CN101261380B - Electro-optic device and electronic apparatus - Google Patents

Electro-optic device and electronic apparatus Download PDF

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Publication number
CN101261380B
CN101261380B CN2008100826961A CN200810082696A CN101261380B CN 101261380 B CN101261380 B CN 101261380B CN 2008100826961 A CN2008100826961 A CN 2008100826961A CN 200810082696 A CN200810082696 A CN 200810082696A CN 101261380 B CN101261380 B CN 101261380B
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mentioned
layer
gas barrier
barrier film
electro
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CN101261380A (en
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樱井慎二
日向章二
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Japan Display Inc
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Sanyo Epson Imaging Devices Corp
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Publication of CN101261380A publication Critical patent/CN101261380A/en
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/28Adhesive materials or arrangements

Abstract

The present invention relates to a photoelectric device and an electronic apparatus thereof, and provides an electronic apparatus installed with the photoelectric device which restrains the decrease of the displaying of the display surface caused by the gas on the protector for protecting the display panel. The liquid crystal display device (1) comprises a display panel (11), a cover (12) which is configured at the viewing side of the display panel (11), an adhering material (14) which is provided between the cover (12) and the display panel (11) for adhering with the cover (12) and the display panel (11), and a gas blocking film (16) which is provided on the surface at the side opposite to the viewing side of the cover (12).

Description

Electro-optical device and electronic equipment
Technical field
The present invention relates to electro-optical device and electronic equipment, particularly relate to electro-optical device and electronic equipment with transparency protected body.
Background technology
In the past, as electro-optical device is known display device such as liquid crystal indicator, organic light-emitting display device, plasm display device were arranged.In these display device,, adopt by plastics etc. and form fender in order to prevent to impact.For example, display panel and fender form (for example, with reference to patent documentation 1) with adhering to the sheet material applying.
Patent documentation 1: the spy opens the 2006-290960 communique
Various display device are under the various environment owing to may be used for electronic equipment such as portable phone sometimes.Portable phone places hot environment sometimes, for example, and in the automobile under the hot weather.
But fender is under the situation of plastics etc., because absorption such as plastics comprise the gases such as air of water, carbon dioxide, nitrogen etc., and the gas that discharge is sometimes at high temperature absorbed.Under the sort of situation, the gas that takes place from fender makes to adhere between sheet material and the fender and produces bubble sometimes.
If, when seeing the display surface of display panel, can regard bubble, spot, island etc. as adhering to gassing between sheet material and the fender.The result is that the display surface of liquid crystal indicator is attractive in appearance have been worsened.In addition, spot of bubble etc. makes watching property of the display image decline of display panel sometimes.
Summary of the invention
Therefore, one of purpose of the present invention provides the electro-optical device of display surface that gas that a kind of inhibition takes place from the protective of protection display panel causes decline attractive in appearance and the electronic equipment of this kind device is housed.
Use example 1: should have: electrooptic panel with the electro-optical device of example; Transparency protected body is configured in the side of watching of above-mentioned electrooptic panel; Adhesives is arranged between above-mentioned electrooptic panel and the above-mentioned transparency protected body; And gas barrier film, be arranged on above-mentioned transparency protected body with the above-mentioned surface of watching the opposite side of side on.
According to such structure, can provide inhibition to cause the electro-optical device of display surface decline attractive in appearance from the gas of the protective generation of protection display panel.
Use example 2: in the electro-optical device of above-mentioned application example, the above-mentioned gas barrier film is preferably inoranic membrane.
According to such structure, can prevent the generation of bubble.
Use example 3: in the electro-optical device of above-mentioned application example, above-mentioned inoranic membrane should comprise 1 layer of silicon oxide film and 1 layer of aluminium oxide.
According to such structure, can prevent the generation of bubble reliably.
Use example 4: in the electro-optical device of above-mentioned application example, above-mentioned inoranic membrane should comprise 2 layers of silicon oxide film.
According to such structure, can prevent the generation of bubble reliably.
Use example 5: in the electro-optical device of above-mentioned application example, above-mentioned inoranic membrane should comprise totally 3 layers in 2 layers of silicon oxide film and 1 layer of aluminium oxide.
According to such structure, can prevent the generation of bubble reliablely.
Use example 6: in the electro-optical device of above-mentioned application example, above-mentioned 1 layer of aluminium oxide should form to such an extent that be connected to above-mentioned transparency protected body, is provided with to such an extent that connect any one deck in above-mentioned 2 layers of silicon oxide film.
According to such structure, can prevent the generation of bubble reliablely.
Use example 7: in the electro-optical device of above-mentioned application example, the one deck in above-mentioned 2 layers of silicon oxide film is arranged on above-mentioned electrooptic panel one side, and another layer is preferably the silicon monoxide film.
According to such structure, can prevent the generation of bubble reliablely.
Use example 8: in the electro-optical device of above-mentioned application example, dispose touch-screen between above-mentioned electrooptic panel and above-mentioned transparency protected body, above-mentioned touch-screen is fixed on the above-mentioned transparency protected body across above-mentioned gas barrier film and above-mentioned adhesives.
According to such structure,, also can provide the electro-optical device that can suppress to cause display surface decline attractive in appearance from the gas that the protective of protection display panel takes place even be provided with under the situation of touch-screen.
Use example 9: should have above-mentioned electro-optical device with the electronic equipment of example.
According to such structure, can provide the electronic equipment that can suppress to cause display surface decline attractive in appearance from the gas that the transparency protected body of protection display panel takes place.
Description of drawings
Fig. 1 is the structural drawing of the structure of the expression liquid crystal indicator relevant with embodiments of the invention;
Fig. 2 is the structural drawing of the structure of the expression gas barrier film relevant with embodiments of the invention;
Fig. 3 is the structural drawing of the another kind of structure of the expression gas barrier film relevant with embodiments of the invention;
Fig. 4 is the structural drawing of the another kind of structure of the expression gas barrier film relevant with embodiments of the invention;
Fig. 5 is at the table that expression permeability experimental data under the situation of gas barrier film is set;
The manufacture method of the liquid crystal indicator that Fig. 6 explanation is relevant with embodiments of the invention;
Fig. 7 represents to comprise the example of structure of the liquid crystal indicator of touch-screen;
Fig. 8 represents to comprise another example of structure of the liquid crystal indicator of touch-screen;
Fig. 9 represents to comprise another example of structure of the liquid crystal indicator of touch-screen; And
Figure 10 is the outward appearance skeleton view of expression as the portable phone of electronic equipment.
The explanation of symbol
1,1A, 1B, 1C... liquid crystal indicator 11... display panel 12... cover 13 ... polarization plate 14,15... adhesives 16... gas barrier film 17... touch-screen
Embodiment
Below, with reference to the description of drawings embodiments of the invention.
(structure)
At first, the structure of the electro-optical device relevant with present embodiment is described according to Fig. 1.Fig. 1 is the structural drawing of the structure of the expression liquid crystal indicator relevant with present embodiment.Below, be example explanation present embodiment with liquid crystal indicator as a kind of electro-optical device.
In Fig. 1, liquid crystal indicator 1 comprises as the display panels 11 of electrooptic panel with as the cover 12 of transparency protected body and polarization plate 13 and constitute.In the picture display face of display panel 11, the glass transparent substrate is set, in its surface, 15 layers polarization plate 13 is set across transparent adhesives.On the face of the opposite side of display panel 11 1 sides of polarization plate 13, cover 12 is set across 14 layers of transparent adhesivess.On the face of adhesives 14 1 sides of cover 12 gas barrier film 16 is set.In other words, on cover 12 bottom surfaces, gas barrier film 16 is set.
Display panel 11 comprises liquid crystal layer in inside, adds electric field on liquid crystal layer, and control optical transmission etc. form image with this with transmitted light or reflected light.Specifically, display panel 11 has 2 pieces of transparency carriers, between its 2 pieces of transparency carriers, is provided as the liquid crystal layer of electro-optical substance, a plurality of electrodes of configuration on 2 pieces of substrates face toward each other.These a plurality of electrodes are formed in the zone of plane overcrossing point can control the pixel that shows form independently, thereby, can carry out image and show.
As shown in Figure 1, on display panel 11, polarization plate 13 is stacked through adhesives 15, and on polarization plate 13, cover 12 is stacked through adhesives 14, constitutes liquid crystal indicator 1.
Such liquid crystal indicator is configured in the framework of electronic equipment, and the user can be from covering 12 1 sides, in other words, watches side to see being presented at the image on the display panel 11.
The sheet material of forming by plastics as the cover 12 of the protective that prevents usefulness such as impacting.Cover 12 thickness that have about 0.2mm~2mm.Cover 12 material is the compound substance, CR39 of PMMA (polymethylmethacrylate), polycarbonate, polycarbonate and PMMA etc.
On the face of the table side (watching side) of polarization plate 13 and inboard, the sheet of fitting respectively adhesives 14,15. Adhesives 14,15 is colloidal transparent components, and for example, propylene resin, silicones are resin, epoxy resin or are made up of their composite bed.
Polarization plate 13 for example has the thickness of 100 μ m.The adhesives 14 of cover 12 sides of polarization plate 13 has the thickness of 25 μ m~400 μ m, and the adhesives 15 of display panel 11 sides has the thickness of 25 μ m~50 μ m.
Polarization plate 13 for example, has 3 layers of structure.These 3 layers, have 2 layers of TAC (triacetyl cellulose) and be arranged on 1 layer of PVA (polyvinyl alcohol (PVA)) between these 2 layers, totally 3 layers.
In addition, on the surface of cover 12 adhesives 14 1 sides, gas barrier film 16 covers setting by evaporation, coating, ion beam evaporation, sputter or CVD (chemical vapor deposition).Gas barrier film 16 for example, has the thickness of 200nm under the situation of aftermentioned silicon oxide film.
Gas barrier film 16 is used for preventing to comprise the display device of liquid crystal indicator 1, for example under the medium hot environment of car from covering the generation of 12 gases of discharging.As a result, can suppress to make the decline attractive in appearance of display surface from gas gassing on adhesives 14,15 that polarization plate 13 takes place.
Fig. 2 is the structural drawing of the structure of expression gas barrier film.
The gas barrier film 16 of Fig. 2 is inoranic membranes of 3 layers of structure.For example, gas barrier film 16 is by silicon monoxide (SiO) layer 21, silicon dioxide (SiO 2) layer 22 and aluminium oxide (Al 2O 3) layer 23 totally 3 layers of composition.In this case, silicon dioxide (SiO 2) layer 22 is configured in adhesives 14 1 sides, aluminium oxide (Al 2O 3) layer 23 is configured in cover 12 1 sides, silicon monoxide (SiO) layer 21 is configured in aluminium oxide (Al 2O 3) layer 23 and silicon dioxide (SiO 2) layer 22 two-layer between.In other words, form aluminium oxide (Al successively from covering 12 1 sides 2O 3) layer 23, silicon monoxide (SiO) layer 21, silicon dioxide (SiO 2) layer 22.
Aluminium oxide (Al under 3 layers situation 2O 3) layer 23, silicon monoxide (SiO) layer 21 and silicon dioxide (SiO 2) layer 22 thickness, be respectively below the above 45nm of 25nm, below the above 45nm of 15nm, below the above 150nm of 100nm.Then, their optimum thickness, aluminium oxide (Al 2O 3) layer 23 is 30nm, silicon monoxide (SiO) layer 21 is 30nm, silicon dioxide (SiO 2) layer 22 is 130nm.
In addition, gas barrier film 16 also can be without the structure of Fig. 2, and uses other structures.Fig. 3 is the structural drawing of the another kind of structure of expression gas barrier film.
As shown in Figure 3, gas barrier film 16A is the inoranic membrane of 2 layers of structure.These 2 layers of structures from covering 12 1 sides, are aluminium oxide (Al 2O 3) layer 23 and silicon dioxide (SiO 2) layer 22.In addition, these 2 layers of structures also can be following structures.For example, from covering 12 1 sides, by aluminium oxide (Al 2O 3) layer 23 and silicon monoxide (SiO) layer 21 composition.In addition, as another example of 2 layers of structure, from covering 12 1 sides, by silicon monoxide (SiO) layer 21 and silicon dioxide (SiO 2) layer 22 composition.
Thickness under 2 layers the situation is different because of composition respectively, have below shown in 3 kinds of situations.
At aluminium oxide (Al 2O 3) layer 23 and silicon dioxide (SiO 2) under layer 22 the situation, thickness is respectively below the above 45nm of 25nm, below the above 150nm of 100nm.Then, their optimum thickness, aluminium oxide (Al 2O 3) layer 23 is 30nm, silicon dioxide (SiO 2) layer 22 is 130nm.
At aluminium oxide (Al 2O 3) under the situation of layer 23 and silicon monoxide (SiO) layer 21, thickness is respectively below the above 45nm of 25nm, below the above 45nm of 15nm.Then, their optimum thickness, aluminium oxide (Al 2O 3) layer 23 is 30nm, silicon monoxide (SiO) layer 21 is 30nm.
Silicon monoxide (SiO) layer 21 and silicon dioxide (SiO 2) under layer 22 the situation, thickness is respectively below the above 95nm of 45nm, below the above 150nm of 100nm.Then, their optimum thickness, silicon monoxide (SiO) layer 21 is 70nm, silicon dioxide (SiO 2) layer 22 is 130nm.
In addition, gas barrier film 16 also can be the inoranic membrane of 1 layer of structure.Fig. 4 is the structural drawing of the another kind of structure of expression gas barrier film.
As shown in Figure 4, the inoranic membrane of 1 layer of structure is silicon monoxide (SiO) layer 21.In addition, the inoranic membrane of this 1 layer of structure also can be following structure.For example, the composition of this inoranic membrane is aluminium oxide (Al 2O 3) layer 23 or silicon dioxide (SiO 2) layer 22.
Under 1 layer the situation, their thickness is different because of film build method separately respectively, has 4 kinds shown below.
At first, the 1st kind, under the situation that makes silicon monoxide (SiO) layer 21 film forming by evaporation or coating, thickness is below the above 95nm of 45nm, best 70nm.
Then, the 2nd kind, passing through aluminium oxide (Al 2O 3) layer 23 film forming situation under, below the above 45nm of thickness 25nm, best 30nm.
In addition, the 3rd kind, make silicon dioxide (SiO by the ion beam evaporation 2) layer 22 film forming situation under, below the above 250nm of thickness 150nm, best 200nm.
At last, the 4th kind, make silicon dioxide (SiO by sputter 2) layer 22 film forming situation under, below the above 150nm of thickness 50nm, best 100nm.
In addition, gas barrier film 16 also can be an organic membrane.As organic membrane, for example, also can be 1 layer of epoxy resin film.In addition, as organic membrane, for example, except that epoxy resin, also can be that Parylene system, silicones are 1 tunic.Under the situation of epoxy, be arranged on the cover 12 by coating.Under the sort of situation, the thickness of gas barrier film 16 is number μ m.
In addition, carry out on the surface that is printed on this gas barrier film 16 in the appearance design.
Wherein, the gas permeation degree experimental result of gas barrier film 16,16A is shown in Fig. 5.
Fig. 5 is the table that expression is provided with permeability experimental data under the situation of (3 layers and 2 layers) and no gas barrier film under the situation of two gas barrier films.In this experiment, thickness is as follows.Under 3 layers the situation, the thickness of silicon monoxide (SiO) layer 21 is 30nm, aluminium oxide (Al 2O 3) layer 23 thickness be 30nm, silicon dioxide (SiO 2) layer 22 thickness be 130nm.Under 2 layers the situation, the thickness of silicon monoxide (SiO) layer 21 is 70nm, silicon dioxide (SiO 2) layer 22 thickness be 130nm.
Fig. 5 table laterally, from the left side, the expression situation of not establishing gas barrier film fully respectively, 3 kinds of situations of the situation (with reference to Fig. 3) of 3 layers situation (with reference to Fig. 2) and 2 layers.Vertical what show, from the top down,, represent carbon dioxide (CO successively as the gaseous species that sees through 2), nitrogen (N 2) and oxygen (O 2) the gas permeation degree separately and the total of 3 kinds of gas permeation degree.
The mensuration of permeability adopts the gas permeation determinator to carry out with differential pressure method, is 760mmHg at test pressure, and measuring temperature is 80 ℃, and seeing through area is 38cm 2Carry out under the situation of (square centimeter).The unit of permeability is cm 3/ m 224hatm.
The result of test is that permeability is minimum under 3 layers the situation, for the total (157.5) under the permeability situation of no gas barrier film, roughly be 20% (=32.45/157.5).Under 2 layers the situation, permeability is time low, for the situation of no gas barrier film, be roughly 32% (=50.19/157.5).In addition, under 1 layer the situation, transmitance is identical with 2 layers situation.
In addition, although do not illustrate in the drawings, covering 12 is compound substances of PMMA and polycarbonate, and gas barrier film 16 is 3 layers of structure, when adhesives 14 is the combination of propylene resin, because permeability is low, is desirable.
In addition, cover 12 is polycarbonate, and gas barrier film 16 is 2 layers of structure, and adhesives 14 is epoxies when being the combination of resin, and permeability is low, is desirable.
(manufacture method)
The manufacture method of the liquid crystal indicator 1 of Fig. 6 key diagram 1.
At first, respectively in the surface and the bottom surface of polarization plate 13, the adhesives 14 and 15 of applying sheet.The polarization plate 13 of adhesives 14 and 15 of having fitted is cut into the size of 1 liquid crystal indicator 1.
Then, on the surface of display panel 11, make the unit 100 that display panel 11 and polarization plate 13 are fitted, sealing adhesives 15.
On the other hand, cover the state that 12 former states keep big plate unchangeably, on a face of the cover 12 of this big plate, form gas barrier films 16 by evaporations such as coating or sputters.Then, cutting is provided with the big plate cover 12 of gas barrier film 16, makes being fitted in a unit 101 on the display panel 11.
2 unit 100 that make and 101, pressurizing attaching makes gas barrier film 16 be close to adhesives 14, finishes liquid crystal indicator shown in Figure 11.This applying also can be pressurizeed and be heated and carry out.
In addition, fitted in 2 unit 100 and 101, make gas barrier film 16 be close to adhesives 14, finish liquid crystal indicator 1.
Variation
Then, do an explanation with regard to variation.
In liquid crystal indicator, touch-screen is set sometimes.Fig. 7 to Fig. 9 represents to comprise the structure of the liquid crystal indicator of touch-screen.Liquid crystal indicator has under the situation of touch-screen, watches the side configuration cover as protective material at its touch-screen.Touch-screen for example is the electrostatic capacitive panel.
In liquid crystal indicator 1A shown in Figure 7, in Fig. 1 polarization plate 13 display panels 11 1 sides, touch-screen 17 is fitted on the polarization plate 13 through adhesives 15, and the space segment 18 with predetermined distance is set between touch-screen 17 and the display panel 11.
In liquid crystal indicator 1B shown in Figure 8, in Fig. 1 polarization plate 13 covers 12 1 sides, touch-screen 17 is fitted on the polarization plate 13, in addition through adhesives 14, cover 12 1 sides at touch-screen 17 are provided with adhesives 19, fit through adhesives 19 touch-screens 17 and cover 12.In this case, configuration gas barrier film 16 between cover 12 and the adhesives 19.
In liquid crystal indicator 1C shown in Figure 9, in Fig. 1 polarization plate 13 covers 12 1 sides, through space segment 20 touch-screen 17 is set, in addition with predetermined distance, cover 12 1 sides of touch-screen 17 are provided with adhesives 19, fit through adhesives 19 touch-screens 17 and cover 12.In this case, configuration gas barrier film 16 between cover 12 and the adhesives 19.
In each liquid crystal indicator of the Fig. 7 to Fig. 9 as above, gas barrier film 16 can both prevent that gas is from covering 12 discharges.
In addition, electro-optical device of the present invention can be applied to various liquid crystal indicators.In addition, display panels not only, the present invention can be used for the device various electro-optical devices such as (Field Emission Display, surface conduction electron emission display devices etc.) of el light emitting device, Organnic electroluminescent device, plasm display device, electrophoretic display apparatus, employing arresting element equally.
Then, just have the liquid crystal indicator relevant and do an explanation as the electronic equipment of display device with the foregoing description.Figure 10 is the skeleton view of expression as the outward appearance of the portable phone of electronic equipment.As shown in figure 10, portable phone 1200 with receiving mouth 1204, mouth piece 1206, also has the liquid crystal indicator 1 that is provided with as above-mentioned electro-optical device except that a plurality of action buttons 1202.
As the electronic equipment that can adopt according to electro-optical device of the present invention, portable data assistance), portable personal computer, digital camera, on-board screen, DITEC Digital Television Camera, LCD TV, find a view type or direct viewing type video tape recorder, auto-navigation system device, beeper, electronics miscellanies basis, desk-top computer, word processor workstation, television telephone set, POS terminating machine etc. except that portable phone, also has PDA (personal digital assistant:.
The invention is not restricted to the foregoing description, in the scope that does not change main points of the present invention, can carry out various changes and modification etc.

Claims (4)

1. electro-optical device is characterized in that having:
Electrooptic panel;
Be configured in the transparency protected body of watching side of above-mentioned electrooptic panel;
Be arranged on the adhesives between above-mentioned electrooptic panel and the above-mentioned transparency protected body; With
Be arranged on above-mentioned transparency protected body and the above-mentioned gas barrier film of watching on the opposite side surface of side;
The above-mentioned gas barrier film comprises 2 layers of silicon oxide film;
One deck of above-mentioned 2 layers of silicon oxide film is arranged on the silicon dioxide film of above-mentioned electrooptic panel side, and another layer is the silicon monoxide film.
2. the electro-optical device of claim 1 record, the above-mentioned gas barrier film also comprises 1 layer of aluminium oxide;
Above-mentioned 1 layer of aluminium oxide forms with above-mentioned transparency protected body and is connected.
3. the electro-optical device of claim 1 record is characterized in that dispose touch-screen between above-mentioned electrooptic panel and above-mentioned transparency protected body, above-mentioned touch-screen is fixed on the above-mentioned transparency protected body across above-mentioned gas barrier film and above-mentioned adhesives.
4. an electronic equipment is characterized in that, has the electro-optical device of any one record in the claim 1 to 3.
CN2008100826961A 2007-03-08 2008-03-06 Electro-optic device and electronic apparatus Active CN101261380B (en)

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JP2007268672A JP4544287B2 (en) 2007-03-08 2007-10-16 Electro-optical device and electronic apparatus
JP268672/2007 2007-10-16

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KR100988214B1 (en) 2010-10-18
JP4544287B2 (en) 2010-09-15
TW200849166A (en) 2008-12-16
KR20080082489A (en) 2008-09-11
TWI416442B (en) 2013-11-21
JP2008250286A (en) 2008-10-16

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