CN101306592A - Synthetic resin bilayer sheet - Google Patents

Synthetic resin bilayer sheet Download PDF

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Publication number
CN101306592A
CN101306592A CNA2007101492889A CN200710149288A CN101306592A CN 101306592 A CN101306592 A CN 101306592A CN A2007101492889 A CNA2007101492889 A CN A2007101492889A CN 200710149288 A CN200710149288 A CN 200710149288A CN 101306592 A CN101306592 A CN 101306592A
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China
Prior art keywords
synthetic resin
resin layer
covering property
sheet
color pigments
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CNA2007101492889A
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Chinese (zh)
Inventor
户田直利
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King Jim Co Ltd
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King Jim Co Ltd
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Publication of CN101306592A publication Critical patent/CN101306592A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents

Abstract

The invention provides a synthetic resin double-layer sheet which can be manufactured easily and inexpensively and has well color rendering and shielding property. The inventive synthetic resin double-layer sheet is integrally formed by laminating a first synthetic resin layer (12) and a second synthetic resin layer (13), the first synthetic resin layer (12) is formed by synthetic resin colorized by color pigments and having transparency, the second synthetic resin layer (13) is formed by synthetic resin which is colorized by the color pigments with transparency and which has shielding property. It is possible to improve the color rendering based on the first synthetic resin layer (12) and the first synthetic resin layer (12) based on the second synthetic resin layer (13) by laminating the two layers of synthetic resins. Furthermore, the color rendering of the first synthetic resin layer (12) can be enhanced once white pigment having the shielding property is used to colorize the second synthetic resin layer (13). Besides, on account of the integral forming that is implemented only by laminating the first synthetic resin layer (12) and the second synthetic resin layer (13), the invention can be manufactured easily and inexpensively.

Description

Synthetic resin bilayer sheet
Technical field
The present invention relates to by sheet and have the synthetic resin bilayer sheet that the sheet of covering property forms with transparency.
Background technology
For example being used for, the thickness of the synthetic resin sheet of file such as transparent file folder is preferably 0.4mm~2.0mm, but, synthetic resin with this ranges of thicknesses does not have the property of covering, synthetic resin sheet can not be guaranteed covering property, thereby, this synthetic resin sheet is contained undertaken painted by color pigments beyond the white and the mixed material of Chinese white with covering property for colour rendering that improves this synthetic resin sheet and covering property.
, in the described synthetic resin sheet, contain Chinese white with covering property of raising herein, because the existence of Chinese white, the color contamination that the color pigments beyond the white forms is turbid, the colour rendering variation.
In addition, when only improving covering property, need a large amount of color pigments with the color pigments beyond the white, in the color pigments and Chinese white beyond the white, color pigments price height beyond the white is not so aspect manufacturing cost, the color pigments beyond the white is preferred.
So, for for example being attached to the cosmetic sheet of using on building materials or the furniture etc., known have a following cosmetic sheet (for example referring to patent documentation 1): its use does not have the synthetic resin sheet of covering property as substrate sheets, by for example intaglio printing or serigraphy etc. white field printing printed layers that is formed by the printing-ink that contains Chinese white and the metal field printing printed layers that is formed by the printing-ink that contains metal dust are set on this substrate sheets, improve colour rendering and covering property with this, and pattern printed layers such as wood grain for example further is set improves aesthetic appearance.
Patent documentation 1: the spy opens flat 5-64870 communique
But, form a plurality of layers by the special printing ink of printing on synthetic resin sheet in the above-mentioned cosmetic sheet, so compare with the existing synthetic resin sheet that is used for file, it is difficult for making the manufacturing cost height.
In addition, for example be used for the synthetic resin sheet of file such as transparent file folder as long as colour rendering and covering property are good, and do not require the aesthetic appearance as the cosmetic sheet of above-mentioned patent documentation 1.
Summary of the invention
In view of this viewpoint, the invention provides a kind of synthetic resin bilayer sheet of can be easily and making at an easy rate, and its colour rendering and covering property are good.
The technical scheme of scheme 1 record be by first synthetic resin layer that forms through the painted synthetic resin of color pigments with transparency and by second synthetic resin layer that forms through the painted synthetic resin of the color pigments with covering property with covering property through lamination and integrated synthetic resin bilayer sheet.
The technical scheme of scheme 2 record be first synthetic resin layer that forms by water white synthetic resin and by second synthetic resin layer that forms through the painted synthetic resin of the color pigments with covering property through lamination and integrated synthetic resin bilayer sheet.
The technical scheme of scheme 3 record is as described in the technical schemes of scheme 1 or 2 records, and wherein, described second synthetic resin layer is by forming through the painted synthetic resin with covering property of the Chinese white with covering property.
The technical scheme of scheme 4 record is as described in the technical scheme of scheme 1~3 arbitrary scheme record, and wherein, described first synthetic resin layer and second synthetic resin layer are 5: 5 to 7: the 3 described synthetic resin bilayer sheets of formation with thickness proportion.
The technical scheme of scheme 5 record is as described in the technical scheme of scheme 1~3 arbitrary scheme record, and wherein, described first synthetic resin layer is formed with recess on the surface.
The technical scheme of scheme 6 record is as described in the technical scheme of scheme 5 records, and wherein, described first synthetic resin layer and second synthetic resin layer are 6: 4 to 7: the 3 described synthetic resin bilayer sheets of formation with thickness proportion.
Technical scheme according to scheme 1 record, by lamination respectively the hang oneself first painted synthetic resin layer and second synthetic resin layer and one-body molded, thereby described first synthetic resin layer develops the color easily, can improve colour rendering, and can improve covering property by described second synthetic resin layer.
In addition, owing to do not mix the color pigments that contains in described second synthetic resin layer in the color pigments that in described first synthetic resin layer, contains, so can make described first synthetic resin layer colour developing with more a spot of color pigments, thereby can make at an easy rate, and, only need these synthetic resin layer laminations can easily be made synthetic resin bilayer sheet.
According to the technical scheme of scheme 2 records, next one-body molded by water white first synthetic resin layer of lamination and second synthetic resin layer with covering property, can improve covering property based on described second synthetic resin layer.And, painted owing to described first synthetic resin layer not being carried out, so can in the true qualities of described second synthetic resin layer of reflection, make at an easy rate.
Technical scheme according to scheme 3 records, second synthetic resin layer is painted by the Chinese white with covering property, so the color of described first synthetic resin layer is not subject to the influence of the color of described second synthetic resin layer, the color of described first synthetic resin layer manifests easily, so can improve colour rendering.
Technical scheme according to scheme 4 records, first synthetic resin layer and second synthetic resin layer are 5: 5 to 7: the 3 described synthetic resin bilayer sheets of formation with thickness proportion, so based on the colour rendering of described first synthetic resin layer and all good based on the covering property of described second synthetic resin layer, and it is bad to prevent to produce when one-body molded moulding.
According to the technical scheme of scheme 5 records, the surface of first synthetic resin layer is formed with recess, with this for example mark or pattern etc. can be set, and can improve versatility.
In addition, because first synthetic resin layer has the transparency,, can obtain three-dimensional visual effect so the shade of this recess is reflected the surface at described second synthetic resin layer.
Technical scheme according to scheme 6 records, first synthetic resin layer and second synthetic resin layer are 6: 4 to 7: the 3 described synthetic resin bilayer sheets of formation with the ratio of thickness, so based on the colour rendering of described first synthetic resin layer and all good based on the covering property of described second synthetic resin layer, and it is good that the recess that forms on the surface of described first synthetic resin layer reflects in the hatching effect of described second synthetic resin layer.
Description of drawings
Fig. 1 is the sectional view that the synthetic resin bilayer sheet of first embodiment that the present invention relates to is described.
Fig. 2 is the sectional view that the synthetic resin bilayer sheet of second embodiment that the present invention relates to is described.
Symbol description
11 synthetic resin bilayer sheets
12 first synthetic resin layers
13 second synthetic resin layers
14 recesses
The specific embodiment
Below, describe the formation of first embodiment of the present invention in detail with reference to Fig. 1.
Synthetic resin bilayer sheet 11 is the synthetic resin sheets that are used for file such as transparent file folder for example, and it is through lamination and integrated synthetic resin bilayer sheet by first synthetic resin layer 12 with transparency and second synthetic resin layer 13 with covering property.
First synthetic resin layer 12 contains color pigments, thereby have color, be in the colored transparent state, when first synthetic resin layer 12 contains a large amount of color pigments, also can improve covering property by color pigments, still, the price comparison height of color pigments, and owing to,, first synthetic resin layer 12 gets final product so being in the colored transparent state by first synthetic resin layer 12 and second synthetic resin layer, 13 laminations can be improved covering property.
Second synthetic resin layer 13 contains the color pigments with covering property, is in through the painted state with covering property.Herein, as long as the color pigments that second synthetic resin layer 13 contains has the property of covering, then do not limited, making second synthetic resin layer 13 contain Chinese white carries out under the painted situation, with first synthetic resin layer 12 and second synthetic resin layer, 13 laminations the time, the color of first synthetic resin layer 12 is difficult for by the influence of the color of second synthetic resin layer 13, so can improve the colour rendering based on first synthetic resin layer 12, so preferred second synthetic resin layer contains Chinese white.
In addition, the surface of first synthetic resin layer 12 is surfaces of synthetic resin bilayer sheet 11, can carry out for example processing such as embossing processing or minute surface fine finishining to it as required.
For with first synthetic resin layer 12 and second synthetic resin layer, 13 laminations and the one-body molded synthetic resin bilayer sheet that obtains 11, when it for example is used for files such as transparent file folder, preferred its thickness after one-body molded is 0.4mm~2.0mm, but to the thickness of synthetic resin bilayer sheet 11 without limits, can carry out suitable setting according to application target etc.
Herein, the thickness ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 5: 5 to 7: 3 o'clock, based on the colour rendering of first synthetic resin layer 12 and all good based on the covering property of second synthetic resin layer 13, and it is bad to prevent that moulding takes place when one-body molded, so the ratio of the thickness of preferred first synthetic resin layer 12 and second synthetic resin layer 13 is 5: 5 to 7: 3.Particularly the thickness ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 7: 3 o'clock, and the balance of colour rendering and covering property is best, so be particularly preferred.
In addition, in this embodiment, first synthetic resin layer 12 has been taked to contain color pigments and the formation that has color, and still, this first synthetic resin layer 12 also can not contain color pigments, takes water white formation.
Then, effect and the effect to above-mentioned first embodiment describes.
Synthetic resin bilayer sheet 11 is with first synthetic resin layer 12 and second synthetic resin layer, 13 laminations and one-body molded obtaining, so first synthetic resin layer 12 has color because of containing color pigments, be in the colored transparent state, second synthetic resin layer 13 has color because of containing the color pigments with covering property, is in the state with covering property.
For this synthetic resin bilayer sheet 11, by having lamination first synthetic resin layer on second synthetic resin layer 13 of covering property, thereby first synthetic resin layer 12 develops the color easily, can improve colour rendering, and can utilize second synthetic resin layer 13 to improve covering property.
In addition, before lamination first synthetic resin layer 12 and second synthetic resin layer 13, make it contain color pigments separately and have color, so in the color pigments that first synthetic resin layer 12 contains, do not mix the color pigments that second synthetic resin layer 13 contains with covering property, thereby, the color pigments that first synthetic resin layer 12 contains develops the color easily, can make 12 colour developings of first synthetic resin layer with more a spot of pigment, so can make at an easy rate.
In addition since only need first synthetic resin layer 12 and second synthetic resin layer, 13 laminations are carried out one-body molded, so can easily make.
Moreover, carry out extrusion molding by synthetic resin that will form first synthetic resin layer 12 and the synthetic resin that forms second synthetic resin layer 13, thereby one-body molded is synthetic resin bilayer sheet 11, wherein, the synthetic resin of described formation first synthetic resin layer 12 is the water white transparency synthetic resin that contains the colored transparent synthetic resin of color pigments or do not contain color pigments, and the synthetic resin of described formation second synthetic resin layer 13 is the synthetic resin that contains the color pigments with covering property.
First synthetic resin layer 12 does not contain color pigments, take under the situation of water white transparency state, first synthetic resin layer 12 and second synthetic resin layer 13 lamination mutually carry out when one-body molded, can improve covering property by second synthetic resin layer 13, and because first synthetic resin layer does not contain color pigments, so can make at an easy rate.
At this moment, because first synthetic resin layer 12 is water white, so can directly reflect the true qualities of the color pigments that second synthetic resin layer 13 contains in the colour developing with covering property.
When the color pigments with covering property that second synthetic resin layer contains is Chinese white or black pigment, covering property is good, so be preferred, among these, if making second synthetic resin layer 13 contain Chinese white carries out painted to it, then at first synthetic resin layer 12 and second synthetic resin layer mutually during lamination, the color of first synthetic resin layer 12 is not vulnerable to the influence of the color of second synthetic resin layer 13, can improve the colour rendering based on first synthetic resin layer 12.
First synthetic resin layer 12 and second synthetic resin layer 13 are 5: 5~7: 3 formation synthetic resin bilayer sheets with the ratio of thickness, so based on the colour rendering of first synthetic resin layer 12 and all good based on the covering property of second synthetic resin layer 13, and, can prevent because first synthetic resin layer 12 and second synthetic resin layer 13 have side moulding such as appearance distortion as thin as a wafer and when one-body molded bad.
Particularly the thickness ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 7: 3 o'clock, and the balance of colour rendering and covering property is best.
Then, with reference to Fig. 2 second embodiment is described.It should be noted that in the following explanation that identical symbol is used in formation identical with above-mentioned embodiment and effect, and omitted explanation it.
The surface of first synthetic resin layer 12 is formed with recess 14, utilizes this recess 14 that for example mark or pattern etc. can be set, and can improve versatility.
In addition, because first synthetic resin layer 12 has the transparency, the surface of first synthetic resin layer 12 is formed with recess 14, and the shade of this recess 14 is reflected on the surface of second synthetic resin layer 13, can obtain three-dimensional visual effect.
In addition, when minute surface fine finishining is implemented on the surface of first synthetic resin layer 12, can improve the hatching effect that recess 14 produces, so preferably minute surface fine finishining is implemented on the surface of first synthetic resin layer 12.
In addition, first synthetic resin layer 12 and second synthetic resin layer 13 are when constituting synthetic resin bilayer sheet in 6: 4 to 7: 3 with the ratio of thickness, based on the colour rendering of first synthetic resin layer 12 and all good based on the covering property of second synthetic resin layer 13, and the recesses 14 that form on first synthetic resin layer, 12 surfaces reflected in the hatching effect of second synthetic resin layer 13 good.
Particularly the thickness ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 7: 3 o'clock, and the balance of colour rendering and covering property is best, and recess 14 is reflected in the hatching effect of second synthetic resin layer 13 best.
[embodiment 1]
Table 1 is the first different synthetic resin layer 12 of the ratio of laminate thickness and second synthetic resin layer 13 and the colour rendering of the one-body molded synthetic resin bilayer sheet that obtains 11 and the evaluation result of covering property.
In addition, in the synthetic resin bilayer sheet 11, first synthetic resin layer 12 contains color pigments, is in the colored transparent state, and second synthetic resin layer 13 contains Chinese white, is in the state with covering property.
[table 1]
Figure A20071014928800091
In the sample of sample number into spectrum 1, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 1: 9, when one-body molded, because first synthetic resin layer 12 is thin, so distortion has taken place, can not guarantee moulding.
In the sample of sample number into spectrum 2 to 4, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 was respectively 2: 8,3: 7,4: 6, and the covering property of these synthetic resin bilayer sheets is all good, but first synthetic resin layer 12 is thin, so colour rendering is poor.
In the sample of sample number into spectrum 5 to 7, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 was respectively 5: 5,6: 4,7: 3, and the colour rendering of these synthetic resin bilayer sheets, covering property are all good, and this ratio is effective condition.
The sample of sample number into spectrum 7 particularly, the balance of its colour rendering and covering property is best.
First synthetic resin layer 12 of sample number into spectrum 8 and the ratio of second synthetic resin layer 13 are 8: 2, and second synthetic resin layer 13 is thin, so covering property is poor, and first synthetic resin layer 12 is colored transparent states, so colour rendering is also poor.
[embodiment 2]
Table 2 is the first different synthetic resin layer 12 of laminate thickness ratio and second synthetic resin layer 13 and one-body molded and then be provided with the covering property of synthetic resin bilayer sheet 11 of recess 14 and the evaluation result of hatching effect on the surface of first synthetic resin layer 12.
In addition, in the synthetic resin bilayer sheet 11, first synthetic resin layer 12 contains color pigments, is in the colored transparent state, and second synthetic resin layer 13 contains Chinese white, is in the state with covering property.
And, implemented minute surface fine finishining on the surface of first synthetic resin layer 12.
[table 2]
Figure A20071014928800101
In the sample of sample number into spectrum 1, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 is 1: 9, when one-body molded, owing to first synthetic resin layer 12 approaches distortion has taken place, and can not guarantee moulding.
In the sample of sample number into spectrum 2 to 5, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 was respectively 2: 8,3: 7,4: 6,5: 5, the covering property of these synthetic resin bilayer sheets is all good, but because first synthetic resin layer 12 is thin, so hatching effect is poor.
In sample number into spectrum 6 and 7 the sample, the ratio of first synthetic resin layer 12 and second synthetic resin layer 13 was respectively 6: 4,7: 3, and the covering property of these synthetic resin bilayer sheets, hatching effect are all good, and this ratio is effective condition.
Particularly the balance of the covering property of the sample of sample number into spectrum 7 and hatching effect is best.
First synthetic resin layer 12 of sample number into spectrum 8 and the ratio of second synthetic resin layer 13 are 8: 2, because second synthetic resin layer 13 is thin, so covering property is poor, accompany therewith, the shade of recess 14 can not be reflected on second synthetic resin layer, so hatching effect is also poor.
The present invention can be used as the synthetic resin sheet that uses in files such as for example transparent file folder.

Claims (6)

1, a kind of synthetic resin bilayer sheet, it is characterized in that, it is that first synthetic resin layer and second synthetic resin layer are through lamination and integrated synthetic resin bilayer sheet, described first synthetic resin layer is by forming through the painted synthetic resin with transparency of color pigments, and described second synthetic resin layer is by forming through the painted synthetic resin with covering property of the color pigments with covering property.
2, a kind of synthetic resin bilayer sheet, it is characterized in that, it is that first synthetic resin layer and second synthetic resin layer are through lamination and integrated synthetic resin bilayer sheet, described first synthetic resin layer is formed by water white synthetic resin, and described second synthetic resin layer is by forming through the painted synthetic resin of the color pigments with covering property.
3, synthetic resin bilayer sheet according to claim 1 and 2 is characterized in that, described second synthetic resin layer is by forming through the painted synthetic resin with covering property of the Chinese white with covering property.
According to each described synthetic resin bilayer sheet of claim 1~3, it is characterized in that 4, described first synthetic resin layer and second synthetic resin layer are 5: 5 to 7: the 3 described synthetic resin bilayer sheets of formation with thickness proportion.
According to each described synthetic resin bilayer sheet of claim 1~3, it is characterized in that 5, described first synthetic resin layer is formed with recess on the surface.
6, synthetic resin bilayer sheet according to claim 5 is characterized in that, described first synthetic resin layer and second synthetic resin layer are 6: 4 to 7: the 3 described synthetic resin bilayer sheets of formation with thickness proportion.
CNA2007101492889A 2007-05-14 2007-09-11 Synthetic resin bilayer sheet Pending CN101306592A (en)

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JP2007128285A JP2008279732A (en) 2007-05-14 2007-05-14 Two-layered synthetic resin sheet
JP2007-128285 2007-05-14

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Cited By (2)

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CN103826850A (en) * 2011-05-31 2014-05-28 爱索尔包装有限公司 Barrier structure and laminate thereof
CN103935093A (en) * 2013-01-21 2014-07-23 惠和株式会社 Decorative sheet for injection molding, sheet laminated body for injection molding and injection molding products

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KR101119631B1 (en) 2009-07-27 2012-03-06 주식회사 영우 Gasket tape for lens mold and method for the same
JP2011063272A (en) * 2009-09-15 2011-03-31 Toyo Seikan Kaisha Ltd Multi-layered plastic container having superior appearance characteristics

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NZ503189A (en) * 1999-04-08 2001-02-23 Premark Rwp Holdings Inc Thermoplastic acrylic sheet compositions comprising PMMA and their use as substitutes for high pressure decorative laminate
JP2001347616A (en) * 2000-06-09 2001-12-18 Okura Ind Co Ltd Sheet for stationery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103826850A (en) * 2011-05-31 2014-05-28 爱索尔包装有限公司 Barrier structure and laminate thereof
CN103935093A (en) * 2013-01-21 2014-07-23 惠和株式会社 Decorative sheet for injection molding, sheet laminated body for injection molding and injection molding products

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JP2008279732A (en) 2008-11-20
TW200843951A (en) 2008-11-16
WO2008139649A1 (en) 2008-11-20

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Open date: 20081119