CN101121835A - Long-acting fragrant printing ink - Google Patents
Long-acting fragrant printing ink Download PDFInfo
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- CN101121835A CN101121835A CN 200710132242 CN200710132242A CN101121835A CN 101121835 A CN101121835 A CN 101121835A CN 200710132242 CN200710132242 CN 200710132242 CN 200710132242 A CN200710132242 A CN 200710132242A CN 101121835 A CN101121835 A CN 101121835A
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Abstract
The present invention relates to a long-effect fragrant ink, including a color material providing the colors, a connecting material, a solvent, a dispersant and a viscosity modifier; the ink also contains a fragrance intermediate of 1 to 10 percent and a solvent which can dissolve the color material, the connecting material and the fragrance intermediate at the same time; the solvent is chosen from the hydrocarbons, alcohols, ketones, esters, or mineral oil. When the fragrance intermediate is exposed in the air, the fragrance intermediate can be oxidated to release the fragrance; when the fragrance intermediate is in the closed space, the oxidation is stopped because of the lack of the oxygen and the release of the fragrance is also suspended. Therefore, the book or the folding-leaf product printed with the fragrant ink can release the fragrance only when opened for reading; when book or the folding-leaf product is closed, the fragrance is weakened and finally disappears; thus the fragrance of the ink can be maintained for a longer period.
Description
Technical field
The present invention relates to print the printing ink of usefulness, particularly have the long-acting fragrant printing ink of ease Xiang Gong energy.
Background technology
At present, fragrance is printed on existing application the in the decoration printing of packing of daily life and some commodity, for example distributes the ceremony printed matters such as business card, greeting card of aromatic odour, can promote the warm romantic sentiment between the kith and kin; The extraordinary fragrance of some packing of product can increase the magnetism of product; In addition, the printing of employing fragrance, the packages printing of food is contained and the identical fragrance of interior dress food, the printing of cosmetic package contains the fragrance consistent with perfume, contain the fragrance of a flower etc. at printed matters such as product description or postcard, monthly calendar, New Year cards, thereby can improve the class of commodity or printed matter itself.At present, the process that spices is printed onto fragrant printing ink has been experienced in the preparation of aromatic printed matter, and fragrant printing ink then experienced the process of powdered flavour to capsule spices.
Initial spices printing is on the good paper of absorptive character, stamp picture and text after, earlier with clear flavor printing ink coating one deck, and then use general ink printing.Afterwards,, directly spices is added in the printing ink, saves " coating " operation in the printing process for simplifying procedures.But above dual mode all can not make fragrance stay for a long time on printing surface, and after a few days, fragrance weakens; Yet but because of fragrance distributes in a large number, fragrance overrich in the machine room not only causes the spices waste in printing process, and the long-time a large amount of this air of suction of pressman, and is unfavorable to health.Afterwards, invented at the beginning of the seventies spices is enclosed in the micelle, micelle adds in the printing ink and prints, when micelle was destroyed, fragrance came out gradually, and the diameter of micelle is 10～30 microns, about 1 micron of micelle thickness, rete can make fragrance stored for a long time, does not distribute in operation process.Generally speaking, the fragrance of printed matter can remain on about 1 year.But, the complicated process of preparation of capsule spices, and it is limited to can be used for encapsulated spices kind.In addition, because capsule is staved by machinery easily, cause fragrance to be escaped, do not reach the effect of slowly-releasing, do not staved, require the print speed (wiping speed) can not be too fast in order to guarantee capsule, squeegee pressure (promptly scraping pressure) can not be too big, so generally only be applicable to screen painting.
Summary of the invention
It is simple to the purpose of this invention is to provide a kind of preparation technology, long-acting fragrant printing ink easy to use, and the printed matter that its printing forms can discharge fragrance for a long time, and is applicable to multiple mode of printing.
This long-acting fragrant printing ink comprises the colorant that color is provided and connects material, solvent, dispersion agent and viscosity-controlling agent, wherein: connect material and be crude vegetal, mineral oil, natural resin or synthetic resins, dispersion agent is a nonionogenic tenside, viscosity-controlling agent is selected from tung oil, oleum lini or soybean oil, or be selected from viscosity reductant aluminium salt, low-viscosity Synolac or paraffin oil, in addition, also contain the oxidized spices intermediate that disengages fragrance of energy when exposing in the printing ink in air, content is 1～10%; Hydro carbons, alcohols, ketone, ester or mineral oil that said solvent is selected from can be dissolved colorant simultaneously, connect material and spices intermediate, its weight content is 3～15%.
Said can the oxidized spices intermediate that disengages fragrance when in air, exposing, such as being beta-myrcene or trans-anethole, preferred content is 2%--4%.
Said solvent is preferably C
1-C
4Alcohols, preferred content are 4%-7%.
Said connection material is preferably the high point petroleum cut or the rosin modified phenolic resin of 230-320 degree.
The spices intermediate that contains in this printing ink itself does not have fragrance, still, in air, expose oxidized after, will generate and contain savory chemical substance, discharge fragrance.And this oxidation is at normal temperature and pressure, does not need slowly to carry out by airborne oxygen under the condition of catalyzer, and under the situation of it and air insulated or lack of air, oxidising process stops, and no longer discharges fragrance.Selecting suitable spices intermediate is key of the present invention, for example: colourless to the easily oxidation and aggregate into tool empty talk face cream fragrance in air of the beta-myrcene of talking yellow liquid; Trans-anethole can obtain anisyl aldehyde by oxidation, has strong anise and hawthorn fragrance.
Colorant in this printing ink is pigment or dyestuff, wherein also adds fillers such as an amount of lime carbonate, aluminium hydroxide or barium sulfate.Pigment is graininess in medium, dyestuff then is molecularity in medium.The effect that connects material is the carrier as colorant, colorant is mixed with filler couples together, and make printing ink can be on the object plane of undertaking the printing of drying, set and film forming.Dispersion agent can make these material homodisperse be integral, and an amount of viscosity-controlling agent can be adjusted printing ink and meet the viscosity that the printshop needs, and guarantees printing quality.
The ratio that the spices intermediate uses can be determined the olfactory stimulation degree and the human body sense of smell custom of human body by the spices that the spices intermediate changes into behind the spices.The spices big to the human body olfactory stimulation, the consumption of its intermediate just can be a little less; The spices little to the human body olfactory stimulation, the consumption of its intermediate just can be more.The consumption of solvent mainly is can fully dissolve with spices intermediate, colorant, connection material, the spices intermediate is dissolved in colorant fully is connected in the material.
Printing ink of the present invention can adopt the ordinary method printing, and when the printed matter that is printed as exposed in air, the spices intermediate is oxidized to form odoriferous spices.When printed matter was closed or do not expose in air, the reaction of spices oxidization of intermediates was interrupted, and fragrance stops loss.Spices oxidization of intermediates process is slowly carried out, and fragrance also is to discharge at leisure, therefore can reach the purpose of long-term lasting; Be specially adapted to the printing of books and periodicals magazine, product description, greeting card.When printed matter is opened when reading, the spices intermediate is the oxidized and elegant fragrance that goes out, and can give the people a kind of sensation of pure and fresh, joyful, restoring consciouness; Close when closing books or greeting card and to put when not reading, oxidizing reaction stops, and fragrance stops loss, thereby fragrance is enjoyed for a long time.
Compare with the microcapsule fragrant printing ink, long-acting fragrant printing ink of the present invention need not complicated manufacturing process, and can adapt to typography widely, the printed matters of often browsing for needs such as books and periodicals magazine, can not produce printed matter as the microcapsule fragrant printing ink because of browsing repeatedly, cause the capsule mechanical destruction and the phenomenon of escape fragrance.Therefore the present invention is specially adapted to the printing of books and periodicals magazine, product description etc.
Embodiment
Embodiment: the preparation of long-acting fragrant printing ink
The selected colorant of this example is the azo pigment powder, and adds an amount of stopping composition as lime carbonate, aluminium hydroxide or barium sulfate.The spices intermediate of selecting for use is a beta-myrcene, and solvent is an ethanol, connects material and selects rosin modified phenolic resin for use, and viscosity-controlling agent is selected oleum lini for use, and dispersion agent is a nonionogenic tenside commonly used in the printing ink.Each component is got the raw materials ready by following weight part: colorant 25-35 weight part, connection material 45-50 weight part, spices intermediate 2-4 weight part, viscosity-controlling agent 1-3 weight part, dispersion agent 2-3 weight part, solvent 4-7 weight part.
This printing ink preparation process is as follows:
Under mechanical stirring, by above-mentioned weight part etoh solvent and spices intermediate beta-myrcene are added in the dissolving bucket, stirring at normal temperature to spices intermediate is dissolved in the solvent fully, gets the beta-myrcene solvent solution.
In mixer, successively add connection material rosin modified phenolic resin, colorant azo pigment powder (adding an amount of filler) by above-mentioned weight part, open mechanical stirring, 15 minutes time.Add above-mentioned beta-myrcene solvent and the nonionogenic tenside that modulates, stirred 40-60 minute.The material that stirring finishes is placed into three rod machines, through several times grinding, and time 200-300 minute, when the fineness of printing ink is controlled at less than 10 microns.Add partial solvent and viscosity-controlling agent oleum lini again, adjust printing ink, have certain fluidity to needed viscosity.Obtain product long-acting fragrant printing ink of the present invention by canned at last.The printing ink of present embodiment manufacturing, the property sort of pressing printing ink, it belongs to fast dried light flexographic ink.
Only as an example of printing ink, its content is not as protection scope of the present invention for above embodiment.
This long-acting printing ink can adopt typography commonly used, prints (coating) with printing ink of the present invention on offset machine, binds into book or hinge.When the reader opens when reading, clear fragrance is to come out from book longly, to the sensation of a kind of pure and fresh, joyful, restoring consciouness of people.When closing books after readding, the decrescence weak and termination immediately of fragrance, so the fragrance of this printing ink can keep the long term.
Claims (6)
1. long-acting fragrant printing ink, comprise the colorant that color is provided and connect material, solvent, dispersion agent and viscosity-controlling agent, wherein: connect material and be crude vegetal, mineral oil, natural resin or synthetic resins, dispersion agent is a nonionogenic tenside, viscosity-controlling agent is selected from tung oil, oleum lini or soybean oil, or be selected from viscosity reductant aluminium salt, low-viscosity Synolac or paraffin oil, and it is characterized in that containing the oxidized spices intermediate that disengages fragrance of energy when in air, exposing, weight content is 1～10%; Hydro carbons, alcohols, ketone, ester or mineral oil that said solvent is selected from can be dissolved colorant simultaneously, connect material and spices intermediate, weight content is 3～15%.
2. long-acting fragrant printing ink according to claim 1 is characterized in that said spices intermediate is beta-myrcene or trans-anethole.
3. long-acting fragrant printing ink according to claim 2, the weight content that it is characterized in that said spices intermediate is 2%--4%.
4. long-acting fragrant printing ink according to claim 1 is characterized in that said solvent is C
1-C
4Alcohols.
5. long-acting fragrant printing ink according to claim 1 is characterized in that said weight of solvent content is 4%-7%.
6. long-acting fragrant printing ink according to claim 1 is characterized in that high point petroleum cut or rosin modified phenolic resin that said connection material is the 230-320 degree.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710132242 CN101121835A (en) | 2007-09-26 | 2007-09-26 | Long-acting fragrant printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710132242 CN101121835A (en) | 2007-09-26 | 2007-09-26 | Long-acting fragrant printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101121835A true CN101121835A (en) | 2008-02-13 |
Family
ID=39084342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710132242 Withdrawn CN101121835A (en) | 2007-09-26 | 2007-09-26 | Long-acting fragrant printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101121835A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531845B (en) * | 2009-04-15 | 2010-12-29 | 苏州科斯伍德油墨股份有限公司 | Flexographic ink with high degradation rate |
| CN103509407A (en) * | 2013-10-25 | 2014-01-15 | 张家港市威迪森油墨有限公司 | Blue fluorescent ink |
| CN103525185A (en) * | 2013-10-25 | 2014-01-22 | 张家港威迪森化学有限公司 | Non-benzene plastic ink |
| CN103589243A (en) * | 2013-11-04 | 2014-02-19 | 张家港市威迪森油墨有限公司 | Fluorescent ink |
| CN103642301A (en) * | 2013-11-19 | 2014-03-19 | 张家港市威迪森油墨有限公司 | Floral mosquito repelling ink |
| CN103642302A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Environment-friendly ink |
| CN103666021A (en) * | 2013-12-11 | 2014-03-26 | 苏州谊恒印务有限公司 | Pure natural ink |
| CN106118229A (en) * | 2016-08-29 | 2016-11-16 | 苏州安洁科技股份有限公司 | A kind of environment-friendly ink |
| CN106497231A (en) * | 2016-10-31 | 2017-03-15 | 秦晴晴 | A kind of temperature sensitive ink for containing 1,2 biphenoxyl ethanes and preparation method thereof |
| CN107686701A (en) * | 2017-10-17 | 2018-02-13 | 天津安光油墨厂有限公司 | A kind of green paper drier |
| US10394154B2 (en) | 2015-07-17 | 2019-08-27 | Hp Indigo B.V. | Electrophotographic composition |
| US10514625B2 (en) | 2016-03-09 | 2019-12-24 | Hp Indigo B.V. | Electrophotographic ink including a volatile fragrance |
-
2007
- 2007-09-26 CN CN 200710132242 patent/CN101121835A/en not_active Withdrawn
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531845B (en) * | 2009-04-15 | 2010-12-29 | 苏州科斯伍德油墨股份有限公司 | Flexographic ink with high degradation rate |
| CN103509407A (en) * | 2013-10-25 | 2014-01-15 | 张家港市威迪森油墨有限公司 | Blue fluorescent ink |
| CN103525185A (en) * | 2013-10-25 | 2014-01-22 | 张家港威迪森化学有限公司 | Non-benzene plastic ink |
| CN103589243A (en) * | 2013-11-04 | 2014-02-19 | 张家港市威迪森油墨有限公司 | Fluorescent ink |
| CN103642301A (en) * | 2013-11-19 | 2014-03-19 | 张家港市威迪森油墨有限公司 | Floral mosquito repelling ink |
| CN103642302A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Environment-friendly ink |
| CN103666021A (en) * | 2013-12-11 | 2014-03-26 | 苏州谊恒印务有限公司 | Pure natural ink |
| US10394154B2 (en) | 2015-07-17 | 2019-08-27 | Hp Indigo B.V. | Electrophotographic composition |
| US10514625B2 (en) | 2016-03-09 | 2019-12-24 | Hp Indigo B.V. | Electrophotographic ink including a volatile fragrance |
| CN106118229A (en) * | 2016-08-29 | 2016-11-16 | 苏州安洁科技股份有限公司 | A kind of environment-friendly ink |
| CN106497231A (en) * | 2016-10-31 | 2017-03-15 | 秦晴晴 | A kind of temperature sensitive ink for containing 1,2 biphenoxyl ethanes and preparation method thereof |
| CN107686701A (en) * | 2017-10-17 | 2018-02-13 | 天津安光油墨厂有限公司 | A kind of green paper drier |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU KESIWODE INK CO.LTD. Free format text: FORMER OWNER: SUZHOU KINGSWOOD PRINTING INK CO.,LTD. Effective date: 20090403 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20090403 Address after: Jiangsu Province, Suzhou City, Xiangcheng District Pan Yang Industrial Park Road, spring post No. 3-1 encoding: 215152 Applicant after: Suzhou Kingswood Printing Ink. Co., Ltd. Address before: Jiangsu city of Suzhou province Xiangcheng District Huang Tai town East Bridge Post encoding: 215152 Applicant before: Suzhou Kingswood Printing Ink Co., Ltd. |
|
| WW01 | Invention patent application withdrawn after publication |
Open date: 20080213 |