CN101205583A - High strength and ductility high-damping wrought magnesium alloy and preparation thereof - Google Patents
High strength and ductility high-damping wrought magnesium alloy and preparation thereof Download PDFInfo
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- CN101205583A CN101205583A CNA2007101994279A CN200710199427A CN101205583A CN 101205583 A CN101205583 A CN 101205583A CN A2007101994279 A CNA2007101994279 A CN A2007101994279A CN 200710199427 A CN200710199427 A CN 200710199427A CN 101205583 A CN101205583 A CN 101205583A
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Abstract
The invention discloses a high-toughness high-damping magnesium alloy and the preparation method thereof and relates to magnesium-based material with high damping and good mechanical performance and the preparation method thereof. The invention solves the contradiction between the damping performance and the mechanical performance of the magnesium alloy; the proportion of the invention is: Si of 0.5 to 5 percent, Cu of 0.2 to 3 percent, Fe of less than 0.003 percent, Ni of less than 0.003 percent, other impurities of less than 0.06 percent, the remainder is magnesium. The preparation method is that: at first, high-pure magnesium is placed into NaOH aqueous solution, dried, then placed into a crucible for melting, is made a temperature rise to between 750 and 850 DEG C by adopting protective atmosphere, added with alloy elements according to the proportion, stirred and kept, then floating slags are fished out, the solution is made a temperature drop to between 640 and 680 DEG C to cast; the casting ingot is made a routine heat extrusion deformation, the temperature is controlled between 320 and 400 DEG C, the time of thermal insulation is 30 minutes, the extrusion speed is between 50 and 120mm/min, the extrusion ratio is 9-16:1, then the casting ingot is made a severe plastic deformation; finally the casting ingot is made a heat treatment, the temperature is controlled between 150 and 350 DEG C, the time of thermal insulation is between 0.5 and 10 hours. The invention successfully solves the contradiction between the strength and the damping performance of the magnesium alloy; the used equipment are all universal equipments, so the invention has strong implantability and low cost.
Description
The application by the applying date is: July 26, application number were in 2006: 2006100103268, denomination of invention is: what Cariaceous high-damping deformation magnesium alloy and manufacture method thereof were made divides an application.
Technical field
The present invention relates to a kind of mg-based material and preparation method thereof with high damping and good mechanical property.
Background technology
In the practical metallic substance, magnesium and alloy density thereof are minimum, are described as the ultralight amount material of 21 century.After nineteen nineties, development along with the magnesium smelting technology, magnesium output increases sharply, price descends, and particularly fields such as automobile, electronics, communication, aerospace and national defense and military industry have been brought the research of new round magnesium and used climax the increase day by day of magnesium alloy demand.Except that density was low, magnesium also has the another one distinguishing feature: in all light metal materials, pure magnesium had the highest damping capacity.But the intensity of pure magnesium is too low.And practical structure magnesium alloy, magnesium alloy as series such as Mg-Al-Zn, Mg-Zn-Zr and Mg-RE-Zr, its strengthening mechanism is mainly solution strengthening, precipitation strength etc., the solute atoms of these solid solutions and precipitated phase cause damping capacity to reduce greatly as the strong pinning point of magnesium basal slip dislocation.Along with the development of magnesium alloy research and the expansion of Application Areas, solve the contradiction between damping capacity and the mechanical property, the mg-based material that exploitation has high damping and good mechanical property simultaneously is one major issue to be solved.
Summary of the invention
The present invention is for the damping capacity that solves existing magnesium alloy and the contradictory problems between the mechanical property, and proposed a kind of Cariaceous high-damping deformation magnesium alloy and preparation method thereof.
Cariaceous high-damping deformation magnesium alloy of the present invention is following proportioning:
The Mg-Si-Cu magnesium alloy: described magnesium alloy comprises magnesium, silicon and copper, and the weight percent of each component is: silicon 0.5～5%, copper: 0.2～3%, and Fe＜0.003%, Ni＜0.003%, other impurity＜0.06%, surplus is a magnesium.
The present invention is prepared as follows Cariaceous high-damping deformation magnesium alloy: a, melting: place the NaOH aqueous solution to soak greater than industrial high-purity magnesium of 99.96% purity, put into iron crucible after the oven dry and melt, protective atmosphere is 10vol%SF
6+ 90vol%CO
2, be warming up to 750～850 ℃, add alloying element according to said ratio, fully stir melt, pull dross on surface of fusant out after leaving standstill, be cooled to 640～680 ℃ and be cast in the swage tool; B, distortion: the magnesium alloy ingot of institute's melting is carried out conventional hot extrusion deformation, the control extrusion temperature is 320～400 ℃, and soaking time is 30 minutes, and extrusion speed is 50～120mm/min, extrusion ratio is 9～16: 1, and the magnesium alloy after the conventional crimp is carried out intense plastic strain; C, thermal treatment: the magnesium alloy after the distortion is heat-treated, and the control thermal treatment temp is 150～350 ℃, and soaking time is 0.5～10 hour.By adding suitable alloying element, adopting specific melting technology, deformation technique and thermal treatment process to prepare Cariaceous high-damping deformation magnesium alloy, the damping capacity of magnesium alloy and the contradiction of mechanical property have been solved.
The invention has the advantages that:
(1) composition advantage: selected the minimum alloying element of copper and silicon solid solubility in magnesium for use, according to the dislocation damping theory, the solid solution atomic percent in the magnesium alloy is little, and then the weak pinning point quantity of mobile dislocation is few, the damping capacity height of alloy.
(2) process advantage: except that conventional hot extrusion, intense plastic strain technology-equal channel angle extrusion technique (ECAP) and multiway forging (MDF) have also been adopted, the distinguishing feature of intense plastic strain is: under the prerequisite of the sectional area that does not change material, can carry out repeated deformation to material, the accumulation strain amount can surpass 10, and the refinement material structure is adjusted grain orientation, obtain the superfine crystal particle material of bulk, significantly increase the intensity and the plasticity of material.
(3) equipment advantage: equipment of the present invention, comprise that alloy melting stove, heat extruder, equal channel angle extruding with pressing machine and heat treatment furnace, are conventional general-purpose equipment, portable strong, with low cost.
The accessible index of performance of the Cariaceous high-damping deformation magnesium alloy of the bright preparation of we is: tensile strength 320～380Mpa, yield strength 230～260Mpa, unit elongation＞10%, Q
-1＞0.01.
Embodiment
Embodiment one: the Cariaceous high-damping deformation magnesium alloy of present embodiment is the Mg-Si-Cu alloy, the weight percent of each component is: silicon 0.5～5%, copper: 0.2～3%, and Fe＜0.003%, Ni＜0.003%, other impurity＜0.06%, surplus are magnesium.
Embodiment two: present embodiment is prepared as follows the Mg-Si-Cu magnesium alloy:
(1) purity being placed concentration greater than industrial high-purity magnesium of 99.96% is after 0.5% the NaOH aqueous solution soaks 0.5 hour, to dry in 150 ℃ of loft drier; The pure magnesium of exsiccant is put into iron crucible melt, protective atmosphere is 10vol%SF
6+ 90%CO
2, be warming up to 750～850 ℃, get silicon 0.5～5%, copper according to weight percent: 0.2～3% adds alloying element, and silicon and copper add with the form of technical pure simple substance.After adding alloying element, fully stir melt, left standstill 20 minutes, pull dross on surface of fusant out, be cooled to 640～680 ℃ and be cast in the swage tool.
(2) magnesium alloy ingot with institute's melting carries out conventional hot extrusion, and hot extrusion is carried out on water pressure engine, and extrusion temperature is 320～400 ℃, soaking time 30 minutes, and extrusion speed is 50～120mm/min, extrusion ratio is 9～16: 1.Magnesium alloy after the conventional crimp is carried out equal channel angle crimp (Equal ChannelAngular Pressing, ECAP), two interchannel angles of equal channel angle extrusion mould are 90 °, texturing temperature is 150～350 ℃, Deformation velocity is 20～60mm/min, rolling pass is 1～8 time, every time magnesium alloy along axis to same direction half-twist.
(3) magnesium alloy after extruding and the equal channel angle crimp is heat-treated, thermal treatment temp is 150～350 ℃, and soaking time is 0.5～10 hour.Yield strength is 192MPa, and tensile strength is 298MPa, unit elongation 21%, Q
-1Be 0.018.
Embodiment three: present embodiment and embodiment two differences are, after magnesium alloy ingot carried out hot extrusion, carry out multiway forging (Multi-Directional Forging, MDF), the multiway forging temperature is 150～350 ℃, and strain rate is 1 * 10
-3～3 * 10
-2S
-1Three (Z) deformation sequence is X → Y → Z for X, Y, X, and Y and Z three between centers angles are 90 ° and satisfy the right-hand rule; It is 0.3～1.0 that each direction is forged dependent variable, and the accumulation strain amount is 7～10.Yield strength is 203MPa, and tensile strength is 287MPa, unit elongation 18%, Q
-1Be 0.016.
Claims (5)
1. Cariaceous high-damping deformation magnesium alloy is characterized in that described magnesium alloy is the Mg-Si-Cu alloy, and the weight percent of each component is: silicon 0.5～5%, copper: 0.2～3%, and Fe＜0.003%, Ni＜0.003%, other impurity＜0.06%, surplus is a magnesium.
2. the preparation method of Cariaceous high-damping deformation magnesium alloy is characterized in that described method is: a, melting: place the NaOH aqueous solution to soak greater than industrial high-purity magnesium of 99.96% purity, put into iron crucible after the oven dry and melt, protective atmosphere is 10vol%SF
6+ 90vol%CO
2, be warming up to 750～850 ℃, add alloying element according to the proportioning of claim 1, fully stir melt, pull dross on surface of fusant out after leaving standstill, be cooled to 640～680 ℃ and be cast in the swage tool; B, distortion: the magnesium alloy ingot of institute's melting is carried out conventional hot extrusion, the control extrusion temperature is 320～400 ℃, and soaking time is 30 minutes, and extrusion speed is 50～120mm/min, extrusion ratio is 9～16: 1, and the magnesium alloy after the conventional crimp is carried out intense plastic strain; C, thermal treatment: the magnesium alloy after the distortion is heat-treated, and the control thermal treatment temp is 150～350 ℃, and soaking time is 0.5～10 hour.
3. the preparation method of Cariaceous high-damping deformation magnesium alloy according to claim 2 is characterized in that described viscous deformation is equal channel angle extruding or multiway forging.
4. the preparation method of Cariaceous high-damping deformation magnesium alloy according to claim 3, the concrete processing parameter that it is characterized in that described equal channel angle extruding is: two interchannel angles of equal channel angle extrusion mould are 90 °, texturing temperature is 150～350 ℃, Deformation velocity is 20～60mm/min, rolling pass is 1～8 time, every time magnesium alloy along axis to same direction half-twist.
5. the preparation method of Cariaceous high-damping deformation magnesium alloy according to claim 3, it is characterized in that the concrete processing parameter of described multiway forging is: the multiway forging temperature is 150～350 ℃, strain rate is 1 * 10
-3～3 * 10
-2S
-1, three shaft distortions are X → Y → Z in proper order, X, and Y and Z three between centers angles are 90 ° and satisfy the right-hand rule; It is 0.3～1.0 that each direction is forged dependent variable, and the accumulation strain amount is 7～10.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710199427A CN100577836C (en) | 2006-07-26 | 2006-07-26 | High strength and ductility high-damping wrought magnesium alloy and preparation thereof |
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| CN200710199427A CN100577836C (en) | 2006-07-26 | 2006-07-26 | High strength and ductility high-damping wrought magnesium alloy and preparation thereof |
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| CNB2006100103268A Division CN100463989C (en) | 2006-07-26 | 2006-07-26 | Cariaceous high-damping deformation magnesium alloy and its prepn process |
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| CN101205583A true CN101205583A (en) | 2008-06-25 |
| CN100577836C CN100577836C (en) | 2010-01-06 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649408B (en) * | 2009-09-09 | 2011-05-25 | 西北工业大学 | Method for preparing Mg-Si high damping alloy |
| CN103911569A (en) * | 2012-12-28 | 2014-07-09 | 北京有色金属研究总院 | Method for weakening anisotropy of wrought magnesium alloy product |
| CN106191586A (en) * | 2016-07-31 | 2016-12-07 | 余姚市婉珍五金厂 | Alloy material that a kind of machine cut blade is special and preparation method thereof |
| CN106282707A (en) * | 2016-07-31 | 2017-01-04 | 余姚市婉珍五金厂 | Magnesium alloy materials that a kind of automobile crane is special and preparation method thereof |
| CN106929723A (en) * | 2017-04-10 | 2017-07-07 | 广西科技大学 | A kind of high damping properties magnesium base alloy mechanical material and preparation method thereof |
| CN107012969A (en) * | 2017-03-27 | 2017-08-04 | 同济大学 | A kind of new masonry constructional device for resisting mud-rock-flow-impact |
| CN107598812A (en) * | 2017-10-23 | 2018-01-19 | 宝鸡金恒瑞金属科技有限公司 | A kind of flywheel disassembling wrench for electric bicycle |
| CN109082572A (en) * | 2018-10-18 | 2018-12-25 | 广州宇智科技有限公司 | A kind of novel flame-retardant and magnesium alloy and its processing technology with high damping properties |
| CN109868380A (en) * | 2017-12-01 | 2019-06-11 | 南京理工大学 | A kind of preparation method of multiple dimensioned precipitation strength magnesium alloy materials |
| EP3325190A4 (en) * | 2015-07-23 | 2019-08-14 | Hydrexia Pty Ltd | Mg-based alloy for hydrogen storage |
| CN113083930A (en) * | 2021-04-12 | 2021-07-09 | 兰州理工大学 | Differential thermal forming method for preparing high-strength and high-toughness magnesium alloy |
-
2006
- 2006-07-26 CN CN200710199427A patent/CN100577836C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649408B (en) * | 2009-09-09 | 2011-05-25 | 西北工业大学 | Method for preparing Mg-Si high damping alloy |
| CN103911569A (en) * | 2012-12-28 | 2014-07-09 | 北京有色金属研究总院 | Method for weakening anisotropy of wrought magnesium alloy product |
| EP3325190A4 (en) * | 2015-07-23 | 2019-08-14 | Hydrexia Pty Ltd | Mg-based alloy for hydrogen storage |
| CN106191586A (en) * | 2016-07-31 | 2016-12-07 | 余姚市婉珍五金厂 | Alloy material that a kind of machine cut blade is special and preparation method thereof |
| CN106282707A (en) * | 2016-07-31 | 2017-01-04 | 余姚市婉珍五金厂 | Magnesium alloy materials that a kind of automobile crane is special and preparation method thereof |
| CN107012969A (en) * | 2017-03-27 | 2017-08-04 | 同济大学 | A kind of new masonry constructional device for resisting mud-rock-flow-impact |
| CN106929723A (en) * | 2017-04-10 | 2017-07-07 | 广西科技大学 | A kind of high damping properties magnesium base alloy mechanical material and preparation method thereof |
| CN107598812A (en) * | 2017-10-23 | 2018-01-19 | 宝鸡金恒瑞金属科技有限公司 | A kind of flywheel disassembling wrench for electric bicycle |
| CN109868380A (en) * | 2017-12-01 | 2019-06-11 | 南京理工大学 | A kind of preparation method of multiple dimensioned precipitation strength magnesium alloy materials |
| CN109868380B (en) * | 2017-12-01 | 2021-09-03 | 南京理工大学 | Preparation method of multi-scale precipitation strengthening magnesium alloy material |
| CN109082572A (en) * | 2018-10-18 | 2018-12-25 | 广州宇智科技有限公司 | A kind of novel flame-retardant and magnesium alloy and its processing technology with high damping properties |
| CN113083930A (en) * | 2021-04-12 | 2021-07-09 | 兰州理工大学 | Differential thermal forming method for preparing high-strength and high-toughness magnesium alloy |
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| CN100577836C (en) | 2010-01-06 |
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