CN101311131A - Sewage handling method and uses thereof - Google Patents

Sewage handling method and uses thereof Download PDF

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CN101311131A
CN101311131A CNA2007100113974A CN200710011397A CN101311131A CN 101311131 A CN101311131 A CN 101311131A CN A2007100113974 A CNA2007100113974 A CN A2007100113974A CN 200710011397 A CN200710011397 A CN 200710011397A CN 101311131 A CN101311131 A CN 101311131A
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sewage
domestic sewage
filter
ozone oxidation
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李培军
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Institute of Applied Ecology of CAS
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Abstract

本发明涉及城市社区污水处理与中水回用技术,具体地说是一种生活污水处理方法及其应用。具体为生活污水经格栅进入集水池,将已去除较大固体颗粒的生活污水通过抽水泵并经过滤器使生活污水抽到预处理后的微氧曝气滤池中降解污水中的有机污染,降解后的水经微氧曝气滤池的出水口自流到臭氧氧化消毒器进行臭氧氧化,氧化后的水经臭氧氧化消毒器出水口自流存放到贮存池;处理后的再生水作为冲洗便池用水,冲厕后直接排入市政污水管网。本发明大幅度降低了处理成本,其工艺操作简单、实用、操作方便,处理效率高、再生水水质优良、回用率高,通过本发明工艺可减少社区污水排放量50%,实现中水回收利用减少水消耗量30-40%。The invention relates to urban community sewage treatment and middle water reuse technology, in particular to a domestic sewage treatment method and its application. Specifically, the domestic sewage enters the sump through the grid, and the domestic sewage from which large solid particles have been removed is pumped through the pump and filtered to the pretreated micro-aerobic aeration filter to degrade the organic pollution in the sewage. The degraded water flows through the outlet of the micro-oxygen aeration filter to the ozone oxidation sterilizer for ozone oxidation, and the oxidized water flows through the outlet of the ozone oxidation sterilizer to the storage pool; the treated regenerated water is used as water for flushing the urinal , directly discharged into the municipal sewage pipe network after flushing the toilet. The invention greatly reduces the treatment cost, and its process operation is simple, practical, convenient to operate, high in treatment efficiency, excellent in regenerated water quality, and high in reuse rate. The process of the invention can reduce community sewage discharge by 50%, and realize the recycling of reclaimed water Reduce water consumption by 30-40%.

Description

一种生活污水处理方法及其应用 A kind of domestic sewage treatment method and its application

技术领域 technical field

本发明涉及城市社区污水处理与中水回用技术,具体地说是一种生活污水处理方法及其应用。The invention relates to urban community sewage treatment and reclaimed water technology, in particular to a domestic sewage treatment method and its application.

背景技术 Background technique

目前,我国城市居民人均生活用水量约为150L/d,其中冲洗厕所用水量占有很大比例,一般单次冲水量为6-8L,按照每日8次计,每日厕所用水约为居民日用水量的40%。应用再生水取代纯净水冲厕,城市生活用水量即可减少40%。At present, the per capita domestic water consumption of urban residents in my country is about 150L/d, of which the water consumption for flushing toilets accounts for a large proportion. Generally, the single flushing volume is 6-8L. Based on 8 times a day, the daily toilet water consumption is about 150L/d. 40% of water usage. Using recycled water instead of pure water for toilet flushing can reduce urban water consumption by 40%.

上世纪90年代,集社区生活污水处理与回用于一体的地下渗滤系统曾在中水回用方面发挥了重要作用,但该技术只适用于社区居民密度较小、建筑物间绿地面积较大的条件。随着城市高层住宅的普及,单位面积居民负荷率成倍提高,人均绿地面积大幅度下降,采用占地面积较大的地下渗滤处理工艺已比较困难。In the 1990s, the underground infiltration system integrating community domestic sewage treatment and reuse played an important role in the reuse of reclaimed water, but this technology is only suitable for communities with low density of residents and large green areas between buildings. big condition. With the popularization of high-rise residential buildings in cities, the load rate of residents per unit area has doubled, and the per capita green area has dropped significantly. It has become more difficult to adopt underground infiltration treatment processes that occupy a large area.

现有的社区污水处理与中水回用工艺,一般均采用污水全部收集、处理、回用的方法,当中水用于冲洗厕所后即进入下一个循环,使得污水可生化性随时间推移而变坏,增加了处理难度与成本。同时随着居民生活水平提高,人均水消耗量逐步增加,污水COD浓度呈下降趋势,对经济技术指标造成不利影响。The existing community sewage treatment and reclaimed water reuse process generally adopts the method of collecting, treating and reusing all the sewage. The reclaimed water enters the next cycle after being used to flush the toilet, so that the biodegradability of the sewage changes with time. Bad, increased processing difficulty and cost. At the same time, with the improvement of residents' living standards, the per capita water consumption gradually increases, and the COD concentration of sewage shows a downward trend, which has a negative impact on economic and technical indicators.

基于上述考虑,从根本上改变现有社区污水就地处理与就地回用工艺,研究建立在新理念基础上的小区污水处理与回用技术,将具有良好的应用前景与巨大的社会经济与环境效益。Based on the above considerations, fundamentally changing the existing community sewage treatment and reuse process on site, and researching community sewage treatment and reuse technology based on new concepts will have good application prospects and huge social, economic and social benefits. environmental benefits.

一般家庭生活用水可分为厨房烹饪用水、日常盥洗用水、洗衣用水与洗浴用水以及冲厕用水四种类型。其中冲厕用水量占总用水量的40%,但其污染负荷则占总污染负荷的80%。如将前三种污水单独收集处理,则不但其处理难度大大降低,处理后产生的中水可基本上满足冲厕需要。Generally, household water can be divided into four types: kitchen cooking water, daily toilet water, laundry water, bath water, and toilet flushing water. Among them, the water consumption for toilet flushing accounts for 40% of the total water consumption, but its pollution load accounts for 80% of the total pollution load. If the first three kinds of sewage are collected and treated separately, not only the difficulty of treatment will be greatly reduced, but the reclaimed water produced after treatment can basically meet the needs of toilet flushing.

根据我国城市小区建筑发展趋势与小区水处理与回用的实际情况,在长期研究基础上,提出了小区污水处理与回用结合的新型技术。According to the development trend of urban community buildings in my country and the actual situation of water treatment and reuse in the community, on the basis of long-term research, a new technology for the combination of sewage treatment and reuse in the community is proposed.

发明内容 Contents of the invention

本发明的目的是提供一种经济、实用、高效、环保并且适用广泛的生活污水处理工艺及其应用。The object of the present invention is to provide an economical, practical, efficient, environmentally friendly and widely applicable domestic sewage treatment process and its application.

为了实现上述目的,本发明的技术方案是:In order to achieve the above object, technical scheme of the present invention is:

处理方法:生活污水经格栅1进入集水池2,将已去除较大固体颗粒的生活污水通过抽水泵3并经过滤器4使生活污水抽到预处理后的微氧曝气滤池5中降解污水中的有机污染,降解后的水经微氧曝气滤池5的出水口自流到臭氧氧化消毒器7进行臭氧氧化,氧化后的水经臭氧氧化消毒器7出水口自流存放到贮存池10;Treatment method: the domestic sewage enters the sump 2 through the grid 1, and the domestic sewage from which larger solid particles have been removed passes through the pump 3 and passes through the filter 4 to pump the domestic sewage into the pretreated micro-aerobic aeration filter 5 for degradation For organic pollution in sewage, the degraded water flows automatically through the outlet of the micro-oxygen aeration filter 5 to the ozone oxidation sterilizer 7 for ozone oxidation, and the oxidized water is stored in the storage pool 10 through the outlet of the ozone oxidation sterilizer 7 ;

其中,微氧曝气滤池5的预处理:微氧曝气滤池5内投放占该池容积2/3的滤料,同时接种降解菌种,接种量按照待处理生活污水体积的百分比计为2%-5%,并通入氧气,氧气流速0.010m3/min-0.012m3/min,使其形成一层生物膜。Among them, the pretreatment of the micro-aerobic aeration filter 5: the filter material accounting for 2/3 of the volume of the pool is put into the micro-aerobic aeration filter 5, and the degradation bacteria are inoculated at the same time, and the inoculation amount is calculated according to the percentage of the domestic sewage volume to be treated It is 2%-5%, and oxygen is passed through, and the flow rate of oxygen is 0.010m 3 /min-0.012m 3 /min, so that a layer of biofilm is formed.

所述降解菌种为芽孢杆菌(Bacillus sp.)、产碱杆菌(Alcaligenes sp.)和动胶杆菌(Zoogloea sp.),其体积份数比为1∶1∶1;其中:所述滤料为活性焦碳和蛭石,其按重量比为1∶1。The degrading bacteria species are Bacillus sp., Alcaligenes sp. and Zoogloea sp., and the volume-to-number ratio is 1:1:1; wherein: the filter material It is activated coke and vermiculite in a weight ratio of 1:1.

微氧曝气滤池5形成生物膜时,滤料和降解菌种在生活污水内,室温下进行培养,每隔4-6天换一次培养滤料和降解菌种的用水,每次换水量占培养滤料和降解菌种所用水总水量的50%-60%,培养25-40天,即形成一层生物膜。When the micro-aerobic aeration filter 5 forms a biofilm, the filter material and the degradation bacteria are cultivated in domestic sewage at room temperature, and the water used for cultivating the filter material and the degradation bacteria is changed every 4-6 days, and the amount of water changed each time Accounting for 50%-60% of the total water used for cultivating filter materials and degrading strains, a layer of biofilm is formed after culturing for 25-40 days.

水力停留时间4-6h。反冲洗周期20天;臭氧氧化消毒器7内的臭氧浓度为40-100mg/L。The hydraulic retention time is 4-6h. The backwash cycle is 20 days; the ozone concentration in the ozone oxidation sterilizer 7 is 40-100mg/L.

处理方法的应用:城市居民小区、宾馆、学校;同时处理后的污水用于冲洗便池。Application of treatment methods: urban residential quarters, hotels, schools; at the same time, the treated sewage is used for flushing urinals.

本发明的原理:采用微氧曝气滤池是将空压机产生的氧用强制的方法溶解到混合污水中,曝气除起供氧外,还起搅拌作用,保证与吸附在滤料表面上的微生物充分接触,并快速降解。上流式生物滤池,氧气与污水均从滤池底部进入,其目的是有利于污水中的污染物与微生物充分接触,保证处理效果。同时生活污水中较难降解的有机污染物来源于洗涤水的表面活性剂和烹饪水的油脂。本发明的微氧曝气滤池内接种经培养、驯化的洗涤剂和动植物油高效降解菌剂,待滤料表面形成一层生物膜。生物膜具有对有机污染物的降解活性,生物膜形成的成功与否关系到污染物的去除效果。并且为保证经微氧曝气滤池处理后的再生水符合中水标准,采用臭氧消毒对其进行深度处理,以进一步降低COD负荷并杀死水中病原菌。臭氧浓度控制在40-100mg/L范围,可保证出水中总大肠菌数小于3个

Figure A20071001139700041
L-1,符合中水指标要求。The principle of the present invention: the use of micro-oxygen aeration filter is to dissolve the oxygen produced by the air compressor into the mixed sewage in a forced way. In addition to supplying oxygen, the aeration also plays a stirring role to ensure and adsorb on the surface of the filter material. Fully contact with microorganisms on the surface, and quickly degrade. In the upflow biological filter, both oxygen and sewage enter from the bottom of the filter, the purpose of which is to facilitate the full contact between the pollutants in the sewage and the microorganisms, and ensure the treatment effect. At the same time, the organic pollutants that are difficult to degrade in domestic sewage come from the surfactant in washing water and the oil in cooking water. The micro-oxygen aeration filter of the present invention is inoculated with cultured and domesticated detergent and animal and vegetable oil high-efficiency degradation bacterial agents, and a layer of biofilm is formed on the surface of the filter material. Biofilm has the ability to degrade organic pollutants, and the success of biofilm formation is related to the removal effect of pollutants. And in order to ensure that the regenerated water treated by the micro-oxygen aeration filter meets the standard of reclaimed water, ozone disinfection is used for advanced treatment to further reduce the COD load and kill pathogenic bacteria in the water. The ozone concentration is controlled in the range of 40-100mg/L, which can ensure that the total number of coliform bacteria in the effluent water is less than 3
Figure A20071001139700041
L -1 , in line with the requirements of reclaimed water indicators.

与现有技术相比,本发明具有如下优点:Compared with prior art, the present invention has following advantage:

1.本发明工艺简单可行、实用、操作方便,处理效率高、再生水水质优良、回用率高的优点,本发明半开放式循环可有效避免污水可生化性变差的问题,实现系统长期稳定运行,通过本发明工艺可减少社区污水排放量50%,实现中水回收利用减少水消耗量30-40%。1. The process of the present invention is simple, feasible, practical, easy to operate, high in treatment efficiency, excellent in regenerated water quality, and high in reuse rate. The semi-open cycle of the present invention can effectively avoid the problem of poor biodegradability of sewage and achieve long-term stability of the system In operation, the process of the invention can reduce community sewage discharge by 50%, realize reclaimed water recycling and reduce water consumption by 30-40%.

2.本发明微氧曝气滤池中具有对有机污染物有降解活性的膜,可保证生活污水中的污染物洗涤剂类和油脂类污染物去除效果。2. The micro-aerobic aeration filter of the present invention has a membrane with degradation activity for organic pollutants, which can ensure the removal effect of pollutant detergents and grease pollutants in domestic sewage.

3.对污染物处理比较彻底,本发明利用上流式微氧过滤系统、过滤器、臭氧氧化消毒器技术等多级处理,处理效率高,使再生水水质优良。3. The treatment of pollutants is relatively thorough. The present invention utilizes multi-stage treatment such as an upflow micro-oxygen filtration system, filter, and ozone oxidation sterilizer technology, so that the treatment efficiency is high and the regenerated water quality is excellent.

3.本发明可根据城市居民小区、宾馆学校等具体情况设计不同规模,例如300人当量,可设计集水池、微氧曝气滤池和贮存池容积15m3,其结构简单、成本低廉、适应性广。3. The present invention can design different scales according to the specific conditions of urban residential areas, hotels and schools, etc., such as 300 equivalents, and can design a water collection tank, a micro-oxygen aeration filter tank and a storage tank with a volume of 15m 3 , which is simple in structure, low in cost, and adaptable. wide range.

4.采用本发明将城市生活污水,例如收集的厨房烹饪用水、日常盥洗用水、洗衣用水与洗澡用水处理后再利用,一方面减少了新鲜自来水用量,同时也减少了污水排放量。对于城市居民小区、宾馆、学校、饭店等具有良好的经济效益和广泛的应用前景。4. Using the present invention to reuse urban domestic sewage, such as collected kitchen cooking water, daily washing water, laundry water and bathing water, on the one hand reduces the consumption of fresh tap water, and also reduces the amount of sewage discharge. It has good economic benefits and broad application prospects for urban residential quarters, hotels, schools, restaurants, etc.

附图说明 Description of drawings

图1为本发明城市社区生活污水处理与回用工艺流程图。Fig. 1 is the flow chart of the present invention for urban community domestic sewage treatment and reuse process.

图2为本发明生活污水处理工艺流程图。Fig. 2 is a flow chart of the domestic sewage treatment process of the present invention.

1.格栅,2.集水池,3.抽水泵,4.过滤器,5.微氧曝气滤池,6.空压机,7.臭氧氧化消毒器,8.臭氧发生器,9.氧气瓶,10.贮存池1. Grille, 2. Pool, 3. Suction pump, 4. Filter, 5. Micro-oxygen aeration filter, 6. Air compressor, 7. Ozone oxidation sterilizer, 8. Ozone generator, 9. Oxygen cylinders, 10. Storage pools

具体实施方式 Detailed ways

下面结合实施例对本发明做进一步详细说明。The present invention will be described in further detail below in conjunction with the examples.

实施例1Example 1

微氧曝气滤池5的预处理:在微氧曝气滤池5内投放占其容积2/3的滤料活性焦碳和蛭石,而后投加生活污水使滤料和降解菌种在其环境,并在室温条件下生长,其接种降解菌种时,按体积百分比计,降解菌种接种量为:滤料和降解菌种生长时投加的生活污水体积的2.5%,并间歇式通氧气,氧气流速0.012m3/min,在室温20℃-28℃条件下运行,每隔5天换一次培养滤料和降解菌种所用的水,换水量占培养滤料和降解菌种所用水总水量的50%,经过35天运行即形成一层生物膜:其中:活性焦碳和蛭石之间的重量比为1∶1,并且微氧曝气滤池5内水位高于滤料;所述降解菌种为芽孢杆菌(Bacillus sp.)、产碱杆菌(Alcaligenes sp.)和动胶杆菌(Zoogloeasp.),其体积份数比为1∶1∶1;其中:所述滤料为活性焦碳和蛭石,其按重量比为1∶1。Pretreatment of the micro-oxygen aeration filter 5: put filter material activated coke and vermiculite accounting for 2/3 of its volume in the micro-oxygen aeration filter 5, and then add domestic sewage to make the filter material and degradation bacteria in the micro-oxygen aeration filter 5 Its environment, and grows under the room temperature condition, when it inoculates the degrading strain, by volume percentage, the inoculum amount of the degrading strain is: 2.5% of the domestic sewage volume added when the filter material and the degrading strain grow, and intermittently Oxygen flow, oxygen flow rate 0.012m 3 /min, operating at a room temperature of 20°C-28°C, changing the water used for cultivating filter materials and degrading bacteria every 5 days, the amount of water exchanged accounted for the cultivation of filter materials and degrading bacteria 50% of the total amount of water is used, and a layer of biofilm is formed after 35 days of operation: wherein: the weight ratio between activated coke and vermiculite is 1: 1, and the water level in the micro-aerobic aeration filter tank 5 is higher than the filter material ; The degrading strains are Bacillus sp., Alcaligenes sp. and Zoogloeasp., and the volume-to-number ratio is 1:1:1; wherein: the filter material It is activated coke and vermiculite in a weight ratio of 1:1.

分别取厨房烹饪污水、盥洗污水、洗衣污水与洗浴污水各2L,共8L,经过间隙为2mm的不锈钢材质的格栅1,去除较大固体颗粒后污水进入集水池2,此时集水池2中污水水质综合指标CODcr为52mg/L,BOD5为29mg/L,pH为7.6,SS为18mg/L(参见表1)进入集水池2的污水通过抽水泵3再经过滤器4使生活污水抽到微氧曝气滤池5中降解污水中的有机污染,并通过空压机6向微氧曝气滤池5内充氧,降解后的水经微氧曝气滤池5的出水口自流到臭氧氧化消毒器7进行臭氧氧化,氧气瓶9中氧气通过臭氧发生器8产生臭氧,该气体通过流量计进入臭氧氧化消毒器7内对其中降解后的水进行氧化消毒,调节臭氧浓度为40-100mg/L,反应时间为20min。氧化后的水经臭氧氧化消毒器7出水口自流存放到贮存池10,贮存池10设计水量调节器,当处理的水位到达设计水位时,贮存池10停止接收,当水位不足时,自来水自动补充。Take 2L each of kitchen cooking sewage, washing sewage, laundry sewage and bathing sewage, totaling 8L, pass through the stainless steel grid 1 with a gap of 2mm, remove larger solid particles, and enter the sump 2. At this time, the sewage in the sump 2 The comprehensive index of sewage water quality CODcr is 52mg/L, BOD 5 is 29mg/L, pH is 7.6, SS is 18mg/L (see Table 1). The organic pollution in the sewage is degraded in the micro-oxygen aeration filter 5, and oxygenated into the micro-oxygen aeration filter 5 through the air compressor 6, and the degraded water flows through the water outlet of the micro-oxygen aeration filter 5 to the The ozone oxidation sterilizer 7 carries out ozonation, and the oxygen in the oxygen bottle 9 generates ozone through the ozone generator 8, and the gas enters the ozone oxidation sterilizer 7 through a flow meter to oxidize and sterilize the degraded water therein, and adjust the ozone concentration to be 40- 100mg/L, the reaction time is 20min. The oxidized water is automatically stored in the storage pool 10 through the outlet of the ozone oxidation sterilizer 7. The storage tank 10 is designed with a water volume regulator. When the treated water level reaches the design water level, the storage tank 10 stops receiving. When the water level is insufficient, tap water is automatically replenished. .

其中,过滤器材料为石英砂;菌种为经培养、驯化后的降解表面活性剂和动植物油脂的优势降解菌;污水泵提水量6m3/h。微氧曝气滤池提水与充氧均采用上流式,空压机6充氧的氧气流速0.018m3/min,水力停留时间5.5h,反冲洗周期为20d。Among them, the filter material is quartz sand; the strains are cultivated and domesticated degrading surfactants and the dominant degrading bacteria of animal and vegetable oils; the water pumping capacity of the sewage pump is 6m 3 /h. The micro-aerobic aeration filter adopts the upflow type for water extraction and oxygenation. The oxygen flow rate of the air compressor 6 for oxygenation is 0.018m 3 /min, the hydraulic retention time is 5.5h, and the backwash cycle is 20d.

检测贮存池10的水质:CODcr 4.6mg/L,BOD5 1.6mg/L,总大肠杆菌2个/L,粪便大肠杆菌未检出,SS 2.1mg/L,pH7(参见表1)。并且处理后的再生水水质指标符合城市生活杂用水水质标准(GB-T18920-2002),完全可作为冲厕所用水,并且冲厕所后用水即可直接排入城市管网。Detect the water quality of the storage tank 10: CODcr 4.6mg/L, BOD 5 1.6mg/L, total E. coli 2/L, fecal E. coli not detected, SS 2.1mg/L, pH7 (see Table 1). Moreover, the quality index of the treated reclaimed water complies with the water quality standard for urban domestic miscellaneous water (GB-T18920-2002), and can be used as water for flushing toilets, and the water can be directly discharged into the urban pipe network after flushing the toilets.

表1Table 1

*城市生活杂用水水质标准(GB-T18920-2002)。*Water quality standard for urban miscellaneous water (GB-T18920-2002).

Claims (6)

1. domestic sewage processing method, it is characterized in that: sanitary sewage enters water collecting basin (2) through grid (1), make sanitary sewage be extracted into the organic contamination in the degradation of sewage in pretreated little oxygen aerating filter (5) by lift pump (3) and through filter (4) sanitary sewage of removing big solid particulate, water after the degraded flows automatically to ozone oxidation sterilizing device (7) through the water outlet of little oxygen aerating filter (5) and carries out ozone oxidation, and the water after the oxidation is stored in storage pool (10) through the gravity flow of ozone oxidation sterilizing device (7) water outlet;
Wherein, the pre-treatment of little oxygen aerating filter (5): throw in the filtrate that accounts for this pool volume 2/3 in little oxygen aerating filter (5), the bacterial classification of inoculation degraded simultaneously, inoculum size is counted 2%-5% according to the per-cent of pending sanitary sewage volume, and aerating oxygen, oxygen gas flow rate 0.010m 3/ min-0.012m 3/ min makes it form one deck microbial film.
2. by the described domestic sewage processing method of claim 1, it is characterized in that: described degraded bacterial classification is genus bacillus, Alcaligenes and moving glue bacillus, and its volume parts ratio is 1: 1: 1; Wherein: described filtrate is activated carbon char and vermiculite, and it is 1: 1 by weight.
3. by the described domestic sewage treatment process of claim 1, it is characterized in that: when little oxygen aerating filter (5) forms microbial film, filtrate and degraded bacterial classification are in sanitary sewage, cultivate under the room temperature, changed the water of once cultivating filtrate and degraded bacterial classification every 4-6 days, each quantity of exchanged water accounts for the 50%-60% that cultivates filtrate and the used water Total Water of degraded bacterial classification, cultivates 25-40 days, promptly forms one deck microbial film.
4. by the described domestic sewage processing method of claim 1, it is characterized in that: hydraulic detention time 4-6h.Backwashing period 20 days.
5. by the described domestic sewage processing method of claim 1, it is characterized in that: the ozone concn in the ozone oxidation sterilizing device (7) is 40-100mg/L.
6. the application of the described domestic sewage processing method of claim 1 is characterized in that: city resident sub-district, hotel, school; Sewage after handling simultaneously is used for flushing toilet bowl.
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