CN101144005A - Nano hydrophobic thermal insulation material and preparation method thereof - Google Patents
Nano hydrophobic thermal insulation material and preparation method thereof Download PDFInfo
- Publication number
- CN101144005A CN101144005A CNA2007100530192A CN200710053019A CN101144005A CN 101144005 A CN101144005 A CN 101144005A CN A2007100530192 A CNA2007100530192 A CN A2007100530192A CN 200710053019 A CN200710053019 A CN 200710053019A CN 101144005 A CN101144005 A CN 101144005A
- Authority
- CN
- China
- Prior art keywords
- component
- thermal insulation
- group
- emulsion
- insulation material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a nano-hydrophobic heat insulating thermal insulation material and a method for preparing the same, which is formulated by A component and B component, wherein the A component mainly comprises polymer emulsion, modified polypropylene cellulose, nano-active calcium carbonate, and silicate mineral, which are well-mixed followed by grouping; and the B component is cement; when used, the A component and the B component are mixed uniformly to get nano-hydrophobic heat insulating thermal insulation material. The invention is characterized in that the product of the invention, which belongs to inorganic thermal insulation material, has long service life, anti-aging performance, and good fireproof performance, and the material per se has hydrophobic performance, decreases thermal conductivity, better thermal insulation performance, good pressure resistant intensity and bonding strength, no crack, no abscission, no pollution to environment, good product workability, easy operation and short construction period.
Description
Technical field
The present invention relates to a kind of nano hydrophobic thermal insulation material and preparation method thereof, belong to building material technical field, product is used in the heat-proof insulation waterproof of interior exterior wall, roofing, vault etc.
Background technology
In recent years, along with the raising of environmental protection and " green " engine request, building energy conservation is extremely urgent, and building energy conservation has become the main contents of carrying out national environmental protection and save energy policy, becomes the important component part of implementing national economy sustainable development.The rational Application of development External Walls Heating Insulation and insulating wall material is to realize the main mode of building energy conservation.Existing heat-insulation and heat-preservation material mainly contains inorganic and organic heat-insulation and heat-preservation material two big classes, the fire prevention ageing resistance of inorganic heat insulation material is good, but water-repellancy is poor, and water is the formidable enemy of external thermal insulation system, when external thermal insulation system seeps water or leaks, heat-insulating property is reduced, even completely lose.In winter, the volumetric expansion 9% of can freezing of the water of infiltration, thus producing expansion stress, these can cause catastrophic destruction to external thermal insulation system.Rodent gas is as CO
2, SO
2Deng, also be to become acid by water to cause external thermal insulation system to damage, simultaneously moisture also can with interactions such as plaster, gypsum, thereby cause thermal insulation layer efflorescence, come off.And organic heat-insulation and heat-preservation material mainly contains polystyrene and urethane, though this class material has less thermal conductivity, but fire line is poor, produces obnoxious flavour during high temperature, and easily degraded is aging, life-span is short, for example the patent No. is ZL200410013231.2, and denomination of invention is heat insulation heat preservation energy-saving waterproof and method for formulating thereof, the granular polystyrene in the used batching, just there is above-mentioned shortcoming, so China lacks the good inorganic heat insulation material of effective heat insulation heat preservation energy-saving waterproof.
Summary of the invention
Problem to be solved by this invention is exactly to provide a kind of nano hydrophobic thermal insulation material at the deficiency of above-mentioned prior art existence, it has excellent hydrophobic, thermal and insulating performance and fire prevention ageing-resistant performance (can with same life-span of buildings), not hollowing cracking, ultimate compression strength and cohesive strength height, and compound method and construction technology are simple, easy to operate, constant product quality, the pollution-free feature of environmental protection.
The technical scheme of nanometer hydrophobicity heat-insulation and heat-preservation material of the present invention is: nano hydrophobic thermal insulation material, and it is formulated by A component and B component, and wherein A component main component is counted by weight:
Emulsion polymerization: 500～600
Modified polypropylene fiber: 2～3
Nm-class active calcium carbonate: 500～600
Silicate mineral: 30～48
It is standby to organize the grouping of 40 parts by weight by each after mixing, and has some groups;
B component main component is counted by weight:
Cement: 6～8 is one group;
In use, A component and each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Press such scheme, described emulsion polymerization is any one or the multiple mixing in acrylic type emulsion, styrene-acrylic emulsion, polyvinyl alcohol type emulsion, polyethylene vinyl acetate type emulsion, Mierocrystalline cellulose emulsion, the ether of cellulose emulsion.
Preparation method's of the present invention technical scheme is: it comprises the steps:
The first step: preparation A component:
A. the weight part of each component is:
Emulsion polymerization: 500～600
Modified polypropylene fiber: 2～3
Nm-class active calcium carbonate: 500～600
Silicate mineral: 30～48;
B. mix: the emulsion polymerization raw material is added in the agitator stir, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 10-30min, silicate mineral is added stir 5～10min at last, promptly get the A component to evenly;
C. packing A component: mix the back and organizes the grouping of 40 weight parts, have some groups by each;
Second step: preparation B component:
By one group of 6-8 weight part grouping, has cement at least one group;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A and one group of B component;
B. in use, A component and the mixing of B component two components got ready are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Characteristics of the present invention are:
1. product of the present invention belongs to inorganic heat insulation material, its long service life (can with same life-span of buildings), ageing-resistant, fire resistance is good, having substituted the patent No. with perlite or glass bead is expanded polystyrene particle in the technical scheme of the ZL200410013231.2 used batching, make the long service life (can with same life-span of buildings) of product, fire protection flame retarding is good;
2. with the A component water-intake rate bigger perlite or glass bead have been carried out surface treatment, make the surface wettability of perlite or glass bead that counter-rotating take place, transform for hydrophobic nature by original water-absorbent, make material itself have hydrophobicity performance, had " lotus leaf effect ", promptly water droplet becomes globule shape on material, just as water droplet on lotus leaf, water is not absorbed by material;
3. having substituted the patent No. with nm-class active calcium carbonate is calcium stearate or Zinic stearas in the masterbatch used in the technical scheme of ZL200410013231.2, because of the thermal conductivity of nm-class active calcium carbonate little than treated carbonates, so adding of the nm-class active calcium carbonate that heat-proof quality is good, make the thermal conductivity of material diminish, heat preservation and insulation is better, better in the actual application in engineering effect of a plurality of roofings, through actual detected, on the steel tile roofing of factory building, do thick this material of 1cm, can make the roofing temperature reduce by 10～15 degree, the house roof temperature reduces by 8～10 degree.
4. ultimate compression strength and cohesive strength are good, do not ftracture, and do not come off environmentally safe;
5. the product workability is good, is convenient to construction, and the duration is short.
Embodiment
Example 1, described nano hydrophobic thermal insulation material A component: polyvinyl alcohol type emulsion 450Kg, acrylic type emulsion 50Kg, modified polypropylene fiber 2Kg, nm-class active calcium carbonate 500Kg, glass bead 30Kg, standby after mixing by 40Kg one component group; Each group of B component is: label is 42.5 black cement 6Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Example 2. described nano hydrophobic thermal insulation material A components: polyvinyl alcohol type emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose (ether) emulsion 100Kg, modified polypropylene fiber 3Kg, nm-class active calcium carbonate 600Kg, perlite 48Kg, standby after mixing by 40Kg one component group; Each group of B component is: label is 32.5 black cement 8Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Example 3. described nano hydrophobic thermal insulation material A components: polyvinyl alcohol emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose (ether) emulsion 50Kg, modified polypropylene fiber 2.5Kg, nm-class active calcium carbonate 550Kg, glass bead 38.5Kg, it is standby that 40Kg one component group is pressed in the mixing back; Each group of B component is: label is 32.5 white cement 7Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Example 4. described nano hydrophobic thermal insulation material A components: acrylic type emulsion 550Kg, modified polypropylene fiber 2.8Kg, nm-class active calcium carbonate 560Kg, glass bead 40Kg, it is standby that 40Kg one component group is pressed in the mixing back; Each group of B component is: label is 42.5 white cement 7Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
The preparation method of described nano hydrophobic thermal insulation material is embodiment.
Embodiment 1:
The first step: preparation A component:
A.A component composition: polyvinyl alcohol type emulsion 450Kg, acrylic type emulsion 50Kg, modified polypropylene fiber 2Kg, nm-class active calcium carbonate 500Kg, glass bead 30Kg;
B. mix: polyvinyl alcohol type emulsion, acrylic type emulsion raw material are added to mix in the agitator stir, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 20min (also can stir 10min or 30min), at last glass bead is added and stir 10min, promptly get the A component to evenly;
C. packing A component: stir the back by one group of 40kg, be distributed into some groups;
Second step: preparation B component:
Be that 42.5 black cement divides into groups by one group of 6kg with label;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A40kg and one group of B component 6kg;
B. in use, the one group of component A that gets ready mixed with one group of B component mix thoroughly, promptly get nano hydrophobic thermal insulation material.
This finished product must use up in three hours.
Embodiment 2:
The first step: preparation A component:
A.A component composition: polyvinyl alcohol type emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose (ether) emulsion 100Kg, modified polypropylene fiber 3Kg, nm-class active calcium carbonate 600Kg, perlite 48Kg;
B. mix: polyvinyl alcohol type emulsion, acrylic type emulsion and Mierocrystalline cellulose (ether) emulsion raw material are added in the agitator mix, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 20min (also can stir 10min or 30min), at last perlite is added and stir 10min, promptly get the A component to evenly;
C. packing A component: stir the back by one group of 40kg, be distributed into some groups;
Second step: preparation B component:
Be that 32.5 black cement divides into groups by one group of 8kg with label;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A40kg and one group of B component 8kg;
B. in use, the one group of component A that gets ready mixed with one group of B component mix thoroughly, promptly get nano hydrophobic thermal insulation material.
This finished product must use up in three hours.
Embodiment 3:
The first step: preparation A component:
A.A component composition: polyvinyl alcohol emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose (ether) emulsion 50Kg, modified polypropylene fiber 2.5Kg, nm-class active calcium carbonate 550Kg, glass bead 38.5Kg;
B. mix: the polyvinyl alcohol emulsion, acrylic type emulsion and Mierocrystalline cellulose (ether) emulsion raw material adds in the agitator and mixes, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 20min (also can stir 10min or 30min), at last glass bead is added and stir 10min, promptly get the A component to evenly;
C. packing A component: stir the back by one group of 40kg, be distributed into some groups;
Second step: preparation B component:
Be that 32.5 white cement divides into groups by one group of 7kg with label;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A40kg and one group of B component 7kg;
B. in use, the one group of component A that gets ready mixed with one group of B component mix thoroughly, promptly get nano hydrophobic thermal insulation material.
This finished product must use up in three hours.
Embodiment 4:
The first step: preparation A component:
A.A component composition: acrylic type emulsion 550Kg, modified polypropylene fiber 2.8Kg, nm-class active calcium carbonate 560Kg, glass bead 40Kg;
B. mix: the acrylic type emulsion is added in the agitator stir, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 20min (also can stir 10min or 30min), glass bead is added stir 10min at last, promptly get the A component to evenly;
C. packing A component: stir the back by one group of 40kg, be distributed into some groups;
Second step: preparation B component:
Be that 42.5 white cement divides into groups by one group of 7kg with label;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A40kg and one group of B component 7kg;
B. in use, the one group of component A that gets ready mixed with one group of B component mix thoroughly, promptly get nano hydrophobic thermal insulation material.
This finished product must use up in three hours.
The detection data of the nano hydrophobic thermal insulation material of above-mentioned preparation see Table one:
The detection data of table one nano hydrophobic thermal insulation material
| The performance title | Unit | The product detected result |
| Thermal conductivity | W/(m·k) | 0.075～0.085 |
| Ultimate compression strength | KPa | 300～600 |
| Heat storage coefficient | W/(m 2·k) | 2～3 |
| The hydrophobic rate | ％ | >99 |
And other products of the same type, it detects data all will be slightly poorer than product of the present invention.
Claims (9)
1. nano hydrophobic thermal insulation material, it is characterized in that: it is formulated by A component and B component, and wherein A component main component is counted by weight:
Emulsion polymerization: 500～600
Modified polypropylene fiber: 2～3
Nm-class active calcium carbonate: 500～600
Silicate mineral: 30～48
It is standby to organize the grouping of 40 parts by weight by each after mixing, and has some groups;
B component main component is counted by weight:
Cement: 6～8 is one group;
In use, A component and each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
2. by the described nano hydrophobic thermal insulation material of claim 1, it is characterized in that described emulsion polymerization is any one or the multiple mixing in acrylic type emulsion, styrene-acrylic emulsion, polyvinyl alcohol type emulsion, polyethylene vinyl acetate type emulsion, Mierocrystalline cellulose emulsion, the ether of cellulose emulsion.
3. by claim 1 or 2 described nano hydrophobic thermal insulation materials, it is characterized in that: described silicate mineral is glass bead or perlite.
4. by claim 1 or 2 described nano hydrophobic thermal insulation materials, it is characterized in that: described cement is that label is 42.5 black cement or white cement.
5. by claim 1 or 2 described nano hydrophobic thermal insulation materials, it is characterized in that: described cement is that label is 32.5 black cement or white cement.
6. by the described nano hydrophobic thermal insulation material of claim 2, it is characterized in that: the A component: polyvinyl alcohol type emulsion 450Kg, acrylic type emulsion 50Kg, modified polypropylene fiber 2Kg, nm-class active calcium carbonate 500Kg, silicate mineral 30Kg, standby after mixing by 40Kg one component group; Each group of B component is: cement 6Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
7. by the described nano hydrophobic thermal insulation material of claim 2, it is characterized in that: the A component: polyvinyl alcohol emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose emulsion or ether of cellulose emulsion 100Kg, modified polypropylene fiber 3Kg, nm-class active calcium carbonate 600Kg, silicate mineral 48Kg, standby after mixing by 40Kg one component group; Each group of B component is: cement 8Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
8. by the described nano hydrophobic thermal insulation material of claim 2, it is characterized in that: the A component: polyvinyl alcohol emulsion 450Kg, acrylic type emulsion 50Kg, Mierocrystalline cellulose emulsion or ether of cellulose emulsion 50Kg, modified polypropylene fiber 2.5Kg, nm-class active calcium carbonate 550Kg, silicate mineral 38.5Kg, it is standby that 40Kg one component group is pressed in the mixing back; Each group of B component is: cement 7Kg;
During use, A component, each the one group of mixing of B component are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
9. the preparation method of the described nano hydrophobic thermal insulation material of claim 1 is characterized in that, it comprises the steps:
The first step: preparation A component:
A. the weight part of each component is:
Emulsion polymerization: 500～600
Modified polypropylene fiber: 2～3
Nm-class active calcium carbonate: 500～600
Silicate mineral: 30～48;
B. mix: the emulsion polymerization raw material is added in the agitator stir, add modified polypropylene fiber and nm-class active calcium carbonate again and stir 10-30min, silicate mineral is added stir 5～10min at last, promptly get the A component to evenly;
C. packing A component: mix the back and organizes the grouping of 40 weight parts, have some groups by each;
Second step: preparation B component:
By one group of 6-8 weight part grouping, has cement at least one group;
The 3rd step: the mixed preparing before the construction:
A. get the raw materials ready in the ratio of one group of component A and one group of B component;
B. in use, A component and the mixing of B component two components got ready are mixed thoroughly, promptly get nano hydrophobic thermal insulation material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100530192A CN100567444C (en) | 2007-08-22 | 2007-08-22 | Nano hydrophobic thermal insulation material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100530192A CN100567444C (en) | 2007-08-22 | 2007-08-22 | Nano hydrophobic thermal insulation material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101144005A true CN101144005A (en) | 2008-03-19 |
| CN100567444C CN100567444C (en) | 2009-12-09 |
Family
ID=39206745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100530192A Expired - Fee Related CN100567444C (en) | 2007-08-22 | 2007-08-22 | Nano hydrophobic thermal insulation material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100567444C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219436A (en) * | 2011-04-04 | 2011-10-19 | 衡水利达宏业复合材料有限公司 | Heat-insulation coating and production method thereof |
| CN104072017A (en) * | 2014-07-04 | 2014-10-01 | 王祥林 | Hydrophobic inorganic gel powder compounded multifunctional insulating mortar, as well as application and preparation method thereof |
| CN105621997A (en) * | 2016-02-26 | 2016-06-01 | 李春松 | Flame-retardant heat preservation material |
| CN105669105A (en) * | 2016-02-26 | 2016-06-15 | 李春松 | Compound insulation material and preparation method thereof |
| CN105819781A (en) * | 2016-02-26 | 2016-08-03 | 李春松 | Heat insulation material |
| CN105819812A (en) * | 2016-02-26 | 2016-08-03 | 李春松 | Inorganic heat insulation material |
-
2007
- 2007-08-22 CN CNB2007100530192A patent/CN100567444C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219436A (en) * | 2011-04-04 | 2011-10-19 | 衡水利达宏业复合材料有限公司 | Heat-insulation coating and production method thereof |
| CN102219436B (en) * | 2011-04-04 | 2012-09-12 | 衡水利达宏业复合材料有限公司 | Heat-insulation coating and production method thereof |
| CN104072017A (en) * | 2014-07-04 | 2014-10-01 | 王祥林 | Hydrophobic inorganic gel powder compounded multifunctional insulating mortar, as well as application and preparation method thereof |
| CN105621997A (en) * | 2016-02-26 | 2016-06-01 | 李春松 | Flame-retardant heat preservation material |
| CN105669105A (en) * | 2016-02-26 | 2016-06-15 | 李春松 | Compound insulation material and preparation method thereof |
| CN105819781A (en) * | 2016-02-26 | 2016-08-03 | 李春松 | Heat insulation material |
| CN105819812A (en) * | 2016-02-26 | 2016-08-03 | 李春松 | Inorganic heat insulation material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100567444C (en) | 2009-12-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108706953B (en) | Homogeneous low thermally conductive inorganic heat-insulation board of one kind and preparation method thereof | |
| CN101628802B (en) | Composite inorganic heat insulation and waterproof mortar and application thereof | |
| CN100337967C (en) | Superlight vitrification micropearl morttar | |
| CN101314536B (en) | Energy-conservation environment-friendly type EPS light aggregate concrete and manufacture method thereof | |
| CN101921096B (en) | Inorganic heat-insulating dry powder mortar | |
| CN101948281B (en) | Cement polymer foam plastic powder light heat-insulating plate and preparation method thereof | |
| CN101007726B (en) | Wall-plastering mortar of architecture fencing wall | |
| CN100567444C (en) | Nano hydrophobic thermal insulation material and preparation method thereof | |
| CN103664122A (en) | Novel light-weight porous heat-insulating material and preparation method thereof | |
| CN104909666A (en) | Hybrid high-efficiency thermal-insulation material and preparation method thereof | |
| CN102659354B (en) | A-grade non-ignitable heat insulating material and preparation method thereof | |
| CN101357828B (en) | Method for preparing lightweight aggregate and inorganic insulation using product thereon as main insulation source | |
| CN107840612B (en) | High-strength light inorganic energy-saving heat-insulating building material and preparation method thereof | |
| CN102701676B (en) | Foam concrete material and preparation method thereof | |
| CN101182178A (en) | Special masonry mortar for self-insulating wall | |
| CN102093030A (en) | Inorganic composite heat insulation material and preparation method thereof | |
| CN101468897B (en) | Inorganic heat preserving and heat insulation material | |
| CN103467058A (en) | Method for preparing waterproof, antifouling, environment-friendly and flame retardant insulation board by using pitchstone beads | |
| CN101634169A (en) | External insulating system for thinly plastered external wall of extruded polystyrene board | |
| CN103183487A (en) | Preparation method of modified common silicate cement based foam insulating plate and special assistant | |
| CN102515689A (en) | Lightweight hollow perlite partition plate and preparation method thereof | |
| CN103044860B (en) | Composite foam heat insulating material and preparation method thereof | |
| CN103524106B (en) | A kind of fireproof heat insulation plate of outer wall and its production method | |
| KR20070107510A (en) | A mortar for concrete having polyurethane foam and method of thereof | |
| CN103274756A (en) | Micro-powder bubble cement fireproofing insulation board and production process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091209 Termination date: 20120822 |