin, sericite, diatomite, feldspar, potter's clay, silicate compound (perlite, バ Na ミ キ ユ ラ イ ト, sericite etc. are arranged); As natural fiber material, pulp fiber, cotton, wool fiber, flaxen fiber etc. are arranged; As the synthetic resin material, polyester, nylon or staple fibre, urethanes (comprising polyurethane), propylene, polypropylene etc. are arranged; As metal material, stainless steel, copper, titanium, tin, platinum, gold, silver etc. are arranged.
Except that the shape of porous body or corpus fibrosum, can also enumerate ojosa or fluxion structure, or tubulose, sheet, pleated structure etc.Necessary condition is to have good water absorbing force and moisture holding capacity.
Again, discharge needle part 12, form clava (rhabodoid), be with water with the end component that the fine mist of 1~100nm discharges, on the single face (simultaneously) of water conservation parts 11, be provided with many (for example 6~24 etc.) highlightedly.Form clava by discharging needle part 12 like this,, again, discharge needle part 12, can increase the burst size that contains the functional components mist by on water conservation parts 11, being provided with many highlightedly easily from discharging the mist that needle part 12 discharges nano-grade size.Again, discharge the structure of the terminal part 12a of needle part 12, and compare than tabular surface, the structure of taper is more excellent, but terminal part 12a there is no need point to sharp degree, preferably has the circular arc (ball body) of appropriateness.Again, for the terminal part 12a that discharges needle part 12, (with reference to Fig. 2, Fig. 3) compares with the quadrangle that corner angle are arranged, the circle or the ellipse (with reference to Fig. 4, Fig. 5) of band circular arc are more excellent (in a word, compare with the acute angle tip, form more excellent with curved surface), by such formation, can make in the mist of release to comprise a large amount of functional components.Again, each discharges needle part 12 and forms, and diameter is counted mm (tens of mm of 2~4mm) length (for example 30mm) for example.In addition, corresponding to different length that discharges needle part 12 or the shape of diameter, radical and terminal part 12a, the burst size of mist is also different, and its details are investigated in embodiment described later.
And the water retention that discharges needle part 12 is preferably 30~150%, and lower limit is more preferably more than 70%, and the upper limit is more preferably below 110%.And, discharge needle part 12 and preferably have the water absorbing force higher than water conservation parts 11.This is or not to stay in the water conservation parts 11 in order to make the water that is drawn onto on the water conservation parts 11, but inhales on the needle part 12 and supply with to discharging.
As discharging needle part 12, can enumerate ceramic fibre (ceramic wire, glass fibre etc.), organic fiber (polyester fiber, staple fibre, nylon fiber etc.), metallic fiber (stainless steel fibre, copper fiber, titanium fiber etc.) are formed claval example.In addition, also can enumerate ceramic particle or metallic are sintered to claval porous body or foaming bodies such as urethane resin or styrene resin are formed claval example.In addition, under the situation of porous body, compare with the aggregate of fine bubble independently, the consecutive porous body of countless minute apertures is more suitable for the aqueous solution to be passed through.
For the porous matter structure of pottery or resin, metal etc., release performance is by the absorption characteristic decision of water, and particularly the last suction amount of the water of unit interval is very important.These performances are by the water absorption rate decision of the unit interval that porous body had, though 30~100% water absorption rate is fit to any material, if especially according to the different choice of material, then ceramic material preferred 30~80%, resin is preferred 70~110%, metal preferred 10~60%.
And, about claval release needle part 12 (with reference to Fig. 6), following parts for example being arranged, it is a porous body, and the consecutive continuous pore of countless minute apertures (with reference to Fig. 7) is arranged.
Again, the concrete scheme as will discharge needle part 12 and form fibrous architectures the time if pottery, then can be enumerated and will be called the parts or the sintered body of the fiber utilization adhesive moulding of the nature of glass of ceramic wire or silica, mullite crystalline; If synthetic resin then has polyester or fibers such as nylon, propylene, if short fiber then is to use adhesive that they are interweaved or twines ground shaping (with reference to Fig. 8).Again, if long fibre then is they to be gathered cut off use (with reference to Fig. 9) according to operating position again after (pack) becomes any rugosity.According to these fibrous structure, can utilize capillarity to inhale the aqueous solution that contains functional components from water conservation parts 11.
In addition, discharging needle part 12 is drums, and again, the radical of the release needle part 12 that is provided with highlightedly on water conservation parts 11 is not limited to many, also 1 (figure does not show).
Again, water supply mechanism 3, be to take in the aqueous solution that contains the vitamins functional components and utilize capillarity etc. to supply with the mechanism of the aqueous solution that contains functional components to water conservation parts 11 always, in the present embodiment, have an accommodating container (bottle) 13 and an end and be arranged on supply pipe (pipeline) 14 in the accommodating container 13, and water sensor 15 has been set up in the bottom in accommodating container 13.Water sensor 15 is electrically connected on DC high-voltage power supply 4.
As functional components, can enumerate vitamin C (L-ascorbic acid), vitamin C ester (L-magnesium ascorbyl phosphate, the L-STAY-C 50, phosphoric acid Magnesium ascorbate etc.), vitamin A, Cobastab, vitamin D, the vitamin D alpha-lipoic acid, amino acid, tea extraction (catechin, tannin, saponin, theanine, caffeine etc.), hyaluronic acid, collagen, volatile oil (lavender, rosemary,, lemon grass (Cymbopogon citratus), テ イ-ト リ-, Salvia japonica, cloves, oranges and tangerines, shaddock, bay, jasmine etc.), coffee bean, tea, scurvy grass, thujaplicin, chitin, chitosan, these organic class soluble components such as propolis, in addition, if inorganic matter (mineral-type soluble component) then can be enumerated silver or salt.
At this, so-called " functional ", be to instigate living environment comfortable, can improve healthy character, mean at least a in the following character: the character of the smelly property that disappears (deodorizing, decomposition etc.), microbial resistance (antibiotic property, bactericidal properties, biocidal property, fungus resistance, antiviral property etc.), the property loosened (releiving property), moisture retention, non-oxidizability, the harmful atom of expulsion, antistatic behaviour, dust tightness etc.
Again, DC high-voltage power supply 4 is the power supplys that for example produce the DC negative voltage of 4~10kV, and its negative pole is connected on the water conservation parts 11 by lead 16, makes the water conservation parts 11 charged one-tenth negative polarity that keep water or contain the aqueous solution of functional components.Be connected on the water conservation parts 11 by negative pole DC high-voltage power supply 4, utilize that electric current has, trend to flow and concentrate on the character in the place of good conductivity such as the place of terminal point or metal usually in the place of easy discharge, electric current is concentrated to discharging needle part 12.The LED17 that lights when on DC high-voltage power supply 4, setting up energising again.
The production method that contains the functional components mist, use the mist generating device (electrostatic atomization apparatus) 1 that as above constitutes to implement, supply with water or contain the aqueous solution 18 of fixedness functional components to water conservation parts 11 from water supply mechanism 3, connect the negative pole 5 of DC high-voltage power supply 4 on the water conservation parts 11 of the aqueous solution 18 of fixedness functional components and make its charged one-tenth negative polarity keeping water or containing.When making like this when keeping water or containing the charged one-tenth negative polarity of the water conservation parts 11 of the aqueous solution 18 of fixedness functional components, electric current flows to the many terminal part 12a... that discharge needle part 12... that are provided with highlightedly on the water conservation parts 11, cause the nature electric discharge phenomena, utilize this discharge process to produce ion wind, utilize this ion wind, (the invisible fine mist 8... form of 1~100nm) naked eyes is discharged in the air with nano-grade size to make functional components such as water and vitamins.
Porous matter formed body 2, it is the compound formation more than a kind or 2 kinds of ceramic material, synthetic resin material, metal material, from discharging the water that needle part 12 discharges or being subjected to the electrical conductivity or the voltage influence of porous matter formed body 2 particle that contains functional components mist 8..., roughly become the particle mist 8... of 1~100nm, so can utilize the wind of the Air Blast fan of air-conditioning or air purifier etc. to disperse to indoor corner.Again, release needle part 12 is in operation and is in enough moistening state always, as mentioned above, according to the moisture-holding capacity of the porous material that constitute to discharge needle part 12, discharge the difference of the length of needle part 12 and shape, radical or the shape of diameter or terminal part 12a (bar-shaped or drum etc.), the performance of mist 8... that discharges water or functional components is also different.
Again, as having the mist generating device that can obtain the effect of functional components for a long time, also can in mist generating device shown in Figure 11, on porous matter formed body 2, form and carry the device (figure does not show) of holding (fixing) fixedness functional components with water conservation parts 11 and release needle part 12.Specifically, on as the key property that discharges needle part 12 aspect absorption energy and the moisture holding capacity on the good water conservation parts 11, use the adhesive impregnation or the attached function composition of inorganic or organic compound, the controllable functions composition to quantity delivered that discharges needle part 12 or stripping quantity, go up suction speed, thereby the rate of release of controllable functions composition or burst size can obtain the long-term release life-span.
That fixes carries porous body or the corpus fibrosum hold thing, must be good aspect water absorbing force and moisture holding capacity, and particularly under the situation of porous body, vesicular structure is that to connect the hole this point very important.As raw material, can enumerate ceramic fibre (ceramic wire, glass fibre etc.), organic fiber (polyester fiber, staple fibre, nylon fiber etc.), metallic fiber (stainless steel fibre, copper fiber, titanium fiber etc.) are shaped to sheet or block example, in addition also have porous plastid that sintered ceramic particle or metallic form, and foaming bodies such as urethane resin or styrene resin.
Again, as functional components being carried the adhesive that is held on the water conservation parts 11, if inorganic compound, then can enumerate silicate such as lithium metasilicate, potassium silicate, sodium metasilicate, zirconium silicate, calcium silicates, alumina silicate, silester, silica gel, organosilicate, or phosphate such as phosphoric acid, polyphosphoric acid, super polyphosphoric acid, aluminum phosphate, calcium phosphate, magnesium phosphate etc.; If organic compound then can be enumerated methylcellulose or carboxy methyl cellulose, polyvinyl alcohol, urethanes latex, propylene latex, vinyl acetate latex etc.
Functional components to the impregnation of the water conservation parts 11 of porous body or corpus fibrosum, adhere to, undertaken by following manner: dissolving cooperates the material that functional components gets more than a kind or 2 kinds in the binder aqueous solution of inorganic or organic compound, makes water conservation parts 11 this aqueous solution of contact and dry solidifications.
Carry the water conservation parts 11 of holding functional components, play for the effect of the functional components bedding plant that is provided with to discharging needle part 12 the supplied with strippings aqueous solution of functional components, water conservation parts 11 desired characteristics, the 1st is the moisture-holding capacity of the aqueous solution, and the 2nd is to be set as the structure of the aqueous solution of functional components of can having supplied with stripping for a long time.That is, slowly stripping then can be for a long time from discharging needle part 12 release function compositions in water if can utilize the adhesive of inorganic or organic compound to make functional components.
Like this, when supplying with water to carrying the water conservation parts 11 of holding functional components from water supply mechanism 3, and on the water conservation parts 11 of water conservation state, connect the negative pole 5 of DC high-voltage power supply 4 and when making the charged one-tenth negative polarity of water conservation parts 11, electric current flows to the many terminal part 12a... that discharge needle part 12... that are provided with highlightedly on the water conservation parts 11, cause the existing picture of nature discharge, utilize this discharge process to produce particle wind, utilize this particle wind, be fixed on functional components on the water conservation parts 11 and move on one side and discharge needle part 12 (1~100nm) the fine mist 8... that is invisible to the naked eye discharges in a large number with nano-grade size on one side with the form of the aqueous solution.And according to the purposes difference of using, material that can be by selecting to discharge needle part 12, suitably design discharges the length of needle part 12 and shape, the radical of diameter or terminal part 12a, designs water arbitrarily or contains the burst size of the mist of functional components.
Of the present inventionly can be in air discharge the mist generating device 1 of water or functional components with the form of mist 8..., can be applicable in the storehouse of freezer or air-conditioning, air purifier and humidifier etc. tin or filter, fan etc.For example, if in the storehouse of freezer, then be expected to have the freshness that keeps fresh food such as vegetables, fruit, meat and fish or deodorizing, effect such as antibiotic; If air-conditioning, air purifier and humidifier etc., then be expected to have wet skin and suppress the antioxidation of dry skin etc. or moistening effect, indoor deodorizing, antibacterial action etc.And then, if in the automobile or clean room etc., then also can be used as the countermeasure of antistatic.
Again, contain the mist 8 of functional components,, be in the atomic thin state of the wall of can not getting wet etc., so can make it arrive in indoor or the car or in the storehouse of freezer or its corner by the wind of fan etc. because its particle diameter is the nano-grade size of 1~100nm.
And,,, use or therapeutic medical mist generating device thereby be expected to be used for beauty care device so be expected to have the effect that skin is preserved moisture for a long time owing to the mist that can obtain to contain to the high ultra tiny functional components of the impregnability of skin.
Below, in vitamin C mist release test equipment 20 shown in Figure 10, carry out the mist release experiment with regard to the release needle part 12 of the terminal part 12a of different shape, relatively inquire into nanometer mist release performance, its result is described.
Release test equipment 20 has porous matter formed body 2, water supply mechanism 3 and makes the charged device for generating high voltage (DC high-voltage power supply) 4 that becomes negative polarity of porous matter formed body 2, and they are identical with mist generating device 1 structure of Fig. 1.Again, release test equipment 20 comprises: container 30, mist recovery part 29 and the vavuum pump 25 of containing pure water, wherein said mist recovery part 29 has and is designed to the shape that the terminal part 12a side that discharges needle part 12... is surrounded and collects the pars infundibularis (glass system) of mist and be communicated with the pipe portion that links pars infundibularis and container 30, and described vavuum pump 25 makes one-tenth vacuum states in the container 30 and applies the mist attraction mist is bubbled in pure water.Porous matter formed body 2, water supply mechanism 3, vavuum pump 25, container 30, mist recovery part 29 are arranged in the aluminum closed box 28 with the square floor of 1m.
And, as shown in figure 11, prepare the variform release needle part of multiple terminal part 12a 12..., each is discharged needle part 12 be arranged on highlightedly on the water conservation parts 11, nanometer mist release performance is compared evaluation.The release needle part of preparing 12 is a cylindrical shape except that terminal part 12a, and, (with reference to Figure 11 (c)) of (with reference to Figure 11 (b)), the triangular pyramid shape of (with reference to Figure 11 (a)), the circular arc of the elongate of circular arc, (with reference to Figure 11 (d)), (with reference to Figure 11 (e)) of general planar shape of elongated sharp triangular pyramid shape are arranged about terminal part 12a.Each discharges needle part 12 and is made of polyester fiber.
And the radical of the release needle part 12... that is provided with highlightedly on the water conservation parts 11 is made as 9, and third rare system case 28 is arranged on the indoor of 25 ℃ of temperature, humidity 55%.Again, 0.5% ascorbic running water has been dissolved in injection in accommodating container 13.And, the needle part 12 that respectively discharges of Figure 11 (a)~Figure 11 (e) was switched on 6 hours with the DC negative voltage of 8kV.
In experiment, the vitamin C concentration of dissolving in the pure water that is recovered in the container 30 is tried to achieve according to the numerical value of the DPPH radical reduction amount of ascorbic acid.This method is the character (antioxidation) that makes the disappearance of DPPH free radical owing to its concentration when utilizing dissolution of ascorbic acid in DPPH solution, and uses the concentration that contains of spectrophotometer quantitative analysis ascorbic acid.In triangular flask, put into 5cc DPPH is modulated to the material of 0.125mmol/L alcoholic solution, this triangular flask is put into 30 ℃ the tank that is called constant temperature oscillator.At first, measure the peak value of DPPH alcoholic solution, put into the 1cc sample.If non-oxidizability is arranged in the sample, then the free radical of DPPH alcoholic solution reduces, and solution is from the purple yellowing.Deduct peak value at this moment from the peak value of DPPH alcoholic solution, resulting value is the value of expression resistance to oxidation.
Figure 12 is expression conduction time and the chart of the relation of the ascorbic acid concentrations that records, and (a)~(e) in the chart represents the result corresponding with the release needle part 12 of Figure 11 (a)~Figure 11 (e) respectively.If from this graph observer, then decidable goes out, shown in Figure 11 (d), be sharp shape if discharge the shape of the terminal part 12a of needle part 12, or shown in Figure 11 (e), be flat condition, even then prolongation ascorbic acid conduction time also is difficult to improve.On the other hand, judge, terminal part 12a has the release needle part 12 of circular arc to be fit to discharge the mist that contains functional components shown in Figure 11 (a) or Figure 11 (b).
Below, the vitamin C mist release test equipment 20 of use Figure 10 changes the radical, diameter and the material that discharge needle part 12, and nanometer mist burst size is compared research, and result of experiment is described.
About discharging needle part 12, utilize polyester fiber and porous ceramic to form the cylindrical shape parts of diameter 2mm and 4mm respectively.That is, prepare 4 kinds and discharge needle part 12, length all is made as 30mm.And, test on water conservation parts 11, being provided with 9,18 situations that respectively discharge needle part 12 highlightedly.Experimental conditions (indoor temperature and moisture, voltage, the running time of case 28 are set) and evaluation method and Figure 11, experiment illustrated in fig. 12 are the same.
Figure 13 is expression conduction time and the chart of the relation of the vitamin release concentration (ascorbic acid concentrations) that records.Find from this chart, if the material of porous matter formed body 2 is polyester fiber and porous ceramic, even then design water retention roughly the same, also can be variant.
Its reason can think that the difference that discharges the last energy-absorbing power of needle part 12 has played bigger influence.The reason of Kao Lving has like this: under the situation of polyester fiber, being formed as fiber all is the states that gather along its length, water moved with about 30 seconds concerning the length orientation that discharges needle part 12, and it is relative with it, if ceramic fibre, then the matrix of porous body is the mesh state, is not easy to move.
Secondly, find that moving of diameter detailed rules and regulations water is slower, the further tendency that reduces of mist burst size of unit interval is arranged.Again, though can not confirm tendency from the chart of Figure 13, when discharging the humidification ability of needle part 12, because even the vitamin C mist is few, also can be from discharging needle part 12 whole water transpirations, thus if take temperature from humidification, then and polyester fiber system between significance difference little.Because the release needle part of polyester fiber system is with foregoing structure moulding, thus with the ceramic phase ratio, few from rising on every side amount.
When hope utilizes the nanometer mist to obtain deodoriging properties or degerming performance, or discharge in the time of to look to the composition of volatilization power is arranged as the vitamin C of functional components or catechuic acid etc., polyester fiber system proper, and paying attention to humidification power, or when require discharging needle part 12 and having anti-flammability, porous ceramic system proper.
If change the porosity of the porous body of pottery system, then can control water retention to a certain extent, but can not obtain the waterborne suction speed equal with the polyester fiber member made.And when wishing big moisture-holding capacity, the intensity of porous body self will descend, the tendency that exist because of assembling operation or the vibration when carrying etc. fractures or the danger of breaking increases.
Then, in cleaning mist release test equipment 21 shown in Figure 14, just, carried out the damping test to the system of (cleaning) mist of the indoor release nano-grade size that can not fully tackle with air purifier or room air conditioner.
This release test equipment 21, have porous matter formed body 2, water supply mechanism 3, make the device for generating high voltage (DC high-voltage power supply) 4 of porous matter formed body 2 charged one-tenth negative polarity, porous matter formed body 2 is the same with the equipment 20 of Figure 10 with these points in water supply mechanism 3 is arranged on aluminum case 28.And this release test equipment 21 comprises: be arranged on the bottom surface in the case 28 and stir air (axial flow) fan 22 of mist and be arranged in the case 28 and measure humidity and change (digital) humiture data logger 23.The shape of case, experiment condition (indoor air temperature, the humidity of case 28 are set) and Figure 11, experiment illustrated in fig. 12 are the same.
About discharging needle part 12, utilize the cylindrical polyester fiber of length 30mm diameter 3mm to form.And, when the radical of the release needle part 12 that is provided with highlightedly on the water conservation parts 11 is made as 6,12,18,24, applies 5kV, 10kV, these 3 kinds of DC negative voltages of 15kV and test.
And, the relation of the humidity (%) in expression conduction time and the case that records 28 is shown in table 1.According to the result of table 1 as can be known, as the radical of the release needle part 12 of cleaning mist production part, as prediction like that, to the mist amount influence that produces greatly.And, when radical is identical, can confirm to clean the size variation of the generation of mist 8 with the voltage that applies.The numeral % of table 1.
Table 1
Running time (hour) Beginning 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5
24/15kV of pin 55 61 63.0 65 67.0 67 68.0 68 68.0 69 69.0 70 71.0 72.0
18/15kV of pin 55 60 63 64 66 68 68 57 57 57 58 58 69 70
12/15kV of pin 55 58 60 61 62 63 64 65 65 65 69 69 67 67
6/15kV of pin 55 58 67 57 58 58 59 59 59 60 60 60 61 61
24/10kV of pin 55 62 65 67 68 69 70 71 71 72 72 73 73 73
18/10kV of pin 55 60 63 65 66 67 68 68 69 70 70 71 71 71
12/10kV of pin 55 58 60 62 63 64 64 64 65 65 66 68 67 67
6/10kV of pin 55 58 58 57 57 57 58 58 58 59 59 59 60 60
24/5kV of pin 55 50 62 64 66 67 68 68 68 68 69 70 70 70
18/5kV of pin 55 59 61 63 64 65 66 68 68 67 67 67 68 68
12/5kV of pin 55 57 59 60 61 62 62 63 63 63 64 64 64 64
6/5kV of pin 55 55 58 58 57 57 58 58 58 59 59 59 59 60
As described above, electrostatic atomization apparatus of the present invention comprises: the release by porous matter is set on the water conservation parts 11 of porous matter highlightedly parts 12 slightly forms and has a water imbibition, water-retaining property and the porous matter formed body 2 of going up the suction characteristic, make the DC high-voltage power supply 4 of porous matter formed body 2 charged one-tenth negative polarity with on this porous matter formed body 2, being connected negative pole 5, and, not relative positive polarity with the porous matter formed body 2 charged negative polarity that form to the utmost point, so, can cause the nature electric discharge phenomena from the release needle part 12... of porous matter, utilize wind to discharge the mist of nano-grade size in a large number.And, since do not have positive to the utmost point, so in the mist that discharges, do not have ozone generating fully.And, can efficiently functional components be included in interior atomizing.
Again, discharge needle part 12, have curved surface shape that forms the band circular arc and the terminal part 12a that is used for concentrating the mist 8 that produces diameter 1~50nm, so, can prevent that electric charge from too concentrating and produce arc discharge.
Again, owing to constitute, the aqueous solution 18 that contains the fixedness functional components is carried to be held on the water conservation parts 11, contains the mist 8 of fixedness functional components from discharging needle part 12 releases, so can tackle the improvement of various atmospheres.And, can obtain deodorizing, bactericidal action effectively.
Again, owing to discharging needle part 12 and water conservation parts 11 is with the porous body of ceramic material, synthetic resin material, metal material or compound formation the more than a kind or 2 kinds in the fiberizing body, so can realize water absorbing force and good release needle part 12 and the water conservation parts 11 of moisture holding capacity.
Again, because the water retention of water conservation parts is 30%~150% and sets to such an extent that be higher than the water retention that discharges needle part 12, and the last suction speed of the water of release needle part 12 is in 60 seconds, so, the aqueous solution that contains functional components can not stayed water conservation parts 11, and can supply with or stripping to discharging needle part 12.
Again, have the clavate shape owing to discharge needle part 12, so, discharge the mist 8 that contains functional components easily, discharge needle part 12... by being provided with many highlightedly, can increase the burst size that contains functional components mist 8.
Again, because water conservation parts 11 are uploaded the fixedness functional components of holding, be with vitamins, vitamin derivative, catechuic acid, hyaluronic acid, amino acid, the so organic class water soluble ingredient of collagen, the perhaps material of the combination more than a kind or 2 kinds in the such mineral-type soluble component of silver or salt, so, the controllable functions composition to quantity delivered that discharges needle part 12 or stripping quantity, go up suction speed, the rate of release of controllable functions composition or burst size are expected to realize the long-term release life-span.
Again, because under the situation of the negative pole 5 of release needle part 12 connection DC high-voltage power supplies 4, moisture in the accommodating container 13 is drawn onto on the water conservation parts 11, only when being drawn onto the terminal part 12a that discharges needle part 12, water conservation parts 11 discharge at moisture, and only discharge mist 8 in when discharge, so cause the nature electric discharge phenomena from the terminal part 12a that discharges needle part 12, this functional components can be discharged in a large number with mist.Therefore, for example can improve environment or indoor environment in the storehouse of freezer.
Because water conservation arrives the release needle part 12 of terminal part 12a under the situation of the negative pole 5 that connects DC high-voltage power supply 4, and produce electric discharge phenomena between the steam in the atmosphere 6, produce the OH base, but can not produce ozone, so the controllable functions composition to quantity delivered that discharges needle part 12 or stripping quantity, go up suction speed, the rate of release of controllable functions composition or burst size.Again, the mist that the particulate diameter is more little contains many more OH bases, thus utilize odorlessization that chemical reaction realizes or antibiotic, the anti-mildew effect is good.

Claims (9)

1, a kind of electrostatic atomization apparatus, it is characterized in that, comprise: form and have water imbibition, water-retaining property and go up the porous matter formed body (2) of inhaling characteristic and go up by the release needle part (12) that porous matter is set on the water conservation parts (11) of porous matter highlightedly and connect the DC high-voltage power supply (4) that negative pole (5) makes the charged one-tenth negative polarity of this porous matter formed body (2) at this porous matter formed body (2), and, not relative positive polarity with the charged above-mentioned negative polarity that forms of above-mentioned porous matter formed body (2) to the utmost point.
2, electrostatic atomization apparatus as claimed in claim 1 is characterized in that, above-mentioned release needle part (12) has curved surface shape that forms the band circular arc and the terminal part (12a) that is used for concentrating the mist (8) that produces diameter 1~50nm.
3, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that, upload at above-mentioned water conservation parts (11) and to hold the aqueous solution (18) that contains the fixedness functional components, discharge the mist (8) that contains above-mentioned fixedness functional components from above-mentioned release needle part (12).
4, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that above-mentioned release needle part (12) and above-mentioned water conservation parts (11) are by with the porous body of ceramic material, synthetic resin material, metal material or compound formation the more than a kind or 2 kinds in the fiberizing body.
5, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that, the water retention of above-mentioned water conservation parts (11) is 30%~150% and sets to such an extent that be higher than the water retention of above-mentioned release needle part (12), and the last suction speed of the water of above-mentioned release needle part (12) is in 60 seconds.
6, electrostatic atomization apparatus as claimed in claim 1 or 2 is characterized in that, above-mentioned release needle part (12) has the clavate shape.
7, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that, above-mentioned water conservation parts (11) are uploaded the above-mentioned fixedness functional components of holding, be with vitamins, vitamin derivative, catechuic acid, hyaluronic acid, amino acid, the so organic class water soluble ingredient of collagen, the perhaps material of the combination more than a kind or 2 kinds in the such mineral-type soluble component of silver or salt.
8, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that, connect at above-mentioned release needle part (12) under the situation of negative pole (5) of DC high-voltage power supply (4), moisture in the accommodating container (13) is drawn onto on the above-mentioned water conservation parts (11), only discharge when this moisture is drawn onto the terminal part (12a) of above-mentioned release needle part (12) from water conservation parts (11) only discharges above-mentioned mist (8) when discharge.
9, electrostatic atomization apparatus as claimed in claim 1 or 2, it is characterized in that, water conservation to the above-mentioned release needle part (12) of terminal part (12a) under the situation of the negative pole (5) that connects DC high-voltage power supply (4), and produce electric discharge phenomena between the steam in the atmosphere (6), produce the OH base, but do not produce ozone.
CNA2007101063760A 2007-05-28 2007-05-28 Electrostatic atomization apparatus Pending CN101314151A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102538358A (en) * 2012-01-31 2012-07-04 合肥美的荣事达电冰箱有限公司 Refrigeration equipment
CN102824972A (en) * 2011-06-13 2012-12-19 株式会社赛勒芙特 Releasing insertion pin component and electrostatic atomizing device using same
CN102853472A (en) * 2012-02-21 2013-01-02 王登银 Multifunctional electric heater
CN103706498A (en) * 2012-09-28 2014-04-09 有限会社科技新领域 Mist-diffusing pin and electrostatic misting apparatus
CN104428596A (en) * 2012-08-23 2015-03-18 株式会社东芝 Air conditioner
CN104646214A (en) * 2013-11-21 2015-05-27 株式会社铁克诺弗隆帝亚 Releasing inserting pin assembly, mist generating assembly, and static atomizing device using same
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102824972A (en) * 2011-06-13 2012-12-19 株式会社赛勒芙特 Releasing insertion pin component and electrostatic atomizing device using same
CN102538358A (en) * 2012-01-31 2012-07-04 合肥美的荣事达电冰箱有限公司 Refrigeration equipment
WO2013113180A1 (en) * 2012-01-31 2013-08-08 合肥美的荣事达电冰箱有限公司 Refrigeration apparatus
CN102853472A (en) * 2012-02-21 2013-01-02 王登银 Multifunctional electric heater
CN104428596A (en) * 2012-08-23 2015-03-18 株式会社东芝 Air conditioner
CN104428596B (en) * 2012-08-23 2018-05-25 东芝生活电器株式会社 Air conditioner
CN103706498A (en) * 2012-09-28 2014-04-09 有限会社科技新领域 Mist-diffusing pin and electrostatic misting apparatus
CN104646214A (en) * 2013-11-21 2015-05-27 株式会社铁克诺弗隆帝亚 Releasing inserting pin assembly, mist generating assembly, and static atomizing device using same
CN104646214B (en) * 2013-11-21 2019-07-19 株式会社铁克诺弗隆帝亚 Discharge contact pin component, mist generates component and the electrostatic atomization apparatus using it
CN114099966A (en) * 2020-08-24 2022-03-01 株式会社傅心堂 Plasma beauty equipment capable of reducing ozone odor through gas recycling

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