CN101270015B - Blasting fuse of high-safety firecracker and preparation method thereof - Google Patents

Blasting fuse of high-safety firecracker and preparation method thereof Download PDF

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Publication number
CN101270015B
CN101270015B CN2008100312582A CN200810031258A CN101270015B CN 101270015 B CN101270015 B CN 101270015B CN 2008100312582 A CN2008100312582 A CN 2008100312582A CN 200810031258 A CN200810031258 A CN 200810031258A CN 101270015 B CN101270015 B CN 101270015B
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China
Prior art keywords
yarn
medicine
potassium
container
medicines
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Expired - Fee Related
Application number
CN2008100312582A
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Chinese (zh)
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CN101270015A (en
Inventor
黄玉国
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LILING SHENMA FIREWORKS CO Ltd
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LILING SHENMA FIREWORKS CO Ltd
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Priority to CN2008100312582A priority Critical patent/CN101270015B/en
Publication of CN101270015A publication Critical patent/CN101270015A/en
Application granted granted Critical
Publication of CN101270015B publication Critical patent/CN101270015B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The present invention relates to a preparation method of a safe firing cable of firecrackers. In the method, yarn is used as a carrier to infuse the following medicines, which are used raw materials, according to the following steps. The medicines comprise potassium perchlorate, potassium terephthalic acid, ammonium dichromate, polyethylene alcohol, moisture resistant agent, charcoal and sulfur. The method has the following steps: the potassium perchlorate, the potassium terephthalic acid, the ammonium dichromate, the charcoal, the sulfur and the polyethylene alcohol are arranged in a container according to the weight ratio; water with a certain proportion is added into the container; the mixture is stirred so that the medicines can be dissolved in the water; then the moisture resistant agent is added; and the mixture is mixed well; the yarn is infused in the container, taken out and then sent to a drying device to be dried; thus the safe firing cable can be prepared. In the method, the yarn is used as the carrier to infuse the medicines of the firing cable; the production is simple; the amount of the medicines is reduced; the method is safe; and the cost is reduced. The application of the potassium perchlorate has the advantages of low oxygen content, low decomposition temperature, excellent stability and low sensitivity. Thus the application of the potassium perchlorate is superior to the application of potassium chlorate. The firing cable solves the problems of storage, transportation and insecurity in use.

Description

A kind of blasting fuse of high-safety firecracker and preparation method thereof
Technical field
The present invention relates to a kind of blasting fuse of high-safety firecracker; Be specially adapted to the firing line of firecrackers firing line or engineering explosion explosive.
Background technology
In the firecrackers firing line or the making of engineering explosion explosive firing line of transmission, all be to adopt Potcrate as oxygenant, Potcrate is because of its oxygen level height, decomposition temperature is low, relative price is low, after combustiblematerials mixes, blast performance is good, but because poor stability, fusing point is low, and mix the back susceptibility with other combustiblematerialss high, accidentally, careless manipulation and cause the burning and explosion hazard, to bring about great losses to the country and people, so State Council's invention regulation in 2002 forbids to use Potcrate preparation fireworks and firecrackers, so the technician of manufacturer begins to develop safety firing cable, some producers begin to adopt potassium perchlorate to replace Potcrate, but all undesirable because of effect, and can't reduce cost, implement as yet.Simultaneously, the making great majority of firing line adopt the paper packaging medicine to carry out hand rubbing firing line or machine-processed firing line, its defective is: because complex production process and complexity and its elasticity differ, cause lead-in wire in the firing line to wrap up in the medicinal powder maldistribution of bag easily, humidity resistance is poor in addition, causes the burst time different in size, and in friction process also idol spontaneous phenomenon arranged, so poor safety performance, the production cost height, efficient is low.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, provide a kind of preparation technology simply, not chloracid potassium, not sulfur-bearing, do not contain composition such as wooden carbon, adopt the blasting fuse of high-safety firecracker of yarn direct impregnation blast medicine.
Technical scheme of the present invention: the preparation method of the firing line of a kind of safety firecracker or engineering explosion 4 prescribe medicines is characterized in that it is that yarn is made firing line as carrier impregnation following raw materials according medicine with by following step:
The weight proportion of each material medicine is:
Potassium perchlorate 50~70%, to benzene dipotassium potassium hydrogen phthalate 3~10%, ammonium dichromate 5~20%,
Polyvinyl alcohol 5~10%, non-blushing thinner 5~8%, charcoal 3~15%, sulphur 1~15%,
Above each component percentage composition sum is 100%;
Each step is:
(1) by above-mentioned weight proportion, with potassium perchlorate, benzene dipotassium potassium hydrogen phthalate, ammonium dichromate, charcoal, sulphur and polyvinyl alcohol are placed in the container, add water in 1: 1 ratio and stirred 3~10 minutes, it is soluble in water to make it medicine, mixes non-blushing thinner again and stirs and get final product; Its non-blushing thinner adopts conventional non-blushing thinner.
(2) yarn is placed in the container flood, promptly yarn enters and makes it yarn in the pharmaceutical liquid of container and stick slowly to extract out behind the medicine to send into and dry in the drying unit;
Blasting fuse of high-safety firecracker that the present invention prepares according to the method described above or engineering blast medicine firing line are important innovations parts of the present invention.
The present invention adopts potassium perchlorate and ammonium dichromate successively as oxygenant and strong oxidizer, its potassium perchlorate decomposition temperature is higher, chemical property is more stable than Potcrate, the mechanical sensitivity degree is low, do not deposit separately and can explode and burn, use as oxygenant, greatly reduce the susceptibility of blasting powders, improved security.Adopt polyvinyl alcohol as tackiness agent, make medicine have viscosity; Potassium benzoate mixes in the medicine as sanitas, makes firing line play preservative activity.When making firing line, mix non-blushing thinner at medicine, make firing line have humidity resistance.Yarn floods its yarn soup and sticks medicine and as combustiblematerials, impel blasting powders to be easy to igniting as carrier.
The present invention adopts yarn as carrier, by yarn dipping firing line medicine, reaches the minimizing dose, not only safety, manufacture craft is very simple but also reduce cost; Firing line implant in the firecrackers or engineering blast medicine in, its rate of explosion and fuel value and sound value are better than Potcrate and go between.These five kinds of medicines of the present invention are made firing line by weight ratio, solved that firing line is deposited, unsafe problem in the transportation, use.Simultaneously, solved the expensive problem of potassium perchlorate.Gordian technique of the present invention is: adopt yarn as the above-mentioned firing line medicine of carrier impregnation, its manufacture craft is simple, do not need loaded down with trivial details and complicated paper packaging medicine to carry out the production technique of hand rubbing or mechanism, but directly adopt yarn is flooded said medicine, the yarn that will stick medicine is then slowly extracted out to send in the drying unit and is dried, safety firing cable.
Safety firing cable of the present invention adopts potassium perchlorate, oxygen level low, low, the good stability of decomposition temperature, and susceptibility is low, so security is better than the Potcrate firing line.
Embodiment
The preparation method of a kind of safety firecracker or engineering blast medicine firing line, it is yarn to be made carrier impregnation following raw materials according medicine and step is made,
The weight proportion of each material medicine is:
Potassium perchlorate 55%, to benzene dipotassium potassium hydrogen phthalate 5%, ammonium dichromate 15%, polyvinyl alcohol 8%, non-blushing thinner 7%, charcoal 6%, sulphur 4%,
Each step is:
(1) by above-mentioned weight proportion, with potassium perchlorate, benzene dipotassium potassium hydrogen phthalate, ammonium dichromate, charcoal, sulphur and polyvinyl alcohol are placed in the container, add water in 1: 1 ratio and stirred 5 minutes, it is soluble in water to make it medicine, mixes non-blushing thinner again and stirs and get final product;
(2) yarn placed in the container flood, promptly yarn enter make it in the pharmaceutical liquid of container yarn stick medicine slowly extract out send into dry in the drying unit blasting fuse of high-safety firecracker or engineering explosive firing line.
The present invention adopts yarn as carrier, by yarn dipping lead-in wire medicine, reaches the minimizing dose, and not only safety but also reduce cost, and rate of explosion and fuel value and sound value are better than the chloric acid firecrackers.Solved that Potcrate is deposited, unsafe problem in the transportation, use.Solved the expensive problem of potassium perchlorate.Its manufacture craft is simple, adopt compositions such as potassium perchlorate, oxygen level is low, low, the good stability of decomposition temperature, susceptibility is low, does not need the paper packaging medicine to carry out the production technique of hand rubbing or mechanism, but directly adopt yarn is flooded said medicine, medicine is bonded on the yarn, the yarn that will be stained with medicine then slowly extract out send into dry in the drying unit safety firing cable.

Claims (2)

1. the preparation method of a blasting fuse of high-safety firecracker is characterized in that described blasting fuse of high-safety firecracker is that yarn is made as carrier impregnation following raw materials according medicine with by following step:
The weight proportion of described each material medicine is:
Potassium perchlorate 50~70%, to benzene dipotassium potassium hydrogen phthalate 3~10%, ammonium dichromate 5~20%,
Polyvinyl alcohol 5~10%, non-blushing thinner 5~8%, charcoal 3~15%, sulphur 1~15%,
Above each component percentage composition sum is 100%;
Described each step is:
(1) by above-mentioned weight proportion, with potassium perchlorate, benzene dipotassium potassium hydrogen phthalate, ammonium dichromate, charcoal, sulphur and polyvinyl alcohol are placed in the container, add water in 1: 1 ratio and stirred 3~10 minutes, it is soluble in water to make it medicine, mixes non-blushing thinner again and stirs and get final product;
(2) yarn is placed in the container flood, promptly yarn enters and makes it yarn in the pharmaceutical liquid of container and stick slowly to extract out behind the medicine to send into and dry in the drying unit.
2. the blasting fuse of high-safety firecracker of the method for claim 1 preparation.
CN2008100312582A 2008-05-09 2008-05-09 Blasting fuse of high-safety firecracker and preparation method thereof Expired - Fee Related CN101270015B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008100312582A CN101270015B (en) 2008-05-09 2008-05-09 Blasting fuse of high-safety firecracker and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008100312582A CN101270015B (en) 2008-05-09 2008-05-09 Blasting fuse of high-safety firecracker and preparation method thereof

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CN101270015A CN101270015A (en) 2008-09-24
CN101270015B true CN101270015B (en) 2010-12-22

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101619009B (en) * 2009-06-22 2011-12-21 鲁向华 Fireworks safety firing cable and manufacturing method thereof
CN102701890A (en) * 2011-12-08 2012-10-03 萍乡市焰花鞭炮科学研究所 Potassium perchlorate ignition harness
CN102718614B (en) * 2012-06-25 2014-12-10 李炳 Explosive composition for preparing fireworks and firecracker-fuse
CN102807462B (en) * 2012-09-02 2015-07-29 利川市忠路烟花爆竹产销有限责任公司 A kind of firecrackers lead live wire medicine
CN102788536A (en) * 2012-09-02 2012-11-21 利川市忠路烟花爆竹产销有限责任公司 Production equipment of firecracker ignition harness
CN102924197B (en) * 2012-11-12 2014-11-19 邓卫科 Drying drum and starch guiding machine containing the same
CN103626612A (en) * 2013-12-02 2014-03-12 湖南明义烟花集团有限公司 Environment-friendly sulfur-free propellant formula
CN104389228B (en) * 2014-09-29 2016-06-08 长沙理工大学 A kind of preparation method of firecrackers lead line base paper
CN104909968A (en) * 2015-06-10 2015-09-16 贵州润晋碳元素材料有限公司 Moistureproof waterproof treatment method for potassium perchlorate
CN106397075B (en) * 2016-08-31 2018-03-13 万载县建坤化工有限公司 A kind of firecrackers safety firing cable composition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640858A (en) * 2004-01-12 2005-07-20 刘青春 Fireworks and fire cracker rapid ignition charge without chlorate and perchlorate
CN1793086A (en) * 2005-11-24 2006-06-28 醴陵神马花炮有限公司 Safety firecracker

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640858A (en) * 2004-01-12 2005-07-20 刘青春 Fireworks and fire cracker rapid ignition charge without chlorate and perchlorate
CN1793086A (en) * 2005-11-24 2006-06-28 醴陵神马花炮有限公司 Safety firecracker

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