CN101144215B - 经颜色涂布的防污导电布和其制造方法 - Google Patents

经颜色涂布的防污导电布和其制造方法 Download PDF

Info

Publication number
CN101144215B
CN101144215B CN200610127564.7A CN200610127564A CN101144215B CN 101144215 B CN101144215 B CN 101144215B CN 200610127564 A CN200610127564 A CN 200610127564A CN 101144215 B CN101144215 B CN 101144215B
Authority
CN
China
Prior art keywords
resin
cloth
conductive fabric
conductive
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200610127564.7A
Other languages
English (en)
Other versions
CN101144215A (zh
Inventor
张峯彰
卓新峰
郑建文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUMAO INDUSTRIAL Co Ltd
Formosa Taffeta Co Ltd
Original Assignee
FUMAO INDUSTRIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUMAO INDUSTRIAL Co Ltd filed Critical FUMAO INDUSTRIAL Co Ltd
Priority to CN200610127564.7A priority Critical patent/CN101144215B/zh
Priority to AT07116227T priority patent/ATE543945T1/de
Priority to EP07116227A priority patent/EP1903140B1/en
Publication of CN101144215A publication Critical patent/CN101144215A/zh
Application granted granted Critical
Publication of CN101144215B publication Critical patent/CN101144215B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1651—Two or more layers only obtained by electroless plating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28—Sensitising or activating
    • C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/48—Coating with alloys
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/041—Conductive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/046—Anti-static
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0807—Coloured

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明涉及一种经颜色涂布的防污导电布和其制造方法。所述方法包含提供以天然纤维或人造纤维织成并包含金属层的导电布，以及以刮刀涂布方式在导电布的金属层上形成至少一个有色树脂涂层，其中树脂涂层表面不超过导电布的经纬向纱线的交叉凸点。本发明导电布具有有色外观、人为或环境污染防止和低表面电阻等特性。

Description

经颜色涂布的防污导电布和其制造方法
技术领域
本发明涉及导电布的技术领域，尤其指具有低表面电阻并经颜色涂布的防污导电布，和其制造方法。
背景技术
现有导电布一般是将布料进行无电解电镀以形成金属化织物，当电镀铜时导电布外观呈金属铜色、镀铜镀镍呈银灰色、镀银呈银白色或镀金呈金色。导电布柔软、光滑且透气，并具有重量轻和易裁剪等优点。然而，由于导电布的表面金属化的结果，导电布无法使用一般布料的染色技术染色，相比于颜色多样化的一般布料，导电布的外观单调且在应用上的限制较大。
此外，由于导电布的表面层为铜、镍、银或金等金属，容易受到使用环境的温度、湿度影响，并且在作业时易受到手痕或其它接触影响，造成氧化、手痕、外观污染或表面电阻升高等缺陷。
常规上有以聚氨酯树脂或丙烯酸树脂等添加导电碳黑后涂布于导电布上，成为具有黑色导电性涂层的导电布。由于所涂的碳黑厚度厚，而且碳黑导电性为约1Ω至约1000Ω，使得具有碳黑涂层的导电布无法保持原来导电布的低表面电阻。一般来说，导电布的表面电阻为约0.007Ω/□至约1Ω/□。此外，碳黑的黑色度不足以显现亮丽的黑色度，甚至只有单一的黑色选择，对产品应用的选择有极大的限制。
由于现有导电布具有颜色限制和易受环境影响等缺陷，因此确有必要加以改良。
发明内容
为了改善上述现有导电布的限制和缺陷，本发明的主要目的在于提供一种可以在其上形成颜色、可防止人为或环境影响其特性并保持原有低表面电阻的导电布。
本发明的另一目的在于提供一种经颜色涂布的防污导电布的制造方法，其包含下列步骤：提供以天然纤维或人造纤维织成并包含金属层的导电布；以及在导电布的金属层上形成至少一个有色树脂涂层；所述方法的特征在于所述树脂涂层表面不超过导电布的经纬向纱线的交叉凸点。
附图说明
无
具体实施方式
在本发明的具体实施例中，经颜色涂布的防污导电布的制造方法包含以下步骤：提供以天然纤维或人造纤维织成的布料；利用无电解电镀在布料表面均匀镀上金属层，成为具导电性的导电布；将颜料与树脂调制成有色树脂涂布配方；以及在导电布的金属层上，涂布至少一个有色树脂的薄涂层，例如涂布一层至四层以调整涂层的颜色深浅，每层涂层是涂布到布料的凹点区域，但不超过布料的经纬向纱线的交叉凸点。
上述方法所使用的天然纤维可以是任何天然纤维，例如但不限于，棉、麻、丝或毛；人造纤维可以是任何人造纤维，例如但不限于，嫘萦纤维(rayon fiber)、尼龙纤维、聚酯纤维或丙烯酸纤维。
上述无电解电镀法是所述领域技术人员所熟知的，其中所使用的金属可为任何导电性良好的金属，例如，但不限于，铜、镍、银、金或其合金。
上述方法所使用的颜料可以是具有任何颜色的染料，如黑色碳黑、有机黑、红、蓝、绿、金等颜料或由任何需要的颜色的染料调制而得，其用量为树脂涂布配方的约1％至约20％。树脂可为溶剂型或水性树脂，例如，但不限于，聚氨酯树脂、聚酯树脂、丙烯酸树脂、乳胶树脂或硅酮树脂，其用量为树脂涂布配方的约10％至约70％。
在本发明的优选实施例中，树脂涂布配方可视需要添加交联剂，例如，但不限于，异氰酸酯(isocyanate)或三聚氰胺(melamine)，其用量为树脂涂布配方的约1％至约10％；及溶剂，例如但不限于甲苯(toluene)、丁酮(methy ethyl ketone；MEK)、二甲基甲酰胺(dimethylformamide；DMF)，其用量为树脂涂布配方的约30％至60％，以将树脂涂布配方稀释到约1000cps至约20000cps的粘度。
在上述方法中，涂布有色树脂的薄涂层的方法是所述领域技术人员所熟知的，例如但不限于刮刀涂布方式、雕刻滚筒涂布方式、喷涂喷洒方式或浸渍压吸搭配刮刀将多余表面树脂刮除方式等以形成薄涂层。
在本发明的优选实施例中，刮刀涂布方式可以悬浮式刮刀涂布，以精确控制各涂层的涂布量。在本发明方法的优选实施例中，刀具可为J型刀或U型刀，刀厚度为约0.5mm至约5mm，刀具下压导电布接触面约0.5mm至约20mm，1次涂布量为约0.1g/M2至约8g/M2，涂布后以约80℃至约160℃烘干约1分钟至约3分钟。
本发明另提供一种经颜色涂布的防污导电布，其包含以天然纤维或人造纤维织成并包含金属层的导电布，及至少一个有色树脂涂层以刮刀方式涂布在导电布的金属层上，其中树脂涂层表面不超过导电布的经纬向纱线的交叉凸点。所述导电布在涂布有色树脂涂层前的表面电阻为约0.007Ω/□至约0.1Ω/□，而在涂布有色树脂涂层后的表面电阻为约0.007Ω/□至约0.1Ω/□。
本发明是利用低涂布量涂布且多次涂布均不超过导电布的经纬纱交叉凸点的技术，以在导电布的单面或双面涂布所需的颜色，使得导电布呈现具有均匀颜色且色度深的外观，导电布的表面金属层由于薄树脂涂层的保护而不会被人为或环境影响其外观和导电性能，且经颜色涂布的导电布表面仍然具有与原导电布相同的导电性能，不会因为涂布涂层过厚而使其表面电阻升高。
本发明导电布具有有色外观、人为或环境污染防止和低表面电阻等特性。本发明的导电布经由涂布或贴合导电压敏胶或热熔胶后，可成为导电布胶带、导电布泡棉或导电布衬垫，且具有防辐射、防静电等特性，可以防止因电子机器泄漏的电磁波影响自身或其它电子机器而产生误动作。
以下实施例仅用于对本发明作进一步说明，而不是限制本发明的范围。任何所述领域技术人员可轻易达成的修正和改变均包括于本案说明书公开内容与所附权利要求书的保护范围之内。
实施例1：经颜色涂布的防污导电布的制备
进行下列步骤以制得经颜色涂布的防污导电布：
织布：以聚酯纤维织成具有经向50旦尼尔/36纤维数、纬向50旦尼尔/72纤维数、经向密度152条/英寸和纬向密度124条/英寸，及厚度为0.1mm的平织布料。
无电解电镀：将布料经过精练洗净、热定型、表面粗化和表面调整后，进行无电解电镀铜与镍以将布料金属化；
其中无电解电镀是所述领域技术人员所熟知的工艺，其包含以下步骤，活化：在30℃下，将布料在包含氯化钯100mg/L、氯化亚锡10g/L和盐酸100ml/L的溶液中浸渍3分钟，然后完全洗净；接着速化：在45℃下，将布料在盐酸100ml/L中浸渍3分钟，然后完全洗净；之后进行无电解镀铜：在40℃下，将布料在包含硫酸铜10g/L、甲醛7.5ml/L、氢氧化钠8g/L、乙二胺四醋酸四钠盐(ethylene diamine tetraacetic acidtetrasodium salt；EDTA-4Na)30g/L及稳定剂0.25ml/L的溶液中浸渍20分钟，以在布料上均匀镀上金属铜25克/M2，然后完全洗净；接着进行无电解镀镍：在40℃下，将布料在包含硫酸镍22.5g/L、次亚磷酸钠18g/L、柠檬酸钠0.1M/L及氨水20ml/L的溶液中浸渍5分钟，以在布料上均匀镀上金属镍5克/M2，然后完全洗净，最后进行烘干，制得银灰色导电布。
以JIS K-7194，Mitsubish Loresta MCP-T600进行四点探针测试法，将测试探针放在布料的表面上测试表面电阻；测得所制银灰色导电布具有约0.03Ω/□的表面电阻。
制备树脂涂布配方：将二液型聚氨酯树脂100克、异氰酸酯9克、丁酮50克、黑色碳黑5克及黑色颜料5克(其中黑色颜料包含32％碳黑、3％分散剂、20％丙烯酸树脂及45％载体)混合以形成底部涂布配方，其粘度为约5000cps；以及将一液型聚氨酯树脂100克、异氰酸酯3克、丁酮50克、黑色碳黑10克及黑色颜料10克(其中黑色颜料包含32％碳黑、3％分散剂、20％丙烯酸树脂及45％载体)混合以形成面料涂布配方，其粘度为约4000cp。
刮刀涂布：以悬浮式机台将调制好的树脂涂布配方涂布在导电布的金属层上，其中所述机台使用刀厚度2mm的J型刀，刀具下压导电布接触面2mm的条件。先以底部涂布配方在导电布上涂布约5克/M2，覆盖布料的凹点区域，但不超过布料的经纬向纱线的交叉凸点，接着以约120℃烘烤约1分钟，再以面料涂布配方涂布约5克/M2在布料的凹点区域上，同样不超过布料的经纬向纱线的交叉凸点，再以约120℃烘烤约1分钟，以形成经颜色涂布的防污导电布。
比较例1：经碳黑涂布的防污导电布的制备
同实施例1的织布和无电解电镀步骤，形成具有约0.03Ω/□的表面电阻的银灰色导电布，接着在导电布的金属层上涂布包含导电碳黑的树脂涂布配方。首先，以包含二液型聚氨酯树脂100克、丁酮50克、异氰酸酯9克及导电碳黑5克，且粘度约5000cps的底部树脂涂料配方，在导电布上形成底部涂层，接着以包含一液型聚氨酯树脂100克、丁酮50克、异氰酸酯3克及导电碳黑10克，且粘度约4000cps的面料树脂涂料配方，在导电布上形成表面涂层，底部涂层的面料涂层的干膜总厚度为约0.08mm，以制得经碳黑涂布的灰黑色防污导电布。
表I列出实施例1与比较例1所制得导电布和未经涂布的导电布的布料颜色、布料厚度、表面电阻、防污性能以及屏蔽性能。
防污性能是以裁剪经向和纬向10厘米×10厘米的导电布料测试样，测试手痕对材料表面污染性和残留痕迹，其中○表示几乎无污染痕迹，△表示少许污染痕迹，以及×表示污染痕迹非常严重)。
表I
  未经涂布的布料   比较例1   实施例1
  布料颜色   银灰色   灰黑色   深黑色
  布料厚度   0.1mm   0.18mm   0.1mm
  表面电阻   0.03Ω/□   0.08Ω/□   0.03Ω/□
  防污性能   ×   △   ○
  屏蔽性能   80dB   80dB   80dB
综上所述，本发明是以低涂布量涂布，配合有色树脂涂布配方，使得导电布呈现有色外观，且不会影响原有导电布表面的导电性能，并具有抗氧化脏污、人为或环境污染防止和性能稳定持久等特点，对于导电布的实用领域范围确有极大的帮助。

Claims (10)

1.一种经颜色涂布的防污导电布的制造方法，其包含下列步骤：
提供以天然纤维或人造纤维织成并包含金属层的导电布；以及
以刮刀涂布方式在所述导电布的金属层上形成至少一个有色树脂涂层，其中所述树脂涂层表面不超过导电布的经纬向纱线的交叉凸点。
2.如权利要求1所述的制造方法，其中所述金属层通过无电解电镀铜、镍、银、金或其合金而形成。
3.如权利要求1所述的制造方法，其中所述有色树脂涂层包含1％至20％颜料和1％至70％树脂。
4.如权利要求3所述的制造方法，其中所述树脂包含溶剂型或水性聚氨酯树脂、聚酯树脂、丙烯酸树脂、乳胶树脂或硅酮树脂。
5.如权利要求3所述的制造方法，其中所述有色树脂涂层另包含1％至10％交联剂和30％至60％溶剂，且其中所述交联剂包含异氰酸酯或三聚氰胺，以及所述溶剂包含甲苯、丁酮或二甲基甲酰胺。
6.一种经颜色涂布的防污导电布，其包含以天然纤维或人造纤维织成并包含金属层的导电布，及至少一个有色树脂涂层以刮刀方式涂布在所述导电布的金属层上，其中所述树脂涂层表面不超过导电布的经纬向纱线的交叉凸点。
7.如权利要求6所述的防污导电布，其中所述金属层通过无电解电镀铜、镍、银、金或其合金而形成。
8.如权利要求6所述的防污导电布，其中所述有色树脂涂层包含1％至20％颜料和1％至70％树脂。
9.如权利要求8所述的防污导电布，其中所述树脂包含溶剂型或水性的聚氨酯树脂、聚酯树脂、丙烯酸树脂、乳胶树脂或硅酮树脂。
10.如权利要求8所述的防污导电布，其中所述有色树脂涂层另包含1％至10％交联剂和30％至60％溶剂，且其中所述交联剂包含异氰酸酯或三聚氰胺，以及所述溶剂包含甲苯、丁酮或二甲基甲酰胺。
CN200610127564.7A 2006-09-12 2006-09-12 经颜色涂布的防污导电布和其制造方法 Active CN101144215B (zh)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN200610127564.7A CN101144215B (zh) 2006-09-12 2006-09-12 经颜色涂布的防污导电布和其制造方法
AT07116227T ATE543945T1 (de) 2006-09-12 2007-09-12 Farbbeschichteter, verschmutzungsresistenter, leitfähiger stoff und herstellungsverfahren dafür
EP07116227A EP1903140B1 (en) 2006-09-12 2007-09-12 Color-coated, fouling-resistant conductive cloth and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200610127564.7A CN101144215B (zh) 2006-09-12 2006-09-12 经颜色涂布的防污导电布和其制造方法

Publications (2)

Publication Number Publication Date
CN101144215A CN101144215A (zh) 2008-03-19
CN101144215B true CN101144215B (zh) 2011-05-18

Family

ID=38776243

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200610127564.7A Active CN101144215B (zh) 2006-09-12 2006-09-12 经颜色涂布的防污导电布和其制造方法

Country Status (3)

Country Link
EP (1) EP1903140B1 (zh)
CN (1) CN101144215B (zh)
AT (1) ATE543945T1 (zh)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012112153B4 (de) 2012-12-12 2018-05-09 Rembert Born Verfahren zur Herstellung einer textilbasierten Elektrode sowie textilbasierte Elektrode
DE102013225702A1 (de) 2013-12-12 2015-06-18 Rembert Born Textilbasierte Elektrode, Verfahren zu deren Herstellung sowie Verwendung
CN105754512A (zh) * 2016-03-28 2016-07-13 江苏伊诺尔新材料科技有限公司 雾面防指纹、抗刮导电布单面胶带及制备方法
CN109733012B (zh) * 2019-01-02 2020-10-13 中国船舶重工集团公司第七二五研究所 一种基于仿生强韧化结构的防污材料及其制备方法
CN114086402B (zh) * 2021-12-02 2022-12-09 湖南昇通新材料科技有限公司 一种超低电阻黑色导电布及其制备方法
CN114921963B (zh) * 2022-04-29 2023-08-25 安安(中国)有限公司 一种合成革的生产工艺及金属镂空合成革

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1232102A (zh) * 1998-04-14 1999-10-20 江都市第一绳网厂 涂覆式阻燃密目立网及其制造方法
CN1518852A (zh) * 2002-06-24 2004-08-04 古河电气工业株式会社 电磁波屏蔽垫片
CN1737248A (zh) * 2005-07-13 2006-02-22 安徽大学 水系聚氨酯－含硅丙烯酸树脂织物涂层胶的辐射聚合方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0448697A (ja) 1990-06-13 1992-02-18 Kowa Kogyosho:Kk 電磁シールド材およびその製造方法
JP4112075B2 (ja) 1998-05-29 2008-07-02 セーレン株式会社 導電性布帛とその製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1232102A (zh) * 1998-04-14 1999-10-20 江都市第一绳网厂 涂覆式阻燃密目立网及其制造方法
CN1518852A (zh) * 2002-06-24 2004-08-04 古河电气工业株式会社 电磁波屏蔽垫片
CN1737248A (zh) * 2005-07-13 2006-02-22 安徽大学 水系聚氨酯－含硅丙烯酸树脂织物涂层胶的辐射聚合方法

Also Published As

Publication number Publication date
ATE543945T1 (de) 2012-02-15
EP1903140B1 (en) 2012-02-01
CN101144215A (zh) 2008-03-19
EP1903140A1 (en) 2008-03-26

Similar Documents

Publication Publication Date Title
CN101144215B (zh) 经颜色涂布的防污导电布和其制造方法
US8173555B2 (en) Color-coated, fouling-resistant conductive cloth and manufacturing method thereof
US8507102B1 (en) Conductive leather materials and methods for making the same
Huang et al. Smart color-changing textile with high contrast based on a single-sided conductive fabric
US6311350B1 (en) Interactive fabric article
US20160015100A1 (en) Material for use with a capacitive touch screen
CA2673501C (en) Heating fabric and method for fabricating the same
CN101153462B (zh) 弹性导电布的制造方法
JP2009155765A (ja) 低発塵性導電糸及びその製造方法
US20060098286A1 (en) Retroreflective materials
CN106906497A (zh) 一种深枪色电磁屏蔽材料及其制备方法
EP1210817A2 (en) Retroreflective materials
CN101338513A (zh) 压花导电布的制造方法
JP2020059952A (ja) 遮熱性繊維布帛及びそれを用いた衣服
JP2000208984A (ja) 電磁波シ―ルド材およびその製造方法
Chen et al. An electrothermochromic fabric prepared by electrodeposition of polypyrrole on single side
Lou et al. Development of camouflage fabric based on continuous thermochromic and electrothermal material
CN110216941A (zh) 一种防水聚氨酯涂层装饰布
CN216268007U (zh) 一种基于镀铝膜的不掉绒植绒桌布
CN117021721A (zh) 一种圆网转移法高亮度反光印花面料的生产工艺及面料
JP3010175B2 (ja) 電磁波シールド効果を有する天然皮革製品
CN220615291U (zh) 可数码打印的珠光刻字膜
CN102041701A (zh) 磁控溅射金属银镀覆纺织面料形成图案的方法
CN115897260A (zh) 一种涂覆有导电墨水的耐水洗智能织物及其制备方法
JP3105972U (ja) 鏡面状の装飾体と装飾体作成用の転写シート

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant