CN101302315A - Isolating film and preparation thereof colloidal compound film and preparation thereof - Google Patents

Isolating film and preparation thereof colloidal compound film and preparation thereof Download PDF

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Publication number
CN101302315A
CN101302315A CNA2008100323182A CN200810032318A CN101302315A CN 101302315 A CN101302315 A CN 101302315A CN A2008100323182 A CNA2008100323182 A CN A2008100323182A CN 200810032318 A CN200810032318 A CN 200810032318A CN 101302315 A CN101302315 A CN 101302315A
Authority
CN
China
Prior art keywords
composite membrane
preparation
glue composite
film
antiblocking agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2008100323182A
Other languages
Chinese (zh)
Inventor
姚瑱
余小双
张瑾瑾
朱自清
王敬华
唐宇鹰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI JINPU PLASTIC PACKING MATERIALS CO Ltd
Original Assignee
SHANGHAI JINPU PLASTIC PACKING MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI JINPU PLASTIC PACKING MATERIALS CO Ltd filed Critical SHANGHAI JINPU PLASTIC PACKING MATERIALS CO Ltd
Priority to CNA2008100323182A priority Critical patent/CN101302315A/en
Publication of CN101302315A publication Critical patent/CN101302315A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/397Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using a single screw

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

The invention relates to a rubber composite membrane and a method for preparing the same. The method comprises the following steps that: 92 to 98 percent of polypropylene resins, 1 to 1.5 percent of antistatic agent and 1 to 6.5 percent of antiblocking agent are uniformly mixed and measured; and the membrane is obtained after lengthwise stretching, transverse stretching and drawing through a single-screw extruder, physicochemical reaction and biaxial tension. Compared with the prior art, the rubber composite membrane is characterized by high tensile strength, good transparency and so on.

Description

A kind of have glue composite membrane and preparation method thereof
Technical field
The present invention relates to a kind of film, relate in particular to a kind of glue composite membrane and preparation method thereof that has.
Background technology
It is a kind of very important flexible packing material that the glue composite membrane is arranged, and uses very extensive.Have the glue composite membrane colourless, do not have smell, tasteless, nontoxic, and have high tensile, shock strength, rigidity, obdurability and the good transparency.There is glue composite membrane surface energy low, need carries out corona treatment before gluing or the printing., the glue composite membrane is arranged after corona treatment, good printing adaptability is arranged, can chromaticity printing and obtain exquisite appearance effect, thereby be commonly used for the surface material of laminated film.
There is the glue composite membrane that deficiency is also arranged, as do not have heat sealability.In order to obtain the heat sealable glue composite membrane that has, can there be glue composite membrane surface corona to handle the heat sealable resin adhesive liquid of back coating, as PVDC latex, EVA latex etc., but also coating solvent glue also can adopt the method for extrusion coated or coextru-lamination to produce the heat sealable glue composite membrane that has.
Have the initiation tear strength of glue composite membrane to increase after stretching, but the secondary tear strength is very low, therefore, BOPP film both ends of the surface can not leave any otch, otherwise tear easily at printing, compound tense.Can produce ew Year pictures after glue composite membrane coating glue is arranged, be one of market that has glue composite membrane large usage quantity.
Summary of the invention
Purpose of the present invention be exactly a kind of high tensile, the good transparency be provided in order to overcome the defective that above-mentioned prior art exists glue composite membrane and preparation method thereof arranged.
Purpose of the present invention can be achieved through the following technical solutions: a kind of have a glue composite membrane, it is characterized in that this film comprises following component and content (weight percent):
Acrylic resin 92-98%,
Static inhibitor 1-1.5%,
Antiblocking agent 1-6.5%.
Described static inhibitor is selected from one or more in erucicamide, amine ethoxylate, the Tegin 55G amine hydroxybenzene.
Described antiblocking agent is selected from one or more in silicon-dioxide, silicon class, the organosilicon.
A kind of preparation method that the glue composite membrane is arranged, it is characterized in that, this method comprises following processing step: with acrylic resin 92-98%, static inhibitor 1-1.5%, antiblocking agent 1-6.5% is after mixing, metering, after physical-chemical reaction is carried out in single screw extrusion machine, longitudinal stretching, cross directional stretch and traction, obtain this film through two-way stretch.
Described screw rod expressing technique temperature is 200-270 ℃.
Compared with prior art, the present invention with the polypropylene be the high tensile of raw material, the good transparency the glue composite membrane arranged, this have the glue composite membrane with its good transparent packing that is widely used in bread, clothes, footgear etc., and the cover package of cigarette, books.
Embodiment
Below in conjunction with specific embodiment the glue composite membrane and preparation method thereof that has involved in the present invention is described.
In following examples, F280 represents: China Petrochemical Industry Company's product acrylic resin;
Static inhibitor is represented: Shanghai Jia Mo company product;
Antiblocking agent is represented: Shu Er Man product;
Acrylic resin, static inhibitor, antiblocking agent and Co-polypropylene through mixing, the metering after, after physical-chemical reaction is carried out in single screw extrusion machine, MDO, TDO and traction, get final product this film.Technological temperature is 200-270 ℃.
The gained film is made corresponding batten according to the ISO testing standard, tests under the dry state condition.I.e. conditions 24 hours in moisture eliminator is tested under 23 ± 2 ℃, the environment of 50 ± 5% relative humidity then.
According to ISO 1133 canonical measure melting index;
According to ISO 527 canonical measure tensile strengths;
Embodiment 1~3
Figure A20081003231800041
Figure A20081003231800051
Performance test is as follows:
Figure A20081003231800052
Embodiment 4
A kind of preparation method that the glue composite membrane is arranged, comprise following processing step: with acrylic resin 95kg, static inhibitor erucicamide 1%, antiblocking agent silicon-dioxide 4%, after mixing, metering, under 200 ℃, after longitudinal stretching (MDO), cross directional stretch (TDO) and traction carry out physical-chemical reaction, obtain this film through single screw extrusion machine through two-way stretch.
Embodiment 5
A kind of preparation method that the glue composite membrane is arranged, comprise following processing step: with acrylic resin 96kg, static inhibitor amine ethoxylate 1.5%, antiblocking agent organosilicon 2.5%, after mixing, metering, under 270 ℃, after longitudinal stretching (MDO), cross directional stretch (TDO) and traction carry out physical-chemical reaction, obtain this film through single screw extrusion machine through two-way stretch.

Claims (5)

1. one kind has the glue composite membrane, it is characterized in that, this film comprises following component and content (weight percent):
Acrylic resin 92-98%,
Static inhibitor 1-1.5%,
Antiblocking agent 1-6.5%.
2. a kind of glue composite membrane that has according to claim 1 is characterized in that described static inhibitor is selected from one or more in erucicamide, amine ethoxylate, the Tegin 55G amine hydroxybenzene.
3. a kind of glue composite membrane that has according to claim 1 is characterized in that described antiblocking agent is selected from one or more in silicon-dioxide, silicon class, the organosilicon.
4. preparation method that the glue composite membrane is arranged as claimed in claim 1, it is characterized in that, this method comprises following processing step: with acrylic resin 92-98%, static inhibitor 1-1.5%, antiblocking agent 1-6.5%, after mixing, metering, after physical-chemical reaction is carried out in single screw extrusion machine, longitudinal stretching, cross directional stretch and traction, obtain this film through two-way stretch.
5. a kind of preparation method that the glue composite membrane is arranged according to claim 4 is characterized in that, described screw rod expressing technique temperature is 200-270 ℃.
CNA2008100323182A 2008-01-04 2008-01-04 Isolating film and preparation thereof colloidal compound film and preparation thereof Pending CN101302315A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2008100323182A CN101302315A (en) 2008-01-04 2008-01-04 Isolating film and preparation thereof colloidal compound film and preparation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2008100323182A CN101302315A (en) 2008-01-04 2008-01-04 Isolating film and preparation thereof colloidal compound film and preparation thereof

Publications (1)

Publication Number Publication Date
CN101302315A true CN101302315A (en) 2008-11-12

Family

ID=40112427

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2008100323182A Pending CN101302315A (en) 2008-01-04 2008-01-04 Isolating film and preparation thereof colloidal compound film and preparation thereof

Country Status (1)

Country Link
CN (1) CN101302315A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861296A (en) * 2015-05-22 2015-08-26 李文东 Packaging composite membrane and preparation method thereof
CN105860268A (en) * 2016-06-18 2016-08-17 李文东 Food packaging film and preparation method thereof
CN105924770A (en) * 2016-05-15 2016-09-07 李文东 Painting and calligraphy packaging film and preparing method thereof
CN106009266A (en) * 2016-06-19 2016-10-12 李文东 Durable adhesive tape film high in safety and preparing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861296A (en) * 2015-05-22 2015-08-26 李文东 Packaging composite membrane and preparation method thereof
CN105924770A (en) * 2016-05-15 2016-09-07 李文东 Painting and calligraphy packaging film and preparing method thereof
CN105860268A (en) * 2016-06-18 2016-08-17 李文东 Food packaging film and preparation method thereof
CN106009266A (en) * 2016-06-19 2016-10-12 李文东 Durable adhesive tape film high in safety and preparing method thereof

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Open date: 20081112