CN101163742A - Beverage container - Google Patents
Beverage container Download PDFInfo
- Publication number
- CN101163742A CN101163742A CNA200680013344XA CN200680013344A CN101163742A CN 101163742 A CN101163742 A CN 101163742A CN A200680013344X A CNA200680013344X A CN A200680013344XA CN 200680013344 A CN200680013344 A CN 200680013344A CN 101163742 A CN101163742 A CN 101163742A
- Authority
- CN
- China
- Prior art keywords
- container
- beverage
- ferric oxide
- alpha
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013361 beverage Nutrition 0.000 title abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 67
- 229920005989 resin Polymers 0.000 claims abstract description 60
- 239000011347 resin Substances 0.000 claims abstract description 60
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 27
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 22
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims abstract description 16
- 229920001225 polyester resin Polymers 0.000 claims abstract description 10
- 238000007493 shaping process Methods 0.000 claims description 48
- 230000035515 penetration Effects 0.000 claims description 35
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 14
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 9
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 239000004645 polyester resin Substances 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 150000005846 sugar alcohols Polymers 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000002834 transmittance Methods 0.000 abstract 1
- -1 3-butyleneglycol Chemical class 0.000 description 24
- 239000000203 mixture Substances 0.000 description 24
- 239000000975 dye Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000006866 deterioration Effects 0.000 description 9
- 238000009499 grossing Methods 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- 239000012756 surface treatment agent Substances 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 235000013405 beer Nutrition 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229920005992 thermoplastic resin Polymers 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- YJCJVMMDTBEITC-UHFFFAOYSA-N 10-hydroxycapric acid Chemical compound OCCCCCCCCCC(O)=O YJCJVMMDTBEITC-UHFFFAOYSA-N 0.000 description 4
- BZUNJUAMQZRJIP-UHFFFAOYSA-N 15-hydroxypentadecanoic acid Chemical compound OCCCCCCCCCCCCCCC(O)=O BZUNJUAMQZRJIP-UHFFFAOYSA-N 0.000 description 4
- IFYDZTDBJZWEPK-UHFFFAOYSA-N 2-hydroxyhexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCC(O)C(O)=O IFYDZTDBJZWEPK-UHFFFAOYSA-N 0.000 description 4
- JYZJYKOZGGEXSX-UHFFFAOYSA-N alpha-hydroxytetradecanoic acid Natural products CCCCCCCCCCCCC(O)C(O)=O JYZJYKOZGGEXSX-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- CPLYLXYEVLGWFJ-UHFFFAOYSA-N 2-hydroxyarachidic acid Chemical compound CCCCCCCCCCCCCCCCCCC(O)C(O)=O CPLYLXYEVLGWFJ-UHFFFAOYSA-N 0.000 description 3
- FOPDLHYJCVRBAQ-UHFFFAOYSA-N 2-hydroxytriacontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)C(O)=O FOPDLHYJCVRBAQ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 235000013334 alcoholic beverage Nutrition 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000005375 organosiloxane group Chemical group 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 2
- ATRNZOYKSNPPBF-CYBMUJFWSA-N (R)-3-hydroxytetradecanoic acid Chemical compound CCCCCCCCCCC[C@@H](O)CC(O)=O ATRNZOYKSNPPBF-CYBMUJFWSA-N 0.000 description 2
- UGAGPNKCDRTDHP-UHFFFAOYSA-N 16-hydroxyhexadecanoic acid Chemical compound OCCCCCCCCCCCCCCCC(O)=O UGAGPNKCDRTDHP-UHFFFAOYSA-N 0.000 description 2
- RPGJJWLCCOPDAZ-UHFFFAOYSA-N 2-hydroxybehenic acid Chemical compound CCCCCCCCCCCCCCCCCCCCC(O)C(O)=O RPGJJWLCCOPDAZ-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 2
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N 3-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1 AFPHTEQTJZKQAQ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002546 agglutinic effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 229920003233 aromatic nylon Polymers 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- MSUOLNSQHLHDAS-UHFFFAOYSA-N cerebronic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCC(O)C(O)=O MSUOLNSQHLHDAS-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 2
- MAYUCBCSAVDUKG-UHFFFAOYSA-N orthoacetic acid Chemical compound CC(O)(O)O MAYUCBCSAVDUKG-UHFFFAOYSA-N 0.000 description 2
- 235000020030 perry Nutrition 0.000 description 2
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 2
- 229940066675 ricinoleate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000000659 thermocoagulation Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- VBSTXRUAXCTZBQ-UHFFFAOYSA-N 1-hexyl-4-phenylpiperazine Chemical compound C1CN(CCCCCC)CCN1C1=CC=CC=C1 VBSTXRUAXCTZBQ-UHFFFAOYSA-N 0.000 description 1
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- AFENDNXGAFYKQO-UHFFFAOYSA-N 2-hydroxybutyric acid Chemical compound CCC(O)C(O)=O AFENDNXGAFYKQO-UHFFFAOYSA-N 0.000 description 1
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 1
- HOFAJRYTDZJFOX-UHFFFAOYSA-N 2-hydroxyoctatriacontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)C(O)=O HOFAJRYTDZJFOX-UHFFFAOYSA-N 0.000 description 1
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 description 1
- QPQKUYVSJWQSDY-UHFFFAOYSA-N 4-phenyldiazenylaniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=CC=C1 QPQKUYVSJWQSDY-UHFFFAOYSA-N 0.000 description 1
- YDCRNMJQROAWFT-UHFFFAOYSA-N 5-hydroxyhexanoic acid Chemical compound CC(O)CCCC(O)=O YDCRNMJQROAWFT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- GVGDNMTUZUVSLQ-UHFFFAOYSA-M C(CCCCCCCCCCC)(=O)[O-].[Mg+] Chemical compound C(CCCCCCCCCCC)(=O)[O-].[Mg+] GVGDNMTUZUVSLQ-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- NGEWQZIDQIYUNV-UHFFFAOYSA-N L-valinic acid Natural products CC(C)C(O)C(O)=O NGEWQZIDQIYUNV-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- JACRWUWPXAESPB-QMMMGPOBSA-N Tropic acid Natural products OC[C@H](C(O)=O)C1=CC=CC=C1 JACRWUWPXAESPB-QMMMGPOBSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000005125 dioxazines Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- GFMIDCCZJUXASS-UHFFFAOYSA-N hexane-1,1,6-triol Chemical compound OCCCCCC(O)O GFMIDCCZJUXASS-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N inositol Chemical compound OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-N mandelic acid Chemical compound OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- FDAKZQLBIFPGSV-UHFFFAOYSA-N n-butyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCCCNC1CC(C)(C)NC(C)(C)C1 FDAKZQLBIFPGSV-UHFFFAOYSA-N 0.000 description 1
- HRYSOBDFNHXNTM-UHFFFAOYSA-N n-butylbutan-1-amine;1,3,5-triazine Chemical compound C1=NC=NC=N1.CCCCNCCCC HRYSOBDFNHXNTM-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- DXGIRFAFSFKYCF-UHFFFAOYSA-N propanehydrazide Chemical class CCC(=O)NN DXGIRFAFSFKYCF-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000015040 sparkling wine Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- UZSAQAWEIQNGJT-UHFFFAOYSA-N tetracontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO UZSAQAWEIQNGJT-UHFFFAOYSA-N 0.000 description 1
- CZIRZNRQHFVCDZ-UHFFFAOYSA-L titan yellow Chemical compound [Na+].[Na+].C1=C(C)C(S([O-])(=O)=O)=C2SC(C3=CC=C(C=C3)/N=N/NC3=CC=C(C=C3)C3=NC4=CC=C(C(=C4S3)S([O-])(=O)=O)C)=NC2=C1 CZIRZNRQHFVCDZ-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
A beverage container produced by forming a colored molding resin containing a molding resin and a master batch, characterized in that the master batch contains (A) polyester resin, (B) surface-treated a-ferric oxide obtained by coating non-acicular a-ferric oxide of 0.01 to 0.06 m average particle diameter and 0.2 to 1.0 aspect ratio with a polyhydric alcohol and an organopolysiloxane, (C) metal salt of oxycarboxylic acid and (D) methine dye, and that the beverage container has part exhibiting a = 500 nm light transmittance of = 1%.
Description
Technical field
The present invention relates to beverage-container.The beverage-container that preferably relates to has the transparency of the degree of the amount of identification content easily, and in order to protect content, can cover the following visible rays of ultraviolet ray even 500nm, and surface smoothing is good.
Background technology
Polyester resin bottle has good thermotolerance, weathering resistance, and cost is also cheap, so can bring into play favourable characteristics such as the transparency, aesthetic appearance, light weight, security, replaces vial, is increased in the purposes of aspects such as food, beverage, cosmetics containers.
Existing beer with, drinks use etc. beverage with vial in order to give UV-preventing, and have the form and aspect of brown system.In recent years, because the business hours in shop are elongated, commodity can make content that peculiar smell or variable color etc. are arranged through throwing light on for a long time to wait, and this just requires higher levels of light-shielding.Considering from the angle of protection content, wish light penetration, is below 30% in the ultra-violet region less than 4% below the 420nm and in the visible region below the 550nm.
In polyester resin bottle, in order to give UV-preventing, consider stripping property, thermotolerance, and use the alpha-ferric oxide particle (for example, special fair 5-81623 communique) of median size below 0.1 μ m that is known as particulate oxide iron usually for content.But above-mentioned alpha-ferric oxide particle has the problems such as aggegation in the production process, and bad dispersibility, disperses insufficient.
In addition, also disclose the technology (for example, the spy opens flat 8-59398 communique) that relatively is difficult to agglutinative alpha-ferric oxide particle, but be difficult to satisfy above-mentioned characteristic.
And then beer container also needs gas shield usually in order to protect content.But the gas shield of general polyester resin bottle is poor, and the problem that makes the content deterioration is arranged.As solution, the technology of the plain film coating of useful charcoal shaping thing (for example, Te Kaiping 8-53116 communique, the spy opens the 2000-309324 communique), the technology that coats with silicon fiml, multiple stratification technology that aromatic nylon is matched with the technology of vibrin or establishes barrier layer for gases in addition, though gas shield is abundant, UV-preventing is insufficient.And, disclosed particulate oxide iron granules in the fair 5-81623 communique of spy is because the thermal thermocoagulation height, so have when shaping owing to take place pigment aggegation, the transparency low, produce to assemble and cause bad order, simultaneously, because around particulate oxide iron, have the space to make gas shield insufficient.
Summary of the invention
The purpose of this invention is to provide the covering property of the transparency, dispersiveness, ultraviolet portion and below the 500nm, the good beverage-container of covering property of the following visible part of 550nm preferably, special ideal purpose provides the beverage-container that is suitable for the seal foaming alcoholic beverage.Sparkling alcoholic beverage of the present invention is meant except with the beer and sparkling wine of Fructus Hordei Germinatus as raw material, also can is with being the alcoholic beverage that contains carbonic acid gas of raw material beyond the Fructus Hordei Germinatus.
The beverage-container that the present invention relates to is to use the painted shaping resin that contains shaping resin and masterbatch and the beverage-container that is shaped, it is characterized in that, masterbatch contains vibrin (A), surface-treated alpha-ferric oxide (B), hydroxycarboxylic acid metal-salt (C) and methyne based dye (D), wherein, the surface-treated alpha-ferric oxide is that to coat median size with polyvalent alcohol and organopolysiloxane be 0.01～0.06 μ m, aspect ratio is that 0.2～1.0 non-acicular alpha-ferric oxide forms, and it is part below 1% that this beverage-container has the following light penetration of 500nm.
Painted shaping resin preferred thickness is that the above 0.5mm of 0.2mm is following, 500nm is following light penetration is at the resin below 1%.
And it is part below 1.5% that above-mentioned beverage-container preferably has the following light penetration of 550nm.
The thickness of painted shaping resin is below the above 0.5mm of 0.2mm, and the following light penetration of 550nm is below 1.5%, uses such resin, and above-mentioned beverage-container can be shaped.
And it is part more than 50% that above-mentioned beverage-container preferably has the above light penetration of 650nm.
In the present invention, as shaping resin, preferably use polyester based resin.
And polyvalent alcohol or organopolysiloxane are preferably with respect to the total amount of surface-treated alpha-ferric oxide (B), and 0.01～10 weight % respectively does for oneself.
In the above-mentioned beverage-container,, preferably use TriMethylolPropane(TMP) or trimethylolethane as polyvalent alcohol.
And, as organopolysiloxane, preferably use dimethicone or methylhydrogenpolysi,oxane.
And, as hydroxycarboxylic acid metal-salt (C), preferably use 12-oxystearic acid calcium.
In addition, as methyne based dye (D), preferably use C.I. solvent brown 53 (C.I.No.SolventBrown53).
In above-mentioned beverage-container, total weight for surface-treated alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C), preferred cooperation ratio is that surface-treated alpha-ferric oxide (B) is 30～60 weight %, and hydroxycarboxylic acid metal-salt (C) is 40～70 weight %.
The application's open patent application 2005-125250 number described theme with application on April 22nd, 2005 is relevant, and these disclosures are herein incorporated by reference.
Embodiment
Beverage-container of the present invention is to use the painted shaping resin that contains shaping resin and masterbatch and the beverage-container that is shaped, it is characterized in that masterbatch contains vibrin (A), surface-treated alpha-ferric oxide (B), as the hydroxycarboxylic acid metal-salt (C) and the methyne based dye (D) of dispersion agent
Surface-treated alpha-ferric oxide (B) is to coat the material that alpha-ferric oxide forms with polyvalent alcohol and organopolysiloxane.
The median size of the alpha-ferric oxide of Shi Yonging is 0.01～0.06 μ m in the present invention, preferred 0.03～0.05 μ m.During median size less than 0.01 μ m, may produce particles aggregate, disperse badly, when surpassing 0.06 μ m, the surfaceness that may have the shaping thing is excessive, and surface smoothing, the transparency reduce the bad order of the shaping thing that the alpha-ferric oxide aggegation causes.Here, median size be meant with minor axis, major diameter on average as particle diameter, show the peaked value of size-grade distribution.
And the alpha-ferric oxide of Shi Yonging is that aspect ratio is 0.2～1.0 non-acicular substance in the present invention, can open flat 8-59398 communique disclosed method by the spy and obtain.Here, said aspect ratio is meant the minor axis that utilizes electron microscope observation and the ratio (minor axis/major diameter) of major diameter.In order to obtain the shaping thing of the transparency, favorable dispersity, proper sphere shape (minor axis/major diameter=1.0) most preferably.
In the present invention, use polyvalent alcohol and organopolysiloxane surface treatment agent jointly as alpha-ferric oxide.
Utilize the surface-treated purpose of the alpha-ferric oxide of polyvalent alcohol to make particle surface hypopolarization and the aggegation again that prevents particle.
Object lesson as polyvalent alcohol, can exemplify out ethylene glycol, propylene glycol, 1, polyoxyalkylene diols such as aklylene glycols such as 3-butyleneglycol, tetramethylene glycol or glycol ether, triglycol, polyoxyethylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol or glycerol, TriMethylolPropane(TMP), trihydroxy-ethane, tetramethylolmethane, sorbyl alcohol, 1,2, polyvalent alcohols such as 6-hexanetriol, Inositol nf12 99, polyvinyl alcohol.Preferred TriMethylolPropane(TMP) (TMP), trihydroxy-ethane (TME).These polyvalent alcohols can with a kind of or mix two kinds with on use.
The surface-treated purpose of utilizing the alpha-ferric oxide of organopolysiloxane is to make the particle surface hydrophobization, improves the wettability of particle and resin, suppresses reduction, the maintenance rerum natura of molecular resin amount.
As the object lesson of organopolysiloxane, can use various sex change polysiloxane such as polysiloxane such as dimethyl polysiloxane or methylhydrogenpolysi,oxane, methyl phenyl silicone, pure sex change polysiloxane, ether sex change polysiloxane, fluorine sex change polysiloxane.These organopolysiloxanes can with a kind or mix 2 kinds with on use.Preferable methyl hydrogen polysiloxanes, dimethyl polysiloxane.
And above-mentioned illustrative methylhydrogenpolysi,oxane is wished and can be represented with following formula.
(in the formula, n represents positive integer, and is preferred below 12.)
The amount of polyvalent alcohol and organo-siloxane is preferably with respect to the total amount of surface-treated alpha-ferric oxide (B), and 0.01～10 weight % respectively does for oneself.Surpass 10 weight %, do not have economy, and in manufacturing process, can produce polyvalent alcohol and organo-siloxane self decomposition etc., in the shaping thing of making, produce foaming and gathering etc.Less than 0.01 weight %, the polyvalent alcohol of iron oxide surface and the covering amount of organo-siloxane are insufficient, are unfavorable for the dispersion in resin, cause bad rerum natura in the shaping thing sometimes.More preferably 0.1～2 weight %, preferred especially 0.5～1 weight %.
The method that coats alpha-ferric oxide with above-mentioned surface treatment agent can be utilized known method such as wet processed or dry process.
Wet processed has alpha-ferric oxide and surface treatment agent added in the polar solvent of alcohol such as water or ethanol floods, after using high shear force mixing machines such as Henschel mixer, high-speed mixer to carry out the homogeneous mixing, revaporization, the dry method of desolvating of removing, or surface treatment agent is dispersed or dissolved in the solvent, then alpha-ferric oxide is mixed into the method for this solution etc.
In wet processed, in the surface treatment or when handling the back, preferably have the heat drying operation of alpha-ferric oxide, because can reduce the water content that moisture absorption etc. causes significantly.The ferric oxide of the low water content that so obtains be because during mixing dispersions, can suppress the resin deterioration in resin, suppress that the molecular resin amount reduces and the multiple advantages such as mechanical properties of maintenance shaping thing so have.
Dry process is added surface treatment agent when pulverizing alpha-ferric oxide with fluid energy pulverizer such as injector-type mill, micronizer mill or stirrers such as high-speed mixer, Henschel mixer.As the fluid of described fluid energy pulverizer, use pressurized air, heated compressed air, steam etc. usually.And, when polyvalent alcohol is solid at normal temperatures, the polyhydric alcohol solutions that is dissolved in the solvent can be used for above-mentioned treatment process.Can exemplify out as the ethanolic soln of TriMethylolPropane(TMP) or water-ethanol (1: 1) solution etc.
In the surface treatment of alpha-ferric oxide, utilize the preferred wet processed of coating of polyvalent alcohol, utilize the coating preferred dry of organopolysiloxane to handle.And, after the surface treatment, pulverize the agglutination particle that produces by surface treatment procedure with brute forces such as airflow milling, can improve dispersiveness more.
The surface treatment of alpha-ferric oxide can be used polyvalent alcohol and organopolysiloxane simultaneously, perhaps also can bring into use organopolysiloxane, and then uses polyvalent alcohol.
Can exemplify out moisture as one of alpha-ferric oxide agglutinative reason.Because the particle surface of alpha-ferric oxide has than higher wetting ability, so at first by coating the hydrophilic radical of handling particle surface with polyvalent alcohol, feasible effect with the moisture absorption that prevents operation subsequently.And the alpha-ferric oxide after polyvalent alcohol is handled is by heat drying, can reduce the water content that moisture absorption etc. causes significantly.
If coat alpha-ferric oxide after polyvalent alcohol is handled with the hydrophobicity organopolysiloxane, then can suppress particle aggegation again, obtain the surface-treated alpha-ferric oxide (B) of favorable dispersity.
And, surface-treated alpha-ferric oxide (B) with the operation of the thermoplastic resin melting mixing of polyester etc. in, can suppress thermal thermocoagulation, so can be scattered in well in the thermoplastic resin formed thing, the transparency raising aspect of shaping thing is good.
And the surface water component of the alpha-ferric oxide (B) that preferred surface is handled is few, because can suppress to add the influence to thermoplastic resin such as water decomposition.More preferably the amount of moisture less than 0.3%.
And the covering amount of above-mentioned surface treatment agent is by adopting known method, change the processing weight of alpha-ferric oxide and the supply concentration or the supply flow rate of surface treatment agent, thus it can be adjusted into fixed covering amount.
Hydroxycarboxylic acid as in the hydroxycarboxylic acid metal-salt (C) of dispersion agent of the present invention just is not particularly limited if having the compound of carboxyl and hydroxyl, but can exemplify out aliphatics or aromatic hydroxycarboxylic acid.Because utilize hydroxycarboxylic acid metal-salt (C) can improve the dispersiveness of alpha-ferric oxide,, simultaneously, particularly when using vibrin, can keep the value of the limiting viscosity (IV) of resin so can obtain the high shaping thing of the transparency.IV is used for representing the resin deterioration state of (adding water decomposition), and it is low more to be worth high more expression resin deterioration, and processibility is also good more.
As the aliphatic hydroxyl carboxylic acid, preferred carbonatoms is 10～30 material, can exemplify out as Alpha-hydroxy tetradecanoic acid, Alpha-hydroxy palmitinic acid, Alpha-hydroxy stearic acid, Alpha-hydroxy eicosanoic acid, Alpha-hydroxy docosanoic acid, Alpha-hydroxy Lignoceric acid, Alpha-hydroxy hexacosanoic acid, Alpha-hydroxy octocosoic acid, Alpha-hydroxy triacontanoic acid, beta-hydroxy tetradecanoic acid, 10-hydroxydecanoic acid, 15-hydroxypentadecanoic acid, juniperic acid, 12-oxystearic acid, ricinoleate acid etc.These can use separately, or also use more than 2 kinds.Consider preferred especially 12-oxystearic acid from the accessibility that raw material obtains.
In addition, as other aliphatic hydroxyl carboxylic acid, can exemplify out oxyacetic acid, lactic acid, hydroxy-propionic acid, α-hydroxybutyric acid, Alpha-hydroxy isobutyric acid, δ-hydroxycaproic acid, Alpha-hydroxy triacontanoic acid, Alpha-hydroxy gheddic acid, Alpha-hydroxy ceroplastic scid, Alpha-hydroxy octatriacontanoic acid, the acid of Alpha-hydroxy tetracontane, R-Glyceric acid, tartronic acid, oxysuccinic acid, citric acid etc.In addition, as aromatic hydroxy-carboxylic, can exemplify out Whitfield's ointment, m-oxygen base M-nitro benzoic acid, p-oxygen base M-nitro benzoic acid, gallic acid, amygdalic acid, tropic acid etc.
As the lithium in the metal preferred as alkali of hydroxycarboxylic acid metal-salt (C), the magnesium in the alkaline-earth metal, calcium.And 12-oxystearic acid metal-salt preferably as the FDA approval, has the magnesium or the calcium that can use advantage.These metal-salts can use a kind, and also two or more kinds may be used.
12-oxystearic acid metal-salt is micropowder preferably.And the method for making of 12-oxystearic acid metal-salt has double decomposition precipitation method, dry type direct method etc., can use any.Utilize the dry type direct method can access the low 12-oxystearic acid metal-salt of water ratio, with the thermoplastic resin melting mixing time, can suppress the influence of the molecular weight reduction etc. of thermoplastic resin, so more by preferably.
Methyne in the beverage-container of the present invention is that fuel (D) is the material that thermotolerance is good, sublimability is few.Specifically can exemplify out Color Index (C.I.) solvent brown 53 (Solvent Brown53), C.I. solvent yellow 133 (Solvent Yellow133), C.I. solvent violet 49 (Solvent Violet49), C.I. pigment orange 70 (Pigment Orange70) etc.They can use separately or and use.Form and aspect and when covering the following visible part of 550nm particularly, C.I. solvent brown 53 (Solvent Brown53) is because be FDA registration thing, so preferably used.
In beverage-container of the present invention, as the vibrin that is used for masterbatch (A), aromatic carboxylic acid or its ester and aliphatic diol can be carried out condensation and obtain, wherein, aromatic carboxylic acid can be as terephthalic acid, m-phthalic acid, naphthalene-2,6-dicarboxylic acid, 4, the 4-diphenyl dicarboxylic acid, aliphatic diol can be as ethylene glycol, propylene glycol, 1,4-butyleneglycol, glycol ether, 1,4 cyclohexane dimethanol etc.That represents can exemplify out polyethylene terephthalate or polybutylene terephthalate.
These vibrin (A) can be the materials of multiple carboxylic acid composition of combination and multiple diol component.That is, described vibrin can also be to add the 3rd composition and the multipolymer of copolymerization except the homopolymer (main composition composition) that is made of above-mentioned aromatic carboxylic acid composition and aliphatic diol composition.As the 3rd composition, when for example the main composition composition is ethylene glycol terephthalate, can exemplify out glycol such as glycol ether, propylene glycol, neopentyl glycol, polyalkylene glycol, 1,4 cyclohexane dimethanol; Succsinic acid, adipic acid, sebacic acid, phthalic acid, different phthalic acid, 2, dicarboxylic acid such as 6-naphthalic acid; Multifunctional polycarboxylic acid such as trihemellitic acid, pyromellitic acid etc.In addition, the main composition composition is an ethylidene-2, during the 6-naphthalene, can exemplify out above-mentioned the 3rd composition (wherein, with 2, the 6-naphthalic acid is as phthalic acid).Particularly consider preferred polyethylene terephthalate from the angle of the transparency, plasticity, cost.And, as vibrin of the present invention (A), also can use the polyester elastic.
In the present invention, the resin thermoplastic resin normally that is used for the shaping of beverage-container.Basic resin in the masterbatch is exactly and the shaping resin of vibrin (A) in beverage-container preferably to use same resin or the resin of intermiscibility is arranged.As the resin that intermiscibility is arranged, can exemplify out polyester based resin, polystyrene resin, polyolefin-based resins, aromatic nylon is resin etc.The resin that these shaping resins also can mix more than 2 kinds comes as shaping resin.
Shaping resin is polyester based resin preferably, can use and the identical resin of above-mentioned vibrin (A) as polyester based resin.
Being used for masterbatch of the present invention can utilize following method to make.
Surface-treated alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C) are pre-mixed with Henschel mixer, high-speed mixer, pony mixer etc., obtain tinting material (particularly with respect to the total weight of surface-treated alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C), be 30～60 weight % preferably with surface-treated alpha-ferric oxide (B), hydroxycarboxylic acid metal-salt (C) is that the ratio of 40～70 weight % cooperates), this tinting material is cooperated with methyne based dye (D).At this moment, can add methyne based dye (D) in the mixture of alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C), also alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C) can be mixed simultaneously with methyne based dye (D).Melt extrude the mixture of vibrin (A), alpha-ferric oxide (B), hydroxycarboxylic acid metal-salt (C), methyne based dye (D) with single shaft or two forcing machines, utilize mixing granulator to make and be used for masterbatch of the present invention.
Beverage-container of the present invention is that above-mentioned masterbatch is cooperated uncoloured shaping resin, obtains painted shaping resin, utilizes it to be configured as container.Ideal situation is to use the injection blow molding forming mill to make beverage-container.In the present invention, also can be also with the resin beyond the painted shaping resin.
In these beverage-containers, with respect to the shaping resin that is colored (painted shaping resin) that constitutes beverage-container, the content of preferred 0.3～1 weight % of surface-treated alpha-ferric oxide (B), the content of preferred 0.04～0.2 weight % of methyne based dye (D).In masterbatch, with respect to whole masterbatch, the content of preferred 3～10 weight % of surface-treated alpha-ferric oxide (B), the content of preferred 0.4～10 weight % of methyne based dye (D).To the addition of the masterbatch of painted shaping resin not, with respect to preferred 3～10 weight % of uncoloured shaping resin.
The feature of beverage-container of the present invention is that (preferred 200～500nm) light penetration is the part below 1%, preferably below 0.8%, more preferably below 0.5% below having 500nm.And (preferred 200～550nm) light penetration was the part below 1.5%, more preferably below 1% below beverage-container of the present invention preferably had 550nm.(preferred 650～700nm) light penetration was in the part more than 50% more than beverage-container of the present invention preferably had 650nm.Light penetration can be protected content in described scope, easily the amount of identification content.
The degree of the light-shielding of ultraviolet portion and visible part changes according to the content of each composition in the beverage-container and the thickness of beverage-container.
As condition with above-mentioned characteristic, the content of the mentioned component in the beverage-container, as required, if the words that beverage-container approaches are just some more, thick words can be less.
In the present invention, there is no particular restriction for the shape of container, can make arbitrary shapes such as sphere, square.And also there is no particular restriction for the capacity of container, can make capacity arbitrarily such as 350ml, 500ml, 1000ml, 1500ml, 2000ml.And then the thickness of container does not have special restriction yet, but below the preferred above 7mm of 0.1mm, more preferably below the above 5mm of 0.2mm, below the further preferred above 4mm of 0.2mm.The thickness of integral container can be homogeneous, can also be the thickness difference of the oral area, shoulder, body, bottom etc. of container.Usually, the thin thickness of the body of beverage-container is below the above 0.7mm of the preferred 0.1mm of its thickness, more preferably below the above 0.5mm of 0.2mm.Beverage-container of the present invention can have the part of using the resin beyond the painted shaping resin and being shaped.
It is part below 1% that beverage-container of the present invention has the following light penetration of 500nm,, has light penetration and be the zone below 1% that is.In the present invention, preferred drink uses the light penetration of integral container below 1%, but also can have light penetration to surpass 1% part.
Beverage-container of the present invention, thickness are below the above 0.5mm of 0.2mm, and being to use 500nm, following (preferred 200～500nm) light penetration is that the painted shaping resin below 1% is shaped.More preferably, beverage-container of the present invention, thickness are below the above 0.5mm of 0.2mm, and being to use 550nm, following (preferred 200～550nm) light penetration is that the painted shaping resin below 1.5% is shaped.Further preferably, thickness is below the above 0.5mm of 0.2mm, and use 650nm is above, and (preferred 650～700nm) light penetration is that the painted shaping resin more than 50% is shaped.
For the thickness that makes painted shaping resin is light penetration below the above 0.5mm of 0.2mm, what 500nm was following is below 1%, what more preferably 550nm was following is below 1.5%, and what further preferred 650nm was above is more than 50%, and then the content of each composition is preferably in above-mentioned scope.The beverage-container that uses so painted shaping resin and be shaped can be protected content, easily the amount of identification content well.The light penetration of the thickness that the above 0.5mm of the 0.2mm of painted shaping resin is following be meant not painted shaping resin and masterbatch mixed and painted shaping resin, be the light penetration that the shaped state below the above 0.5mm of 0.2mm is measured with thickness.
In the present invention, the painted shaping resin that is used to be shaped, thickness are below the above 0.5mm of 0.2mm, and the following light penetration of preferred 500nm is below 0.8%, and the following light penetration of further preferred 500nm is below 0.5%.In addition, in beverage-container of the present invention, the following light penetration of preferred 550nm is below 1%.
In addition, in the present invention, in the scope that does not hinder above-mentioned effect, can use dyestuff, pigment and other plastics additive.
Corresponding desirable form and aspect are used pigment or dyestuff.Specifically, can use azo system, anthraquinone is the perylene, Perry dense (perynone) is, quinacridone system, phthalocyanine pigment system, isoindolinone system, dioxazines system, indanthrene (indanthrene) is, quinophthalone (quinophthalone) such as is at a pigment dyestuff, zinc oxide, titanium oxide, ultramarine, cobalt blue, carbon black, coloured mineral dye such as titan yellow, barium sulfate, kaolin, pigment extenders such as mica, anthraquinone is the perylene, Perry dense (perynone) is, monoazo system, the methyne system of other kinds, heterocycle system, lactone system, oil-soluble colourant such as phthalocyanine system, dispersed dye.
And can use metal fatty acid salt is that the metal-salt of higher fatty acid or hydroxycarboxylic acid metal-salt are as lubrication prescription.Can exemplify out as calcium stearate, Magnesium Stearate, barium stearate, Zinic stearas, aluminum stearate, lithium stearate, calcium laurate, zinc laurate, Magnesium monolaurate is as the Alpha-hydroxy tetradecanoic acid of hydroxycarboxylic acid metal-salt, the Alpha-hydroxy palmitinic acid, the Alpha-hydroxy stearic acid, the Alpha-hydroxy arachic acid, the Alpha-hydroxy docosanoic acid, the Alpha-hydroxy Lignoceric acid, the Alpha-hydroxy hexacosanoic acid, the Alpha-hydroxy octocosoic acid, the Alpha-hydroxy triacontanoic acid, the beta-hydroxy tetradecanoic acid, the 10-hydroxydecanoic acid, the 15-hydroxypentadecanoic acid, juniperic acid, the 12-oxystearic acid, the metal-salt of ricinoleate acid etc.
And, can cooperate additives such as the antioxidant that is generally used for vibrin, UV light absorber, photostabilizer, metal inert agents.As antioxidant, can use phenol system, phosphorous acid ester system etc.As phenol system, can exemplify out as diethyl [[3, two (1, the 1-the dimethyl ethyl)-4-hydroxyphenyl of 5-] methyl] phosphonic acid ester, octadecyl-3-(3,5-two-tertiary butyl-4-hydroxyphenyl) propionic ester etc.As phosphorous acid ester, can exemplify out as three (2,4-two-tert-butyl-phenyl) phosphorous acid ester two (2,6-two-tertiary butyl-4-aminomethyl phenyl) tetramethylolmethane-two-phosphorous acid ester etc.
As anti UV agent, can use benzotriazole system, triazine system etc.As benzotriazole be, can exemplify out as 2, [4-(1 for the 2-methylene-bis, 1,3,3-tetramethyl butyl) phenol 6[(2H-benzotriazole-2-yl)]], 2-(2H-benzotriazole-2-yl)-4-(1,1,3,3-tetramethyl butyl) phenol, 2-[5-chloro-2H-benzotriazole-2-yl]-4-methyl-6-(tertiary butyl) phenol etc.As triazine system, can exemplify out as 2-(4,6-biphenyl-1,3,5-triazines-2-yl)-5-[(hexyl) the oxygen base] phenol etc.
As photostabilizer, can use hindered amine system etc.As hindered amine system, can exemplify out as two (2,2,6,6-tetramethyl--4-piperidyl) sebate, poly-[{ 6-(1,1,3, the 3-tetramethyl butyl) ammonia-1,3,5-triazine-2,4-two bases } { (2,2,6,6-tetramethyl--4-piperidyl) imido grpup } cyclohexyl { (2,2,6,6-tetramethyl--4-piperidyl) imido grpup }], dibutylamine 1,3,5-triazine N, N-pair (2,2,6,6-tetramethyl--4-piperidyl-1, the polycondensate of 6-hexamethylenediamine N-(2,2,6,6-tetramethyl--4-piperidyl) butylamine etc.As the metal inert agents, can exemplify out as 2 two [[3-[3,5-two-tertiary butyl-4-hydroxyphenyl] propionyl] propionyl hydrazines of 3-etc.
The masterbatch that uses in the beverage-container of the present invention contains surface-treated alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C), so surface-treated alpha-ferric oxide (B) can be dispersed in well in the vibrin (A) and in the shaping resin, wherein, described surface-treated alpha-ferric oxide (B) is the non-acicular alpha-ferric oxide of median size 0.01～0.06 μ m, aspect ratio 0.2～1.0 to be coated with polyvalent alcohol and organopolysiloxane form.Therefore, beverage-container of the present invention can cover the light of ultraviolet portion.And beverage-container of the present invention is because contain methyne based dye (D), so can cover the following visible part of 500nm.Thus, when using beverage-container of the present invention, even for a long time by irradiate light, content also undergo no deterioration (peculiar smell, variable color), and then, beverage-container of the present invention is because the transparency is good, thus the amount of identification content easily, and, because surface smoothing is good, so the whipability of contents such as good gas shield and beer is arranged.
In addition, when polyvalent alcohol is TriMethylolPropane(TMP) or trimethylolethane, not aggegation of surface-treated alpha-ferric oxide (B), dispersiveness is good especially.
In addition, when organopolysiloxane is dimethicone or methylhydrogenpolysi,oxane, not aggegation of surface-treated alpha-ferric oxide (B), dispersiveness is good especially.
In addition, beverage-container of the present invention is because surface smoothing is good, so can coat equably when his-and-hers watches bread covers carbon element film or silicon fiml.Therefore, gas shield is very high.
Embodiment
Utilize embodiment to specify the present invention, but the invention is not restricted to these embodiment.Among the embodiment, part and % represent weight part and weight % separately.
As shown in table 1 for the material that uses in the present embodiment, alpha-ferric oxide is as shown in table 2, and vibrin is as shown in table 3 with the composition of masterbatch, and the composition of beverage-container etc. are as shown in table 4, and the result of evaluation test is as shown in table 5.
Table 1
| Alpha-ferric oxide | FRO-3, median size 0.03 μ m, aspect ratio 0.9, Sakai chemical industry (strain) |
| Polyvalent alcohol | TriMethylolPropane(TMP) |
| Trimethylolethane | |
| Organopolysiloxane | Methylhydrogenpolysi,oxane |
| Dimethyl polysiloxane | |
| The hydroxycarboxylic acid metal-salt | 12-oxystearic acid calcium, chemistry industry (strain) in big day |
| Methyne based dye (D) | Port リ シ Application ス レ Application Block ラ ウ Application R (C.I. solvent brown 53), Clariant Japan (strain) |
| Other dyestuffs | Sandoplast Red G (C.I. solvent 135), Clariant Japan (strain) Sandoplast Yellow G (C.I. solvent 135), Clariant Japan (strain) |
| Vibrin (A) | ミ Star イ ペ Star ト SA-135 (PET), Mitsui Chemicals (strain) |
Alpha-ferric oxide
Alpha-ferric oxide is pulverized (use fluid: pressurized air), add surface treatment agent simultaneously, obtain ferric oxide-1～2 with micronizer mill.With the untreated ferric oxide-3 of making.Polyvalent alcohol and organopolysiloxane add simultaneously.By using known method, change the processing weight of ferric oxide and the supply concentration or the supply flow rate of treatment agent, make each surface treatment agent can be adjusted into table 2 fixed covering amount.And, be TriMethylolPropane(TMP) to be dispersed in the ethanol use.
Table 2
| The ferric oxide kind | Alpha-ferric oxide | Polyvalent alcohol | Organopolysiloxane | ||
| FRO-3 | TriMethylolPropane(TMP) | Trimethylolethane | Dimethyl polysiloxane | Methylhydrogenpolysi,oxane | |
| Ferric oxide-1 | 100 | 1 | - | - | 0.5 |
| Ferric oxide-2 | 100 | - | 1 | 1 | 0.5 |
| Ferric oxide-3 | 100 | - | - | - | - |
(unit serving)
Masterbatch
At first; with the composition ratio shown in the table 3; ferric oxide, dispersion agent and dyestuff beyond the vibrin are mixed with the high speed flow dynamic formula mixing machine or the mobile vibrating mixer that suspends; obtain intermediate; this intermediate is matched with 4 hours vibrin of 160 ℃ of dryings; mix with high speed flow dynamic formula mixing machine, extrude granulating, obtain masterbatch-1～5 with the single shaft forcing machine.
Table 3
| Vibrin | Alpha-ferric oxide | Dispersion agent | Dyestuff | |||
| The masterbatch name | PET | The ferric oxide kind | 12-oxystearic acid Ca | ポリシンスレ ンブラウンR | Sandoplast Red G | Sandoplast Yellow G |
| Masterbatch-1 | 91.2 | (1)3.5 | 3.5 | 1.8 | - | - |
| Masterbatch-2 | 91.2 | (2)3.5 | 3.5 | 1.8 | - | - |
| Masterbatch-3 | 89.9 | (1)3.5 | 3.5 | 0.5 | 1.8 | 0.8 |
| Masterbatch-4 | 91.2 | (3)3.5 | 3.5 | 1.8 | - | - |
| Masterbatch-5 | 94.7 | (1)3.5 | - | 1.8 | - | - |
(% of unit)
Polyester resin bottle (embodiment 1～3, comparative example 1～5)
With the composition ratio shown in the table 4, with masterbatch-1～5 separately after 4 hours vibrin of 160 ℃ of dryings add to mix, stretch-blow (STRETCH BLOW) forming mill that uses the mechanical society of day smart ASB to make, making capacity are that two of 1000ml extend bottles (weight 42g).
Table 4
| Bottle | PET | The masterbatch kind |
| Embodiment-1 | 100 | (1)10 |
| Embodiment-2 | 100 | (2)10 |
| Embodiment-3 | 100 | (3)10 |
| Comparative example-1 | 100 | (4)10 |
| Comparative example-2 | 100 | (1)7 |
| Comparative example-3 | 100 | (3)5 |
| Comparative example-4 | 100 | (5)10 |
| Comparative example-5 | 100 | - |
(unit serving)
Estimate
(1) the light perviousness and the transparency of shaping thing
Downcut as sample in the place that bottle main part 0.3mm is thick, carries out following evaluation test.
Light penetration: contain 4 kinds of wavelength 380,500,550, in the wavelength region may of 650nm and 200nm～700nm, as blank (100%), the UV-265FW that makes with Shimadzu Seisakusho Ltd. measures with air.The transparency: as blank (0), the hard instrument of transmission mist (ヘ イ ズ ガ one De プ ラ ス) that uses Bi Ke chemistry Japanese firm to make is measured with air.The value of the shaping thing of making of shaping resin only is roughly about 1.The transparency is high, be worth lowly, and opacity is high, the value height.Haze value opacity more than 15 is remarkable, can determine with visual.
Below the A:4
Below the B:10
C: bigger than 10
(2) surface smoothing
Downcut the thick place of bottle main part 0.3mm as sample, estimate the surface smoothing of bottle inner face.
The evaluation of the surface smoothing of bottle inner face: use AFM (manufacturing of Seiko Instruments company) to carry out surface observation, measure the highest rising height in the poorest visual field, use following benchmark evaluation.The surface smoothing of bottle inner face is relevant with the dispersing of pigments of interpolation, shaggy words, and not only covering property is poor, and is also influential to whipabilitys such as content such as beer.
A: less than 0.5 μ m
B: less than 1 μ m
More than the C:1 μ m
(3) taste suitability
Sensory testing: the bottle that injects beer is implemented irradiate light promote test.Irradiate light promotes test to be to use xenon lamp as light source, from the bottle side-irradiation after 8 hours, by the group member of specialty from sensuously estimating the generation of light deterioration material.
A: whole 5 group members do not feel light deterioration material
The above group member of B:1 name has felt light deterioration material
C: whole 5 group members have felt light deterioration material
Table 5
| Light penetration | The transparency | Surface smoothing | Taste is fit to test | ||||
| 380nm | 500nm | 550nm | 650nm | The Haze value | |||
| Embodiment-1 | 0.1 below | 0.7 | 1 | 65 | A | A | A |
| Embodiment-2 | 0.1 below | 0.7 | 1 | 67 | A | A | A |
| Embodiment-3 | 0.1 below | 1 | 1.4 | 67 | A | A | A |
| Comparative example-1 | 0.1 below | 0.6 | 1.1 | 60 | C | C | A |
| Comparative example-2 | 0.7 | 1.4 | 2.7 | 70 | A | A | B |
| Comparative example-3 | 0.8 | 4.2 | 5.4 | 74 | A | A | C |
| Comparative example-4 | 0.1 below | 0.7 | 1.3 | 60 | C | C | A |
| Comparative example-5 | 83 | 86 | 87 | 88 | A | A | C |
And in embodiment 1 and 2, the light penetration of 200～500nm is below 0.7%, and the light penetration of 500～550nm is below 1%.Among the embodiment 3, the light penetration of 200～500nm is below 1%, and the light penetration of 500～550nm is below 1.4%.And in embodiment 1～3, the light penetration of 650～700nm is more than 50%.
Industrial application
Beverage-container of the present invention preferably covers the luminous ray of a part, so that the storage stability of content is effective by high UV-preventing, in addition, identification with high transparent, content, but simultaneously also lightweight are so can replace vial.
Claims (12)
1. beverage-container, it contains the beverage-container that the painted shaping resin of shaping resin and masterbatch is shaped for use, it is characterized in that, masterbatch contains vibrin (A), surface-treated alpha-ferric oxide (B), hydroxycarboxylic acid metal-salt (C) and methyne based dye (D), wherein, the surface-treated alpha-ferric oxide is that to coat median size with polyvalent alcohol and organopolysiloxane be that 0.01～0.06 μ m, aspect ratio are that 0.2～1.0 non-acicular alpha-ferric oxide forms, and it is part below 1% that this beverage-container has the following light penetration of 500nm.
2. beverage-container according to claim 1 is characterized in that, painted shaping resin is that thickness is below the above 0.5mm of 0.2mm, and the following light penetration of 500nm is the resin below 1%.
3. beverage-container according to claim 1 and 2 is characterized in that, it is part below 1.5% that beverage-container has the following light penetration of 550nm.
4. according to each described beverage-container of claim 1～3, it is characterized in that painted shaping resin is that thickness is below the above 0.5mm of 0.2mm, the following light penetration of 550nm is the resin below 1.5%.
5. according to each described beverage-container of claim 1～4, it is characterized in that it is part more than 50% that beverage-container has the above light penetration of 650nm.
6. according to each described beverage-container of claim 1～5, it is characterized in that shaping resin is a polyester based resin.
7. according to each described beverage-container of claim 1～6, it is characterized in that, with respect to the total amount of surface-treated alpha-ferric oxide (B), polyvalent alcohol or organopolysiloxane 0.01～10 weight % that respectively does for oneself.
8. according to each described beverage-container of claim 1～7, it is characterized in that polyvalent alcohol is TriMethylolPropane(TMP) or trimethylolethane.
9. according to each described beverage-container of claim 1～8, it is characterized in that organopolysiloxane is dimethyl polysiloxane or methylhydrogenpolysi,oxane.
10. according to each described beverage-container of claim 1～9, it is characterized in that hydroxycarboxylic acid metal-salt (C) is a 12-oxystearic acid calcium.
11., it is characterized in that methyne based dye (D) is a C.I. solvent brown 53 according to each described beverage-container of claim 1～10.
12. according to each described beverage-container of claim 1～11, it is characterized in that, total weight with respect to surface-treated alpha-ferric oxide (B) and hydroxycarboxylic acid metal-salt (C), the cooperation ratio of using is that surface-treated alpha-ferric oxide (B) is 30～60 weight %, and hydroxycarboxylic acid metal-salt (C) is 40～70 weight %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP125250/2005 | 2005-04-22 | ||
| JP2005125250A JP4683991B2 (en) | 2005-04-22 | 2005-04-22 | Beverage container |
| PCT/JP2006/308450 WO2006115216A1 (en) | 2005-04-22 | 2006-04-21 | Beverage container |
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| Publication Number | Publication Date |
|---|---|
| CN101163742A true CN101163742A (en) | 2008-04-16 |
| CN101163742B CN101163742B (en) | 2012-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200680013344XA Expired - Fee Related CN101163742B (en) | 2005-04-22 | 2006-04-21 | Beverage container |
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|---|---|
| JP (1) | JP4683991B2 (en) |
| CN (1) | CN101163742B (en) |
| WO (1) | WO2006115216A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102695653A (en) * | 2009-11-03 | 2012-09-26 | 嘉士伯酿酒有限公司 | Preventing the generation of MBT in a hops based beverage |
| CN102695654A (en) * | 2009-11-03 | 2012-09-26 | 嘉士伯酿酒有限公司 | Eliminating the generation of MBT in a hops based beverage |
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| JP5308039B2 (en) | 2007-02-20 | 2013-10-09 | 富士フイルム株式会社 | Polymer materials containing UV absorbers |
| JP2009067983A (en) | 2007-03-30 | 2009-04-02 | Fujifilm Corp | Ultraviolet absorbing agent composition |
| WO2009022736A1 (en) | 2007-08-16 | 2009-02-19 | Fujifilm Corporation | Heterocyclic compound, ultraviolet ray absorbent, and composition comprising the ultraviolet ray absorbent |
| JP5167472B2 (en) * | 2007-11-21 | 2013-03-21 | 北海製罐株式会社 | Inner coated polyethylene container |
| JP5244437B2 (en) | 2008-03-31 | 2013-07-24 | 富士フイルム株式会社 | UV absorber composition |
| JP5250289B2 (en) | 2008-03-31 | 2013-07-31 | 富士フイルム株式会社 | UV absorber composition |
| JP2009270062A (en) | 2008-05-09 | 2009-11-19 | Fujifilm Corp | Ultraviolet absorbent composition |
| JP5793371B2 (en) * | 2011-08-23 | 2015-10-14 | 株式会社初田製作所 | Fire extinguisher storage container and fire extinguisher equipped with the same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6022920A (en) * | 1998-01-23 | 2000-02-08 | Eastman Chemical Company | Method for the production of clear bottles having improved reheat |
| JP4862977B2 (en) * | 2000-09-14 | 2012-01-25 | 戸田工業株式会社 | Fine green pigment, paint and resin composition using the fine green pigment |
| JP3781033B2 (en) * | 2003-08-01 | 2006-05-31 | 東洋インキ製造株式会社 | Colorant for thermoplastic resin and use thereof |
| JP3826933B2 (en) * | 2003-10-24 | 2006-09-27 | 東洋インキ製造株式会社 | Colorant for thermoplastic resin and use thereof |
-
2005
- 2005-04-22 JP JP2005125250A patent/JP4683991B2/en not_active Expired - Fee Related
-
2006
- 2006-04-21 WO PCT/JP2006/308450 patent/WO2006115216A1/en active Application Filing
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102695653A (en) * | 2009-11-03 | 2012-09-26 | 嘉士伯酿酒有限公司 | Preventing the generation of MBT in a hops based beverage |
| CN102695654A (en) * | 2009-11-03 | 2012-09-26 | 嘉士伯酿酒有限公司 | Eliminating the generation of MBT in a hops based beverage |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006115216A1 (en) | 2006-11-02 |
| JP2006298456A (en) | 2006-11-02 |
| JP4683991B2 (en) | 2011-05-18 |
| CN101163742B (en) | 2012-06-13 |
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