CN101121586A - C100 high-performance concrete and formulation method thereof - Google Patents

C100 high-performance concrete and formulation method thereof Download PDF

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Publication number
CN101121586A
CN101121586A CNA2007102011320A CN200710201132A CN101121586A CN 101121586 A CN101121586 A CN 101121586A CN A2007102011320 A CNA2007102011320 A CN A2007102011320A CN 200710201132 A CN200710201132 A CN 200710201132A CN 101121586 A CN101121586 A CN 101121586A
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China
Prior art keywords
cement
high performance
concrete
water
performance concrete
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CNA2007102011320A
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CN100509688C (en
Inventor
路来军
马雪英
王安领
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BEIJING XINAO CONCRETE GROUP CO LTD
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Beijing Enn Concrete Co Ltd
BEIJING NEW VOYAGING Co Ltd
Beijing Dongfangjianyu Institute Of Concrete Science & Technology Ltd Compan
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention discloses a C100 high performance concrete, which is made of glue material, sand, stone, water and additive; the glue material comprises cement and mixture; the adding amount for the glue material is 500 to 600kg concrete per stere; thereinto, the cement is 42.5; the mixture comprises three components such as silicon powder, coal ash and scoria powder; the active SiO2, the mount of whch is 20 -40 percent of the total weight in the glue material, and the surface area of which is 1000-1200m2/kg; is included in the glue material, the additive is polymer carboxyl acid with high-efficient dewater ability, the amount of which is 2 - 5 percent of the total glue material; The catalyzer is a mixture consisting of smoke ash and coal waste rock grain, the amount of which are 1-5 percent of the total weight in the glue material. The material does not need high-mark cement with simple produce process and low produce cost; the device can not only enhance the intension of the concrete, but also enhance the working performance and wear ability for the concrete.

Description

C100 high performance concrete and compound method thereof
Technical field
The present invention relates to a kind of building concrete material and compound method thereof.
Background technology
Along with the development of urban construction and the progress of operating technique, concrete quality parameter and economic target are had higher requirement, promote that concrete develops towards high-strength, lightweight, fluidised form, durable contour performance direction.
Especially over past ten years, because the development of efficient additive and concrete admixture technology,, high performance concrete high-strength for preparation under the ordinary process condition provides favourable technical qualification.In some large scale structures, railway engineering and the public works design, the concrete that C50, C60 label have occurred morely, the C100 high performance concrete also is the focus that domestic and international concrete material is studied over year surplus in the of nearly ten, all drops into a large amount of human and material resources and financial resources both at home and abroad this is studied.In general, existing C 100 high performance concrete compounding processs are as follows:
Under the situation that does not change the various raw material ratios (dewatering) and the concrete slump, reduce the consumption of water, can improve concrete intensity greatly, early strong and later strength improves more than 60% and 20% than the concrete that does not add water reducer respectively, by diminishing, can realize building the high-strength concrete of C100 label.
High efficiency water reducing agent commonly used has following several: naphthalenesulfonate formaldehyde condensation compound, polycyclic aromatic hydrocarbon sulfonate formaldehyde condensation products, melamine sulfonate and formaldehyde polycondensate, para-anilinesulfonic acid formaldehyde condensation products, sulfonated ketone aldehyde polycondensate, polyacrylate and graft copolymer thereof etc.
Generally with high grade cement such as No. 52.5 or No. 62.5, cement consumption is 500kg/m to the gelling material of preparation C100 high-strength concrete 3~700kg/m 3
In order to save cement consumption, concrete admixture commonly used has silica flour isoreactivity mineral spike.
The exciting agent that the mineral spike is commonly used has three classes: I type exciting agent is to mix industrial mineral alkali (A) 3%; II type exciting agent is to mix industrial mineral alkali (A) 3% and vitriol (B) 2%; III type exciting agent is to mix mineral alkali 2% and vitriol (B) 3%.
The technical problem that the C100 high performance concrete is badly in need of solving has following four:
1, because non-common starting material and unconventional production technique such as employing cement of high index make the manufacturing cost of C100 high performance concrete higher relatively.
2, when increasing substantially concrete strength, can not realize improvement and raising to workability of concrete energy and endurance quality.
3, owing to Beijing area aggregate material reason and consolidating material cohesive strength deficiency, be difficult to make the C100 high performance concrete.
4, the C100 high performance concrete moves towards the heavy construction application by testing laboratory and is still waiting realization.
Summary of the invention
The purpose of this invention is to provide a kind of C100 high performance concrete and compound method thereof, solving existing C100 high performance concrete preparation needs special source materials such as cement of high index, complex manufacturing, problem that manufacturing cost is high; And solve when increasing substantially concrete strength, improve the technical problem of workability of concrete and weather resistance.
For achieving the above object, the present invention adopts following technical scheme:
This C100 high performance concrete is formed by gelling material, sand, stone, water and admixture mixing, gelling, comprises cement and adulterant in the gelling material, and it is characterized in that: the add-on of gelling material is every cubic meter of concrete 500~600kg, wherein,
Cement: be 42.5 cement;
Adulterant: containing volume is the active SiO of gelling material gross weight 20%~40% 2, its specific surface area 10001200m 2/ kg;
Admixture: volume is the high-efficiency water-reducing agent of poly-carboxylic acid of gelling material gross weight 2%~5%;
Exciting agent: volume is the cigarette ash of gelling material gross weight 1~5% and the mixture that the coal gangue fine powder is formed.
The solid content of above-mentioned high-efficiency water-reducing agent of poly-carboxylic acid is 18%~30%, and water-reducing rate is 30%~45%.
Above-mentioned 42.5 cement are normal silicate 42.5 cement or silicate 42.5 cement.
Silica flour, flyash and three kinds of components of slag powders are arranged in the above-mentioned adulterant, and the weight ratio of above-mentioned three kinds of components is: 1: (1~3): (1~3).
The specific surface area of above-mentioned exciting agent is 600 ± 50m 2/ kg contains the cigarette ash that accounts for gross weight 5070% and 3050% coal gangue fine powder in the mixture.
Above-mentioned C100 high performance concrete is characterized in that every cubic metre mixing ratio by weight is:
Water-cement ratio (water/gelling material): 0.24-0.28;
Sand coarse aggregate ratio: 34-40%;
Cement: 400-500kg/m 3
Admixture: 10-30kg/m 3
Fine aggregate: 600-750kg/m 3
Coarse aggregate: 1000-1100kg/m 3
Additive: 100-200kg/m 3
Exciting agent: 5-30kg/m 3
The compound method of above-mentioned C100 high performance concrete is characterized in that following steps are arranged: sand, stone, cement, adulterant, admixture, exciting agent are put into forced mixer stirred for 5 seconds, add restir discharging in 180 seconds behind the water.
The new approaches that C100 high performance concrete of the present invention provides the diversification direction to develop are suitable for other permanent concrete structure engineerings such as Highrise buildings, highway, railway and bridge.Compared with prior art the present invention has following characteristics and beneficial effect:
1. the present invention adopts conventional raw materials such as common label cement, makes the C100 high performance concrete with conventional production technique, utilizes industrial waste in large quantities, and manufacturing cost is relatively low.
Economic analysis of the present invention: C100 high performance concrete, adopt P.O42.5 ordinary Portland cement, clean medium sand and rubble, high efficiency water reducing agent and the high-quality adulterant that quality is hard, grating is good, do not adopt special starting material, do not change conventional construction technology yet, its cost value is suitable with commercial goods concrete price, C100 concrete replaced C 40 concrete, deadweight can alleviate 40%, reduces cost 16%; C100 replaced C 35 concrete, constant as weight, can save steel 40%, reduce cost 14%.It not only can save a large amount of concrete, but also can increase usage space about 10%.
2. added special exciting agent and high-efficiency water-reducing agent of poly-carboxylic acid in this concrete, made concrete intensity reach f Cu, 28〉=115MPa, favorable working performance: the slump 〉=200mm, internal mobility remained unchanged substantially in 5 hours, good endurance: freeze-thaw-circulation>300 times, impervious grade>P35, chloride diffusion coefficient>2 * 10 -8Cm 2/ s has realized when increasing substantially concrete strength, has improved workability of concrete energy and endurance quality, makes it possess the principal character of high performance concrete.
3. special exciting agent contains cigarette ash and coal gangue fine powder, cigarette ash is the thin ash in the iron-smelting furnace chimney, to corrode glassiness shell and to expose active higher kernel, can improve the activity of gelling material, and improved the flowability of mixture effectively, fundamentally solved by aggregate material reason and consolidating material cohesive strength not enough and can not prepare the difficulty of C100 high performance concrete.The mineralogical composition of exciting agent is as metakaolin, illite etc.The basic active of these mineralogical compositions is much higher than the basic active of flyash, the gel state material that generates in initial reaction stage played the effect that improves gelling material and aggregate interface, and excited the latent hydraulicity of noncrystalline attitude silicon-dioxide and pentacoordinate aluminium in the flyash.
4. adopt the C100 high performance concrete of compound method preparation of the present invention all very easy from producing to the whole process of constructing, workability of concrete can be good, thickness not, do not emanate, be easy to cast, good from close performance, mechanical property and endurance quality have all satisfied design requirements, and greatly reduce the manufacturing cost of C100 high performance concrete, realized that the C100 high performance concrete is moved towards the practical application of heavy construction by testing laboratory, help the construction and the on-the-spot quality control of ready mixed concrete, and C100 high performance concrete rigidity is big, be out of shape little, good endurance, can bear the erosion of severe environment, extending structure work-ing life, be particularly suitable for the railway of large span, the beam column of highway bridge and Highrise buildings etc.
Embodiment
Embodiment: this C100 high performance concrete, formed by gelling material, sand, stone, water and admixture mixing, gelling, comprise cement and adulterant in the gelling material, it is characterized in that: the add-on of gelling material is every cubic meter of concrete 500~600kg, wherein
Cement: be 42.5 cement;
Adulterant: containing volume is the active SiO of silica flour of gelling material gross weight 20%~40% 2, its specific surface area 1050m 2/ kg;
Admixture: volume is the high-efficiency water-reducing agent of poly-carboxylic acid of gelling material gross weight 2%~5%;
The solid content of above-mentioned high-efficiency water-reducing agent of poly-carboxylic acid is 18%~30%, and water-reducing rate is 30%~45%.
Above-mentioned 42.5 cement are normal silicate 42.5 cement or silicate 42.5 cement.
Also contain flyash and slag powders in the above-mentioned adulterant except that silica flour, the weight ratio of above-mentioned silica flour, flyash and three kinds of components of slag powders is: 1: (1~3): (1~3).
Also add the exciting agent that volume is a gelling material gross weight 1~5% in the above-mentioned gelling material, volume is the cigarette ash of gelling material gross weight 1~5% and the mixture that the coal gangue fine powder is formed.The specific surface area of exciting agent is 600 ± 50m 2/ kg contains the cigarette ash that accounts for gross weight 50-70% and the coal gangue fine powder of 30-50% in the mixture.
The mixing ratio by weight that the C100 high performance concrete is every cubic metre is:
Water-cement ratio W/C (water/gelling material): 0.24-0.28; Water should adopt tap water, not handy seawater or sewage preparation, and reply water quality is analyzed when adopting underground water, must not contain the deleterious composition of cement;
Sand coarse aggregate ratio Sp (%): 34-40%; Sand coarse aggregate ratio can be according to the workability and the Concrete Construction of concrete mix
Performance is adjusted, and is generally 36-38%;
Cement (C): 400-500kg/m 3Select for use steady quality, strength grade to be not less than 42.5 grades silicon
Acid salt cement; Cement consumption generally is no less than 400kg/m 3
Admixture (W): 10-30kg/m 3
Fine aggregate (S): 600-750kg/m 3Fineness modulus should be greater than 2.6, and silt content should be greater than 1.0%
, must not contain clod, other indexs should meet " regular concrete sand quality mark
Standard and method of inspection " JGJ52;
Coarse aggregate (G): 1000-1100kg/m 3, should adopt the good rubble of grating, maximum particle diameter should be not big
In 25mm, faller gill shape granule content should be greater than 5.0%, silt content not should greater than
0.5%, must not contain clod, other indexs should meet " normal concrete stone
Quality standard and method of inspection " regulation of JGJ53;
Adulterant: 100-200kg/m 3, the main component of silica flour is active SiO 2, CaO, Al 2O 3,
Its specific surface area 1000-1200m 2/ kg; Binder total amount is no more than
600kg/m 3
Exciting agent: volume is the cigarette ash of gelling material gross weight 1~5% and mixing of coal gangue fine powder composition
Compound.The specific surface area 600-700m of cigarette ash 2/ kg, the ratio table of coal gangue fine powder
Area 400-500m 2/ kg.
The compound method of above-mentioned C100 high performance concrete is characterized in that following steps are arranged: sand, stone, cement, adulterant, admixture are put into forced mixer simultaneously stirred for 5 seconds, add restir discharging in 180 seconds behind the water.
The preparation strength of C100 high performance concrete can be by " design of common concrete proportioning technical regulation " regulation (JGJ/T55-1996), as calculated, examination join, adjust come definite.Preparation strength f Cu, oFor: f Cu, o=f Cu, k-1.645
In the formula: f Cu, o-high performance concrete preparation strength (MPa)
f Cu, kThe standard value of-high performance concrete (MPa)
The standard deviation of σ-high performance concrete (MPa)
As no data, when design strength was C100, σ got 6Mpa.
After proportioning is determined, still use the revision test that this proportioning is no less than 6 times and verify that its mean value should not be lower than preparation strength.
Each component ratio of C100 high performance concrete is given an example:
W/C Sp (%) C kg/m 3 S kg/m 3 G kg/m 3 W2 kg/m 3 Adulterant kg/m 3 Exciting agent kg/m 3
0.26 36 450 614 1092 30.0 150 15
0.27 36 480 614 1092 27.0 120 12
0.26 36 420 614 1092 30.0 180 18
0.25 38 420 648 1058 32.0 180 18
0.25 34 450 580 1126 32.0 150 15

Claims (7)

1. a C100 high performance concrete is formed by gelling material, sand, stone, water and admixture mixing, gelling, comprises cement and adulterant in the gelling material, and it is characterized in that: the add-on of gelling material is every cubic meter of concrete 500~600kg, wherein,
Cement: be 42.5 cement;
Adulterant: containing volume is the active SiO2 of gelling material gross weight 20%~40%, its specific surface area 1000-1200m2/kg;
Admixture: volume is the high-efficiency water-reducing agent of poly-carboxylic acid of gelling material gross weight 2%~5%;
Exciting agent: volume is the cigarette ash of gelling material gross weight 1~5% and the mixture that the coal gangue fine powder is formed.
2. C100 high performance concrete according to claim 1 is characterized in that: the solid content of above-mentioned high-efficiency water-reducing agent of poly-carboxylic acid is 18%~30%, and water-reducing rate is 30%~45%.
3. C100 high performance concrete according to claim 1 is characterized in that: above-mentioned 42.5 cement are normal silicate 42.5 cement or silicate 42.5 cement.
4. C100 high performance concrete according to claim 1 is characterized in that: silica flour, flyash and three kinds of components of slag powders are arranged in the above-mentioned adulterant, and the weight ratio of above-mentioned three kinds of components is: 1: (1~3): (1~3).
5. according to any described C100 high performance concrete of claim 1-4, it is characterized in that: the specific surface area of above-mentioned exciting agent is 600 ± 50m2/kg, contains the cigarette ash that accounts for gross weight 50-70% and the coal gangue fine powder of 30-50% in the mixture.
6. C100 high performance concrete according to claim 5 is characterized in that every cubic metre mixing ratio by weight is:
Water-cement ratio (water/gelling material): 0.24-0.28;
Sand coarse aggregate ratio: 34-40%;
Cement: 400-500kg/m3;
Admixture: 10-30kg/m3;
Fine aggregate: 600-750kg/m3;
Coarse aggregate: 1000-1100kg/m3;
Additive: 100-200kg/m3;
Exciting agent: 5-30kg/m3.
7. a claim 1 or 2 or 3 or the compound method of 4 or 6 any described C100 high performance concretes, it is characterized in that following steps are arranged: sand, stone, cement, adulterant, admixture, exciting agent are put into forced mixer stirred for 5 seconds, add restir discharging in 180 seconds behind the water.
CNB2007102011320A 2007-07-19 2007-07-19 C100 high-performance concrete and formulation method thereof Active CN100509688C (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503283A (en) * 2011-11-10 2012-06-20 江苏建华管桩有限公司 High-performance concrete and preparation method thereof
CN102690090A (en) * 2012-06-21 2012-09-26 江苏建华管桩有限公司 Concrete doped with cement modification agent and preparation method for concrete
CN102757195A (en) * 2012-08-03 2012-10-31 中建商品混凝土有限公司 High strength concrete composite admixture, preparation method and application thereof
CN101560080B (en) * 2009-05-25 2013-06-19 中煤第七十一工程处 Coal mine freezing deep well C100 concrete and application thereof
CN103265259A (en) * 2012-10-28 2013-08-28 甘肃立之林建材有限公司 Concrete composite admixture used for manufacturing high-speed railway sleeper and track plate
CN104058676A (en) * 2014-07-15 2014-09-24 宏峰集团(福建)有限公司 High-toughness concrete and preparation method thereof
CN104326709A (en) * 2014-09-21 2015-02-04 山东农业大学 New frost resistant vegetation concrete using gangue as crude aggregate
CN105294006A (en) * 2015-10-23 2016-02-03 上海建工集团股份有限公司 C100-C120 graded ultrahigh-strength concrete having high workability
CN111763043A (en) * 2019-04-02 2020-10-13 四川功予名图文设计有限公司 Mix proportion design method of regenerated all-light concrete
CN112225503A (en) * 2020-10-12 2021-01-15 四川省川铁枕梁工程有限公司 High-performance pre-dispersed silica mortar concrete and preparation method thereof
CN114498234A (en) * 2021-12-20 2022-05-13 陕西建工新能源有限公司 Novel photovoltaic square matrix lightning protection grounding method

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560080B (en) * 2009-05-25 2013-06-19 中煤第七十一工程处 Coal mine freezing deep well C100 concrete and application thereof
CN102503283A (en) * 2011-11-10 2012-06-20 江苏建华管桩有限公司 High-performance concrete and preparation method thereof
CN102690090A (en) * 2012-06-21 2012-09-26 江苏建华管桩有限公司 Concrete doped with cement modification agent and preparation method for concrete
CN102757195A (en) * 2012-08-03 2012-10-31 中建商品混凝土有限公司 High strength concrete composite admixture, preparation method and application thereof
CN102757195B (en) * 2012-08-03 2014-06-18 中建商品混凝土有限公司 High strength concrete composite admixture, preparation method and application thereof
CN103265259A (en) * 2012-10-28 2013-08-28 甘肃立之林建材有限公司 Concrete composite admixture used for manufacturing high-speed railway sleeper and track plate
CN104058676A (en) * 2014-07-15 2014-09-24 宏峰集团(福建)有限公司 High-toughness concrete and preparation method thereof
CN104326709A (en) * 2014-09-21 2015-02-04 山东农业大学 New frost resistant vegetation concrete using gangue as crude aggregate
CN105294006A (en) * 2015-10-23 2016-02-03 上海建工集团股份有限公司 C100-C120 graded ultrahigh-strength concrete having high workability
CN111763043A (en) * 2019-04-02 2020-10-13 四川功予名图文设计有限公司 Mix proportion design method of regenerated all-light concrete
CN112225503A (en) * 2020-10-12 2021-01-15 四川省川铁枕梁工程有限公司 High-performance pre-dispersed silica mortar concrete and preparation method thereof
CN114498234A (en) * 2021-12-20 2022-05-13 陕西建工新能源有限公司 Novel photovoltaic square matrix lightning protection grounding method

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Address after: 100020 No. 297 village head, Songzhuang Town, Songzhuang Town, Beijing, Tongzhou District

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