CN101148849A - Surface layer abrasion-proof paper - Google Patents

Surface layer abrasion-proof paper Download PDF

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Publication number
CN101148849A
CN101148849A CNA2006100690835A CN200610069083A CN101148849A CN 101148849 A CN101148849 A CN 101148849A CN A2006100690835 A CNA2006100690835 A CN A2006100690835A CN 200610069083 A CN200610069083 A CN 200610069083A CN 101148849 A CN101148849 A CN 101148849A
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surface layer
proof paper
consumption
agent
layer abrasion
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CN100497822C (en
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李学峰
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Qi Feng new materials Limited by Share Ltd
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李学峰
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Abstract

The surface wear resistant paper for making decorating thermosetting laminated sheet contains stuffing and assistant. It has high transparency, high wear resistance, long service life, environment friendship and other advantages. It is applied widely for the surface of furniture, vehicle, ship, airplane, floor, instrument, etc.

Description

Surface layer abrasion-proof paper
Technical field
Surface layer abrasion-proof paper the present invention relates to be directly used in a kind of surface layer abrasion-proof paper of making the heat curing-type decorative laminate.
Background technology
Before this product comes out, be with pattern in the polywood paper printing at first, back side coated with adhesive is colded pressing and is done the technology of facing to the wood-based plate, and this method is polluted big, the easy layering of paper and sheet material, water resistance is poor, and not wear-resisting.Through " Chinese patent " retrieval, still find no at present and match with wood-based plate veneer product, can improve and improve performances such as the wear-resisting of original veneer and anti-soil stain, enlarge the surface layer abrasion-proof paper in the use field of wood-based plate veneer.
Summary of the invention
The technical problem to be solved in the present invention is: fill up the blank of prior art, the surface layer abrasion-proof paper of a kind of heigh clarity, highly abrasion-resistant, long service life is provided.
The technical solution adopted for the present invention to solve the technical problems is: this kind surface layer abrasion-proof paper is characterized in that: this abrasion-proof paper comprises filler, auxiliary agent.
Filler comprises: white fused alumina (Al 2O 3) composite high-abrasive material.
White fused alumina (Al 2O 3) the consumption of composite high-abrasive material by weight being 1-60%, particle diameter is 1-150 μ m.
White fused alumina (Al 2O 3) the preferable amount of composite high-abrasive material by weight being 2-50%, particle diameter is 3-130 μ m.
Auxiliary agent comprises: wet strength agent, anion surfactant, retention agent, degasser, dispersant.
The consumption of wet strength agent, anion surfactant, retention agent, degasser, dispersant is 0.01-20% by weight.
The preferable amount of wet strength agent, anion surfactant, retention agent, degasser, dispersant is 2-10% by weight.
Auxiliary agent is by weight calculating: the consumption 80-95% of wet strength agent, the consumption 0.05-10% of anion surfactant, the consumption 0-5% of retention agent, the consumption 0.5-10% of degasser, the consumption 0-2% of dispersant.
Surface layer abrasion-proof paper of the present invention, be by weight being 50-98% at the consumption of cellulose paper pulp mixture, the mixture that specifically comprises the mixture of long fiber wood pulp or long fiber, staple fibre wood pulp or long fiber wood pulp, cellulose slurry, weight ratio is the long fiber of 60-100% to 40-0% and the mixture of staple fibre, and particularly preferred consumption is the long fiber of 70-100% to 30-0% and the mixture of staple fibre by weight.Weight ratio is the long fiber of 60-100% to 40-0% and the mixture of cellulose slurry, adds filler in the long fiber that particularly preferred consumption weight ratio is 70-100% to 30-0% and the mixture of cellulose slurry, auxiliary agent is made.
The grammes per square metre of surface layer abrasion-proof paper of the present invention is 14-70g/m normally 2
Preparation method: paper pulp is prepared according to certain proportioning, and wear-resistant material and above-mentioned auxiliary agent are added in size degradation, making beating, prepare burden, beating consistency is controlled at 2-5%, and beating degree 16-30 ° of SR debugs PH to 5.5-7 with chelating agent, last machine is manufactured paper with pulp, and through arrangement later, makes finished product.
Cellulose paper pulp mixture: come down to the millboard of fiber, as the base stock of producing surface layer abrasion-proof paper through handling, being pressed into.Paper pulp fiber is prescinded through making beating and divide silk and add auxiliary material, the l Water Paper page or leaf of the fiber interweaving of manufacturing paper with pulp in paper machine is made the finished product paper through dehydrating again.White fused alumina (Al 2O 3) mainly play wear-resisting effect.Wet strength agent: improve the green tensile strength of paper in dipping process.Surfactant: the transparency that improves page.Retention agent: improve the retention of filler, reduce and run off.Degasser: the effect of eliminating the foam of paper pulp in blending process and suppressing to produce foam.Dispersant: the dispersiveness and the uniformity that improve paper pulp and filler.
The beneficial effect that compared with prior art the present invention had is: have heigh clarity, highly abrasion-resistant, long service life, and great variety of goods, technology is simple, and cost is low.And belong to resource-conserving, the friendly type of environmental protection.Can be widely used in furniture manufacturing, vehicle, boats and ships, aircraft, floor, sales counter, bowling lanes, interior of building finishing, various instrument, equipment and the table top of Sewing machines and the fields such as shell manufacturing of household electrical appliance.
The specific embodiment
Embodiment 1:
After getting the raw materials ready, by weight calculating: the cellulose paper pulp mixture (long fiber wood pulp 60%, cellulose slurry 40%) of adding 98%, 1% white fused alumina (Al 2O 3) the composite wear-resistant material of 1 μ m.0.01% auxiliary agent (PAE wet strength agent 95%, anion surfactant 0.05%, silicone based degasser 4.95%), beating consistency is controlled at 2%, and 16 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 14 grams.
Embodiment 2:
After getting the raw materials ready, by weight calculating: the cellulose paper pulp mixture (long fiber wood pulp 80%, cellulose slurry 20%) of adding 97%, 2% white fused alumina (Al 2O 3) 3The composite wear-resistant material of μ m.2% auxiliary agent (PAE wet strength agent 95%, anion surfactant 0.05%, silicone based degasser 4.95%), beating consistency is controlled at 2%, and 16 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 18 grams.
Implement 3:
After getting the raw materials ready, by weight calculating: the long fiber wood pulp of adding 95%, add 15% white fused alumina (Al 2O 3) the composite wear-resistant material of 60 μ m, 5% auxiliary agent (PPE wet strength agent 93%, anion surfactant 1%, double base retention agent 1%, silicone based degasser 5%), beating consistency is controlled at 2%, 18 ° of SR of beating degree debug extremely PH to 5.5-7, as slurry mix with chelating agent.The surface layer abrasion-proof paper of production grammes per square metre 22 grams.
Embodiment 4:
After getting the raw materials ready, by weight calculating: the long fiber staple fibre wood pulp mixture (long fiber wood pulp 60%, staple fibre wood pulp 40%) of adding 69%, add 30% white fused alumina (Al 2O 3) the composite wear-resistant material of 100 μ m, 8% auxiliary agent (PAE wet strength agent 85%, anion surfactant 5%, double base glidant 4%, silicone based degasser 5%, coating dispersant 1%), beating consistency is controlled at 3%, 20 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 33 grams.
Embodiment 5:
After getting the raw materials ready, by weight calculating: add 65% long fiber staple fibre wood pulp mixture (long fiber wood pulp 80%, staple fibre wood pulp 20%), add 35% white fused alumina (Al 2O 3) the composite wear-resistant material of 120 μ m, 10% auxiliary agent (PAE wet strength agent 85%, anion surfactant 6%, double base glidant 4%, silicone based degasser 3.5%, coating dispersant 1.5%), beating consistency is controlled at 4%, 20 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 38 grams.
Embodiment 6:
After getting the raw materials ready, by weight calculating: add 60% long fiber wood pulp, add 50% white fused alumina (Al 2O 3) the composite wear-resistant material of 130 μ m, 15% auxiliary agent (PAE wet strength agent 80%, anion surfactant 6%, double base glidant 2.5%, silicone based degasser 10%, coating dispersant 1.5%), beating consistency is controlled at 4%, 25 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 45 grams.
Embodiment 7:
After getting the raw materials ready, by weight calculating: the cellulose paper pulp mixture (long fiber wood pulp 90%, cellulose slurry 10%) of adding 50%, add 60% white fused alumina (Al 2O 3) the composite wear-resistant material of 150 μ m, 20% auxiliary agent (PPE wet strength agent 80%, anion surfactant 10%, double base glidant 5%, silicone based degasser 3%, coating dispersant 2%), beating consistency is controlled at 5%, 30 ° of SR of beating degree debug PH to 5.5-7 with chelating agent, as slurry mix.The surface layer abrasion-proof paper of production grammes per square metre 70 grams.

Claims (8)

1. surface layer abrasion-proof paper, it is characterized in that: this abrasion-proof paper comprises filler, auxiliary agent.
2. surface layer abrasion-proof paper according to claim 1, it is characterized in that: filler comprises: white fused alumina (Al 2O 3) composite high-abrasive material.
3. surface layer abrasion-proof paper according to claim 2 is characterized in that: white fused alumina (Al 2O 3) the consumption of composite high-abrasive material by weight being 1-60%, particle diameter is 1-150 μ m.
4. surface layer abrasion-proof paper according to claim 3 is characterized in that: white fused alumina (Al 2O 3) the consumption of composite high-abrasive material by weight being 2-50%, particle diameter is 3-130 μ m.
5. surface layer abrasion-proof paper according to claim 1, it is characterized in that: auxiliary agent comprises: wet strength agent, anion surfactant, retention agent, degasser, dispersant.
6. surface layer abrasion-proof paper according to claim 5 is characterized in that: the consumption of wet strength agent, anion surfactant, retention agent, degasser, dispersant is by weight being 0.01-20%.
7. surface layer abrasion-proof paper according to claim 6 is characterized in that: the consumption of wet strength agent, anion surfactant, retention agent, degasser, dispersant is by weight being 2-10%.
8. surface layer abrasion-proof paper according to claim 7, it is characterized in that: auxiliary agent is by weight calculating: the consumption 80-95% of wet strength agent, the consumption 0.05-10% of anion surfactant, the consumption 0-5% of retention agent, the consumption 0.5-10% of degasser, the consumption 0-2% of dispersant.
CNB2006100690835A 2006-09-22 2006-09-22 Surface layer abrasion-proof paper Active CN100497822C (en)

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Application Number Priority Date Filing Date Title
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CN101148849A true CN101148849A (en) 2008-03-26
CN100497822C CN100497822C (en) 2009-06-10

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101624795B (en) * 2009-08-07 2011-06-01 山东齐峰特种纸业股份有限公司 Gold and silver piece color intrigue decorative paper and manufacturing method thereof
CN101824770B (en) * 2009-03-06 2012-06-06 乐山市成发造纸机械有限责任公司 Method for preparing wear resistant paper by using layer forming technique
CN105297545A (en) * 2015-09-11 2016-02-03 句容市兴武包装有限公司 Wear resistant paper and preparation method thereof
CN109137621A (en) * 2018-09-04 2019-01-04 江苏星光新材料科技有限公司 A kind of ultra-high performance wearable paper
CN109306246A (en) * 2018-10-11 2019-02-05 广东福美新材料科技有限公司 A kind of shock proof automatically cleaning impregnated paper and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102535251B (en) * 2011-12-30 2013-11-06 淄博欧木特种纸业有限公司 Dustless abrasion-proof paper and making method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101824770B (en) * 2009-03-06 2012-06-06 乐山市成发造纸机械有限责任公司 Method for preparing wear resistant paper by using layer forming technique
CN101624795B (en) * 2009-08-07 2011-06-01 山东齐峰特种纸业股份有限公司 Gold and silver piece color intrigue decorative paper and manufacturing method thereof
CN105297545A (en) * 2015-09-11 2016-02-03 句容市兴武包装有限公司 Wear resistant paper and preparation method thereof
CN109137621A (en) * 2018-09-04 2019-01-04 江苏星光新材料科技有限公司 A kind of ultra-high performance wearable paper
CN109306246A (en) * 2018-10-11 2019-02-05 广东福美新材料科技有限公司 A kind of shock proof automatically cleaning impregnated paper and preparation method thereof
CN109306246B (en) * 2018-10-11 2023-12-01 广东福美新材料科技有限公司 Impact-resistant self-cleaning impregnated paper and preparation method thereof

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Owner name: SHANDONG QIFENG SPECIAL PAPER CO.LTD.

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Address after: Linzi District of Shandong city of Zibo province Zhu Tai Zhen Zhu Tai Lu No. 22 post encoding: 255432

Applicant after: Shandong Qifeng Special Paper Co., Ltd.

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Applicant before: Li Xuefeng

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Assignee: Zibo Oumu Special Paper Industry Co., Ltd.

Assignor: Shandong Qifeng Special Paper Co., Ltd.

Contract record no.: 2011370000064

Denomination of invention: Surface layer abrasion-proof paper

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Address after: Linzi District 255432 of Shandong city of Zibo province Zhu Tai Zhen Zhu Tai Lu No. 22

Patentee after: Qi Feng new materials Limited by Share Ltd

Address before: Linzi District 255432 of Shandong city of Zibo province Zhu Tai Zhen Zhu Tai Lu No. 22

Patentee before: Shandong Qifeng Special Paper Co., Ltd.