CN101142357A - Fabric care compositions - Google Patents
Fabric care compositions Download PDFInfo
- Publication number
- CN101142357A CN101142357A CNA200680008843XA CN200680008843A CN101142357A CN 101142357 A CN101142357 A CN 101142357A CN A200680008843X A CNA200680008843X A CN A200680008843XA CN 200680008843 A CN200680008843 A CN 200680008843A CN 101142357 A CN101142357 A CN 101142357A
- Authority
- CN
- China
- Prior art keywords
- composition
- weight
- helping
- fabric treatment
- treatment composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Abstract
An ironing aid fabric treatment composition comprising: a) a nanoparticle dispersion comprising particles having an average particle size in the range 5 to 500nm, b) a lubricant phase comprising a lubricant selected from silicone oil, sucrose polyester oil and mixtures thereof, and c) water wherein the weight ratio of a) : b) is in the range 4 : 1 to 1: 4. with the proviso that when the colloidal nanoparticle dispersion comprises a silicone resin the composition is not delivered through an iron.
Description
Invention field
The present invention relates to Fabrid care composition.More particularly, the present invention relates to the Fabrid care composition that is used to press, described composition reduces cockline, and is especially dry or wear wrinklingly, gives the outward appearance of fabric whole day flatiron.
Background of invention
The Fabrid care composition that reduces the cockline of wearing is known.
Mechanics subtracts the wrinkle technology, as heating and pressurization (for example flatiron), is the effective ways that make clothing smooth.Yet, since when wearing, apply certain limit shearing, reverse and compression power, its effect can not be lasting, and fold reappears.Body temperature and humidity make it lax to fabric generation effect, and have therefore increased the weight of the wrinkle that increases of these deformation forces.
Can explain into three kinds of methods with having crease-resistant technology now:
(a) with lubricator improve from the fine wrinkle recovery,
(b) make the fiber hardening with crosslinking agent and film forming agent, with previously crease-resistant and
(c) with (a) and (b) combination.
The used lubricant of prior art comprises silicone (for example silicone of PDMS, amodimethicone, modification, silicone copolymer), softening agent (as quaternary ammonium compound) and other lubricants (as clay, wax, polyolefin, synthetic and natural oil).
Film forming agent and crosslinking agent that prior art is used comprise:
Natural polymer-enzyme, albumen, cyclodextrin, polysaccharide (for example, starch), chitin, chitan, cellulose, 3-1,4-polysaccharide, SCMC, guar gum, HEC etc.,
Synthetic polymer-polyamide, polyurethane, polyamine, polyolefin, polyalcohol, PEG, polystyrene, PVA, PVC, polyvinyl, acrylic polymer,
Film forming polymer-copolymer, adhesive,
Reactive polymer-contain epoxychloropropane, contain isocyanates, contain epoxy curable type polymer,
Elastomer polymer-thermoplasticity silicone elastomer,
Micromolecule-salt, amino acid, sugar, carbohydrate, compound sugar, alcohol, acid and
Crosslinking agent-based on compound, carboxylic acid, formaldehyde, ammonia, triazine, the epoxides of methylolurea.
WO 2004/018762A1 (Philips) discloses in spray or has scalded and utilized the fusible elastomer film forming agent with crosslinked particulate to improve the effect of recovering from fold to fold in the tube application.
WO 2004/048677 (Philips) discloses and has been suitable in spray or scalds the film forming agent that tube recovers in using, and described film forming agent comprises fusible elastomer+the be used for crosslinked polycation salt of elastomer x-.
WO 2001/25381-5 (Ciba) discloses a kind of composition, described composition has (A) fabric softener, (b) additive and (c) the poly-organosilicon ketone through selecting are to give fabric ANTIPILLING, elasticity, hydrophily, drapability and fold recovery properties respectively in domestic. applications.These character are given by organic silicone.In these additives, mentioned poly-silicic acid.
WO 2002/088293 and US-A1-2002/019236 (Unilever) all disclose the Fabrid care composition that comprises through coated particle, and this comprises having 10 to 700nm diameter D through coated particle
3,2The solid core of average particle size and the silicone copolymer coating that is covalently bound to solid core.Wherein in the solid core list of substances that is suitable for, mentioned silica.
EP 1201817 (A1) (Procter ﹠amp; Gamble) disclose and be used to wear the crease-resistant amodimethicone with steric hindrance functional group, this compounds is in and is preferably carried by spraying in the iron process of front yard.
EP 1096060 (A1) (Procter ﹠amp; Gamble) disclose water-soluble silicone lubricant with various polymerizable compounds (film forming agent) combinations, fabric has been had reach on the water on water at least+15 according to stating lubricant that the fold of unit recovers the angle.
EP 953675 (A2, A3) (Dow Corning) discloses a kind of textile fabric, and this textile fabric scribbles based on the compound of elastomer silicone and the laminar filler of reinforcer (being preferably silica)+second (being preferably talcum and mica).Except other beneficial effects, the fabric of coating also has less friction, and is used for automobile safety seat belt.Saying to the crease-resistant benefit of mixing silicone+particulate filler does not also occur.
GB 842027 (Monsanto Chemicals) discloses based on the textile friction enhancing composition that is dispersed in the silica nanoparticles in the fat liquor droplet.Oil can be any known fabric oil, comprises mineral oil or vegetable oil.Oil surpasses 6 with the ratio of silica, and deposition counts 3-7% oil by fabric weight and 0.1-0.5% silica is preferred.
US 2635056 (Monsanto) discloses with the hydrosol of silica and polyalcohol (as glycerine) and has handled textiles and fabric.Blend is called as alcohol-hydrosol, and owing to exist glycerine to provide unique skid resistance for textiles, and have surprising good hand and fabric sense.Used silica is 1.4 with the ratio of glycerine in this example.It is said that polyalcohol content should not surpass the twice of dioxide-containing silica.
WO-2001/083875 (Ajinomoto Co.) discloses except that other nursing and also applied silica and softening agent the composition to the nylon Lingerie, so that the skin nursing beneficial effect is provided when wearing Lingerie.
(A2, A3) (Relats) discloses by containing SiO EP 1024119
2The textiles made of fiber and the step of its heat endurance of improvement.
JP 04255767 (Nichihan Kenkyusho K.K.) discloses the coating composition that is used for textiles, described composition comprises synthetic emulsion (acrylic compounds), colloid or particle metal oxide silica gel and zeolite, so that fabric coating has good antibiotic property, deodorizes, drying and heat-proof quality.
NL 8900473 (Hesco Fashion Netherlands) discloses the manufacturing of the viscose artificial silk-polyester that applies with a kind of mixture, and described mixture comprises nonionic aliphatic acid condensation fabric softener and inhibitor (stoping moving freely-friction enhancer of direction of warp and weft) acid silicon dioxide dispersion.Softening agent is 1: 1 with the ratio of silica, and addition is 1% silica and 1% softening agent.
EP 0474207, EP 1178150, US 5102930, US 3077460 and US2881146 all disclose fabric treatment composition, described composition comprises silica, organopolysiloxane and catalyst/curing agent, so that form thin polymer film on fabric.
EP 1371718 discloses polymer nano particle and as the purposes of fabric care additive.
On market, also do not satisfy at present the product that the consumer effectively wears crease-resistant needs or whole day flatiron outward appearance benefit.
Wrinkling while fabric keeps excellent handle, pliability and effective, highly efficient process comfortable and easy to wear when therefore, needing a kind of elimination or minimizing fabric and clothing flatiron back to wear.
Goal of the invention
The present invention seeks to solve one or more the problems referred to above.
Summary of the invention
One aspect of the present invention provides a kind of helping to press fabric treatment composition, and described composition comprises:
A) nanoparticle dispersion, this dispersion comprises the particulate with 5nm to 500nm average particle size,
B) lubricant phase, this lubricant comprise mutually the lubricant that is selected from silicone oil, sucrose polyester oil and composition thereof and
C) water
Wherein a): weight ratio b) is 4: 1 to 1: 4,
Condition is that described composition is not sent by flatiron when described colloidal nano microparticle dispersion comprises organic siliconresin.
Another aspect of the present invention provides a kind of method of handling fabric, and described method is included in to use to help on the fabric presses fabric treatment composition, and described composition comprises:
A) colloidal nano microparticle dispersion, described dispersion comprises the particulate with 1nm to 500nm average particle size,
B) lubricant phase,
C) water,
Wherein a): ratio b) is 4: 1 to 1: 4, and
When carrying out described application or subsequently, the described fabric of flatiron under the temperature and pressure that raises, condition is that described composition is not sent by flatiron when described colloidal nano microparticle dispersion comprises organic siliconresin.
Surprisingly, when finding that some nanoparticle friction promoter is used in combination with the ratio of lubricant with certain particulate with some lubricant, significant synergy can take place, reduce the wrinkling tendency of fabric when wearing.Its physical property of Drawing upon, nanoparticle provides required character with lubricant balance mutually.Composition of the present invention does not contain catalyst and curing agent, and does not react film forming on being deposited on fabric the time.Preferred nanoparticle comprises cataloid and organic siliconresin mutually, and preferred lubricant is silicone oil and sucrose polyester oil.Particulate is 3: 1 to 1: 3 with lubricant preferred ratio mutually, more preferably 2: 1 to 1: 2.
Unruffled advantage can obtain by rinse cycle fabric care product and flatiron spray applications when deriving from the wearing of particulate and lubricant combination mutually.
Detailed Description Of The Invention
Composition of the present invention is generally the spray form of using with conventional steam iron.Described composition is moisture usually.
Nanoparticle
Composition of the present invention comprises nanoparticle dispersion.Particulate can be mixtures inorganic or organic nano particulate or one or more nanoparticles.
The inorganic nano-particle that is fit to comprises silica (SiO
2), titanium dioxide (TiO
2), aluminium oxide (Al
2O
3), zinc oxide (ZnO) and mixed oxide class such as ITO (indium tin oxide target, In
2O
3-SnO
2).
Easily purchase and the amorphous silica of preferred inorganic nano-particle for obtaining with colloidal sol or colloidal form, as The Chemistry of Silica, R K Iler, Wiley-Interscience, New York, 1979, page 330 defines.
Silica nanoparticles also can be non-siliceous nuclear, as long as the surface silica-coating of nanoparticle, as described in the 330th page of the books of Iler.Endorse and be the organic polymer properties.
The organic fine particles that is fit to comprises those (for example organic siliconresins) of being derived by silicon.Preferred organic fine particles is not the type that comprises the solid core that applies with polymer (as silicone polymer).Preferred organic fine particles uncoated, but comprise the solia particle of polymer or resin.In the context of the invention, " nanoparticle " refers to the particulate with 5nm to 500nm average particle size.The silica of big particle size also helps wrinkle resistance, but obviously they are effective not as those particulates of 15nm to 100nm.Preferably all particulates have the 500nm of being lower than, more preferably less than the particle size of 100nm.
Have been found that 500nm or littler particle size provide good wrinkle resistance to the poplin fiber, and 300nm or littler particle size provide good wrinkle resistance to cotton fiber.
Dispersion with 10nm to 50nm average particle size is particularly useful.The amount of deposition between 0.25% to 2%, preferably between 0.25% to 0.5% weight owf (every gram fabric 0.0025 gram is to 0.005 gram).
Inorganic nano-particle can provide additional benefit-help absorption smell during wearing according to its structure, increases the long-term feeling of freshness that continues, and reduces to press the dazzle and the flash of light of article, and is antifouling, and is easy to decontamination in washing afterwards.
The used preferred nanoparticle of the present invention is a cataloid.Term used herein " cataloid " is meant the dispersion or the colloidal sol of the discrete particles of preferred stable amorphous silica.Active silica is a used hydrophobic fumed silica in the anti-foam as mentioned above emulsion.
Comprise up to 50% commercially available cataloid and buy with trade name Ludox (Grace Davison) and Snowtex (Nissan) with 10-21nm mean particle dia silica.Instantiation comprises Ludox Cl (cationic silicon dioxide) and Ludox HS50 (anion silica), and the two has the particle size of 20nm.The size of quoting is represented the linear diameter of particulate.
Well known, can be easily with the surface modification of silicon dioxide microparticle, to give its additional benefit.For example, allow surface charge modification (positive charge) with the aluminate modification.Can silica is organically-modified (the 412nd page of above document the above organosol).Preferred silica has suitable surface charge modification and/or other textile function benefits; comprise antimicrobial benefit; skin and percutaneous benefit; the release of control fragrance and repellant; improve abrasion stability; water and oil; dirt repellency and UV protection; as Journal ofSol-Gel Science and Technology 27; 43-52; 2003, B Mahltig and HBottcher, Modified Silica Sol coatings for Water-Repellent Textiles is described.
The lubricant phase
Favourable lubricant comprises silicone oil and oiliness sugar derivatives mutually.
Favourable silicone lubricant comprises traditional three classes: the silicone polymer of nonactive silicone polymer (PDMS), reactive silicone polymer (with the PDMS of silanol end-blocking) and modification (amino/amide functional siloxanes, nonionic modified siloxanes or polyether-modified siloxanes).Preferred silicone is the PDMS type of emulsion or emulsion droplets form, these types can be buied, for example Dow Corning 1716 (cationic) emulsion droplets etc. comprises that also DC amodimethicone 2-8669 nonionic emulsion droplets, 2-8203 nonionic emulsion droplets, 28197 nonionics slightly drip emulsion.
Another kind of preferred silicone is available from those of Wacker, comprise Wetsoft CTA (aminodiol PDMS), Finish CT 34E (amino PDMS emulsion), Finish CT 208E (amino OH PDMS emulsion), Finish CT 96E (amino PDMS emulsion) and their Fluid L series, for example Fluid L 652 (amino PDMS).
Though preferably improve fabric feeling and pliability with silicone oil, non-silicone lubricant as sucrose polyester oil, also can recover to provide required lubricating from fold for fabric.
WO2002/019236A1 (Unilever) more exhaustive list favourable silicone polymer, and EP1205538 (Unilever) has also enumerated the drying oil kind.
Wherein particulate mutually and the combined preferred commercially available material of a class of lubricant include but not limited to silicone+active silica blend of the Dow Corning that sells as antifoaming agent comprise DOW CORNING Antifoam B, DOW CORNING 544, DOWCORNING Q2-3302 ANTIFOAM COMPOUND, DOW CORNING 1581 WATER REPELLENT, DOW CORNING 2-1912 FLUID.
Wherein particulate mutually and the combined another kind of preferred material of lubricant include but not limited to Dow Corning MQ organic siliconresin series, this series comprises PDMS silicone oil and organic siliconresin nanoparticle mutually.
Preferred especially described nanoparticle is silica or organic siliconresin, more preferably cataloid or reaction pyrogenic silica.
The sucrose polyester oil that is fit to is the fatty acid methyl ester (FAME) of natural oil and the product of sucrose.The oil and the preparation thereof that are suitable for are described in EP 323670B1, EP 383404B1, WO2001/46210, WO 98/16538, WO 01/46359A1.
Preferred oil is by mainly comprising C
16And C
18The natural oil of hydrocarbon chain is derived, for example palm-kernel oil.
Water
Described composition comprises water.Demineralized water most preferably.
Demineralized water is meant the water that removes major part (even not being whole basically) dissolving salt in anhydrating.Preferably do not use other ions (Na for example simply
+) replace hardness ions (as Ca
2+, Mg
2+) water.The term demineralized water also comprises distilled water.
If described composition is pressed spray composite for helping, then the French hardness of water should be 20 or below, be preferably 12 or below, more preferably 5 or below.French hardness be the water of 12-20 so-called in hardness water (Medium water), and French hardness to be the water of 5-12 be called soft water, and French hardness is called very soft water less than 5 water.
Spices
Fragrance component (or perfume ingredient) is conventionally known to one of skill in the art, and is described in Perfume and Flavor Chemicals, Steffan Arctander (ISDN 75-91398).The solubility of various fragrance components in water can be represented with the calculation of distribution coefficient (ClogP) of 20 ℃ of following these compositions in distilled water and octanol.The ClogP value is more little, and then the solubility of this composition in water is big more.The computational methods of ClogP value most convenient are to calculate by the 11CLOGP11 program that derives from Daylight CIS.
Preservative agent
When described composition was pressed spray composite for helping, it also can comprise the preferred of 0.1ppm-3% weight was water miscible preservative agent.Preferred described preservative agent should not discharge or be decomposed into to flatiron person detrimental substance under steam generating iron temperature (be preferred 150,200 or even 250 ℃).The safety margin guide of number of chemical product is provided by the occupational exposure boundary that derives from OHSE (Exposure Limits), and lists in the EH40 that derives from HMSO.
Many known preservative agents, Bronopol for example " (Myacide), DowicilTm 75 or 200, Germaben " II GermallTm 115, Germal 1 TM II, Glycac i 1TM, GlydantTM, GlydantT1 plus, Oxaban Tm A and Suttocide TI can discharge or resolve into harmful or excitant chemical substance (for example formaldehyde) under the steam iron temperature.
If preservative agent (being different from preferred those preservative agents) is waited to be contained in the described composition, then its amount should be not more than 0.5% weight.
Preferred preservative agent comprises those preservative agents that are selected from aromatics, straight or branched C1-C20 alcohol and composition thereof, and amount can be 0.1ppm-3% weight, perhaps is preferably 0.5-1% weight.Preferred at least a preservative agent is selected from benzylalcohol (phenoxy group methyl alcohol) and phenoxetol and composition thereof.In these preservative agents, more preferably benzylalcohol.If used benzylalcohol, preferably use other benzylalcohol of high-purity-grade to make and contain minimum known impurities (benzaldehyde), preferred composition of the present invention does not contain this impurity substantially, promptly is low to moderate described helping and presses composition and still can use safely.
Particularly preferred preservative agent comprises at least a compound based on isothiazolone, Kathon TM CG ICP II (deriving from Rohm and Haas) for example, it is to contain 3: 1 5-chloro-2-methyl-3 (the 2H)-isothiazolone of low content salt and the mixture of 2-methyl-3-(2H)-isothiazolone.
Buffer
When described composition was pressed spray composite for helping, preferred described composition was neutral or omits alkalescence, as most of running water.Therefore in composition of the present invention, can comprise the pH of buffer, make pH, be preferably 7-9, more preferably 7-8 more than or equal to 6 with regulator solution.The amount of this class buffer can be 0.0001% (preferred 0.001%) to 0.1% or 1% weight.
Secondary solvent
The present invention can comprise secondary solvent, and its amount is 0.01 to 5% (or possible 20%), and more preferably 0.1 to 5 or 10% weight most preferably is 0.2 to 1 or 2% weight.
The secondary solvent that is fit to comprises dipropylene glycol, glycerine, propylene glycol, ethanol and isopropyl alcohol (IPA) and composition thereof.Dipropylene glycol most preferably in these solvents.We find that dipropylene glycol can be used for flatiron as humidizer especially and be convenient to flatiron.
The amount of ethanol in the described composition and/or isopropyl alcohol (IPA) preferably is no more than 5% weight.
Therefore, help the total amount of pressing solvent in the composition, comprise the solvent that can be present in the water soluble flavours, can be up to and comprise about 25% weight, more preferably 15,10,5 or even be 2 or 3% weight.
Help and press preparation of compositions
Described helping pressed spray composite and can be provided for the concentrate form of ultimate consumer dilution.
Preferably use 0.5-100, more preferably 1-10, most preferably 2-5 part water (w/w) dilutes 1 part of concentrate.Provide to obtain helping and press the required ultimate density of composition and the coefficient of dilution, can easily calculate the accurate composition of concentrate.
For example when the ultimate density of spices in the composition was 3.0-5.0% weight, then the coefficient of dilution was defined as and is at most 20.It should be apparent to those skilled in the art that helping after the dilution pressed composition need comprise the highest lower flavour content when using the higher coefficient of dilution (for example 100).
Described composition also comprises and well known to a person skilled in the art surfactant, super spreading agent (superspreader), softener.
Other optional members
Also can add other optional non-ionic softener, bactericide, dirt releasing agents.
This based composition also can be included in conventional one or more optional members that use in the liquid rinse fabric-conditioning compositions, as pH buffer, fragrance carrier, fluorescer, colouring agent, hydrotropic solvent, defoamer, anti redeposition agent, polyelectrolyte, enzyme, fluorescent whitening agent, antishrinking agent, anti wrinkling agent, anti-spot agent, antioxidant, sun-screening agent, anticorrosive, tax drapability agent (drape imparting agent), antistatic agent, polymeric viscosity modifiers, flatiron auxiliary agent and dyestuff.
Preparation of compositions
Can adopt any suitable method to prepare described composition.
Be used for first kind of preferable methods of spray, silicon dioxide colloid is being dispersed in the water that comprises the less composition of content (as optional dyestuff, preservative agent and surfactant), adding silicone emulsion or microemulsion subsequently, adding spices again.
Product form
When being in room temperature, undiluted state, preferred described product is liquid, it is liquid, aqueous to be preferably.
Product uses
In family expenses flatiron operating process, can easily described composition be sent from sprayer.Those compositions that do not contain organic silicones nanoparticle can be sent by the sprayer of steam iron or steam generator flatiron.
The accompanying drawing summary
Fig. 1 a and 1b representative are available from James H Heal ﹠amp; Co.Ltd. standard fold recovers tester 155 types (Wrinkle Recovery Tester Instrument Model 155),
Fig. 2 represents existing AATCC 128 grade figure,
Fig. 3 represents new U grade figure, and
Fig. 4 is for showing the comparison diagram of AATCC grade and new U grade.
Wear wrinkling assessment
Find, show traditional fine wrinkle or recovering of folds angle (CRA) method of anti-wrinkle composition feature of the present invention, i.e. AATCC66-1990 (consulting EP 1096060 (A1)), the fold assessment is uncorrelated greatly with wearing. In dress was wrinkling, definition folding and distortion was very important, and this does not detect by CRA.
There are a lot of textile industry standard methods to describe generation and the detection (Association of American Textile Chemists and Colourists-AATCC) of cockline.
AATCC 128 recovering of folds method of testings (AATCC 128 Wrinkle Recovery Test) are to be widely used in the method for determining the clothing recovering of folds most, and externally extensively quote in the document. Test fabric uses standard recovering of folds tester 155 types (Fig. 1) that provided by James H Heal ﹠ Co Ltd wrinkling under gauge load, time and environmental condition. Fold recovering state level is with stipulating lighting device normative reference 3D duplicate grade WR1-WR5 visual rating scale, and wherein WR1=does not recover from wrinkle, and WR5=recovers fully. Fig. 2 has shown this 3D AATCC 128 fold grades.
Yet owing to following reason, when wrinkling fabric was worn in test, existing 3D AATCC 128 grades were undesirable.
Existing AATCC 128 3D standards do not allow the panelist to distinguish the tiny difference of wrinkling intensity. For example, wearing when wrinkling, the fold scope is about 2.5 to 3.5, and 128 grades cover 1 to 5 rough (broad brush) grade, does not have the details of 2.5 to 3.5 scopes paid attention to.
Therefore, need to assess with good discrimination the more relevant grade of wrinkling intensity.
New grade hereinafter referred to as the U grade, is utilized recovering of folds tester 155 types, is revealed as 0=not wrinkling (put down) and the 10=degree between seriously wrinkling from the image of wrinkling woven cotton wool Pueraria lobota monitoring thing, as shown in Figure 3. Therefore, these level covers the wider fold scope in the medium range, thereby allows the panelist to distinguish minor detail in the systematization mode.
The AATCC128 grade shows quite flat insensitive scope at mark about 3, compares with the AATCC128 grade, debates not between the wrinkling intensity of new about this scope of U grade permission. Fig. 4 is presented at the comparison of making between two kinds of grades with figure.
Method
1. monitoring thing preparation
Prepare test solution with desired concn or required %owf, and spend the night in that roll row (roller bank) is stable.
Then will monitor thing and weigh (W1), and immerse in the test solution, and between the roller of Werner Mathis AG padder, compress, so that its weight is 2 times of original weight.
(20 ℃/65%RH) dry 24 hours, (W2) again then weighed controlling temperature and relative humidity to make the monitoring thing.
The weight of additive is (W2-W1) on the monitoring thing, can calculate %owf thus.
Drying is monitored thing in the hottest setting and with the highest steam ironing is set with Philips Azur 4000 flatirons, it is being controlled (20 ℃/65%RH) further nursed one's health 24 hours of temperature and relative humidity.
Process six this test monitoring things of preparation for every kind.
Contrast monitoring thing is arranged in each test, be used for comparing with the monitoring thing of compositions-treated. These contrast monitoring things are with demineralized water and without compositions-treated, and in an identical manner preparation.
2. wrinkling
For producing wrinkling state, will monitor thing and be carried on recovering of folds tester 155 types, in order to make warp-wise vertical. Then without impost fabric is compressed (wrinkling) 8 minutes.
After wrinkling, hung the monitoring thing 24 hours at 20 ℃/65%RH.
3. monitoring thing assessment
Under the equal illumination condition, take digital photograph images with the Nokia digital camera for each monitoring thing. Reach the standard illuminants condition with Verivide fine wrinkle imaging chamber (Verivide Crease Imaging Cabinet).
With the image grouper of packing into, every image is contrasted the image scoring of used grade AATCC128 or U grade to the panelist.
The fold intensity of all monitoring things is marked with respect to these level by 6 trained panelists.
In each test, also prepare 6 undressed contrast monitoring things, and with wrinkling with the identical mode of above-mentioned treated monitoring thing, comparing with composition.
To the present invention be described by following unrestricted embodiment now.Further revise apparent to those skilled in the art.Sample of the present invention is by numeral.Comparative sample is by letter representation.Except as otherwise noted, all numerical value are all by the % weight of active component.
Embodiment
Table 1 is determined used lubricant and particulate character mutually with 2.
The physical property of the silicone emulsion that table 1. records (lubricant)
| Chemical descriptor | Emulsifying agent | Droplet size/nm | Oil viscosity/mPass | |
| DC2-8663(Dow?Corning) | Linear amodimethicone | Nonionic | 50 | 3500 |
| DC2-8177(Dow?Corning) | Linear amodimethicone | Nonionic | 50 | 12000 |
| DC1652(Dow?Corning) | Linear pdms | Nonionic | 700 | 350 |
| HMW2220(Dow?Corning) | The polymer that linear pdms-MW is very high | Nonionic | 500 | 1.2M |
| DC1716(Dow?Corning) | The PDMS microemulsion | CATION | Unknown | Unknown |
| CT208E(Wacker) | Linear amodimethicone | Nonionic | Unknown | Unknown |
The physical property of some cataloid dispersion that table 2. records
| Trade name | Charged | Particle size/nm | Dioxide-containing silica/% weight |
| Ciba?820(Ciba) | (+) | 22 | 11 |
| Ludox CL-P silica (Grace) | (+) | 22 | 30 |
| Ludox?TM40(Grace) | (-) | 22 | 50 |
| Ciba?911(Ciba) | (+) | 22 | ？ |
| Ciba?1143(Ciba) | (-) | ？ | ？ |
| Ludox?SP532-10519(Grace?Davison) | (+) | 50 | 40 |
Table 3 expression lubricated effect alone.With water contrast proof relatively, use silicone oil or most of other lubricants almost not to have or the crease-resistant benefit when not wearing.
The AATCC128 fold scoring of the silicone sample of the different %owf of table 3..Mark is high more, and the fold of then monitoring thing is few more.
| Silicone emulsion | 0.07％owf | 0.25％owf | 0.5％owf | The water contrast |
| DC2-8663 | 3.91 | 3.74 | 3.66 | 3.73 |
| DC2-8177 | 3.28 | 2.73 | 2.7 | 3.11 |
| DC1652 | 3.47 | 3.38 | 3.48 | 3.49 |
| HMW2220 | 3.01 | 2.9 | 2.07 | 3.3 |
| DC1716 | 2.91 | 2.6 | 2.58 | 3.42 |
| CT208E | 3.48 | 3.29 | 2.65 | 4.04 |
Crease-resistant benefit when table 4,5 and 6 expression silicon dioxide microparticles provide (only by sclerosis or increase friction) improved dress alone.When but silicon dioxide microparticle used alone, textile feel and feel were very coarse.
Table 4. utilizes the U grade fold scoring behind silica sample Ludox W501 hour of different %owf.Mark is low more, and the fold of then monitoring thing is few more.
| Test | 0.50％owf | 1.00％owf | 2.00％owf | The |
| Test | ||||
| 1 | 2.62 | 2.50 | 2.58 | 3.58 |
| Test 2 | - | 3.53 | - | 4.3 |
| |
2.03 | - | - | 2.45 |
Table 5. utilizes the AATCC128 fold scoring of silica sample C820 after 24 hours of different %owf.Mark is high more, and the fold of then monitoring thing is few more.
| 0.20％owf | 0.40％owf | 0.79％owf | 1.57％owf | The water contrast |
| 3.21 | 3.21 | 3.55 | 3.51 | 2.89 |
Table 6. utilizes the U grade fold scoring of silica sample C820 after 24 hours of different %owf.Mark is low more, and the fold of then monitoring thing is few more.
| 0.20％owf | 0.40％owf | The water contrast |
| 2.50 | - | 2.70 |
| 3.11 | - | 3.40 |
| 2.06 | - | 2.52 |
| - | 2.26 | 3.30 |
Particulate of the present invention in the table 7 mutually and lubricant is combined shows concertedness aspect crease-resistant when wearing under specific ratio.
Table 7. utilizes the different silica of different %owf: the U grade scoring of Ludox W50 lubricant blend after 1 hour of silicone ratio.Mark is low more, and the fold of then monitoring thing is few more.
| Lubricant | ? |
1∶1 | 2∶1 | 1∶2 | The water contrast |
| DC21310 | ?0.5 | 2.93 | 2.13 | 2.68 | 2.45 |
| DC21310 | ?1.0 | 3.48 | 3.13 | 3.46 | 4.30 |
| SPE | ?0.5 | 3.63 | 2.15 | 3.07 | 2.46 |
(available from DOW CORNING, be the dimethyl silicone polymer that provides with the anion microemulsion form, the viscosity before emulsification is 60 to silicone DC21310 PDMS, 000cSt).SPE is the sucrose polyester based on palm-kernel oil.
Test the pliability and the feel of monitoring thing by judge group.The silica/silicon ketone of 0.5% level shown in the table 7 and the monitoring thing that silica/SPE handled show good pliability.The easy flatiron of silica+silica blend is comparable to commercially available Comfort fabric conditioner, but only uses the compositions table of silica to reveal unacceptable flatiron slip.
Another kind of lubricant-particulate blend belongs to the MQ organic siliconresin class that derives from Dow Corning shown in the table 8., compare with unprocessed after 1 hour and 24 hours with preferred deposition content processing, the intensity of fold reduces.
Table 8. utilizes the U grade fold scoring of o/w emulsion after 1 hour and 24 hours of the silicone oil/organic siliconresin blend of cationic emulsifier
| The ratio (cationic emulsifier) of PDMS/ organic siliconresin blend | ||||||||
| ％owf | 40/60 | 30/70 | 20/80 | Be untreated | ||||
| 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | |
| 0.1 | 3.71 | 2.97 | 3.17 | 2.61 | 3.25 | 2.49 | 3.60 | 2.88 |
| 0.25 | 3.08 | 2.49 | 2.78 | 2.29 | 2.40 | 1.93 | 3.60 | 2.88 |
Table 9. utilizes the U grade fold scoring of o/w emulsion after 1 hour and 24 hours of the silicone oil/organic siliconresin blend of nonionic emulsifier
| The ratio (nonionic emulsifier) of PDMS/ organic siliconresin blend | ||||||||
| ％owf | 40/60 | 30/70 | 20/80 | Be untreated | ||||
| 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | 1 hour mark | 24 hours marks | |
| 0.1 | 2.67 | 1.67 | 215 | 2.08 | 2.75 | 2.38 | 3.58 | 2.89 |
| 0.25 | 1.83 | 2.14 | 2.92 | 2.25 | 3.58 | 2.38 | 4.00 | 2.89 |
In table 8 and table 9, phase composition is identical in the emulsion of all samples, just the used surfactant difference of emulsification.
Table 10 expression D5, PDMS/ resin blend and the percentage of water in emulsion compositions.Described PDMS/ resin blend is dissolved in D5 (a kind of low-molecular-weight silicone oil solvent), emulsification in water subsequently.
The water of table 10. emulsion and the composition of oil phase (not comprising surfactant)
| Composition | W% accounts for composition |
| Water | ?50 |
| D5 | ?25 |
| The PDMS/ resin blend | ?25 |
Silicone resin is by having formula R
3SiO
1/2Unit price three siloxies (M) and have formula SiO
4/2Tetravalence siloxy (Q) form, polymer is the aminofunctional PDMS with a certain amount of end position OH, its viscosity is 4000mPas.
Table 11 provides resin blend distribution of particle size of emulsion used in table 8 and the table 9.
The emulsion droplet size of table 11.Dow Corning PDMS/ resinous polymer blend
| PDMS/MQ blend ratio | Surfactant types | Size/nm |
| 40/60 | Nonionic | 139 |
| 30/70 | Nonionic | 129 |
| 20/80 | Nonionic | 161 |
| 40/60 | Cationic | 116 |
| 30/70 | Cationic | 154 |
| 20/80 | Cationic | 139 |
With with equating that the silica of addition compares, show preferable pliability and feel with the monitoring thing of organic siliconresin blend processing.Compare with silica, its easily flatiron property also improve.
Claims (21)
1. one kind is helped and presses fabric treatment composition, and described composition comprises:
A) nanoparticle dispersion, described dispersion comprises the particulate with 5 to 500nm average particle size,
B) lubricant phase, described lubricant comprise mutually the lubricant that is selected from silicone oil, sucrose polyester oil and composition thereof and
C) water
Wherein a): weight ratio b) is 4: 1 to 1: 4,
Condition is that described composition is not sent by flatiron when described colloidal nano microparticle dispersion comprises organic siliconresin.
2. helping of claim 1 pressed fabric treatment composition, and all particulates of wherein said nanoparticle dispersion have the particle size less than 500nm.
3. helping of claim 2 pressed fabric treatment composition, and all particulates of wherein said nanoparticle dispersion have the particle size less than 100nm.
4. helping of each pressed fabric treatment composition in the aforementioned claim, and the particulate of wherein said nanoparticle dispersion has 15 to 50nm average particle size.
5. helping of each pressed fabric treatment composition in the aforementioned claim, and wherein said nanoparticle is selected from silica, titanium dioxide, aluminium oxide, zinc oxide and organic siliconresin.
6. helping of claim 5 pressed fabric treatment composition, and wherein said nanoparticle dispersion is CATION, anion or the neutral colloid dispersion of silica.
7. helping of claim 5 pressed fabric treatment composition, and the particulate of wherein said colloidal nano microparticle dispersion comprises organic siliconresin.
8. helping of each pressed fabric treatment composition in the aforementioned claim, and wherein said silicone oil comprises dimethyl silicone polymer.
9. helping of each pressed fabric treatment composition in the aforementioned claim, and wherein a): weight ratio b) is 3: 1 to 1: 3.
10. helping of claim 9 pressed fabric treatment composition, and wherein a): weight ratio b) is 2: 1 to 1: 2.
11. helping of each pressed fabric treatment composition in the aforementioned claim, described composition comprises:
The component of 0.1-50% weight a),
The components b of 0.1-50% weight),
The water that is up to 99.8% weight.
12. fabric treatment composition is pressed in helping of claim 10, described composition comprises:
The component of 0.5-20% weight a),
The components b of 0.5-20% weight),
The surfactant of 0.1-15% weight,
The spices of 0.1-5% weight and
The deionized water that is up to 70% weight.
13. one kind is helped and presses the fabric treating product, described product comprises storage and the spraying distributing valve that contains each composition in the aforementioned claim.
14. a tube that inserts in the steam iron, described tube comprises that the storage that contains each preparation among the claim 1-12, condition are that described colloidal nano microparticle dispersion does not comprise organic siliconresin.
Press fabric treatment composition 15. a method of handling fabric, described method are included in to use to help on the fabric, described composition comprises:
A) colloidal nano microparticle dispersion, described dispersion comprises the particulate with 1 to 500nm average particle size,
B) lubricant phase,
C) water,
Wherein a): ratio b) is 4: 1 to 1: 4, and
When carrying out described application or subsequently, the described fabric of flatiron under the temperature and pressure that raises, condition is that described fabric treatment composition is not sent by flatiron when described colloidal nano microparticle dispersion comprises organic siliconresin.
16. the method for claim 15, wherein said composition is used with the amount of lubricant 0.25 to 2% weight mutually mutually to deposit whole particulates.
17. the method for claim 16, wherein said composition is used with the amount of lubricant 0.5 to 1% weight mutually mutually to deposit whole particulates.
18. each method among the claim 15-17, each defines among wherein said composition such as the claim 1-12.
19. each method among the claim 14-18, wherein said composition is used from steam iron, and condition is that described composition does not comprise the nanoparticle dispersion that contains the organic siliconresin particulate.
20. each method among the claim 14-18, wherein said composition passed through spray applications before flatiron.
21. each composition is being handled fabric so that the purposes in the crease-resistant benefit to be provided among the claim 1-13.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0505618.9A GB0505618D0 (en) | 2005-03-18 | 2005-03-18 | Fabric care compositions |
| GB0505618.9 | 2005-03-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101142357A true CN101142357A (en) | 2008-03-12 |
Family
ID=34531499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200680008843XA Pending CN101142357A (en) | 2005-03-18 | 2006-03-08 | Fabric care compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20090050838A1 (en) |
| EP (1) | EP1859099A2 (en) |
| CN (1) | CN101142357A (en) |
| AR (1) | AR053181A1 (en) |
| BR (1) | BRPI0608731A2 (en) |
| CA (1) | CA2598314A1 (en) |
| GB (1) | GB0505618D0 (en) |
| WO (1) | WO2006097227A2 (en) |
| ZA (1) | ZA200707392B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102348846A (en) * | 2009-03-09 | 2012-02-08 | 荷兰联合利华有限公司 | Fabric treatment composition and method |
| CN106637928A (en) * | 2016-11-22 | 2017-05-10 | 闫博文 | Preparation method of rice husk fabric softening agent |
| CN107075126A (en) * | 2014-07-28 | 2017-08-18 | 瓦克化学股份公司 | The method for preparing amino silicone polymer nanoemulsions |
| CN111212895A (en) * | 2017-10-13 | 2020-05-29 | 荷兰联合利华有限公司 | Aqueous spray composition |
| US11649416B2 (en) | 2017-10-13 | 2023-05-16 | Conopco, Inc. | Aqueous spray composition comprising silicone and perfume microemulsions |
| US11807834B2 (en) | 2017-10-13 | 2023-11-07 | Conopco, Inc. | Aqueous spray composition |
| US11987771B2 (en) | 2017-10-13 | 2024-05-21 | Conopco, Inc. | Fabric spray composition comprising a non-functionalized silicone nanoemulsion and peg-40 hydrogenated castor oil |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8637442B2 (en) | 2010-09-20 | 2014-01-28 | The Procter & Gamble Company | Non-fluoropolymer surface protection composition comprising a polyorganosiloxane-silicone resin mixture |
| EP2431421B1 (en) | 2010-09-20 | 2013-11-06 | Wacker Chemie AG | Aqueous mixtures comprising aminoalkyl-containing polyorganosiloxanes and silicone resins |
| MX338305B (en) | 2010-09-20 | 2016-04-11 | Procter & Gamble | Non-fluoropolymer surface protection composition. |
| EP2431402B1 (en) | 2010-09-20 | 2013-09-18 | Wacker Chemie AG | Mixtures comprising aminoalkyl-containing polyorganosiloxanes and silicone resins |
| EP2980125B1 (en) | 2014-07-28 | 2017-06-14 | Wacker Chemie AG | Process for making an aminosiloxane polymer nanoemulsion |
| US20190048291A1 (en) | 2016-03-23 | 2019-02-14 | Novozymes A/S | Use of Polypeptide Having DNase Activity for Treating Fabrics |
| CN110843275B (en) * | 2019-11-29 | 2021-12-10 | 广州市新荔缘鞋业有限公司 | Preparation method of high-breathability antibacterial functional composite fabric |
| CN114197209B (en) * | 2021-02-25 | 2024-02-20 | 义乌市裕泉服饰有限公司 | Skin feel fabric |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6491840B1 (en) * | 2000-02-14 | 2002-12-10 | The Procter & Gamble Company | Polymer compositions having specified PH for improved dispensing and improved stability of wrinkle reducing compositions and methods of use |
| FR2813312B1 (en) * | 2000-08-25 | 2006-07-14 | Rhodia Chimie Sa | COMPOSITION BASED ON POLYMER NANOLATEX FOR LAUNDRY CARE |
| FR2814064B1 (en) * | 2000-09-20 | 2005-06-17 | Oreal | WASHING COMPOSITION COMPRISING ALUMINUM OXIDE PARTICLES, AT LEAST ONE CONDITIONING AGENT AND AT LEAST ONE DETERGENT SURFACTANT |
| AU2002239795A1 (en) * | 2000-10-27 | 2002-05-27 | The Procter And Gamble Company | Process for the ironing of fabrics, and refill cartridge for irons |
| US6681506B2 (en) * | 2000-10-27 | 2004-01-27 | The Procter & Gamble Company | Process for the ironing of fabrics, and refill cartridge for irons |
| CN1313586C (en) * | 2000-12-22 | 2007-05-02 | 荷兰联合利华有限公司 | Fabric care compositions |
| EP1487396A1 (en) * | 2002-03-28 | 2004-12-22 | The Procter & Gamble Company | Emulsion compositions |
| US7196043B2 (en) * | 2002-10-23 | 2007-03-27 | S. C. Johnson & Son, Inc. | Process and composition for producing self-cleaning surfaces from aqueous systems |
-
2005
- 2005-03-18 GB GBGB0505618.9A patent/GB0505618D0/en not_active Ceased
-
2006
- 2006-03-08 EP EP06707473A patent/EP1859099A2/en not_active Withdrawn
- 2006-03-08 CA CA002598314A patent/CA2598314A1/en not_active Abandoned
- 2006-03-08 ZA ZA200707392A patent/ZA200707392B/en unknown
- 2006-03-08 WO PCT/EP2006/002116 patent/WO2006097227A2/en not_active Application Discontinuation
- 2006-03-08 US US11/886,616 patent/US20090050838A1/en not_active Abandoned
- 2006-03-08 CN CNA200680008843XA patent/CN101142357A/en active Pending
- 2006-03-08 BR BRPI0608731-0A patent/BRPI0608731A2/en not_active IP Right Cessation
- 2006-03-17 AR ARP060101045A patent/AR053181A1/en unknown
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102348846A (en) * | 2009-03-09 | 2012-02-08 | 荷兰联合利华有限公司 | Fabric treatment composition and method |
| CN102348846B (en) * | 2009-03-09 | 2013-09-11 | 荷兰联合利华有限公司 | Fabric treatment composition and method |
| CN107075126A (en) * | 2014-07-28 | 2017-08-18 | 瓦克化学股份公司 | The method for preparing amino silicone polymer nanoemulsions |
| CN106637928A (en) * | 2016-11-22 | 2017-05-10 | 闫博文 | Preparation method of rice husk fabric softening agent |
| CN111212895A (en) * | 2017-10-13 | 2020-05-29 | 荷兰联合利华有限公司 | Aqueous spray composition |
| US11649416B2 (en) | 2017-10-13 | 2023-05-16 | Conopco, Inc. | Aqueous spray composition comprising silicone and perfume microemulsions |
| US11725163B2 (en) | 2017-10-13 | 2023-08-15 | Conopco, Inc. | Aqueous spray composition |
| US11807834B2 (en) | 2017-10-13 | 2023-11-07 | Conopco, Inc. | Aqueous spray composition |
| US11987771B2 (en) | 2017-10-13 | 2024-05-21 | Conopco, Inc. | Fabric spray composition comprising a non-functionalized silicone nanoemulsion and peg-40 hydrogenated castor oil |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0608731A2 (en) | 2010-01-26 |
| WO2006097227A3 (en) | 2007-04-19 |
| ZA200707392B (en) | 2008-12-31 |
| US20090050838A1 (en) | 2009-02-26 |
| CA2598314A1 (en) | 2006-09-21 |
| EP1859099A2 (en) | 2007-11-28 |
| GB0505618D0 (en) | 2005-04-27 |
| WO2006097227A2 (en) | 2006-09-21 |
| AR053181A1 (en) | 2007-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101142357A (en) | Fabric care compositions | |
| CN101142306B (en) | Fabric care compositions | |
| EP1885939B1 (en) | Surface treatment compositions comprising saccharide-siloxane copolymers | |
| JP6479861B2 (en) | Method of using compositions comprising quaternary ammonium compounds, cationic polysaccharides and non-ionic polysaccharides | |
| EP2785768B1 (en) | Consumer product compositions comprising organopolysiloxane emulsions | |
| JP6430440B2 (en) | Aqueous dispersion for stain repellency, soft product for stain repellency, and production method thereof | |
| DE69924123T2 (en) | LAUNDRY CARE COMPOSITION | |
| JP4485055B2 (en) | Fabric wrinkle inhibiting composition and method | |
| CN1361837A (en) | Fabric softening compositions | |
| US20070163463A1 (en) | Interior protectant/cleaner composition | |
| JP2002513077A (en) | Fabric wrinkle suppressing composition and method | |
| AU769162B2 (en) | Siloxane emulsions | |
| EP1201817B1 (en) | Clothes treatment for dry wrinkle resistance | |
| DE60033960T2 (en) | IMPROVEMENT OF CREATING RECREATION OF FABRICS | |
| US10954343B2 (en) | Compositions comprising beta-ketocarbonyl-functional organosilicon compounds | |
| CN112724827B (en) | Multifunctional fabric coating based on strawberry type microcapsules and preparation method and application thereof | |
| EP1204793B1 (en) | Stable silicone oil emulsion composition, article of manufacture, and method of fabric wrinkle control | |
| JP3420692B2 (en) | How to process clothing | |
| EP1746153B1 (en) | Improvements relating to domestic laundering | |
| JP5427219B2 (en) | Anti-allergenic textile and allergen reducing agent | |
| JPH0610268A (en) | Fiber treating agent composition and treated fiber | |
| JPH10110387A (en) | Treating agent for processing fiber product and production of fiber product | |
| AT7366U1 (en) | IMPREGNATION | |
| MXPA00011115A (en) | Water/oil repellant composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20080312 |
|
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |