CN101125952A - Polyurethane foam stabilizer with low density and low thermal conductivity factor and preparation method thereof - Google Patents
Polyurethane foam stabilizer with low density and low thermal conductivity factor and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a low-density and low thermal-conduction-index polyurethane foam stabilizer and a preparation method thereof. The stabilizer can be widely used in polyurethane blowing technique, and enable the thermal conduction index of the pentane-blowing polyurethane foam to be lowered down to 0.0195-0.0200W/m.K, and has excellent functions of heat protection and heat preservation. The low-density and low thermal-conduction-index polyurethane foam stabilizer of the invention is provided with the structures: wherein, the figure of m is 10-80, the figure of n is 1-10, the figure of x is 10-70, the figure of y is 0-30, and m plus n is 11-90, x plus y is 10-100; R can be paraffin, radical aromatic, acyloxy or hydrogen atom that contains 1-4 carbon atoms.
Description
Technical field
The present invention relates to a kind of polyurethane foam stabilizer and preparation method thereof, more specifically to a kind of low density and low heat conduction coefficient polyurethane foam stabilizer and preparation method thereof, this stablizer can be widely used in the polyurethane foam technology of pentane-blown system.
Background technology
Urethane foam is a kind of important synthetic materials, has characteristics such as porousness, relative density are little, specific tenacity height, and variations different according to used raw material and prescription can be made into common soft bubble, high rebound foam and hard bubble etc.Since coming out, its output is always in continuous increase, and polyurethane foam stabilizer is one of indispensable auxiliary agent in the polyurethane foam foam process, and it develops along with the whole adjustment development of polyurethane foam industry.
Suds-stabilizing agent also claims foam stabilizer, be make polyurethane foam combination material have emulsifying property, become nuclearity, one of flowability and stable most important auxiliary agent.In the hard polyurethane foam field, all being to use CFC-11 in early days is whipping agent, though this product cost is lower, performance is good, but because it is the chlorine fluoride compound, ozonosphere in the atmosphere is had tangible destruction, seriously caused the deterioration of atmospheric environment to face at present to eliminate comprehensively and banned use of.Pentane class whipping agent is because its ODP value is zero, and is minimum to environmental influence, substitutes whipping agent as F11 and is widely used at present.But pentane class whipping agent also has its shortcoming, except that poor stability mainly be poor with intermiscibility such as polyethers, the gas phase thermal conductivity is high, this just proposes higher requirement to polyurethane foam stabilizer.Especially in the refrigerator industry, the polyurethane material of use not only needs it that low thermal conductivity is arranged, and also requires low density at present, promptly under the prerequisite that guarantees foamy body, makes the density of its foam core lower, thereby reduces cost.Yet functions such as the emulsification that suds-stabilizing agent is risen in the urethane foam moulding process, nucleation, foam stabilization, it is contradiction that its performance has both, may will sacrifice a part of nucleation performance if improved emulsifying property, how making these performances reach perfect balance is emphasis and difficult point.How to design a kind of molecular structure of low density and low heat conduction coefficient polyurethane foam stabilizer, make it satisfy the application performance of urethane foam, just become key with suds-stabilizing agent.
Disclose a kind of combination material in " synthesizing of hard polyurethane foam organosilicon foam stabilizer " literary composition in the prior art as in 2005 03 phases " Speciality Petrochemicals " and shown that its product thermal conductivity can reach 0.021W/m.K; Also disclosing a kind of in the literary composition of " producing the method for the urethane closed pore rigid foam of low thermal conductivity " in 2004 03 phases " world rubber industry " is that whipping agent is that the product thermal conductivity of stablizer reaches 0.0206W/m.K with the polysiloxane with the pentamethylene.The thermal conductivity of product is still waiting further reduction in these prior aries, they are the density that simple reduction thermal conductivity does not consider to reduce its foam core in addition, also cause its cost higher, and the surfactivity of its suds-stabilizing agent, emulsifying property and comprehensive balance quality all have much room for improvement.
Summary of the invention
The objective of the invention is to solve deficiency and the problem that exists in the above-mentioned present technology, a kind of low density and low heat conduction coefficient polyurethane foam stabilizer is provided.
The present invention simultaneously also provides the preparation method of this low density and low heat conduction coefficient polyurethane foam stabilizer.
Technical scheme of the present invention is as follows:
Low density and low heat conduction coefficient polyurethane foam stabilizer of the present invention, it has following structure:
Wherein: the value of m is 10～80, and the value of n is 1～10, and the value of x is 10～70, and the value of y is 0～30, and m+n is 11～90, and x+y is 10～100; R is that carbonatoms is alkane, aromatic group, acyloxy or the hydrogen atom of 1～4 C.
The preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer of the present invention, it may further comprise the steps:
A) with the vinyl carbinol be initiator, in reactor, add oxyethane and propylene oxide, in the presence of catalyzer a, pressure-controlling is at≤0.4MPa, temperature of reaction is to react 4～6 hours under 100～130 ℃ of conditions, obtain holding propenyl polyethers (I), wherein the mol ratio of the consumption of oxyethane and propylene oxide consumption sum and initiator vinyl carbinol is 10～50: 1;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under catalyzer b effect, in temperature of reaction is to react 5～7 hours under 60～90 ℃ of conditions, obtain polysiloxane (II), wherein the mol ratio between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 1～40: 1～5: 0～3;
C) the end propenyl polyethers (I) that top two-step reaction is obtained, polysiloxane (II), Pt catalyzer and solvent add reactor, heat temperature raising to 60 under normal pressure～120 ℃, the Inlet and outlet water of reflux exchanger the time is opened in heating, make solvent by condenser at the still internal reflux; Be incubated 2～5 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat that solvent has been steamed the back cooling discharge, promptly gets low density and low heat conduction coefficient polyurethane foam stabilizer.
Among the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer of the present invention, its steps A) the catalyzer a described in is a basic catalyst, preferred KOH or NaOH, and its consumption is 0.1～0.5% of oxyethane and the total weight of material of propylene oxide; Its steps A) weight proportion between oxyethane described in and the propylene oxide is preferably: oxyethane is 50～100%, and propylene oxide is 0～50%; Its step B) the catalyzer b described in is a Lewis acid, is preferably sulfuric acid, and its consumption is 0.1～3% of a used weight of material; Its step B) content of hydrogen is preferably 0.15～1.0% in the containing hydrogen silicone oil described in; It is characterized in that step C) described in end propenyl polyethers (I) and polysiloxane (II) consumption weight proportion be (50-120)/(10-20), Pt catalyzer and solvent load are respectively the 5-50ppm and the 30-90% of weight of material, and described solvent is preferably toluene, dimethylbenzene or ethylene glycol.
Compared with prior art the invention has the beneficial effects as follows:
1) can make the thermal conductivity of the polyurethane foam of pentane class foaming be reduced to 0.0195～0.0200W/m.K, its heat preservation and insulation is good, and in cabinet insulation layer fields such as refrigerator, freezer, the every reduction by 9% of thermal conductivity, energy consumption will reduce by 5%, on refrigerator, use to make refrigerator more energy-conservation, thereby realized the green energy conservation requirement that the freon-free refrigerator combination is expected; 2) have excellent emulsifying property, become nuclearity and froth stability and over-all properties to reach good balance, have powerful nucleation ability, froth product density is low and have fine and closely woven foam structure and a high rate of closed hole; 3) improve the structural strength of polyurethane foam, make that foam is difficult for shrinking; Foamy core density is lower simultaneously, thereby the cost of product is reduced; 4) can make material in foaming process, have good flowability; make porous plastics have excellent cohesive force; when on refrigerator, using; help bonding and the sealing between foam and the steel plate in making the process of foam article of refrigerator combination material; the insulation tank material and the building thermal insulation material that also can be used for thermal container simultaneously reach save energy and protection environment.
Preparation method of the present invention in addition is simple, the constant product quality of production, and raw material is easy to get, and is lower from its production cost of original raw material, and two key end-blocking rates can reach more than 93%.
Embodiment
Embodiment 1
A) in reactor, add vinyl carbinol 5.8g, oxyethane 120g and propylene oxide 100g, in the presence of the 1.1g catalyzer KOH, pressure≤0.4Mpa, temperature of reaction be to react 5 hours under 110 ℃ of conditions, obtains holding the propenyl polyethers;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under effect of sulfuric acid, in temperature of reaction is to react 5 hours under 80 ℃ of conditions, obtain polysiloxane (II), wherein the consumption mole proportioning between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 10: 1: 1.5;
C) modified polyether that top two-step reaction is obtained (I) 150g and polysiloxane (II) 80g are under the 30ppmPt catalyst action and in the presence of the 120g toluene, heat temperature raising to 115 ℃ under normal pressure, the Inlet and outlet water of reflux exchanger the time is opened in heating, make toluene by condenser at the still internal reflux; Be incubated 4 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat that solvent has been steamed the back cooling discharge and promptly got low density and low heat conduction coefficient polyurethane foam stabilizer, its structural formula result behind phenetic analysis is:
Product properties and effect that this suds-stabilizing agent is applied to polyurethane foam see Table 1 through detecting.
Embodiment 2
A) in reactor, add vinyl carbinol 5.8g, oxyethane 160g and propylene oxide 100g, in the presence of the 1.06g catalyzer KOH, pressure≤0.4Mpa, temperature of reaction be to react 6 hours under 100 ℃ of conditions, obtains holding the propenyl polyethers;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under effect of sulfuric acid, in temperature of reaction is to react 5 hours under 80 ℃ of conditions, obtain polysiloxane (II), wherein the consumption mole proportioning between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 15: 1: 1.5;
C) modified polyether that top two-step reaction is obtained (I) 200g and polysiloxane (II) 80g are under the 50ppm Pt catalyst action and in the presence of the 180g dimethylbenzene, heat temperature raising to 115 ℃ under normal pressure, the Inlet and outlet water of reflux exchanger the time is opened in heating, make dimethylbenzene by condenser at the still internal reflux; Be incubated 4 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat that solvent has been steamed the back cooling discharge and promptly got low density and low heat conduction coefficient polyurethane foam stabilizer, its structural formula result behind phenetic analysis is:
Product properties and effect that this suds-stabilizing agent is applied to polyurethane foam see Table 1 through detecting.
Embodiment 3
A) in reactor, add vinyl carbinol 5.8g, oxyethane 120g and propylene oxide 100g, in the presence of the 1.0g catalyzer KOH, pressure≤0.4Mpa, temperature of reaction be to react 4 hours under 130 ℃ of conditions, obtains holding the propenyl polyethers;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under effect of sulfuric acid, in temperature of reaction is to react 5 hours under 80 ℃ of conditions, obtain polysiloxane (II), wherein the consumption mole proportioning between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 20: 2.5: 2;
C) modified polyether that top two-step reaction is obtained (I) 150g and polysiloxane (II) 75g are under the 10ppm Pt catalyst action and in the presence of the 110g toluene, heat temperature raising to 115 ℃ under normal pressure, the Inlet and outlet water of reflux exchanger the time is opened in heating, make solvent by condenser at the still internal reflux; Be incubated 4 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat that solvent has been steamed the back cooling discharge and promptly got low density and low heat conduction coefficient polyurethane foam stabilizer, its structural formula result behind phenetic analysis is:
Product properties and effect that this suds-stabilizing agent is applied to polyurethane foam see Table 1 through detecting.
Embodiment 4
A) in reactor, add vinyl carbinol 5.8g, oxyethane 160g and propylene oxide 100g, in the presence of 1.1g catalyzer KOH basic cpd, pressure≤0.4Mpa, temperature of reaction be to react 5 hours under 110 ℃ of conditions, obtains holding the propenyl polyethers;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under effect of sulfuric acid, in temperature of reaction is to react 5 hours under 80 ℃ of conditions, obtain polysiloxane (II), wherein the consumption mole proportioning between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 25: 2.0: 1.4;
C) modified polyether that top two-step reaction is obtained (I) 200g and polysiloxane (II) 70g are under the 30ppm Pt catalyst action and in the presence of the 190g toluene, heat temperature raising to 115 ℃ under normal pressure, the Inlet and outlet water of reflux exchanger the time is opened in heating, make solvent by condenser at the still internal reflux; Be incubated 4 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat solvent steamed the back cooling discharge promptly get low density and low heat conduction coefficient polyurethane foam stabilizer, in its structure behind phenetic analysis the result be:
Product properties and effect that this suds-stabilizing agent is applied to polyurethane foam see Table 1 through detecting.
Table 1: this suds-stabilizing agent is applied to pentane-blown system polyurethane foamy product properties
| Foam article thermal conductivity (W/m.K) | Foam article density (kg/m 3) | Compressive strength KPa | Emulsifying property | Fluidity index (cm/g) | |
| Embodiment 1 | 0.0197 | 31.56 | 156.2 | Transparent | 0.091 |
| Embodiment 2 | 0.0196 | 31.45 | 158.3 | Transparent | 0.091 |
| Embodiment 3 | 0.0192 | 31.68 | 155.9 | Transparent | 0.091 |
| Embodiment 4 | 0.0195 | 30.59 | 156.6 | Transparent | 0.092 |
| External product 1 | 0.0197 | 31.84 | 152.1 | Transparent | 0.089 |
| External product 2 | 0.0198 | 32.63 | 161.0 | Transparent | 0.091 |
| Domestic usual production | 0.0217 | 35.72 | 143.7 | Opaque | 0.088 |
Annotate: go up the goods of Performance Detection data in the table, make by following polyurethane foam prescription (weight proportion): (4110) 80 parts of polyethers, (635) 20 parts of polyethers, 1.5 parts in water, 1.5 parts of dimethyl cyclohexanes, DMP301.3 part, 2.0 parts of suds-stabilizing agents, 13 parts of pentamethylene, 143 parts of MDI.
Claims (9)
1. low density and low heat conduction coefficient polyurethane foam stabilizer is characterized in that having following structure:
Wherein: the value of m is 10～80, and the value of n is 1～10, and the value of x is 10～70, and the value of y is 0～30, and m+n is 11～90, and x+y is 10～100; R is that carbonatoms is alkane, aromatic group, acyloxy or the hydrogen atom of 1～4 C.
2. the preparation method of a kind of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 1 is characterized in that may further comprise the steps:
A) with the vinyl carbinol be initiator, in reactor, add oxyethane and propylene oxide, in the presence of catalyzer a, pressure-controlling is at≤0.4MPa, temperature of reaction is to react 4～6 hours under 100～130 ℃ of conditions, obtain holding propenyl polyethers (I), wherein the mol ratio of the consumption of oxyethane and propylene oxide consumption sum and initiator vinyl carbinol is 10～50: 1;
B) make octamethylcyclotetrasiloxane, containing hydrogen silicone oil, hexamethyldisiloxane under catalyzer b effect, in temperature of reaction is to react 5～7 hours under 60～90 ℃ of conditions, obtain polysiloxane (II), wherein the mol ratio between octamethylcyclotetrasiloxane, containing hydrogen silicone oil, the hexamethyldisiloxane is 1～40: 1～5: 0～3;
C) the end propenyl polyethers (I) that top two-step reaction is obtained, polysiloxane (II), Pt catalyzer and solvent add reactor, heat temperature raising to 60 under normal pressure～120 ℃, the Inlet and outlet water of reflux exchanger the time is opened in heating, make solvent by condenser at the still internal reflux; Be incubated 2～5 hours then and carry out polyreaction, carry out air distillation earlier and carry out underpressure distillation again, treat that solvent has been steamed the back cooling discharge, promptly gets low density and low heat conduction coefficient polyurethane foam stabilizer.
3. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 2 is characterized in that step
A) the catalyzer a described in is a basic catalyst, and its consumption is 0.1～0.5% of oxyethane and the total weight of material of propylene oxide.
4. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 3 is characterized in that described basic catalyst is KOH or NaOH.
5. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 2, it is characterized in that steps A) described in oxyethane and the weight proportion between the propylene oxide be: oxyethane is 50～100%, and propylene oxide is 0～50%.
6. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 2 is characterized in that step
B) the catalyzer b described in is a Lewis acid, and its consumption is 0.1～3% of a used weight of material.
7. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 2 is characterized in that step
B) content of hydrogen is 0.15～1.0% in the containing hydrogen silicone oil described in.
8. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 2 is characterized in that step
C) the end propenyl polyethers (I) described in is (50-120)/(10-20) with polysiloxane (II) consumption weight proportion, and Pt catalyzer and solvent load are respectively the 5-50ppm and the 30-90% of weight of material.
9. the preparation method of low density and low heat conduction coefficient polyurethane foam stabilizer according to claim 8 is characterized in that described solvent is toluene, dimethylbenzene or ethylene glycol.
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