CN101168476B - Low radiation coated glass capable of being bended by baking - Google Patents

Low radiation coated glass capable of being bended by baking Download PDF

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CN101168476B
CN101168476B CN200710009649XA CN200710009649A CN101168476B CN 101168476 B CN101168476 B CN 101168476B CN 200710009649X A CN200710009649X A CN 200710009649XA CN 200710009649 A CN200710009649 A CN 200710009649A CN 101168476 B CN101168476 B CN 101168476B
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coated glass
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CN101168476A (en
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施忠惠
尚贵才
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Fuyao Glass Industry Group Co Ltd
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Fuyao Glass Industry Group Co Ltd
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Abstract

A bake-bent low-radiation coated glass relates to coated glass, in particular to low-radiation coated glass. The invention provides a low-radiation coated glass and an interlayer thermal-insulation glass composed of the low-radiation coated glass, wherein the film structure of the low-radiation coated glass comprises a glass plate, a first dielectric layer, a low-radiation layer, a second dielectric layer, and a protective layer, wherein the film structure of one embodiment comprises a glass substrate SiOx/SiOxNy/SnOx/NiCrOx/ZnSnOx/Ag/NiCrOx/SnOx/SiOxNy film from inner to outer at the glass plate, the low-radiation coated glass, PVB (polyvinyl butyral) and another glass plate are layered to form an interlayer thermal-insulation glass which visible light transmission is more than 76% and solar energy transmission is lower than 53%, therefore, the interlayer thermal-insulation glass is particularly applied on vehicle front shield glass.

Description

Bendable low-emission coated glass
[technical field]
The present invention relates to a kind of coated glass, be particularly useful for low radiation coated glass.
[background technology]
Common laminated glass is the sandwich structure of glass/pvb film/glass, does not have heat insulating function.But laminated glass can reach heat insulating function by the different technologies means.
Chinese patent discloses a kind of heat reflection laminated glass No. 200620004861.8, this patent has been described by changing PVB (Polyvinyl Butyral, polyvinyl butyral acetal) structure and material is realized the heat reflection function of laminated glass, because common laminated glass does not have heat reflection or heat-proof quality.Its structure comprises a PVB functional film layer and the PVB film layers between the first layer glass, second layer glass and the layer glass, the PVB functional film layer comprises a PVB film layers and heat reflection rete laminated together with it, this heat reflection rete is made up of the ordered arrangement of plural layer non-metallic layer, has that height pastes and snappiness.
Chinese patent the 97209697.3rd discloses a kind of heat reflection laminated glass, the used PVB of the structure of its PVB and common laminated glass is the same, having a slice in the former glass sheets that its difference is to be adopted at least is coated glass, promptly adjacent with PVB glass surface is coated with one deck heat reflection rete, thereby makes laminated glass have the heat reflection function.
The glass coating product can be divided into thermal reflecting coating and low-radiation film according to functional classification.But by retrieval, do not have to find to be coated with the laminated glass of low-radiation film, thereby make laminated glass have the technical literature of low radiation functions or heat insulating function.The laminated glass that has the low radiation functions plated film is in space state at home.
Low radiation coated glass also is the Low-E coated glass, is meant that the surface plates the special glass of the stratified film that the metal that has extremely low emissivity or other compounds form.The Low-E coated glass is the glassy product of kind of a green, energy-saving and environmental protection.The emissivity of simple glass is about 0.84, and the emissivity of Low-E coated glass is below 0.25.This low-radiation film layer less than one of hairline percentage thickness is very high to the reflectivity of far-infrared thermal radiation, far-infrared thermal radiation more than 80% can be reflected back, and the far infrared reflectivity of normal transparent float glass, antisolar glass is only about 12%, so the Low-E coated glass has the effect that good blocking radiant heat sees through.In winter, the thermal radiation that it distributes room heater and indoor object can be as a hot mirror, and most reflected backs are indoor, guarantees that indoor heat does not does not scatter and disappear to outdoor, thereby saves heat cost.In summer, it can stop in the thermal radiation inlet chamber that outdoor ground, buildings send, and saves the air conditioner refrigerating expense.The visible reflectance of Low-E coated glass is generally below 11%, and is close with the common white glass, is lower than the visible reflectance of common sunlight controlling coated glass, can avoid causing reflected light to pollute.
According to the manufacturing process of low-E coated glass, can be divided into two kinds of online low-E coated glass and off-line low-E coated glasses, the invention belongs to off-line low-E coated glass field.
Off-line low-E coated glass is to be made of rete repeatedly, be to adopt magnetron sputtering technology to produce, its functional layer is mainly silver layer, because silver layer oxidation especially easily, so common off-line low-E coated glass can not carry out heating operation, can only be that synthetic immediately double glazing uses behind the plated film.
Along with technology is constantly progressive, but occurred tempering low-E coated glass in recent years, but the glass coating producer of the bigger employing magnetron sputtering technique of domestic a few family can produce this tempering low-E coated glass." but tempering " just is meant glass elder generation plated film, tempering again behind the plated film, and can film quality not impacted; But tempering low-E coated glass is meant that glass plates the low-radiation film layer earlier, and then removes tempering, and the key property behind the tempering as radiant ratio (E value), transmitance etc., all can not change, and that is to say original performance that can also keep rete behind the tempering.But the film layer structure of this tempering low-E coated glass is generally: glass/Si 3N 4/ TiO x/ ZnO/Ag/NiCrO x/ Si 3N 4This film layer structure can carry out tempering or thermal treatment, and still can keep original performance after carrying out tempering or thermal treatment; Described product relatively is suitable for the top-grade building cladding glass, and transmitance belongs to high-transparency coated glass product more than 65%, so can not produce serious anti-dazzle public hazards.
But but the coated glass of this tempering film layer structure can not stand to dry by the fire curved operation, can cause low radiance decline and/or transmitance to change after baking is curved,, particularly can not be used to make windshield glass of automobile so but this tempering coated glass product can not be used to make laminated glass.
The curved operation of baking is the critical process in the laminated glass manufacturing process, because although the hot bending operation in curved operation of baking and the toughened glass manufacturing process all will be born the high temperature more than 600 ℃, but the residence time of coated glass in two kinds of operations is different, the hot bending operation of toughened glass stopped at most 2-4 minute, and the curved operation of the baking of laminated glass need stop 5-10 minute, and the residence time at high temperature is the most severe to the influence of the film quality of coated glass, so the residence time under the high temperature has just determined the complexity of coated glass technological development.
By retrieval, domestic up to now also the discovery utilized magnetron sputtering technology to be used to make the front windshield coated glass and is used for the correlation technique that laminated glass dries by the fire curved film layer structure.
[summary of the invention]
The objective of the invention is to overcome in the prior art rete can not long-time resistant to elevated temperatures defective, and a kind of bendable low-emission coated glass is provided.
Technical scheme of the present invention is: film layer structure outwards is followed successively by from sheet glass: glass substrate/first dielectric layer/low radiating layer/second dielectric layer/protective layer, and wherein low radiating layer is a silver layer, first dielectric layer is SiO x/ TiO x/ SiO xN y/ NbO x/ ZnO xOr SiO x/ SiO xN y/ SnO x/ NiCrO x/ ZnSnO xOr SiO x/ SiO xN y/ TiO x/ NiCrO x/ ZnO xOr SiO x/ SnO x/ SiO xN y/ NbO x/ ZnSnO xStructure; Second dielectric layer is NbO x/ TiO xOr NbO x/ SnO xOr NiCrO x/ SnO xOr NiCrO x/ TiO xStructure; Protective layer is SiO xN yStructure; Film layer structure is followed successively by outside sheet glass is same: glass substrate/SiO x/ SiO xN y/ TiO x/ NbO x/ ZnSnO x/ Ag/NbO x/ TiO x/ SiO xN yStructure; NbO in first dielectric layer and second dielectric layer xLayer can be by NiCrO xLayer substitutes; TiO xLayer can be by SnO xLayer substitutes; ZnO xLayer can be by ZnSnO xSubstitute.
Another scheme of the present invention is: a kind of interlayer heat-protecting glass, this interlayer heat-protecting glass comprises a glass plies, a PVB layer and an other glass plies, an other sheet glass is the bendable low-emission coated glass plate, and bendable low-emission coated glass plate and PVB layer, glass plies stack constitute the interlayer heat-protecting glass.
Advantage of the present invention is: disclosed low radiation coated glass plate can stand the curved operation of baking in the laminated glass manufacturing process, promptly can bear long pyroprocess, after overbaking is curved, film layer structure remains intact, film quality can not change, Key Performance Indicator before and after baking is curved as visible light transmissivity, radiant ratio etc., all can not change.Because low radiation coated glass plate of the present invention can stand to dry by the fire the long-time resistant to elevated temperatures test of curved operation, and its performance is changed, and can keep 〉=78% visible light transmissivity, so, low radiation coated glass plate of the present invention can be used for making laminated glass, and makes laminated glass have unique effect of heat insulation.
Interlayer heat-protecting glass disclosed in this invention has low radiation functions, allows the visible light in the sunlight spectrum to pass through, and the far-infrared heat radiation more than 80% can be reflected back.In winter, the thermal radiation that it distributes object in heating installation and the car as minute surface, is reflected the overwhelming majority in the carriage return, guarantees that heat does not does not scatter and disappear outside car in the car, thereby saves heat cost; In summer, it can stop thermal radiation that the outer sunlight of car and buildings, ground sends into the car, saves air-conditioning refrigeration expense.So this laminated glass that is coated with low-radiation film has energy-saving effect truly.
The visible light transmissivity of this interlayer heat-protecting glass 〉=76%, sun power transmitance≤53%, every performance index all can satisfy GB9656-2003 " automobile shatter proof glass " national standard.The alternative common laminated glass of interlayer heat-protecting glass of the present invention uses, and is specially adapted to windshield glass of automobile.
[description of drawings]
Fig. 1 is wherein a kind of structural representation of bendable low-emission coated glass of the present invention;
Fig. 2 is wherein a kind of structural representation of the interlayer heat-protecting glass that is made of bendable low-emission coated glass of the present invention.
[embodiment]
The film layer structure synoptic diagram of Fig. 1 low radiation coated glass plate of the present invention outwards is followed successively by from sheet glass: glasssubstrate/SiO x/ TiO x/ SiO xN y/ NbO x/ ZnO x/ Ag/NbO x/ TiO x/ SiO xN y, wherein 1 is glass substrate (English is translated into glass substrate), 3 is SiO xLayer, 0＜x≤2; 5 is TiO xLayer, 0＜x≤2; 7 is SiO xN yLayer, 0≤x＜2,0＜y≤4/3, and 2x+3y=4; 9 is NbO xLayer, 0＜x≤2.5; 11 is ZnO xLayer, 0＜x≤1; 13 is the Ag layer; 15 is NbO xLayer, 0＜x≤2.5; 17 is TiO xLayer, 0＜x≤2; 19 is SiO xN yLayer, 0≤x＜2,0＜y≤4/3, and 2x+3y=4.
First dielectric layer is SiO x/ TiO x/ SiO xN y/ NbO x/ ZnO xStructure, low radiating layer are the Ag layer, and second dielectric layer is NbO x/ TiO xLayer, protective layer is the SiOxNy layer; NbO in first dielectric layer and second dielectric layer xLayer can be by NiCrO xLayer substitutes, NiCrO xIn 0＜x≤3; TiO xLayer can be by SnO xLayer substitutes, SnO xIn 0＜x≤2; ZnO xLayer can be by ZnSnO xSubstitute ZnSnO xIn 0＜x≤3.
The manufacturing process of this low radiation coated glass comprises: thickness be not less than 1.6mm former section of fresh float glass, last slice, cutting, edging, washing, successively through each target plated film, online detection, sheet, packing etc. down, this manufacturing process realizes at the magnetron sputtering film production line, this coating film production line comprises 9-13 sputtering target material, requirement according to film material, each target is arranged, the flow of required power and argon gas, nitrogen, oxygen etc. is set, just can produces the product that meets the demands.
Wherein, plating SiO x, TiO x, SiO xN yDeng the used target of rete is rotary target, plating NbO x, the used target of rete such as Ag is planar target, ZnO xRete can be with rotary target or planar target.The thickness of each rete is respectively: in first dielectric layer, and SiO xThicknesses of layers is 10-25nm, TiO xThicknesses of layers is 10-16nm, SiO xN yThicknesses of layers be 25-35nm, NbO xLayer thickness is 5-15nm, ZnO xThicknesses of layers is 5-15nm; Low radiating layer Ag layer thickness is 5-20nm; In second dielectric layer, NbO xThicknesses of layers is 8-18nm, TiO xThicknesses of layers is 25-35nm, in the protective layer, and SiO xN yThicknesses of layers is 45-60nm.In addition, SiO x, TiO x, SiO xN y, ZnO xPlay the antireflection effect Deng rete, thereby the transmitance of maintenance low radiation coated glass is more than 78%.
Described in background of invention of the present invention, but present prior art develops into tempering low-E coated glass, and the film layer structure of this radiation coated glass capable of being toughened is generally: glass/Si 3N 4/ TiO x/ ZnO/Ag/NiCrO x/ Si 3N 4This film layer structure can only stand the hot bending process in the toughened glass manufacturing processed, and heat-up time is greatly about 2-4 minute, if prolong heat-up time, will cause the film material oxidation or burns out, and lose its low radiation functions.
Compared with prior art, film layer structure of the present invention has obvious difference:
First point, film layer structure disclosed in this invention is an example with Fig. 1, first tunic that is plated is SiO x, microtexture is the Si-O key, and the glass pane surface micro chemical is the Si-OH key, the two microtexture is basic identical, consistency is fine, in conjunction with closely, thereby sheet glass is combined closely with rete, adhesiveproperties is good;
Second point is among the present invention, at plating ZnO xBefore, plate one deck NbO earlier xLayer is because NbO xHave excellent high temperature resistant and insulating property, so NbO xLayer can prevent that the Ag layer is oxidized or destroy; In addition, NbO xWith Seed Layer ZnO xBonding force relatively good;
Thirdly, the present invention is coated with a TiO than prior art more in second dielectric layer xLayer can further be protected low radiating layer Ag layer, has strengthened the anti-oxidation ability of rete;
The 4th point, protective layer material therefor of the present invention is SiO xN yLayer, owing to have partial oxygen to exist, so oxygen is difficult to enter in the film layer structure; And prior art is Si 3N 4, because of silicon target do not have fully oxidized, so oxygen enters structure easily;
The 5th point, the present invention is coated with 9 tunics altogether, and prior art only is coated with 6 tunics; And the order of the permutation and combination of identical film layer structure is also different, and a kind of performances such as just might causing transmitance that puts in order of every change changes.
In sum, compared with prior art, it is good that bendable low-emission coated glass of the present invention has with PVB, sheet glass adhesiveproperties, can stop advantages such as rete oxidation, therefore can be high temperature resistant for a long time, be higher than under 600 ℃ of conditions, bore 5-10 minute, based on these advantages, this low radiation coated glass just can be put in the baking and bending furnace and use, this product is applicable to manufacturing laminated glass, particularly windshield glass of automobile.
Fig. 2 is wherein a kind of structural representation of the interlayer heat-protecting glass that is made of bendable low-emission coated glass of the present invention, the structure of this interlayer heat-protecting glass is followed successively by sheet glass 1/ low-radiation film layer/PVB/ sheet glass 2, the thickness of sheet glass 1 is 1.6-2.3mm, the low-radiation film layer thickness is 150-250nm, the thickness of PVB is 0.76mm, and sheet glass 2 thickness are 1.6-2.3mm; Wherein, 1 is sheet glass 1 (English is translated into glass substrate 1), and 3 is SiO xLayer, 5 is TiO xLayer, 7 is SiO xN yLayer, 9 is NbO xLayer, 11 is ZnO xLayer, 13 is the Ag layer, 15 is NbO xLayer, 17 is TiO xLayer, 19 is SiO xN yLayer, 21 is the PVB layer, 23 are sheet glass 2 (English is translated into glass substrate 2); The low-radiation film layer is plated on the sheet glass 1, and is on the surface of the sheet glass 1 of PVB.
The manufacture method of this interlayer insulated glazing unit: at first, sheet glass 2 through cutting, last slice, washing, edging, dust, print each operation such as limit, oven dry and arrive baking and bend stage; Then with sheet glass 1 pairing that has the low-radiation film layer, sheet glass 2 is placed in together to dry by the fire with the sheet glass 1 that has the low-radiation film layer and bends with on the mould then, mould is put into the baking and bending furnace baking bend, through closing operations such as sheet, first pressing, high pressure, packing, produce final interlayer heat-protecting glass finished product then.
When baking is curved, two sheet glass are applied, and are placed on together to dry by the fire curvedly on the mould, and same domain technician abbreviates this two sheet glass as " sheet " and " small pieces " respectively, a slice of being close to mould is called " sheet ", is superimposed upon large stretch of top a slice and is called " small pieces ".The low-radiation film layer can be plated on " sheet ", also can be plated on " small pieces ", as long as rete towards pvb film, nestle up pvb film.No matter be plated on " sheet " or be plated on " small pieces ", can both play identical low radiation functions.
Embodiment one
On former of the float glass that through the clean thickness after washing, polishing, the oven dry is 1.8mm, plate first dielectric layer earlier, promptly plate SiO in order successively x/ TiO x/ SiO xN y/ NbO x/ ZnO xRete wherein plates SiO x, TiO x, SiO xN yWhat use Deng rete is rotary target, plating NbO xThe used target of rete is a planar target, ZnO xWhat rete was used is rotary target; Wherein,
SiO xIn the rete, x=0.8, thicknesses of layers are 19nm;
TiO xIn the rete, x=1.2, thickness are 13nm;
SiO xN yIn the rete, x=0.5, y=1, thickness are 30nm;
NbO xIn the rete, x=2, thickness are 10nm;
ZnO xIn the rete, x=0.6, thickness are 8nm.
Plate the low-radiation film layer and then, i.e. Ag layer, used target is a planar target, thicknesses of layers is 7nm.
And then plate second dielectric layer, plate NbO in order successively x/ TiO xLayer; Wherein
Plating NbO xTarget be planar target, NbO xIn the rete, x=1.1, thickness are 10nm;
Plating TiO xBe rotary target, in the rete, x=0.5, thickness are 30nm.
Plate protective layer at last, i.e. SiO xN yRete, used target are rotary target, x=0.8, and y=0.8, thicknesses of layers are 50nm.
Optical property
Through online detection, the radiant ratio of monolithic low radiation coated glass is 0.09, and visible light transmissivity is 83%; The curved back of baking is detected, and the radiant ratio of monolithic low radiation coated glass is 0.09, and visible light transmissivity is 84%; Make the interlayer heat-protecting glass through closing laminated glass manufacturing processes such as sheet, high pressure then, after testing, its radiant ratio is 0.09, and visible light transmissivity is 80.5%, and the total transmitance of sun power is 53%.
Physicals
Knock experiment: this experiment is a most important detection method of weighing adhesiveproperties between rete and PVB, the glass, experimental procedure is: the experiment slice that downcuts 100mm * 300mm from full wafer interlayer heat-protecting glass, cut two altogether, two samples are placed on-18 ± 2 ℃ preserved 2 hours down, take out, placed 2 minutes at normal temperatures, be placed on the sample case and knock with iron hammer, after treating the water of condensation volatilization, the contrast of back sample and standard sample of photo will be knocked, just the grade of knocking experiment can be judged.After testing, knocking experiment is 3 grades, satisfies the requirement of GB9656-2003.
According to GB9656-2003, impact experiment, anti-irradiation experiment, damp and hot circulation experiment etc. all can meet the demands.
Embodiment two
Being on former of the 2.1mm float glass, plate SiO in order successively through the clean thickness after washing, polishing, the oven dry x/ SiO xN y/ SnO x/ NiCrO x/ ZnSnO x/ Ag/NiCrO x/ SnO x/ SiO xN yRete, wherein:
SiO xIn the rete, x=1.4, thicknesses of layers are 22nm;
SiO xN yIn the rete, x=1.5, y=0.33, thickness are 26nm;
SnO xIn the rete, x=0.7, thickness are 11nm;
NiCrO xIn the rete, x=1, thickness are 13nm;
ZnSnO xIn the rete, x=0.4, thickness are 12nm.
Plate the low-radiation film layer and then, i.e. Ag layer, thicknesses of layers is 17nm.
And then plate second dielectric layer, plate NiCrO in order successively x/ SnO xLayer; Wherein
NiCrO xIn the rete, x=1.6, thickness are 15nm;
SnO xIn the rete, x=1.3, thickness are 26nm.
Plate protective layer at last, i.e. SiO xN yRete, used target are rotary target, x=1.1, and y=0.6, thicknesses of layers are 55nm.
The same among the used target type of each rete and the embodiment one.
Optical property
Through online detection, the radiant ratio of monolithic low radiation coated glass is 0.07, and visible light transmissivity is 80%; The curved back of baking is detected, and the radiant ratio of monolithic low radiation coated glass is 0.065, and visible light transmissivity is 80.5%; Make the interlayer heat-protecting glass through closing laminated glass manufacturing processes such as sheet, high pressure then, after testing, its radiant ratio is 0.065, and visible light transmissivity is 76%, and the total transmitance of sun power is 49%.
Physicals
Knock experiment: this experiment is a most important detection method of weighing adhesiveproperties between rete and PVB, the glass, and experimental procedure is identical with embodiment one.After testing, knocking experiment is 4 grades, and good than embodiment one satisfied the requirement of GB9656-2003.
According to GB9656-2003, impact experiment, anti-irradiation experiment, damp and hot circulation experiment etc. all can meet the demands.

Claims (2)

1. bendable low-emission coated glass; film layer structure outwards is followed successively by from sheet glass: glass substrate/first dielectric layer/low radiating layer/second dielectric layer/protective layer; wherein low radiating layer is a silver layer, and it is characterized in that: described first dielectric layer is SiO x/ TiO x/ SiO xN y/ NbO x/ ZnO xOr SiO x/ SiO xN y/ SnO x/ NiCrO x/ ZnSnO xOr SiO x/ SiO xN y/ TiO x/ NiCrO x/ ZnO xOr SiO x/ SnO x/ SiO xN y/ NbO x/ ZnSnO xStructure, wherein SiO xIn 0＜x≤2; TiO xIn 0＜x≤2; SiO xN yIn 0≤x＜2,0＜y≤4/3, and 2x+3y=4; NbO xIn 0＜x≤2.5; ZnO xIn 0＜x≤1; SnO xIn 0＜x≤2; NiCrO xIn 0＜x≤3; ZnSnO xIn 0＜x≤3; Described second dielectric layer is NbO x/ TiO xOr NbO x/ SnO xOr NiCrO x/ SnO xOr NiCrO x/ TiO xStructure, wherein NbO xIn 0＜x≤2.5; TiO xIn 0＜x≤2; SnO xIn 0＜x≤2; NiCrO xIn 0＜x≤3; Described protective layer is SiO xN yStructure, described SiO xN yIn 0≤x＜2,0＜y≤4/3, and 2x+3y=4.
2. bendable low-emission coated glass according to claim 1 is characterized in that: described bendable low-emission coated glass and PVB layer, glass plies stack constitute the interlayer heat-protecting glass.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6033785A (en) * 1996-07-29 2000-03-07 Central Glass Company, Limited Vehicular colored glass pane with light transmittance and reflectance adjustment
US6592996B1 (en) * 1998-02-06 2003-07-15 Nippon Sheet Glass Co., Ltd. Solar-shading light-transmissive panel and solar-shading multi-layer light-transmissive panel using same
CN2666663Y (en) * 2003-10-17 2004-12-29 湖南三才光电信息材料有限公司 Safety energy-saving sandwich glass
CN2755088Y (en) * 2004-12-30 2006-02-01 格兰特工程玻璃(中山)有限公司 Tempering thermal reflective coated glass
CN200958077Y (en) * 2006-10-19 2007-10-10 林嘉宏 Low-radiant strengthened film-coating glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6033785A (en) * 1996-07-29 2000-03-07 Central Glass Company, Limited Vehicular colored glass pane with light transmittance and reflectance adjustment
US6592996B1 (en) * 1998-02-06 2003-07-15 Nippon Sheet Glass Co., Ltd. Solar-shading light-transmissive panel and solar-shading multi-layer light-transmissive panel using same
CN2666663Y (en) * 2003-10-17 2004-12-29 湖南三才光电信息材料有限公司 Safety energy-saving sandwich glass
CN2755088Y (en) * 2004-12-30 2006-02-01 格兰特工程玻璃(中山)有限公司 Tempering thermal reflective coated glass
CN200958077Y (en) * 2006-10-19 2007-10-10 林嘉宏 Low-radiant strengthened film-coating glass

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