CN101154544B

CN101154544B - Filter plate with anti-electromagnetic radiation and optical filtering function of plasma display

Info

Publication number: CN101154544B
Application number: CN2006100219527A
Authority: CN
Inventors: 甘国工
Original assignee: Individual
Current assignee: Individual
Priority date: 2006-09-27
Filing date: 2006-09-27
Publication date: 2011-04-13
Anticipated expiration: 2026-09-27
Also published as: CN101154544A

Abstract

The invention provides a light filter plate having anti-electromagnetic radiation and light filtering functions for a plasma display panel (PDP), comprising a glass substrate wherein, one side is plated with a plating layer having anti-electromagnetic radiation and light filtering function by continuous magnetron sputtering method; the plating layer is compounded with plastic film layer which can prevent the oxidation corrosion of the plating layer and is provided with an anti-reflection film layer on the surface and metallic film which contacts the plating layer and leads out the electrode; the plating layer is of compounded thirteen layers or seventeen layers plated repeatedly by film systems such as TiO2/AZOY or ITO/Ag/AZOY or ITO/TiO2; the other side of the glass substrate is compounded with a plastic film layer which has an anti-reflection function. The light filtering plate of the invention has greatly reduced costs, high working efficiency, high luminousness, anti-electromagnetic radiation and light filtering functions and long service life.

Description

The filter with anti-electromagnetic radiation and filtering functions of plasma scope

Technical field:

The present invention is relevant with the filter in the display device, and is special relevant with the filter with anti-electromagnetic radiation and filtering functions in the plasma scope (PDP).

Background technology:

The antireflection of present PDP filter and anti-electromagnetic radiation and filtering functions are to form like this: the outer surface at a sheet glass is pasted the plastic film that is coated with the antireflection rete, pastes the anti-electromagnetic radiation that formed by two layers of plastics and the diaphragm of filtering functions at another side.Wherein one deck is to adopt photoetch method or woven wire wiring method to make the metallic conduction grid on diaphragm to form the anti-electromagnetic radiation function.Have the method that adopts brushing pigment film to form rete or paste on the film of metal wire or wire mesh grid at this layer, form the function of anti-electromagnetic radiation and optical filtering by this two membranes with infrared light optical attenuation plastic film.Because lamination lamination composite methods, various functional membranes are on each tunic sheet, attaching process and combination process require high, be difficult for mechanization and produce continuously, and the cost height, rate of finished products is low, production efficiency is low, and light transmittance is low.

The name of publication number CN1509490A is called the plasma display panel filter and discloses lamination and the various antireflections of lamination (AR) film on transparent substrate, near-infrared (NIR) screened film and electromagnetic interference (EMI) screened film, this functional membrane is the crux film that filter needs, they are that the difference plated film is on plastic basis material or plastic film, need lamination in layer by function again and be stacked on the transparent substrate, transparent substrate is to place being overrided to form of adhesive layer between the resin bed by at least two glassy layers and at least one.

This plated film respectively, the shaping manufacture method of lamination does not still have the essence progress with preceding method again, and still efficient is low, rate of finished products is low, cost is high.Particularly multi-level lamination lamination, the residual volatile matter of the solvent that steam bubble between the lamination and binding agent may exist greatly reduces rate of finished products.

Number of patent application is 200410069275.7; name is called laminated body and uses the filter of display of this laminated body to disclose; in the screened film of the crux functional membrane electromagnetic interference (EMI) that filter needs most, how to solve the anti-oxidant or erosion problem of silver film in the EMI screened film; in this application, erosion is called the cohesion of the silver atoms of silver-colored thin layer; the silver-colored thin layer that shows as that corrodes produces " white point "; this application is also promptly increasing by a protective layer on the superficial layer at three layers of silver-colored thin layer on for the film of the anti-reflection transparent high index of refraction that must have on the crux thin layer of the anti-electromagnetic interference silver thin layer, and this protective layer is made up of the adhesive material and the inorganic fine particles of polymer.

Inorganic fine particles is to adopt the silicon dioxide of metal oxide such as its recommendation, tin oxide, zinc oxide, indium oxide, antimonous oxide, aluminium oxide, zirconia etc., more preferential selective oxidation antimony tin monoxide composite oxides, antimony oxide one zinc oxide composite oxides.

Adhesive and inorganic fine particles are by solvent or solution dissolved adhesive; and dispersion inorganic fine particles; be coated on the rete of forming by silver-colored thin layer and anti-reflection high refractive index film layer with rubbing method; be actually and be coated on the high refractive index film layer; and finally forming protective layer, this application claims to forming " white point " obviously surprised inhibitory action is arranged.

This metal oxide of solvent or solution coat formation and the thin layer of binding agent combination of utilizing; say with regard to technical process and to relate to environmental issue and pollution; wayward with regard to film forming thickness and visible light transmissivity; and can't the testing product qualification rate on production line; can not control and qualification rate low; the rete fastness is not enough; and rete is the most surperficial; survey surface resistivity on the protection aspect, participate in combination because of macromolecule resin is arranged, surface resistivity is higher than not increasing this protective layer on the contrary; the EMI function of shielding is descended; for the film layer structure of three layers of silver, solved so-called " white point " problem, but reduced the EMI screening ability of three layers of silver.The document has been talked about the method for controlling that suppresses silver-colored thin layer is corroded or claims to reduce " white point "; but be coated with this layer protective layer owing to only adopt on the transparent high refractive index film layer of the superficial layer of three layers of silver-colored structural film layer; to the effect of EMI screened film not enough, surface resistivity preferably can only reach 2 Ω/cm ²Also do not reach the standard of household electrical appliance less than 1.5 Ω/cm2, this application does not have method or scheme being divided into report or the prompting that increases the metal-oxide film layer between three layers (if four layers of silver-colored film layer structure should have four layers) between every layer of silver-colored thin layer and the transparent high refractive index film layer, more do not utilize the continuous magnetron sputtering method plate these three layers or four layers of metal oxide such as ITO (indium tin oxide) or AZOY (aluminium, zinc oxide) film and with all the other ITO or AZOY/Ag/TiO ₂Film organically combines and improves visible light transmittance rate, improves the anti-oxidant corrosion resistance of coatings and improves the EMI screening ability, simultaneously near infrared light, far red light, ultraviolet light has been stopped the report and the prompting of filtering functions.

The patent documentation of number of patent application 01804419.0, a kind of display filter is disclosed, this filter is a lamination transparency conducting layer (D) on the one or both sides of macromolecule membrane (B), transparency conducting layer is that combination (Dt)/(DM) with high refractive index transparent thin layer (Dt) and metal film layer (MD) is as repetitive, carry out lamination 2-4 times repeatedly, lamination high refractive index transparent thin layer (Dt) and constituting thereon more also discloses one deck at least in this high refractive index transparent thin layer (Dt) by with indium, more than one of tin and zinc are that the oxide of main component forms.The one deck at least that also discloses in a plurality of metal film layers (DM) is formed by silver or silver alloy.Also disclosing in the close air side of macromolecule membrane (B) also promptly watches face to be shaped on the scheme of individual layer antireflection film layer.Also open and clear conductive layer (D) has the sheet resistance of 0.01-30 Ω/, even but film 7 tunics of 2-4 repetitions of the Dt/DM film of in fact disclosed lamination, so long as adopt the mode of plated film lamination to form transparent conductive film, its sheet resistance is all at 2.2 Ω/more than the, most at 5 Ω/more than the, do not reach the standard that domestic TV is lower than 1.5 Ω/, be actually and come into operation.Even the method by its patent disclosure can be used, in fact this so-called transparency conducting layer (D) EM1 interfere wave shielding net of remaining the compound copper coin of the disclosed etching of front several patents of employing or adopting the wire cloth network method to form, this layer net do not possess the function of absorption or block ultraviolet, near infrared light, far red light simultaneously.The scheme of this patent disclosure is to be exclusively used in the macromolecule membrane that sticks on the scope face.

This patent does not have open and enlightenment is main rete with silver, TiO of lamination one deck high index of refraction on it ₂Rete is at silver layer and TiO ₂Between the metal oxide rete of special lamination layer of transparent, utilize this one deck metal oxide self anti-aging capability to stablize the protection that increases silver layer, utilizing this tunic simultaneously is that the nanoscale film has special absorbability to infrared waves, with silver layer and TiO ₂Common absorption and the blocking capability that improves ultraviolet light, near infrared light, far red light in rete combination back.This patent is not open based on silver layer yet, at the symmetrical lamination metal oxide film layer/TiO of its both sides difference ₂5 layers of structure, by these 5 layers of structures can form cleverly 3 to 4 groups repetition and form 13 layers or 17 tunic structures, finally realize that by 13 layers and 17 tunics the sheet resistance of 1.5 Ω/below the reaches the filtering functions to ultraviolet light, near infrared light.

Summary of the invention:

The objective of the invention is in order to overcome above deficiency, but provide the method for the continuous magnetically controlled sputter method plated film of a kind of employing large tracts of land, can reduce cost greatly, the production efficiency height, the intensity height, the light transmittance height, anti-electromagnetic radiation and filter effect are good, the filter with anti-electromagnetic radiation and filtering functions of long service life.

The object of the present invention is achieved like this:

Filter of the present invention, comprise glass substrate, the coatings that anti-electromagnetic radiation and filtering functions are arranged that the method that adopts continuous magnetron sputtering plates in the one side of glass substrate, there is the plastic membranous layer of anti-reflection function rete on the surface that is compounded with prevention coatings oxidation or erosion on coatings, be compounded with plastic membranous layer with anti-reflection function rete at the glass substrate another side, the metallic film as extraction electrode that contacts with coatings, coatings are by three groups or four groups of TiO ₂/ AZOY/Ag/AZOY/TiO ₂Or TiO ₂/ ITO/Ag/AZOY/TiO ₂Or TiO ₂/ ITO/Ag/ITO/TiO ₂Or TiO ₂/ AZOY/Ag/ITO/TiO ₂13 layers or the 17 tunic layer structure repeating to form of such film system, wherein AZOY is the oxide membranous layer that zinc oxide and alumina doped material are formed, ITO is the rete that the tin-doped indium oxide material is formed, and the structure of plating 13 tunic layers is on glass substrate: the ground floor rete is TiO ₂, second layer rete is AZOY or ITO, and the trilamellar membrane layer is Ag, and the 4th tunic layer is AZOY or ITO, and the layer 5 rete is TiO ₂, the layer 6 rete is AZOY or ITO, and the layer 7 rete is Ag, and the 8th tunic layer is AZOY or ITO, and the 9th tunic layer is TiO ₂, the tenth tunic layer is AZOY or ITO, and the eleventh floor rete is Ag, and the Floor 12 rete is AZOY or ITO, and the tenth trilamellar membrane layer is TiO ₂, the structure of plating 17 tunic layers is on glass substrate: the ground floor rete is TiO ₂, second layer rete is AZOY or ITO, and the trilamellar membrane layer is Ag, and the 4th tunic layer is AZOY or ITO, and the layer 5 rete is TiO ₂, the layer 6 rete is AZOY or ITO, and the layer 7 rete is Ag, and the 8th tunic layer is AZOY or ITO, and the 9th tunic layer is TiO ₂, the tenth tunic layer is AZOY or ITO, and the eleventh floor rete is Ag, and the Floor 12 rete is AZOY or ITO, and the tenth trilamellar membrane layer is TiO ₂, the 14 tunic layer is AZOY or ITO, and the 15 tunic layer is Ag, and the 16 tunic layer is AZOY or ITO, and the 17 tunic layer is TiO ₂, be compounded with the plastic membranous layer that the surface has the anti-reflection function rete at the glass substrate another side.Plastic membranous layer can adopt light transmittance to be higher than 85% even 90% the plastic film that can stop coatings oxidation or erosion; this diaphragm not only can prevent and delay the erosion and the performance degradation of electromagnetic interference (EMI) shielding coatings; can also be used to preventing the glass substrate fragmentation of pasting; adopt high-intensity plastic film the glass impact resistance can be improved; make it to become safety glass; be not only a good filter of performance; become the PDP display protection simultaneously, particularly use the continuous magnetron sputtering method at Ag coating and TiO ₂One deck ITO or AZOY metal oxide layer have been plated between the coating, make Ag coating increase anti-oxidant and erosiveness, solve so-called " white point " problem,, on the contrary coatings surface resistivity≤1.5 Ω/cm2 there is not contribution because of this layer plated film that repeats three groups or four groups reduces the filter overall light transmittance requirement.And the production efficiency height, coating process is unified, convenient, and cost is low.All be compounded with plastic membranous layer on the glass substrate two sides, further protected glass substrate with anti-reflection function rete.Anti-reflection function rete on the plastic membranous layer can adopt magnetically controlled sputter method plated film or sol-gel process compound.

Each tunic layer thickness in the above-mentioned coatings with 13 layers or 17 layers structure is following thickness range: TiO ₂Be 10～150nm (nanometer), AZOY or ITO are 1.0～30nm (nanometer), and Ag is 5～30nm (nanometer), and AZOY or ITO are 1.0～30nm (nanometer), TiO ₂Be 10～200nm (nanometer), AZOY or ITO are 1.0～30nm (nanometer), and Ag is 5～30nm (nanometer), and AZOY or ITO are 1.0～30nm (nanometer), TiO ₂Be 10～200nm (nanometer), AZOY or ITO are 1.0～30nm (nanometer), and Ag is 5～30nm (nanometer), and AZOY or ITO are 1.0～30nm (nanometer), TiO ₂Be 10～200nm (nanometer), AZOY or ITO are 1.0～30nm (nanometer), and Ag is 5～30nm (nanometer), and AZOY or ITO are 1.0～30nm (nanometer), TiO ₂Be 10～150nm (nanometer).

Above-mentioned metallic film is to coat around the glass substrate and by conducting resinl on the metallic film and coatings bonding to be composited, or the metallic conduction binding agent is by being composited with the coatings bonding around the printing curing coating glass substrate, metallic film not only can be contacted EMI shielding coatings and be the U type coat the substrate edge or only in EMI shielding plated film face surrounding along stickup, metallic film shields the electromagnetic radiation of coatings shielding under stopping as extraction electrode with EMI and passes to display until ground connection.Metallic film also can be with solidifying to form after the printing of conducting metal binding agent, with compound the comparing that bond with metallic film higher automation efficient is arranged, can reducing cost bonding and more firm to the sealing of EMI coating.

Above-mentioned surface has two plastic membranous layers of anti-reflection function rete and pastes compound with coatings and glass substrate respectively by adhesive layer, reflectivity＜3% of the visible light section of filter behind the compound plastic membranous layer, the reflectivity of filter is also less than 6% behind compound two plastic membranous layers.

Plastic membranous layer is pasted compound by adhesive layer and coatings, plastic film self also can bond compoundly for one becomes filter because of needs become adhesive layer and other substrate, also can be bonded as one with the PDP display panel and makes display thinner.

Above-mentioned plastic membranous layer is polyester film or the polycarbonate membrane or the polyvinyl butyral film of biaxial tension, add blue pigment in the binding agent to regulate and the yellow characteristic light of the 596nm (nanometer) that the decay display sends, add at least a in purple, redness, the black pigment to regulate the colour temperature and the light transmittance of display.Plastic membranous layer is the polyester film (BOPET) of biaxial tension, also can be polycarbonate membrane (PC film), polyvinyl butyral resin (PVB) film or polyester film (PET film).Add blueness in the binding agent and can regulate and decay the 596nm yellow characteristic light and make redness more bright-coloured, also can add other pigment such as purple and/or redness and/or black pigment to regulate the colour temperature and the visible light transmissivity of display.Also can in binding agent, add ultra-violet absorber and antioxidant increase ageing resistance because of needs.

The anti-reflection function rete is at least by SiO on the above-mentioned plastic membranous layer ₂With Nb ₂O ₅, or SiO ₂With TiO ₂Two layers of composition.Also can be by SiO ₂/ Nb ₂O ₅Or TiO ₂/ SiO ₂/ Nb ₂O ₅Or TiO ₂Four tunics are formed, and paste the plastic film that is coated with the AR film on EMI shielding plated film face, and the visible light that filter is seen through has higher transmitance, improves the brightness of display.Also can be coated with anti-electromagnetic radiation and filtering functions coating and paste thereon be coated with the AR film this one side of plastic film as watching face, not only play EMI shielding action and filter action, can also resist reflection of ambient light, the raising viewing quality.

Above-mentioned filter compound prevention coatings oxidation or plastic membranous layer of erosion on the coatings of glass substrate are binding agents, at least the blue pigment that has added the yellow characteristic light of the 596nm (nanometer) that the colour temperature of regulating display and decay display send therein, this substrate and the other substrate formation filter that is bonded to one.Utilizing plastic membranous layer is adhesive layer, can fit having the glass substrate of EMI function of shielding and filtering functions and other glass substrate, plastic substrate easily, has multi-purpose filter and become.

This above-mentioned filter by with the compound prevention coatings oxidation of coatings or the plastic membranous layer of erosion, this plastic membranous layer is regulated the pigment and the ultra-violet absorber of colour temperature as binding agent and adding, direct and plasma display panel is pasted and is one, and the attenuate display thickness improves side wide-angle viewing quality more.

The surface resistivity of above-mentioned coatings≤1.5 Ω/cm ²(also together with Ω/ unit representation).

The glass substrate of above-mentioned filter is half tempered glass or the toughened glass that adopts chemical method or physical method to handle; increase its intensity; add and paste compound with high-intensity plastic film; add the anti-electromagnetic radiation and the filtering functions of existing EMI coatings, possess the function of filter and protection screen simultaneously.

Above-mentioned filter is watched face at display, and less than 75%, the light transmittance during infrared light 850nm is less than 18% greater than 30% for the light transmittance when measuring filter visible light 380～780nm, and the light transmittance of 950nm leaf is less than 10%.

The present invention is ITO rete or AZOY rete at the bottom of Ag layer; topped on the face of Ag layer also is ITO rete or AZOY rete; the easier control on coating process of ITO rete of the present invention or AZOY rete; so the present invention not only technology controls easily; the rate of finished products height; optical index is also stable; light transmittance is better; rete can be thicker; protection and oxygen barrier ability to the Ag layer are higher; the more important thing is on the two sides of Ag layer it is ITO and/or AZOY; that is to say symmetrical rete; this filter two sides can be assembled with the PDP display; and play EMI shielding and ultraviolet light wave, and near infrared light involves the filtering function of far infrared light wave, and thickness is designed to symmetry in addition; equipment during plated film is as long as satisfy four layers of coating process that can carry out single Ag; just can obtain the repetition film layer structure of 3 silver medals or 4 silver medals easily, and make things convenient for plated film, save equipment investment by repeating the plated film mode.

Filter of the present invention is composited with the metallic film stickup as extraction electrode that has the plastic membranous layer that stops coatings oxidation and erosion and contact with the EMI coatings by the coated glass or the glass substrate of plating EMI shielding coatings, becomes the most basic filter of PDP display.Utilize the plastic film that pastes to plate the AR film thereon, increase the filter visible light transmissivity, reduce visible reflectance, and the pad pasting face is assembled use in the face of spectators, and make glass become safety glass in the face of spectators.Be compounded with the plastic membranous layer that is coated with the AR film at the substrate another side, it faced watch the face also can antireflection, particularly anti-environment improves the picture quality of watching to the light reflection of screen.This coatings has solved the filtration difficult problem of EMI shielding that the lamination of multilayer functional membrane stack in the past could solve and ultraviolet light, near infrared light, far red light, and the production efficiency height, cost is low, the life-span is long, performance is more perfect.

Filter cost of the present invention is low, the production efficiency height, and the intensity height, the light transmittance height, anti-electromagnetic radiation and filter effect are good, long service life.

Description of drawings:

Fig. 1 is a structural representation of the present invention.

Fig. 2 is three layers of repetitive structure schematic diagram of anti-electromagnetic radiation coatings.

Fig. 3 is for involving near-infrared, far infrared, ultraviolet shielding and filtration and visible light transmittance rate curve chart to electromagnetism.

Fig. 4 is the anti-reflection film structure schematic diagram.

Fig. 5 is reflectivity (R%) curve chart of anti-reflective film (AR film).

Fig. 6 is the present invention's structural representation again.

Embodiment:

Embodiment 1:

Fig. 1 has provided present embodiment 1 figure.Mix and see Fig. 1, glass substrate 1 enters the three silverskin system (also can be four silverskin systems) that plates in the continuous magnetron sputtering film production line as shown in Figure 2, promptly by TiO after washed with de-ionized water ₂/ ITO or AZOY/Ag/ITO or AZOY/TiO ₂13 tunics (the adjacent TiO of adjacent structure layer that repetitive structure is formed ₂Layer coincidence) the anti-electromagnetic radiation and the coatings of filtering functions (being EMI shielding coatings) 2, TiO wherein ₂Adopt the method preparation of twin intermediate frequency reaction magnetocontrol sputtering, and Ag and ITO or AZOY adopt plane direct current magnetron sputtering to be equipped with.AZOY is the oxide membranous layer that zinc oxide and aluminum oxide dopant material are formed, this ZnO and Al ₂O ₃The target that material is formed is the open and ripe target that uses of Germany " GfE Metalle und MaterralienGmbH " company, ZnO and Al ₂O ₃Account for 99.95% of material, it and ITO rete relatively have similar performance, and higher light transmittance is arranged under the same thickness situation.With the DC pulse magnetron sputtering convenient controlled film lamination process conditions are arranged, material cost saves 3/4 than ITO, and using value is preferably arranged.If at three layers of TiO ₂/ ITO or AZOY/Ag/ITO or AZOY/TiO ₂Repetitive structure rete (i.e. three silver medals) is gone up increases TiO ₂/ ITO or AZOY/Ag/ITO or AZOY/TiO ₂Rete i.e. four layers of composite construction (i.e. four silver medals), becomes 17 layers at last, and various performance index are more guaranteed, and particularly surface resistivity can be by≤1.5 Ω/cm ²Drop to≤1.3 Ω/cm ²Below.The performance of the EMI barrier film layer of producing as shown in Figure 3, the light transmittance of visible light should be greater than 75%, and should descend rapidly in the near-infrared section, in 596 nanometers also is that the yellow characteristic light section that the display neon sends produces absorption because of adding blue pigment, light transmittance has a low peak valley, has only 30% light transmittance approximately.Surface resistance R=1.3 ± 0.02 Ω/cm ², sheet resistance is more little, and the ability of anti-electromagnetic radiation is strong more.Paste the last layer light transmittances on the surface of EMI shielding coatings 2 by acrylate adhesives layer 3 and be higher than the plastic film 4 that 85% the polyester film (BOPET film) with the biaxial tension that stops coatings oxidation and erosion is made.After sticking plastic membranous layer and adding blue pigment and regulate the pigment of colour temperature, can satisfy light transmittance greater than 30% less than 75% index.Paste with conducting resinl 7 and EMI shields that coatings contacts and as the metallic film (paillon foil) 5 of extraction electrode in the about 10mm part of the substrate face that is coated with EMI barrier film layer hem width around it.According to this filter EMI film whether towards PDP display 8, metallic film (paillon foil) not only can be contacted EMI shielding coatings and be the U type coat the substrate edge or only in EMI shielding plated film aspect surrounding along stickup.Be the U type and coat the substrate edge, can make this filter only as anti-electromagnetic radiation and filtering functions use the time, the filter two sides can make things convenient for installed surface to the PDP display.Another side at plastic film and substrate adopts twin intermediate frequency reaction magnetocontrol sputtering method to plate anti-reflection function (AR) rete 6 respectively.The structure of anti-reflection function rete as shown in Figure 4, by SiO ₂/ Nb ₂O ₅Or TiO ₂The four-layer structure of forming.The performance of the AR rete of producing, its reflectivity curve superpose the back reflection rate also less than 3% in reflectivity R＜0.5%, two aspect of visible light section as shown in Figure 5, and this embodiment has utilized TiO ₂/ ITO or AZOY/Ag/ITO or AZOY/TiO ₂The rete of continuous magnetron sputtering method plating of three layers or four layers repetitive structure, not only rete is firm, the visible light transmissivity height satisfies household electrical appliances anti-electromagnetic radiation standard, surface resistivity is less than 1.5 Ω/cm ², production efficiency height, rate of finished products height, cost are low, also because of watching face to increase the antireflection coatings, improved picture quality, and more important is to have improved the useful life that EMI shields coatings.

The present embodiment i.e. thickness of 13 layers or 14 layers EMI screened film is mixed several as following table:

Film material (13 layers)	Thickness (nm)	Film material (17 layers)	Thickness (nm)
				Substrate	?	Substrate	?
TiO ₂	25?	TiO ₂	30?
				ITO or AZOY	5?	ITO or AZOY	4?
Ag?	18?	Ag?	15?
				ITO or AZOY	5?	ITO or AZOY	4?
TiO ₂	50?	TiO ₂	60?

ITO or AZOY	5?	ITO or AZOY	4?
				Ag?	18?	Ag?	15?
ITO or AZOY	5?	ITO or AZOY	4?
				TiO ₂	50?	TiO ₂	60?
ITO or AZOY	5?	ITO or AZOY	4?
				Ag?	20?	Ag?	17?
ITO or AZOY	5?	ITO or AZOY	4?
				TiO ₂	25?	TiO ₂	60?
?	?	ITO or AZOY	4?
				?	?	Ag?	17?
?	?	ITO or AZOY	4?
				?	?	TiO ₂	30?

Embodiment 2:

Fig. 6 has provided the structural representation of present embodiment 2.Mix and see Fig. 6, the glass substrate 1 of EMI shielding coatings will be coated with, utilize acrylate adhesives 3 and PDP display panel to be bonded as one, another side (watching face) at substrate 1 is pasted the BOPET plastic film 4 that is coated with AR film 6, attenuate display thickness, the plastic film to PDP display panel one side of the foregoing description has been changed to binding agent, the function that prevents oxidation of EMI screened film and erosion has still been arranged.

The various embodiments described above are that foregoing of the present invention is further described, but this should be interpreted as that the scope of the above-mentioned theme of the present invention only limits to the foregoing description.All technology that realizes based on foregoing all belong to scope of the present invention.

Claims

1. the filter with anti-electromagnetic radiation and filtering functions of a plasma scope, it is characterized in that comprising glass substrate, the coatings that anti-electromagnetic radiation and filtering functions are arranged that the method that adopts continuous magnetron sputtering plates in the one side of glass substrate, there is the plastic membranous layer of anti-reflection function rete on the surface that is compounded with prevention coatings oxidation or erosion on coatings, the metallic film as extraction electrode that contacts with coatings, coatings are by three groups or four groups of TiO ₂/ AZOY/Ag/AZOY/TiO ₂Or TiO ₂/ ITO/Ag/AZOY/TiO ₂Or TiO ₂/ ITO/Ag/ITO/TiO ₂Or TiO ₂/ AZOY/Ag/ITO/TiO ₂13 layers or the 17 tunic layer structure repeating to form of such film system, wherein AZOY is the oxide membranous layer that zinc oxide and alumina doped material are formed, ITO is the rete that the tin-doped indium oxide material is formed, and the structure of plating 13 tunic layers is on glass substrate: the ground floor rete is TiO ₂, second layer rete is AZOY or ITO, and the trilamellar membrane layer is Ag, and the 4th tunic layer is AZOY or ITO, and the layer 5 rete is TiO ₂, the layer 6 rete is AZOY or ITO, and the layer 7 rete is Ag, and the 8th tunic layer is AZOY or ITO, and the 9th tunic layer is TiO ₂, the tenth tunic layer is AZOY or ITO, and the eleventh floor rete is Ag, and the Floor 12 rete is AZOY or ITO, and the tenth trilamellar membrane layer is TiO ₂, the structure of plating 17 tunic layers is on glass substrate: the ground floor rete is TiO ₂, second layer rete is AZOY or ITO, and the trilamellar membrane layer is Ag, and the 4th tunic layer is AZOY or ITO, and the layer 5 rete is TiO ₂, the layer 6 rete is AZOY or ITO, and the layer 7 rete is Ag, and the 8th tunic layer is AZOY or ITO, and the 9th tunic layer is TiO ₂, the tenth tunic layer is AZOY or ITO, and the eleventh floor rete is Ag, and the Floor 12 rete is AZOY or ITO, and the tenth trilamellar membrane layer is TiO ₂, the 14 tunic layer is AZOY or ITO, and the 15 tunic layer is Ag, and the 16 tunic layer is AZOY or ITO, and the 17 tunic layer is TiO ₂, be compounded with the plastic membranous layer that the surface has the anti-reflection function rete at the glass substrate another side.

2. the filter with anti-electromagnetic radiation and filtering functions of plasma scope as claimed in claim 1, each the tunic layer thickness that it is characterized in that having in the coatings of 13 layers or 17 layers structure is followed successively by following thickness range: TiO by substrate to outermost layer ₂Be 10～150nm, AZOY or ITO are 1.0～30nm, and Ag is 5～30nm, and AZOY or ITO are 1.0～30nm, TiO ₂Be 10～200nm, AZOY or ITO are 1.0～30nm, and Ag is 5～30nm, and AZOY or ITO are 1.0～30nm, TiO ₂Be 10～200nm, AZOY or ITO are 1.0～30nm, and Ag is 5～30nm, and AZOY or ITO are 1.0～30nm, TiO ₂Be 10～200nm, AZOY or ITO are 1.0～30nm, and Ag is 5～30nm, and AZOY or ITO are 1.0～30nm, TiO ₂Be 10～150nm.

3. the filter with anti-electromagnetic radiation and filtering functions of plasma scope as claimed in claim 1, it is characterized in that metallic film is to be composited around the coating glass substrate and by conducting resinl on the metallic film and coatings bonding, or the metallic conduction binding agent is by being composited with the coatings bonding around the printing curing coating glass substrate.

4. the filter with anti-electromagnetic radiation and filtering functions of plasma scope as claimed in claim 1, it is characterized in that two plastic membranous layers that the surface has an anti-reflection function rete paste compound with coatings and glass substrate respectively by adhesive layer, reflectivity＜3% of the visible light section of filter behind the compound plastic membranous layer, the reflectivity of filter is also less than 6% behind compound two plastic membranous layers.

5. the filter with anti-electromagnetic radiation and filtering functions of plasma scope as claimed in claim 4, it is characterized in that plastic membranous layer is polyester film or the polycarbonate membrane or the polyvinyl butyral film of biaxial tension, add blue pigment in the binding agent to regulate and the yellow characteristic light of the 596nm that the decay display sends, add at least a in purple, redness, the black pigment to regulate the colour temperature and the light transmittance of display.

6. as the filter with anti-electromagnetic radiation and filtering functions of the described plasma scope of one of claim 1～5, it is characterized in that the anti-reflection function rete is at least by SiO on the plastic membranous layer ₂With Nb ₂O ₅Two layers of composition, or SiO ₂With TiO ₂Two layers of composition.

7. as the filter with anti-electromagnetic radiation and filtering functions of the described plasma scope of one of claim 1～3, the plastic membranous layer that it is characterized in that prevention coatings oxidation compound on the coatings of glass substrate or erosion is a binding agent, at least the blue pigment that has added the yellow characteristic light of the colour temperature of regulating display and the pigment of light transmittance and the 596nm that the decay display sends therein, this substrate and the other substrate formation filter that is bonded to one.

8. as the filter with anti-electromagnetic radiation and filtering functions of the described plasma scope of one of claim 1～3, it is characterized in that filter by with the compound prevention coatings oxidation of coatings or the plastic membranous layer of erosion, with pigment and the ultra-violet absorber of this plastic membranous layer as binding agent and adding adjusting colour temperature and light transmittance, direct and plasma display panel is pasted and is one.

9. as the filter with anti-electromagnetic radiation and filtering functions of the described plasma scope of one of claim 1～5, it is characterized in that the surface resistivity≤1.5 Ω/cm of coatings ²

10. as the filter with anti-electromagnetic radiation and filtering functions of the described plasma scope of one of claim 1～5, the glass substrate that it is characterized in that filter is half tempered glass or the toughened glass that adopts chemical method or physical method to handle.

11. filter with anti-electromagnetic radiation and filtering functions as the described plasma scope of one of claim 1～5, it is characterized in that watching planar survey at display, light transmittance during the visible light 380～780nm of filter greater than 30% less than 75%, light transmittance during infrared light 850nm is less than 18%, and the transmitance during 950nm is less than 10%.