CN101285259A - Process for drying by imitating sunlight and removing ozone by using ultra-oxygen negative ion - Google Patents
Process for drying by imitating sunlight and removing ozone by using ultra-oxygen negative ion Download PDFInfo
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- CN101285259A CN101285259A CNA2008100906699A CN200810090669A CN101285259A CN 101285259 A CN101285259 A CN 101285259A CN A2008100906699 A CNA2008100906699 A CN A2008100906699A CN 200810090669 A CN200810090669 A CN 200810090669A CN 101285259 A CN101285259 A CN 101285259A
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- ozone
- superoxide anion
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Abstract
The invention discloses a method for imitating the sun drying and adopting superoxide anion to remove ozone. The method adopts a drying structure of a washing machine. The drying structure refers to a circulation path of the drying structure of a dryer of the washing machine in the prior art. The inside of the air path for drying clothes is provided with an ozone generator and a catalyzed sorption device. The clothes are irradiated by near infrared rays, far infrared rays and ultraviolet rays. The sunlight is imitated to dry the clothes. After the imitated sun drying is completed, a catalyst is used to absorb the residual ozone in order to remove the ozone which is harmful to human body. The method has the advantages of the function of sterilization, fiber bulking and the ability to be performed all weather and has the effect basically the same as the natural sun drying.
Description
Technical field
What the present invention relates to is a kind of method of simulated solar airing clothes, concretely, it is the circulation canal that utilizes the inside and outside bucket in the clothes washer-dryer, air duct formation in the prior art, and in conjunction with near-infrared, far infrared, ultraviolet irradiation to clothing, and the contacting of ozone and/or superoxide anion and clothing, carry out the simulated solar airing.
Background technology
At present airing clothes all needs clothing is placed in the sun, but if continuous several days cloudy or sleety weather, then can't airing clothes.
CN92225414 discloses a kind of Ms's articles for use sterilizer, and the sterilization effect of its simulated solar irradiation and designing mainly is made up of heating, ultraviolet lamp and article box etc.Simple in structure, easily manufactured.Initiation and infection to disease have the good preventing effect, for family, hospital provide a kind of not only easy but also safety quick sterilization means, also can be used as the cleaning-sterilizing of other various small articles simultaneously.
CN96242313 discloses a kind of sunlight analogue means, the sunlight analogue means that uses in a kind of greenhouse of main proposition, it mainly partly is made of illuminator and modulation of source, illuminator comprises reflective hood that an aperture surface is a parabolic shape and the light source body of being made up of incandescent lamp, chromolume, ultraviolet (infrared) lamp that sets within it, and modulation of source partly then mainly is provided with the generation of wide dutycycle square-wave signal, modulation circuit and electronic switching circuit.
CN00213559 discloses a kind of non-yellowing test case, it comprises casing, chamber door, electrical installation, power drive mechanism and temperature controller and air exhausting device, it is characterized in that: casing is provided with the rotating disk that is connected with power drive mechanism, and the casing inner top surface above rotating disk is provided with the bulb of a simulated solar irradiation.
CN01113032 discloses a kind of sunlight simulator with pulsive xenon lamp and three-freedom paraboloid for scattered reflection, adopting the tubulose xenon flash lamp is line source, the axis of light source along the line is settled parabolic diffuse reflection minute surface, by adjusting X-axis, Y-axis, Z axle adjustable skid fixing on the light source base, line source is transferred to correct position with respect to parabolic diffuse reflection minute surface, make by optical uniformity and reach requirement according to plane, assembly place, and on light path, be provided with filter system and silk screen, to improve the spectrum of simulated light.
CN200310108102 discloses a kind of quasi-continuous light generating power supply of single flash operation solar simulator, LC network charging and discharging circuit and pre-burning loop are connected with long arc discharge xenon lamp by anti-return diode separately, LC network charging and discharging circuit is connected with main discharge circuit, control loop is connected with LC network charging and discharging circuit, wherein LC network charging and discharging circuit is formed by connecting by ten electric capacity and ten inductance mode by cascade, discharge can allow xenon long-arc lamp Discharge illuminating waveform be square wave, constitute real-time closed-loop control by six circuit in the control loop, the discharge safe sequential circuits is made of four time-delay square-wave pulse circuit, and line security is reliable when guaranteeing discharge.
CN87205109 discloses a kind of photocopier ozone purifier, partly is made up of wind-collecting cover, adapter, air exhauster and purifying box etc., and the catalyst that ozone is decomposed is housed in the purifying box.The air that contains ozone that this clarifier can in use be produced duplicator (or duplicator) is extracted out, discharges clarifier after catalysis is decomposed ozone.
CN200520060779 discloses a kind of air cleaner with ozonolysis equipment, comprise air cleaner, described air cleaner comprises shell, air duct, anion generator and control circuit, anion generator is positioned at air duct, it is characterized in that: also comprise ozonolysis equipment, described ozonolysis equipment is made of one or two above heating elements, and heating element is positioned at air duct, distributing is arranged near the ozone generator.
The irradiation of open simulated solar to personal belongings that though above-mentioned document has, any simulated solar spectrum is perhaps disclosed so that use at other field, but, above-mentioned document does not all have open, how to utilize the clothes drying structure of washing machine, the perhaps mechanism of dryer is in conjunction with simulated solar, produce the effect of similar natural sunlight with drying, prior art does not provide the report that utilizes the superoxide anion ozone decomposition yet simultaneously.
In view of this, special proposition the present invention.
Summary of the invention
Main purpose of the present invention is to provide a kind of washing machine clothes drying structure of using, utilization is provided with ozone generating-device and with the superoxide anion generating means clothing is contacted in the air duct that drying clothes is used, and utilize near infrared ray, far infrared and ultraviolet ray that clothing is shone, simulated solar irradiation carries out airing to clothing, and utilizes superoxide anion to decompose the method for remaining ozone.
Superoxide anion of the present invention is meant, air, comprise the admixture of gas that multiple gases such as oxygen, nitrogen, steam, carbon dioxide are formed, ray, be heated and the effect of highfield under, described gas molecule can lose some electronics, promptly so-called air ionization, and these electronics that lose are called free electron, the described free electron gas molecule that obtains electronics that combines with other neutral molecule is electronegative, is called negative aeroion.
Anion has pyroelectricity and piezoelectricity, both made under the situation that small temperature and pressure changes, also can cause the electrical potential difference between the anion crystal, thereby make air generation ionization, in the air, the ability that the multiple gases molecule " is captured " electronics have have by force a little less than, wherein oxygen and carbon dioxide are stronger, and oxygen accounts in air more than 20%, and carbon dioxide only accounts for 0.03%.Therefore the free electron major part of air ionization generation is obtained by oxygen, forms negative oxygen ion, claims superoxide anion again.
The process that described superoxide anion produces can be represented with reaction equation: O
2+ e → O
2 -At occurring in nature, though can not touch, people cannot see, can experience the existence of anion.After the thunder and lightning, because a large amount of anions that electric shock causes in air, open-air air can be especially pure and fresh; Also have in the ocean except thunder and lightning, springing up also that wave is frequent can cause a large amount of anions, taken to the seashore by sea wind, and it is relaxed and joyful that the seashore air can make us too.On the contrary, the too much cation of air can cause reactions such as insomnia, headache, vexed, elevation of blood pressure.Day of blast blown sand for example, in that the crowd is dense, the place of air dirt, positive aeroion increases suddenly.
The present invention has simulated the ozone of the superoxide anion of actual contact, trace in the airing clothes just, and near-infrared, far infrared and ultraviolet irradiation, and the clothes drying structure that utilizes washing machine is finished described simulation, in the indoor same effect that obtains with the nature sunlight with drying, perhaps, better than the effect of nature acquisition.
Though the research to the sunshine airing clothes shows, really the composition to airing and the fresh and clean effect of acquisition has comprised above several, but, realistic simulation is not to be that described composition or irradiation simple superposition are got final product, the priority that comprises various composition contacts, the arrangement of irradiation and order all need be carried out complexity adjustment.Below be that the composition of other several necessity is analyzed.
Occurring in nature, solar spectrum is divided into radio wave, infrared ray, visible light, ultraviolet ray and ray (X ray and ﹠amp by wavelength length; Gamma; Ray) several wave spectrums district such as.
Sunshine mainly comprises three kinds of ultraviolet ray, visible light and infrared rays.
Irradiation of sunlight then arrives the earth through atmosphere, can produce filtration, the light combination that therefore arrives the surface of the earth is about: ultraviolet ray accounts for 7% (can change the structure of matter and have destructiveness), visible light accounts for 71% (illumination, photosynthesis can be provided) infrared ray and accounts for 22% (can produce heat energy, bactericidal action).
Arrive in the solar radiation on ground, maximum with ultrared energy, account for 50-70%, secondly visible ratio accounts for 46-30%, and ultraviolet ray is minimum, only accounts for 4-0.1%.
The analysis showed that visible light is to the not significant effect of the airing of clothing, in the infrared ray, what play a major role is near-infrared and far infrared.
Imitating sunlight with drying method of the present invention, comprise clothing is carried out near-infrared, far infrared, ultraviolet irradiation, and utilize ozone that clothing is carried out contact sterilizing under the air dielectric, ozone and clothing contact after, utilize superoxide anion to decompose residual ozone, after the process of decomposing residual ozone was finished, superoxide anion continued and contact with clothing.Superoxide anion of the present invention comes from and utilizes ultraviolet ray that photocatalyst is carried out irradiation to produce highly active superoxide anion, perhaps utilize negative oxygen ion generator to produce superoxide anion.In the present invention, the about 2-8 minute contact time of ozone and clothing, then, about 3～10 minutes of the time that superoxide anion and residual ozone contact with the mixing of clothing, about 8～20 minutes of total time of superoxide anion and contact with clothing.Near-infrared, far infrared, ultraviolet irradiation exist in whole process all the time in the said method, perhaps gap irradiation, and described irradiation contact with ozone simultaneously or priority is carried out, and still, superoxide anion carries out after ozone and contact with clothing are finished.
In the present invention, when the air mixture of ozone or superoxide anion or air mixture between them and contact with clothing, be the centrifugal force that the bucket rotation produces in utilizing, substantially be attached to bed clothes or clothing on the inner barrel wall, described centrifugal force passes clothing or bed clothes with the air mixture of ozone or superoxide anion, and forms circulation between air duct in the dry again structure and the inside and outside bucket of washing machine.
For clothing or the bed clothes of shaking up, can adopt the anxious mode of stopping or reversing to make clothing or the reverse shake of bed clothes.
In above-mentioned method, can also be when opening near-infrared, far infrared, ultraviolet ray generating apparatus irradiation or before, open sunlight factor washing agent sprayer unit with accelerated decomposition clothing dirt and elimination peculiar smell, this sprayer unit is small-sized sprayer unit, its spray time is for making that the clothing week age that all rolls is best, that is, 1-2 minute, make spraying cover on the clothing fully.
The sunlight factor is a kind of photosensitizer, also is a kind of optical bleaching agent.It can absorb the energy (infrared ray and ultraviolet ray) in the sunlight and pass to oxygen ubiquitous in the air, the oxygen molecule of this excitation state has very high energy, can be immediately and pigment dirt and microbial action, make it to become colourless fragment, reach the effect of bleaching and disinfection, also can decompose peculiar smell, reach purpose with fresh air.The sunlight factor does not consume the peroxide as active oxygen source, but utilizes the free energy of the Nature, by the exciting of micro substance, energy transmission, and then produces active material, reaches the bleaching purpose.
The sunlight factor structure is as follows, and itself and various washing agent commonly used all can be used.
R＝O(CH
2CH
2O)
nH，SO
3H，COOH，OCOCHSO
3CH
2COOH，N(CH
3)
3
No matter roller washing machine or rotary drum washing machine, all can there be can the go directly opening of clothing of a light in they, certainly, a kind of roller washing machine exception of backing down that occurs in recent years, near-infrared, far infrared and ultraviolet ray can utilize described opening irradiation clothing, during irradiation, can make the various piece of all bed clothes or clothing all be scanned irradiation interior bucket rotation.
In the light of simulation, the energy of near-infrared and far infrared accounts for 50-70%, and ultraviolet ray accounts for 0.2-3%.
With prior art relatively, the present invention has following advantage: 1, clothing and bed clothes adopt imitative sunlight effectively to sterilize, 2, can be effectively give clothing and the bed clothes drying of drying, 3, make similar sunlight with drying such as fiber is loose resultant effect, 4, imitating sunlight with drying of the present invention can round-the-clockly carry out, be not subjected to the influence of weather and solar radiation situation, 5, whole process only needs 15-30 minute, and can carry out continuously, 6, utilize the superoxide anion that needs in the airing composition, both pure and fresh smell can be produced, remaining ozone can be decomposed again.
Below in conjunction with accompanying drawing the specific embodiment of the present invention is described in further detail.
Description of drawings
Accompanying drawing 1 is the washing machine that has imitating sunlight with drying and use superoxide ion catalysis absorption residual ozone of the present invention.
In order to clearly demonstrate washing machine of the present invention, below component names and accompanying drawing mark are enumerated as follows, concrete is impeller 1, buffer beam 2, casing 3, cabinet cover 4, outer bung 5, washing clothes 6, heater 7, fan 8, upturning lid 9, line bits filter 10, catalyst layer 11, down turnover cover 12, air duct 13 drives assembly 14, electromagnetic valve 15, drainpipe 16, ultraviolet, near-infrared, far infrared generator assembly 17.
The specific embodiment
Embodiment one
Present embodiment relates generally to and a kind ofly utilizes titanium dioxide on the photocatalyst as catalyst, makes to be adsorbed on its surperficial oxygen and to be excited into and to have active O
2 -Free radical, the extremely strong free radical of this oxidizing force almost can decompose all to human body or harmful organic substance and the part inorganic substances of environment, make its rapid oxidation Decomposition be stable and harmless material (water, carbon dioxide), purify air to reach, the function of sterilization, deodorization.
Embodiment two
Other are identical with embodiment one, and different is, because in the method for simulated solar airing of the present invention, used ultraviolet ray that clothing is carried out necessary irradiation, therefore, present embodiment utilizes and ultraviolet photocatalyst is shone, and strengthens the activity of photocatalyst.
Embodiment three
Present embodiment is described to be, utilize negative oxygen ion generator to obtain described superoxide anion, in the present embodiment, can air ionization be obtained, concrete, can utilize high voltage to be added in the glow discharge of pin electrode discharge generation and produce air ionization and obtain superoxide anion.
Utilizing superoxide anion to decompose in the process of residual ozone about 5～8 minutes of the contact time of ozone and superoxide anion.
Embodiment four
Present embodiment mainly is to the analysis of simulated solar and synthetic.
Near-infrared of the present invention is meant that wavelength is the light of 600～1200nm, and preferred light is near the 760nm place, or between 980～990nm, radiated time is 2～3 minutes.
Far infrared of the present invention is meant 2.5～50 microns of wavelength, optimal wavelength 3～25 μ m, that be more preferably is 5-20 μ m, most preferred wavelength is 8～15 μ m, radiation area stopped 3～4 minutes in the wave-length coverage of described far infrared, made the loose far infrared radiation district of the whole fiber of clothing cotton-padded mattress.
The ultraviolet ray that the present invention adopts selects the light source of wave-length coverage at 180nm～380nm for use, preferably adopts the wavelength of 220～350nm, the employing 250nm-280nm wavelength ultraviolet radiation absorption that is more preferably.The action of ultraviolet ray time is 15～20 minutes, combined with ozone, and ultraviolet and ozone can carry out sterilizing to the clothing cotton-padded mattress, and simultaneously, exposure light catalyst when needed is to strengthen the activity of photocatalyst.
Ozone generating-device can adopt the high pressure generation discharge mode of prior art to obtain, any can ozoniferous prior art, can introduce source as ozone of the present invention.Described ozone generator can be arranged on air duct 13 tops, so that when air circulation, contacts with washing clothes.
Embodiment five
Present embodiment mainly is that the principle among the embodiment one is used in the rotary drum washing machine.
Be applicable to clothes washer-dryer of the present invention, referring to accompanying drawing 1, comprise casing 3, the top of casing 3 is provided with cabinet cover 4, in casing 3, transfer and hang outer barrel with buffer beam 2, on the outer bucket an outer bung 5 is set, interior bucket is set in the bucket outside, the bottom of interior bucket is provided with impeller 1, and Tong bottom is provided with line bits filter 10 to outer setting one air duct 13 at top on described air duct 13 tops outside, heater 7, fan 8, Tong bottom is provided with and drives assembly 14 outside, be used to drive impeller 1, at drainpipe 16 electromagnetic valve 15 be set and be used to control discharge water, in washing, place washing clothes 6 in the bucket.
One bypass pipe is set on air duct 13, and the upper and lower part of described bypass pipe is two parts of UNICOM's air duct 13 respectively, on the top of bypass pipe upturning lid 9 are set, and in the bottom of bypass pipe down turnover cover 12 are set, and at the bypass pipe middle part catalyst layer 11 are set.When needing, can open upturning lid 9 and down turnover cover 12, so that make remaining ozone by catalyst layer 11.
Outer bucket top at washing machine is provided with a ultraviolet ray, near infrared ray, infrared generator assembly 17.
In described air duct 13, place heater 7, described air utilizes the wind-force of fan 8 to send into bucket in the rotation after air duct 13 heating, adopt retractile tube connector to be connected between described air duct 13 and the outer bucket, buffer beam 2 flexiblely is bearing in outer bucket in the casing, and impeller 1 is located in the described interior bucket in rotation mode freely.
The foregoing description also can be used in the tumble drier, ultraviolet ray, near infrared ray, infrared generator assembly can be located at a body inboard, ozone generator can be arranged in the import that air duct enters cylinder, and a bypass pipe is set on air duct, at the bypass pipe middle part catalyst layer is set.
Embodiment six
Present embodiment mainly is that the structure in embodiment five adds sunlight factor washing agent sprayer unit, and this device is located at the outer bucket top of washing machine, can be located at the below (not shown) of near-infrared, far infrared, ultraviolet ray generating apparatus.When opening near-infrared, far infrared, ultraviolet ray generating apparatus irradiation or before, open sunlight factor washing agent sprayer unit with accelerated decomposition clothing dirt and elimination peculiar smell, this sprayer unit is small-sized sprayer unit, its spray time is for making that the clothing week age that all rolls is best, promptly, 1-2 minute, make spraying cover on the clothing fully.
Claims (13)
1, a kind of imitating sunlight with drying and remove the method for ozone with superoxide anion, it is characterized in that: described method comprises carries out near-infrared, far infrared, ultraviolet irradiation to clothing, and utilize ozone that clothing is carried out contact sterilizing under the air dielectric, after reaching the fixed time contact time of ozone and clothing, utilize superoxide anion to decompose residual ozone, after the process of decomposing residual ozone was finished, superoxide anion continued and contact with clothing.
2, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: described superoxide anion produces highly active superoxide anion, the superoxide anion that perhaps uses negative oxygen ion generator to produce for using ultraviolet ray that photocatalyst is carried out irradiation.
3, imitating sunlight with drying according to claim 1 and 2 and remove the method for ozone with superoxide anion, it is characterized in that: be 2-8 minute the contact time of ozone and clothing, then, superoxide anion is 3～10 minutes with the time that residual ozone contacts with the mixing of clothing, and total time of superoxide anion and contact with clothing is 8～20 minutes.
4, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: when the air mixture of ozone or superoxide anion or ozone and superoxide anion between the two air mixture and during contact with clothing, fair speed of bucket in giving, the centrifugal force that produces is attached to bed clothes or clothing on the inner barrel wall, described centrifugal force passes clothing or bed clothes with above-mentioned air mixture, and forms circulation between the bucket inside and outside air duct in dry structure and the washing machine.
5, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion is characterized in that: described method adopts the anxious mode of stopping to make clothing or the reverse shake of bed clothes, shake up clothing or bed clothes.
6, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: described near-infrared, far infrared and ultraviolet ray are carried out irradiation from the peristome of washing machine to clothing.
7, imitating sunlight with drying according to claim 6 and remove the method for ozone with superoxide anion, it is characterized in that: the rotation of bucket in utilizing makes the various piece of all bed clothes or clothing all be scanned irradiation.
8, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: in the light of simulation, the energy of near-infrared and far infrared accounts for 50-70%, and ultraviolet ray accounts for 0.2-3%.
9, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: the near-infrared of employing is meant that wavelength is the light of 600～1200nm, and radiated time is 2～3 minutes.
10, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: far infrared is meant 2.5～50 microns of wavelength, radiation area irradiation is 3～4 minutes in the wave-length coverage of described far infrared.
11, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: the ultraviolet light source of selecting wave-length coverage at 180nm～380nm for use, the action of ultraviolet ray time is 15～30 minutes.
12, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: near-infrared, far infrared, ultraviolet irradiation exist in whole process all the time, perhaps gap irradiation, described irradiation contacts with ozone simultaneously or successively carries out, and superoxide anion carries out after ozone and contact with clothing are finished.
13, imitating sunlight with drying according to claim 1 and remove the method for ozone with superoxide anion, it is characterized in that: when opening near-infrared, far infrared, ultraviolet ray generating apparatus irradiation or before, open sunlight factor washing agent sprayer unit with accelerated decomposition clothing dirt with eliminate peculiar smell.
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| CN2008100906699A CN101285259B (en) | 2007-04-09 | 2008-04-09 | Process for drying by imitating sunlight and removing ozone by using ultra-oxygen negative ion |
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| CN200710090841 | 2007-04-09 | ||
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| CN101818441A (en) * | 2010-05-10 | 2010-09-01 | 海尔集团公司 | Washing machine with deodorizing and sterilizing functional drawer and deodorizing method |
| CN101899766A (en) * | 2010-05-19 | 2010-12-01 | 海尔集团公司 | Washing machine with functions of ozone deodorization and anionic sterilization and working method thereof |
| CN101899766B (en) * | 2010-05-19 | 2015-07-01 | 海尔集团公司 | Washing machine with functions of ozone deodorization and anionic sterilization and working method thereof |
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| JP2016500770A (en) * | 2012-11-02 | 2016-01-14 | コーニンクレッカ フィリップス エヌ ヴェＫｏｎｉｎｋｌｉｊｋｅ Ｐｈｉｌｉｐｓ Ｎ．Ｖ． | Cloth product treatment |
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| CN109957909B (en) * | 2017-12-22 | 2021-12-07 | 博西华电器（江苏）有限公司 | Method for sterilizing clothes by using washing machine and washing machine capable of implementing method |
| CN109957909A (en) * | 2017-12-22 | 2019-07-02 | 博西华电器（江苏）有限公司 | With washing machine to the method for clothing degerming and the washing machine of implementable this method |
| WO2019184708A1 (en) * | 2018-03-28 | 2019-10-03 | 青岛海尔洗衣机有限公司 | Washing-drying integrated machine |
| CN111334974A (en) * | 2018-12-18 | 2020-06-26 | 青岛海尔滚筒洗衣机有限公司 | Control method of clothes treatment equipment and clothes treatment equipment |
| CN109865150A (en) * | 2019-04-19 | 2019-06-11 | 陈小飞 | A kind of Hand-Food-Mouth Disease nursing combination unit |
| CN111839098A (en) * | 2020-07-07 | 2020-10-30 | 周相真 | Full-transparent fresh-keeping refrigeration display cabinet with sterilization and deodorization functions |
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| WO2024078536A1 (en) * | 2022-10-12 | 2024-04-18 | 青岛海尔洗衣机有限公司 | Ozone treatment apparatus |
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