CN101143768A - Method for preparing light porous thermal insulation brick by using silicon-containing tailings - Google Patents
Method for preparing light porous thermal insulation brick by using silicon-containing tailings Download PDFInfo
- Publication number
- CN101143768A CN101143768A CNA2007100125897A CN200710012589A CN101143768A CN 101143768 A CN101143768 A CN 101143768A CN A2007100125897 A CNA2007100125897 A CN A2007100125897A CN 200710012589 A CN200710012589 A CN 200710012589A CN 101143768 A CN101143768 A CN 101143768A
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- China
- Prior art keywords
- slurry
- agent
- tailings
- initiator
- mine tailing
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- 239000011449 brick Substances 0.000 title claims abstract description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 9
- 239000010703 silicon Substances 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims description 11
- 238000009413 insulation Methods 0.000 title abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000006260 foam Substances 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005065 mining Methods 0.000 claims abstract description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000292 calcium oxide Substances 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 238000012423 maintenance Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000011505 plaster Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000002910 solid waste Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 2
- -1 biphenol Natural products 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 229910010272 inorganic material Inorganic materials 0.000 abstract description 2
- 239000011147 inorganic material Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000009740 moulding (composite fabrication) Methods 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011470 perforated brick Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Silicon Compounds (AREA)
Abstract
A method for producing lightweight porous thermal insulation bricks with silicon tailings belongs to an inorganic material technology. The invention is characterized in that a prescribed amount of tailings is mixed and ground with a small amount of initiator and excitant, then water and firming agent are added to obtain slurry; foams with proper elasticity is prepared through chemical reaction under ambient temperature, which will be added into the slurry in order to make foamy slurry; and finally the foamy slurry are solidified in moulds and lightweight porous thermal insulation bricks can be obtained following a proper curing period. The utilization rate of tailings proves to be high in the invention, amounting to 65 percent as a minimum for porous bricks. The thermal insulation bricks made through ambient temperature forming, reaction and solidification has advantages of light weight, porousness, thermal insulation, which can be widely employed in the construction of non load-bearing walls and roofs. The invention can allow effective utilization of tailings, reduce the environmental pollution as a result of tailings stock and improve the economic effects in the mining sector.
Description
Technical field
A kind of utilization contains the method that silicon tailings is produced light porous heat-insulating brick, belongs to technical field of inorganic material.
Background technology
Mine tailing is raw ore depleted solid waste behind ore dressing or other technology recovery useful component of mining, and the whole nation annual discharging mine tailing surpasses 200,000,000 t.The content of SiO2 is generally more than 45% in the mine tailing, and remaining difference owing to the mine kind contains different metallic elements.At present to the treatment process of mine tailing be enter the river course, cheuch is stored up, and has not only taken a large amount of farmlands, and has polluted water, atmosphere, has destroyed ecotope, causes certain environmental hazard.Therefore, the improvement of mine tailing and effectively utilize oneself to become the mining industry urgent problem.The present invention will provide a kind of utilization to contain the technology that silicon tailings prepares light-weight insulating brick, mine tailing and a small amount of additive are mixed with the light porous heat-insulating brick that becomes to have heat insulation function, product is widely used in the insulation on non-bearing wall body or roof, and the insulating brick cost of this method preparation is low, and intensity is big.Utilization contains silicon tailings and produces the stacking that light-weight insulating brick can reduce mine tailing, makes full use of the mine tailing resource, and the Sustainable development of the mining industry of China is had profound significance.
Summary of the invention
The purpose of this invention is to provide a kind of is the method that main raw material prepares light porous heat-insulating brick to contain silicon tailings, thereby effectively utilizes mine tailing, reduces the pollution of mine tailing to environment, improves the economic benefit of mineral products industry.
Technical scheme of the present invention is at first quantitative mine tailing to be mixed, grinds with a small amount of initiator, exciting agent; Add entry again, solidifying agent stirs into slurry; Prepare certain elastic foam at normal temperatures by chemical reaction then, and quantitative foam is driven into makes foamed slurry in the slurry; Foamed slurry is put into that mould solidifies, obtained light porous heat-insulating brick behind the maintenance certain hour.
Effect of the present invention and benefit are, the utilization ratio height of mine tailing, content can reach more than 65% in perforated brick, normal temperature is foaming down, and reaction is solidified, the insulating brick light weight of preparation, porous, heat insulation, insulation, can be widely used in the insulation on non-bearing wall body and roof, in addition, the whole process of the present invention does not have waste discharge, belongs to the environment friendly technology.
Embodiment
Be described in detail the specific embodiment of the present invention and step below in conjunction with technical scheme.
The invention provides a kind ofly, it is characterized in that the kind of mine tailing, initiator, solidifying agent, whipping agent, catalyzer in slurry and the foamed slurry and formula rate are as follows to contain the method that silicon tailings is the main material production light porous heat-insulating brick:
Slurry is made of mine tailing, initiator, exciting agent, water and solidifying agent, and mine tailing is meant raw ore depleted solid waste behind ore dressing or other technology recovery useful component of mining, and wherein dioxide-containing silica requires greater than 30%; Initiator is calcium chloride, calcium oxide, sodium-chlor, lime carbonate, potassium hydroxide, chooses wherein one or more; Exciting agent is calcium oxide, sodium hydroxide, potassium hydroxide, Repone K, chooses wherein one or more; Solidifying agent is plaster stone, magnesium oxide, calcium chloride, calcium oxide, chooses wherein one or more; Foam be by whipping agent and catalyzer at normal temperatures prepared in reaction form, whipping agent is wherein one or more of rosin, phenol, biphenol, benzene, selection, catalyzer is wherein one or more of sulfuric acid, nitric acid, hydrochloric acid, acetate, selection; Foamed slurry is squeezed into foam and is prepared in the slurry; The part by weight of mine tailing, initiator, exciting agent, water, solidifying agent is 100 in the slurry: 1-25: 0-20: 1-50: 1-30; The part by weight of whipping agent and catalyzer is 100 in the foam: 15-65; Slurry and foamy weight ratio are 100 in the foamed slurry: 1-20; The technical process of technology of preparing is as follows:
Step 1: mine tailing and initiator, exciting agent are mixed in proportion, add entry behind the ball milling 5-10min, solidifying agent stirs into slurry;
Step 2: proportionally add whipping agent and catalyzer in reactor, reaction is at normal temperatures produced and is had certain elastic foam;
Step 3: in slip, squeeze into the foam of preparation, after stir, be prepared into foamed slurry with even hole;
Step 4: foamed slurry is put into mould, solidify, obtain light-weight insulating brick after maintenance 1-14 days in the cool.
Embodiment 1
The 100g iron tailings is mixed back ball milling 5~8 minutes with the potassium hydroxide of 1~15g calcium oxide, 0~15g, add the water of 1~40g then, the plaster stone of 1~20g prepares slurry; Getting 0~40g rosin, 0~40g phenol, 0~10g vitriol oil prepared in reaction foam under the normal temperature in reactor, is that mix 100:1~10 by slurry and foamy weight ratio, obtains foamed slurry after stirring; Foamed slurry is put into mould solidify, obtain product after maintenance 1-7 days in the cool, product blank foaming effect is good, does not have cracking, is light-weight insulating brick.Product performance: apparent density: 570 ± 40Kg/m
3Ultimate compression strength: 830 ± 70KPa; Drying shrinkage: 0.82 ± 0.05mm/m; Frost resistance: (40~40 ℃); Thermal conductivity 0.17 ± 0.06W/ (m.K).
Claims (1)
1. a utilization contains the method that silicon tailings prepares light porous heat-insulating brick, it is characterized in that the kind of mine tailing, initiator, solidifying agent, whipping agent, catalyzer in slurry and the foamed slurry and formula rate are as follows:
Slurry is made of mine tailing, initiator, exciting agent, water and solidifying agent, and mine tailing is meant raw ore depleted solid waste behind ore dressing or other technology recovery useful component of mining, and wherein dioxide-containing silica requires greater than 30%; Initiator is calcium chloride, calcium oxide, sodium-chlor, lime carbonate, potassium hydroxide, chooses wherein one or more; Exciting agent is calcium oxide, sodium hydroxide, potassium hydroxide, Repone K, chooses wherein one or more; Solidifying agent is plaster stone, magnesium oxide, calcium chloride, calcium oxide, chooses wherein one or more; Foam be by whipping agent and catalyzer at normal temperatures prepared in reaction form, whipping agent is wherein one or more of rosin, phenol, biphenol, benzene, selection, catalyzer is wherein one or more of sulfuric acid, nitric acid, hydrochloric acid, acetate, selection; Foamed slurry is squeezed into foam and is prepared in the slurry; The part by weight of mine tailing, initiator, exciting agent, water, solidifying agent is 100 in the slurry: 1-25: 0-20: 1-50: 1-30; The part by weight of whipping agent and catalyzer is 100 in the foam: 15-65; Slurry and foamy weight ratio are 100 in the foamed slurry: 1-20; The technical process of technology of preparing is as follows:
Step 1: mine tailing and initiator, exciting agent are mixed in proportion, add entry behind the ball milling 5-10min, solidifying agent stirs into slurry;
Step 2: proportionally add whipping agent and catalyzer in reactor, reaction is at normal temperatures produced and is had certain elastic foam;
Step 3: in slip, squeeze into the foam of preparation, after stir, be prepared into foamed slurry with even hole;
Step 4: foamed slurry is put into mould, solidify, obtain light-weight insulating brick after maintenance 1-14 days in the cool.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2007100125897A CN101143768A (en) | 2007-08-24 | 2007-08-24 | Method for preparing light porous thermal insulation brick by using silicon-containing tailings |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2007100125897A CN101143768A (en) | 2007-08-24 | 2007-08-24 | Method for preparing light porous thermal insulation brick by using silicon-containing tailings |
Publications (1)
Publication Number | Publication Date |
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CN101143768A true CN101143768A (en) | 2008-03-19 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNA2007100125897A Pending CN101143768A (en) | 2007-08-24 | 2007-08-24 | Method for preparing light porous thermal insulation brick by using silicon-containing tailings |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101550021B (en) * | 2009-05-11 | 2011-07-20 | 大连理工大学 | Method for preparing light spume multi-hole bricks with fly ash |
CN101786844B (en) * | 2010-01-25 | 2012-08-08 | 厦门三荣陶瓷开发有限公司 | Light heat-preserving brick and fabrication method thereof |
CN102815965A (en) * | 2012-08-30 | 2012-12-12 | 武汉钢铁(集团)公司 | Porous ceramsite made of low-silicon iron tailings and preparation method of porous ceramsite |
CN102850004A (en) * | 2012-09-27 | 2013-01-02 | 张家港嘉成建设材料有限公司 | Shale brick |
WO2014079126A1 (en) * | 2012-11-26 | 2014-05-30 | 中国铝业股份有限公司 | Process for producing light-weight insulating brick |
CN104529521A (en) * | 2015-01-24 | 2015-04-22 | 曹进 | High-strength heat-insulation brick |
CN106630954A (en) * | 2016-12-27 | 2017-05-10 | 定远县明友墙体材料有限责任公司 | Preparation method of insulating brick with high hardness and excellent wear resistance |
CN113336528A (en) * | 2021-07-06 | 2021-09-03 | 蚌埠学院 | Foamed ceramic material taking quartz sand tailings as raw material and preparation method thereof |
-
2007
- 2007-08-24 CN CNA2007100125897A patent/CN101143768A/en active Pending
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101550021B (en) * | 2009-05-11 | 2011-07-20 | 大连理工大学 | Method for preparing light spume multi-hole bricks with fly ash |
CN101786844B (en) * | 2010-01-25 | 2012-08-08 | 厦门三荣陶瓷开发有限公司 | Light heat-preserving brick and fabrication method thereof |
CN102815965A (en) * | 2012-08-30 | 2012-12-12 | 武汉钢铁(集团)公司 | Porous ceramsite made of low-silicon iron tailings and preparation method of porous ceramsite |
CN102815965B (en) * | 2012-08-30 | 2014-03-26 | 武汉钢铁(集团)公司 | Porous ceramsite made of low-silicon iron tailings and preparation method of porous ceramsite |
CN102850004A (en) * | 2012-09-27 | 2013-01-02 | 张家港嘉成建设材料有限公司 | Shale brick |
WO2014079126A1 (en) * | 2012-11-26 | 2014-05-30 | 中国铝业股份有限公司 | Process for producing light-weight insulating brick |
CN104529521A (en) * | 2015-01-24 | 2015-04-22 | 曹进 | High-strength heat-insulation brick |
CN106630954A (en) * | 2016-12-27 | 2017-05-10 | 定远县明友墙体材料有限责任公司 | Preparation method of insulating brick with high hardness and excellent wear resistance |
CN113336528A (en) * | 2021-07-06 | 2021-09-03 | 蚌埠学院 | Foamed ceramic material taking quartz sand tailings as raw material and preparation method thereof |
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