CN101244943A - Wedding agent for large-scale blast furnace stemming and blast furnace stemming - Google Patents
Wedding agent for large-scale blast furnace stemming and blast furnace stemming Download PDFInfo
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- CN101244943A CN101244943A CNA2008100546759A CN200810054675A CN101244943A CN 101244943 A CN101244943 A CN 101244943A CN A2008100546759 A CNA2008100546759 A CN A2008100546759A CN 200810054675 A CN200810054675 A CN 200810054675A CN 101244943 A CN101244943 A CN 101244943A
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Abstract
The invention relates to a large-scale blast furnace stemming used bond and the blast furnace stemming thereof, and the components of the bond (the weight proportion) is: coal tar: 10 to 60, phenolic resin: 5 to 20 and asphalt: 20 to 80. The asphalt is high temperature powder asphalt or high polymerization asphalt, and the softening point is no less than 100 DEG C; the bond is made by stirring under 50 DEG C to 70 DEG C. The blast furnace stemming with the bond is the large-scale blast furnace stemming of the invention. The large-scale blast furnace stemming used bond has the advantages that: (1) the bond which is fast in sintering speed can adjust structure defects and improve the rate of residual carbon at the same time, and the stemming slag resistance, the sintering strength and the opening performance can be improved obviously; (2) when in use, the bond is superior to tar in the aspect of environmental and healthy, and the product stemming is environment-friendly and has less odor; (3) the stemming prepared by the bond is lower than resin-bond stemming in price; (4) the plasticity of the stemming prepared by the bond is better than that of the resin-bond stemming and is equivalent to that of tar-bond stemming.
Description
Technical field
The present invention relates to a kind of large blast furnace stemming wedding agent and large blast furnace stemming thereof.
Background technology
Blast furnace mud has water, tar, resin and multiple wedding agent to unite the wedding agent of use with wedding agent.The water system blast furnace mud can only be used for small blast furnace, most tar and the resinoid bonds of adopting of large blast furnace stemming, and tar is widely adopted in conjunction with the stemming excellent property, but the shortcoming of following several respects is arranged: the harmful fugitive constituent of part is arranged in (1) production and the use; (2) the volatile gases evaporation rate is slow, causes tar articulated system sintering velocity slow.It is suitable that existing resin-bonded stemming and this wedding agent combine the stemming performance, but have following shortcoming: (1) poor plasticity, and it is poor to reach workability; (2) shortcoming on the high side.
Summary of the invention
In order to overcome the above-mentioned deficiency of existing large blast furnace stemming with wedding agent, the invention provides a kind of blast furnace mud wedding agent, the stemming sintering velocity that adds this wedding agent is fast, and plasticity-is better than the resin-bonded stemming; Provide a kind of sintering velocity fast simultaneously, plasticity-is better than the blast furnace mud of resin-bonded stemming.
The performance of composition decision wedding agent, this large blast furnace stemming with the composition (weight proportion) of wedding agent is:
Coal tar 10-60;
Resol 5-20;
Pitch 20-80
Pitch is that high temperature powdered asphalt or high polymerization shape are gone through green grass or young crops, and softening temperature is not less than 100 ℃, and general softening temperature is 125 ℃-140 ℃.
Stir the wedding agent that modulation forms at 50 ℃-70 ℃.
The optimal components of this wedding agent (weight proportion) is:
Coal tar 35 resol 12.5 pitches 50.
The composition (weight proportion) that contains the large blast furnace stemming of this wedding agent is:
Fused corundom 40~60 silicon carbide 15~20 clays 5~10
Coke powder 5~8 sericites 5~10 wedding agent 10-18.
This large blast furnace stemming has following advantage with wedding agent: (1) adopts the stemming sintering velocity of this wedding agent fast, simultaneously can regulate tissue defects, improve the carbon residue rate, stemming slag resistance, sintering strength, opening performance all are significantly increased, be embodied in: tapped a blast furnace time lengthening 30-60 minute when adopting the stemming of this wedding agent to use on blast furnace, opening time shortens 5-8 minute; (2) with the stemming of this wedding agent preparation environmental protection and healthy aspect be better than tar, be in particular in that finished product stemming environmental protection smell is little; (3) stemming with this wedding agent is lower than resin-bonded stemming price; (4) plasticity-with the stemming of this wedding agent is better than the resin-bonded stemming, and to combine stemming suitable with tar.
Embodiment
Describe the embodiment of this large blast furnace stemming in detail below in conjunction with embodiment, but this large blast furnace stemming is not limited to following embodiment with the embodiment of wedding agent and blast furnace mud with wedding agent and blast furnace mud.
Wedding agent embodiment one
This large blast furnace stemming be divided into (weight proportion) of wedding agent present embodiment is:
Tar 60; Resin 20; Pitch 80
Stirring modulation at 70 ℃ forms.
Wedding agent embodiment two
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 10; Resin 5; Pitch 20
Stirring modulation at 50 ℃ forms.
Wedding agent embodiment three
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 35; Resin 12.5; Pitch 50
Stirring modulation at 60 ℃ forms.
Wedding agent embodiment four
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 60; Resin 20; Pitch 20
Stirring modulation at 55 ℃ forms.
Wedding agent embodiment five
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 10; Resin 5; Pitch 80
Stirring modulation at 65 ℃ forms.
Wedding agent embodiment six
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 10; Resin 20; Pitch 20
Stirring modulation at 60 ℃ forms.
Wedding agent embodiment seven
This large blast furnace stemming be divided into (weight proportion) of wedding agent is:
Tar 60; Resin 5; Pitch 80
Stirring modulation at 70 ℃ forms.
The advantage of this wedding agent mainly is to be embodied by the large blast furnace stemming of making, so the advantage of this wedding agent and stemming thereof is described with five following large blast furnace stemming embodiment.Other composition (weight proportion) of selected stemming is among the following embodiment:
Firm 40~60 silicon carbide of electric smelting 15~20 clays 5~10 coke powders 5~8
Sericite 5~10.
Large blast furnace stemming embodiment one
That the wedding agent in the present embodiment adopts is wedding agent embodiment one, is the stemming of high furnace temperature running phase.The composition that wedding agent accounts in stemming is 15%, and the composition of this blast furnace mud embodiment is:
Fused corundom 60 silicon carbide 20 clays 10 coke powders 8
Sericite 10 wedding agents 19
Large blast furnace stemming embodiment two
That the wedding agent in the present embodiment adopts is wedding agent embodiment two, is the blast furnace staying stemming, and the composition that wedding agent accounts in stemming is 15%, and the composition of this blast furnace mud embodiment is:
Fused corundom 40 silicon carbide 15 clays 5 coke powders 5
Sericite 5 wedding agents 12.3
Large blast furnace stemming embodiment three
That the wedding agent in the present embodiment adopts is wedding agent embodiment three, is blast furnace normal operation stemming, and the composition that wedding agent accounts in stemming is 15%, and the composition of this blast furnace mud embodiment is:
Fused corundom 50 silicon carbide 17 clays 7
Coke powder 7 sericites 7 wedding agents 15.5
Large blast furnace stemming embodiment four
That the wedding agent in the present embodiment adopts is wedding agent embodiment five, is blast furnace opening initial stage stemming, and the composition that wedding agent accounts in stemming is 15%, and the composition of this blast furnace mud embodiment is:
Fused corundom 60 silicon carbide 20 clays 10
Coke powder 5 wedding agents 15
Large blast furnace stemming embodiment five
That the wedding agent in the present embodiment adopts is wedding agent embodiment six, is the low furnace temperature running of blast furnace phase stemming, and the composition that wedding agent accounts in stemming is 15%, and the composition of this blast furnace mud embodiment is:
Fused corundom 40 silicon carbide 15 clays 10 coke powders 8 sericites 10
Wedding agent 18.
The composition of wedding agent in stemming can account for 13%-18% among above-mentioned five embodiment, and it is preferable to account for 14%-16%.
The main technical details that above-mentioned five wedding agent embodiment join five stemming embodiment that are prepared in the stemming sees Table 1
Table 1
The stemming kind | Time min taps a blast furnace | Opening time min | Whether leak iron | Have or not wattenshlick | The environmental protection smell |
Existing stemming 1 | 90~150 | 5~10 | Be | Have | Greatly |
Stemming example 1 | 100~160 | 2~8 | Not | Do not have | Little |
Existing stemming 2 | 100~150 | 10~15 | Be | Have | Greatly |
Stemming example 2 | 120~160 | 5~10 | Not | Do not have | Little |
Existing stemming 3 | 90~150 | 5~10 | Be | Have | Greatly |
Stemming example 3 | 120~150 | 3~10 | Not | Do not have | Little |
Existing stemming 4 | 90~150 | 10~15 | Be | Have | Greatly |
Stemming example 4 | 120~150 | 5~10 | Not | Do not have | Little |
Existing stemming 5 | 80~120 | 5~10 | Be | Have | Greatly |
Stemming example 5 | 100~160 | 3~10 | Not | Do not have | Little |
Claims (4)
1, a kind of large blast furnace stemming wedding agent, its composition (weight proportion) is:
Coal tar 10-60;
Resol 5-20;
Pitch 20-80
Pitch is that high temperature powdered asphalt or high polymerization shape are gone through green grass or young crops, and softening temperature is not less than 100 ℃; At 50 ℃ of-70 ℃ of wedding agents that stirring is modulated into.
2, large blast furnace stemming wedding agent according to claim 1, its composition (weight proportion) is:
Coal tar 35 resol 12.5 pitches 50.
3, a kind of large blast furnace stemming is characterized in that: the said wedding agent of claim 1 that contains 13%-18% in its composition (weight proportion).
4, large blast furnace stemming according to claim 3 is characterized in that the composition (weight proportion) of said wedding agent is:
Coal tar 35 resol 12.5 pitches 50.
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CNA2008100546759A CN101244943A (en) | 2008-03-20 | 2008-03-20 | Wedding agent for large-scale blast furnace stemming and blast furnace stemming |
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CNA2008100546759A CN101244943A (en) | 2008-03-20 | 2008-03-20 | Wedding agent for large-scale blast furnace stemming and blast furnace stemming |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102417729A (en) * | 2011-07-28 | 2012-04-18 | 应城市力发化工有限责任公司 | Preparation method of environment-friendly high-temperature initiated resin for blast furnaces |
CN102875178A (en) * | 2012-11-09 | 2013-01-16 | 高金菊 | Bonding agent for stemming of large-scale blast furnace |
CN101613213B (en) * | 2009-06-26 | 2013-04-03 | 河南省耕生耐火材料有限公司 | Environment-friendly stemming for blast furnace taphole and preparation method thereof |
CN103193406A (en) * | 2013-04-01 | 2013-07-10 | 武汉钢铁(集团)公司 | Binding agent for regulating stemming plasticity |
CN103214257A (en) * | 2013-05-17 | 2013-07-24 | 长兴云峰炉料有限公司 | Novel stemming at tap hole |
CN108218451A (en) * | 2018-02-09 | 2018-06-29 | 天津荣程联合钢铁集团有限公司 | A kind of anhydrous stemming and preparation method thereof |
CN108218448A (en) * | 2018-01-17 | 2018-06-29 | 山西禄纬堡太钢耐火材料有限公司 | A kind of mineral hot furnace stemming and preparation method thereof |
CN108503382A (en) * | 2018-05-09 | 2018-09-07 | 宜兴市龙宸炉料有限公司 | It is a kind of to mitigate the processing method that nuisance overflows in anhydrous stemming production process |
CN109776098A (en) * | 2019-03-25 | 2019-05-21 | 义马瑞能化工有限公司 | A kind of binding agent for magnesium carbon brick |
CN116854490A (en) * | 2022-11-14 | 2023-10-10 | 太原科技大学 | Environment-friendly carbonaceous binding agent for blast furnace, preparation method and stemming for blast furnace |
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2008
- 2008-03-20 CN CNA2008100546759A patent/CN101244943A/en active Pending
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101613213B (en) * | 2009-06-26 | 2013-04-03 | 河南省耕生耐火材料有限公司 | Environment-friendly stemming for blast furnace taphole and preparation method thereof |
CN102417729A (en) * | 2011-07-28 | 2012-04-18 | 应城市力发化工有限责任公司 | Preparation method of environment-friendly high-temperature initiated resin for blast furnaces |
CN102417729B (en) * | 2011-07-28 | 2013-03-27 | 应城市力发化工有限责任公司 | Preparation method of environment-friendly high-temperature initiated resin for blast furnaces |
CN102875178B (en) * | 2012-11-09 | 2013-11-27 | 高金菊 | Bonding agent for stemming of large-scale blast furnace |
CN102875178A (en) * | 2012-11-09 | 2013-01-16 | 高金菊 | Bonding agent for stemming of large-scale blast furnace |
CN103193406A (en) * | 2013-04-01 | 2013-07-10 | 武汉钢铁(集团)公司 | Binding agent for regulating stemming plasticity |
CN103193406B (en) * | 2013-04-01 | 2015-05-06 | 武汉钢铁(集团)公司 | Binding agent for regulating stemming plasticity |
CN103214257A (en) * | 2013-05-17 | 2013-07-24 | 长兴云峰炉料有限公司 | Novel stemming at tap hole |
CN108218448A (en) * | 2018-01-17 | 2018-06-29 | 山西禄纬堡太钢耐火材料有限公司 | A kind of mineral hot furnace stemming and preparation method thereof |
CN108218451A (en) * | 2018-02-09 | 2018-06-29 | 天津荣程联合钢铁集团有限公司 | A kind of anhydrous stemming and preparation method thereof |
CN108218451B (en) * | 2018-02-09 | 2020-02-21 | 天津荣程联合钢铁集团有限公司 | Anhydrous stemming and preparation method thereof |
CN108503382A (en) * | 2018-05-09 | 2018-09-07 | 宜兴市龙宸炉料有限公司 | It is a kind of to mitigate the processing method that nuisance overflows in anhydrous stemming production process |
CN109776098A (en) * | 2019-03-25 | 2019-05-21 | 义马瑞能化工有限公司 | A kind of binding agent for magnesium carbon brick |
CN116854490A (en) * | 2022-11-14 | 2023-10-10 | 太原科技大学 | Environment-friendly carbonaceous binding agent for blast furnace, preparation method and stemming for blast furnace |
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