CN101221155A - Photocatalytic separation membrane performance testing device and testing method thereof - Google Patents
Photocatalytic separation membrane performance testing device and testing method thereof Download PDFInfo
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- CN101221155A CN101221155A CNA2007100195620A CN200710019562A CN101221155A CN 101221155 A CN101221155 A CN 101221155A CN A2007100195620 A CNA2007100195620 A CN A2007100195620A CN 200710019562 A CN200710019562 A CN 200710019562A CN 101221155 A CN101221155 A CN 101221155A
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- 230000001699 photocatalysis Effects 0.000 title claims abstract description 103
- 238000000926 separation method Methods 0.000 title claims abstract description 86
- 238000012360 testing method Methods 0.000 title claims abstract description 40
- 239000012528 membrane Substances 0.000 title abstract 7
- 239000012530 fluid Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 24
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- 238000001179 sorption measurement Methods 0.000 claims abstract description 8
- 238000007146 photocatalysis Methods 0.000 claims description 95
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 38
- 239000007857 degradation product Substances 0.000 claims description 31
- 238000011056 performance test Methods 0.000 claims description 21
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims description 14
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 14
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 12
- 238000000870 ultraviolet spectroscopy Methods 0.000 claims description 12
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- 238000013033 photocatalytic degradation reaction Methods 0.000 claims description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000006731 degradation reaction Methods 0.000 claims description 9
- 230000015556 catabolic process Effects 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000006555 catalytic reaction Methods 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
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- 238000006862 quantum yield reaction Methods 0.000 claims description 2
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- 239000000376 reactant Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 33
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- 238000009434 installation Methods 0.000 description 6
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- 230000003197 catalytic effect Effects 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
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- 239000011941 photocatalyst Substances 0.000 description 3
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- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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Abstract
The invention discloses a device and a method for testing the performance of a photocatalytic separation membrane. The device is characterized in that a photocatalytic separation membrane (3) is arranged between a to-be-degraded material container (2) and a reactant container (6), wherein the inlet of the to-be-degraded material container (2) is sequentially connected with a flow sensor (10), an electromagnetic regulating valve (11), a pressure increasing and decreasing device (12) and a to-be-detected material container (13), the outlet of the to-be-detected material container is connected with a detector (4), a light source (1) and the photocatalytic separation membrane (3) are arranged in parallel, and the flow sensor (10), the electromagnetic regulating valve (11), the pressure increasing and decreasing device (12) and the detector (4) are; the method comprises the steps of preparing fluid, selecting a detector, determining a light source, controlling a photodegradation process by a computer, and calculating the photocatalytic quantum efficiency and the adsorption capacity of the photocatalytic separation membrane according to the concentration of the fluid and data measured by the detector and a formula rho = r/phi and an adsorption curve, thereby obtaining the performance of the photocatalytic separation membrane. It can automatically and comprehensively test the performance of the photocatalytic separation membrane.
Description
Technical field
The present invention relates to a kind of proving installation and method of testing, especially photocatalysis separation film performance test device and method of testing thereof.
Background technology
Photocatalysis technology can make full use of inexhaustible, nexhaustible sun power, at normal temperature and pressure, do not consume under the condition of other energy and material and water decomposition to be produced hydrogen, a series of organic compound of degraded and some as microorganisms such as bacterium, germ, viruses, thereby regenerative resource and these two problems of environmental pollution of solving social sustainable development effectively and being faced.As the material base of realizing photocatalysis technology, the performance decisive role of photocatalyst before with its practical application, if can be known the performance index of photocatalyst quantitatively, and then the utmost point is beneficial to giving full play to of its usefulness.For this reason, people have done some trials and effort, attempt to set up corresponding testing device and method of testing, carry out quantitative test with performance, as a kind of " evaluation method for nano powder material light catalysis property " that discloses among the disclosed Chinese invention patent ublic specification of application CN 1409109A on April 9th, 2003 to the photocatalyst product.It comprises sets up photocatalysis apparatus, preparation photocatalytic degradation solution, add nano-powder material to be assessed, the photocatalytic degradation reaction, centrifugal, get solution, measure last absorbance and assessment nano powder material light catalysis property seven operation stepss, photocatalysis apparatus wherein is by being equipped with uviol lamp in the sandwich-type isothermal reactor and stirrer constitutes.But, no matter be this appraisal procedure, or the device of implementation method all exist weak point, at first, only can test, and can not the performance of photocatalysis separation film be tested the photocatalysis performance of nano-powder material; Secondly, operation steps is numerous and diverse, very easily makes mistakes; At last, automaticity is low, in real time online evaluation.
Summary of the invention
The technical problem to be solved in the present invention is for overcoming weak point of the prior art, provide a kind of simple in structure, automaticity is high, photocatalysis separation film performance test device easy to use and method of testing thereof.
Photocatalysis separation film performance test device comprises light source, reaction vessel and its built-in photocatalysis thing, particularly (a) said reaction vessel comprise be connected treat degradation product container and reaction vessel, said photocatalysis thing is a photocatalysis separation film, said photocatalysis separation film places said treating between degradation product container and the reaction vessel, and will treat that degradation product container and reaction vessel are isolated; (b) said light source places and treats degradation product container one side, and be arranged in parallel with photocatalysis separation film; (c) the said inflow point of degradation product container that treats is connected with flow sensor, solenoid valve, increase and decrease depressor and determinand container in turn, the exit of said reaction vessel is connected with detecting device, and said flow sensor, solenoid valve, increase and decrease depressor and detecting device all are electrically connected with computing machine.
As the further improvement of photocatalysis separation film performance test device, described light source is visible light or ultraviolet light; Described visible light is that wavelength is the visible light of 500nm, and ultraviolet light is that wavelength is that ultraviolet light or the wavelength of 365nm is the ultraviolet light of 254nm; Described treating is equipped with pressure transducer in the degradation product container, and said pressure transducer is electrically connected with computing machine; Be equipped with temperature sensor in the described reaction vessel, said temperature sensor is electrically connected with computing machine; Described detecting device is the special gas detector of ultraviolet-visible spectrophotometer or gas chromatograph or corresponding gas; Described detecting device is connected with container.
The method of testing of photocatalysis separation film performance test device comprises the preparation for the treatment of degradation product and the catalysis of light, particularly method comprises following steps: (a) according to test purpose, prepare corresponding fluid, photocatalytic degradation reaction for liquid phase, obtain solution, for the photocatalytic degradation reaction of gas phase, preparation gas; (b) according to the test needs, select the relevant detection device,, select ultraviolet-visible spectrophotometer,, select the special gas detector of gas chromatograph or corresponding gas for the photocatalytic degradation reaction of gaseous fluid for the photocatalytic degradation reaction of liquid phase fluid; (c), determine that light source is visible light or ultraviolet light according to the type of photocatalysis separation film to be measured; (d) record degradation data by the photodegradative process of flow control of computing machine, and by detecting device by setting; (e) by computing machine according to the concentration of formulated fluids and the data that record, by formula
Calculate the photocatalysis quantum efficiency of photocatalysis separation film, in the formula: ρ be quantum yield, the r of catalyzer be reaction rate (per second reaction molecule molal quantity),
Be photon flow (per second useful photon number); (f) calculate the adsorbance of photocatalysis separation film by computing machine by adsorption curve, thereby obtain the performance of the photocatalysis separation film tested.
As the further improvement of the method for testing of photocatalysis separation film performance test device, described solution is the methylene blue fluid of 20 μ mol/L or the phenol fluid of 20mg/L; Described gas is the formaldehyde fluid of 5 μ mol/L or the triclene fluid of 5 μ mol/L.
Beneficial effect with respect to prior art is, one, employing places photocatalysis separation film and treats between degradation product container and the reaction vessel, and it is both are isolated, light source places treats degradation product container one side, and the structure that be arranged in parallel with photocatalysis separation film treats that for using liquid phase fluid or gaseous fluid degradation product test photocatalysis separation film established material base.Be selected to inflow point connection traffic sensor, solenoid valve, increase and decrease depressor and the determinand container successively for the treatment of the degradation product container, the exit connection detector of reaction vessel, and the structure that flow sensor, solenoid valve, increase and decrease depressor and detecting device all are electrically connected with computing machine, increased the automaticity of proving installation, made the process of test have intellectuality; Its two, the one-piece construction of proving installation is simple, cost is low, and is reliable, test and the A wide selection of colours and designs of analyzing, can test photocatalysis separation film to the degradation property of liquid phase fluid, can test its degradation property to gaseous fluid again, and the speed of test is fast, data reappearance is good; Its three, the method for testing science is feasible, and presses close to and contained the possible usable range of tested photocatalysis separation film, the step of test is succinct, the data of mensuration are true and reliable, can be used as the direct foundation when tested photocatalysis separation film is actual to be used.
Further embodiment as beneficial effect, the one, light source is visible light or ultraviolet light, wavelength of visible light is preferably the visible light of 500nm, the ultraviolet light wavelength is preferably the ultraviolet light of 365nm or the ultraviolet light of 254nm, both made the optical range that is subjected to of tested photocatalysis separation film obtain bigger expansion, the photosensitivity to tested photocatalysis separation film commonly used has had specific aim again; The 2nd, to treat also to be equipped with pressure transducer and the temperature sensor that is electrically connected with computing machine in degradation product container and the reaction vessel respectively, they have all promoted the intelligent degree of proving installation, make the result who records have more comparability; The 3rd, detecting device adopts the special gas detector of ultraviolet-visible spectrophotometer or gas chromatograph or corresponding gas, makes it can not only be applicable to the test of liquid phase photocatalytic degradation reaction, also can be applicable to the test of gas-phase photocatalysis degradation reaction; The 4th, solution is selected the methylene blue fluid of 20 μ mol/L or the phenol fluid of 20mg/L for use, has tested out the performance of photocatalysis separation film under the liquid phase fluid condition fully typically; The 5th, gas is elected the formaldehyde fluid of 5 μ mol/L or the triclene fluid of 5 μ mol/L as, can test out the performance of photocatalysis separation film under the gaseous fluid condition typically.
Description of drawings
Below in conjunction with accompanying drawing optimal way of the present invention is described in further detail.
Fig. 1 is a kind of basic structure synoptic diagram of photocatalysis separation film performance test device of the present invention;
Fig. 2 be methylene blue on proving installation shown in Figure 1 by the concentration change figure before and after the photocatalysis separation film to be measured degraded, wherein, horizontal ordinate is the time, ordinate is a concentration, the A point among the figure is the starting point of illumination;
Fig. 3 be methylene blue on proving installation shown in Figure 1 by the pressure variation before and after the photocatalysis separation film to be measured degraded, wherein, horizontal ordinate is the time, ordinate is a pressure, the A point among the figure is the starting point of illumination.
Embodiment
Referring to Fig. 1, being configured to of photocatalysis separation film performance test device: photocatalysis separation film 3 places treating between degradation product container 2 and the reaction vessel 6 of being connected, and it is isolated.Light source 1 places treats degradation product container 2 one sides, and be arranged in parallel with photocatalysis separation film 3; Wherein, light source 1 is selected visible light or ultraviolet light for use according to tested photocatalysis separation film, if select visible light, then selecting wavelength is the visible light of 500nm, if select ultraviolet light, then selecting wavelength is that ultraviolet light or the wavelength of 365nm is the ultraviolet light of 254nm.Treat to be equipped with pressure transducer 9 in the degradation product container 2, treat that the inflow point of degradation product container 2 is connected with flow sensor 10, solenoid valve 11, increase and decrease depressor 12 and determinand container 13 in turn.Be equipped with temperature sensor 7 in the reaction vessel 6, the exit of reaction vessel 6 is connected with detecting device 4 and container 5 in turn; Wherein, detecting device 4 is that ultraviolet-visible spectrophotometer is (when with liquid phase fluid degraded test; If during, then use the special gas detector of gas chromatograph or corresponding gas) with gaseous fluid degraded test.Above-mentioned pressure transducer 9, flow sensor 10, solenoid valve 11, increase and decrease depressor 12, detecting device 4 and temperature sensor 7 all are electrically connected with computing machine 8.
Referring to Fig. 1, Fig. 2 and Fig. 3, the method for testing of photocatalysis separation film performance test device is:
Embodiment 1: finish test according to the following steps successively: a) according to the purpose of the activity of test optically catalytic TiO 2 diffusion barrier degraded liquid phase methylene blue, be placed in the determinand container after preparing the methylene blue solution of 20 μ mol/L.B) selecting detecting device is ultraviolet-visible spectrophotometer, is used for the concentration of the methylene blue solution behind the test reaction.C) photocatalysis separation film to be tested is installed on treating between degradation product container and the reaction vessel of being connected, and it is isolated.Determine that light source is a ultraviolet light, its wavelength is elected 365nm as, the photon flow is elected per second 6.94 * 10 as
-7The mole photon is installed in this ultraviolet source and treats degradation product container one side, and be arranged in parallel with photocatalysis separation film.D) by the 1m of computing machine by setting
3The photodegradative process of the flow control of/h, computing machine sends the Signal Regulation solenoid valve to keep the stable of flow according to actual flow and the difference of setting flow.Methylene blue wherein is degraded under the acting in conjunction of ultraviolet source and photocatalysis separation film, methylene blue solution after the degraded ultraviolet-visible spectrophotometer of flowing through obtains the methylene blue concentration curve in reaction vessel exit, and the output of ultraviolet-visible spectrophotometer is by the process of computer recording and control degradation.E) by the concentration difference of computing machine according to methylene blue solution degraded front and back, drawing reaction rate is per second reaction 1.388 * 10
-8The mole molecule, the photocatalysis quantum efficiency of photocatalysis separation film is 2% (by formula
Calculate).F) by computing machine with photocatalysis separation film to be tested in unglazed according to the time concentration curve that methylene blue is caused be its adsorption curve to methylene blue, the adsorbance that calculates tested photocatalysis separation film is 0.01mg, thus the performance of the photocatalysis separation film that acquisition is tested.
Embodiment 2: finish test according to the following steps successively: a) according to the purpose of the activity of testing optically catalytic TiO 2 diffusion barrier degraded liquid phase phenol, be placed in the determinand container after the phenol solution of preparation 20mg/L.B) selecting detecting device is ultraviolet-visible spectrophotometer, is used for the concentration of the phenol solution behind the test reaction.C) photocatalysis separation film to be tested is installed on treating between degradation product container and the reaction vessel of being connected, and it is isolated.Determine that light source is a ultraviolet light, its wavelength is elected 254nm as, the photon flow is elected per second 8.02 * 10 as
-7The mole photon is installed in this ultraviolet source and treats degradation product container one side, and be arranged in parallel with photocatalysis separation film.D) by the 0.5m of computing machine by setting
3The photodegradative process of the flow control of/h, computing machine sends the Signal Regulation solenoid valve to keep the stable of flow according to actual flow and the difference of setting flow.Phenol wherein is degraded under the acting in conjunction of ultraviolet source and photocatalysis separation film, phenol solution after the degraded ultraviolet-visible spectrophotometer of flowing through obtains the phenol concentration change curve in reaction vessel exit, and the output of ultraviolet-visible spectrophotometer is by the process of computer recording and control degradation.E) by the concentration difference of computing machine according to phenol solution degraded front and back, drawing reaction rate is per second reaction 1.604 * 10
-9The mole molecule, the photocatalysis quantum efficiency of photocatalysis separation film is 0.2% (by formula
Calculate).F) by computing machine with photocatalysis separation film to be tested in unglazed according to the time Pyrogentisinic Acid concentration curve that causes be its Pyrogentisinic Acid's adsorption curve, the adsorbance that calculates tested photocatalysis separation film is 10
-4Mg, thereby the performance of the photocatalysis separation film that acquisition is tested.
Embodiment 3: finish test according to the following steps successively: a) according to the purpose of the activity of test optically catalytic TiO 2 diffusion barrier degraded gaseous formaldehyde, be placed in the determinand container after preparing the formaldehyde gas of 5 μ mol/L.B) selecting detecting device is formaldehyde special gas detector, is used for the concentration of the formaldehyde gas behind the test reaction.C) photocatalysis separation film to be tested is installed on treating between degradation product container and the reaction vessel of being connected, and it is isolated.Determine that light source is a ultraviolet light, its wavelength is elected 254nm as, the photon flow is elected per second 6.94 * 10 as
-7The mole photon is installed in this ultraviolet source and treats degradation product container one side, and be arranged in parallel with photocatalysis separation film.D) by the 1m of computing machine by setting
3The photodegradative process of the flow control of/h, computing machine sends the Signal Regulation solenoid valve to keep the stable of flow according to actual flow and the difference of setting flow.Formaldehyde gas wherein is degraded under the acting in conjunction of ultraviolet source and photocatalysis separation film, formaldehyde gas after the degraded formaldehyde special gas detector of flowing through obtains the concentration of formaldehyde change curve in reaction vessel exit, and the output of formaldehyde special gas detector is by the process of computer recording and control degradation.E) by the concentration difference of computing machine according to formaldehyde gas degraded front and back, drawing reaction rate is per second reaction 3.47 * 10
-8The mole molecule, the photocatalysis quantum efficiency of photocatalysis separation film is 5% (by formula
Calculate).F) by computing machine with photocatalysis separation film to be tested in unglazed according to the time PARA FORMALDEHYDE PRILLS(91,95) concentration curve that causes be the adsorption curve of its PARA FORMALDEHYDE PRILLS(91,95), the adsorbance that calculates tested photocatalysis separation film is 10
-6Mg, thereby the performance of the photocatalysis separation film that acquisition is tested.
Embodiment 4: finish test according to the following steps successively: a) purpose of the activity of the optically catalytic TiO 2 diffusion barrier degraded gas phase triclene that mixes according to test is placed in the determinand container after preparing the triclene gas of 5 μ mol/L.B) selecting detecting device is gas chromatograph, is used for the concentration of the triclene gas behind the test reaction.C) photocatalysis separation film to be tested is installed on treating between degradation product container and the reaction vessel of being connected, and it is isolated.Determine that light source is a ultraviolet light, its wavelength is elected 500nm as, the photon flow is elected per second 5.12 * 10 as
-7The mole photon is installed in this ultraviolet source and treats degradation product container one side, and be arranged in parallel with photocatalysis separation film.D) by the 1m of computing machine by setting
3The photodegradative process of the flow control of/h, computing machine sends the Signal Regulation solenoid valve to keep the stable of flow according to actual flow and the difference of setting flow.Triclene gas wherein is degraded under the acting in conjunction of ultraviolet source and photocatalysis separation film, triclene gas stream after the degraded obtains the triclene concentration curve in reaction vessel exit through gas chromatograph, and the output of gas chromatograph is by the process of computer recording and control degradation.E) by the concentration difference of computing machine according to triclene gas degraded front and back, drawing reaction rate is per second reaction 1.536 * 10
-8The mole molecule, the photocatalysis quantum efficiency of photocatalysis separation film is 3% (by formula
Calculate).F) by computing machine with photocatalysis separation film to be tested in unglazed according to the time concentration curve that triclene is caused be its adsorption curve to triclene, the adsorbance that calculates tested photocatalysis separation film is 10
-5Mg, thereby the performance of the photocatalysis separation film that acquisition is tested.
Obviously, those skilled in the art can carry out various changes and modification to photocatalysis separation film performance test device of the present invention and method of testing thereof and not break away from the spirit and scope of the present invention.Like this, if of the present invention these are revised and modification belongs within the scope of claim of the present invention and equivalent technologies thereof, then the present invention also is intended to comprise these changes and modification interior.
Claims (10)
1. a photocatalysis separation film performance test device comprises light source (1), reaction vessel and its built-in photocatalysis thing, it is characterized in that:
(a) said reaction vessel comprise be connected treat degradation product container (2) and reaction vessel (6), said photocatalysis thing is photocatalysis separation film (3), said photocatalysis separation film (3) places said treating between degradation product container (2) and the reaction vessel (6), and will treat that degradation product container (2) and reaction vessel (6) are isolated;
(b) said light source (1) places and treats degradation product container (2) one sides, and be arranged in parallel with photocatalysis separation film (3);
(c) the said inflow point of degradation product container (2) that treats is connected with flow sensor (10), solenoid valve (11), increase and decrease depressor (12) and determinand container (13) in turn, the exit of said reaction vessel (6) is connected with detecting device (4), and said flow sensor (10), solenoid valve (11), increase and decrease depressor (12) and detecting device (4) all are electrically connected with computing machine (8).
2. photocatalysis separation film performance test device according to claim 1 is characterized in that light source (1) is visible light or ultraviolet light.
3. photocatalysis separation film performance test device according to claim 2 is characterized in that visible light is that wavelength is the visible light of 500nm, and ultraviolet light is that wavelength is that ultraviolet light or the wavelength of 365nm is the ultraviolet light of 254nm.
4. photocatalysis separation film performance test device according to claim 1 is characterized in that treating being equipped with in the degradation product container (2) pressure transducer (9), and said pressure transducer (9) is electrically connected with computing machine (8).
5. photocatalysis separation film performance test device according to claim 1 is characterized in that being equipped with in the reaction vessel (6) temperature sensor (7), and said temperature sensor (7) is electrically connected with computing machine (8).
6. photocatalysis separation film performance test device according to claim 1 is characterized in that detecting device (4) is ultraviolet-visible spectrophotometer or gas chromatograph.
7. according to claim 1 or 6 described photocatalysis separation film performance test devices, it is characterized in that detecting device (4) is connected with container (5).
8. the method for testing of photocatalysis separation film performance test device according to claim 1 comprises the preparation for the treatment of degradation product and the catalysis of light, it is characterized in that said method comprises following steps:
(a) according to test purpose, prepare corresponding fluid, for the photocatalytic degradation reaction of liquid phase, obtain solution is for the photocatalytic degradation reaction of gas phase, preparation gas;
(b) according to the test needs, select the relevant detection device,, select ultraviolet-visible spectrophotometer,, select gas chromatograph for the photocatalytic degradation reaction of gaseous fluid for the photocatalytic degradation reaction of liquid phase fluid;
(c), determine that light source is visible light or ultraviolet light according to the type of photocatalysis separation film to be measured;
(d) record degradation data by the photodegradative process of flow control of computing machine, and by detecting device by setting;
(e) by computing machine according to the concentration of formulated fluids and the data that record, by formula
Calculate the photocatalysis quantum efficiency of photocatalysis separation film, in the formula: the quantum yield of ρ catalyzer, r be reaction rate,
Be the photon flow;
(f) calculate the adsorbance of photocatalysis separation film by computing machine by adsorption curve, thereby obtain the performance of the photocatalysis separation film tested.
9. the method for testing of photocatalysis separation film performance test device according to claim 8 is characterized in that solution is the methylene blue fluid of 20pmol/L or the phenol fluid of 20mg/L.
10. the method for testing of photocatalysis separation film performance test device according to claim 8 is characterized in that gas is the formaldehyde fluid of 5 μ mol/L or the triclene fluid of 5 μ mol/L.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101988890B (en) * | 2009-08-05 | 2012-05-16 | 中国科学院物理研究所 | Device and method for in situ measuring and evaluating properties of catalyst |
| CN102590439A (en) * | 2012-03-02 | 2012-07-18 | 中国建筑股份有限公司 | Detection apparatus and detection method for photocatalyzed gas degradation rate |
| CN103115999A (en) * | 2013-01-17 | 2013-05-22 | 长沙理工大学 | Gas-solid phase photocatalytic reaction effect detection device and method with controllable influence factor change |
| CN107748136A (en) * | 2017-09-26 | 2018-03-02 | 河海大学 | A kind of multifunctional photocatalysis film properties test system and its method of testing |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000162129A (en) * | 1998-11-30 | 2000-06-16 | Shinku Riko Kk | Evaluating method and evaluating device of photocatalyst function |
| US6290180B1 (en) * | 1999-09-09 | 2001-09-18 | Lockheed Martin Corporation | Photocatalytic coatings on optical solar reflectors to decompose organic contaminants |
| JP2001183321A (en) * | 1999-12-28 | 2001-07-06 | Research Institute Of Innovative Technology For The Earth | Method for evaluating photocatalytic film |
| CN1409109A (en) * | 2002-09-06 | 2003-04-09 | 华东师范大学 | Evaluation method for nano powder material light catalysis property |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101988890B (en) * | 2009-08-05 | 2012-05-16 | 中国科学院物理研究所 | Device and method for in situ measuring and evaluating properties of catalyst |
| CN102590439A (en) * | 2012-03-02 | 2012-07-18 | 中国建筑股份有限公司 | Detection apparatus and detection method for photocatalyzed gas degradation rate |
| CN102590439B (en) * | 2012-03-02 | 2014-10-29 | 中国建筑股份有限公司 | Detection apparatus and detection method for photocatalyzed gas degradation rate |
| CN103115999A (en) * | 2013-01-17 | 2013-05-22 | 长沙理工大学 | Gas-solid phase photocatalytic reaction effect detection device and method with controllable influence factor change |
| CN103115999B (en) * | 2013-01-17 | 2015-05-20 | 长沙理工大学 | Gas-solid phase photocatalytic reaction effect detection device and method with controllable influence factor change |
| CN107748136A (en) * | 2017-09-26 | 2018-03-02 | 河海大学 | A kind of multifunctional photocatalysis film properties test system and its method of testing |
| CN107748136B (en) * | 2017-09-26 | 2020-04-28 | 河海大学 | Multifunctional photocatalytic film performance test system and test method thereof |
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