CN101143985A - Low odor lacquer - Google Patents
Low odor lacquer Download PDFInfo
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- CN101143985A CN101143985A CNA2006100626415A CN200610062641A CN101143985A CN 101143985 A CN101143985 A CN 101143985A CN A2006100626415 A CNA2006100626415 A CN A2006100626415A CN 200610062641 A CN200610062641 A CN 200610062641A CN 101143985 A CN101143985 A CN 101143985A
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Abstract
The invention discloses a pyroxylin lacquer with low smell, wherein the pyroxylin lacquer has no benzene hydrocarbon, and the lacquer formula includes 10 percent-25 percent by weight of at least one resin, 25 percent-55 percent by weight of at least one of alcohol ether solvent, ester solvent or alcoholic solvent, , 20 percent-50 percent by weight of at least one curing agent, plasticizer and additive, the pyroxylin lacquer of the invention uses non-benzene solvent, and ensure the superiority of pyroxylin lacquer per se, so as to effectively avoid environmental pollution produced in production, construction and using process of the benzene hydrocarbon, and health hazard to production operator and constructer.
Description
Technical field:
The present invention relates to a kind of coating compositions, relate in particular to a kind of low odor lacquer of non-toluene solvent.
Background technology:
Various in the market lacquer coating types are various, and that pyroxylin(e)finish has is economical and practical, proportioning simple, good leveling property, feel are soft and smooth, fast drying, soft, the tough and tensile competent characteristic of film forming of gloss, and can show the timber native texture especially, the effect uniqueness, pyroxylin(e)finish relies on its excellent workability and enriches changeable effect, by wide selection on woodenware perforate (American application) finishing and hotel, market, automobile, train upholstery.But, all use benzene kind solvent in the at present existing pyroxylin(e)finish manufacturing prescription, as benzene,toluene,xylene, and aromatic hydrocarbon solvents such as benzene, dimethylbenzene produce anesthesia and hormesis to nerve system of human body, even more serious is that this solvent is a kind of carcinogenic substance, can cause marrow and genetic damage as long-term contact benzene, the blood picture inspection can be found white corpuscle, thrombopenia, even leukemia takes place; Toluene can produce infringement to neural system.This kind solvent is a class to human body and environment detrimental substance all.Therefore there are the serious problem of environmental pollution in the production and the workyard of pyroxylin(e)finish, and this will inevitably make site operation personnel and neighboring area population health be subjected to serious threat.Procuring equipment solves problem of environmental pollution in the production although the manufacturer can inject capital into, and for construction with use on-the-spotly, then can't fundamentally solve it to the pollution of environment with to the harm of workmen's health.This is a long-term existence and unresolved problem.
It is that 92105305.3 Chinese invention patent discloses a kind of water soluble internal use nitrocellulose lacquer without benzene poison that name is called " production method of water soluble internal use nitrocellulose lacquer without benzene poison ", the patent No., and its formula constituent (with weight percent) is made up of 6%-20% N-BUTYL ACETATE, 4%-15% vinyl acetic monomer, 5%-10% butanols, 20%-30% nitro-cotton, 10%-25% Synolac, 2%-3% softening agent, 40-50% deionized water, 3%-6% emulsifying agent, 1% dispersion agent and 10%-15% pigment.Though being primary solvent with water, this invention replaces making solvent production without benzene toxicity pyroxylin(e)finish with toluene and dimethylbenzene.But still all with the pyroxylin(e)finish of oil-based solvent a certain distance is arranged from the weather resistance aspect from decorative effect, therefore, this patent of invention still can't solve benzene and pollute and the murder by poisoning problem under the prerequisite of guaranteeing the high-performance of pyroxylin(e)finish own.
Summary of the invention:
Pollute and the murder by poisoning problem for solving the benzene that exists in the pyroxylin(e)finish production that exists in the prior art and the construction, and guarantee the high-performance of pyroxylin(e)finish own, the present invention proposes the technical solution of the pyroxylin(e)finish of following not containing benezene solvent:
The basal component of low odor lacquer prescription of the present invention comprises following composition, and weight percent is separately:
A, at least a resin, consumption are 10wt%-25wt%;
B, solvent: it is central at least a to be selected from pure ether solvent, esters solvent and alcoholic solvent, and consumption is 25wt%-55wt%;
C, additive: at least a in the middle of solidifying agent, softening agent and the auxiliary agent, consumption is 20wt%-50wt%.
After deliberation, better effects if when we find that described solvent is combination solvent, wherein pure ether solvent consumption 2wt%-5wt%, the esters solvent consumption is 10wt%-25wt%, the alcoholic solvent consumption is 15wt%-20wt%, and at this moment, described additive amount is 25%-50%.
For satisfying the special performance of pyroxylin(e)finish of the present invention better, the individual character requirement when satisfying construction can also be added this area additive in common knowledge, reaches as the adding solidifying agent and improves intensity; Suppleness when the interpolation softening agent can be promoted the pyroxylin(e)finish construction, auxiliary agent is meant leveling auxiliary agent, hides flavor auxiliary agent etc., this moment, described weight resin per-cent was 10wt%-20wt%, the weight percent of described additive is: solidifying agent 20wt%-25wt%, softening agent 5wt%-15wt%, auxiliary agent 1wt%-2wt%, described solvent load are 38%-55%.
Described resin is selected from the middle of the Synolac, Gum Rosin, soluble cotton at least a, we find that after deliberation described resin preferably is selected from fatty acid modified short oil-ity alcohol acid resin, Malin's acid modified rosin resin, central a kind of or its combination of soluble cotton.
In addition, adding the hardened resin of 0-4wt% and the flatting silica of 0-4wt% can optimize the performance of pyroxylin(e)finish of the present invention and can improve its gloss, at this moment, the weight percent of described resin is 10wt%-20wt%, and the weight percent of described solvent is 25wt%-50wt%; If select combination solvent for use, then pure ether solvent consumption 2wt%-5wt%, the esters solvent consumption is 10wt%-25wt%, the alcoholic solvent consumption is 15wt%-20wt%.。
For obtaining the pyroxylin(e)finish of white, can add the titanium dioxide of 0-4wt%.
Pure ether solvent of the present invention is selected ethylene glycol monobutyl ether for use, and described esters solvent is selected from one of 1-Methoxy-2-propyl acetate, butylacetate, ethyl acetate, methylcarbonate or its combination, and described alcoholic solvent is Virahol, ethanol.
Esters solvent of the present invention is selected from 1-Methoxy-2-propyl acetate, butylacetate, and described alcoholic solvent is a Virahol.
Solidifying agent of the present invention is a nitro-cotton, described softening agent is selected from the middle of the dibutyl phthalate, dioctyl phthalate (DOP), adipate polyester, epoxidised soybean oil at least a, and described auxiliary agent is that the leveling auxiliary agent that contains polysiloxane, the leveling auxiliary agent that contains CALCIUM ACRYLATE, froth breaking auxiliary agent, coating hide in the flavor auxiliary agent at least a.
Compared with prior art, pyroxylin(e)finish of the present invention uses non-toluene solvent, guarantee simultaneously the high-performance of pyroxylin(e)finish itself again, thereby effectively avoided environmental pollution that benzene kind solvent produces and to the harm of production operation personnel and workmen's health in production, construction and use, realized high-quality, environmental protection, harmless purpose.
Embodiment:
Further set forth technical scheme of the present invention below by embodiment:
Embodiment 1, and its prescription is as follows: Malin's acid modified rosin resin 250kg, and nitro-cotton 200kg, dibutyl phthalate 50kg, flow agent A10kg, flow agent B5kg, froth breaking auxiliary agent 5kg, 1-Methoxy-2-propyl acetate 480kg makes 1000kg varnish.
Embodiment 2, and its prescription is as follows: Malin's acid modified rosin resin 155kg, and nitro-cotton 225kg, dioctyl phthalate (DOP) 50kg, flow agent A15kg, flow agent B2kg, froth breaking auxiliary agent 3kg, ethyl acetate 500kg, ethylene glycol monobutyl ether 50kg makes varnish 1000kg.
Embodiment 3, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 155kg, nitro-cotton 250kg, dioctyl phthalate (DOP) 100kg, flow agent A15kg, flow agent B2kg, froth breaking auxiliary agent 3kg, ethyl acetate 225kg, Virahol 200kg, ethylene glycol monobutyl ether 50kg makes varnish 1000kg.
Embodiment 4, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 250kg, and nitro-cotton 250kg, adipate polyester 220kg, flow agent A25kg, flow agent B2kg, froth breaking auxiliary agent 3kg, ethyl acetate 150kg, Virahol 100kg makes varnish 1000kg.
Embodiment 5, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 100kg, nitro-cotton 300kg, dioctyl phthalate (DOP) 180kg, flow agent A15kg, flow agent B2kg, froth breaking auxiliary agent 3kg, ethyl acetate 250kg, Virahol 100kg, ethylene glycol monobutyl ether 50kg makes varnish 1000kg.
Embodiment 6, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 180kg, and dioctyl phthalate (DOP) 370kg, ethyl acetate 250kg, Virahol 150kg, ethylene glycol monobutyl ether 50kg makes varnish 1000kg.
Embodiment 7, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 155kg, nitro-cotton 220kg, dioctyl phthalate (DOP) 100kg, epoxidised soybean oil 50kg, flow agent A10kg, flow agent B1kg, froth breaking auxiliary agent 2kg, hide flavor auxiliary agent 5kg, 1-Methoxy-2-propyl acetate 225kg, ethanol 200kg, ethylene glycol monobutyl ether 32kg makes varnish 1000kg.
Embodiment 8, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 130kg, nitro-cotton 210kg, dioctyl phthalate (DOP) 90kg, dibutyl phthalate 60kg, flow agent A10kg, flow agent B1kg, froth breaking auxiliary agent 2kg hides flavor auxiliary agent 5kg, hardened resin 40kg, flatting silica 40kg, 1-Methoxy-2-propyl acetate 180kg, ethanol 200kg, ethylene glycol monobutyl ether 32kg makes varnish 1000kg.
Embodiment 9, and its prescription is as follows: fatty acid modified short oil-ity alcohol acid resin 190kg, nitro-cotton 220kg, dioctyl phthalate (DOP) 100kg, flow agent A10kg, flow agent B2kg, froth breaking auxiliary agent 2kg, hide flavor auxiliary agent 6kg, titanium dioxide 40kg, 1-Methoxy-2-propyl acetate 180kg, ethanol 200kg, ethylene glycol monobutyl ether 40kg makes white pyroxylin(e)finish 1000kg.
Flow agent A described in all embodiment is meant the leveling auxiliary agent that contains polysiloxane, and flow agent B is meant the leveling auxiliary agent that contains CALCIUM ACRYLATE, and titanium dioxide is a titanium dioxide powder.
Preparation process of the present invention comprises: solid material sieves earlier, mixes then, and adding liquid starting material remix is even, then adds solvent, stirs, and filters check, packing.
Claims (10)
1. low odor lacquer is characterized in that: the basal component of this paint formula and separately weight percent be:
A, at least a resin, consumption are 10wt%-25wt%;
B, solvent: it is central at least a to be selected from pure ether solvent, esters solvent and alcoholic solvent, and consumption is 25wt%-55wt%;
C, additive: at least a in the middle of solidifying agent, softening agent and the auxiliary agent, consumption is 20wt%-50wt%.
2. low odor lacquer according to claim 1, it is characterized in that: described solvent is a combination solvent, wherein pure ether solvent consumption 2wt%-5wt%, the esters solvent consumption is 10wt%-25wt%, the alcoholic solvent consumption is 15wt%-20wt%, and described additive amount is 25%-50%.
3. low odor lacquer according to claim 1, it is characterized in that: described weight resin per-cent is 10wt%-20wt%, described solvent load is 38%-55%, the weight percent of described additive is: solidifying agent 20wt%-25wt%, softening agent 5wt%-15wt%, auxiliary agent 1wt%-2wt%.
4. according to claim 1,2 or 3 described low odor lacquers, it is characterized in that: described resin is selected from the middle of the Synolac, Gum Rosin, soluble cotton at least a.
5. according to claim 1,2 or 3 described low odor lacquers, it is characterized in that: described resin is selected from the middle of fatty acid modified short oil-ity alcohol acid resin, Malin acid modified rosin resin, the soluble cotton at least a.
6. low odor lacquer according to claim 1 and 2 is characterized in that: the weight percent of described resin is 10wt%-18wt%, and adds the hardened resin of 0-4wt% and the flatting silica of 0-4wt%.
7. low odor lacquer according to claim 1 and 2 is characterized in that: the weight percent of described resin is 10wt%-18wt%, and adds the titanium dioxide of 0-4wt%.
8. low odor lacquer according to claim 1 and 2, it is characterized in that: described pure ether solvent is selected ethylene glycol monobutyl ether for use, described esters solvent is selected from one of 1-Methoxy-2-propyl acetate, butylacetate, ethyl acetate, methylcarbonate or its combination, and described alcoholic solvent is Virahol, ethanol.
9. low odor lacquer according to claim 8 is characterized in that: described esters solvent is selected from 1-Methoxy-2-propyl acetate, butylacetate, and described alcoholic solvent is a Virahol.
10. according to claim 1 or 2 described low odor lacquers, it is characterized in that: described solidifying agent is a nitro-cotton, described softening agent is selected from the middle of the dibutyl phthalate, dioctyl phthalate (DOP), adipate polyester, epoxidised soybean oil at least a, and described auxiliary agent is that the leveling auxiliary agent that contains polysiloxane, the leveling auxiliary agent that contains CALCIUM ACRYLATE, froth breaking auxiliary agent, coating hide in the flavor auxiliary agent at least a.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100626415A CN100467552C (en) | 2006-09-13 | 2006-09-13 | Low odor lacquer |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100626415A CN100467552C (en) | 2006-09-13 | 2006-09-13 | Low odor lacquer |
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| CN101143985A true CN101143985A (en) | 2008-03-19 |
| CN100467552C CN100467552C (en) | 2009-03-11 |
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| CN101386727B (en) * | 2008-10-24 | 2011-05-11 | 深圳市广田环保涂料有限公司 | Yellowing-resistant nitro white matt finish and preparation method thereof, use method |
| CN102433060A (en) * | 2011-10-19 | 2012-05-02 | 上海大宝化工制品有限公司 | Yellowing-resistance nitrolacquer |
| CN102604489A (en) * | 2012-03-20 | 2012-07-25 | 惠州市长润发涂料有限公司 | Water-based environment-friendly nitrolacquer and construction method for same |
| CN102757698A (en) * | 2012-06-28 | 2012-10-31 | 广东千叶松化工有限公司 | Low-VOC (Volatile Organic Compounds) nitrolacquer |
| CN102816527A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Super-scratch-resistant self volatilizing and curing paint |
| CN102888153A (en) * | 2011-07-19 | 2013-01-23 | 上海富臣化工有限公司 | Quick-drying roller-coating special-purpose general priming nitrolacquer |
| CN103013308A (en) * | 2012-11-27 | 2013-04-03 | 常州大学 | Novel environment-friendly polyester wood coating |
| CN103173067A (en) * | 2011-12-23 | 2013-06-26 | 上海富臣化工有限公司 | Oily yellow pulp and preparation method thereof |
| CN103409050A (en) * | 2013-08-16 | 2013-11-27 | 天津灯塔涂料工业发展有限公司 | Epoxy modified nitrocellulose enamel and preparation method thereof |
| CN103409056A (en) * | 2012-12-31 | 2013-11-27 | 东莞市泰发化工有限公司 | Ultrahard transparent PU (poly urethane) paint |
| CN103483912A (en) * | 2012-06-12 | 2014-01-01 | 上海富臣化工有限公司 | Oily red paste and preparation method thereof |
| CN103602108A (en) * | 2013-10-22 | 2014-02-26 | 芜湖市鸿坤汽车零部件有限公司 | Nitrolacquer and preparation method thereof |
| CN103722652A (en) * | 2013-12-30 | 2014-04-16 | 四川北方硝化棉股份有限公司 | Continuous preparation system and continuous preparation method of nitrocellulose chip |
| CN104263142A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Nitro-lacquer and preparation method thereof |
| CN104327604A (en) * | 2014-10-18 | 2015-02-04 | 刘星 | Nitro paint with dibutyl phthalate and preparation method of nitro paint |
| CN104497661A (en) * | 2014-12-23 | 2015-04-08 | 刘骏 | Environmental protection coating |
| CN105482563A (en) * | 2016-01-05 | 2016-04-13 | 安徽名士达涂料有限公司 | Odorless nitrocellulose lacquer and preparing method thereof |
| CN105670473A (en) * | 2014-11-21 | 2016-06-15 | 奥克化学扬州有限公司 | Environment-friendly nitro-lacquer |
| CN106398400A (en) * | 2016-09-22 | 2017-02-15 | 广东珠江化工涂料有限公司 | Environment-friendly nitrocellulose varnish and preparation method thereof |
| CN107189653A (en) * | 2017-07-18 | 2017-09-22 | 合肥峰腾节能科技有限公司 | A kind of weather-proof floor paint vehicle of high-performance environment-friendly and preparation method thereof |
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| CN101386727B (en) * | 2008-10-24 | 2011-05-11 | 深圳市广田环保涂料有限公司 | Yellowing-resistant nitro white matt finish and preparation method thereof, use method |
| CN102888153A (en) * | 2011-07-19 | 2013-01-23 | 上海富臣化工有限公司 | Quick-drying roller-coating special-purpose general priming nitrolacquer |
| CN102433060A (en) * | 2011-10-19 | 2012-05-02 | 上海大宝化工制品有限公司 | Yellowing-resistance nitrolacquer |
| CN103173067A (en) * | 2011-12-23 | 2013-06-26 | 上海富臣化工有限公司 | Oily yellow pulp and preparation method thereof |
| CN103173067B (en) * | 2011-12-23 | 2016-06-08 | 上海展辰涂料有限公司 | A kind of oiliness yellow pulp and preparation method thereof |
| CN102604489A (en) * | 2012-03-20 | 2012-07-25 | 惠州市长润发涂料有限公司 | Water-based environment-friendly nitrolacquer and construction method for same |
| CN102604489B (en) * | 2012-03-20 | 2013-11-13 | 惠州市长润发涂料有限公司 | Water-based environment-friendly nitrolacquer and construction method for same |
| CN103483912B (en) * | 2012-06-12 | 2016-06-08 | 上海展辰涂料有限公司 | A kind of oiliness redness slurry and its preparation method |
| CN103483912A (en) * | 2012-06-12 | 2014-01-01 | 上海富臣化工有限公司 | Oily red paste and preparation method thereof |
| CN102757698B (en) * | 2012-06-28 | 2014-08-13 | 广东千叶松化工有限公司 | Low-VOC (Volatile Organic Compounds) nitrolacquer |
| CN102757698A (en) * | 2012-06-28 | 2012-10-31 | 广东千叶松化工有限公司 | Low-VOC (Volatile Organic Compounds) nitrolacquer |
| CN102816527B (en) * | 2012-08-10 | 2016-12-21 | 三棵树涂料股份有限公司 | Super scratch resistance is coating material solidified from volatilization |
| CN102816527A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Super-scratch-resistant self volatilizing and curing paint |
| CN103013308A (en) * | 2012-11-27 | 2013-04-03 | 常州大学 | Novel environment-friendly polyester wood coating |
| CN103409056B (en) * | 2012-12-31 | 2016-04-27 | 东莞市泰发化工有限公司 | The transparent PU paint of a kind of ultrahard |
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| CN103409050B (en) * | 2013-08-16 | 2017-09-12 | 天津灯塔涂料工业发展有限公司 | A kind of epoxy modified nitrocellulose enamel and preparation method thereof |
| CN103602108A (en) * | 2013-10-22 | 2014-02-26 | 芜湖市鸿坤汽车零部件有限公司 | Nitrolacquer and preparation method thereof |
| CN103722652B (en) * | 2013-12-30 | 2015-10-28 | 四川北方硝化棉股份有限公司 | Nitrocellulose chip continuous production system and preparation method |
| CN103722652A (en) * | 2013-12-30 | 2014-04-16 | 四川北方硝化棉股份有限公司 | Continuous preparation system and continuous preparation method of nitrocellulose chip |
| CN104263142A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Nitro-lacquer and preparation method thereof |
| CN104327604A (en) * | 2014-10-18 | 2015-02-04 | 刘星 | Nitro paint with dibutyl phthalate and preparation method of nitro paint |
| CN105670473A (en) * | 2014-11-21 | 2016-06-15 | 奥克化学扬州有限公司 | Environment-friendly nitro-lacquer |
| CN104497661A (en) * | 2014-12-23 | 2015-04-08 | 刘骏 | Environmental protection coating |
| CN105482563A (en) * | 2016-01-05 | 2016-04-13 | 安徽名士达涂料有限公司 | Odorless nitrocellulose lacquer and preparing method thereof |
| CN106398400A (en) * | 2016-09-22 | 2017-02-15 | 广东珠江化工涂料有限公司 | Environment-friendly nitrocellulose varnish and preparation method thereof |
| CN107189653A (en) * | 2017-07-18 | 2017-09-22 | 合肥峰腾节能科技有限公司 | A kind of weather-proof floor paint vehicle of high-performance environment-friendly and preparation method thereof |
| CN114181598A (en) * | 2022-02-16 | 2022-03-15 | 天津市津宝乐器有限公司 | Brass instrument multilayer paint and production process |
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