CN101270317B - High-lubricity environment-friendly water-based core rod lubricant agent - Google Patents
High-lubricity environment-friendly water-based core rod lubricant agent Download PDFInfo
- Publication number
- CN101270317B CN101270317B CN200810023977XA CN200810023977A CN101270317B CN 101270317 B CN101270317 B CN 101270317B CN 200810023977X A CN200810023977X A CN 200810023977XA CN 200810023977 A CN200810023977 A CN 200810023977A CN 101270317 B CN101270317 B CN 101270317B
- Authority
- CN
- China
- Prior art keywords
- core rod
- lubricity
- methyl
- agent
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000000314 lubricant Substances 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010439 graphite Substances 0.000 claims abstract description 5
- -1 alkali metal salt Chemical class 0.000 claims description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229940079832 sodium starch glycolate Drugs 0.000 claims description 3
- 239000008109 sodium starch glycolate Substances 0.000 claims description 3
- 229920003109 sodium starch glycolate Polymers 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 229940071117 starch glycolate Drugs 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 240000003936 Plumbago auriculata Species 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 239000001488 sodium phosphate Substances 0.000 description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 5
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 5
- 235000019801 trisodium phosphate Nutrition 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a high-lubricity water-based core rod lubricant friendly to the environment, which consists of scale-like plumbago, fused salt, an inorganic binder, a viscosity increaser, water and auxiliary materials. The invention is usable and has excellent lubricity at high temperature; the core rod has long service life, and can meet the requirement of the current pipe mills for adjusting product structure and product quality.
Description
Technical field:
The present invention relates to a kind of water-based core rod lubricant agent of seamless steel pipe hot-rolling perforation usefulness.
Background technology:
Because the tube product structure is constantly significantly adjusted to the high alloy of highly difficult, high quality, high added value, the high grade of steel line of production, simultaneously quality product requires also to improve constantly, and is therefore also more and more higher to the requirement of the requirement of the used core rod lubricant agent of the core unit of pipe mill and mandrel surface quality.Continuous rolling load, plug work-ing life, mandrel surface quality and core rod lubricant agent quality are closely related, because problems such as former core rod lubricant agent MD1700 exists that the high temperature bond effect is relatively poor, high temperature lubricating poor-performing, plug work-ing life is short can not adapt to the adjustment of present pipe mill product structure and the requirement of quality product fully.
Summary of the invention:
The object of the present invention is to provide a kind of high-lubricity environment-friendly water-based core rod lubricant agent of high temperature lubricating excellent performance.
Technical solution of the present invention is:
A kind of high-lubricity environment-friendly water-based core rod lubricant agent is characterized in that: be made up of weight components:
Flaky graphite 10～50%
Fused salt material 1～20%
Mineral binder bond 1～20%
Tackifier 0.01～2%
Water 20～80%
Auxiliary material 0～10%.
The fused salt material is dipotassium hydrogen phosphate, Tri sodium Phosphate, borax, borate, trisodium phosphate or silicate.
Mineral binder bond is an alkali metal salt of clay, wilkinite, phosphoric acid, an alkali metal salt of boric acid or an alkali metal salt of silicic acid.
Tackifier are Natvosol, carboxymethyl cellulose, calcium carboxymethylcellulose, Xylo-Mucine, carboxymethyl starch or sodium starch glycolate.
Auxiliary material is one or more in dispersion agent, wetting agent, sterilant, the PH buffer reagent.
Dispersion agent is the multipolymer of alkyl sodium sulfonate formaldehyde condensation products, low-molecular-weight polyacrylic acid salt or low molecular weight phenylethylene-maleic acid salt.
Wetting agent is polyoxyethylene fatty acid ester, polyoxyethylene alkyl phenyl ether or polyoxyethylene succinate.
Sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone or methyl-N-benzimidazole-2-carbamate.
The PH buffer reagent is ammoniacal liquor, organic amine or mineral alkali.
The present invention is easy to use, the high temperature lubricating excellent performance, and the plug long service life, advantages of nontoxic raw materials is harmless, and the feature of environmental protection is good, adapts to the requirement of product restructuring of present pipe mill and quality product.The frictional coefficient of product of the present invention is 0.07 when being 0.05,1250 ℃ when being 0.046,1150 ℃ when being 0.04,1050 ℃ in the time of 950 ℃.
The invention will be further described below in conjunction with embodiment:
Embodiment:
Embodiment 1:
Following components in weight percentage is mixed stirring, gets product:
Flaky graphite 35%
Tri sodium Phosphate 15%
Clay 15%
Natvosol 0.1%
Water 33%
5-chloro-2-methyl-4-isothiazoline-3-ketone 1.9%.
Embodiment 2:
A kind of high-lubricity environment-friendly water-based core rod lubricant agent is characterized in that: be made up of weight components:
Flaky graphite 10～50% (example 10%, 30%, 50%)
Fused salt material 1～20% (example 1%, 10%, 20%)
Mineral binder bond 1～20% (example 1%, 10%, 20%)
Tackifier 0.01～2% (example 0.01%, 1%, 2%)
Water 20～80% (example 20%, 50%, 80%)
Auxiliary material 0～10% (example 0%, 5%, 10%).
The fused salt material is dipotassium hydrogen phosphate, Tri sodium Phosphate, borax, borate, trisodium phosphate or silicate.
Mineral binder bond is an alkali metal salt of clay, wilkinite, phosphoric acid, an alkali metal salt of boric acid or an alkali metal salt of silicic acid.
Tackifier are Natvosol, carboxymethyl cellulose, calcium carboxymethylcellulose, Xylo-Mucine, carboxymethyl starch or sodium starch glycolate.
Auxiliary material is one or more in dispersion agent, wetting agent, sterilant, the PH buffer reagent.
Dispersion agent is the multipolymer of alkyl sodium sulfonate formaldehyde condensation products, low-molecular-weight polyacrylic acid salt or low molecular weight phenylethylene-maleic acid salt.
Wetting agent is polyoxyethylene fatty acid ester, polyoxyethylene alkyl phenyl ether or polyoxyethylene succinate.
Sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone or methyl-N-benzimidazole-2-carbamate.
The PH buffer reagent is ammoniacal liquor, organic amine or mineral alkali.
Claims (1)
1. high-lubricity environment-friendly water-based core rod lubricant agent is characterized in that: be made up of weight components:
Flaky graphite 10～50%
Fused salt material 1～20%
Mineral binder bond 1～20%
Tackifier 0.01～2%
Water 20～80%
Auxiliary material 0～10%;
The fused salt material is dipotassium hydrogen phosphate, borax or borate; Mineral binder bond is an alkali metal salt of clay, wilkinite or boric acid; Tackifier are Natvosol, carboxymethyl cellulose, calcium carboxymethylcellulose, Xylo-Mucine, carboxymethyl starch or sodium starch glycolate; Auxiliary material is one or more in dispersion agent, wetting agent, sterilant, the PH buffer reagent; Dispersion agent is the multipolymer of alkyl sodium sulfonate formaldehyde condensation products, low-molecular-weight polyacrylic acid salt or low molecular weight phenylethylene-maleic acid salt; Wetting agent is polyoxyethylene fatty acid ester, polyoxyethylene alkyl phenyl ether or polyoxyethylene succinate; Sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone or methyl-N-benzimidazole-2-carbamate; The PH buffer reagent is ammoniacal liquor, organic amine or mineral alkali.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810023977XA CN101270317B (en) | 2008-04-17 | 2008-04-17 | High-lubricity environment-friendly water-based core rod lubricant agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810023977XA CN101270317B (en) | 2008-04-17 | 2008-04-17 | High-lubricity environment-friendly water-based core rod lubricant agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101270317A CN101270317A (en) | 2008-09-24 |
| CN101270317B true CN101270317B (en) | 2011-06-08 |
Family
ID=40004547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810023977XA Active CN101270317B (en) | 2008-04-17 | 2008-04-17 | High-lubricity environment-friendly water-based core rod lubricant agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101270317B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5392134B2 (en) * | 2010-02-15 | 2014-01-22 | 新日鐵住金株式会社 | Lubricant for hot rolling tool and surface treatment method for mandrel bar for hot seamless pipe manufacturing |
| CN101914409B (en) * | 2010-08-25 | 2013-01-09 | 新乡学院 | Method for preparing high-temperature resistant lubricant |
| JP5142232B2 (en) * | 2010-12-22 | 2013-02-13 | 新日鐵住金株式会社 | Seamless steel pipe manufacturing method |
| CN103509640A (en) * | 2012-06-26 | 2014-01-15 | 江南大学 | Water-based lubricant containing MoS2 and preparation method thereof |
| CN104327932A (en) * | 2013-07-22 | 2015-02-04 | 江苏华宇碳素有限公司 | Graphite lubricant |
| CN104277895B (en) * | 2014-09-25 | 2016-08-24 | 苏州长盛机电有限公司 | A kind of chain greasisng oil and preparation method thereof |
| CN107118835A (en) * | 2017-05-22 | 2017-09-01 | 句容康泰膨润土有限公司 | A kind of water base bentonite lubricant and preparation method thereof |
| CN107353993A (en) * | 2017-07-10 | 2017-11-17 | 上海尤希路化学工业有限公司 | High alloy oil well pipe hot continuous rolling special core rod lubricant |
| DE102017215713A1 (en) * | 2017-09-06 | 2019-03-07 | Sms Group Gmbh | Method for operating a rolling or metallurgical plant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405286A (en) * | 2001-08-13 | 2003-03-26 | 衡阳市高新技术金化实业有限责任公司 | Water-based graphite core rod lubricant |
| CN1493674A (en) * | 2002-10-28 | 2004-05-05 | 启东尤希路化学工业有限公司 | Water based core rod lubricating agent |
-
2008
- 2008-04-17 CN CN200810023977XA patent/CN101270317B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405286A (en) * | 2001-08-13 | 2003-03-26 | 衡阳市高新技术金化实业有限责任公司 | Water-based graphite core rod lubricant |
| CN1493674A (en) * | 2002-10-28 | 2004-05-05 | 启东尤希路化学工业有限公司 | Water based core rod lubricating agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101270317A (en) | 2008-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101270317B (en) | High-lubricity environment-friendly water-based core rod lubricant agent | |
| CN105441181A (en) | Metal cutting fluid and preparation method thereof | |
| CN101597539B (en) | Method for preparing special lubricating grease and thickening agent for cylinder of electric tool | |
| CN101724502B (en) | Water-soluble rolling oil | |
| CN102994194B (en) | Synthetic multiple-effect lubricant additive and preparation method thereof | |
| CN104031732A (en) | Special micro-lubricant for oil-water-gas-phase micro-lubricating system and preparation method of lubricant | |
| CN101928631A (en) | Environment-friendly high-temperature lubricant for processing metal thermoplasticity and use method thereof | |
| CN101624547A (en) | Anti-rust oil for automobile leaf-spring | |
| CN102703193A (en) | High-temperature water-based core rod lubricant and preparation method | |
| CN103865623B (en) | A kind of multi-functional nontoxic aqueous rustproof cutting liquid | |
| CN110734804B (en) | Nano cutting oil and preparation method and application thereof | |
| CN104073322A (en) | Metal processing liquid and preparation method thereof | |
| CN113474442B (en) | Lubricant for metal hot forming | |
| CN104498168A (en) | Water-based lubricant for metal stamping | |
| CN103666721A (en) | Corrosion-free anti-wear semi-synthetic cutting fluid and preparation method thereof | |
| CN109233955B (en) | High-performance environment-friendly water-based punch oil and preparation method thereof | |
| CN103484203A (en) | Lubricating grease composition suitable for small rolling mill bearing and preparation method thereof | |
| CN103589495A (en) | Green environment-friendly cutting fluid | |
| CN105154195A (en) | Extreme pressure complex grease composition | |
| CN107629859A (en) | A kind of water-base cutting fluid | |
| CN107573992A (en) | Extreme-pressure anti-wear and easily scattered additive and preparation method and application for oil for drawing copper wire | |
| CN103305322B (en) | Lubricant for hardware processing | |
| CN103725401A (en) | Water-soluble lubricating antirust cutting fluid and preparation method thereof | |
| CN102899129A (en) | Powdery graphite core rod lubricant and preparation method thereof | |
| CN102703186A (en) | Medium-temperature high-efficiency cold drawing lubricant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |