CN101148534A - Colored modified building asphalt and preparation method thereof - Google Patents
Colored modified building asphalt and preparation method thereof Download PDFInfo
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- CN101148534A CN101148534A CNA2006101131636A CN200610113163A CN101148534A CN 101148534 A CN101148534 A CN 101148534A CN A2006101131636 A CNA2006101131636 A CN A2006101131636A CN 200610113163 A CN200610113163 A CN 200610113163A CN 101148534 A CN101148534 A CN 101148534A
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Abstract
The present invention relates to one kind of color modified building asphalt prepared through modifying distillate oil of naphthene-base crude oil. The color modified building asphalt has the materials comprising base oil 12-52 wt%, SBS 2-18 wt%, ferric oxide 2-20 wt% and/or SBR 0.1-16 wt% and/or PE 0.1-26 wt% and/or titania 0.1-9 wt%, and petroleum resin for the rest. The modified building asphalt has good high temperature and low temperature performance, good temperature sensing performance, simple preparation process, bright color and high comprehensive performance.
Description
Technical field
The present invention relates to a kind of properties-correcting agent that utilizes and the distillate in the naphthenic base crude is carried out a kind of colored modified building asphalt that is prepared from after modification is handled.
Background technology
Black oil building asphalt is a kind of base mateiral that is usually used in the buildings waterproof aspect in the market, but that its exists is too strong to temperature sensitivity, winter easy hardening embrittlement, easy deliquescing trickling in summer, the defective that work-ing life is short.The patent of CN97121664.9 has been announced a kind of preparation method of the building asphalt of retrofiting, it is at first asphalt stock to be handled, after reaching certain index, the basic asphalt performance adds properties-correcting agent again, make the building asphalt of preparing reach all modified asphalt for construction preferably of better high and low temperature performance and temperature sensibility, manufacturing procedure is complicated, color is a black but this method exists, the defective that lacks aesthetic especially is being used for aspect the roof water-proof processing, far can not satisfy people's esthetic requirement.And for example Chinese patent application number is that 94118271.1 patent application discloses a kind of color asphalt and preparation method thereof, application number is that 03135423.8 patent application has disclosed a kind of paving with chromatic cementing agent and preparation method thereof, they all are the road construction materials, penetration degree is big, softening temperature is low, can not be used for building trade.
Summary of the invention
The object of the present invention is to provide a kind of bright in luster, over-all properties to be better than colored modified building asphalt product of common black oil building asphalt and preparation method thereof, can be modulated into versicolor building asphalt as required.
The present invention is in the viscous crude distillate, adds a certain amount of weighting agent, properties-correcting agent, chemical coupling agent and stablizer and makes the colored modified building asphalt base-material, adds needed pigment at last, is prepared into colored modified building asphalt.
The raw materials by weight of preparation colored modified building asphalt product consists of: 12～52% base oil, 2～18% SBS, 2～20% ferric oxide and/or 0.1～16% SBR and/or 0.1～26% PE and/or 0.1～9% titanium oxide and surplus are petroleum resin.
Above-mentioned base oil is 250～550 ℃ of distillates or KN4010, KN4006, BS150, BS200 in the light high aromatic hydrocarbons heavy grease in the naphthenic base crude or suitable with performance in the naphthenic base crude, subtract a kind of in the four hydrogenation heavy greases or two or more base oil that combines arbitrarily, and this base oil can phase trans-substitution.
Above-mentioned SBS is a styrene-butadiene-styrene block copolymer, and wherein the weight percent that accounts for of SBS is 1～10%.
Above-mentioned SBR is Powdered styrene-butadiene rubber(SBR).
Above-mentioned PE is that molecular weight is 100,000～400,000 linear low density polyethylene.
Above-mentioned petroleum resin are C
5Hydrogenation or not hydrogenated petroleum resin, C
9Hydrogenation or not hydrogenated petroleum resin or C
5With C
6The petroleum resin of copolymerization.
Above-mentioned titanium oxide is a powdery white solid.
Ferric oxide is red, yellow, blue or green or other color pulverulent solids.
The preparation method of colored modified building asphalt provided by the invention is: the base oil with 12～52% is heated to 80～200 ℃, add 2～18% SBS and/or 0.1～16% SBR then, stirring melts to SBS and SBR dissolve fully after, after being warming up to 120～250 ℃, again/or add 0.1～26% PE and/or 0.1～9% titanium oxide and surplus petroleum resin, add 2～20% ferric oxide at last, after stirring, promptly obtain building stone oil base modified color asphaltic products..
Modified asphalt for construction provided by the invention not only has better high and low temperature performance and temperature-sensitive performance, and the preparation method is simple, can be prepared into the pitch of all kinds of exquisiteness bright in luster according to actual needs, the product over-all properties is better than the building petroleum asphalt standard of regulation in the GB 68494.
Embodiment
Further illustrate implementation of the present invention and characteristics below in conjunction with embodiment, but the present invention is not subjected to the restriction of following embodiment, can determines concrete embodiment according to technical scheme of the present invention and practical situation.
The raw material that is used for product of the present invention among the embodiment all is weight percentage.
GB494 building petroleum asphalt quality standard of the present invention sees Table 1.
Table 1 building petroleum asphalt quality standard
| Project | Building petroleum asphalt GB494 | |
| No. 10 | No. 30 | |
| Softening temperature, ℃ | ≥95 | ≥70 |
| Penetration degree (25 ℃, 100g, 5s), 0.1mm | 10-25 | 26-40 |
| Ductility (25 ℃, 5cm/min), cm | ＞1.5 | ＞3.0 |
Embodiment 1:
KN4010 with 14% is heated to 80 ℃, adds 10% SBS and 6% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 120 ℃, to add 20% molecular-weight average again be 200,000 PE, 3% titanium oxide and surplus C
5Hydrogenated petroleum resin adds 7% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 10,103.0 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 16 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 10cm.
Embodiment 2:
KN4006 with 30% is heated to 90 ℃, adds 12% SBS and 15.5% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 140 ℃, to add 8% molecular-weight average again be 150,000 PE, 0.5% titanium oxide and surplus C
5Hydrogenated petroleum resin not adds 2% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 30,82.0 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 33 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 10cm.
Embodiment 3:
BS with 12% is heated to 120 ℃, adds 5% SBS and 4% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 180 ℃, to add 4% molecular-weight average again be 100,000 PE, 2% titanium oxide and surplus C
5Hydrogenated petroleum resin adds 3% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 10,106 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 15 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 16cm.
Embodiment 4:
BS150 with 23% is heated to 80 ℃, adds 15% SBS and 2% SBR then, stir melt to SBS and dissolve fully with SBR after, the molecular-weight average that is warmed up to 150 ℃ of addings 5% is 250,000 PE, 5% titanium oxide and surplus C
9Hydrogenated petroleum resin adds 5% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 30,79 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 31 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 22cm.
Embodiment 5:
BS200 with 25% is heated to 100 ℃, adds 2% SBS and 1% SBR then, stir melt to SBS and dissolve fully with SBR after, the molecular-weight average that is warmed up to 185 ℃ of addings 10% is 250,000 PE, surplus C
9Hydrogenated petroleum resin not adds 20% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 10,99 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 14 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 19cm.
Embodiment 6:
28% the four hydrogenation heavy greases that subtract are heated to 200 ℃, add 18% SBS and 16% SBR then, stir melt to SBS and dissolve fully with SBR after, the molecular-weight average that is warmed up to 250 ℃ of addings 1% is 300,000 PE, 1% titanium oxide and surplus C
5With C
9The hydrogenated petroleum resin of copolymerization adds 15% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 30,80 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 30 (0.1mm), ductility (25 ℃ 5cm/min) are 28cm.
Embodiment 7:
With the boiling range in 20% the naphthenic base crude is that 250～550 ℃ of distillates are heated to 120 ℃, adds 8% SBS then, stir melt to SBS and dissolve fully after, being warmed up to 200 ℃, to add 26% molecular-weight average be 400,000 PE, 5% titanium oxide and surplus C
5With C
9The not hydrogenated petroleum resin of copolymerization adds 2% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 10,100 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 17 (0.1mm), ductility (25 ℃ 5cm/min) are 12cm.
Embodiment 8:
With the boiling range in 36% the naphthenic base crude is that 250～550 ℃ of distillates are heated to 140 ℃, add 5% SBS and 6% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 220 ℃, to add 24% molecular-weight average be 350,000 PE, 7% titanium oxide and surplus C
9Hydrogenated petroleum resin adds 4% red iron oxide at last, after stirring, promptly obtains red modified asphalt for construction product No. 30,76 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 33 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 19cm.
Embodiment 9:
KN4006 with 16% is heated to 80 ℃, adds 8% SBS and 6% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 170 ℃, to add 11% molecular-weight average be 200,000 PE, 3% titanium oxide and surplus C
5Hydrogenated petroleum resin not adds 4% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 10,103 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 16 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 10cm.
Embodiment 10:
BS150 with 33% is heated to 100 ℃, adds 12% SBS and 15.5% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 160 ℃, to add 18% molecular-weight average be 220,000 PE, 0.5% titanium oxide and surplus C
9Hydrogenated petroleum resin not adds 12% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 30,82 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 33 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 30cm.
Embodiment 11:
BS200 with 30% is heated to 110 ℃, adds 5% SBS and 10% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 210 ℃, to add 4% molecular-weight average be 130,000 PE, 2% titanium oxide and surplus C
5Hydrogenated petroleum resin not adds 3% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 10,106 ℃ of its softening temperatures, and (25 ℃, 100g 5s) is 15 (0.1mm) to penetration degree, ductility (25 ℃ 5cm/min) are 16cm.
Embodiment 12:
KN4010 with 52% is heated to 80 ℃, adds 15% SBS and 12% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 130 ℃, to add 6% molecular-weight average be 230,000 PE, 8% titanium oxide and surplus C
5With C
9The hydrogenated petroleum resin of copolymerization adds 8% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 30,79 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 31 (0.1mm), ductility (25 ℃ 5cm/min) are 22cm.
Embodiment 13:
BS200 with 45% is heated to 160 ℃, adds 2% SBS and 1% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 190 ℃, to add 10% molecular-weight average be 160,000 PE, surplus C
5With C
9The not hydrogenated petroleum resin of copolymerization adds 20% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 10,99 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 14 (0.1mm), ductility (25 ℃ 5cm/min) are 19cm.
Embodiment 14:
BS150 with 38% is heated to 100 ℃, adds 8% SBS and 14% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 155 ℃, to add 1% molecular-weight average be 400,000 PE, 1% titanium oxide and surplus C
5With C
9The hydrogenated petroleum resin of copolymerization adds 10% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 30,80 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 30 (0.1mm), ductility (25 ℃ 5cm/min) are 28cm.
Embodiment 15:
With boiling range in 18% the naphthenic base crude is that 250-550 ℃ of distillate is heated to 130 ℃, add 14% SBS and 6% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 230 ℃, to add 22% molecular-weight average be 200,000 PE, 5% titanium oxide and surplus C
9The hydrogenated petroleum resin of copolymerization adds 2% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 10,100 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 17 (0.1mm), ductility (25 ℃ 5cm/min) are 12cm.
Embodiment 16:
40% the four hydrogenation heavy greases that subtract are heated to 150 ℃, add 5% SBS and 6% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 240 ℃, to add 11% molecular-weight average be 360,000 PE, 6% titanium oxide and surplus C
9The not hydrogenated petroleum resin of copolymerization adds 17% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 30,100 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 17 (0.1mm), ductility (25 ℃ 5cm/min) are 12cm.
Embodiment 17:
BS200 with 20% and 12%KN4006 are heated to 180 ℃, add 2% SBS and 6% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 225 ℃, to add 10% molecular-weight average be 180,000 PE, 3% titanium oxide and surplus C
9The hydrogenated petroleum resin of copolymerization adds 9% iron oxide green at last, after stirring, promptly obtains green modified asphalt for construction product No. 10,103 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 16 (0.1mm), ductility (25 ℃ 5cm/min) are 10cm.
Embodiment 18:
BS150 with 10% and 33% BS200 are heated to 150 ℃, add 12% SBS and 16% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 200 ℃, to add 3% molecular-weight average be 270,000 PE, 5% titanium oxide and surplus C
5The hydrogenated petroleum resin of copolymerization adds 3% iron oxide yellow at last, after stirring, promptly obtains yellow modified asphalt for construction product No. 30,81 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 32 (0.1mm), ductility (25 ℃ 5cm/min) are 23cm.
Embodiment 19:
KN4010 with 24% and 24% BS150 are heated to 80 ℃, add 6% SBS and 10% SBR then, stir melt to SBS and SBR and dissolve fully after, being warmed up to 170 ℃, to add 16% molecular-weight average be 100,000 PE, 2% titanium oxide and surplus C
5The hydrogenated petroleum resin of copolymerization adds 5% iron oxide yellow at last, after stirring, promptly obtains yellow modified asphalt for construction product No. 10,99 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 15 (0.1mm), ductility (25 ℃ 5cm/min) are 11cm.
Embodiment 20:
With boiling range in 40% the naphthenic base crude is that the BS150 of 250-550 ℃ of distillate and 12% is heated to 100 ℃, add 10% SBS and 8% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 150 ℃, to add 3% molecular-weight average be 180,000 PE, 3% titanium oxide and surplus C
5The hydrogenated petroleum resin of copolymerization adds 6% iron oxide yellow at last, after stirring, promptly obtains yellow modified asphalt for construction product No. 30,79 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 33 (0.1mm), ductility (25 ℃ 5cm/min) are 20cm.
Embodiment 21:
With boiling range in 40% the naphthenic base crude is that the BS200 of 250-550 ℃ of distillate and 12% is heated to 200 ℃, add 10% SBS and 6% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 250 ℃, to add 14% molecular-weight average be 180,000 PE, 4% titanium oxide and surplus C
5The hydrogenated petroleum resin of copolymerization adds 4% iron oxide blue at last, after stirring, promptly obtains blue modified asphalt for construction product No. 30,79 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 33 (0.1mm), ductility (25 ℃ 5cm/min) are 20cm.
Embodiment 22:
With boiling range in 40% the naphthenic base crude is that the KN4006 of 250-550 ℃ of distillate and 12% is heated to 120 ℃, add 14% SBS and 5% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 170 ℃, to add 6% molecular-weight average be 180,000 PE, 5% titanium oxide and surplus C
5With the hydrogenated petroleum resin of C9 copolymerization, add 8% iron oxide blue at last, after stirring, promptly obtain blue modified asphalt for construction product No. 10,100 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 18 (0.1mm), ductility (25 ℃ 5cm/min) are 15cm.
Embodiment 23:
With boiling range in 40% the naphthenic base crude is that the KN4010 of 250-550 ℃ of distillate and 12% is heated to 140 ℃, adds 10% SBS and 3% SBR then, stir melt to SBS and SBR and dissolve fully after, be warmed up to 180 ℃, add 8% titanium oxide and surplus C
9The hydrogenated petroleum resin of copolymerization adds 6% iron oxide blue at last, after stirring, promptly obtains blue modified asphalt for construction product No. 30,79 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 33 (0.1mm), ductility (25 ℃ 5cm/min) are 22cm.
Embodiment 24:
With boiling range in 20% the naphthenic base crude is that the four hydrogenation heavy greases that subtract of 250-550 ℃ of distillate and 12% are heated to 150 ℃, add 10% SBS and 1% SBR then, stirring melts to SBS and SBR dissolve fully after, be warmed up to 190 ℃, the molecular-weight average of adding 8% is 350,000 PE, 6% titanium oxide and surplus C
9The hydrogenated petroleum resin of copolymerization adds 13% iron oxide blue at last, after stirring, promptly obtains blue modified asphalt for construction product No. 30,82 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 36 (0.1mm), ductility (25 ℃ 5cm/min) are 25cm.
Embodiment 25:
With boiling range in 10% the naphthenic base crude is that 250-550 ℃ of distillate, 5% KN4006 and 10% BS150 are heated to 170 ℃, add 18% SBS and 3% SBR then, stirring melts to SBS and SBR dissolve fully after, being warmed up to 210 ℃, to add 5% molecular-weight average be 150,000 PE, 9% titanium oxide and surplus C
5With C
9The hydrogenated petroleum resin of copolymerization adds 8% iron oxide blue at last, after stirring, promptly obtains blue modified asphalt for construction product No. 10,99 ℃ of its softening temperatures, and penetration degree (25 ℃, 100g, 5s) be 17 (0.1mm), ductility (25 ℃ 5cm/min) are 10cm.
Claims (6)
1. colored modified building asphalt, it is characterized in that: raw materials by weight is grouped into by following one-tenth: 12～52% base oil, 2～18% SBS, 2～20% ferric oxide and/or 0.1～16% SBR and/or 0.1～26% PE and/or 0.1～9% titanium oxide and surplus are petroleum resin;
Base oil is in the naphthenic base crude or suitable with its performance 250～550 ℃ of distillates and/or light high aromatic hydrocarbons heavy grease;
SBS is a styrene-butadiene-styrene block copolymer, and wherein to account for the weight percent of multipolymer be 1～10% to SBS;
SBR is a styrene-butadiene rubber(SBR);
PE is that molecular weight is 100,000～400,000 linear low density polyethylene.
2. colored modified building asphalt according to claim 1 is characterized in that: the high aromatic hydrocarbons heavy grease of described base oil light color is KN4010, KN4006, BS150, BS200, subtract a kind of in the four hydrogenation heavy greases or two or more composition arbitrarily.
3. colored modified building asphalt according to claim 1 is characterized in that: ferric oxide is red, yellow, blue or green or other color pulverulent solids.
4. colored modified building asphalt according to claim 1 is characterized in that: described petroleum resin are C
5Hydrogenation or not hydrogenated petroleum resin, C
9Hydrogenation or not hydrogenated petroleum resin or C
5With C
9The hydrogenation of copolymerization or hydrogenated petroleum resin not.
5. colored modified building asphalt according to claim 1 is characterized in that: described titanium oxide is a powdery white solid.
6. the preparation method of colored modified building asphalt according to claim 1, it is characterized in that: the base oil with 12～52% is heated to 80-200 ℃, add 2～18% SBS and/or 0.1～16% SBR then, stirring melts to SBS and SBR dissolve fully after, after being warming up to 120～250 ℃, again/or add 0.1～26% PE and/or 0.1～9% titanium oxide and surplus petroleum resin, add 2～20% ferric oxide at last, after stirring, promptly obtain building stone oil base modified color asphaltic products..
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| CNB2006101131636A CN100572444C (en) | 2006-09-18 | 2006-09-18 | A kind of colored modified building asphalt and preparation method thereof |
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|---|---|---|---|
| CNB2006101131636A CN100572444C (en) | 2006-09-18 | 2006-09-18 | A kind of colored modified building asphalt and preparation method thereof |
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| CN101148534A true CN101148534A (en) | 2008-03-26 |
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| CN101838510A (en) * | 2010-06-02 | 2010-09-22 | 安徽三缔沥青材料有限公司 | High efficiency resin fissures cementation glue and preparation thereof |
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| CN102796385B (en) * | 2011-05-26 | 2016-03-09 | 上海嘉亘材料科技有限公司 | Superpolymer Warm-Mix Bitumen Mixture plasticized modifier |
| CN102796385A (en) * | 2011-05-26 | 2012-11-28 | 上海嘉亘材料科技有限公司 | High-polymer warm-mixed asphalt mixture toughening modifier |
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