CN101235275B - Environmental protection type refrigerant - Google Patents
Environmental protection type refrigerant Download PDFInfo
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- CN101235275B CN101235275B CN200810082668XA CN200810082668A CN101235275B CN 101235275 B CN101235275 B CN 101235275B CN 200810082668X A CN200810082668X A CN 200810082668XA CN 200810082668 A CN200810082668 A CN 200810082668A CN 101235275 B CN101235275 B CN 101235275B
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- fluoroethane
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- 239000003507 refrigerant Substances 0.000 title abstract description 6
- 230000007613 environmental effect Effects 0.000 title description 14
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims abstract description 84
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 19
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 19
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 19
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001294 propane Substances 0.000 claims abstract description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 6
- 238000005057 refrigeration Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 10
- KLZDCUBZWUSEGO-UHFFFAOYSA-N CC.F.F.F.F.F Chemical compound CC.F.F.F.F.F KLZDCUBZWUSEGO-UHFFFAOYSA-N 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 5
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 abstract description 64
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 abstract description 17
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 11
- 238000010792 warming Methods 0.000 abstract description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 5
- 230000007774 longterm Effects 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 abstract description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 229940051271 1,1-difluoroethane Drugs 0.000 abstract 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 14
- 238000009835 boiling Methods 0.000 description 8
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 5
- 239000010687 lubricating oil Substances 0.000 description 5
- 238000004378 air conditioning Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 2
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 description 2
- 239000010725 compressor oil Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- -1 HC-600a Chemical compound 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- OCVXZQOKBHXGRU-UHFFFAOYSA-N iodine(1+) Chemical compound [I+] OCVXZQOKBHXGRU-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Abstract
The invention discloses a novel environment-friendly refrigerant, which is formed by a first component, difluoromethane, penta-fluoroethane and hydrocarbon component, wherein the first component is one of fluoroethane and 1, 1-difluoroethane, hydrocarbon component is the combination of one or more than one of isobutene, normal butene, propane and propylene. The refrigerant whose ODP is zero, which does not damage atmospheric ozone layer, and largely reduces GWP value compared with HCFC-22 and current substitutes R407 C and R410A, and has excellent environment-friendly property. The refrigerant whose thermal property is equivalent to HCFC-22 can be directly used in a system which originally uses HCFC-22, can reduce charge amount and increase energy effect ratio, and has the advantages of saving resources and energy. The refrigerant can be used as long-term substitute of HCFC-22, which provides a reliable technology which is easy to be popularized and applied and can take effect rapidly for the global to cope with climate warming.
Description
Technical field
The present invention relates to a kind of refrigeration agent, relate in particular to that a kind of system is substantially constant for the equipment such as refrigeration, air-conditioning, heat pump directly substitute HCFC-22, destroy the environment friendly refrigerating fluid that atmospheric ozone potential is zero, Greenhouse effect are low, for whole world reply climate warming provides a kind of being easy to apply, the robust techniques that takes effect fast.
Technical background
HCFC-22 is owing to having good physical chemistry and thermomechanical property and good safety in utilization, economy, become most widely used in the domestic and international refrigerating and air conditioning industry, the classic refrigeration agent of over-all properties, but HCFC-22 has higher GWP (global warming potential) value and ODP (ozone depletion potential) value, not friendly to the environment is the material that is required that time limit is eliminated.
The substitute of present most popular HCFC-22 is R410A and R407C, but they have again certain defect separately, the thermal conduction that is R407C is relatively poor, refrigerating effect per unit swept volume under nominal condition and COP value are all less than HCFC-22, in order to reach the refrigerating duty identical with HCFC-22, the heat-transfer effect that needs the enhanced heat exchange device, manufacturing cost will increase; And the evaporating pressure of R410A, condensing pressure and volume refrigerating capacity compressor are all much larger than HCFC-22, can not directly be used for substituting HCFC-22, will redesign compressor, interchanger, pipeline and system in use.Because these two kinds of mix refrigerants still have improvements on performance, especially it has higher GWP value (Greenhouse effect value), and therefore R410A even more taller than the GWP value of HCFC-22 also is not desirable HCFC-22 surrogate.
Except R410A and R407C, also the HCFC-22 surrogate has been carried out a large amount of research both at home and abroad, mainly as follows:
1) publication number is the patent of invention of CN1055300C and CN1244663C, adopt the tertiary mixture of HFC-32, HFC-125 and HFC-152a as the surrogate of HCFC-22, have the thermal performance close with HCFC-22, but unresolved under long-time running, the compatibility problem of this Substitute Working Medium and HCFC-22 compressor and lubricating oil.
2) patent of invention of publication number CN1412266A, the mixture replacing HCFC-22 of employing HFC-32, HFC-134a and HFC-143a; The patent of invention of publication number CN1136065A, the mixture replacing HCFC-22 of employing HFC-32, HFC-125 and HFC-227ea; CN1189525A adopts the mixture replacing HCFC-22 of HFC-32, HFC-134a and HFC-227ea, but all has the higher problem of GWP value.
3) patent of invention of publication number CN1173525A, the mixture replacing HCFC-22 of employing HC-290, HC-600a and TS fire retardant; The patent of invention of publication number CN1255502C adopts the mixture replacing HCFC-22 of HC-1270, FC-13I1 and HC-170, and such mixture as main body, has the hidden danger of optical haze effect with hydrocarbon polymer and composition thereof, might cause new environmental problem.
4) patent of invention of publication number CN1189525A has also adopted the mixture replacing HCFC-22 of HFC-32, HFC-134a, HFC-152a and FC-13I1; The patent of invention of publication number CN1255502C has adopted the mixture replacing HCFC-22 of FC-13I1, HFC-134a and CO2, such mixture has adopted FC-13I1, have better environmental performance and thermal performance, but because iodine (I) can not synthetic, so that FC-13I1 is expensive, use cost is high, is unfavorable for being widely used.
5) patent of invention of publication number CN1780892A, adopted the mixture replacing HCFC-22 of HFC-161, HFC-32 and HFC-125, but this surrogate can not use compressor and the lubricating oil of HCFC-22, must use compressor and the ester class oil of R407C or R410A, alternative cost is high, is not suitable for directly substituting in the system of HCFC-22 using.
6) also having the part invention is that the method that adopts HCFC-22 and other materials to mix substitutes HCFC-22, adopts HCFC-22 and HFC-152a mixture such as publication number CN1269391A; The patent of invention of publication number CN1236801A adopts the mixture of HCFC-22, HFC-152a and HFC-125; The patent of invention of publication number CN1837323A adopts the mixture of HCFC-22, HFC-152a and HCFC-124; Such surrogate all belongs to transitional surrogate, is not the long-term surrogate of HCFC-22.
Face the environmental protection new demand that day by day urgent environmental problem and ODP and GWP lay equal stress on, seek a kind of thermal performance and be not less than HCFC-22, thus environmental performance especially the GWP novel environment friendly refrigerating fluid that is better than HCFC-22 and can directly uses HCFC-22 compressor and lubricating oil to reduce alternative cost become the task of top priority.
Summary of the invention
The present invention's purpose is to provide a kind of environment friendly refrigerating fluid that meets current Ozonosphere protection and suppress the environmental requirement that global warming lays equal stress on; another object of the present invention provide a kind of have be better than HCFC-22 or thermal parameter and the thermal performance suitable with it; can directly be used in the system of HCFC-22 and lubricating oil thereof, and can be used as the refrigeration agent of the long-term surrogate of HCFC-22.
For achieving the above object, the present invention adopts following technical scheme:
A kind of novel environment friendly refrigerating fluid, this refrigeration agent is comprised of the first component, methylene fluoride (HFC-32) and hydrocarbon components basically, wherein the first component is fluoroethane (HFC-161) and 1, the combination of the one or both arbitrary proportion in the 1-C2H4F2 C2H4F2 (HFC-152a), hydrocarbon components is for being selected from one or more arbitrary proportion combinations in Trimethylmethane (HC-600a), normal butane (HC-600), propane (HC-290) and the propylene (HC-1270).
Also can add pentafluoride ethane in this refrigeration agent, namely this refrigeration agent is comprised of the first component, methylene fluoride (HFC-32), pentafluoride ethane (HFC-125) and hydrocarbon components, wherein the first component is fluoroethane (HFC-161) and 1, the combination of the one or both arbitrary proportion in the 1-C2H4F2 C2H4F2 (HFC-152a), hydrocarbon components is for being selected from one or more arbitrary proportion combinations in Trimethylmethane (HC-600a), normal butane (HC-600), propane (HC-290) and the propylene (HC-1270).
Each constituent mass per-cent is: the first component: 5%-98%; HFC-32:1%-60%; HFC-125:0%-30%; Hydrocarbon components: 1%-94%.
Preferably, described refrigeration agent is comprised of the first component, methylene fluoride (HFC-32) and hydrocarbon components, and each constituent mass per-cent is: the first component: 5%-98%; HFC-32:1%-60%; Hydrocarbon components: 1%-94%.
Perhaps, described refrigeration agent is comprised of the first component, methylene fluoride (HFC-32), pentafluoride ethane (HFC-125) and hydrocarbon components, and each constituent mass per-cent is: the first component: 5%-97%; HFC-32:1%-60%; HFC-125:1%-30%; Hydrocarbon components: 1%-93%.
Refrigeration agent of the present invention is compared with existing disclosed technology, has the following advantages:
1, environmental performance is good, and depletion potential ODP value is 0, and global warming potential GWP value meets environmental requirement more much smaller than HCFC-22.
2, thermal parameter such as evaporating pressure, condensing pressure and pressure ratio and HCFC-22 are close, and under the prerequisite that does not change the equipment major parts, unit volume heating capacity, COP value all are not less than HCFC-22.Refrigeration agent of the present invention can be directly used in the system of former use HCFC-22, and can use compressor and the lubricating oil of HCFC-22; The quality refrigerating duty is large and density is little, can reduce filling quantity, improves Energy Efficiency Ratio, has advantages of saving resource, save energy.This refrigeration agent can be used as the long-term surrogate of HCFC-22.
Embodiment
Refrigeration agent provided by the invention, its preparation method is with fluoroethane (HFC-161) or 1,1-C2H4F2 C2H4F2 (HFC-152a), methylene fluoride (HFC-32), pentafluoride ethane (HFC-125) and hydrocarbon components namely are selected from one or more the hydrocarbon polymer combinations in Trimethylmethane (HC-600a), normal butane (HC-600), propane (HC-290) and the propylene (HC-1270), carry out physical mixed according to its corresponding proportioning under liquid phase state.
Fluoroethane in the said components (HFC-161), its molecular formula are CH
3CH
2F, molecular weight are 48.06, and normal boiling point is-37.1 ℃, and critical temperature is 102.2 ℃, and emergent pressure is 4.70MPa.
In the said components 1, its molecular formula of 1-C2H4F2 C2H4F2 (HFC-152a) is CH
3CHF
2, molecular weight is 66.05, and normal boiling point is-24.02 ℃, and critical temperature is 113.26 ℃, and emergent pressure is 4.52MPa.
Pentafluoride ethane in the said components (HFC-125), its molecular formula are CHF
2CF
3, molecular weight is 120.02, and normal boiling point is-48.1 ℃, and critical temperature is 66.2 ℃, and emergent pressure is 3.63MPa.
Methylene fluoride in the said components (HFC-32), its molecular formula are CH
2F
2, molecular weight is 52.02, and normal boiling point is-51.7 ℃, and critical temperature is 78.2 ℃, and emergent pressure is 5.78MPa.
Trimethylmethane in the said components (HC-600a), its molecular formula are CH (CH
3)
2CH
3, molecular weight is 58.12, and normal boiling point is-11.6 ℃, and critical temperature is 134.7 ℃, and emergent pressure is 3.64MPa.
Normal butane in the said components (HC-600), its molecular formula are CH
3CH
2CH
2CH
3, molecular weight is 58.12, and normal boiling point is-0.5 ℃, and critical temperature is 152.0 ℃, and emergent pressure is 3.80MPa.
Propane in the said components (HC-290), its molecular formula are CH
3CH
2CH
3, molecular weight is 44.10, and normal boiling point is-42.1 ℃, and critical temperature is 96.7 ℃, and emergent pressure is 4.25MPa.
Propylene in the said components (HC-1270), its molecular formula are CH
3CHCH
2, molecular weight is 42.08, and normal boiling point is-47.7 ℃, and critical temperature is 92.4 ℃, and emergent pressure is 4.67MPa.
The following examples are used for illustrating several embodiment of the present invention, but do not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained all alternativess, improvement project and the equivalents that may comprise in claims scope.
Embodiment 1: with HFC-161, HFC-125, HFC-32, HC-600 under liquid phase by 71: 10: 14: 5 mass percent is carried out physical mixed.
Embodiment 2: HFC-161, HFC-32, the HC-600 mass percent by 75: 20: 5 under liquid phase is carried out physical mixed.
Embodiment 3: HFC-152a, HFC-32, the HC-600 mass percent by 45: 50: 5 under liquid phase is carried out physical mixed.
Embodiment 4: with HFC-152a, HFC-125, HFC-32, HC-600a under liquid phase by 35: 30: 30: 5 mass percent is carried out physical mixed.
Embodiment 5: HFC-161, HFC-32, the HC-1270 mass percent by 89: 10: 1 under liquid phase is carried out physical mixed.
Embodiment 6: HFC-152a, HFC-32, the HC-600a mass percent by 40: 20: 40 under liquid phase is carried out physical mixed.
Embodiment 7: HFC-161, HFC-32, the HC-290 mass percent by 89: 10: 1 under liquid phase is carried out physical mixed.
Embodiment 8: with HFC-152a, HFC-32, HC-290, HC-600 under liquid phase by 49: 46: 1: 4 mass percent is carried out physical mixed.
Embodiment 9: with HFC-161, HFC-32, HC-600a, HC-600 under liquid phase by 79: 16: 3: 2 mass percent is carried out physical mixed.
Embodiment 10: with HFC-161, HFC-32, HC-600a, HC-290 under liquid phase by 85: 10: 1: 4 mass percent is carried out physical mixed.
Embodiment 11: with HFC-161, HFC-32, HC-600a, HC-600, HC-290 under liquid phase by 84: 10: 1: 1: 4 mass percent is carried out physical mixed.
Embodiment 12: with HFC-161, HFC-32, HC-600a, HC-600, HC-290, HC-1270 under liquid phase by 80: 15: 1: 2: 1: 1 mass percent is carried out physical mixed.
Embodiment 13: with HFC-161, HFC-32, HFC-152a, HC-600 under liquid phase by 70: 20: 5: 5 mass percent is carried out physical mixed.
Embodiment 14: HFC-161, HFC-32, the HC-600 mass percent by 98: 1: 1 under liquid phase is carried out physical mixed.
Embodiment 15: HFC-161, HFC-32, the HC-290 mass percent by 5: 1: 94 under liquid phase is carried out physical mixed.
Embodiment 16: HFC-152a, HFC-32, the HC-600 mass percent by 15: 25: 60 under liquid phase is carried out physical mixed.
Comparative Examples 1: HFC-161, HFC-152a, the HC-600 mass percent by 15: 75: 10 under liquid phase is carried out physical mixed.
Comparative Examples 2: with HFC-125, HFC-134a, HFC-161, HC-600a under liquid phase by 10: 10: 50: 30 mass percent is carried out physical mixed.
Comparative Examples 3: with HCFC-22, HCFC-124, HFC-161, HC600 under liquid phase by 60: 15: 20: 5 mass percent is carried out physical mixed.
Now the performance of above-described embodiment and HCFC-22 and Comparative Examples 1～3 are compared, characteristics of the present invention and effect are described.
1) environmental performance:
Table 1 has compared the environmental performance of above-described embodiment and HCFC-22.Wherein as benchmark value 1.0, the GWP value is with CO with CFC-11 for the ODP value
2As benchmark value 1.0 (100 years).
Table 1 comparison of environmental performance
| Working medium | ODP | GWP |
| Embodiment 1 | 0 | 454 |
| Embodiment 2 | 0 | 145 |
| Embodiment 3 | 0 | 394 |
| Embodiment 4 | 0 | 1297 |
| Embodiment 5 | 0 | 78 |
| Embodiment 6 | 0 | 193 |
| Embodiment 7 | 0 | 78 |
| Embodiment 8 | 0 | 372 |
| Embodiment 9 | 0 | 118 |
| Embodiment 10 | 0 | 79 |
| Embodiment 11 | 0 | 79 |
| Embodiment 12 | 0 | 112 |
| Embodiment 13 | 0 | 150 |
| Embodiment 14 | 0 | 19 |
| Embodiment 15 | 0 | 26 |
| Embodiment 16 | 0 | 429 |
| Comparative Examples 1 | 0 | 97 |
| Comparative Examples 2 | 0 | 505 |
| Comparative Examples 3 | 0.033 | 1181 |
| HCFC-22 | 0.050 | 1810 |
| R407C | 0 | 1800 |
| R410A | 0 | 2100 |
As can be seen from Table 1, Ozone depletion potential (ODP) value of above-described embodiment is zero, atmospheric ozone layer is not had destruction, and the ODP value of Comparative Examples 3 is 0.033, does not meet environmental requirement.
Moreover; the global warming potential of above-described embodiment (GWP) value is all less than HCFC-22; remove embodiment 4 slightly large; for HCFC-22 GWP value 71.7% beyond; the GWP value of all the other embodiment only is 1.05%～25.2% of HCFC-22 GWP value; much smaller than the GWP value of HCFC-22, with Comparative Examples 1,2 suitable, more meet current Ozonosphere protection, reduce the environmental protection requirement that the Global warming effect is laid equal stress on.
2) thermal parameter and thermal performance
Under the standard air conditioning condition (being vaporization temperature=7.2 ℃, condensing temperature=54.4 ℃, suction temperature=35 ℃, supercooling temperature=46.1 ℃), the thermal parameter of above-described embodiment and HCFC-22 (that is: evaporating pressure P
0, condensing pressure P
k, pressure ratio P
k/ P
0, exhaust temperature t
2) and relative thermal performance (that is: relatively COP, relative unit quality heating capacity q
0, relative unit volume heating capacity q
v, relative unit volume wasted work amount w
v) relatively see Table 2.
Above-mentioned relative thermal performance refers to the ratio of each embodiment thermal performance and HCFC-22 thermal performance, the relative fluid density when relative density refers to 25 ℃.
The comparison of table 2 thermal parameter and thermal performance
| Embodiment 13 | 0.656 | 2.237 | 3.410 | 96.9 | 1.006 | 1.683 | 1.033 | 0.570 |
| Embodiment 14 | 0.542 | 1.902 | 3.509 | 95.2 | 1.028 | 1.842 | 0.888 | 0.541 |
| Embodiment 15 | 0.625 | 1.974 | 3.158 | 84.1 | 1.033 | 1.771 | 0.917 | 0.418 |
| Embodiment 16 | 0.662 | 2.361 | 3.566 | 100.6 | 0.947 | 1.487 | 1.019 | 0.654 |
| Comparative Examples 1 | 0.382 5 | 1.422 | 3.718 | 91.4 | 1.048 | 1.556 | 0.669 | 0.665 |
| Comparative Examples 2 | 0.464 1 | 1.632 | 3.517 | 86.1 | 1.029 | 1.526 | 0.749 | 0.552 |
| Comparative Examples 3 | 0.526 0 | 1.850 | 3.517 | 94.3 | 1.019 | 1.153 | 0.855 | 0.819 |
| HCFC-22 | 0.625 | 2.146 | 3.434 | 102.0 | 1.000 | 1.000 | 1.000 | 1.000 |
| R407C | 0.651 | 2.326 | 3.573 | 92.2 | 0.998 | 0.982 | 1.088 | 0.956 |
As seen from Table 2, under the standard air conditioning condition, the condensing pressure of the various embodiments described above and pressure ratio are all suitable with HCFC-22, and except embodiment 3,8, exhaust temperature all is lower than HCFC-22, can directly charge in the system of former use HCFC-22.The unit mass refrigerating duty of the various embodiments described above is all far above HCFC-22, and density this means the filling quantity that can significantly reduce systematic working medium much smaller than HCFC-22.Except embodiment 3,4,16, the COP value of all the other embodiment is all greater than HCFC-22, and therefore, these embodiment have energy-saving effect.Except embodiment 14,15, the volume refrigerating capacity compressor of all the other each embodiment all is not less than HCFC-22, and this shows can improve refrigerating speed.And the volume refrigerating capacity compressor of each embodiment all is higher than Comparative Examples 1,2,3, shows with Comparative Examples and compares, and all can improve refrigerating speed.
Claims (2)
1. novel environment friendly refrigerating fluid, it is characterized in that described refrigeration agent is comprised of fluoroethane, methylene fluoride, pentafluoride ethane and hydrocarbon components, hydrocarbon components is one or more arbitrary proportion combinations that are selected from Trimethylmethane, normal butane, propane and the propylene, and each constituent mass per-cent is: fluoroethane: 5%-98%; Methylene fluoride: 1%-60%; Pentafluoride ethane: 0%-10%; Hydrocarbon components: 1%-94%.
2. novel environment friendly refrigerating fluid according to claim 1 is characterized in that each constituent mass per-cent of described fluoroethane, methylene fluoride, pentafluoride ethane and hydrocarbon components is: fluoroethane: 5%-97%; Methylene fluoride: 1%-60%; Pentafluoride ethane: 1%-10%; Hydrocarbon components: 1%-93%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810082668XA CN101235275B (en) | 2007-11-09 | 2008-02-25 | Environmental protection type refrigerant |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710156803.6 | 2007-11-09 | ||
| CNA2007101568036A CN101157849A (en) | 2007-11-09 | 2007-11-09 | Environment-friendly type refrigerant |
| CN200810082668XA CN101235275B (en) | 2007-11-09 | 2008-02-25 | Environmental protection type refrigerant |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102608256A Division CN101735772B (en) | 2007-11-09 | 2008-02-25 | Novel environment friendly refrigerating fluid |
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| Publication Number | Publication Date |
|---|---|
| CN101235275A CN101235275A (en) | 2008-08-06 |
| CN101235275B true CN101235275B (en) | 2013-01-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101568036A Withdrawn CN101157849A (en) | 2007-11-09 | 2007-11-09 | Environment-friendly type refrigerant |
| CN200810082668XA Active CN101235275B (en) | 2007-11-09 | 2008-02-25 | Environmental protection type refrigerant |
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| CNA2007101568036A Withdrawn CN101157849A (en) | 2007-11-09 | 2007-11-09 | Environment-friendly type refrigerant |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8721916B2 (en) | 2011-05-12 | 2014-05-13 | A.S. Trust & Holdings Inc. | Refrigerant composition |
| CN104277767B (en) * | 2014-09-09 | 2017-02-22 | 西安交通大学 | Mixed refrigerant for replacing HCFC-22 as well as preparation method and application of mixed refrigerant |
| CN104263324B (en) * | 2014-09-09 | 2017-06-06 | 西安交通大学 | A kind of mix refrigerant of replacement HCFC 22 and its preparation method and application |
| CN104263322B (en) * | 2014-09-09 | 2017-06-27 | 西安交通大学 | A kind of mix refrigerant of replacement R502 and its preparation method and application |
| CN104293300A (en) * | 2014-09-09 | 2015-01-21 | 西安交通大学 | Mixed refrigerant replacing HCFC-22 and preparation method and application thereof |
| CN106479442B (en) | 2016-09-27 | 2019-08-23 | 宁波艾科制冷工程有限公司 | A kind of refrigerant composition and preparation method |
| JPWO2020158731A1 (en) * | 2019-01-30 | 2021-12-02 | ダイキン工業株式会社 | Air control device in the refrigerator |
| CN113528090B (en) * | 2020-04-09 | 2023-09-26 | 浙江省化工研究院有限公司 | Environment-friendly refrigeration composition capable of replacing R410A |
| CN112126410B (en) * | 2020-09-25 | 2021-07-20 | 珠海格力电器股份有限公司 | Mixed refrigerant, preparation method and application thereof, and automobile air conditioning system |
| CN113004870A (en) * | 2021-02-26 | 2021-06-22 | 青岛万宝压缩机有限公司 | Refrigerant mixture, mixed working medium and compressor |
| CN113789156B (en) * | 2021-09-26 | 2023-07-25 | 浙江巨化联州制冷科技有限公司 | Heat transfer composition and application thereof and heat transfer system |
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| CN101235275A (en) | 2008-08-06 |
| CN101157849A (en) | 2008-04-09 |
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