CN101193950A - Fragrance alcohol-releasing polysiloxane - Google Patents

Fragrance alcohol-releasing polysiloxane Download PDF

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Publication number
CN101193950A
CN101193950A CNA2006800201451A CN200680020145A CN101193950A CN 101193950 A CN101193950 A CN 101193950A CN A2006800201451 A CNA2006800201451 A CN A2006800201451A CN 200680020145 A CN200680020145 A CN 200680020145A CN 101193950 A CN101193950 A CN 101193950A
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Prior art keywords
alcohol
methyl
acid
dimethyl
organopolysiloxane
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H-J·克勒
T·萨洛蒙
小R·C·史密斯
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Evonik Operations GmbH
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Evonik Degussa GmbH
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Abstract

The invention relates to organopolysiloxanes which contain an alcohol odorous substance Y-OH, are tied up by means of a betaine ester group having a -N<+>R<1>R<2>-CH2-C(O)OY structure, split the alcohol odorous substance under acid conditions and are hydrolysis stable in a neutral and slightly acid area. The inventive organopolysiloxanes are fixable to textile fibres, skin and hairs and are suitable in the form of perfume components for textile treatment and body care agents.

Description

Discharge the polysiloxane of fragrance alcohol
The invention provides the organopolysiloxane that under acidic conditions, can therefrom discharge fragrance alcohol (fragrancealcohol).
For fabric-treating agent and personal care product, need for a long time attached to the perfume composition on fabric fibre, hair or the skin, they are in these places chronically and discharge the fragrance matter of spices under the condition of control.The user who it is desirable to the dry goods article handled until personal care product or fabric-treating agent herein especially perspires and just discharges the perfume composition of its fragrance matter when forming body odour beastly owing to perspire.Body odour beastly is generally formed by bacterium, and it decomposes the composition of sweat.Except the compound of offensive odour was sent in formation, this degradation by bacteria also produced the acid degradation product.Therefore, fabric-treating agent and personal care product's perfume composition need comprise fragrance matter with the form of bonding, and only discharges them under acidic conditions, savours thereby the spices that can obtain to strengthen under these conditions is used for eliminating producing.
The betaine ester of fragrance alcohol is known from WO 96/38528, and it can be used for washing composition, fabric softener or sanitising agent, and adheres on the surface of fabric fibre for example.Discharge fragrance alcohol by hydrolysis from these betaine esters, the release of fragrance alcohol only takes place under acidic conditions very lentamente.Only 7 or higher pH under from betaine ester, discharge fragrance alcohol.
The betaine ester of known fragrance alcohol hydrolysis in acid range also from WO 97/36978, and only under the pH value more than 7, discharge fragrance alcohol by hydrolysis.
The betaine ester of disclosed fragrance alcohol also is stable in acid range in EP-A 1 099 689.
For using betaine ester as the hair products composition, DE 35 27 974 also discloses the pH-dependency of identical betaine ester stability.
At US 4,524, in 018 in the disclosed organoalkoxysilane, with the savory alcohol roh of form bonding of Si-O-R group.From these compounds, discharge fragrance alcohol lentamente.The document does not have the open pH-dependency that discharges fragrance alcohol from organoalkoxysilane, and disclosed organoalkoxysilane is not because they demonstrate or can not produce positive charge and can maintenance and the adhesion of fabric fibre, skin or hair.
EP-A 0 982 023 has described and has comprised the polysiloxane of bonding fragrance alcohol by the Si-O-R group, and they are as the purposes of the composition of cosmetic formulations.Fragrance alcohol discharges from polysiloxane in the presence of acetate lentamente.But disclosed polysiloxane does not show enough sticking power to the surface (for example fabric fibre, skin or hair) with negative surface charge, because they do not demonstrate or can not produce positive charge.
Be to have been found that now to comprise to be-N astoundingly by structure +R 1R 2-CH 2The cracking under acidic conditions of the organopolysiloxane of the fragrance alcohol Y-OH of the betaine ester group bonding of-C (O) OY produces fragrance alcohol, and anti-hydrolysis in neutrality or weakly alkaline scope unexpectedly.These organopolysiloxanes demonstrate good adhering to fabric fibre, skin or hair, and this makes them be suitable as fabric-treating agent or personal care product's perfume composition.
Therefore, the invention provides the organopolysiloxane that therefrom can discharge fragrance alcohol, wherein said organopolysiloxane comprises at least one Z of functional group with following structure:
-N +R 1R 2-CH 2-C(O)OYA -
R wherein 1, R 2Be selected from C independently of each other 1-30In alkyl and the hydroxyethyl,
Y is the group of fragrance alcohol Y-OH, and
A -It is the negatively charged ion of the compatible sour HA of physiology.
The present invention also provides and has comprised at least a fabric-treating agent and personal care product with organopolysiloxane of said structure; And comprise at least a tensio-active agent and at least a washing composition with organopolysiloxane of said structure; Comprise at least a fragrant fabric purificant with form with organopolysiloxane of said structure with aqueous dispersions.
The organopolysiloxane of indication is the compound that comprises at least three Siliciumatoms among the present invention, described three Siliciumatoms are bonded together by the Si-O-Si unit, and Siliciumatom wherein over half demonstrates at least one group by carbon atom and silicon atom bonding.Preferably comprise 3-200 and preferred especially 5-100 Siliciumatom according to organopolysiloxane of the present invention.In organopolysiloxane according to the present invention, preferably surpass 50% and especially preferably surpass 80% Siliciumatom and have two groups by carbon atom and silicon atom bonding.Group by carbon atom and silicon atom bonding can be C 1-30Alkyl, C 2-30Thiazolinyl or C 6-30Aryl, they can demonstrate other substituting group.Group by carbon atom and silicon atom bonding is methyl or phenyl and special preferable methyl preferably.
Organopolysiloxane according to the present invention comprises at least one betaine ester group with following structure:
-N +R 1R 2-CH 2-C(O)OYA -
This group and polysiloxane covalent bonding and wherein
R 1, R 2Be selected from C independently of each other 1-30In alkyl and the hydroxyethyl,
Y is the group of fragrance alcohol Y-OH, and
A -It is the negatively charged ion of the compatible sour HA of physiology.
In a preferred embodiment of the invention, the betaine ester group is connected with the Siliciumatom of organopolysiloxane by the hydroxy ethylene bridge, and organopolysiloxane has following structure:
R 3R 4R 5Si-O-CH 2-CH 2-N +R 1R 2-CH 2-C(O)OYA -
Wherein
R 3Be polysiloxane group by the Sauerstoffatom bonding,
R 4Be C 1-30Alkyl or phenyl,
R 5=R 3Or R 4And
R 1, R 2, Y and A -Has above-mentioned meaning.
In particularly preferred embodiment of the present invention, the betaine ester group is by hydroxy ethylene bridge and the terminal silicon atom bonding with polydimethylsiloxane of 2-300 Siliciumatom.In this particularly preferred embodiment, organopolysiloxane has following structure:
R 6-O-[Si(CH 3) 2-O] n-R 6
Wherein
n＝3-200，
R 6=-CH 2-CH 2-N +(CH 3) 2-CH 2-C (O) OYA -, and
Y and A -Has above-mentioned meaning.
Fragrance alcohol Y-OH in meaning of the present invention has fragrance and has compound with the hydroxyl of carbon atom bonding, and wherein dehydrogenation and carbon do not have other atom and this carbon atom bonding outward.Preferably comprise fragrance alcohol Y-OH according to organopolysiloxane of the present invention as the flavoring formulation composition with bonding scheme.
Especially preferably comprise the fragrance alcohol Y-OH:4-allyl group-2-methoxyphenol (Eugenol) that is selected from the following series according to organopolysiloxane of the present invention with bonding scheme, 3-(2-borneol oxygen base)-2-methyl isophthalic acid-propyl alcohol, 2-tertiary butyl hexalin, 4-tertiary butyl hexalin, benzylalcohol, 1-decanol, 9-decen-1-ol, dihydroterpineol, 2,4-dimethyl-4-tetrahydrobenzene-1-base methyl alcohol, 2,4-Dimethylcyclohexyl methyl alcohol, 2,6-dimethyl-2-enanthol, 2, the 6-2,6-dimethyl-4-heptanol, 3a, 4,5,6,7,7a-six hydrogen-2,4-dimethyl-4,7-methyl alcohol [1H] indenes-5-alcohol, 3,7-dimethyl-1,6-nonadiene-3-alcohol, 2,6-dimethyl-2,7-octadiene-6-alcohol (Linaool), suitable-3,7-dimethyl-2,6-octadiene-1-alcohol (vernol), instead-3,7-dimethyl-2,6-octadiene-1-alcohol (Geraniol), 3,7-dimethyl-1, the 7-ethohexadiol, 3,7-dimethyl-1-octanol (tetrahydrogeraniol), 2,6-dimethyl-sec-n-octyl alcohol (Tetrahydromyrcenol), 3,7-dimethyl-3-octanol (tetrahydrolinalool), 2,6-dimethyl-7-octen-2-ol (dihydromyrcenol), 3,7-dimethyl-6-octen-1-ol (geraniol), 2,2-dimethyl-3-(3-aminomethyl phenyl)-1-propyl alcohol, 2,2-dimethyl-3-phenyl-1-propyl alcohol, 2-oxyethyl group-4-creosol, 2-ethyl-4-(2,2,3-trimethylammonium-3-tetrahydrobenzene-1-yl)-2-butylene-1-alcohol, suitable-blatter alcohol, 4-(4-hydroxy 3-methoxybenzene base)-2-butanone, 1-hydroxyl-2-(1-methyl isophthalic acid-hydroxyethyl)-5-methylcyclohexanone, 3-(methylol)-methyl n-heptyl ketone, 4-(4-hydroxy-4-methyl amyl group)-3-cyclic ethylene-1-carboxyl aldehyde, iso-borneol, the 3-Santalex, 2-pseudoallyl-5-methyl-cyclohexanol (l-Isopulegol), 1-sec.-propyl-4-methyl cyclohexane-3-enol (Terpineol 350), the 4-isopropyl cyclohexanol, 1-(4-isopropylcyclohexyl-) ethanol, 4-isopropylcyclohexyl-methyl alcohol, 2-sec.-propyl-5-methyl-cyclohexanol (menthol), 2-sec.-propyl-5-cresols (thymol), 5-sec.-propyl-2-cresols (isothymol), 2-(4-methyl-3-cyclohexyl)-2-propyl alcohol (Terpineol 350), 2-(4-methylcyclohexyl)-2-propyl alcohol (dihydroterpineol), 4-methoxyl group benzylalcohol, 2-methoxyl group-4-cresols, 3-methoxyl group-5-cresols, 1-methoxyl group-4-propenylbenzene (methyl allylphenol), 2-methoxyl group-propenylphenol (isoeugenol), 4-methyl-3-decene-5-alcohol, 2-methyl-6-methylene radical-7-octen-2-ol (myrcenol), 3-methyl-4-phenyl-2-butanols, 2-(2-aminomethyl phenyl) ethanol, 2-methyl-4-phenyl-1-amylalcohol, 3-methyl-5-phenyl-1-amylalcohol, 2-methyl isophthalic acid-phenyl-2-propyl alcohol, (1-methyl-2-(1,2,2-trimethylammonium dicyclo [3.1.0] oneself-the 3-ylmethyl) cyclopropyl) methyl alcohol, 3-methyl-4-(2,2,6-trimethyl cyclohexene-1-yl)-the 2-butanols, 2-methyl-4-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-2-butylene-1-alcohol, (3-methyl isophthalic acid-(2,2,3-trimethylammonium-3-cyclopentenyl)-and 3-tetrahydrobenzene-1-yl) methyl alcohol, 3-methyl-5-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-4-amylene-2-alcohol, 2-methyl-2-vinyl-5-(1-hydroxyl-1-methylethyl) tetrahydrofuran (THF), instead, suitable-2, the 6-nonadienol, 1 nonyl alcohol, nopol, 1,2,3,4,4a, 5,6,7-octahydro-2,5,5-trimethylammonium-beta naphthal, the 1-octanol, 3,4,5,6,6-pentamethyl--2-enanthol, the 2-phenylethyl alcohol, the 2-phenyl propanol, 3-phenyl propanol (hydrocinnamyl alcohol), 3-phenyl-2-propylene-1-alcohol (styryl carbinol), 4-(5,5,6-trimethylammonium dicyclo [2.2.1] heptan-2-yl)-hexanaphthene-1-alcohol, 3,5, the 5-cyclonol, 2,4,6-trimethylammonium-4-tetrahydrobenzene-1-base methyl alcohol, 5-(2,2,3-trimethylammonium-3-cyclopentenyl)-3-methylpent-2-alcohol, 3,7,11-trimethylammonium-2,6,10-12 carbon triolefin-1-alcohol (farnesol), 3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol (nerolidol), 3,5,5-trimethylammonium-1-hexanol (isononyl alcohol), the 1-undecyl alcohol, the pure and mild vetiverol of 10-hendecene-1-.
The negatively charged ion A of the sour HA that physiology in meaning of the present invention is compatible -It all is the negatively charged ion that human skin is not had corrodibility or obvious stimulation effect.Negatively charged ion A -Be preferably selected from chlorion, bromide anion, methylsulfate (methyl sulfate), ethyl sulphate (ethyl sulfate), sulfate radical, nitrate radical, phosphate radical or the hydrogen phosphate.
The organopolysiloxane and the chloracetate of fragrance alcohol that can be by comprising uncle's amino according to organopolysiloxane of the present invention react and obtain.The chloracetate of fragrance alcohol can obtain by the currently known methods of Mono Chloro Acetic Acid muriate and fragrance alcohol reaction, and described reaction is preferably carried out in the presence of alkali, and alkali combines with the hydrogenchloride of release in the reaction.
The organopolysiloxane that comprises uncle's amino can obtain by a series of known methods.The universal method for preparing these compounds is in nucleophilic substitution reaction, secondary amine and the reaction that comprises the organopolysiloxane of suitable leavings group.The specific embodiments of this reaction is the reaction that comprises the organopolysiloxane and the secondary amine of the group with epoxide group, epoxide open loop and formation beta-alkamine.
In the preferred organopolysiloxane, the betaine ester group is connected with the Siliciumatom of organopolysiloxane by the hydroxy ethylene bridge, and it is the organopolysiloxane by comprising at least one Si-H group and have structure HO-CH preferably 2-CH 2-NR 1R 2Thanomin reaction, react with the chloracetate of fragrance alcohol subsequently and obtain, wherein R 1And R 2Has aforementioned meaning.
R 3R 4R 5Si-H+HO-CH 2-CH 2-NR 1R 2→
R 3R 4R 5Si-O-CH 2-CH 2-NR 1R 2
R 3R 4R 5Si-O-CH 2-CH 2-NR 1R 2+ClCH 2-C(O)OY→
R 3R 4R 5Si-O-CH 2-CH 2-N +R 1R 2-CH 2-C(O)OY Cl -
In aqueous dispersions, organopolysiloxane according to the present invention demonstrates high resistance to hydrolysis, and can adhere to from aqueous dispersions on fabric fibre, skin or the hair.In meaning of the present invention, the term aqueous dispersions is not limited to the dispersion liquid of SOLID ORGANIC polysiloxane, and it also comprises emulsion and the microemulsion and the micellar solution of liquid organopolysiloxane.Therefore, organopolysiloxane according to the present invention is suitable as fabric-treating agent or personal care product's composition, and give such character can for these reagent and product: fabric of handling with described fabric-treating agent or the character that demonstrates long-term fragrance with the hair or the skin of described personal care product's processing, described fragrance is from the delay release of fragrance alcohol from organopolysiloxane.
According to organopolysiloxane of the present invention herein preferably under the pH3 than under pH9 in aqueous dispersions the organopolysiloxane of faster release fragrance alcohol Y-OH.The faster release of fragrance alcohol is unexpected and unforeseen in acid range because from the betaine ester of the known fragrance alcohol of prior art all slower under the pH3 than under pH9, discharging fragrance alcohol.
These preferred organopolysiloxanes can be used to provide fabric-treating agent or personal care product, wherein fabric of handling with fabric-treating agent or the hair of handling with described personal care product or skin are wetting by sweat, and when the degradation by bacteria of sweat composition descends pH, produce stronger fragrance by discharging fragrance alcohol.Therefore, comprise the fabric-treating agent of this organopolysiloxane or personal care product and can eliminate the offensive odour that the degradation by bacteria by the sweat composition causes effectively.
Fabric-treating agent according to the present invention comprises at least a according to organopolysiloxane of the present invention, and is preferred for handling fabric with the aqueous solution or the dispersion liquid of this fabric-treating agent, and organopolysiloxane wherein according to the present invention adheres on the fabric fibre.Except the target release of fragrance alcohol, also make the fiber that has adhered to organopolysiloxane cause that fabric has softer feel according to organopolysiloxane of the present invention.Therefore, also demonstrate fabric softening character according to fabric-treating agent of the present invention.
According to fabric-treating agent of the present invention can be solid form, for example powder, particle or moulded product, for example form of extrudate, pill, briquetting or tablet.The fabric-treating agent of solid form also can comprise be administered on the suitable solid support material according to liquid organopolysiloxane of the present invention.The porosu solid composition that preferably uses the fabric-treating agent of realizing additional function in fabric-treating agent is as the solid support material that is used for according to liquid organopolysiloxane of the present invention.The fabric-treating agent of the moulded product form by extruding caking method (for example extrude, briquetting or compressing tablet) preparation can also comprise the intensity that binding agent improves moulded product.But fabric-treating agent does not preferably contain other binding agent, and with a kind of function ingredients of fabric-treating agent, preferred nonionic surfactants is as binding agent.
In optional embodiment, can also be liquid or gel form according to fabric-treating agent of the present invention.In these embodiments, fabric-treating agent preferably comprise the dissolving or discrete form according to organopolysiloxane of the present invention, wherein term dispersive form contains the emulsion of the dispersion liquid and the liquid organopolysiloxane of SOLID ORGANIC polysiloxane, and microemulsion and micellar solution.
The fabric-treating agent of liquid form can demonstrate the rheological property of isotropy, thixotropic, false plastomer or shear-thinning.In order to regulate rheological property, liquid or gel fabric-treating agent can comprise additive swelling clay, particularly montmorillonite, precipitation or pyrogenic silica, vegetable jelly, and particularly xanthan gum or polymer gel agent for example comprise the vinyl polymer of carboxyl.These additives at first give fabric-treating agent required viscosity, and next is kept insoluble composition and is dispersed in the fabric-treating agent with the dispersive form.
Comprise at least a tensio-active agent and at least a washing composition and be a preferred embodiment according to fabric-treating agent of the present invention according to organopolysiloxane of the present invention.Washing composition in meaning of the present invention all is to be suitable for to contain the preparation of water lotion cleaning fabric.
Be applicable to that the tensio-active agent according to washing composition of the present invention the most important thing is negatively charged ion, nonionic and cats product.
Suitable anion surfactant is for example to have sulfonic tensio-active agent, preferred alkyl benzene sulfonate, alkylsulfonate, sulfonated, alpha-sulfo fatty acid ester or sulfosuccinate.Alkylbenzene sulfonate with straight or branched alkyl of 8-20 carbon atom, a particularly 10-16 carbon atom is preferred.Preferred alkylsulfonate is the example with linear alkyl chain of 12-18 carbon atom.The preferred use has the alpha-olefin sulfonation reaction product of 12-18 carbon atom as the alpha-olefin sulphonate.From lipid acid with 12-18 carbon atom and the sulfonated products with fatty acid ester that the short chain alcohol of 1-3 carbon atom makes preferably as alpha-sulfo fatty acid ester.The tensio-active agent that has sulfate groups in the molecule, preferred alkyl vitriol and sulfuric acid ether also are suitable as anion surfactant.Preferred alkyl-sulphate is the example with straight chained alkyl of 12-18 carbon atom.β-branched-chain alkyl the vitriol and the alkyl-sulphate that replace at long alkyl chain middle part monoalkyl or many alkyl also are fit to.Preferred sulfuric acid ether is by the linear alcohol with 12-18 carbon atom and 2-6 ethylene oxide unit ethoxylation and the alkyl sodium sulfate ether that obtains of sulfation subsequently.At last, soap also can be used as anion surfactant, for example an alkali metal salt of lauric acid, tetradecanoic acid, palmitinic acid, stearic acid and/or natural acid mixture (for example coconut, palm kernel or the acid of animal resin acid).
For example, oxyalkylated compound is suitable as nonionogenic tenside, particularly ethoxylation and propenoxylated compound.Particularly suitable is alkylphenol or Fatty Alcohol(C12-C14 and C12-C18) and 1-50mol, the oxyethane of preferred 1-10mol and/or the condensation product of propylene oxide.Polyhydroxy fatty acid amide also is suitable, wherein has one or more hydroxyls and organic group and amide nitrogen bonding that can alkoxyization.Have the alkylglycoside of straight or branched alkyl of 8-22 carbon atom, a particularly 12-18 carbon atom and single glycosides or two glycosides that preferably come from glucose and also be suitable as nonionogenic tenside.
Suitable cats product for example has, and has the C with the nitrogen bonding 6-C 18Monoalkoxyization and quaternary amines dialkoxyization of alkyl group and one or two hydroxyalkyl.
According to organopolysiloxane of the present invention and at least a tensio-active agent, for example can also comprise washing assistant, basic component, SYNTHETIC OPTICAL WHITNER, bleach-activating agent, enzyme, chelating complexing agent, ashing inhibitor, froth suppressor, white dyes, spices and dyestuff component as a supplement except at least a according to washing composition of the present invention.
Washing composition according to the present invention when in water, using, can comprise can with dissolved calcium and magnesium ion bonded washing assistant.Suitable washing assistant has alkali metal phosphate and alkali metal polyphosphates, particularly Thermphos SPR, water-soluble and water-insoluble water glass, particularly has general formula Na 5Si 2O 5Layered silicate; Zeolite with structure A, X and/or P; And trisodium citrate.Except washing assistant, can also use organic altogether washing assistant (co-builder), for example the multipolymer of polyacrylic acid, poly aspartic acid and/or vinylformic acid and methacrylic acid, propenal or contain the vinyl monomer of sulfonic acid and their an alkali metal salt.
Generally also comprise basic component according to washing composition of the present invention, it makes in washing lotion or the water-detergent solution pH when using as required in the 8-12 scope.Yellow soda ash, sodium sesquicarbonate, Starso and other soluble alkalimetal silicate are suitable as basic component most.
Can also comprise SYNTHETIC OPTICAL WHITNER according to washing composition of the present invention, for example alkali metal perborate, alkaline carbonate perhydrate, basic metal persilicate, alkali metal persulphate, basic metal peroxide phosphoric acid salt, basic metal pyrophosphate peroxide, peroxidation two acyls, aromatic series peroxy acid and aliphatics peroxy acid.Preferred SYNTHETIC OPTICAL WHITNER is that four hydrated sodium perborates, sodium perborate monohydrate, hydrogen peroxide close yellow soda ash, peroxide lauric acid, peroxide stearic acid, ε-phthalimido-peroxycarboxylic acid, 1,12-diperoxy dodecanedioic acid, 1,9-diperoxy nonane diacid and 2-diperoxy in last of the ten Heavenly stems butane-1, the 4-diacid.Particularly preferably be four hydrated sodium perborates, sodium perborate monohydrate and hydrogen peroxide and close yellow soda ash, particularly hydrogen peroxide closes yellow soda ash.It is known from WO 2004/056955 that the hydrogen peroxide that is applicable to liquid washing agent closes yellow soda ash.
Except that SYNTHETIC OPTICAL WHITNER, can also comprise bleach-activating agent according to washing composition of the present invention.Have acyl group one or more and nitrogen or oxygen bonding, and can cross hydrolysis, the compound with the hydroperoxidation formation peroxycarboxylic acid that discharges from SYNTHETIC OPTICAL WHITNER in washing lotion is suitable as the bleach-activating agent that is used for according to washing composition of the present invention most.These examples for compounds have many acidylates Alkylenediamine, for example particularly tetra-acetylated ethylene diamine (TAED); The acidylate pyrrolotriazine derivatives, particularly 1,5-diacetyl-2,4-dioxy six hydrogen-1,3,5-triazines (DADHT); The acidylate glycoluril, particularly tetra-acetylated glycoluril (TAGU); N-acyl group imines, particularly N-nonanoyl succinimide (NOSI); Acidylate sulfonic acid phenol, particularly positive nonanoyl or different nonanoyl sulphonyl oxybenzene ester (just-or different-NOBS); Carboxylic acid anhydride, for example Tetra hydro Phthalic anhydride; The acidylate polyvalent alcohol, glycol diacetate, 2 for example, 5-diacetoxy-2, the sugar of 5-dihydrofuran, acetylize sorbitanic and mannitol and acidylate, for example five acetyl glucose; Enol ester; And N-acyl lactam, particularly N-acyl caprolactam and N-acyl group Valerolactim.The nitrile of aminofunctional and salt thereof (season nitrile) also are suitable as bleach-activating agent, and they are for example from magazine Tenside Surf.Det.1997, and 34 (6), known in the 404-409 page or leaf.Hydrogen peroxide can be activated and also bleach-activating agent can be used as by the transition metal complex of bleaching scrubbing.Suitable transition metal complex is for example known from following document: EP-A 0 544 490 page 2 the 4th walk to page 3 the 57th row, WO 00/52124 page 5 the 9th walks to the 8th page of the 7th row and the 8th page the 19th and walks to the 11st page of the 14th row, WO 04/039932 page 2 the 25th walks to the 10th page of the 21st row, WO 00/12808 walks to the 33rd page of the 29th row for the 6th page the 29th, WO 00/60043 walks to the 17th page of the 22nd row for the 6th page the 9th, capable and the page 3 the 7th of WO 00/27975 page 2 1-18 walks to page 4 the 6th row, WO 01/05925 page 1 the 28th walks to page 3 the 14th row, WO 99/64156 page 2 the 25th walks to the 9th page of the 18th row, and GB-A 2 309976 page 3 the 1st walk to the 8th page of the 32nd row.
Also comprise enzyme according to washing composition of the present invention, it has strengthened cleaning action, particularly lipase, at, amylase, neutrality and Sumizyme MP, esterase, cellulase, polygalacturonase, Sumylact L and/or peroxidase.Enzyme can be adsorbed onto on the solid support material or be wrapped in and prevent their decomposition in the coated substance herein.
Can also comprise the chelating complexing agent of transition metal according to washing composition of the present invention, it can be used for preventing the catalytic decomposition of the reactive oxygen compounds in the washing lotion.For instance, phosphonic acid ester, hydroxyl ethane-1 for example, 1-bisphosphonates, WSI 3310 ester, diethylenetriamine five (methene phosphonate ester), ethylenediamine tetraacetic (methene phosphonate ester), hexanediamine four (methene phosphonate ester) and their an alkali metal salt are suitable.Nitrilotriacetic acid(NTA) and polyamino carboxylic acid, for example particularly ethylenediamine tetraacetic acid (EDTA), diethylene triaminepentaacetic acid(DTPA), quadrol-N, N '-disuccinic acid, methylglycine etheric acid and poly aspartic acid and their basic metal and ammonium salt also are suitable.At last, polycarboxylic acid is hydroxycarboxylic acid particularly, and for example particularly tartrate and citric acid also are suitable as the chelating complexing agent.
Also comprise the ashing inhibitor according to washing composition of the present invention, it makes dust break away from the fiber in the suspension and prevents that dust from adhering on the fiber again.Suitable ashing inhibitor for example has ether of cellulose such as carboxymethyl cellulose and an alkali metal salt thereof, methylcellulose gum, Natvosol and hydroxypropylcellulose.Polyvinylpyrrolidone also is fit to.
Can also comprise foamy froth suppressor in the minimizing washing lotion according to washing composition of the present invention.Suitable froth suppressor for example has organopolysiloxane such as polydimethylsiloxane, paraffin and/or wax, and the mixture of they and fine-particle silicon dioxide.
Can randomly comprise white dyes according to washing composition of the present invention, it adheres on the fiber, absorbs the light in the ultraviolet range and sends the flavescence that blue-fluorescence comes compensation fibre.Suitable white dyes for example has the derivative of diaminostilbene disulfonic acid, for example 4,4 '-two-(2-phenylamino-4-morpholine-1,3,5-triazinyl-6-amino) stilbene-2,2 '-the cinnamic an alkali metal salt of phenylbenzene of disulfonic acid or replacement, for example an alkali metal salt of 4,4 '-two-(2-sulfo group styryl) biphenyl.
Washing composition according to the present invention can also comprise dyestuff and spices at last except organopolysiloxane according to the present invention.
Liquid form or gel form can also randomly comprise the organic solvent of maximum 30 weight % according to washing composition of the present invention, for example methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, ethylene glycol, 1,2-propylene glycol, 1, ammediol, 1,4-butyleneglycol, glycerine, glycol ether, ethylene glycol monomethyl ether, thanomin, diethanolamine and/or trolamine.
Personal care product according to the present invention comprises at least a according to organopolysiloxane of the present invention, and is intended for use to nurse and/or clean people's skin and/or hair.In meaning of the present invention, the term personal care product particularly comprises soap, liquid soap, shower cream, cleaning and nourishing liquid, protective skin cream, shampoo, hair dye and sunscreen.
Can comprise personal care product's well known in the prior art all the components according to personal care product of the present invention, during wherein said personal care product does not preferably contain not and the acidic components of form.According to the organopolysiloxane of the present invention, for example can also comprise tensio-active agent, emulsifying agent, softener, fat and wax, pearlescent waxes, supe rfatting agent, membrane-forming agent, hydrotropic agent, viscosity modifier, rust-preventive agent, moistening agent, polysiloxane-based, antioxidant, ultravioletlight screening agent, anti-dandruff agent, deodorant activities material, biogenic active substance, dyestuff and perfume oil component as a supplement except at least a according to personal care product of the present invention.
Can comprise tensio-active agent according to personal care product of the present invention, if when especially they are intended for use cleaning skin and/or hair.Preferred herein the use has the very tensio-active agent of the gentleness of pinprick effect to skin.Can use negatively charged ion and nonionic, positively charged ion and/or amphoterics.
Be applicable to that the anion surfactant according to personal care product of the present invention has soap; alkylbenzene sulfonate; alkylsulfonate; ethylenic sulfonate; alkylether sulfonate; glycerol ether sulfonate; sulfonic acid α-methyl esters; sulfo-fatty acid; alkyl-sulphate; sulfated alkyl ether; glycerol ether sulfate; fatty acid ether sulfate; hydroxyl mixed ether vitriol; monoglyceride (ether) vitriol; fatty acid amide (ether) vitriol; list and dialkyl sulfosuccinate succinate; list and dialkyl sulfosuccinate Succinamate; the sulfo group glycerinate; acid amides soap; ether carboxylic acid and salt thereof; the lipid acid isethionate; the lipid acid sarcosinate; lipid acid taurate (taurides); the N-acylamino acid is for instance as acyl-lactate; acyl group tartaric acid salt; acyl glutamic acid and acylaspartic acid salt; alkyl oligoglycosides vitriol; protein fatty acid condensation product (the particularly plant prod of wheat-based) and alkyl (ether) phosphoric acid salt.
Be applicable to that the nonionogenic tenside according to personal care product of the present invention has fatty alcohol polyglycol ether, alkyl phenol polyoxyethylene glycol ether, fatty acid polyglycol ester, the fatty acid amide polyglycol ether, the aliphatic amide polyglycol ether, the alkoxylate tri-glyceride, the alkane of partial oxidation (alkene) oligoglycosides or glucuronic acid (glucoronic acid) derivative, lipid acid N-alkyl glucose amide, protein hydrolystate (the particularly plant prod of wheat-based), many alcohol fatty acid esters, sugar ester, sorbitan ester, polysorbate and amine oxide.
Be applicable to that the cats product according to personal care product of the present invention has quaternary ammonium compound, for example dimethyl distearyl ammonium chloride, tetrahydroglyoxaline (imidazolinium quats) and season ester, particularly seasonization lipid acid three alkanolamine ester salt.
Be applicable to that the amphoterics according to personal care product of the present invention has alkyl betaine, alkylamino trimethyl-glycine, aminopropionate, amino glycinate and sultaine.
Be applicable to that the tensio-active agent according to personal care product's of the present invention preferred gentleness has fatty alcohol polyglycol ether vitriol; monoglyceride vitriol; the monoalkyl sulfosuccinate; the dialkyl sulfosuccinate succinate; the lipid acid isethionate; the lipid acid sarcosinate; lipid acid taurate (taurides); the lipid acid glutaminate; alpha-alefinically sulfonate; the ether carboxylic acid; oligomeric alkyl glucoside; the lipid acid glucamide; alkylamino trimethyl-glycine and protein fatty acid condensation product.
Can comprise emulsifying agent according to personal care product of the present invention, use emulsifying agent to obtain O/W type or the stable emulsion of w/o type from water and water-insoluble composition.Term emulsion herein contains liquid preparation and creme and semi-solid state preparation.Negatively charged ion and nonionic, positively charged ion and/or amphoteric emulsifier may be used to according to personal care product of the present invention.
Be applicable to that the anionic emulsifier according to personal care product of the present invention has the aliphatic fatty acid with 12-22 carbon atom, for example palmitinic acid, stearic acid or docosoic and di-carboxylic acid, for example nonane diacid or sebacic acid with 12-22 carbon atom.
Be applicable to the alkoxylated polymerization product that straight-chain fatty alcohol, the lipid acid with 12-22 carbon atom with 8-22 carbon atom, the alkylphenol with 14-21 carbon atom, the alkylamine with 8-22 carbon atom and Viscotrol C and/or hydrogenated castor oil are arranged according to personal care product's of the present invention nonionic emulsifying agent; The alkoxylated polymerization product that preferably comprises 2-30mol oxyethane and/or 1-5mol propylene oxide.The oligomeric glycosides of alkyl that has 8-18 carbon atom in the alkyl group; Partial glyceride, for example oxystearic acid monoglyceride, oxystearic acid diacylglycerol fat, the Unimac 5680 monoglyceride, Unimac 5680 diacylglycerol fat, the oleic acid monoglyceride, oleic acid diacylglycerol fat, the ricinolic acid monoglyceride, ricinolic acid diacylglycerol fat, the linolic acid monoglyceride, linolic acid diacylglycerol fat, the linolenic acid monoglyceride, linolenic acid diacylglycerol fat, the sinapinic acid monoglyceride, sinapinic acid diacylglycerol fat, the tartrate monoglyceride, tartrate diacylglycerol fat, the citric acid monoglyceride, citric acid diacylglycerol fat, oxysuccinic acid monoglyceride or oxysuccinic acid diacylglycerol fat; Sorbitan ester, for example sorbitanic list isostearate, sorbitanic sesquialter isostearate, the sorbitanic diisopstearate, sorbitanic three isostearates, the sorbitanic monoleate, the sorbitanic sesquioleate, the sorbitanic dioleate, the sorbitanic trioleate, sorbitanic list eruciate, sorbitanic sesquialter eruciate, sorbitanic two eruciate, sorbitanic three eruciate, sorbitanic list ricinoleate ester, sorbitanic sesquialter ricinoleate ester, sorbitanic two ricinoleate esters, sorbitanic three ricinoleate esters, sorbitanic monohydroxy stearate, sorbitanic sesquialter hydroxy stearic acid ester, sorbitanic dihydroxystearic acid ester, sorbitanic trihydroxy-stearate, sorbitanic list tartrate, sorbitanic sesquialter tartrate, sorbitanic two tartrates, sorbitanic three tartrates, sorbitanic list citrate, sorbitanic sesquialter citrate, sorbitanic two citrates, sorbitanic three citrates, sorbitanic list maleic acid ester, sorbitanic sesquialter maleic acid ester, sorbitanic dimaleate or sorbitanic three maleic acid esters; And the ethoxylated product of these compounds and 2-30mol oxyethane.Suitable nonionic emulsifying agent also has polyglycerol ester, for example Polyglycerine-2-two multi-hydroxy stearic acid esters (Dehymuls PGPH), Polyglycerine-3 diisopstearate (Lameform TGI), Polyglycerine-4 diisopstearate (Isolan GI 34), Polyglycerine-3 oleic acid ester, two isostearoyl Polyglycerine-3 diisopstearates (Isolan PDI), Polyglycerine-3 methyl glucoside SUNSOFT Q-182S (Tego Care 450), Polyglycerine-3 beeswax (Cera bellina), Polyglycerine-4 decylate (Polyglycerine decylate T2010/90), Polyglycerine-3 cetyl ether (Chimexane NL), Polyglycerine-3 SUNSOFT Q-182S (Cremophor GS32) and Polyglycerine poly ricinoleate ester (Admul WOL 1403).
Be applicable to that the cationic emulsifier according to personal care product of the present invention has season fatty amines ester, it uses alkylating reagent (preferably sulfuric acid dimethyl ester or oxyethane) seasonization to obtain by alkanolamine (preferred trolamine or methyldiethanolamine) and fatty acid esterification subsequently.The preferred use preferably obtains from plant or animal oil or fat, and the natural origin fatty acid mixt that mainly comprises C16 and C18 lipid acid is as described lipid acid, and wherein said fatty acid mixt can or use under the hydrogenation fully at natural degree of unsaturation, partial hydrogenation.The preferred fatty acid mixt of iodine number in the 5-50 scope that use.Preferred especially average esterification degree is at the season of every mole of triethanolamine 1.5-2.0 mole fatty acid triethanol amine.
Be applicable to that the amphoteric emulsifier according to personal care product of the present invention has trimethyl-glycine; glycine N-alkyl-N for example; N-dimethylammonium, glycine N-amido propyl group-N; N-dimethylammonium and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazole quinoline; every kind has 8-18 carbon atom in alkyl or acyl group, preferably the CTFA name is called the compound of AMONYL 380LC.Every kind of N-alkyl glycine, N-alkyl propionic acid, N-alkylamino butyric acid, N-alkylamino dipropionic acid, N-hydroxyethyl-N-alkylamide propyl glycine, N-alkyl taurine, N-alkyl sarkosine, 2-alkylamino propionic acid and alkylamino acetate that has about 8-18 carbon atom in alkyl also is suitable.
Can comprise softener according to personal care product of the present invention, softener can dissolve water-insoluble activeconstituents, and self or determined personal care product's organoleptic property with emulsifier combination.In meaning of the present invention, softener is a liquid under 20 ℃, and at 25 ℃ of following and the immiscible material of water or substance mixture.
Suitable softener has based on having 6-18, Guerbet alcohol (for example Eutanol G), the straight chain C of the Fatty Alcohol(C12-C14 and C12-C18) of preferred 8-10 carbon atom 6-C 22Lipid acid and straight or branched C 6-C 22The ester of Fatty Alcohol(C12-C14 and C12-C18), and side chain C 6-C 13Carboxylic acid and straight or branched C 6-C 22The ester of Fatty Alcohol(C12-C14 and C12-C18) is for instance as Tetradecyl tetradecanoate, the palmitinic acid myristin, the stearic acid myristin, the Unimac 5680 myristin, the oleic acid myristin, mountain Yu acid myristin, the erucic acid myristin, cetyl myristate, the hexadecanol cetylate, hexadecyl stearate, the hexadecyl isostearate, the hexadecyl oleic acid ester, the hexadecyl behenate, the hexadecyl eruciate, the stearyl myristinate, the stearyl cetylate, the stearyl stearate, the stearyl isostearate, the stearyl oleic acid ester, stearyl docosane acid esters, the stearyl eruciate, the isostearoyl myristinate, the isostearoyl cetylate, the isostearoyl stearate, the isostearoyl isostearate, the isostearoyl oleic acid ester, isostearoyl docosane acid esters, the isostearoyl oleic acid ester, the oleyl myristinate, the oleyl cetylate, the oleyl stearate, the oleyl isostearate, the oleyl oleic acid ester, oleyl docosane acid esters, the oleyl eruciate, the docosyl myristinate, the docosyl cetylate, the docosyl stearate, the docosyl isostearate, the docosyl oleic acid ester, docosyl docosane acid esters, the docosyl eruciate, the erucyl myristinate, the erucyl cetylate, the erucyl stearate, the erucyl isostearate, the erucyl oleic acid ester, erucyl docosane acid esters and erucyl eruciate; C 3-C 38Alkyl hydroxy carboxylic acid and straight or branched C 6-C 22The ester of Fatty Alcohol(C12-C14 and C12-C18), for example diethylhexyl malate; And the ester of straight or branched lipid acid and polyvalent alcohol, for example propylene glycol, dipropylene glycol or tripropylene glycol.Suitable also has based on C 6-C 10The tri-glyceride of lipid acid; Based on C 6-C 18Liquid single acid, diacid and the triglyceride mixture of lipid acid; C 6-C 22The for example benzoic ester of Fatty Alcohol(C12-C14 and C12-C18) or Guerbet alcohol and aromatic carboxylic acid; C 2-C 12Dicarboxylic acid is pure or have an ester of the polyvalent alcohol of 2-10 carbon atom and 2-6 hydroxyl with the straight or branched with 1-22 carbon atom; Vegetables oil, branched-chain primary alcohol, straight or branched C 6-C 22Fatty Alcohol(C12-C14 and C12-C18) carbonic ether, for example carbonic acid two decoyl esters (Cetiol CC); Based on having 6-18, the Guerbet carbonic ether of the Fatty Alcohol(C12-C14 and C12-C18) of preferred 8-10 carbon atom; The C of phenylformic acid and straight or branched 6-C 22The ester of alcohol, for example Finsolv TN; Each alkyl has straight or branched, symmetrical or asymmetric dialkyl ether, for example two decoyl ethers (Cetiol OE) of 6-22 carbon atom; The open-loop products of epoxidized fatty acid ester and polyvalent alcohol, for example HydagenHSP, Sovermol 750, Sovermol 1102; And aliphatic hydrocarbon, for example mineral oil, Vaseline, vaseline, squalane, squalene or dialkyl cyclic hexane.
Can comprise fat and wax according to personal care product of the present invention, use them can regulate emulsus particularly or semi-solid personal care product's organoleptic property.Suitable wax is natural wax, for example gama wax, carnauba wax, Japan tallow, alfa wax, cork wax, guaruma wax, rice germ oil wax, sugar-cane wax, ouricury wax, montanin wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), the fat of tail fat, pure white ceresine, ceresine (ceresine), vaseline and paraffin; Chemical modification, hydrogenant wax, for example brown coal ester type waxes, sasol wax and hydrogenant jojoba wax; And synthetic paraffin, for example polyalkylene wax and polyethylene glycol wax.Basically the animal or plant fat of being made up of the mixed glyceride of higher fatty acid also is suitable as fat.Can also use phosphatide, Yelkin TTS, sphingosine and sphingolipid as fat.
Can also comprise pearlescent waxes according to personal care product of the present invention, it gives nacreous attracting outward appearance to the personal care product.Suitable pearlescent waxes has alkylene glycol ester, for example Unister E 275; Fatty acid alkyl amide, for example coconut fatty acid diglycollic amide; Partial glyceride, for example glyceryl monostearate; The polycarboxylic acid and the ester with Fatty Alcohol(C12-C14 and C12-C18) of 6-22 carbon atom, particularly tartaric long-chain ester that can replace with hydroxyl; The Fatty Alcohol(C12-C14 and C12-C18), fatty alcohol-ether and Fatty Alcohol(C12-C14 and C12-C18) carbonic ether, for example distearyl ether that comprise at least 24 carbon atoms altogether; Lipid acid, for example stearic acid, oxystearic acid or behenic acid; Alkene oxide with 12-22 carbon atom with have the Fatty Alcohol(C12-C14 and C12-C18) of 12-22 carbon atom or have the open-loop products of the Fatty Alcohol(C12-C14 and C12-C18) of 2-15 carbon atom and 2-10 carbonyl.
Can also comprise supe rfatting agent according to personal care product of the present invention, for example the ethoxylate of lanolin or Yelkin TTS or these compounds, polyhydric alcohol fatty acid ester, monoglyceride or fatty acid alkyl amide.
Can also comprise membrane-forming agent according to personal care product of the present invention, use them that activeconstituents is fixed on skin or the hair.Suitable membrane-forming agent has chitosan, the season chitosan, Polyvinylpyrolidone (PVP), vinylpyrrolidone/vinyl acetate copolymer of chitosan, crystallite, based on the polymkeric substance of vinylformic acid and methacrylic acid, season Mierocrystalline cellulose, collagen, hyaluronic acid and their salt.
Can also comprise hydrotropic agent according to personal care product of the present invention, for example ethanol, Virahol or the polyvalent alcohol matter that improves liquidity.It is suitable especially having 2-15 carbon atom and at least two hydroxyls and can randomly comprising other functional group, particularly An Ji polyvalent alcohol.These examples of polyhydric alcohols have glycerine; Alkylene glycol, for example ethylene glycol, glycol ether, propylene glycol, butyleneglycol, pentanediol, hexylene glycol and molecular-weight average are the polyoxyethylene glycol of 100-1000g/mol; Condensation degree is the oligomeric glycerol mixture of 1.5-10, and for example diglycerol content is the technical grade diglycerol mixture of 40-50 weight %; Methylol compound, for example trimethylolethane, TriMethylolPropane(TMP), tri hydroxy methyl butane, tetramethylolmethane and Dipentaerythritol; The short-chain alkyl glucosides that has 1-8 carbon atom in the alkyl group, for example methyl and butyl glycoside; Sugar alcohol with 5-12 carbon atom, for example Sorbitol Powder or mannitol; Sugar with 5-12 carbon atom, for example glucose or sucrose; Aminosugar is glycosamine for example; And the dioxane hydramine, for example diethanolamine or 2-amino-1, ammediol.
Viscosity modifier be can also comprise according to personal care product of the present invention and the viscosity of product and thickening product randomly improved.Suitable viscosity modifier is natural water gel formation thing, for example xanthan gum, guar gum, agar-agar, alginate and methylcellulose gum; The polyose of modification, for example ether of cellulose and cellulose ester, for example carboxymethyl cellulose, methylcellulose gum, Natvosol, methyl hydroxyethylcellulose and methylhydroxypropylcellulose; Inorganic hydrocolloid, for example wilkinite, magnesium-aluminosilicate and silicon-dioxide; The synthetic hydrocolloid, for example polyacrylate(s) (can be used as Carbopols and Pemulen level is purchased, is purchased, is purchased, is purchased and is purchased from Allied Colloids as the Salcare level from Seppic as the Sepigel level from Kelco as the Keltrol level from Sigma as Synthalens from Goodrich) is purchased, uncrosslinked and polyacrylic acid polyol crosslink, polyacrylamide, polyvinyl alcohol and Polyvinylpyrolidone (PVP); Ionogen, for example salt and ammonium chloride; And it is anionic, zwitterionic, amphoteric and non-ionic multipolymer, for example vinyl-acetic ester/Ba Dousuan multipolymer, vinyl pyrrolidone/vinylacrylic acid ester copolymer, vinyl-acetic ester/butyl maleic acid ester/iso-bornyl acrylate multipolymer, vinyl methylether/maleic anhydride copolymers and their ester, acrylamide propyl trimethylammonium chloride/acrylate copolymer, octyl acrylamide/methyl methacrylate/methacrylic acid tertiary butyl aminoethyl ester/hydroxypropyl methacrylate multipolymer, vinyl pyrrolidone/vinyl acetate copolymer and vinyl pyrrolidone/dimethylaminoethyl acrylate methyl base aminoethyl ester/caprolactam terpolymer.Other suitable thickening material is listed in Cosm.Toil.108, in 95 (1993).
Can also comprise sanitas according to personal care product of the present invention, its prevent personal care product's composition at lay up period by Bacteria destroyed.Suitable preservatives has Phenoxyethanol, formaldehyde solution, p-hydroxybenzoic acid, pentanediol or Sorbic Acid and is called the silver complex of Surfacine TM.A and B part is as can be known from the appendix 6 of German makeup regulations for other suitable preservatives.
Can also comprise moistening agent according to personal care product of the present invention, moistening agent is regulated the humidity of handling skin, and can improve personal care product's organoleptic property.Suitable moistening agent has split product, chitosan or the chitosan salt/derivative of natural amino acid, pyrrolidone carboxylic acid, lactic acid and their salt, Saccharum lactis, urea and urea derivative, uric acid, glycosamine, creatinine, collagen.Suitable also have polyvalent alcohol and polyol derivative, for example glycerine, diglycerol, two triglycerols (triglycerol), ethylene glycol, propylene glycol, butyleneglycol, pentanediol, tetrahydroxybutane and 1,2,6-hexanetriol; Polyoxyethylene glycol, for example PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20, sugar and sugar derivatives, for example fructose, glucose, maltose, maltose alcohol, mannitol, inositol, sorbyl alcohol, sucrose, trehalose, wood sugar, Xylitol and glucuronic acid and their salt; And the sorbyl alcohol of ethoxylation, for example Sobeth-6, Sorbeth-20, Sorbeth-30 and Sorbeth-40.The suitable mixture that also has honey and hydrogenant honey, hydrogenant starch hydrolysate and hydrogenation wheat protein and PEG-20 acetate copolymer.Preferred glycerine, diglycerol, two triglycerols or the butyleneglycol of using is as moistening agent.
Can also comprise according to personal care product of the present invention and to have the polysiloxane-based of following structure type: SILIBIONE OIL 70047 V20 (cyclomethicones), dimethicone, dimethyl polysiloxane, methyl phenyl silicone, cyclic polysiloxanes and amino-, lipid acid-, alcohol-, polyethers-, epoxy-, fluoro-, glycosides-and the polysiloxane compounds of alkyl-modification.Suitable also have dimethyl silicone oil, and it is that mean chain length is the mixture of dimethicone of the dimethyl siloxane units of 200-300, and silicon-dioxide or hydrogenated silicate.
Can also comprise antioxidant according to personal care product of the present invention, it can interrupt the photochemical reaction chain that triggers when ultraviolet transdermal.Suitable antioxidant has amino acid, for example glycine, Histidine, tyrosine and tryptophane and their derivative; Peptide, D for example, L-carnosine, D-carnosine, L-carnosine and their derivative, for example anserine; Carotenoid and carotene, for example alpha-carotene, β-Hu Luobusu and Lyeopene and their derivative; Chlorogenic acid and derivative thereof; Thioctic Acid and derivative thereof, for example Thioctic acid, dihydro-; Gold thioglucose, propylthiouracil and other mercaptan, for example sulphur hydrogen reduction albumen, gsh, halfcystine, Guang nitronic acid and cystamine and their glycosyl, N-ethanoyl, methyl, ethyl, propyl group, amyl group, butyl, lauryl, palmitoyl, oleyl, gamma-linoleic acid base, cholesteryl and glyceryl ester and and their salt; Tyox B, distearyl thiodipropionate and thio-2 acid and their ester, ether, peptide, lipoid, Nucleotide, nucleosides and salt; The sulfo group group with imine moiety, for example thionine sulfo group imines, homocysteine sulfo group imines, thionine sulfone and five-, six-and seven thionine sulfo group imines; Metallo-chelate, for example alpha-hydroxy fatty acid, palmitinic acid, phytic acid, lactoferrin, alpha-hydroxy acid, particularly citric acid, lactic acid and oxysuccinic acid, humic acid, bile acide, bile extracting solution, bilirubin, uteroverdine, EDTA and EGTA; Unsaturated fatty acids and their derivative, for example gamma-linolenic acid, linoleic plus oleic acid; Folic acid and derivative thereof; Ubiquinone and ubiquinol (ubiquinol) and their derivative; Xitix and derivative thereof, for example anti-bad blood acyl palmitate, ascorbigen trimagnesium phosphate and xitix yl acetate; Tocopherol and derivative thereof, for example vitamin E acetate; And vitamin A and derivative thereof, for example Vitamin A Palmitate 1.7 M.I.U/Gram.Terebinic acid and derivative thereof, alpha-glycosyl rutin, forulic acid, furfurylidene sorbitol, carnosine, butylhydroxy toluene, butyl hydroxyanisole, remove first dihydroguaiaretic acid resinous acid (nordihydroguaiac resin acid), nordihydroguaiaretic acid, THBP 2,4,5 trihydroxybutyrophenone, uric acid and their derivative, seminose and derivative thereof, superoxide dismutase, zinc and its derivative, for example zinc oxide, selenium and its derivative, for example selenomethionine and stilbene and its derivative, for example the stilbene oxide compound also is suitable as antioxidant.
Can also comprise ultraviolet screening agent according to personal care product of the present invention, it absorbs UV-A ray and/or UV-B ray.Organic substance and mineral dye can be used as ultraviolet screening agent, and wherein organic substance can be oil-soluble or water miscible and insoluble.Suitable oil soluble UV-B photomask agent has 3-benzylidene camphor and 3-benzylidene Norcamphor and derivative thereof, for example known 3-(4-methyl benzylidene) camphor from EP-A 0 693 471; The 4-aminobenzoic acid derivative, preferred 4-(dimethylamino) phenylformic acid-2-ethylhexyl, 4-(dimethylamino) phenylformic acid-2-monooctyl ester and 4-(dimethylamino) amyl benzoate; Laurate, preferred 4-methoxy cinnamic acid-2-ethylhexyl, 4-methoxy cinnamic acid propyl ester, 4-methoxy cinnamic acid isopentyl ester and 2-cyano group-3,3-phenyl-cinnamic acid-2-ethylhexyl (Octocrylene), salicylate, preferred Whitfield's ointment-2-ethylhexyl, Whitfield's ointment-4-sec.-propyl benzyl ester and Uniderm Homsal; Benzophenone derivates, preferred 2-hydroxyl-4-methoxy benzophenone, 2-hydroxyl-4-methoxyl group-4 '-methyldiphenyl ketone and 2,2 '-dihydroxyl-4-methoxy benzophenone; The ester of Ben Yajiaji propanedioic acid (benzalmalonic acid), preferred 4-anisole methylene radical propanedioic acid two-2-ethylhexyl; Pyrrolotriazine derivatives, for example known 2,4 from EP-A 0 818 450,6-triphen amido-(right-carbon-2 '-ethyl-1 '-hexyloxy)-1,3,5-triazines, UVINUL T-150 and dioctyl butyramide triazone (Uvasorb HEB); Propane-1,3-diketone, 1-(4-tert-butyl-phenyl)-3-(4 '-p-methoxy-phenyl) propane-1 for example, 3-diketone; And known ketone three encircles (5.2.1.0) decane derivatives from EP-A 0 694 521.Suitable water-soluble UV-B photomask agent has 2-Phenylbenzimidazole-5-sulfonic acid and their basic metal, alkaline-earth metal, ammonium, alkylammonium, alkanol ammonium and sugared ammonium salt; The sulfonic acid of benzophenone, preferred 2-hydroxyl-4-methoxy benzophenone-5-sulfonic acid and salt thereof; And the sulfonic acid of 3-benzylidene camphor, for example 4-(the bornenyl methyl of 2-oxygen-3-) Phenylsulfonic acid and 2-methyl-5-(2-oxygen-3-is bornenyl) sulfonic acid and salt thereof.The derivative of benzoyl methane; 1-(4 '-tert-butyl-phenyl)-3-(4 '-p-methoxy-phenyl) propane-1 for example; 3-diketone, the 4-tertiary butyl-4 '-methoxy dibenzoyl methylmethane (Parsol 1789) and 1-phenyl-3-(4 '-isopropyl phenyl) propane-1, the 3-diketone and from DE 191 12 033 known enamine compound all be suitable as the organic UV-A photomask agent.UV-A and UV-B photomask agent also can use with mixture naturally.Preferred combination comprises the derivative of benzoyl methane; for example the 4-tertiary butyl-4 '-methoxy dibenzoyl methylmethane and 2-cyano group-3, the combination of 3-phenyl-cinnamic acid-2-ethylhexyl and laurate (for example 4-methoxy cinnamic acid-2-ethylhexyl, 4-methoxy cinnamic acid propyl ester or 4-methoxy cinnamic acid isopentyl ester).These make up advantageously combination water dissolubility filtering agent, for example 2-Phenylbenzimidazole-5-sulfonic acid and their basic metal, alkaline-earth metal, ammonium, alkylammonium, alkanol ammonium and sugared ammonium salt.The suitable inorganic delustering pigment that covers has finely divided metal oxide powder, the form that they are preferably hydrophobic, particularly titania powder, alumina powder, Zinc oxide powder and have the mixed oxide powder of elements Si, Ti, Al, Zn, Fe, B, Zr and/or Ce.Preferred so-called micron pigment or the nano dye of using, its particle median size be less than 100nm, preferably between 5 and 50nm between, and particularly between 15 and 30nm between.They can be spherical, but these particles also can have elliptical form or other departs from the spheric form.The example of commercially available inorganic smooth stable pigments has titanium dioxide UV-titanium M212, M 262 and the X 111 available from the coating of Kemira; AEROXIDE TiO available from Degussa 2P25, PF2, T 805 and T817; Micron order titanium dioxide MT-150 W, MT-100 AQ, MT-100SA, MT-100 HD and MT-100 TV available from Tayca; Eusolex T2000 available from Merck; Available from Haarmann ﹠amp; The neutral H﹠amp of the zinc oxide of Reimer; R and zinc oxide NDM; And available from Z-Cote and the Z-Cote HP1 of BASF.Other suitable ultravioletlight screening agent from P.Finkel at S  FW-Journal 122,543 (1996) and Parf.Kosm.3, known in 11 (1999) the summary.
The personal care product who is used for hair treatment according to the present invention also comprises the anti-dandruff agent.Suitable anti-dandruff agent has 1-hydroxy-4-methyl-6-(2,4,4-tri-methyl-amyl)-combination of 2-(1H)-pyridine alkane ketone monoethanolamine, Crinipan AD, KETOKONAZOL, elubiol, Selenium Sulfide, sulfoid, sulphur polyoxyethylene glycol sorbitol monooleate, sulphur castor-oil plant alcohol (ricinol) polyethoxylated, sulphur tar cuts, Whitfield's ointment and Hexachlorophene, undecylenic acid monoethanolamine sulfosuccinate sodium, protein undecylenic acid condenses, 2-Mercaptopyridine-N-oxide zinc, 2-Mercaptopyridine-N-oxide aluminium and 2-Mercaptopyridine-N-oxide magnesium.
Can also comprise reodorant according to personal care product of the present invention.Suitable reodorant has astringent metallic salts, fungistat, enzyme inhibitors and the deodorant agent with antiperspirant effect, and they can be used alone or in combination.The suitable astringent metallic salts with antiperspirant effect has chlorine aluminium hydroxide, chlorine aluminium hydroxide zirconium, hydroxyl Aluctyl and zinc salt.Suitable commerical prod is available from the Locron of Clariant with available from the Rezal 36G of Reheis.All have the active material of anti-leather orchid-positive bacteria and all are suitable as fungistat in principle, for example 4-hydroxy-benzoic acid and salt thereof and ester, N-(4-chloro-phenyl-)-N '-(3, the 4-dichlorophenyl) urea, 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether (triclosan), 4-chloro-3, the 5-xylenol, 2,2 '-methylene radical two-(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl) phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1, the 2-propylene glycol, 3-iodo-2-propynyl butyl carbamate, chlorhexidine, 3,4,4 '-trichlorine diphenylurea (TTC), thymol, thyme oil, oxymethoxyallylbenzene, Syzygium aromaticum stem oil, menthol, spearmint oil, farnesol, Phenoxyethanol, glycerine list capric acid grease (caprinate), Monooctamoin, glyceryl monolaurate (GML), diglycerol list capric acid grease (monocaprinate) (DMC), and Whitfield's ointment-N-alkylamide, for example Whitfield's ointment-n-octyl acid amides or Whitfield's ointment-positive decyl acid amides.Suitable enzyme inhibitors is an esterase inhibitor, preferred trialkyl citrate, for example trimethyl citrate, citric acid three propyl ester, citric acid three isopropyl esters, tributyl citrate, and triethyl citrate particularly; Sterols sulfuric ester and sterols phosphoric acid ester, for example lanosterol, cholesterol, campesterol, Stigmasterol and Sitosterol sulfuric ester or phosphoric acid ester; Dicarboxylic acid and their ester, for example pentanedioic acid, pentanedioic acid monoethyl ester, ethyl glutarate, hexanodioic acid, hexanodioic acid monoethyl ester, diethylene adipate, propanedioic acid and diethyl malonate; And the ester of hydroxycarboxylic acid and they for example citric acid, oxysuccinic acid, tartrate or diethyl tartrate.Be suitable as deodorant agent by the material that the dividing potential drop that reduces independent component can absorb and maintenance produces the compound of smell basically.As their main ingredient, for example they comprise ricinoleic acid the network zinc salt or special, be mainly smell-neutral spices, they are known as " fixative " for those skilled in the art, for example the extracting solution of labdanum, Styrox or some rosin acid derivative.
Can also comprise biogenic active substance according to personal care product of the present invention, for example tocopherol, VITAMIN E ACETATE, tocopherol cetylate, xitix, (deoxidation) Yeast Nucleic Acid and their cracked product, beta-glucan, Vogan-Neu, Hydagen B, wallantoin, Phytantriol, panthenol, pantothenic acid, fruit acid, alpha-hydroxy acid, amino acid, N-fatty acyl group sphingosine, false N-fatty acyl group sphingosine, volatile oil and VITAMIN mixture.Can also use plant extraction liquid, the most important thing is that the extracting solution of arnica oil, birch, Phytoconcentrol Chamomile, Root of Great Burdock, born lichens, white poplar, small British nettle, Prunus species, Ban Balei xylocarp and walnut shell can be used as biogenic active substance.
Also comprise dyestuff according to personal care product of the present invention, soluble dye and soluble pigment all are suitable.Suitable soluble dye is the plant and animal dyestuff, for example betanin, bixin, carmetta, carotene, chlorophyll or sepia pigment, and the synthetic organic dye, for example preferably water miscible or in water dispersible azo, anthraquinone or triphenylmethane dye.Suitable insoluble pigment has natural inorganic pigment for example ochre, umber, reddle, loess or chalk, and the synthetic mineral dye is ferric oxide, blue lake, titanium dioxide, zinc oxide or mica-based pigment, particularly pearly pigment for example.
At last, can also comprise spice oil, give attracting smell to the personal care product according to personal care product of the present invention.Used spice oil is the mixture of fragrance matter traditionally, wherein can use natural and the synthetic fragrance matter.Suitable natural flavor material has extracting solution and resin and the face cream of flower, stem and leaf, fruit, pericarp, root, timber, vanilla and grass, needle and sprig.Suitable animal fragrance matter has for example civet and castoreum.Typical synthetic fragrance matter compound has the product of ester, ether, aldehyde, ketone, alcohol or hydrocarbon types.The fragrance matter of ester type for example has jasmal, to tert.-butylacetic acid cyclohexyl ester, phanteine, Phenylethyl ethanoate, linalyl benzoate, benzyl formate, propionic acid allyl group cyclohexyl ester, propionic acid vinylbenzene third (styrallyl) ester and benzyl salicylate.Ethers for example comprises benzyl ethyl ether, aldehydes comprises straight chain alkanal, citral, geranial, lemongrass oxygen base (citronellyloxy) acetaldehyde, Xian Kelaiquan, laurine, Ling Lanquan and the clean big vast aldehyde of ripple that for example has 8-18 carbon atom, ketone comprises for example jononeionone and methyl cdear alcohol ketone, alcohols comprises methyl allylphenol, geraniol, oxymethoxyallylbenzene, isoeugenol, Geraniol, Linaool, phenylethyl alcohol and terpinol, and hydro carbons mainly comprises terpenes and face cream.The preferred mixture of various fragrance matters that uses produces attracting fragrance together.The main lower volatile oil of volatility as aromatised fraction also is suitable as spice oil, for example sage oil, chamomile oil, Syzygium aromaticum stem oil, melissa oil, spearmint oil, Cortex Cinnamomi leaf oil, lime-caul-fat, juniper oil, vetiver oil, olibanum oil, galbanum oil, ladanum oil and lavandin oil.Preferably use Oils, bergamot peel separately or with mixture, dihydromyrcenol, Ling Lanquan, LYRAL, geraniol, phenylethyl alcohol, α-basic phenylacrolein, Geraniol, benzyl acetone, Xian Kelaiquan, Linaool, boisambrene forte, ambrane, indoles, methyl dihydrojasmonate, sandelice, lemon oil, mandarin oil, orange oil, Allyl amyl glycolate, cyclovertal, lavandin oil, Salvia Sclare L.oil, β-damascone, geranium oil Bourbon, the Whitfield's ointment cyclohexyl, vertofix coeur top grade (Vertofix Coeur), ambrotone (Iso-E-Super), Fixolide NP, the atractylic acid methyl esters, iraldein gamma, toluylic acid, meraneine, jasmal, the rose oxide compound, romilat, irotyl and floramat.
The preferred embodiment of fabric-treating agent according to the present invention is the fragrant fabric purificant.Fragrant fabric purificant in the meaning of the present invention is to comprise liquid preparation according to organopolysiloxane of the present invention with the aqueous dispersions form, and when being used for the water of rinsing in the rinse step of carrying out after the fragrant fabric purificant is added in the Actual laundering step, organopolysiloxane wherein according to the present invention adheres on the fabric fibre during cleaning fabric in containing water lotion.
The fragrant fabric purificant that comprises according to organopolysiloxane of the present invention with liquid form also preferably comprises at least a emulsifying agent, and itself and liquid organopolysiloxane form stable O/W emulsion.Negatively charged ion, nonionic and amphoteric emulsifier that the front is described as personal care product's possibility composition according to the present invention all are suitable as the emulsifying agent that fragrant fabric purificant according to the present invention is used.
Also preferably comprise buffer composition according to fragrant fabric purificant of the present invention, use it can make the pH of fragrant fabric purificant remain on pH5-9, in the scope of preferred pH6-8.
Fragrant fabric purificant according to the present invention can also comprise other component for example hydrotropic agent, viscosity modifier, sanitas, polysiloxane and spice oil, and wherein the front is all suitable as the compound of personal care product's possibility composition according to the present invention description.In addition, fragrant fabric purificant according to the present invention can also comprise ashing inhibitor, froth suppressor, white dyes and dyestuff, they be applicable to all that the front described according to washing composition of the present invention.
Embodiment
Embodiment 1
The preparation of Mono Chloro Acetic Acid lemongrass alcohol ester
With 3 of 94.5g (1.0mol) Monochloro Acetic Acid and 203.2g (1.4mol), 7-dimethyl-6-octen-1-ol (geraniol) heats 6h to 130 ℃ under 50mbar, wherein boils off the water that esterification forms by distillation tower.The acid number of gained reaction mixture is 5mg KOH/g.Then, boil off unreacted geraniol under 6mabr, bottom temp reaches 130 ℃.Distillation leftover under the 6mabr obtains 198g Mono Chloro Acetic Acid lemongrass alcohol ester colourless liquid.
Embodiment 2
Preparation with organopolysiloxane of following structure:
R 6-O-[Si(CH 3) 2-O] n-R 6
N=10 wherein, R 6=-CH 2-CH 2-N +(CH 3) 2-CH 2-C (O) OYCl -And YOH=geraniol.
With 346g (0.4mol) molecular-weight average is the α of 865g/mol, 11h to 60 ℃ of ω-two (2-dimethylamino ethoxy) poly-(dimethyl siloxane) and the heating of 163g (0.7mol) Mono Chloro Acetic Acid lemongrass alcohol ester.Free muriatic content is 4.43 weight % in the products therefrom, and the chloride content of organic bonding is 0.05 weight %, and the transformation efficiency that obtains betaine ester is 99%.
Embodiment 3
Preparation with organopolysiloxane of following structure:
R 6-O-[Si(CH 3) 2-O] n-R 6
N=50 wherein, R 6=-CH 2-CH 2-N +(CH 3) 2-CH 2-C (O) OYCl -And YOH=geraniol.
With 308.5g (0.08mol) molecular-weight average is the α of 3856g/mol, 56h to 60 ℃ of ω-two (2-dimethylamino ethoxy) poly-(dimethyl siloxane) and the heating of 32.6g (0.14mol) Mono Chloro Acetic Acid lemongrass alcohol ester.Free muriatic content is 2.29 weight % in the products therefrom, and the chloride content of organic bonding is 0.04 weight %, and the transformation efficiency that obtains betaine ester is 98%.
Embodiment 4
From the aqueous dispersions of the organopolysiloxane of embodiment 3, discharge the pH-dependency of geraniol
In the pH value is to measure the release of geraniol from organopolysiloxane in 3,6 and 9 the commercially available damping fluid under room temperature.Organopolysiloxane and 0.5g emulsifying agent Rewopal C6 (coconut monoethanol amide polyglycol ether) with 0.5g embodiment 3 fills to 50ml with damping fluid, and emulsification is 1 minute in ultra sonic bath, and at room temperature stores formed stable emulsion.At the appointed time, take a sample, extract, and determine the ratio of the geraniol of release with gas-chromatography with toluene.Table 1 has been represented the geraniol and the relation of time and pH of buffer that discharge, the value in every kind of situation be twice experiment on average.
Measuring result shows and discharges about 9% geraniol by ultra-sonic dispersion.Then, it is about 2% that the amount of the geraniol that discharges in 24 hours under pH6 and pH9 has only increased, and in other words this trimethyl-glycine is stable.Compare, under pH3, in 24 hours, discharge about 42% geraniol again.
The amount of the geraniol that table 1 discharges
Storage period (h) pH3 pH6 pH9
0.25 10.3 9.4 8.8
2 9.8 8.7
2.5 17.3
24 52.0 11.1 10.8
36 62.0 11.4
Embodiment 5
The organopolysiloxane of embodiment 3 is used for the fragrant fabric purificant, and this organopolysiloxane is attached on the fabric fibre, and discharges geraniol by the effect of acid.
Stir organopolysiloxane and the 5.0g Rewopal LA6 (having 6 unitary lauryl alcohol ethoxylates of EO) of 20g embodiment 3 by damping fluid with 75g pH7.Obtain 100g fragrant fabric purificant emulsion.
In the family expenses washing machine, go the odor type washing composition to wash 3.5kg cotton T-shirt down at 40 ℃ with WFT alkalescence.Washing composition by washing machine adds inlet and add fragrant fabric rinsing emulsion in last rinse cycle.Dry the T-shirt of washing and be placed on rope and go up air drying at least 4 days until no longer detecting fragrance.When spraying T-shirt with the citric acid solution of 1 weight % subsequently, produce dense geraniol fragrance.Even after the exsiccant place is deposited around the T-shirt, after with the citric acid solution spraying, still can be measured to dense geraniol fragrance.
Embodiment 6
The organopolysiloxane of embodiment 3 is used for fragrant fabric purificant and the organopolysiloxane ramollescence to fabric fibre.
To be of a size of 80 * 50cm and weight is 350g/m 23kg Frottana cotton towel with 75g available from the IEC-A alkalis washed twice of WKF-Testgewebe, and in MieleMondia 1120 automatic washing machines in 95 ℃ without twice of detergent washing and at 1200min -1The following drying.With washed fabric the rope at air drying.Under agitation the fragrant fabric rinsing emulsion that 10g prepares is diluted to 2 liters in embodiment 5 with tap water.A slice is washed once fabric folded and be placed in the bucket of 40 * 50cm, and with the fragrant fabric purificant emulsion submergence of diluting.Fabric was kept in bucket 10 minutes, overturn once during this period, then at 1200min -1Under dry 2 minutes and the rope in air drying.Then, the pliability of the towel handled of group's sensory evaluation by 9 test people is marked to 5 (very softnesses) from 0 (firmly).For relatively, estimate the towel of handling with following fragrant fabric purificant emulsion: use to have 50 rather than 30 [Si (CH 3) 2O] the quaternised polysiloxane of the unitary EP-A of demonstrating 1 199350 formula ofs (III) compound structure replaces the organopolysiloxane of embodiment 3 to prepare described purificant.In order more also to have estimated the towel that replaces fragrant fabric purificant emulsion to handle with tap water.
Pliability after table 2 is handled with fragrant fabric purificant emulsion
The activeconstituents of fragrant fabric purificant Pliability (maximum 45 minutes)
The organopolysiloxane of embodiment 3 32
Quaternised polysiloxane according to EP-A 1 199 350 * 34
Do not have 0
*Not according to of the present invention
Experimental result shows uses fragrant fabric clean-out system according to the present invention to produce and the use corresponding pliability of pliability that commercially available fabric softener obtained to cotton fabric.

Claims (9)

1. therefrom can discharge the organopolysiloxane of fragrance alcohol, it is characterized in that it comprises the Z of functional group that at least one has following structure:
-N +R 1R 2-CH 2-C(O)OYA -
Wherein
R 1, R 2Be selected from C independently of each other 1-30In alkyl and the hydroxyethyl,
Y is the group of fragrance alcohol Y-OH, and
A -It is the negatively charged ion of the compatible sour HA of physiology.
2. the organopolysiloxane of claim 1 is characterized in that
It has the structure according to general formula (I)
(I)R 3R 4R 5Si-O-CH 2-CH 2-Z
Wherein
R 3Be polysiloxane group by the Sauerstoffatom bonding,
R 4Be C 1-30Alkyl or phenyl,
R 5=R 3Or R 4And
Z have with claim 1 in identical meaning.
3. the organopolysiloxane of claim 1 is characterized in that
It has the structure according to general formula (I)
(I)R 6-O-[Si(CH 3) 2-O] n-R 6
Wherein
n＝3-200，
R 6=-CH 2-CH 2-N +(CH 3) 2-CH 2-C (O) OYA -And
Y and A -Have with claim 1 in identical meaning.
4. each organopolysiloxane among the claim 1-3 is characterized in that
Described fragrance alcohol Y-OH is selected from following material: 4-allyl group-2-methoxyphenol (Eugenol), 3-(2-borneol oxygen base)-2-methyl isophthalic acid-propyl alcohol, 2-tertiary butyl hexalin, 4-tertiary butyl hexalin, benzylalcohol, 1-decanol, 9-decen-1-ol, dihydroterpineol, 2,4-dimethyl-4-tetrahydrobenzene-1-base methyl alcohol, 2,4-Dimethylcyclohexyl methyl alcohol, 2,6-dimethyl-2-enanthol, 2, the 6-2,6-dimethyl-4-heptanol, 3a, 4,5,6,7,7a-six hydrogen-2,4-dimethyl-4,7-methylene radical [1H] indenes-5-alcohol, 3,7-dimethyl-1,6-nonadiene-3-alcohol, 2,6-dimethyl-2,7-octadiene-1-alcohol (Linaool), suitable-3,7-dimethyl-2,6-octadiene-1-alcohol (vernol), instead-3,7-dimethyl-2,6-octadiene-1-alcohol (Geraniol), 3,7-dimethyl-1, the 7-ethohexadiol, 3,7-dimethyl-1-octanol (tetrahydrogeraniol), 2,6-dimethyl-sec-n-octyl alcohol (Tetrahydromyrcenol), 3,7-dimethyl-3-octanol (tetrahydrolinalool), 2,6-dimethyl-7-octen-2-ol (dihydromyrcenol), 3,7-dimethyl-6-octen-1-ol (geraniol), 2,2-dimethyl-3-(3-aminomethyl phenyl)-1-propyl alcohol, 2,2-dimethyl-3-phenyl-1-propyl alcohol, 2-oxyethyl group-4-creosol, 2-ethyl-4-(2,2,3-trimethylammonium-3-tetrahydrobenzene-1-yl)-2-butylene-1-alcohol, suitable-blatter alcohol, 4-(4-hydroxy 3-methoxybenzene base)-2-butanone, 1-hydroxyl-2-(1-methyl isophthalic acid-hydroxyethyl)-5-methylcyclohexanone, 3-(methylol)-methyl n-heptyl ketone, 4-(4-hydroxy-4-methyl amyl group)-3-cyclic ethylene-1-carboxyl aldehyde, iso-borneol, the 3-Santalex, 2-pseudoallyl-5-methyl-cyclohexanol (l-Isopulegol), 1-sec.-propyl-4-methyl cyclohexane-3-enol (Terpineol 350), the 4-isopropyl cyclohexanol, 1-(4-isopropylcyclohexyl-) ethanol, 4-isopropylcyclohexyl-methyl alcohol, 2-sec.-propyl-5-methyl-cyclohexanol (menthol), 2-sec.-propyl-5-cresols (thymol), 5-sec.-propyl-2-cresols (isothymol), 2-(4-methyl-3-cyclohexyl)-2-propyl alcohol (Terpineol 350), 2-(4-methylcyclohexyl)-2-propyl alcohol (dihydroterpineol), 4-methoxyl group benzylalcohol, 2-methoxyl group-4-cresols, 3-methoxyl group-5-cresols, 1-methoxyl group-4-propenylbenzene (methyl allylphenol), 2-methoxyl group-propenylphenol (isoeugenol), 4-methyl-3-decene-5-alcohol, 2-methyl-6-methylene radical-7-octen-2-ol (myrcenol), 3-methyl-4-phenyl-2-butanols, 2-(2-aminomethyl phenyl) ethanol, 2-methyl-4-phenyl-1-amylalcohol, 3-methyl-5-phenyl-1-amylalcohol, 2-methyl isophthalic acid-phenyl-2-propyl alcohol, (1-methyl-2-(1,2,2-trimethylammonium dicyclo [3.1.0] oneself-the 3-ylmethyl) cyclopropyl) methyl alcohol, 3-methyl-4-(2,2,6-trimethyl cyclohexene-1-yl)-the 2-butanols, 2-methyl-4-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-2-butylene-1-alcohol, (3-methyl isophthalic acid-(2,2,3-trimethylammonium-3-cyclopentenyl)-and 3-tetrahydrobenzene-1-yl) methyl alcohol, 3-methyl-5-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-4-amylene-2-alcohol, 2-methyl-2-vinyl-5-(1-hydroxyl-1-methylethyl) tetrahydrofuran (THF), instead, suitable-2, the 6-nonadienol, 1 nonyl alcohol, nopol, 1,2,3,4,4a, 5,6,7-octahydro-2,5,5-trimethylammonium-beta naphthal, the 1-octanol, 3,4,5,6,6-pentamethyl--2-enanthol, the 2-phenylethyl alcohol, the 2-phenyl propanol, 3-phenyl propanol (hydrocinnamyl alcohol), 3-phenyl-2-propylene-1-alcohol (styryl carbinol), 4-(5,5,6-trimethylammonium dicyclo [2.2.1] heptan-2-yl)-hexanaphthene-1-alcohol, 3,5, the 5-cyclonol, 2,4,6-trimethylammonium-4-tetrahydrobenzene-1-base methyl alcohol, 5-(2,2,3-trimethylammonium-3-cyclopentenyl)-3-methylpent-2-alcohol, 3,7,11-trimethylammonium-2,6,10-12 carbon triolefin-1-alcohol (farnesol), 3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol (nerolidol), 3,5,5-trimethylammonium-1-hexanol (isononyl alcohol), the 1-undecyl alcohol, 10-hendecene-1-alcohol, vetiverol.
5. each organopolysiloxane among the claim 1-4 is characterized in that
In the aqueous dispersions of described organopolysiloxane, fragrance alcohol Y-OH under pH3 than under pH9, discharging sooner.
6. fabric-treating agent, it comprises among at least a claim 1-5 each organopolysiloxane.
7. washing composition, it comprises among at least a tensio-active agent and at least a claim 1-5 each organopolysiloxane.
8. fragrant fabric purificant, it comprises among the claim 1-5 of at least a aqueous dispersions form each organopolysiloxane.
9. personal care product, it comprises among at least a claim 1-5 each organopolysiloxane.
CNA2006800201451A 2005-06-09 2006-05-05 Fragrance alcohol-releasing polysiloxane Pending CN101193950A (en)

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CN107880269A (en) * 2017-11-15 2018-04-06 华东理工大学 Containing half times of silicone-based compound of polyhedral oligomeric and application thereof
CN107880269B (en) * 2017-11-15 2020-11-27 华东理工大学 Polyhedral oligomeric silsesquioxane-containing compound and use thereof
CN113557261A (en) * 2019-03-08 2021-10-26 宝洁公司 Compositions comprising siloxane compounds having pendant silyl ether moieties
CN113144750A (en) * 2021-04-08 2021-07-23 珠海市昇恒贸易有限公司 Functional filter and fiber incorporating functional ingredients
CN115386425A (en) * 2022-09-20 2022-11-25 广州芬豪香精有限公司 Daily chemical essence for hair dye and preparation method thereof
CN115386425B (en) * 2022-09-20 2023-09-19 广州芬豪香精有限公司 Daily chemical essence for hair dye and preparation method thereof

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