CN101149997A - Copper/aluminum magnesium alloy composite wire and its quenching production method - Google Patents
Copper/aluminum magnesium alloy composite wire and its quenching production method Download PDFInfo
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- CN101149997A CN101149997A CNA2007101580470A CN200710158047A CN101149997A CN 101149997 A CN101149997 A CN 101149997A CN A2007101580470 A CNA2007101580470 A CN A2007101580470A CN 200710158047 A CN200710158047 A CN 200710158047A CN 101149997 A CN101149997 A CN 101149997A
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Abstract
This invention relates to fine and micro-fine multi-metal composite wires and their preparation method, in which, the composite wire is composed of a core and a cover layer, the core is made of AlMg alloy, the cover layer is a ribbon copper with the purity over 99.6% and interfaces of the core and the cover layer are combined by metallurgy characterizing that the section thickness of the cover is 0.000975-0.1014mm and the weight of the cover is 35.4-39.3% of the gross weight of the composite wire. This invention also discloses a manufacturing method for increasing quenching process.
Description
Technical field
The present invention relates to a kind of fine rule, many metal composite of glass-coated microwire wire rod and preparation method thereof, especially relate to fine rule, glass-coated microwire composite wire and the manufacture method thereof of a kind of " aluminium in copper magnesium ".
Background technology
At present, for replacing pure copper wire, solve copper resource scarcity, defect of high cost, " fine rule, many metal composite of glass-coated microwire wire rod " technology is in continuous development, especially also a lot of about the relevant introduction of copper clad aluminum magnesium alloy fine rule, glass-coated microwire composite material, but pure cu conductor exists density big, and weight is big, is difficult for defectives such as laying; And the substitute material aluminum-magnesium conductor exists conductance relatively poor, mechanical strength is on the low side, flexible poor, welding performance is poor, defectives such as contact resistance is big, therefore, if will alleviate wire weight, the more copper product of saving reduces cost, and the substitute material percentage by weight is excessive will to have influence on final electric conductivity of composite material and comprehensive mechanical performance etc., can't satisfy performance requirement, and if satisfy performance requirement, the copper layer that coats in the prior art is often thicker again, and the percentage by weight of copper is still very big, still can't reach the saving copper product, the intended purposes that reduces cost, therefore, how to make full use of these materials advantage separately itself, it is organic in conjunction with a difficult problem that is the puzzlement people always.
On the other hand, the traditional view of preparation composite wire is thought: fine copper is not suitable for quenching, quenching can make copper hardness improve, think that drawing procedure must directly could guarantee comprehensive mechanical performances such as its tensile property and ductility by annealing in process, therefore traditional manufacturing " many metal composite wire rod " preparation method generally adopts is to carry out " annealing in process " to guarantee its tensile property and to have preferably comprehensive mechanical performance such as ductility after drawing procedure, but " annealing in process " of available technology adopting is in any case operation is set treatment conditions, the comparatively perfect performance that all can't obtain to expect, the properties of product of final acquisition neither be very desirable.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of in light weight, tensile strength, electric conductivity, all comparatively desirable fine rule, many metal composite of the glass-coated microwire wire rod of comprehensive mechanical performance are provided.
On the other hand, the present invention overcomes the technology prejudice that exists in the prior preparation method, a kind of method for preparing fine rule, many metal composite of glass-coated microwire wire rod that has increased Quenching Treatment is provided, thereby has improved the performance of fine rule, many metal composite of glass-coated microwire wire rod greatly.
The technical solution used in the present invention is as follows:
Fine rule of the present invention, many metal composite of glass-coated microwire wire rod are made up of core body and coating layer, core body is the almag wire rod, coating layer is the copper strips of purity more than 99.6%, metallurgical binding is passed through at the interface of core body and coating layer, the coating layer section thickness is 0.000975～0.1014mm, and the weight of coating layer accounts for 35.4～39.3% of composite wire total weight.
More preferably, the cross-sectional area of coating layer accounts for 14.90～15.12% of the total cross-sectional area of composite wire.
The resistivity of composite wire is 0.027003～0.029936m Ω/cm3.
Composite wire proportion is 3.75 ± 3%g/cm3
Composite wire tensile strength is 250～340Mpa.
Preferred, when composite wire was circular wire rod, its line directly was 0.025～2.60mm.
On the other hand, the present invention also provides a kind of method of making fine rule, many metal composite of glass-coated microwire wire rod, and this method comprises the steps:
A, the method for using machinery or chemical industry to handle, removing almag wire rod core body and purity is the grease and the oxidation passivation layer of the copper strips cover surface more than 99.6%;
B, the copper strips coating layer is coated on the almag wire rod core body makes composite blank, wherein the weight of coating layer accounts for 35.4～39.3% of composite wire total weight;
C, drawing typing are drawn to the required diameter scope with composite blank and form composite wire, and wherein the coating layer section thickness is 0.000975～0.1014mm;
D, Quenching Treatment, in the Quenching Treatment process, composite wire is 800～2500m/min by the translational speed of treatment fluid, cooldown rate is 0.2～0.5 ℃/min;
E, annealing softening are handled, and obtain final products.
Fine rule of the present invention, many metal composite of glass-coated microwire wire rod, setting coating layer copper strips section thickness and weight by resultant, the superior function of various materials is organically combined, solved a difficult problem of the prior art, thereby a kind of fine rule lighter, many metal composite of glass-coated microwire wire rod have been obtained than prior art weight, when alleviating composite wire weight, guaranteed that again its tensile strength, electric conductivity, comprehensive mechanical performance are all comparatively desirable.
On the other hand, the present invention overcomes the technology prejudice that exists in the prior preparation method, by increasing this operation of Quenching Treatment, thereby guarantee that fine rule of the present invention, many metal composite of glass-coated microwire wire rod are under the prerequisite that alleviates composite wire weight, still can guarantee that its tensile strength, electric conductivity, comprehensive mechanical performance are all comparatively desirable, meet the correlated performance requirement fully.
Description of drawings
Fig. 1 is the fine rule that the present invention relates to, the cross sectional representation of many metal composite of glass-coated microwire wire rod.
Embodiment
In conjunction with the accompanying drawings 1, fine rule of the present invention, many metal composite of glass-coated microwire wire rod is made up of core body 1 and coating layer copper strips 2, wherein core body 1 is an almag wire rod core body, coating layer 2 employing purity are the copper strips more than 99.6%, metallurgical binding is passed through at the interface of core body 1 and coating layer 2, there are not other interlayers between the two, wherein coating layer 2 section thicknesses are 0.000975～0.1014mm, and the weight of coating layer 2 accounts for 35.4～39.3% of composite wire total weight, in order to prove absolutely fine rule of the present invention, the superior function and the beneficial effect of many metal composite of glass-coated microwire wire rod, what table 1 was listed is fine rule of the present invention, the embodiment 1-22 of many metal composite of glass-coated microwire wire rod, the thickness and the percentage by weight of the coating layer 2 among the embodiment 1-22, relevant parameter and performance index are as shown in table 1:
Table 1:
| Diameter specifications (mm) | Coating thickness (mm) | The percentage of the cross-sectional area of coating layer (%) | The percentage by weight of coating layer (%) | Proportion (g/cm 3) | Resistivity (m Ω/cm 3) | Tensile strength (Mpa) | Comprehensive mechanical performance |
| 0.025 | 0.000975 | 14.90 | 35.4～39.3 | 3.75±3％ | 0.029936 | 250～340 | Better |
| 0.06 | 0.00234 | 14.90 | 35.4～39.3 | 3.75±3％ | 0.029901 | 250～340 | Better |
| 0.08 | 0.0031 | 14.90 | 35.4～39.3 | 3.75±3％ | 0.029864 | 250～340 | Well |
| 0.10 | 0.0039 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.029603 | 250～340 | Better |
| 0.12 | 0.0047 | 15.05 | 35.4～39.3 | 3.75±3％ | 0.029324 | 250～340 | Better |
| 0.14 | 0.0055 | 15.10 | 35.4～39.3 | 3.75±3％ | 0.029135 | 250～340 | Excellent |
| 0.15 | 0.0059 | 15.12 | 35.4～39.3 | 3.75±3％ | 0.028972 | 250～340 | Better |
| 0.16 | 0.0062 | 14.90 | 35.4～39.3 | 3.75±3％ | 0.028647 | 250～340 | Better |
| 0.18 | 0.007 | 14.95 | 35.4～39.3 | 3.75±3％ | 0.028125 | 250～340 | Well |
| 0.20 | 0.0078 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027612 | 250～340 | Well |
| 0.25 | 0.0098 | 15.07 | 35.4～39.3 | 3.75±3％ | 0.027304 | 250～340 | Well |
| 0.40 | 0.0156 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027293 | 250～340 | Well |
| 0.60 | 0.0234 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027283 | 250～340 | Well |
| 0.80 | 0.0312 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027275 | 250～340 | Better |
| 1.00 | 0.0390 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027271 | 250～340 | Better |
| 1.20 | 0.0468 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027268 | 250～340 | Excellent |
| 1.40 | 0.0546 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027265 | 250～340 | Better |
| 1.60 | 0.0624 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027241 | 250～340 | Better |
| 1.80 | 0.0702 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027236 | 250～340 | Well |
| 2.05 | 0.0799 | 14.98 | 35.4～39.3 | 3.75±3％ | 0.027225 | 250～340 | Well |
| 2.15 | 0.0839 | 15.00 | 35.4～39.3 | 3.75±3％ | 0.027112 | 250～340 | Well |
| 2.60 | 0.1014 | 14.99 | 35.4～39.3 | 3.75±3％ | 0.027003 | 250～340 | Well |
Can clearly find out from table 1, coating layer section thickness of the present invention only is 0.000975～0.1014mm, weight only accounts for 35.4～39.3% of composite wire total weight, and the percentage 14.90～15.12% of the cross-sectional area of coating layer guarantees that wire rod proportion is 3.75 ± 3%g/cm
3, reduced fine rule, many metal composite of glass-coated microwire wire rod proportion widely, alleviated weight, adopt wire rod of the present invention simultaneously, resistivity reaches 0.027003～0.029936m Ω/cm
3, tensile strength reaches 250～340Mpa, has guaranteed that it can have resistivity and advantages of higher tensile strength preferably, and comprehensive mechanical performance also guaranteed, thereby the superior function of various materials is organically combined, and has solved a difficult problem of the prior art.
And wherein, preferred, when composite wire was circular wire rod, its line directly was 0.025～2.60mm.Fine rule, many metal composite of glass-coated microwire wire rod have more excellent performance index.
On the other hand, in order to obtain the more excellent fine rule of performance of the present invention, many metal composite of glass-coated microwire wire rod, the present invention has overcome the technology prejudice that traditional preparation method exists, after the drawing typing, increase this step of Quenching Treatment, adopted this preparation method, not only do not reduced the performance index of many metal composite wire rod, fully played the superior function of various materials on the contrary, guaranteed that many metal composite wire rod can reach optimum performance index.
Below, a concrete preparation method's of the present invention embodiment is provided:
Embodiment 1:
A, the method for using machinery or chemical industry to handle, removing almag wire rod core body and purity is the grease and the oxidation passivation layer of the copper strips cover surface more than 99.6%;
B, the copper strips coating layer is coated on the almag wire rod core body makes composite blank, wherein the weight of coating layer accounts for 35.4～39.3% of composite wire total weight;
C, drawing typing are drawn to the required diameter scope with composite blank and form composite wire, and wherein the coating layer section thickness is 0.000975～0.1014mm;
D, Quenching Treatment, in the Quenching Treatment process, composite wire is 800～2500m/min by the translational speed of treatment fluid, cooldown rate is 0.2～0.5 ℃/min;
E, annealing softening are handled, and obtain final products
Adopt above-mentioned similar preparation method, at the thickness and the weight of different coating layers, composite wire of the present invention is as shown in table 2 below respectively by the translational speed and the cooldown rate of Quenching Treatment liquid:
Table 2:
| Diameter specifications (mm) | Coating thickness (mm) | The percentage of the cross-sectional area of coating layer (%) | The percentage by weight of coating layer (%) | Translational speed (m/min) | Cooldown rate (℃/min) |
| 0.025 | 0.000975 | 14.90 | 35.4～39.3 | 1700～2000 | 0.20 |
| 0.06 | 0.00234 | 14.90 | 35.4～39.3 | 1800～2100 | 0.20 |
| 0.08 | 0.0031 | 14.90 | 35.4～39.3 | 1800～2300 | 0.20 |
| 0.10 | 0.0039 | 14.99 | 35.4～39.3 | 2000～2400 | 0.20 |
| 0.12 | 0.0047 | 15.05 | 35.4～39.3 | 2300～2500 | 0.20 |
| 0.14 | 0.0055 | 15.10 | 35.4～39.3 | 2200～2500 | 0.25 |
| 0.15 | 0.0059 | 15.12 | 35.4～39.3 | 2100～2300 | 0.25 |
| 0.16 | 0.0062 | 14.90 | 35.4～39.3 | 2200～2400 | 0.25 |
| 0.18 | 0.0070 | 14.95 | 35.4～39.3 | 2000～2300 | 0.30 |
| 0.20 | 0.0078 | 14.99 | 35.4～39.3 | 2000～2200 | 0.30 |
| 0.25 | 0.0098 | 15.07 | 35.4～39.3 | 1800～2100 | 0.30 |
| 0.40 | 0.0156 | 14.99 | 35.4～39.3 | 1500～1800 | 0.35 |
| 0.60 | 0.0234 | 14.99 | 35.4～39.3 | 1500～1700 | 0.35 |
| 0.80 | 0.0312 | 14.99 | 35.4～39.3 | 1400～1700 | 0.35 |
| 1.00 | 0.0390 | 14.99 | 35.4～39.3 | 1400～1700 | 0.40 |
| 1.20 | 0.0468 | 14.99 | 35.4～39.3 | 1300～1600 | 0.40 |
| 1.40 | 0.0546 | 14.99 | 35.4～39.3 | 1200～1500 | 0.40 |
| 1.60 | 0.0624 | 14.99 | 35.4～39.3 | 1100～1400 | 0.45 |
| 1.80 | 0.0702 | 14.99 | 35.4～39.3 | 1000～1200 | 0.45 |
| 2.05 | 0.0799 | 14.98 | 35.4～39.3 | 900～1200 | 0.50 |
| 2.15 | 0.0839 | 15.00 | 35.4～39.3 | 850～1150 | 0.50 |
| 2.60 | 0.1014 | 14.99 | 35.4～39.3 | 800～1100 | 0.50 |
Fine rule of the present invention; many metal composite of glass-coated microwire wire rod is by the setting coating layer section thickness and the percentage by weight of resultant; the superiority of various materials is organically combined; but to those skilled in the art; be easy to know by inference; fine rule of the present invention; many metal composite of glass-coated microwire wire rod not only comprises circular cross-section; also comprise multiple non-circular special-shaped line; as oblateness; square; rectangle; flat rhombus or ellipse or the like; and for the material that has similar performance by conversion or method to obtain similar fine rule; many metal composite of glass-coated microwire wire rod does not all break away from spirit of the present invention, all falls into protection scope of the present invention.
Claims (7)
1. a fine rule, many metal composite of glass-coated microwire wire rod, this composite wire is made up of core body (1) and coating layer (2), described core body (1) is the almag wire rod, described coating layer (2) purity is the copper strips more than 99.6%, metallurgical binding is passed through at the interface of described core body (1) and coating layer (2), it is characterized in that: described coating layer (2) section thickness is 0.000975～0.1014mm, and the weight of described coating layer (2) accounts for 35.4～39.3% of composite wire total weight.
2. fine rule as claimed in claim 1, many metal composite of glass-coated microwire wire rod is characterized in that the cross-sectional area of described coating layer accounts for 14.90～15.12% of the total cross-sectional area of composite wire.
3. fine rule as claimed in claim 1, many metal composite of glass-coated microwire wire rod, the resistivity that it is characterized in that described composite wire is 0.027003～0.029936m Ω/cm
3
4. fine rule as claimed in claim 1, many metal composite of glass-coated microwire wire rod is characterized in that described composite wire proportion is 3.75 ± 3%g/cm
3
5. fine rule as claimed in claim 1, many metal composite of glass-coated microwire wire rod is characterized in that described composite wire tensile strength is 250～340Mpa.
6. fine rule as claimed in claim 1, many metal composite of glass-coated microwire wire rod is characterized in that described composite wire is circular wire rod, and its line directly is 0.025～2.60mm.
7. a method of making any described fine rule of claim 1-6, many metal composite of glass-coated microwire wire rod is characterized in that comprising the steps:
A, the method for using machinery or chemical industry to handle, removing almag wire rod core body (1) and purity is the grease and the oxidation passivation layer on copper strips coating layer (2) surface more than 99.6%;
B, copper strips coating layer (2) is coated on the almag wire rod core body (1) makes composite blank, the weight of wherein said coating layer (2) accounts for 35.4～39.3% of composite wire total weight;
C, drawing typing are drawn to the required diameter scope with composite blank and form composite wire, and wherein said coating layer (2) section thickness is 0.000975～0.1014mm;
D, Quenching Treatment, in the described Quenching Treatment process, composite wire is 800～2500m/min by the translational speed of treatment fluid, cooldown rate is 0.2～0.5 ℃/min;
E, annealing softening are handled, and obtain final products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101580470A CN101149997A (en) | 2007-11-09 | 2007-11-09 | Copper/aluminum magnesium alloy composite wire and its quenching production method |
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| CNA2007101580470A CN101149997A (en) | 2007-11-09 | 2007-11-09 | Copper/aluminum magnesium alloy composite wire and its quenching production method |
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| CNA2007101580470A Pending CN101149997A (en) | 2007-11-09 | 2007-11-09 | Copper/aluminum magnesium alloy composite wire and its quenching production method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104167234A (en) * | 2014-08-29 | 2014-11-26 | 孙金福 | Copper-clad aluminum magnesium alloy wire |
| CN105469902A (en) * | 2015-12-22 | 2016-04-06 | 广东中德电缆有限公司 | High-conductivity copper-clad magnesium-aluminum alloy wire production method |
| CN105869702A (en) * | 2016-05-30 | 2016-08-17 | 张家港市亚亨金属制品有限公司 | Copper-clad aluminum composite wire |
| CN108699716A (en) * | 2016-06-21 | 2018-10-23 | 东京特殊电线株式会社 | Copper clad magnesium line and its manufacturing method |
-
2007
- 2007-11-09 CN CNA2007101580470A patent/CN101149997A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104167234A (en) * | 2014-08-29 | 2014-11-26 | 孙金福 | Copper-clad aluminum magnesium alloy wire |
| CN105469902A (en) * | 2015-12-22 | 2016-04-06 | 广东中德电缆有限公司 | High-conductivity copper-clad magnesium-aluminum alloy wire production method |
| CN105869702A (en) * | 2016-05-30 | 2016-08-17 | 张家港市亚亨金属制品有限公司 | Copper-clad aluminum composite wire |
| CN108699716A (en) * | 2016-06-21 | 2018-10-23 | 东京特殊电线株式会社 | Copper clad magnesium line and its manufacturing method |
| CN108699716B (en) * | 2016-06-21 | 2019-10-15 | 东京特殊电线株式会社 | Copper clad magnesium line and its manufacturing method |
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Open date: 20080326 |