CN101186723A - Ultra-wearable rubber formulation for sports shoes sole - Google Patents
Ultra-wearable rubber formulation for sports shoes sole Download PDFInfo
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- CN101186723A CN101186723A CNA2006101460934A CN200610146093A CN101186723A CN 101186723 A CN101186723 A CN 101186723A CN A2006101460934 A CNA2006101460934 A CN A2006101460934A CN 200610146093 A CN200610146093 A CN 200610146093A CN 101186723 A CN101186723 A CN 101186723A
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Abstract
The invention discloses a superwear-resisting rubber formulation of sport sole, which is characterized in that the formulation according to parts by weight comprises 80 parts of polybutadiene rubber, 20 parts of natural gum STR-5L, 1 part of uniform tackiness resin, 45-48 parts of white carbon black, 3.5 parts of softening oil, 3-3.2 parts of coupler, 5.2-5.8 parts of activator, 1 part of zinc stearate, 1 part of antifog agent, 1.9-2.1 parts of sulphur, and 1.65-1.95 part of accelerating agent, an ideal raw material functional combination can be obtained after applying the rubber formulation for sports shoes, which makes the sport shoe rubber sole having superwear resistance which is superior to the ordinary rubber sole, and has excellent properties such as wet-skid resistance, shock resistance and the like.
Description
Technical field
The present invention relates to a kind of rubber compounding, be meant at the bottom of a kind of sports shoes prescription especially with rubber.
Background technology
Sports shoes is because its special purposes, require its sole should be wear-resisting, anti-slippery with rubber, also require to have good shock resistance, yet present sports shoes is with in the rubber technology, because the irrationality of prescription, many shortcomings occurred: sports shoes is in spring repeatedly, the process of running, and sole is quick-wearing very, lose elastic force, skid.
Summary of the invention
At the weak point of above existence, the invention provides a kind of wear resisting property excellence, anti-slippery, have excellent impact resistance can ultra-wearable rubber formulation for sports shoes sole.
For achieving the above object, technical solution of the present invention is:
Ultra-wearable rubber formulation for sports shoes sole, it is characterized in that: this prescription is mainly by polybutadiene rubber 80 mass parts, natural gum 20 mass parts, tackifier 1 mass parts, strengthening agent 45-48 mass parts, softening agent 3.5 mass parts, coupling agent 3-3.2 mass parts, promoting agent 5.2-5.8 mass parts, stearic acid 1 mass parts, anti-aging agent 1 mass parts, vulcanizing agent 1.9-2.1 mass parts, promotor 1.65-1.95 mass parts is formed.
Described natural gum is STR-5L, tackifier are even tackifying resin, strengthening agent is a white carbon black, softening agent is a softening oil, promoting agent 5.2-5.8 mass parts is specially: promoting agent DEG 1.4-1.6 mass parts, promoting agent PEG 2.4-2.6 mass parts, promoting agent ZNO 1.4-1.6 mass parts, stearic acid is a Zinic stearas, anti-aging agent is antifog wax, vulcanizing agent is a sulphur, and promotor 1.65-1.95 mass parts is specially: altax 1.2-1.5 mass parts, captax 0.3 mass parts, promotor TS 0.15 mass parts.
The usefulness of technique scheme is:
Adopt at the bottom of the above-mentioned sports shoes with behind the rubber compounding, can obtain the ideal raw material function combinations, this prescription adopts polybutadiene rubber 80 mass parts of wear resisting property excellence as material of main part, for improving over-all propertieies such as polybutadiene rubber processibility and tear resistance, with natural gum STR-5L 20 mass parts and usefulness with good over-all properties, thus the overall performance of raising rubber aniseed itself.
The adding of described even tackifying resin 1 mass parts makes divinyl rubber and natural gum STR-5L decomposition separately more abundant, is stirred evenly, mixes easilier;
Use white carbon black 45-48 mass parts in the prescription strengthening agent, can improve the flexible resistance of rubber, make it to have the good fatigue performance that deflects;
At white carbon black very easily conglomeration in the course of processing, the bad phenomenon of dispersion, use environment-friendly type coupling agent 3-3.2 mass parts dialogue carbon black modified, and use softening agent softening oil 3.5 mass parts simultaneously, make white carbon black and powder Synergist S-421 95 soak into fully, disperse, to reach best effect;
Protection system uses has good antioxygen, ozone resisting antifogging agent 1 mass parts, and it can form the cured film of one deck on the sizing material surface, can stop the infiltration of ozone, and reaching well has protective effect;
Vulcanizing agent adopts sulphur 1.9-2.1 mass parts, promoting agent DEG 1.4-1.6 mass parts, promoting agent PEG 2.4-2.6 mass parts, promoting agent ZNO 1.4-1.6 mass parts, and the proportioning of Zinic stearas 1 mass parts, activated whole vulcanization system, improve the cross-linking density of cross-linked rubber and improved the heat aging property of cross-linked rubber, improved the fatigue lifetime of cross-linked rubber, and dynamic property is good.The effect of altax 1.2-1.5 mass parts, captax 0.3 mass parts, promotor TS 0.15 mass parts in addition, sulfidation is better; With the sports shoes rubber soles that this technical scheme is made, have the General Purpose Rubber sole incomparable super wear resisting property, and have good anti-slippery, multiple performance such as shock resistance.
Description of drawings
Do not have
Embodiment
Optimum weight makes up as table 1 in a ultra-wearable rubber formulation for sports shoes sole and the batch of material:
The starting material title | Mass parts | Weight (kg) |
Polybutadiene rubber | 80 | 30.5 |
Natural gum STR-5L | 20 | 7.5 |
Even tackifying resin | 1 | 0.4 |
White carbon black | 45-48 | 18 |
Softening oil | 3.5 | 1.3 |
Coupling agent | 3-3.2 | 1.2 |
Promoting agent DEG | 1.4-1.6 | 0.5 |
Promoting agent PEG | 2.4-2.6 | 1 |
Promoting agent ZNO | 1.4-1.6 | 0.6 |
Zinic stearas | 1 | 0.4 |
Antifogging agent | 1 | 0.4 |
Sulphur | 1.9-2.1 | 0.74 |
Altax | 1.2-1.5 | 0.5 |
Captax | 0.3 | 0.12 |
Promotor TS | 0.15 | 0.06 |
Implement the detected result such as the table 2 of motion shoe rubber behind the above-mentioned prescription:
Hardness Shao Er A | 72 |
Tensile strength Mpa | 13 |
Elongation at break % | 580 |
Right-angle tearing N/cm | 63 |
200% tensile modulus Mpa | 3 |
Setafter break % | 30 |
Density g/cm 3 | 1.15 |
AKRONcm 3 | 0.05 |
Claims (3)
1. ultra-wearable rubber formulation for sports shoes sole is characterized in that by the mass parts prescription as follows:
Polybutadiene rubber: 80 parts,
Natural gum: 20 parts,
Tackifier: 1 part,
Strengthening agent: 45-48 part,
Softening agent: 3.5 parts,
Coupling agent: 3-3.2 part,
Promoting agent: 5.2-5.8 part,
Stearic acid: 1 part,
Anti-aging agent: 1 part,
Vulcanizing agent: 1.9-2.1 part,
Promotor: 1.65-1.95 part.
2. ultra-wearable rubber formulation for sports shoes sole as claimed in claim 1 is characterized in that: described natural gum is STR-5L.
3. as claim 1,2 described ultra-wearable rubber formulation for sports shoes sole, it is characterized in that: described tackifier are even tackifying resin, strengthening agent is a white carbon black, softening agent is a softening oil, promoting agent 5.2-5.8 mass parts is specially: promoting agent DEG 1.4-1.6 mass parts, promoting agent PEG 2.4-2.6 mass parts, promoting agent ZNO 1.4-1.6 mass parts, stearic acid is a Zinic stearas, anti-aging agent is antifog wax, vulcanizing agent is a sulphur, and promotor 1.65-1.95 mass parts is specially: altax 1.2-1.5 mass parts, captax 0.3 mass parts, promotor TS 0.15 mass parts.
Priority Applications (1)
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CN2006101460934A CN101186723B (en) | 2006-11-16 | 2006-11-16 | Ultra-wearable rubber formulation for sports shoes sole |
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CN2006101460934A CN101186723B (en) | 2006-11-16 | 2006-11-16 | Ultra-wearable rubber formulation for sports shoes sole |
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CN101186723A true CN101186723A (en) | 2008-05-28 |
CN101186723B CN101186723B (en) | 2011-01-12 |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏(中国)有限公司 | Rubber for sneaker sole and preparation method thereof |
CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
CN101649092B (en) * | 2009-06-22 | 2012-07-04 | 泰亚鞋业股份有限公司 | Shock-absorbing rubber formulation for sport sole |
CN101643562B (en) * | 2009-06-22 | 2012-07-11 | 泰亚鞋业股份有限公司 | Formula of rubber with high slip preventing performance for soles of sports shoes |
CN103450613A (en) * | 2013-08-22 | 2013-12-18 | 吴江市英力达塑料包装有限公司 | Wear-resistant plastic used for preparing shoe soles and preparation method thereof |
CN103937046A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Self-cleaning rubber used for shoe sole and preparing method thereof |
CN103937048A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Non-frosting rubber used for dark-color shoe sole and preparing method thereof |
CN103937042A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Low-hardness anti-wear rubber used for shoe sole and preparing method thereof |
CN103937049A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Scratch-resistant glossy-surface shoe sole rubber and preparation method thereof |
CN106003662A (en) * | 2013-12-26 | 2016-10-12 | 青岛东昌源仪器有限公司 | Making method for shoe sole finished products |
CN106589478A (en) * | 2016-12-05 | 2017-04-26 | 钦州市钦南区生产力促进中心 | Wear-resistant shoe sole material and preparation method thereof |
CN108752661A (en) * | 2018-06-22 | 2018-11-06 | 南通龙邦橡塑有限公司 | A kind of formula and its preparation process at Labor protection shoes bottom |
CN109608705A (en) * | 2018-12-14 | 2019-04-12 | 瑞安市大虎鞋业有限公司 | Military wear-resistant rubber sole |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6120880A (en) * | 1995-03-23 | 2000-09-19 | Crow; William R. | Performance enhancing athletic shoe components and methods |
CN1154296A (en) * | 1995-10-25 | 1997-07-16 | 株式会社东星化学 | Method for manufacturing outsoles of shoes |
CN1243061A (en) * | 1998-07-27 | 2000-02-02 | 港台集团有限公司 | Mfg. method for sport-shoe sole |
-
2006
- 2006-11-16 CN CN2006101460934A patent/CN101186723B/en active Active
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101649092B (en) * | 2009-06-22 | 2012-07-04 | 泰亚鞋业股份有限公司 | Shock-absorbing rubber formulation for sport sole |
CN101643562B (en) * | 2009-06-22 | 2012-07-11 | 泰亚鞋业股份有限公司 | Formula of rubber with high slip preventing performance for soles of sports shoes |
CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
CN102212216B (en) * | 2010-04-09 | 2012-10-31 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏(中国)有限公司 | Rubber for sneaker sole and preparation method thereof |
CN102061017B (en) * | 2010-12-06 | 2012-10-10 | 安踏(中国)有限公司 | Rubber for sneaker sole and preparation method thereof |
CN103937048A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Non-frosting rubber used for dark-color shoe sole and preparing method thereof |
CN103937046A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Self-cleaning rubber used for shoe sole and preparing method thereof |
CN103937042A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Low-hardness anti-wear rubber used for shoe sole and preparing method thereof |
CN103937049A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Scratch-resistant glossy-surface shoe sole rubber and preparation method thereof |
CN103450613A (en) * | 2013-08-22 | 2013-12-18 | 吴江市英力达塑料包装有限公司 | Wear-resistant plastic used for preparing shoe soles and preparation method thereof |
CN103450613B (en) * | 2013-08-22 | 2015-07-22 | 吴江市震宇缝制设备有限公司 | Wear-resistant plastic used for preparing shoe soles and preparation method thereof |
CN106003662A (en) * | 2013-12-26 | 2016-10-12 | 青岛东昌源仪器有限公司 | Making method for shoe sole finished products |
CN106589478A (en) * | 2016-12-05 | 2017-04-26 | 钦州市钦南区生产力促进中心 | Wear-resistant shoe sole material and preparation method thereof |
CN108752661A (en) * | 2018-06-22 | 2018-11-06 | 南通龙邦橡塑有限公司 | A kind of formula and its preparation process at Labor protection shoes bottom |
CN108752661B (en) * | 2018-06-22 | 2020-11-27 | 南通龙邦橡塑有限公司 | Formula and preparation process of labor protection sole |
CN109608705A (en) * | 2018-12-14 | 2019-04-12 | 瑞安市大虎鞋业有限公司 | Military wear-resistant rubber sole |
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