CN101139765A - Chitin yarn and production method thereof - Google Patents

Chitin yarn and production method thereof Download PDF

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Publication number
CN101139765A
CN101139765A CNA2006100689166A CN200610068916A CN101139765A CN 101139765 A CN101139765 A CN 101139765A CN A2006100689166 A CNA2006100689166 A CN A2006100689166A CN 200610068916 A CN200610068916 A CN 200610068916A CN 101139765 A CN101139765 A CN 101139765A
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chitin
yarn
fiber
spinning
mins
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CNA2006100689166A
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CN100549260C (en
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郑德选
董书善
李鹏举
杨茂伟
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Abstract

The invention discloses a chitin yarn and the chitin yarn production method. Pure chitin like fibers are used as raw materials to produce chitin yarn through material preparation, scutching, carding, drawing, roving, spinning and finishing. Pure chitin fiber yarn being produced with the production method has outstanding performances, such as perfect yarn quality and strength, etc. Moreover, with simple technique, the pure chitin yarn production method solves the problem that prior chitin fiber cannot be made together with other fiber blends but spun separately.

Description

A kind of chitin yarn and production method thereof
Technical field
The present invention relates to textile technology field, especially relating to a kind of chitin fiber that adopts is the chitin yarn of raw material production and the method for producing this chitin yarn.
Background technology
Chitin is that occurring in nature is only second to the cellulosic second family macromolecule compound, generally is to extract from shrimp, crab shell.Because chitin is a kind of positively charged natural nitrogenous polysaccharide polymer, therefore also have positive charge by the chitin fiber that its processing spinning is formed, this positive charge can neutralize and have the microorganisms such as bacterium of negative electrical charge, thereby suppress bacterium it is lost activity, and reaches effect antibacterial, sterilization, prevented of the healthy harm of bacterium intrusion human body to people, and, the weaving face fabric softness that adopts chitin fiber to produce, comfortable and easy to wear, therefore, be subjected to very much liking of people.But, because the design feature of chitin itself, its fiber is thicker, and powerful special low (main cause is a porous fibre) is wet especially strong, proportion is bigger, these have determined the spinnability of chitin fiber and spinning process relatively poor, and in addition because the contained positive charge of molecule in the chitin fiber, same sex electric charge is mutually exclusive, therefore the fiber in the strip can not be embraced and be in the same place, and this has brought difficulty to spinning.Therefore, this has caused present chitin fiber to only limit to fiber blend with other kind in field of textiles, and few yarn that adopts pure chitin fiber to produce that exists, and for adopting pure chitin fiber spinning, people never have reasonable production method, and this has influenced demand and the utilization of people to chitin fiber to a certain extent; And in the chitin blended yarn that exists, the content of chitin fiber is general also lower at present, and its production performance can not satisfy people's requirement, and these have all limited further developing of chitin to a certain extent.
Summary of the invention
Technical problem to be solved by this invention provided a kind of have that good bar is done and the chitin yarn of excellent properties such as intensity to satisfy the demand of people to chitin yarn.
The present invention also provides a kind of method of producing chitin yarn, and this production method only adopts chitin fiber to produce pure chitin fiber yarn, to solve the difficulty that current people produce pure chitin fiber yarn.
For solving the problems of the technologies described above, technical scheme of the present invention provides a kind of chitin yarn, be that employing chitin kind fiber is the fine-count yarn of raw material processing, the yarn of producing index can reach 17.0~19.5, km details (50%) 400~550, km slubbing (+50%) 1100~1500, km cotton knot (+200%) 1100~1700, intensity 7.5~9.0CN/TEX, hairiness index 6~8.And the chitin kind fiber comprises chitosan (CS) fiber and/or chitin (ACT) fiber, promptly can adopt a kind of in chitosan (CS) fiber or chitin (ACT) fiber merely, use after also can adopting chitosan (CS) fiber and chitin (ACT) mixed with fibers, it is fibre length 35~40mm that chitosan and chitin fiber can adopt specification, fibre fineness 1.5~2.5D, single fiber intensity 1.53~2CN/dtex, pH value 6~7, moisture regain 15.0~15.5% is produced.And according to the situation in the actual production, the weight mixing ratio that can adopt chitosan fiber and chitin fiber is a chitosan fiber 45%, and the mixed proportion of chitin 55% is produced fine-count yarn.
Produce the method for chitin yarn among the present invention, for adopting the chitin kind fiber is that raw material is through getting the raw materials ready, blowing, comb and parallel cotton fibers prior to spinning, drafting, spinning (rove, spun yarn) and back processing chitin yarn, wherein, cotton cleaning process comprises grabs cotton, opener, gives cotton rolling operation, wherein can adopt twice opener operation, pass through the mixing and blowing machine earlier, when fiber is carried out opener, also it be carried out combing by card wire formula opener again the fiber opener; Because the chitin kind fiber strength is lower, and than great, saturation force is also low between fiber, so in whole spinning process, should adhere to following technological principle, adopt " low velocity, the strong comb, quantitatively big that divides " when being blowing, then take the principle of " low velocity, the amount of resetting, small tension receiving coil " during comb and parallel cotton fibers prior to spinning, then adopt the principle of " close setting, the big twist, low-tension, low velocity " when drafting, rove, spun yarn.
Like this, in the chitin spinning, cotton cleaning process adopts the card wire formula hired roughneck of low velocity that fiber is strengthened dividing comb under big quantitative prerequisite, and promptly the hired roughneck of opener and lapper adopts the card wire formula, and adopts mixing and blowing machine and card wire formula opener to be used the opening or cleaning of strengthening fiber; Amplify hired roughneck and the spacing of giving cotton roller and feed plate, and improve rotation speed of fan; Adopt the quantitatively big of 400~500g/m during rolling, and length adopts smaller length, prevents the web broken hole, and, sticking volume takes place easily, can in volume, adopt to fetter with kind rove bar because the fiber rolling is more fluffy.
Adopt in the carding step and before carding machine, install the cotton plate of holder additional, 290~310 rev/mins of control cylinder rotating speeds, 685~720 rev/mins of licker-in rotating speeds, 18~20 rev/mins of doffer's rotating speeds, and can give fine length with relative increase with the feed plate bed hedgehopping 6mm on the carding machine, reduce fibre damage; The branch comb that adopts spaces and is 0.2mm, 0.15mm, 0.15mm, 0.15mm, 0.2mm.
Can adopt two during drafting also, 950~1050 rev/mins of the rotating speeds of front roller, and quantitative 19.5 ± 0.5g/5m, head and adopt 1.4, two and adopt 1.2 during back area draft.And, adjust the size of head of the trumpet according to the actual conditions in producing.
Because the ratio of chitin fiber is great, the thick cross-section fibers radical of fiber number is few, adds with electric charge mutually exclusive, thereby make between fiber saturation force very little, so quantitatively answer grasp bigger than normal ripe of rove Working Procedure Controlling, generally at/5 meters of 19 grams, twist factor 75~90, regular roving feeding 5.5 ± 0.3g/10m, the grasp less than normal of machine forward pull is adjusted tension force conversion wheel, to feed tension force behind the reduction machine behind the machine, raise bar tube pallet, after reducing Speed frames, break end; The grasp less than normal of machine forward pull is breaked end to reduce before the reduction machine, roller gauge 25mm * 30mm, and apron spacing block 2.5~3.5mm, back area draft is then 1.2.
Twist factor is 370~390 in the spinning process, 9700~9900 rev/mins of spindle rotating speeds, roller gauge 18mm * 26mm, apron spacing block 2.5~3.5mm, back area draft 1.18.
The chitin kind fiber can adopt a kind of in chitosan (CS) fiber or chitin (ACT) fiber merely, use after also can adopting chitosan (CS) fiber and chitin (ACT) mixed with fibers, as to adopt the weight mixing ratio be chitosan fiber 45%, the mixed proportion of chitin fiber 55% is produced, and it is fibre length 35~40mm that chitosan and chitin fiber can adopt specification, fibre fineness 1.5~2.5D, single fiber intensity 1.53~2CN/dtex, pH value 6~7, moisture regain 15.0~15.5% is produced.
After add man-hour because the chitin fiber yarn strength is very little,, tension pulley can be removed so tension force must be little during spinning, adopt balloon controller, the bobbin package is little, for guaranteeing back processing, can incorporate a water soluble vinylon in yarn
The pure chitin yarn that the present invention produces not only has indexs such as good bar is dried, and its intensity is also better, can adapt to people's needs fully.And produce the method for pure chitin yarn among employing the present invention, its technology is simple, and is easy to operate, solves current chitin fiber and can only adopt the problem that can not purely spin with other fiber blend, and the spinning method of pure chitin fiber is provided for people.
In the present invention, chitin kind fiber chitosan (CS) fiber and chitin (ACT) fiber are two kinds of chitin fibers that current people generally use, and the spinning equipment that in spinning process, uses, the mixing and blowing machine A035 when griping cotton machine that uses when grabbing cotton in the cotton cleaning process such as A002, opener and card wire formula opener A036C, cotton feeder such as A092AST, lapper such as A076, carding machine such as A186F, drawing frame such as A272F, Speed frames such as A454, fine spining machine such as FA502 etc. are the equipment that people use in the spinning of reality.And in the production of reality, technological parameter in each procedure is carried out suitable adjustment according to the needs of producing, with carrying out smoothly of helping producing, as the rotating speed of adjusting griping cotton machine, carding machine etc., this all is the known general knowledge of those skilled in the art.
The specific embodiment
Embodiment one
Getting the raw materials ready and adopting weight ratio is chitosan fiber 45%, chitin fiber 55% mixes, by griping cotton machine, mixing and blowing machine, card wire formula opener, the lapper of cotton feeder and kirschner beater formula makes the raw material rolling, and 400~500 rev/mins of the rotating speeds of control griping cotton machine, and about 450 rev/mins of card wire formula opener hired roughnecks, about 700 rev/mins of lapper hired roughnecks, while and the spacing of amplifying the hired roughneck and giving cotton roller and feed plate, and improve rotation speed of fan; Adopt the quantitatively big of 400~500g/m during rolling, and volume length adopts smaller length, prevents the web broken hole, and, sticking volume takes place easily, can in volume, adopt to fetter with kind rove bar because the fiber rolling is more fluffy.
Before carding machine, install the cotton plate of holder in the carding step additional, solve easily broken web in the chitin fiber net process, shift difficulty, the problem of being caught, 290~310 rev/mins of control cylinder rotating speeds, 685~720 rev/mins of licker-in rotating speeds, 18~20 rev/mins of doffer's rotating speeds, give fine length with the feed plate bed hedgehopping 6mm on the carding machine with relative increase, reduce fibre damage; Adopt the branch comb of 0.2mm, 0.15mm, 0.15mm, 0.15mm, 0.2mm to space, it is thick and stiff to solve chitin fiber, is difficult for being gripped by pin, has the problem of not dividing the tow of comb in the web.
Drafting can adopt two also, because the chitin fiber brute force is less, long filament is easily broken, can control 950~1050 rev/mins of the rotating speeds of front roller, and quantitative 19.5 ± 0.5g/5m, head and adopt 1.4 during back area draft, two and adopt 1.2, and, adjust the size of head of the trumpet according to the actual conditions in producing.
Ripe of rove Working Procedure Controlling is quantitatively answered grasp bigger than normal, generally at/5 meters of 19 grams, twist factor 75~90, regular roving feeding 5.5 ± 0.3g/10m, tension force conversion wheel is adjusted in the grasp less than normal of machine forward pull behind the machine, to feed tension force behind the reduction machine, raise bar tube pallet, after reducing Speed frames, break end; Sliver control pressing device should be around 3 circles, the grasp less than normal of machine forward pull, to reduce broken end, roller gauge 25mm * 30mm, apron spacing block 2.5~3.5mm before the reduction machine, back area draft is then 1.2, great with the ratio that solves chitin fiber, the thick cross-section fibers radical of fiber number is few, and is mutually exclusive with electric charge, thereby it is poor to embrace with power between the solution chitin fiber, the problem of resultant yarn difficulty.
Twist factor is 370~390 in spinning process, and steel traveler can adopt 7702, and its weight ratio is cotton little 4~No. 6,9700~9900 rev/mins of spindle rotating speeds, roller gauge 18mm * 26mm, apron spacing block 2.5~3.5mm, back area draft 1.18.
Add man-hour after carrying out, because the chitin fiber yarn strength is very little, so tension force must be little during spinning, can take to remove tension pulley, use balloon controller, the bobbin package is little, for guaranteeing back processing, can incorporate a water soluble vinylon into.
The chitin fiber yarn quality: 30 of kinds, bar are done the coefficient of variation (%) 18.2, km details (50%) 430, km slubbing (+50%) 1200, km cotton knot (+200%) 1350, intensity 7.7CN/TEX, hairiness index 7.6.
Embodiment two
Raw material adopts pure chitosan fiber, and other technological parameter is with embodiment one.
The chitin fiber yarn quality: 21 of kinds, bar are done the coefficient of variation (%) 17.5, km details (50%) 410, km slubbing (+50%) 1100, km cotton knot (+200%) 1250, intensity 8.0CN/TEX, hairiness index 7.5.
Embodiment three
Raw material adopts pure chitin fiber, and other technological parameter is with embodiment one.
The chitin fiber yarn quality: 40 of kinds, bar are done the coefficient of variation (%) 19.1, km details (50%) 505, km slubbing (+50%) 1400, km cotton knot (+200%) 1610, intensity 7.8CN/TEX, hairiness index 7.8.

Claims (10)

1. chitin yarn, for adopting the chitin kind fiber is the fine-count yarn of raw material processing, it is characterized in that: the bar of described yarn is done the coefficient of variation (%) 17.0~19.5, km details (50%) 400~550, km slubbing (+50%) 1100~1500, km cotton knot (+200%) 1100~1700, intensity 7.5~9.0CN/TEX, hairiness index 6~8.
2. a kind of chitin yarn as claimed in claim 1 is characterized in that described chitin kind fiber comprises chitosan fiber and/or chitin fiber.
3. a kind of chitin yarn as claimed in claim 2, the weight mixing ratio that it is characterized in that described chitosan fiber and chitin fiber is a chitosan fiber 45%, chitin 55%.
4. produce the method for chitin yarn, for adopting the chitin kind fiber is that raw material is through blowing, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn and back processing chitin yarn, cotton cleaning process in it is characterized in that spinning adopts the card wire formula hired roughneck of low velocity that fiber is carried out branch comb opening or cleaning, and amplify hired roughneck and the spacing of giving cotton roller and feed plate, and improve rotation speed of fan; Adopt the quantitatively big of 400~500g/m during rolling, and rolling length employing smaller length, adopt in the volume to fetter with kind rove bar.
5. the method for production chitin yarn as claimed in claim 4, install the cotton plate of holder in the carding step in it is characterized in that spinning before the machine additional, 290~310 rev/mins of cylinder rotating speeds, 685~720 rev/mins of licker-in rotating speeds, 18~20 rev/mins of doffer's rotating speeds, feed plate bed hedgehopping 6mm gives fine length with relative increase, divides and combs space 0.2mm, 0.15mm, 0.15mm, 0.15mm, 0.2mm.
6. the method for production chitin yarn as claimed in claim 4 is characterized in that adopting during drafting in the spinning two also, 950~1050 rev/mins of front roller rotating speeds, quantitative 19.5 ± 0.5g/5m, back area draft head and 1.4, two and 1.2.
7. the method for production chitin yarn as claimed in claim 4, it is characterized in that: the rove operation twist factor 75~90 in the spinning, regular roving feeding 5.5 ± 0.3g/10m, the grasp less than normal of machine forward pull, adjust tension force conversion wheel behind the machine, to feed tension force behind the reduction machine, roller gauge 25mm * 30mm, apron spacing block 2.5~3.5mm, back area draft 1.2.
8. the method for production chitin yarn as claimed in claim 4, the spinning process twist factor 370~390 in it is characterized in that spinning, 9700~9900 rev/mins of spindle rotating speeds, roller gauge 18mm * 26mm, apron spacing block 2.5~3.5mm, back area draft 1.18.
9. the method for production chitin yarn as claimed in claim 4 is characterized in that incorporating a water soluble vinylon into behind the chitin kind fiber spinning resultant yarn.
10. as the method for each described production chitin yarn in the claim 4 to 9, it is characterized in that described chitin kind fiber comprises chitosan fiber and/or chitin fiber.
CNB2006100689166A 2006-09-08 2006-09-08 A kind of chitin yarn and production method thereof Expired - Fee Related CN100549260C (en)

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CN100549260C CN100549260C (en) 2009-10-14

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105734746A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
CN105734749A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
CN105734747A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
CN105970383A (en) * 2016-07-01 2016-09-28 河南新野纺织股份有限公司 Production method of three-component compact siro blended yarn
FR3035123A1 (en) * 2015-04-14 2016-10-21 Entofly Chitine PROCESS FOR PRODUCING TISSUE OR KNIT FROM ARTHROPODIC PARTS

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105734746A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
CN105734749A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
CN105734747A (en) * 2014-12-10 2016-07-06 常熟市新康盛化纤有限公司 Composite yarn
FR3035123A1 (en) * 2015-04-14 2016-10-21 Entofly Chitine PROCESS FOR PRODUCING TISSUE OR KNIT FROM ARTHROPODIC PARTS
CN105970383A (en) * 2016-07-01 2016-09-28 河南新野纺织股份有限公司 Production method of three-component compact siro blended yarn

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